US20120189935A1 - Fuel cell system and method for operating fuel cell system - Google Patents
Fuel cell system and method for operating fuel cell system Download PDFInfo
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- US20120189935A1 US20120189935A1 US13/354,328 US201213354328A US2012189935A1 US 20120189935 A1 US20120189935 A1 US 20120189935A1 US 201213354328 A US201213354328 A US 201213354328A US 2012189935 A1 US2012189935 A1 US 2012189935A1
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- Prior art keywords
- pressure
- supply path
- fuel
- fuel supply
- fuel cell
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- 239000000446 fuel Substances 0.000 title claims abstract description 211
- 238000000034 method Methods 0.000 title claims description 25
- 239000002737 fuel gas Substances 0.000 claims abstract description 34
- 238000011144 upstream manufacturing Methods 0.000 claims description 19
- 238000004891 communication Methods 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 37
- 230000008569 process Effects 0.000 description 13
- 230000007423 decrease Effects 0.000 description 5
- 230000003213 activating effect Effects 0.000 description 4
- 230000007257 malfunction Effects 0.000 description 4
- 238000001994 activation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0438—Pressure; Ambient pressure; Flow
- H01M8/04432—Pressure differences, e.g. between anode and cathode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0438—Pressure; Ambient pressure; Flow
- H01M8/04388—Pressure; Ambient pressure; Flow of anode reactants at the inlet or inside the fuel cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
- H01M8/04753—Pressure; Flow of fuel cell reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Definitions
- the present invention relates to a fuel cell system and a method for operating a fuel cell system.
- a pressure reducing valve provided in the fuel supply path is used to reduce the pressure of the hydrogen gas supplied to the fuel cell (see, for example, Japanese Unexamined Patent Application Publication No. 2009-64681).
- shut-off valve a main stop valve that switches between a supply mode and a shut-off mode for the hydrogen gas supplied toward the fuel supply path from the hydrogen gas tank
- a fuel cell system comprises a fuel cell, a fuel-gas supplier, a fuel supply path, a shut-off valve, a pressure reducing valve, an auxiliary device, a pressure sensor, a depressurizing device, and a controller.
- the fuel supply path connects the fuel cell to the fuel-gas supplier.
- the shut-off valve is to switch between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplier.
- the pressure reducing valve is provided in the fuel supply path between the shut-off valve and the fuel cell to reduce a downstream pressure relative to an upstream pressure.
- the auxiliary device is provided in the fuel supply path between the pressure reducing valve and the fuel cell to activate the fuel cell.
- the pressure sensor is configured to detect a pressure in the fuel supply path located downstream of the pressure reducing valve.
- the depressurizing device is to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve.
- the controller is configured to control the depressurizing device to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds a predetermined threshold pressure.
- a method for operating a fuel cell system that includes a fuel cell, a fuel-gas supplier, a fuel supply path connecting the fuel cell to the fuel-gas supplier, a shut-off valve to switch between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplier, a pressure reducing valve provided in the fuel supply path between the shut-off valve and the fuel cell to reduce a downstream pressure relative to an upstream pressure, and a controller, the method comprising: detecting a pressure in the fuel supply path located downstream of the pressure reducing valve using a pressure sensor; determining whether or not the pressure detected by the pressure sensor exceeds a predetermined threshold pressure; and reducing the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds the predetermined threshold pressure.
- FIG. 1 illustrates the configuration of a fuel cell system according to the embodiment of the present invention.
- FIG. 2 is an operation flowchart corresponding to an activation process of the fuel cell system.
- FIG. 3 is a timing chart corresponding to the activation process of the fuel cell system.
- a fuel cell system is mounted in, for example, a fuel-cell-powered vehicle and includes a hydrogen gas tank 10 (corresponding to a fuel-gas supplying section) filled with high-pressure (e.g., several tens of MPa) hydrogen gas (corresponding to fuel gas); a tank temperature sensor 12 that detects the temperature of the hydrogen gas tank 10 ; a fuel cell 20 ; an auxiliary unit 21 (including an injector, a humidifier, and a hydrogen pump) for activating the fuel cell 20 ; fuel supply paths 30 a and 30 b that connect the hydrogen gas tank 10 to the fuel cell 20 ; a main stop valve 11 (corresponding to a shut-off valve) that opens and closes the connection between the hydrogen gas tank 10 and the fuel supply path 30 a so as to switch between a supply mode and a shut-off mode for the hydrogen gas supplied toward the fuel supply path 30 a from the hydrogen gas tank 10
- a hydrogen gas tank 10 corresponding to a fuel-gas supplying section
- high-pressure e.g., several tens
- the depressurizing valve 34 and the pressure responsive valve 35 are on-off valves that switch between a communication mode and a shut-off mode between the fuel supply path 30 b and the atmosphere communication path 40 .
- the depressurizing valve 34 is, for example, an electromagnetic valve or an injector, and opens or closes in accordance with a control signal from the controller 50 .
- the pressure responsive valve 35 switches from a closed state to an open state when a built-in pressure-sensitive section thereof receives a predetermined upper limit pressure or higher.
- the controller 50 is an electronic unit including a central processing unit (CPU) and a memory, and uses the CPU to execute a fuel-cell-system control program contained in the memory so as to control the operation of the fuel cell system.
