US20160181636A1 - Open-loop system and method for fuel cell stack start-up with low-voltage source - Google Patents
Open-loop system and method for fuel cell stack start-up with low-voltage source Download PDFInfo
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- US20160181636A1 US20160181636A1 US14/644,844 US201514644844A US2016181636A1 US 20160181636 A1 US20160181636 A1 US 20160181636A1 US 201514644844 A US201514644844 A US 201514644844A US 2016181636 A1 US2016181636 A1 US 2016181636A1
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- fuel cell
- battery
- air compressor
- cell system
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- 239000000446 fuel Substances 0.000 title claims abstract description 136
- 238000000034 method Methods 0.000 title abstract description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000010926 purge Methods 0.000 claims abstract description 31
- 238000004891 communication Methods 0.000 claims abstract description 28
- 239000001257 hydrogen Substances 0.000 claims abstract description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 239000012530 fluid Substances 0.000 claims description 11
- 239000002826 coolant Substances 0.000 description 8
- 238000009792 diffusion process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
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- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
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- H01M16/00—Structural combinations of different types of electrochemical generators
- H01M16/003—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
- H01M16/006—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers of fuel cells with rechargeable batteries
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- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Definitions
- the present disclosure relates to a fuel cell system and, more particularly, to a start-up system and open-loop method for starting a fuel cell stack.
- a fuel cell has been proposed as a clean, efficient and environmentally responsible energy source for electric vehicles and various other applications.
- the fuel cell has been identified as a potential alternative for the traditional internal-combustion engine used in modern vehicles.
- the PEM fuel cell typically includes three basic components: a cathode, an anode, and an electrolyte membrane.
- the cathode and anode typically include a finely divided catalyst, such as platinum, supported on carbon particles and mixed with an ionomer.
- the electrolyte membrane is sandwiched between the cathode and the anode to form a membrane-electrolyte-assembly (MEA).
- MEA membrane-electrolyte-assembly
- the MEA is often disposed between porous diffusion media (DM) which facilitate a delivery of gaseous reactants, typically hydrogen and oxygen from air, for an electrochemical fuel cell reaction.
- DM porous diffusion media
- the fuel cell stack is capable of supplying a quantity of electricity sufficient to provide power to a vehicle.
- hydrogen gas is supplied to the anodes from a hydrogen storage source, such as a pressurized hydrogen tank.
- the air is supplied to the cathodes by an air compressor unit.
- a low-voltage battery is typically employed to power vehicle components and the air compressor unit prior to operation of the fuel cell stack.
- a high-voltage hybrid battery adapted to store electrical energy from previous vehicle operation may also be used as a source of electrical energy prior to fuel cell stack operability. Start-up with the low-voltage battery is also generally necessary with fuel cell vehicles in freezing conditions.
- the fuel cell system and method provides an efficient start-up while meeting emissions and fuel cell performance requirements, for example, under freezing conditions.
- the fuel cell system and method provides a robust system start-up with minimal voltage instability, and minimizes stack degradation by optimizing the hydrogen-air front time during the start-up.
- a fuel cell system and method that provides a low-voltage start-up while meeting emissions and fuel cell performance requirements, provides a robust system start-up with minimal voltage instability, and minimizes the hydrogen-air front time during the start-up, is surprisingly discovered.
- a fuel cell system in one embodiment, includes a fuel cell stack having a plurality of fuel cells, a cathode inlet, and an anode inlet.
- An air compressor is in fluid communication with the cathode inlet.
- a hydrogen source is in fluid communication with the anode inlet.
- the fuel cell system includes a start-up battery in electrical communication with the air compressor.
- a power conversion module is in electrical communication with the start-up battery and the air compressor. The power conversion module is adapted to selectively boost a voltage of the start-up battery supplied to the air compressor at start-up.
- a controller is in electrical communication with the power conversion module and is adapted to set an air compressor speed based on an available electrical energy.
- a method of operating the fuel cell system at start-up includes the steps of: receiving a start request; and enabling a power conversion module to boost the voltage of the low-voltage battery.
- the available electrical energy from the boosted low-voltage battery, and an estimated speed of the air compressor based on the available electrical energy, are then determined.
- the air compressor is started and is set to the estimated speed.
- An actual speed of the air compressor is measured, and an anode purge based on the available electrical energy is scheduled when one of a) the actual speed is greater than a desired speed, and b) a compressor ramp-up time has elapsed.
- the provided method includes the step of determining the available electrical energy from at least one of a) the low-voltage battery with a voltage boost, b) a high-voltage battery with a voltage boost, and c) the high-voltage battery without a voltage boost.
- the start-up battery is then selected from one of the low-voltage battery and the high-voltage battery, in boosted and non-boosted states, having the greater available electrical energy.
- FIG. 1 illustrates a schematic, exploded perspective view of a PEM fuel cell stack of the prior art, showing only two cells;
- FIG. 2 is a schematic diagram of a fuel cell system having a low-voltage battery according to an embodiment of the present disclosure
- FIG. 3 is a schematic diagram of the fuel cell system of FIG. 2 , further including a high-voltage battery;
- FIG. 4 is a schematic flow diagram showing a start-up method without an operable high-voltage battery.
- FIG. 5 is a schematic flow diagram showing a start-up method with an operable high-voltage battery.
- FIG. 1 depicts a fuel cell stack 2 having a pair of MEAs 4 , 6 separated from each other by an electrically conductive bipolar plate 8 .
- a two-cell stack i.e. one bipolar plate
- FIG. 1 depicts a fuel cell stack 2 having a pair of MEAs 4 , 6 separated from each other by an electrically conductive bipolar plate 8 .
- a two-cell stack i.e. one bipolar plate
- the MEAs 4 , 6 and bipolar plate 8 are stacked together between a pair of clamping plates 10 , 12 and a pair of unipolar end plates 14 , 16 .
- the clamping plates 10 , 12 are electrically insulated from the end plates 14 , 16 by a gasket or a dielectric coating (not shown).
- the unipolar end plates 14 , both working faces of the bipolar plate 8 , and the unipolar end plate 16 include flowfields 18 , 20 , 22 , 24 .
- the flow fields 18 , 20 , 22 , 24 distribute hydrogen gas and air over an anode and a cathode, respectively, of the MEAs 4 , 6 .
- Nonconductive gaskets 26 , 28 , 30 , 32 provide seals and an electrical insulation between the several components of the fuel cell stack 2 .
- Gas-permeable diffusion media 34 , 36 , 38 , 40 abut the anodes and the cathodes of the MEAs 4 , 6 .
- the end plates 14 , 16 are disposed adjacent the diffusion media 34 , 40 , respectively, while the bipolar plate 8 is disposed adjacent the diffusion media 36 on the anode face of MEA 4 .
- the bipolar plate 8 is further disposed adjacent the diffusion media 38 on the cathode face of MEA 6 .
