US20120060304A1

US20120060304A1 - Cushioning device

Info

Publication number: US20120060304A1
Application number: US13/300,050
Authority: US
Inventors: Philip C. Yang; Charles E. Lundy, Jr.
Original assignee: MSD Consumber Care Inc
Current assignee: Bayer Consumer Care Holdings LLC
Priority date: 2008-06-27
Filing date: 2011-11-18
Publication date: 2012-03-15
Also published as: JP2012224868A; EP2310467A2; JP5244238B2; JP2011525446A; MX2010014523A; AR089933A2; CA2728540A1; BRPI0913961A2; US20090320324A1; AR089932A2; AU2009262057A1; WO2009158560A3; CO6331356A2; WO2009158560A2; AR072377A1

Abstract

A cushioning device comprising a sticky surface, the device comprising a gel material bound to a thermoplastic film material having a polarity compatible with the gel material, wherein the thermoplastic film material further comprises a pressure sensitive adhesive located on a surface of the film material opposite to the surface that is bonded to the gel material.

Description

BACKGROUND OF THE INVENTION

The subject invention is directed to cushioning devices comprising a pressure sensitive adhesive. In particular, the invention concerns the use of pressure sensitive adhesive materials to improve the hold of soft gel cushioning devices. One of the key attributes of the footwear cushions is to prevent the footwear from rubbing sensitive areas of skin, in particular in the heel area. However, in order to achieve all the desired attributes of the cushion, the cushion needs to stay in place firmly during movement associated with normal use of footwear. Cushioning devices made of soft gels are known in the art and are desirable for their comfort, flexibility, durability and look. The assignee of this invention, Schering-Plough Healthcare Products, Inc., markets a cushioning device under the trade name Dr. Scholl's® Gel Heel Liner, which comprises a thermoplastic polyurethane (TPU) film bonded to a polyurethane (PU) gel, where the PU gel is produced in a way to have a sticky surface. However, no additional adhesive is used in this product. The Heel Liner is packaged with a release film to preserve the tackiness of the PU gel sticky surface, which is then applied to the shoe to hold the liner in place. The TPU film provides a nonstick surface opposite the sticky surface, which nonstick contacts the wearers foot, sock, or hosiery.
It has now been determined, however, that the sticky PU gel does not hold the liner in place for extended periods of use as may be desired for a cushioning element. Pressure sensitive adhesive materials have been used in the art. However, direct modification of a sticky PU gel with a pressure sensitive adhesive did not produce a cushioning element with a stronger hold. Thus, a cushioning device that provides the benefit of a gel and provides for long term hold in the shoe where placed would be desirable. Further, a method of manufacturing a gel cushioning device with a pressure sensitive adhesive would also be desirable. These and other advantages follow from the invention described and claimed here.

SUMMARY OF THE INVENTION

The subject invention provides a cushioning device comprising a layer of polyurethane gel material comprising top and bottom surfaces, at least one layer of thermoplastic polyurethane film material bonded to the one or both of said top and bottom surfaces thereof, and a layer of pressure sensitive adhesive bonded to one of said at least one thermoplastic polyurethane film material, wherein the pressure sensitive adhesive is located on a surface of the thermoplastic polyurethane film opposite to the surface contacting said bottom surface of said polyurethane gel material.
The subject invention also provides a gel cushioning device comprising a sticky surface, the device comprising a gel material bound to a thermoplastic film material having good compatibility with the gel material, wherein the thermoplastic film material further comprises a pressure sensitive adhesive located on a surface of the film material opposite to the surface that is bonded to the gel material.
The subject invention further provides gel cushioning device comprising a sticky surface, the device comprising a layer of gel material having an upper and lower surface and two layers of thermoplastic film material, each film material comprising upper and lower surfaces, wherein the upper surface of the gel material is bonded with the lower surface of one of said layers of film material and the lower surface of the gel material is bonded with the upper surface of the other of said layers of film material, wherein at least one of the layers of film material comprises a pressure sensitive adhesive on a surface opposite the surface bonded to the gel material thereby providing the sticky surface of the device.
The subject invention also provides a method of constructing a gel cushioning device comprising a sticky surface, which comprises loading gel material into a mold cavity comprising at least one layer of thermoplastic film material, said at least one layer of thermoplastic film material comprising upper and lower surfaces, and curing the gel material to form a solid gel, such that the cured gel material is bonded with the film material and wherein said at least one of the layer of thermoplastic film material comprises a pressure sensitive adhesive on a surface opposite the surface bonded to the gel material thereby providing the sticky surface of the device.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1A depicts a cross section of a prior art cushioning element.