- CPU central processing unit
- the fuel cell 20 generates electric power by an oxidation-reduction reaction occurring between the hydrogen gas supplied from the hydrogen gas tank 10 via the fuel supply paths 30 a and 30 b and air serving as oxidant gas supplied from an oxidant-gas supplying section (not shown).
- the controller 50 adjusts the amount of hydrogen gas and air to be supplied to the fuel cell 20 in accordance with required electric power of an electric load connected to the fuel cell 20 so as to control the amount of electric power to be generated in the fuel cell system.
- the controller 50 closes the main stop valve 11 so as to shut off the supply of hydrogen gas from the hydrogen gas tank 10 to the fuel supply path 30 a .
- the fuel supply path 30 a located upstream of the pressure reducing valve 31 is filled with high-pressure hydrogen gas.
- the high-pressure hydrogen gas in the fuel supply path 30 a located upstream of the pressure reducing valve 31 gradually diffuses toward the fuel supply path 30 b located downstream thereof via the pressure reducing valve 31 , causing the pressure in the fuel supply path 30 b to increase with the diffusion.
- the fuel supply path 30 a between the hydrogen gas tank 10 and the pressure reducing valve 31 is long, and the fuel supply path 30 a between the main stop valve 11 of the hydrogen gas tank 10 and the pressure reducing valve 31 thus has a large capacity. Therefore, the fuel supply path 30 a contains a large amount of high-pressure fuel.
- the pressure in the fuel supply path 30 b located downstream of the pressure reducing valve 31 may sometimes exceed the maximum normal pressure value of the auxiliary unit 21 . Supposing that the pressure rises to a level at which the auxiliary unit 21 possibly becomes inoperable, when the controller 50 opens the main stop valve 11 to resume the power generating operation of the fuel cell 20 , there is a possibility that the fuel cell 20 cannot be activated due to the malfunction of the auxiliary unit 21 .
- the controller 50 performs a process for preventing such an inability to activate the fuel cell 20 caused by an increase in the pressure in the fuel supply path 30 b . This process will be described below with reference to a flowchart shown in FIG. 2 .
- step 1 in FIG. 2 the controller 50 determines whether or not an ignition (IG) switch (starter switch) of the fuel-cell-powered vehicle is turned on.
- IG ignition
- starter switch starter switch
- step 2 the controller 50 determines whether or not the pressure P 2 detected by the intermediate-pressure sensor 33 exceeds a threshold pressure Pth (set to near the maximum normal pressure value of the auxiliary unit 21 ). If the pressure P 2 detected by the intermediate-pressure sensor 33 exceeds the threshold pressure Pth, the process proceeds to step 3 , whereas if the pressure P 2 detected by the intermediate-pressure sensor 33 is lower than or equal to the threshold pressure Pth, the process diverges to step 6 .
- a threshold pressure Pth set to near the maximum normal pressure value of the auxiliary unit 21 .
- step 2 for determining whether or not the pressure P 2 detected by the intermediate-pressure sensor 33 has exceeded the threshold pressure Pth corresponds to a pressure determining step in a method for operating a fuel cell system according to the embodiment of the present invention.
- step 3 the controller 50 outputs a control signal to the depressurizing valve 34 so as to open the depressurizing valve 34 .
- the hydrogen gas in the fuel supply path 30 b is exhausted to the atmosphere (corresponding to the low-pressure area) from the atmosphere communication path 40 via the depressurizing valve 34 and an orifice 41 .
- step 3 for reducing the pressure in the fuel supply path 30 b by opening the depressurizing valve 34 when the pressure P 2 detected by the intermediate-pressure sensor 33 has exceeded the threshold pressure Pth corresponds to a pressure reducing step in the method for operating a fuel cell system according to the embodiment of the present invention.
- the atmosphere communication path 40 may be connected to a diluting section (not shown) so that the hydrogen gas is diluted with air before being exhausted to the atmosphere.
- the hydrogen gas delivered to the atmosphere communication path 40 may be recovered and used in the fuel cell 20 .
- step 4 the controller 50 waits until the pressure P 2 detected by the intermediate-pressure sensor 33 decreases to the threshold pressure Pth or lower.
- the process proceeds to step 5 where the controller 50 closes the depressurizing valve 34 .
- the controller 50 opens the main stop valve 11 in step 6 and actuates the auxiliary unit 21 in step 7 . Then, the process proceeds to step 8 where the process ends. Due to the opened main stop valve 11 , the supply of hydrogen gas from the hydrogen gas tank 10 toward the fuel supply paths 30 a and 30 b commences with an appropriate pressure. Moreover, with the actuation of the auxiliary unit 21 , the hydrogen gas is supplied to the fuel cell 20 , thereby activating the fuel cell 20 .
- FIG. 3 is a timing chart showing the transition of the pressure P 2 detected by the intermediate-pressure sensor 33 when the process according to the flowchart in FIG. 2 described above is performed. Specifically, beginning at the top, FIG. 3 illustrates changes in the IG switch, the depressurizing valve 34 , the main stop valve 11 , the auxiliary unit 21 , and the pressure P 2 detected by the intermediate-pressure sensor 33 , relative to a common time axis t.
- the depressurizing valve 34 When the IG switch is turned on at time point t 1 , since the pressure P 2 detected by the intermediate-pressure sensor 33 exceeds the threshold pressure Pth, the depressurizing valve 34 is opened at time point t 2 . By opening the depressurizing valve 34 , the pressure P 2 detected by the intermediate-pressure sensor 33 gradually decreases. When the pressure P 2 decreases to the threshold pressure Pth or lower at time point t 3 , the depressurizing valve 34 is closed.