- the bipolar plate 8 , unipolar end plates 14 , 16 , and the gaskets 26 , 28 , 30 , 32 each include a cathode supply aperture 72 and a cathode exhaust aperture 74 , a coolant supply aperture 75 and a coolant exhaust aperture 77 , and an anode supply aperture 76 and an anode exhaust aperture 78 .
- Supply manifolds and exhaust manifolds of the fuel cell stack 2 are formed by an alignment of the respective apertures 72 , 74 , 75 , 77 , 76 , 78 in the bipolar plate 8 , unipolar end plates 14 , 16 , and the gaskets 26 , 28 , 30 , 32 .
- the hydrogen gas is supplied to an anode supply manifold via an anode inlet conduit 80 .
- the air is supplied to a cathode supply manifold of the fuel cell stack 2 via a cathode inlet conduit 82 .
- An anode outlet conduit 84 and a cathode outlet conduit 86 are also provided for an anode exhaust manifold and a cathode exhaust manifold, respectively.
- a coolant inlet conduit 88 is provided for supplying liquid coolant to a coolant supply manifold.
- a coolant outlet conduit 90 is provided for removing coolant from a coolant exhaust manifold.
- FIG. 2 shows a fuel cell system 200 according to an embodiment of the invention.
- the fuel cell system 200 includes the fuel cell stack 2 having a plurality of fuel cells.
- the fuel cell stack 2 includes the anode inlet 80 , the cathode inlet 82 , the anode outlet 84 , and the cathode outlet 86 , each in fluid communication with the respective anodes and cathodes of the fuel cell stack 2 .
- the fuel cell stack 2 is connected to an electrical load, such as an electrical drive motor (not shown) of a non-hybrid or hybrid fuel cell vehicle.
- the fuel cell system 200 includes an air compressor 202 in fluid communication with the cathode inlet 82 .
- the air compressor 202 is adapted to receive air, for example, from the ambient atmosphere and supply the air to the cathodes of the fuel cell stack 2 .
- a speed of the air compressor 202 is adjustable based on the electrical energy employed to operate the air compressor 202 .
- a particularly suitable air compressor 202 may have a maximum operational speed of about 80 , 000 rpm.
- the speed of the air compressor 202 may be adjusted by alternative suitable means known in the art for providing a desired flow rate of air to the fuel cell stack 2 .
- the fuel cell system 200 further includes a bypass valve 204 disposed between the air compressor 202 and the fuel cell stack 2 .
- the bypass valve 204 is adapted to direct a flow of the air from the air compressor 202 around the fuel cell stack 2 , or to the fuel cell stack 2 , as desired.
- the bypass valve 204 directs the flow of air from the air compressor 202 to an exhaust. The air intermixes with and dilutes residual reactants and products exhausted from the fuel cell stack 2 .
- the fuel cell system 200 includes a water vapor transfer (WVT) unit 206 , as is known in the art.
- WVT water vapor transfer
- the WVT unit 206 is in fluid communication with both the air compressor 202 and the cathode inlet 82 of the fuel cell stack 2 .
- the WVT unit 206 is adapted to humidify the air provided by the air compressor 202 to a level desirable for efficient operation of the fuel cell stack 2 .
- the fuel cell system 200 further includes a hydrogen source 208 , such as a high pressure storage container for storage of compressed hydrogen gas.
- the hydrogen source 208 is in fluid communication with the anode inlet 80 of the fuel cell stack 2 and is adapted to supply hydrogen to the anodes of the fuel cell stack 2 .
- the fuel cell system 2 may include a regulator valve 210 in fluid communication with the hydrogen source 208 and the fuel cell stack 2 .
- the regulator valve 210 is configured to control a flow rate of the hydrogen gas from the hydrogen source 208 . It should be appreciated that the timing of the flow of the hydrogen gas to the fuel cell stack 2 may also be scheduled via the regulator valve 210 .
- the fuel cell system 200 of the disclosure has a start-up battery adapted to power fuel cell system 200 components, such as the air compressor 202 at start-up.
- the start-up battery is a low-voltage battery 212 .
- the low-voltage battery may be the only energy source available to power the air compressor 202 until the fuel cell stack 2 is operational.
- Nonlimiting examples of the low-voltage battery 212 includes a 12 V battery, a 36 V battery, and a 48 V battery. Other suitable low-voltage battery types and voltages may be selected as desired.
- the fuel cell system 200 further includes a power conversion module (PCM) 214 .
- the PCM 214 boosts a low voltage to a higher voltage that can be used by fuel cell system 200 components during start-up, for example.
- the PCM 214 is in electrical communication with the low-voltage battery 212 and the air compressor 202 .
- the PCM 214 is configured to boost a voltage output of the low-voltage battery 212 , thereby providing a voltage sufficient to operate the air compressor 202 and supply the flow of air to the exhaust of the fuel cell stack 2 .
- the PCM 214 is a bi-directional converter.
- suitable devices adapted to increase or decrease the voltage output of a battery may be employed as desired.
- a controller 216 may also be employed in the fuel cell system 200 of the disclosure.
- the controller 216 may be in electrical communication with the bypass valve 204 , for example, and selectively direct the flow of the air.
- the controller 216 is in electrical communication with the PCM 214 and is adapted to set an air compressor 202 speed based on the available electrical energy.
- the controller 216 can also be adapted to control the regulator valve 210 , for example, by scheduling the timing and flow rate of hydrogen to the fuel cell stack 2 . As described further herein, the scheduling of the flow rate may be based on the available electrical energy from the PCM 214 .
- the fuel cell system 200 may include a variety of sensors adapted to provide system input. The system input from the sensors may be provided to the controller 216 .
- the fuel cell system 200 includes at least one voltage sensor adapted to measure, for example, a voltage of the low-voltage battery 212 .
- the fuel cell system 200 also may have at least one sensors adapted to measure the available electrical energy of the start-up battery, such as the electrical power or state of charge (SOC) of the start-up battery.
- SOC state of charge
- the fuel cell system 200 further includes a speed sensor 220 .
- the speed sensor 220 may be adapted to measure an actual speed of the air compressor 202 in operation, for example. The actual speed may be a rotational speed of the air compressor 202 .
- the fuel cell system 200 of the disclosure may further include a high-voltage battery 300 .
- the high-voltage battery 300 is in selective electrical communication with the PCM 214 and the air compressor 202 and may be used as the start-up battery.
- the high-voltage battery 300 when sufficiently charged, has an electrical energy sufficient to operate the air compressor 202 during a start-up of the fuel cell system 200 .
- the high-voltage battery 300 may have a voltage of up to about 500 V.
- the high-voltage battery has a voltage from about 250 V to about 400 V.
- the high-voltage battery 300 is a hybrid battery adapted to store electrical energy generated from previous vehicle operation, for example, from a braking operation.