FIG. 1B depicts a cross section of an example embodiment of the cushioning element of the invention.

FIG. 2 depicts a cross section of a second example embodiment of the cushioning element of the invention.

DETAILED DESCRIPTION

As depicted in FIG. 1, the products of the invention comprise an advance over prior art TPU/PU molded cushioning elements in that they provide for a means to attach a pressure sensitive adhesive to a gel material to provide extra holding capabilities. FIG. 1A shows a cross section of a prior art material comprising gel material (104) bonded to a film material (102). The film material provides an exterior surface that resists friction to allow for smooth contact with skin or articles of clothing. FIG. 1B shows a cross section of an example embodiment of the subject invention wherein a layer of gel material having top and bottom surfaces comprises two layers of film material (102, 103) bonded to each surface of the gel material. In the practice of the invention, the gel material may comprise, for example polyurethane gel, styrenic based gels, or silicone gels. The gel materials useful in the invention may typically have a Shore 00 hardness of between about 10 and about 80, preferably between about 30 and about 60. In certain embodiments of the invention, the polyurethane gel materials are used and may have a Shore 00 hardness of about 50. The gel material may typically have a thickness of between 0.3 and 3 mm. The film material may comprise thermoplastic polymeric film material that is compatible with the gel material used in the cushion. For example, where a polyurethane gel material is used in the cushion, the film material will likely comprise a thermoplastic polyurethane film material. Likewise, when an SEBS gel material is used in the cushion, the film material will likely comprise SEBS thermoplastic film. The film materials may typically have a Shore A hardness of between about 40 to about 95 and may typically have a thickness of between 0.025 mm and 0.25 mm. In certain embodiments according to this invention where more than one layer of film is used, the individual layers of film will have the same thickness. In certain additional embodiments according to this invention, individual layers of film will have different thicknesses. In practice, varying the thickness of the film will affect the softness and flexibility of the film and will likewise affect the softness and flexibility of the final gel cushion product. In certain embodiments, a thermoplastic polyurethane film is used and may be at least 0.025 mm thick.
As used herein polyurethane material will be understood to encompass polymers that contain a plurality of urethane linkages and comprised of either aliphatic or aromatic isocyanate prepolymers, and combinations thereof, both with either di or trifunctional polyol polymers or prepolymers. The polyurethane material may optionally also contain other kinds of chemical linkages formed from the reactions of polyisocyanates, including but not limited to urea linkages, isocyanurate linkages, oxazolidone linkages, biuret linkages, allophanate linkages, combinations of these, and the like. Polyurethane gel materials are typically formed by reacting polyisocyanates with polyols. Examples of poly isocyanates include those formed from aliphatic or aromatic isocyanate prepolymers or combinations thereof. Examples of polyols include di or trifunctional polyol polymers or prepolymers Examples of polyols used include polyether polyols such as polyethylene oxide) and polypropylene oxide), modified polyether polyols, polytetramethylene glycol, condensation polyester polyols produced by reacting dicarboxylic acids with dials, lactone-type polyester polyols produced by ring opening polymerization of epsilon-caprolactone or the like, and polycarbonate polyols, vinyl polymers into which hydroxyl groups are introduced such as polyols having polyisobutylene as the main chain.
The gel layer can also be made from a non-foam elastomer such as the class of materials known as viscoelastic polymers or silicone gels, which show high levels of damping when tested by dynamic mechanical analysis performed in the range of −50 degree Celsius to 100 degrees Celsius. Gels material can include, but not limited to, the Kraton family of styrene-olefin-rubber block copolymers, thermoplastic polyurethanes, thermoset polyurethanes, thermoplastic poly olefins, polyamides, polyureas, polyesters and other polymer materials that reversibly soften as a function of temperature. The preferred elastomers are a Kraton block copolymer of styrene/ethylene-co-butylene/styrene (SEBS) or Styrene/butadiene/styrene (SBS) with mineral oil incorporated into the matrix as a plasticizer.