- the main stop valve 11 is opened so as to start supplying the hydrogen gas from the hydrogen gas tank 10 toward the fuel supply paths 30 a and 30 b .
- the auxiliary unit 21 is actuated.
- the fuel cell 20 starts to generate electric power. Due to consumption of hydrogen gas with the power generating operation, the pressure P 2 detected by the intermediate-pressure sensor 33 decreases at time point t 5 .
- the auxiliary unit 21 is actuated after reducing the pressure in the fuel supply path 30 b located downstream of the pressure reducing valve 31 to the threshold pressure Pth or lower, thereby preventing an inability to activate the fuel cell 20 due to a malfunction of the auxiliary unit 21 caused by excessive pressure. If it is confirmed in advance that the pressure in the fuel supply path 30 b located downstream of the pressure reducing valve 31 is lower than or equal to the threshold pressure Pth, the order of step 6 and step 7 may be interchanged.
- the pressure P 2 detected by the intermediate-pressure sensor 33 is checked and the pressure in the fuel supply path 30 b is reduced by using the depressurizing valve 34 .
- the pressure P 2 detected by the intermediate-pressure sensor 33 may be constantly monitored while the controller 50 is in operation, and the pressure in the fuel supply path 30 b may be reduced by using the depressurizing valve 34 when the pressure P 2 exceeds the threshold pressure Pth.
- the pressure responsive valve 35 opens when the pressure in the fuel supply path 30 b exceeds the upper limit pressure that is set to be higher than the threshold pressure Pth. Therefore, a pressure increase in the fuel supply path 30 b can be avoided. It should be noted that the advantages of the embodiment of the present invention can still be achieved even in a case where the pressure responsive valve 35 is not provided.
- the hydrogen gas tank 10 is provided as a fuel-gas supplying section in the present embodiment, a fuel-gas supplying section that generates and supplies hydrogen gas from fossil fuel by using a reformer may be provided as an alternative.
- the embodiment of the present invention relates to a fuel cell system having a fuel cell, a fuel-gas supplying section, a fuel supply path that connects the fuel cell to the fuel-gas supplying section, a shut-off valve that switches between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplying section, a pressure reducing valve that is provided in the fuel supply path between the shut-off valve and the fuel cell and that reduces a downstream pressure relative to an upstream pressure, and an auxiliary unit that is provided in the fuel supply path between the pressure reducing valve and the fuel cell and that is provided for activating the fuel cell.
- the fuel cell system includes a pressure sensor that detects a pressure in the fuel supply path located downstream of the pressure reducing valve, a depressurizing section that reduces the pressure in the fuel supply path located downstream of the pressure reducing valve, and a control unit that causes the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds a predetermined threshold pressure.
- the control unit when the pressure in the fuel supply path located downstream of the pressure reducing valve exceeds the threshold pressure, the control unit causes the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve. This can prevent an inability for the fuel cell to generate electric power, which may be caused when the auxiliary unit becomes inoperable due to an increase in the pressure in the fuel supply path located downstream of the pressure reducing valve owing to the fuel gas diffusing downstream from the upstream side of the pressure reducing valve.
- the depressurizing section is configured to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, which is lower than the pressure at the upstream side of the pressure reducing valve, the depressurizing section does not need to be large in size, unlike a shut-off valve provided in the fuel supply path located upstream of the pressure reducing valve. Therefore, increases in cost, weight, and volume of the fuel cell system can be suppressed, as compared with a case where a shut-off valve is provided upstream of the pressure reducing valve.
- control unit may determine whether or not the pressure detected by the pressure sensor exceeds the threshold pressure when the fuel cell is to be activated.
- the control unit When the power generating operation of the fuel cell is stopped and the shut-off valve is closed, the pressure in the fuel supply path located downstream of the pressure reducing valve sometimes exceeds the threshold pressure due to the high-pressure fuel gas diffusing downstream from the upstream side of the pressure reducing valve.
- the control unit performs a process for reducing the pressure in the fuel supply path located downstream of the pressure reducing valve. This can prevent an inability to activate the fuel cell caused by a malfunction of the auxiliary unit due to an increase in the pressure in the fuel supply path located downstream of the pressure reducing valve.
- the control unit may cause the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve to the threshold pressure or lower, and subsequently open the shut-off valve and actuate the auxiliary unit so as to activate the fuel cell.
- control unit reduces the pressure in the fuel supply path located downstream of the pressure reducing valve to the threshold pressure or lower so as to supply the fuel and reliably actuate the auxiliary unit, whereby the fuel cell can be activated.
- the depressurizing section may be a low-pressure open valve that is provided in the fuel supply path located downstream of the pressure reducing valve and that switches between a state in which the fuel supply path is in communication with a low-pressure area with a pressure lower than the threshold pressure and a state in which the fuel supply path is shut off from the low-pressure area.
- control unit may open the low-pressure open valve so as to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, and may include a pressure responsive valve that is provided in the fuel supply path located downstream of the pressure reducing valve and that switches from a closed state to an open state when the pressure in the fuel supply path located downstream of the pressure reducing valve exceeds an upper limit pressure set to be higher than the threshold pressure so as to allow the fuel supply path to communicate with the low-pressure area.
- the control unit opens the pressure responsive valve so as to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve. Therefore, a failure of the auxiliary unit for activating the fuel cell, caused by an excessive pressure applied to the auxiliary unit, can be prevented.