- the at least one voltage sensor 218 may be configured to measure a voltage of the high-voltage battery 300 . The measured voltage of the high-voltage battery 300 may thereby be provided to the controller 216 .
- the present disclosure further includes a method for starting the fuel cell stack 2 of the fuel cell system 200 .
- a first method depicted in FIG. 4 may be employed with a vehicle only having access to the low-voltage battery 212 at start-up. Such a vehicle may be a non-hybrid fuel cell vehicle.
- the method includes the step of receiving a start request 400 from an operator.
- the PCM 214 is then activated 402 .
- the activation 402 of the PCM 214 boosts the voltage of the low-voltage battery 212 by increasing the low voltage to a higher voltage that can be used to power the air compressor 202 .
- an available electrical energy from the boosted low-voltage battery 212 is determined.
- the available electrical energy may be determined, for example, by measuring the available electrical energy from the PCM 214 directly. In other embodiments, the available electrical energy may be determined by measuring the voltage of the low-voltage battery 212 and calculating the available electrical energy therefrom.
- An estimated speed of the air compressor 202 is selected 404 based on the available electrical energy. In one particular embodiment, the estimated speed is determined from a look-up table correlating the available electrical energy and the speed of the air compressor 202 . It should be appreciated that the estimated speed may also be based on a calculation relating the estimated speed and the available electrical energy.
- the air compressor 202 is then started and the air compressor 202 is set at the estimated speed. In one example, the air compressor 202 is set at about 40,000 rpm. A skilled artisan should understand that other suitable estimated speeds may also be employed.
- the method of the disclosure further includes a step 406 of measuring an actual speed of the air compressor 202 and comparing the measured actual speed with a desired speed.
- an anode purge based on the available electrical energy is scheduled.
- the anode purge is scheduled in a scheduling step 408 .
- the desired speed is selected to provide a sufficient flow of air to the exhaust of the fuel cell system 200 in a time-optimized manner.
- the desired speed may be the difference between the estimated speed and a pre-selected “delta speed.”
- the delta speed may be about 2000 rpm, and the estimated speed about 60,000 rpm, resulting in a desired speed of about 58,000 rpm.
- the desired speed is a percentage of the estimated speed.
- the anode purge may be triggered when the actual speed approaches the desired speed.
- the anode purge scheduling step 408 may be performed.
- the set time may be sufficient for the air compressor 202 to provide an estimated sufficient air flow to the exhaust.
- the elapsed time may be particularly useful for triggering the anode purge scheduling step 408 when the estimated speed remains greater than the actual speed for the desired length of time.
- the time for the air compressor to ramp up may be about 5 seconds.
- the elapsed time may be an estimate based on the available electrical energy from the start-up battery and the estimated speed desired for the air compressor 202 to ramp to. Suitable time limits within which to perform the scheduling step 410 may be selected as desired.
- the anode purge scheduling step 408 includes at least one of the steps of a) setting a time for the anode purge, and b) setting a flow rate for the anode purge.
- at least one of the estimated speed and the anode purge flow rate is calculated from a look-up table.
- the look-up table provides a relationship to the available electrical energy for start-up, and is adapted to maintain an exhausted hydrogen concentration of less than a desired amount.
- the preferred concentration of exhausted hydrogen is less than about four percent (4%) by volume, although other concentrations may be targeted.
- the anode purge step is followed by a step of providing a controlled flow of hydrogen to the anodes and a step of diverting the air flow to the cathodes, wherein the fuel cell stack 2 is placed in an operational mode.
- the method of the disclosure may be used with a vehicle having access to both the low-voltage battery 212 and the high-voltage battery 300 at start-up.
- a vehicle may be a hybrid fuel cell vehicle.
- the method includes an energy source selection step 500 .
- the energy source selection step 500 includes determining the available electrical energy from at least one of a) the low-voltage battery 212 with a voltage boost, b) the high-voltage battery 300 with a voltage boost, and c) the high-voltage battery 300 without the voltage boost.
- a start-up battery particularly employable in the start-up operation of the fuel cell stack 2 is selected from the strongest energy source.
- the low-voltage battery 212 is selected if the available electrical energy from the low-voltage battery 212 is greater than the available electrical energy from the high-voltage battery 300 .
- the high-voltage battery 300 is selected as the start-up battery if the available electrical energy from the low-voltage battery is less than the available electrical energy form the high-voltage battery 300 .
- the high-voltage battery 300 is selected if the available electrical energy from the high-voltage battery 300 is within a desired start-up energy range.
- the desired start-up energy range may be a power greater than about 1.5 kW.
- the desired start-up energy range is a power greater than about 1.8 kW.
- the desired start-up energy range is a power greater than about 2.0 kW.
- a suitable start-up energy range adapted to select the start-up battery may be chosen as desired.
- the selected start-up battery may alternate between the low-voltage battery 212 and the high-voltage battery 300 .
- the fuel cell system 200 may switch to the low-voltage battery 212 to complete the start-up operation. The employment of the strongest source of energy throughout the start-up operation is thereby facilitated.
- the employment of the available electrical energy in selecting the start-up battery may be particularly useful in vehicles employing a high-voltage battery 300 that is a hybrid battery.
- the hybrid battery directly powers the air compressor 202 during the start-up operation.
- the low-voltage battery 212 may be employed to start-up the fuel cell stack 2 if the SOC of the hybrid battery is insufficient.
- the PCM 214 may be employed to boost the voltage of the low SOC hybrid battery if the hybrid battery has the electrical energy within the desired energy range, and would provide a greater electrical energy than the low-voltage battery 212 .
- the present method facilitates the use of the strongest energy source in starting the fuel cell stack 2 .
- the present method also provides a system redundancy at fuel cell start-up, militating against a start-up failure due to insufficient battery SOC or inoperability of one or more vehicle batteries.
- the method of the invention is an “open-loop” method, as opposed to a “closed-loop” method where system feedback is employed to determine anode purge conditions.
- the anode purge in the open-loop method is scheduled in response to the initial determination of the available electrical energy from at least one of the low-voltage battery 212 and the high-voltage battery 300 .
- the determination of the available electrical energy for start-up of the fuel cell stack 2 enables an estimation of both the speed of the air compressor 202 and the resulting flow rate of air that will be provided to the exhaust of the fuel cell system 200 .
- the anode purge may be scheduled accordingly so that the concentration of hydrogen in the exhaust does not exceed the desired level.
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Abstract
A fuel cell system is provided that includes a fuel cell stack and an air compressor in communication with a cathode inlet, a hydrogen source in communication with an anode inlet, and a start-up battery adapted to power the air compressor. The start-up battery is at least one of a low-voltage battery and a high-voltage battery. A power conversion module is in electrical communication with the start-up battery and the air compressor. The power conversion module is adapted to boost a voltage of the start-up battery as desired and power the air compressor at start-up. A controller is in communication with the power conversion module and is adapted to set an air compressor speed based on an available electrical energy. An open-loop method of operating the fuel cell system at start-up is also provided, wherein an anode purge is scheduled based on the available electrical energy from the battery.
Description
- This application is a divisional of U.S. patent application Ser. No. 11/860,121 filed on Sep. 24, 2007, now U.S. Pat. No. ______. The entire disclosure of the above application is hereby incorporated herein by reference.
- The present disclosure relates to a fuel cell system and, more particularly, to a start-up system and open-loop method for starting a fuel cell stack.
- A fuel cell has been proposed as a clean, efficient and environmentally responsible energy source for electric vehicles and various other applications. In particular, the fuel cell has been identified as a potential alternative for the traditional internal-combustion engine used in modern vehicles.
- One type of fuel cell is known as a proton exchange membrane (PEM) fuel cell. The PEM fuel cell typically includes three basic components: a cathode, an anode, and an electrolyte membrane. The cathode and anode typically include a finely divided catalyst, such as platinum, supported on carbon particles and mixed with an ionomer. The electrolyte membrane is sandwiched between the cathode and the anode to form a membrane-electrolyte-assembly (MEA). The MEA is often disposed between porous diffusion media (DM) which facilitate a delivery of gaseous reactants, typically hydrogen and oxygen from air, for an electrochemical fuel cell reaction.
- Individual fuel cells can be stacked together in series to form a fuel cell stack. The fuel cell stack is capable of supplying a quantity of electricity sufficient to provide power to a vehicle. In a vehicle power system employing the fuel cell stack, hydrogen gas is supplied to the anodes from a hydrogen storage source, such as a pressurized hydrogen tank. The air is supplied to the cathodes by an air compressor unit. In a non-hybrid fuel cell vehicle or a hybrid vehicle with an inoperable high-voltage battery, a low-voltage battery is typically employed to power vehicle components and the air compressor unit prior to operation of the fuel cell stack. In a hybrid fuel cell vehicle, a high-voltage hybrid battery adapted to store electrical energy from previous vehicle operation may also be used as a source of electrical energy prior to fuel cell stack operability. Start-up with the low-voltage battery is also generally necessary with fuel cell vehicles in freezing conditions.
- During start-up of the fuel cell system, hydrogen gas is used to purge the anodes of air accumulated during shut-down. The purge is desirably rapid to minimize the known carbon degradation that occurs as the hydrogen-air front moves across the anodes. Air is also bypassed to an exhaust of a fuel cell stack during start-up to dilute exhausted purge hydrogen. Vehicle emissions standards generally require the exhausted hydrogen concentration to be less than four percent (4%) by volume. However, due to the inconsistent conditions of the fuel cell system following a shut-down period, including battery state of charge (SOC) and a variable quantity of accumulated air on the anodes, known fuel cell systems are not particularly effective in optimizing hydrogen emissions and minimizing carbon corrosion during start-up.
- There is a continuing need for a fuel cell system and method that provides an efficient start-up while meeting emissions and fuel cell performance requirements, for example, under freezing conditions. Desirably, the fuel cell system and method provides a robust system start-up with minimal voltage instability, and minimizes stack degradation by optimizing the hydrogen-air front time during the start-up.
- In concordance with the instant disclosure, a fuel cell system and method that provides a low-voltage start-up while meeting emissions and fuel cell performance requirements, provides a robust system start-up with minimal voltage instability, and minimizes the hydrogen-air front time during the start-up, is surprisingly discovered.
- In one embodiment, a fuel cell system is provided. The fuel cell system includes a fuel cell stack having a plurality of fuel cells, a cathode inlet, and an anode inlet. An air compressor is in fluid communication with the cathode inlet. A hydrogen source is in fluid communication with the anode inlet. The fuel cell system includes a start-up battery in electrical communication with the air compressor. A power conversion module is in electrical communication with the start-up battery and the air compressor. The power conversion module is adapted to selectively boost a voltage of the start-up battery supplied to the air compressor at start-up. A controller is in electrical communication with the power conversion module and is adapted to set an air compressor speed based on an available electrical energy.
- In another embodiment, a method of operating the fuel cell system at start-up is also provided. The method first includes the steps of: receiving a start request; and enabling a power conversion module to boost the voltage of the low-voltage battery. The available electrical energy from the boosted low-voltage battery, and an estimated speed of the air compressor based on the available electrical energy, are then determined. The air compressor is started and is set to the estimated speed. An actual speed of the air compressor is measured, and an anode purge based on the available electrical energy is scheduled when one of a) the actual speed is greater than a desired speed, and b) a compressor ramp-up time has elapsed.
- In a further embodiment, the provided method includes the step of determining the available electrical energy from at least one of a) the low-voltage battery with a voltage boost, b) a high-voltage battery with a voltage boost, and c) the high-voltage battery without a voltage boost. The start-up battery is then selected from one of the low-voltage battery and the high-voltage battery, in boosted and non-boosted states, having the greater available electrical energy.
- The above, as well as other advantages of the present disclosure, will become readily apparent to those skilled in the art from the following detailed description, particularly when considered in the light of the drawings described hereafter.
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FIG. 1 illustrates a schematic, exploded perspective view of a PEM fuel cell stack of the prior art, showing only two cells; -
FIG. 2 is a schematic diagram of a fuel cell system having a low-voltage battery according to an embodiment of the present disclosure; -
FIG. 3 is a schematic diagram of the fuel cell system ofFIG. 2 , further including a high-voltage battery; -
FIG. 4 is a schematic flow diagram showing a start-up method without an operable high-voltage battery; and -
FIG. 5 is a schematic flow diagram showing a start-up method with an operable high-voltage battery. - The following description is merely exemplary in nature and is not intended to limit the present disclosure, application, or uses. It should also be understood that throughout the drawings, corresponding reference numerals indicate like or corresponding parts and features. In respect of the methods disclosed, the steps presented are exemplary in nature, and thus, are not necessary or critical.