- the embodiment of the present invention relates to a method for operating a fuel cell system having a fuel cell, a fuel-gas supplying section, a fuel supply path that connects the fuel cell to the fuel-gas supplying section, a shut-off valve that switches between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplying section, a pressure reducing valve that is provided in the fuel supply path between the shut-off valve and the fuel cell and that reduces a downstream pressure relative to an upstream pressure, and a control unit.
- the method for operating a fuel cell system includes a pressure determining step in which the control unit causes a pressure sensor to detect a pressure in the fuel supply path located downstream of the pressure reducing valve and determines whether or not the detected pressure exceeds a predetermined threshold pressure, and a pressure reducing step in which the control unit causes a depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds the threshold pressure.
- the control unit when it is determined in the pressure determining step that the pressure in the fuel supply path located downstream of the pressure reducing valve has exceeded the threshold pressure, the control unit causes the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve in the pressure reducing step.
- This can prevent an inability for the fuel cell to generate electric power, which may be caused when the auxiliary unit becomes inoperable due to an increase in the pressure in the fuel supply path located downstream of the pressure reducing valve owing to the fuel gas diffusing downstream from the upstream side of the pressure reducing valve.
- the depressurizing section is configured to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, which is lower than the pressure at the upstream side of the pressure reducing valve, the depressurizing section does not need to be large in size, unlike a shut-off valve provided in the fuel supply path located upstream of the pressure reducing valve. Therefore, increases in cost, weight, and volume of the fuel cell system can be suppressed, as compared with a case where a shut-off valve is provided upstream of the pressure reducing valve.
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Abstract
A fuel cell system includes a fuel cell, a fuel-gas supplier, a fuel supply path, a shut-off valve, a pressure reducing valve, an auxiliary device, a pressure sensor, a depressurizing device, and a controller. The fuel supply path connects the fuel cell to the fuel-gas supplier. The pressure sensor is configured to detect a pressure in the fuel supply path located downstream of the pressure reducing valve. The depressurizing device is to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve. The controller is configured to control the depressurizing device to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds a predetermined threshold pressure.
Description
- The present application claims priority under 35 U.S.C. §119 to Japanese Patent Application No. 2011-014549, filed Jan. 26, 2011, entitled “Fuel Cell System and Method for Operating Fuel Cell System.” The contents of this application are incorporated herein by reference in their entirety.
- 1. Field of the Invention
- The present invention relates to a fuel cell system and a method for operating a fuel cell system.
- 2. Discussion of the Background
- In a fuel cell system in the related art that supplies hydrogen gas from a hydrogen gas tank filled with high-pressure hydrogen gas (fuel gas) to a fuel cell via a fuel supply path, a pressure reducing valve provided in the fuel supply path is used to reduce the pressure of the hydrogen gas supplied to the fuel cell (see, for example, Japanese Unexamined Patent Application Publication No. 2009-64681).
- Furthermore, in order to improve the reliability of the fuel cell system, there has been proposed a configuration having a function for determining whether or not there is a malfunction in a main stop valve (shut-off valve) that switches between a supply mode and a shut-off mode for the hydrogen gas supplied toward the fuel supply path from the hydrogen gas tank (see, for example, Japanese Unexamined Patent Application Publication No. 2007-173158).
- According to one aspect of the present invention, a fuel cell system comprises a fuel cell, a fuel-gas supplier, a fuel supply path, a shut-off valve, a pressure reducing valve, an auxiliary device, a pressure sensor, a depressurizing device, and a controller. The fuel supply path connects the fuel cell to the fuel-gas supplier. The shut-off valve is to switch between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplier. The pressure reducing valve is provided in the fuel supply path between the shut-off valve and the fuel cell to reduce a downstream pressure relative to an upstream pressure. The auxiliary device is provided in the fuel supply path between the pressure reducing valve and the fuel cell to activate the fuel cell. The pressure sensor is configured to detect a pressure in the fuel supply path located downstream of the pressure reducing valve. The depressurizing device is to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve. The controller is configured to control the depressurizing device to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds a predetermined threshold pressure.
- According to another aspect of the present invention, a method for operating a fuel cell system that includes a fuel cell, a fuel-gas supplier, a fuel supply path connecting the fuel cell to the fuel-gas supplier, a shut-off valve to switch between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplier, a pressure reducing valve provided in the fuel supply path between the shut-off valve and the fuel cell to reduce a downstream pressure relative to an upstream pressure, and a controller, the method comprising: detecting a pressure in the fuel supply path located downstream of the pressure reducing valve using a pressure sensor; determining whether or not the pressure detected by the pressure sensor exceeds a predetermined threshold pressure; and reducing the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds the predetermined threshold pressure.
- A more complete appreciation of the invention and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings.
-
FIG. 1 illustrates the configuration of a fuel cell system according to the embodiment of the present invention. -
FIG. 2 is an operation flowchart corresponding to an activation process of the fuel cell system. -
FIG. 3 is a timing chart corresponding to the activation process of the fuel cell system. - The embodiments will now be described with reference to the accompanying drawings, wherein like reference numerals designate corresponding or identical elements throughout the various drawings.
- The embodiment of the present invention will now be described with reference to
FIGS. 1 to 3 . Referring toFIG. 1 , a fuel cell system according to the present embodiment is mounted in, for example, a fuel-cell-powered vehicle and includes a hydrogen gas tank 10 (corresponding to a fuel-gas supplying section) filled with high-pressure (e.g., several tens of MPa) hydrogen gas (corresponding to fuel gas); atank temperature sensor 12 that detects the temperature of thehydrogen gas tank 10; afuel cell 20; an auxiliary unit 21 (including an injector, a humidifier, and a hydrogen pump) for activating thefuel cell 20;fuel supply paths hydrogen gas tank 10 to thefuel cell 20; a main stop valve 11 (corresponding to a shut-off valve) that opens and closes the connection between thehydrogen gas tank 10 and thefuel supply path 30 a so as to switch between a supply mode and a shut-off mode for the hydrogen gas supplied toward thefuel supply path 30 a from thehydrogen gas tank 10; apressure reducing valve 31 that reduces the pressure of the hydrogen gas within thefuel supply path 30 a located upstream thereof and supplies the hydrogen gas to thefuel supply path 30 b located downstream thereof; a high-pressure sensor 32 that detects a pressure P1 within thefuel supply path 30 a (i.e., the fuel supply path located upstream of the pressure reducing valve 31); an intermediate-pressure sensor 33 (corresponding to a pressure sensor) that detects a pressure P2 within thefuel supply path 30 b (i.e., the fuel supply path located downstream of the pressure reducing valve 31); a depressurizing valve 34 (corresponding to a depressurizing section) and a pressureresponsive valve 35 that are provided in thefuel supply path 30 b and that open thefuel supply path 30 b to the atmosphere (corresponding to a low-pressure area) via anatmosphere communication path 40; and a controller 50 (corresponding to a control unit) that controls the overall operation of the fuel cell system. - The depressurizing
valve 34 and the pressureresponsive valve 35 are on-off valves that switch between a communication mode and a shut-off mode between thefuel supply path 30 b and theatmosphere communication path 40. The depressurizingvalve 34 is, for example, an electromagnetic valve or an injector, and opens or closes in accordance with a control signal from thecontroller 50. The pressureresponsive valve 35 switches from a closed state to an open state when a built-in pressure-sensitive section thereof receives a predetermined upper limit pressure or higher. - The
controller 50 is an electronic unit including a central processing unit (CPU) and a memory, and uses the CPU to execute a fuel-cell-system control program contained in the memory so as to control the operation of the fuel cell system. - The
fuel cell 20 generates electric power by an oxidation-reduction reaction occurring between the hydrogen gas supplied from thehydrogen gas tank 10 via thefuel supply paths - The
controller 50 adjusts the amount of hydrogen gas and air to be supplied to thefuel cell 20 in accordance with required electric power of an electric load connected to thefuel cell 20 so as to control the amount of electric power to be generated in the fuel cell system. - When the
fuel cell 20 is not generating electric power, thecontroller 50 closes themain stop valve 11 so as to shut off the supply of hydrogen gas from thehydrogen gas tank 10 to thefuel supply path 30 a. When the power generating operation of thefuel cell 20 is stopped and themain stop valve 11 is closed in this manner, thefuel supply path 30 a located upstream of thepressure reducing valve 31 is filled with high-pressure hydrogen gas. - The high-pressure hydrogen gas in the
fuel supply path 30 a located upstream of thepressure reducing valve 31 gradually diffuses toward thefuel supply path 30 b located downstream thereof via thepressure reducing valve 31, causing the pressure in thefuel supply path 30 b to increase with the diffusion. - Especially in a case where the installation space of the fuel cell system is limited and spreads over a wide area, as in a fuel-cell-powered vehicle, the
fuel supply path 30 a between thehydrogen gas tank 10 and thepressure reducing valve 31 is long, and thefuel supply path 30 a between themain stop valve 11 of thehydrogen gas tank 10 and thepressure reducing valve 31 thus has a large capacity. Therefore, thefuel supply path 30 a contains a large amount of high-pressure fuel. - Since this large amount of high-pressure fuel diffuses downstream, the pressure in the
fuel supply path 30 b located downstream of thepressure reducing valve 31 may sometimes exceed the maximum normal pressure value of theauxiliary unit 21. Supposing that the pressure rises to a level at which theauxiliary unit 21 possibly becomes inoperable, when thecontroller 50 opens themain stop valve 11 to resume the power generating operation of thefuel cell 20, there is a possibility that thefuel cell 20 cannot be activated due to the malfunction of theauxiliary unit 21. - Thus, the
controller 50 performs a process for preventing such an inability to activate thefuel cell 20 caused by an increase in the pressure in thefuel supply path 30 b. This process will be described below with reference to a flowchart shown inFIG. 2 . - In step 1 in
FIG. 2 , thecontroller 50 determines whether or not an ignition (IG) switch (starter switch) of the fuel-cell-powered vehicle is turned on. When the IG switch is turned on, the process proceeds to step 2. - In step 2, the
controller 50 determines whether or not the pressure P2 detected by the intermediate-pressure sensor 33 exceeds a threshold pressure Pth (set to near the maximum normal pressure value of the auxiliary unit 21). If the pressure P2 detected by the intermediate-pressure sensor 33 exceeds the threshold pressure Pth, the process proceeds to step 3, whereas if the pressure P2 detected by the intermediate-pressure sensor 33 is lower than or equal to the threshold pressure Pth, the process diverges to step 6. - The process performed by the