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FIG. 1 depicts afuel cell stack 2 having a pair ofMEAs 4, 6 separated from each other by an electrically conductivebipolar plate 8. For simplicity, only a two-cell stack (i.e. one bipolar plate) is illustrated and described inFIG. 1 , it being understood that a typical fuel cell stack will have many more such cells and bipolar plates. - The
MEAs 4, 6 andbipolar plate 8 are stacked together between a pair ofclamping plates unipolar end plates clamping plates end plates unipolar end plates 14, both working faces of thebipolar plate 8, and theunipolar end plate 16 includeflowfields flow fields MEAs 4, 6. -
Nonconductive gaskets fuel cell stack 2. Gas-permeable diffusion media MEAs 4, 6. Theend plates diffusion media bipolar plate 8 is disposed adjacent thediffusion media 36 on the anode face ofMEA 4. Thebipolar plate 8 is further disposed adjacent thediffusion media 38 on the cathode face of MEA 6. - The
bipolar plate 8,unipolar end plates gaskets cathode supply aperture 72 and acathode exhaust aperture 74, acoolant supply aperture 75 and acoolant exhaust aperture 77, and ananode supply aperture 76 and ananode exhaust aperture 78. Supply manifolds and exhaust manifolds of thefuel cell stack 2 are formed by an alignment of therespective apertures bipolar plate 8,unipolar end plates gaskets anode inlet conduit 80. The air is supplied to a cathode supply manifold of thefuel cell stack 2 via acathode inlet conduit 82. Ananode outlet conduit 84 and acathode outlet conduit 86 are also provided for an anode exhaust manifold and a cathode exhaust manifold, respectively. Acoolant inlet conduit 88 is provided for supplying liquid coolant to a coolant supply manifold. Acoolant outlet conduit 90 is provided for removing coolant from a coolant exhaust manifold. It should be understood that the configurations of thevarious inlets outlets FIG. 1 are for the purpose of illustration, and other configurations may be chosen as desired. -
FIG. 2 shows afuel cell system 200 according to an embodiment of the invention. Thefuel cell system 200 includes thefuel cell stack 2 having a plurality of fuel cells. Thefuel cell stack 2 includes theanode inlet 80, thecathode inlet 82, theanode outlet 84, and thecathode outlet 86, each in fluid communication with the respective anodes and cathodes of thefuel cell stack 2. In a particular embodiment, thefuel cell stack 2 is connected to an electrical load, such as an electrical drive motor (not shown) of a non-hybrid or hybrid fuel cell vehicle. - The
fuel cell system 200 includes anair compressor 202 in fluid communication with thecathode inlet 82. Theair compressor 202 is adapted to receive air, for example, from the ambient atmosphere and supply the air to the cathodes of thefuel cell stack 2. In certain embodiments, a speed of theair compressor 202 is adjustable based on the electrical energy employed to operate theair compressor 202. As a nonlimiting example, a particularlysuitable air compressor 202 may have a maximum operational speed of about 80,000 rpm. A skilled artisan should understand that the speed of theair compressor 202 may be adjusted by alternative suitable means known in the art for providing a desired flow rate of air to thefuel cell stack 2. - The
fuel cell system 200 further includes abypass valve 204 disposed between theair compressor 202 and thefuel cell stack 2. Thebypass valve 204 is adapted to direct a flow of the air from theair compressor 202 around thefuel cell stack 2, or to thefuel cell stack 2, as desired. In one embodiment, thebypass valve 204 directs the flow of air from theair compressor 202 to an exhaust. The air intermixes with and dilutes residual reactants and products exhausted from thefuel cell stack 2. - In certain embodiments, the
fuel cell system 200 includes a water vapor transfer (WVT)unit 206, as is known in the art. A skilled artisan should understand that theWVT unit 206 is in fluid communication with both theair compressor 202 and thecathode inlet 82 of thefuel cell stack 2. TheWVT unit 206 is adapted to humidify the air provided by theair compressor 202 to a level desirable for efficient operation of thefuel cell stack 2. - The
fuel cell system 200 further includes ahydrogen source 208, such as a high pressure storage container for storage of compressed hydrogen gas. Thehydrogen source 208 is in fluid communication with theanode inlet 80 of thefuel cell stack 2 and is adapted to supply hydrogen to the anodes of thefuel cell stack 2. For example, thefuel cell system 2 may include aregulator valve 210 in fluid communication with thehydrogen source 208 and thefuel cell stack 2. Theregulator valve 210 is configured to control a flow rate of the hydrogen gas from thehydrogen source 208. It should be appreciated that the timing of the flow of the hydrogen gas to thefuel cell stack 2 may also be scheduled via theregulator valve 210. - The
fuel cell system 200 of the disclosure has a start-up battery adapted to powerfuel cell system 200 components, such as theair compressor 202 at start-up. In a particularly illustrative embodiment, the start-up battery is a low-voltage battery 212. It should be appreciated that, in afuel cell system 200 employed in the operation of a non-hybrid vehicle, the low-voltage battery may be the only energy source available to power theair compressor 202 until thefuel cell stack 2 is operational. Nonlimiting examples of the low-voltage battery 212 includes a 12 V battery, a 36 V battery, and a 48 V battery. Other suitable low-voltage battery types and voltages may be selected as desired. - The
fuel cell system 200 further includes a power conversion module (PCM) 214. ThePCM 214 boosts a low voltage to a higher voltage that can be used byfuel cell system 200 components during start-up, for example. ThePCM 214 is in electrical communication with the low-voltage battery 212 and theair compressor 202. When enabled, thePCM 214 is configured to boost a voltage output of the low-voltage battery 212, thereby providing a voltage sufficient to operate theair compressor 202 and supply the flow of air to the exhaust of thefuel cell stack 2. In particular embodiments, thePCM 214 is a bi-directional converter. One of ordinary skill in the art should understand that suitable devices adapted to increase or decrease the voltage output of a battery may be employed as desired. - A
controller 216 may also be employed in thefuel cell system 200 of the disclosure. Thecontroller 216 may be in electrical communication with thebypass valve 204, for example, and selectively direct the flow of the air. In a particularly illustrative embodiment, thecontroller 216 is in electrical communication with thePCM 214 and is adapted to set anair compressor 202 speed based on the available electrical energy. Thecontroller 216 can also be adapted to control theregulator valve 210, for example, by scheduling the timing and flow rate of hydrogen to thefuel cell stack 2. As described further herein, the scheduling of the flow rate may be based on the available electrical energy from thePCM 214. - In relation to the
controller 216, thefuel cell system 200 may include a variety of sensors adapted to provide system input. The system input from the sensors may be provided to thecontroller 216. Thefuel cell system 200 includes at least one voltage sensor adapted to measure, for example, a voltage of the low-voltage battery 212. Thefuel cell system 200 also may have at least one sensors adapted to measure the available electrical energy of the start-up battery, such as the electrical power or state of charge (SOC) of the start-up battery. It should be appreciated that the available electrical energy of the start-up battery may be determined by any conventional means known in the art, however. For example, the available electrical energy may be calculated or estimated from one or more conventional measurements of the start-up battery. Thefuel cell system 200 further includes aspeed sensor 220. Thespeed sensor 220 may be adapted to measure an actual speed of theair compressor 202 in operation, for example. The actual speed may be a rotational speed of theair compressor 202. - As shown in
FIG. 3 , thefuel cell system 200 of the disclosure may further include a high-voltage battery 300. The high-voltage battery 300 is in selective electrical communication with thePCM 214 and theair compressor 202 and may be used as the start-up battery. The high-voltage battery 300, when sufficiently charged, has an electrical energy sufficient to operate theair compressor 202 during a start-up of thefuel cell system 200. As nonlimiting examples, the high-voltage battery 300 may have a voltage of up to about 500 V. In a particular example, the high-voltage battery has a voltage from about 250 V to about 400 V. In one embodiment, the high-voltage battery 300 is a hybrid battery adapted to store electrical energy generated from previous vehicle operation, for example, from a braking operation. As illustrated, the at least onevoltage sensor 218 may be configured to measure a voltage of the high-voltage battery 300. The measured voltage of the high-voltage battery 300 may thereby be provided to thecontroller 216. - The present disclosure further includes a method for starting the
fuel cell stack 2 of thefuel cell system 200. A first method depicted inFIG. 4 may be employed with a vehicle only having access to the low-voltage battery 212 at start-up. Such a vehicle may be a non-hybrid fuel cell vehicle. The method includes the step of receiving astart request 400 from an operator. ThePCM 214 is then activated 402. Theactivation 402 of thePCM 214 boosts the voltage of the low-voltage battery 212 by increasing the low voltage to a higher voltage that can be used to power theair compressor 202. - Following the
activation step 402, an available electrical energy from the boosted low-voltage battery 212 is determined. The available electrical energy may be determined, for example, by measuring the available electrical energy from thePCM 214 directly. In other embodiments, the available electrical energy may be determined by measuring the voltage of the low-voltage battery 212 and calculating the available electrical energy therefrom. An estimated speed of theair compressor 202 is selected 404 based on the available electrical energy. In one particular embodiment, the estimated speed is determined from a look-up table correlating the available electrical energy and the speed of theair compressor 202. It should be appreciated that the estimated speed may also be based on a calculation relating the estimated speed and the available electrical energy. Theair compressor 202 is then started and theair compressor 202 is set at the estimated speed. In one example, theair compressor 202 is set at about 40,000 rpm. A skilled artisan should understand that other suitable estimated speeds may also be employed. - The method of the disclosure further includes a
step 406 of measuring an actual speed of theair compressor 202 and comparing the measured actual speed with a desired speed. When the actual speed is greater than the desired speed, an anode purge based on the available electrical energy is scheduled. The anode purge is scheduled in ascheduling step 408. The desired speed is selected to provide a sufficient flow of air to the exhaust of thefuel cell system 200 in a time-optimized manner. The desired speed may be the difference between the estimated speed and a pre-selected “delta speed.” For example, the delta speed may be about 2000 rpm, and the estimated speed about 60,000 rpm, resulting in a desired speed of about 58,000 rpm. In another nonlimiting example, the desired speed is a percentage of the estimated speed. Thus, the anode purge may be triggered when the actual speed approaches the desired speed. - Alternatively, when a set time for the
air compressor 202 to ramp up to the estimated speed has elapsed, the anodepurge scheduling step 408 may be performed. In particular embodiments, the set time may be sufficient for theair compressor 202 to provide an estimated sufficient air flow to the exhaust. The elapsed time may be particularly useful for triggering the anodepurge scheduling step 408 when the estimated speed remains greater than the actual speed for the desired length of time. In a nonlimiting example, the time for the air compressor to ramp up may be about 5 seconds. In another nonlimiting example, the elapsed time may be an estimate based on the available electrical energy from the start-up battery and the estimated speed desired for theair compressor 202 to ramp to. Suitable time limits within which to perform the scheduling step 410 may be selected as desired. - In certain embodiments, the anode
purge scheduling step 408 includes at least one of the steps of a) setting a time for the anode purge, and b) setting a flow rate for the anode purge. As nonlimiting examples, at least one of the estimated speed and the anode purge flow rate is calculated from a look-up table. The look-up table provides a relationship to the available electrical energy for start-up, and is adapted to maintain an exhausted hydrogen concentration of less than a desired amount. The preferred concentration of exhausted hydrogen is less than about four percent (4%) by volume, although other concentrations may be targeted. The anode purge step is followed by a step of providing a controlled flow of hydrogen to the anodes and a step of diverting the air flow to the cathodes, wherein thefuel cell stack 2 is placed in an operational mode. - As depicted in
FIG. 5 , the method of the disclosure may be used with a vehicle having access to both the low-voltage battery 212 and the high-voltage battery 300 at start-up. Such a vehicle may be a hybrid fuel cell vehicle. In one embodiment, after receiving thestart request 400, the method includes an energysource selection step 500. The energysource selection step 500 includes determining the available electrical energy from at least one of a) the low-voltage battery 212 with a voltage boost, b) the high-voltage battery 300 with a voltage boost, and c) the high-voltage battery 300 without the voltage boost. - In the method of the disclosure, a start-up battery particularly employable in the start-up operation of the
fuel cell stack 2 is selected from the strongest energy source. As a nonlimiting example, the low-voltage battery 212 is selected if the available electrical energy from the low-voltage battery 212 is greater than the available electrical energy from the high-voltage battery 300. In another example, the high-voltage battery 300 is selected as the start-up battery if the available electrical energy from the low-voltage battery is less than the available electrical energy form the high-voltage battery 300. - In a further embodiment, the high-
voltage battery 300, without the voltage boost, is selected if the available electrical energy from the high-voltage battery 300 is within a desired start-up energy range. For example, the desired start-up energy range may be a power greater than about 1.5 kW. In a particular example, the desired start-up energy range is a power greater than about 1.8 kW. In a particularly illustrative example, the desired start-up energy range is a power greater than about 2.0 kW. A suitable start-up energy range adapted to select the start-up battery may be chosen as desired. - In another embodiment, the selected start-up battery may alternate between the low-
voltage battery 212 and the high-voltage battery 300. As a nonlimiting example, if the high-voltage battery 300 is initially selected as the start-up battery, but SOC of the high-voltage battery 300 drops below the desired energy range during the start-up operation, thefuel cell system 200 may switch to the low-voltage battery 212 to complete the start-up operation. The employment of the strongest source of energy throughout the start-up operation is thereby facilitated. - It should be appreciated that the employment of the available electrical energy in selecting the start-up battery may be particularly useful in vehicles employing a high-
voltage battery 300 that is a hybrid battery. For example, when the state-of-charge (SOC) of the hybrid battery is sufficient, the hybrid battery directly powers theair compressor 202 during the start-up operation. However, the low-voltage battery 212 may be employed to start-up thefuel cell stack 2 if the SOC of the hybrid battery is insufficient. Alternatively, thePCM 214 may be employed to boost the voltage of the low SOC hybrid battery if the hybrid battery has the electrical energy within the desired energy range, and would provide a greater electrical energy than the low-voltage battery 212. Thus, the present method facilitates the use of the strongest energy source in starting thefuel cell stack 2. The present method also provides a system redundancy at fuel cell start-up, militating against a start-up failure due to insufficient battery SOC or inoperability of one or more vehicle batteries. - A skilled artisan should appreciate that the method of the invention is an “open-loop” method, as opposed to a “closed-loop” method where system feedback is employed to determine anode purge conditions. The anode purge in the open-loop method is scheduled in response to the initial determination of the available electrical energy from at least one of the low-
voltage battery 212 and the high-voltage battery 300. The determination of the available electrical energy for start-up of thefuel cell stack 2 enables an estimation of both the speed of theair compressor 202 and the resulting flow rate of air that will be provided to the exhaust of thefuel cell system 200. Based on the estimated flow rate of air to the exhaust, the anode purge may be scheduled accordingly so that the concentration of hydrogen in the exhaust does not exceed the desired level. - The employment of the strongest energy source during start-up of the
fuel cell stack 2 militates against carbon corrosion by optimizing the rate at which hydrogen can be fed to thefuel cell stack 2. It also should be understood that the estimated compressor speed and the scheduling of the anode purge are adapted to provide the sufficient flow of air to the exhaust. The sufficient flow of air to the exhaust militates against undesirable levels of hydrogen emissions such as levels greater than about four (4) percent, for example. Thus, it is surprisingly found that employment of the open-loop system and method of the disclosure militates againstfuel cell stack 2 degradation and controls vehicle emissions within desired bounds by determining how much and when to feed hydrogen to thefuel cell stack 2, particularly during the anode purge upon start-up. - While certain representative embodiments and details have been shown for purposes of illustrating the invention, it will be apparent to those skilled in the art that various changes may be made without departing from the scope of the disclosure, which is further described in the following appended claims.