controller 50 in step 2 for determining whether or not the pressure P2 detected by the intermediate-pressure sensor 33 has exceeded the threshold pressure Pth corresponds to a pressure determining step in a method for operating a fuel cell system according to the embodiment of the present invention. - In step 3, the
controller 50 outputs a control signal to the depressurizingvalve 34 so as to open the depressurizingvalve 34. Thus, the hydrogen gas in thefuel supply path 30 b is exhausted to the atmosphere (corresponding to the low-pressure area) from theatmosphere communication path 40 via the depressurizingvalve 34 and anorifice 41. - The process performed by the
controller 50 in step 3 for reducing the pressure in thefuel supply path 30 b by opening the depressurizingvalve 34 when the pressure P2 detected by the intermediate-pressure sensor 33 has exceeded the threshold pressure Pth corresponds to a pressure reducing step in the method for operating a fuel cell system according to the embodiment of the present invention. - As an alternative to the above example in which the hydrogen gas in the
fuel supply path 30 b is directly exhausted to the atmosphere from theatmosphere communication path 40, theatmosphere communication path 40 may be connected to a diluting section (not shown) so that the hydrogen gas is diluted with air before being exhausted to the atmosphere. As a further alternative, the hydrogen gas delivered to theatmosphere communication path 40 may be recovered and used in thefuel cell 20. - In step 4, the
controller 50 waits until the pressure P2 detected by the intermediate-pressure sensor 33 decreases to the threshold pressure Pth or lower. When the pressure P2 detected by the intermediate-pressure sensor 33 decreases to the threshold pressure Pth or lower, the process proceeds to step 5 where thecontroller 50 closes the depressurizingvalve 34. - Subsequently, the
controller 50 opens themain stop valve 11 in step 6 and actuates theauxiliary unit 21 in step 7. Then, the process proceeds to step 8 where the process ends. Due to the openedmain stop valve 11, the supply of hydrogen gas from thehydrogen gas tank 10 toward thefuel supply paths auxiliary unit 21, the hydrogen gas is supplied to thefuel cell 20, thereby activating thefuel cell 20. -
FIG. 3 is a timing chart showing the transition of the pressure P2 detected by the intermediate-pressure sensor 33 when the process according to the flowchart inFIG. 2 described above is performed. Specifically, beginning at the top,FIG. 3 illustrates changes in the IG switch, the depressurizingvalve 34, themain stop valve 11, theauxiliary unit 21, and the pressure P2 detected by the intermediate-pressure sensor 33, relative to a common time axis t. - When the IG switch is turned on at time point t1, since the pressure P2 detected by the intermediate-
pressure sensor 33 exceeds the threshold pressure Pth, the depressurizingvalve 34 is opened at time point t2. By opening the depressurizingvalve 34, the pressure P2 detected by the intermediate-pressure sensor 33 gradually decreases. When the pressure P2 decreases to the threshold pressure Pth or lower at time point t3, the depressurizingvalve 34 is closed. - At time point t3, the
main stop valve 11 is opened so as to start supplying the hydrogen gas from thehydrogen gas tank 10 toward thefuel supply paths auxiliary unit 21 is actuated. In response to the actuation of theauxiliary unit 21, thefuel cell 20 starts to generate electric power. Due to consumption of hydrogen gas with the power generating operation, the pressure P2 detected by the intermediate-pressure sensor 33 decreases at time point t5. - According to the above-described process performed by the
controller 50, when thefuel cell 20 is to be activated, theauxiliary unit 21 is actuated after reducing the pressure in thefuel supply path 30 b located downstream of thepressure reducing valve 31 to the threshold pressure Pth or lower, thereby preventing an inability to activate thefuel cell 20 due to a malfunction of theauxiliary unit 21 caused by excessive pressure. If it is confirmed in advance that the pressure in thefuel supply path 30 b located downstream of thepressure reducing valve 31 is lower than or equal to the threshold pressure Pth, the order of step 6 and step 7 may be interchanged. - In the present embodiment, when the
fuel cell 20 is to be activated, the pressure P2 detected by the intermediate-pressure sensor 33 is checked and the pressure in thefuel supply path 30 b is reduced by using the depressurizingvalve 34. Alternatively, regardless of the state of thefuel cell 20, the pressure P2 detected by the intermediate-pressure sensor 33 may be constantly monitored while thecontroller 50 is in operation, and the pressure in thefuel supply path 30 b may be reduced by using the depressurizingvalve 34 when the pressure P2 exceeds the threshold pressure Pth. - Furthermore, in the present embodiment, even if there is a failure of the depressurizing
valve 34, the pressureresponsive valve 35 opens when the pressure in thefuel supply path 30 b exceeds the upper limit pressure that is set to be higher than the threshold pressure Pth. Therefore, a pressure increase in thefuel supply path 30 b can be avoided. It should be noted that the advantages of the embodiment of the present invention can still be achieved even in a case where the pressureresponsive valve 35 is not provided. - Although the
hydrogen gas tank 10 is provided as a fuel-gas supplying section in the present embodiment, a fuel-gas supplying section that generates and supplies hydrogen gas from fossil fuel by using a reformer may be provided as an alternative. - The embodiment of the present invention relates to a fuel cell system having a fuel cell, a fuel-gas supplying section, a fuel supply path that connects the fuel cell to the fuel-gas supplying section, a shut-off valve that switches between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplying section, a pressure reducing valve that is provided in the fuel supply path between the shut-off valve and the fuel cell and that reduces a downstream pressure relative to an upstream pressure, and an auxiliary unit that is provided in the fuel supply path between the pressure reducing valve and the fuel cell and that is provided for activating the fuel cell.