Claims (20)
1. A fuel cell system comprising:
a fuel cell stack including a plurality of fuel cells and having an anode inlet and a cathode inlet;
an air compressor in fluid communication with the cathode inlet;
a hydrogen source in fluid communication with the anode inlet;
a start-up battery in electrical communication with the air compressor;
a power conversion module in electrical communication with the start-up battery and the air compressor, the power conversion module configured to selectively boost a voltage of the start-up battery supplied to the air compressor; and
a controller in electrical communication with the power conversion module configured to set an air compressor speed based on an electrical energy available at the compressor.
2. The fuel cell system of claim 1 , wherein the start-up battery includes at least one of a low-voltage battery and a high-voltage battery.
3. The fuel cell system of claim 2 , wherein the high-voltage battery is a hybrid battery.
4. The fuel cell system of claim 1 , further comprising a voltage sensor configured to measure a voltage of the start-up battery.
5. The fuel cell system of claim 1 , further comprising a bypass valve disposed between the air compressor and the cathode inlet, the bypass valve configured to selectively bypass an air flow around the fuel cell stack to an exhaust.
6. The fuel cell system of claim 1 , further comprising a regulator valve disposed between the hydrogen source and the fuel cell stack, the regulator valve configured to selectively supply an anode purge to the fuel cell stack.
7. The fuel cell system of claim 1 , further comprising at least one speed sensor configured to measure a rotational speed of the air compressor.
8. The fuel cell system of claim 1 , wherein the controller is configured to schedule an anode purge based on the available electrical energy in the start-up battery.
9. A fuel cell system comprising:
a fuel cell stack including a plurality of fuel cells and having an anode inlet and a cathode inlet;
an exhaust directly emitting from the fuel cell stack to an environment external to the fuel cell system, an air compressor in fluid communication with the cathode inlet and the exhaust, wherein a flow of air bypasses the fuel cell stack and is provided to the exhaust by the compressor;
a hydrogen source in fluid communication with the anode inlet;
a start-up battery in electrical communication with the air compressor, wherein the start-up battery has an operating voltage less than a fuel cell stack operating voltage;
a power conversion module in electrical communication with the start-up battery and the air compressor, the power conversion module configured to selectively boost a voltage of the start-up battery supplied to the air compressor; and
a controller in electrical communication with the power conversion module configured to set an air compressor speed based on an electrical energy available at the compressor.
10. The fuel cell system of claim 9 , wherein the start-up battery includes at least one of a low-voltage battery and a high-voltage battery.
11. The fuel cell system of claim 10 , wherein the high-voltage battery is a hybrid battery.
12. The fuel cell system of claim 9 , further comprising a voltage sensor configured to measure a voltage of the start-up battery.
13. The fuel cell system of claim 9 , further comprising a bypass valve disposed between the air compressor and the cathode inlet, the bypass valve configured to selectively bypass an air flow around the fuel cell stack to an exhaust.
14. The fuel cell system of claim 9 , further comprising a regulator valve disposed between the hydrogen source and the fuel cell stack, the regulator valve configured to selectively supply an anode purge to the fuel cell stack.
15. The fuel cell system of claim 9 , further comprising at least one speed sensor configured to measure a rotational speed of the air compressor.
16. The fuel cell system of claim 15 , wherein the speed sensor measures an actual speed of the air compressor.
17. The fuel cell system of claim 16 , wherein an anode purge is scheduled when one of (a) the actual speed of the air compressor is greater than a desired speed, and (b) an air compressor ramp up time has elapsed, wherein the anode purge is scheduled by at least one of (i) setting a time for the anode purge, and (ii) setting a flow rate for the anode purge, wherein the flow rate for the anode purge is calculated from a look-up table based on the electrical energy available.
18. The fuel cell system of claim 9 , wherein the controller is configured to schedule an anode purge based on an electrical energy available in the start-up battery.
19. The fuel cell system of claim 18 , wherein the controller is further configured to divert the flow of air from the exhaust to the cathode inlet upon completion of the anode purge.
20. The fuel cell system of claim 9 , wherein no flow of air is provided to the fuel cell stack during an anode purge.
Priority Applications (1)
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US14/644,844 US20160181636A1 (en) | 2007-09-24 | 2015-03-11 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
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US11/860,121 US9005785B2 (en) | 2007-09-24 | 2007-09-24 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
US14/644,844 US20160181636A1 (en) | 2007-09-24 | 2015-03-11 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
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US11/860,121 Division US9005785B2 (en) | 2007-09-24 | 2007-09-24 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
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US20160181636A1 true US20160181636A1 (en) | 2016-06-23 |
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US11/860,121 Expired - Fee Related US9005785B2 (en) | 2007-09-24 | 2007-09-24 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
US14/644,844 Abandoned US20160181636A1 (en) | 2007-09-24 | 2015-03-11 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
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US11/860,121 Expired - Fee Related US9005785B2 (en) | 2007-09-24 | 2007-09-24 | Open-loop system and method for fuel cell stack start-up with low-voltage source |
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US (2) | US9005785B2 (en) |
CN (1) | CN101399355B (en) |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2692475C1 (en) * | 2017-11-09 | 2019-06-25 | Тойота Дзидося Кабусики Кайся | Fuel cell system and method of its control |
RU2692464C1 (en) * | 2017-10-20 | 2019-06-25 | Тойота Дзидося Кабусики Кайся | Fuel cell system and method of controlling fuel cell system |
KR20190108303A (en) | 2018-03-14 | 2019-09-24 | 현대자동차주식회사 | Start up control method and contorl system for fuel cell |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20120020686A (en) | 2010-08-31 | 2012-03-08 | 현대자동차주식회사 | System and method for emergency startup of fuel cell vehicle |
CN103700871B (en) * | 2013-12-07 | 2015-09-09 | 西南交通大学 | Optimal Efficiency Control Method for Locomotive Proton Exchange Membrane Fuel Cell System |
KR101679970B1 (en) * | 2015-05-11 | 2016-11-25 | 현대자동차주식회사 | Apparatus for controlling purge valve of fuel cell vehicle and method thereof |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020110710A1 (en) * | 2000-02-11 | 2002-08-15 | General Motors Corporation | Staged venting of fuel cell system during rapid shutdown |
US20030232231A1 (en) * | 2002-04-17 | 2003-12-18 | Daimlerchrysler Ag | Device and method for supplying air to a fuel cell |
US20040076860A1 (en) * | 2002-10-22 | 2004-04-22 | Nissan Motor Co., Ltd. | Fuel cell system and related control method |
US20050053814A1 (en) * | 2003-09-05 | 2005-03-10 | Denso Corporation | Fuel cell system, related method and current measuring device for fuel cell system |
US20060012340A1 (en) * | 2004-06-03 | 2006-01-19 | Hibiki Saeki | Method of determining voltage condition of fuel cell vehicle |
US20060141305A1 (en) * | 2003-04-10 | 2006-06-29 | Nissan Motor Co., Ltd. | Electric power generation control system and electric power generation control method for fuel cell |
US20060240300A1 (en) * | 2005-04-22 | 2006-10-26 | Thompson Eric L | Combustion-thawed fuel cell |
US20060280977A1 (en) * | 2005-06-09 | 2006-12-14 | Denso Corporation | Fuel cell system |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5175439A (en) * | 1987-12-21 | 1992-12-29 | Robert Bosch Gmbh | Power supply circuit for motor vehicles |
US6507506B1 (en) * | 1999-06-09 | 2003-01-14 | Lear Automotive (Eeds) Spain, S. L. | Dual voltage electrical distribution system |
US6369461B1 (en) * | 2000-09-01 | 2002-04-09 | Abb Inc. | High efficiency power conditioner employing low voltage DC bus and buck and boost converters |
JP2002110258A (en) * | 2000-10-03 | 2002-04-12 | Alps Electric Co Ltd | Battery with protection circuit |
JP3580236B2 (en) | 2000-10-04 | 2004-10-20 | 日産自動車株式会社 | Fuel cell system |
JP4390028B2 (en) * | 2000-10-04 | 2009-12-24 | 日産化学工業株式会社 | Positive photosensitive polyimide resin composition |
JP4470346B2 (en) * | 2001-01-18 | 2010-06-02 | トヨタ自動車株式会社 | In-vehicle fuel cell system and hydrogen off-gas discharge method |
DE10102243A1 (en) * | 2001-01-19 | 2002-10-17 | Xcellsis Gmbh | Device for generating and distributing electrical energy to consumers in a vehicle |
JP3879635B2 (en) * | 2002-09-06 | 2007-02-14 | 日産自動車株式会社 | Mobile fuel cell power plant system |
WO2004049478A2 (en) * | 2002-11-27 | 2004-06-10 | Hydrogenics Corporation | Fuel cell power system with external humidification and reactant recirculation and method of operating the same |
JP2005191001A (en) * | 2003-12-02 | 2005-07-14 | Canon Inc | Method of replacing gas in fuel cell apparatus, fuel cell apparatus, and equipment for fuel cell apparatus |
JP4636425B2 (en) * | 2004-04-02 | 2011-02-23 | トヨタ自動車株式会社 | Fuel cell system |
JP4687023B2 (en) * | 2004-07-06 | 2011-05-25 | 日産自動車株式会社 | Fuel cell system |
US7682719B2 (en) * | 2006-09-22 | 2010-03-23 | Gm Global Technology Operations, Inc. | Method for adaptive prediction of stack voltage in automotive fuel cell systems |
US9496572B2 (en) | 2007-09-21 | 2016-11-15 | GM Global Technology Operations LLC | Closed-loop method for fuel cell system start-up with low voltage source |
-
2007
- 2007-09-24 US US11/860,121 patent/US9005785B2/en not_active Expired - Fee Related
-
2008
- 2008-09-18 DE DE200810047868 patent/DE102008047868A1/en not_active Ceased
- 2008-09-24 CN CN2008101656690A patent/CN101399355B/en not_active Expired - Fee Related
-
2015
- 2015-03-11 US US14/644,844 patent/US20160181636A1/en not_active Abandoned
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020110710A1 (en) * | 2000-02-11 | 2002-08-15 | General Motors Corporation | Staged venting of fuel cell system during rapid shutdown |
US20030232231A1 (en) * | 2002-04-17 | 2003-12-18 | Daimlerchrysler Ag | Device and method for supplying air to a fuel cell |
US20040076860A1 (en) * | 2002-10-22 | 2004-04-22 | Nissan Motor Co., Ltd. | Fuel cell system and related control method |
US20060141305A1 (en) * | 2003-04-10 | 2006-06-29 | Nissan Motor Co., Ltd. | Electric power generation control system and electric power generation control method for fuel cell |
US20050053814A1 (en) * | 2003-09-05 | 2005-03-10 | Denso Corporation | Fuel cell system, related method and current measuring device for fuel cell system |
US20060012340A1 (en) * | 2004-06-03 | 2006-01-19 | Hibiki Saeki | Method of determining voltage condition of fuel cell vehicle |
US20060240300A1 (en) * | 2005-04-22 | 2006-10-26 | Thompson Eric L | Combustion-thawed fuel cell |
US20060280977A1 (en) * | 2005-06-09 | 2006-12-14 | Denso Corporation | Fuel cell system |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2692464C1 (en) * | 2017-10-20 | 2019-06-25 | Тойота Дзидося Кабусики Кайся | Fuel cell system and method of controlling fuel cell system |
RU2692475C1 (en) * | 2017-11-09 | 2019-06-25 | Тойота Дзидося Кабусики Кайся | Fuel cell system and method of its control |
KR20190108303A (en) | 2018-03-14 | 2019-09-24 | 현대자동차주식회사 | Start up control method and contorl system for fuel cell |
US11631871B2 (en) | 2018-03-14 | 2023-04-18 | Hyundai Motor Company | Startup control method and control system for fuel cell |
Also Published As
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US20090081502A1 (en) | 2009-03-26 |
DE102008047868A1 (en) | 2009-05-07 |
CN101399355B (en) | 2012-04-18 |
US9005785B2 (en) | 2015-04-14 |
CN101399355A (en) | 2009-04-01 |
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