- The fuel cell system according to the embodiment of the present invention includes a pressure sensor that detects a pressure in the fuel supply path located downstream of the pressure reducing valve, a depressurizing section that reduces the pressure in the fuel supply path located downstream of the pressure reducing valve, and a control unit that causes the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds a predetermined threshold pressure.
- According to the embodiment of the present invention, when the pressure in the fuel supply path located downstream of the pressure reducing valve exceeds the threshold pressure, the control unit causes the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve. This can prevent an inability for the fuel cell to generate electric power, which may be caused when the auxiliary unit becomes inoperable due to an increase in the pressure in the fuel supply path located downstream of the pressure reducing valve owing to the fuel gas diffusing downstream from the upstream side of the pressure reducing valve.
- In this case, it is not necessary to provide another shut-off valve in addition to the aforementioned shut-off valve (main stop valve). Moreover, since the depressurizing section is configured to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, which is lower than the pressure at the upstream side of the pressure reducing valve, the depressurizing section does not need to be large in size, unlike a shut-off valve provided in the fuel supply path located upstream of the pressure reducing valve. Therefore, increases in cost, weight, and volume of the fuel cell system can be suppressed, as compared with a case where a shut-off valve is provided upstream of the pressure reducing valve.
- In fuel cell system according to the embodiment of the present invention, the control unit may determine whether or not the pressure detected by the pressure sensor exceeds the threshold pressure when the fuel cell is to be activated.
- When the power generating operation of the fuel cell is stopped and the shut-off valve is closed, the pressure in the fuel supply path located downstream of the pressure reducing valve sometimes exceeds the threshold pressure due to the high-pressure fuel gas diffusing downstream from the upstream side of the pressure reducing valve. When the fuel cell is to be activated in this state, the control unit performs a process for reducing the pressure in the fuel supply path located downstream of the pressure reducing valve. This can prevent an inability to activate the fuel cell caused by a malfunction of the auxiliary unit due to an increase in the pressure in the fuel supply path located downstream of the pressure reducing valve.
- In fuel cell system according to the embodiment of the present invention, if the pressure detected by the pressure sensor exceeds the threshold pressure when the fuel cell is to be activated, the control unit may cause the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve to the threshold pressure or lower, and subsequently open the shut-off valve and actuate the auxiliary unit so as to activate the fuel cell.
- Accordingly, the control unit reduces the pressure in the fuel supply path located downstream of the pressure reducing valve to the threshold pressure or lower so as to supply the fuel and reliably actuate the auxiliary unit, whereby the fuel cell can be activated.
- In fuel cell system according to the embodiment of the present invention, the depressurizing section may be a low-pressure open valve that is provided in the fuel supply path located downstream of the pressure reducing valve and that switches between a state in which the fuel supply path is in communication with a low-pressure area with a pressure lower than the threshold pressure and a state in which the fuel supply path is shut off from the low-pressure area. Moreover, the control unit may open the low-pressure open valve so as to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, and may include a pressure responsive valve that is provided in the fuel supply path located downstream of the pressure reducing valve and that switches from a closed state to an open state when the pressure in the fuel supply path located downstream of the pressure reducing valve exceeds an upper limit pressure set to be higher than the threshold pressure so as to allow the fuel supply path to communicate with the low-pressure area.
- Accordingly, if the pressure in the fuel supply path located downstream of the pressure reducing valve cannot be reduced due to a failure of the pressure sensor or the depressurizing section, the control unit opens the pressure responsive valve so as to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve. Therefore, a failure of the auxiliary unit for activating the fuel cell, caused by an excessive pressure applied to the auxiliary unit, can be prevented.
- The embodiment of the present invention relates to a method for operating a fuel cell system having a fuel cell, a fuel-gas supplying section, a fuel supply path that connects the fuel cell to the fuel-gas supplying section, a shut-off valve that switches between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplying section, a pressure reducing valve that is provided in the fuel supply path between the shut-off valve and the fuel cell and that reduces a downstream pressure relative to an upstream pressure, and a control unit.
- The method for operating a fuel cell system according to the embodiment of the present invention includes a pressure determining step in which the control unit causes a pressure sensor to detect a pressure in the fuel supply path located downstream of the pressure reducing valve and determines whether or not the detected pressure exceeds a predetermined threshold pressure, and a pressure reducing step in which the control unit causes a depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds the threshold pressure.
- According to the embodiment of the present invention, when it is determined in the pressure determining step that the pressure in the fuel supply path located downstream of the pressure reducing valve has exceeded the threshold pressure, the control unit causes the depressurizing section to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve in the pressure reducing step. This can prevent an inability for the fuel cell to generate electric power, which may be caused when the auxiliary unit becomes inoperable due to an increase in the pressure in the fuel supply path located downstream of the pressure reducing valve owing to the fuel gas diffusing downstream from the upstream side of the pressure reducing valve.
- In this case, it is not necessary to provide another shut-off valve in addition to the aforementioned shut-off valve (main stop valve). Moreover, since the depressurizing section is configured to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, which is lower than the pressure at the upstream side of the pressure reducing valve, the depressurizing section does not need to be large in size, unlike a shut-off valve provided in the fuel supply path located upstream of the pressure reducing valve. Therefore, increases in cost, weight, and volume of the fuel cell system can be suppressed, as compared with a case where a shut-off valve is provided upstream of the pressure reducing valve.
- Obviously, numerous modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.
Claims (7)
1. A fuel cell system comprising:
a fuel cell;
a fuel-gas supplier;
a fuel supply path connecting the fuel cell to the fuel-gas supplier;
a shut-off valve to switch between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplier;
a pressure reducing valve provided in the fuel supply path between the shut-off valve and the fuel cell to reduce a downstream pressure relative to an upstream pressure;
an auxiliary device provided in the fuel supply path between the pressure reducing valve and the fuel cell to activate the fuel cell;
a pressure sensor configured to detect a pressure in the fuel supply path located downstream of the pressure reducing valve;
a depressurizing device to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve; and
a controller configured to control the depressurizing device to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds a predetermined threshold pressure.
2. The fuel cell system according to claim 1 , wherein
the controller determines whether or not the pressure detected by the pressure sensor exceeds the predetermined threshold pressure when the fuel cell is to be activated.
3. The fuel cell system according to claim 2 , wherein
if the pressure detected by the pressure sensor exceeds the predetermined threshold pressure when the fuel cell is to be activated, the controller controls the depressurizing device to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve to the predetermined threshold pressure or to a pressure lower than the predetermined threshold pressure, and subsequently opens the shut-off valve and actuates the auxiliary device so as to activate the fuel cell.
4. The fuel cell system according to claim 1 , wherein
the depressurizing device comprises a low-pressure open valve provided in the fuel supply path located downstream of the pressure reducing valve, the a low-pressure open valve being to switch the fuel supply path between a state in which the fuel supply path is in communication with a low-pressure area with a pressure lower than the predetermined threshold pressure and a state in which the fuel supply path is shut off from the low-pressure area, and
the controller opens the low-pressure open valve so as to reduce the pressure in the fuel supply path located downstream of the pressure reducing valve, and includes a pressure responsive valve provided in the fuel supply path located downstream of the pressure reducing valve, the pressure responsive valve being to switch from a closed state to an open state when the pressure in the fuel supply path located downstream of the pressure reducing valve exceeds an upper limit pressure set to be higher than the predetermined threshold pressure so as to allow the fuel supply path to communicate with the low-pressure area.
5. The fuel cell system according to claim 1 , wherein
the predetermined threshold pressure is set based on a maximum normal pressure value of the auxiliary device.
6. A method for operating a fuel cell system that includes a fuel cell, a fuel-gas supplier, a fuel supply path connecting the fuel cell to the fuel-gas supplier, a shut-off valve to switch between a supply mode and a shut-off mode for fuel gas supplied toward the fuel supply path from the fuel-gas supplier, a pressure reducing valve provided in the fuel supply path between the shut-off valve and the fuel cell to reduce a downstream pressure relative to an upstream pressure, and a controller, the method comprising:
detecting a pressure in the fuel supply path located downstream of the pressure reducing valve using a pressure sensor;
determining whether or not the pressure detected by the pressure sensor exceeds a predetermined threshold pressure; and
reducing the pressure in the fuel supply path located downstream of the pressure reducing valve when the pressure detected by the pressure sensor exceeds the predetermined threshold pressure.
7. The method according to claim 6 , wherein
the predetermined threshold pressure is set based on a maximum normal pressure value of the auxiliary device.
Priority Applications (1)
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US15/221,602 US9825318B2 (en) | 2011-01-26 | 2016-07-28 | Method for operating fuel cell system |
Applications Claiming Priority (2)
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JP2011014549A JP5258912B2 (en) | 2011-01-26 | 2011-01-26 | FUEL CELL SYSTEM AND METHOD FOR OPERATING FUEL CELL SYSTEM |
JP2011-014549 | 2011-01-26 |
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US15/221,602 Division US9825318B2 (en) | 2011-01-26 | 2016-07-28 | Method for operating fuel cell system |
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US20120189935A1 true US20120189935A1 (en) | 2012-07-26 |
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US13/354,328 Abandoned US20120189935A1 (en) | 2011-01-26 | 2012-01-20 | Fuel cell system and method for operating fuel cell system |
US15/221,602 Active US9825318B2 (en) | 2011-01-26 | 2016-07-28 | Method for operating fuel cell system |
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US15/221,602 Active US9825318B2 (en) | 2011-01-26 | 2016-07-28 | Method for operating fuel cell system |
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US (2) | US20120189935A1 (en) |
JP (1) | JP5258912B2 (en) |
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US20160133966A1 (en) * | 2014-11-07 | 2016-05-12 | Toyota Jidosha Kabushiki Kaisha | Fuel Cell System and a Method for Controlling a Fuel Cell System |
CN108470928A (en) * | 2017-02-20 | 2018-08-31 | 武汉众宇动力系统科技有限公司 | Fuel system and its detection method for unmanned plane fuel cell |
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JP5920240B2 (en) * | 2013-02-19 | 2016-05-18 | トヨタ自動車株式会社 | Fuel cell piping, fuel gas discharging method and connecting pipe |
JP6155795B2 (en) * | 2013-04-22 | 2017-07-05 | 日産自動車株式会社 | Fuel cell system |
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Also Published As
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US9825318B2 (en) | 2017-11-21 |
JP5258912B2 (en) | 2013-08-07 |
JP2012156019A (en) | 2012-08-16 |
US20160336608A1 (en) | 2016-11-17 |
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