As used herein, pressure sensitive adhesives (also known as contact adhesives) are those that form viscoelastic bonds that are aggressively and permanently tacky, adhere without the need of more than slight pressure, and require no activation by water, solvent or heat. Pressure sensitive adhesives are typically available in solvent and latex or water based forms and are often based on non-crosslinked rubber adhesives, acrylics or polyurethanes.
In certain embodiments of the invention, the pressure sensitive adhesives may comprise acrylic and methacrylate adhesives, rubber-based pressure sensitive adhesives, styrene copolymers such as styrene-isoprene-styrene (SIS) and styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, and silicones. Acrylic adhesives often use an acrylate system such as ethylene ethyl acrylate (EEA) or ethylene methyl acrylate (EMA) copolymers, which are used to form hot melt PSA adhesives. Natural rubber, synthetic rubber or elastomer adhesives may typically comprise a variety of materials such as silicone, polyurethane, chloroprene, butyl, polybutadiene, isoprene or neoprene. Rubber and elastomers are characterized by their high degree of flexibility and elasticity.
In certain embodiments, the pressure sensitive adhesive material may comprise acrylate-based adhesive materials. The thickness of the layer of the pressure sensitive adhesive material may be varied by those of ordinary skill in the art according to the adhesive material used and the desired tack. In the practice of certain example embodiments of the invention, the pressure sensitive adhesive may have a thickness of between about 0.0125 mm and about 025 mm.
An additional aspect of the invention comprises a method of manufacturing a cushioning element comprising a polyurethane gel material, which method comprises the step of bonding a polyurethane gel and a thermoplastic film material, wherein the thermoplastic film material comprises a pressure sensitive adhesive. In preparation of one embodiment of the invention it was discovered that the pressure sensitive adhesive layer cannot bond directly to the soft polyurethane gel during the molding process. To overcome this limitation, a layer of thermoplastic film material comprising the pressure sensitive adhesive layer was added to the mold and bonded to the polyurethane gel.
In certain embodiments of the invention, the cushioning element is prepared by a direct molding process where the gel material is applied directly to the mold, for example by injecting the gel prepolymer into the mold cavity. During a direct molding process, before the gel material is injected, the film material layer comprising the pressure sensitive adhesive is applied to the mold cavity with the adhesive on the side of the film material closest to the mold and then the PU gel material is injected into the mold over the film material. The mold can be treated to resist bonding of the pressure sensitive adhesive or a release liner material can be applied in the mold first before the film material is applied to the mold. In certain embodiments of the invention, the mold may be preheated to the desired curing temperature prior to injecting the gel material or heated after all materials are loaded into the mold. For example, when using polyurethane gel materials according to the invention the mold temperature is typically between 85-95 C and the cycle time is approximately 8 min. The pressure is typically low and not critical for this type of operation provided that the pressure is high enough to fill the cavity-mold with polyurethane prepolymer.
As depicted in FIG. 2, a release liner 106 is shown contacting the exposed surface of the PSA layer depicted in FIG. 1B. In this example embodiment of the invention, the gel cushion can be manufactured by direct molding process. In this manner, the thin release liner laminate comprises the bottom layer assembly of the gel cushioning element and also aids in the ease of removing the formed gel cushioning element from a mold. The top thermoplastic film comprises the cover layer of the liner during the molding process. The release liner can be kept on the product when packaged for sale and discarded before applying the gel cushioning element to a surface, such as a shoe or other article of footwear. In certain embodiments the cushioning device may further comprise a synthetic rubber foam, a woven cotton fabric, a synthetic fiber, a knit fabric, a polyvinyl chloride film, and/or a synthetic non-woven fabric.
The products of the invention can be formed into any shape suitable for use as a cushioning device, for example for insertion into footwear to prevent rubbing between sensitive skin and hard or exposed surfaces of the footwear. The cushioning elements can also be applied to other garments e.g., hats, helmets, protective sporting gear such as elbow and knee pads and other garments requiring extra padding for comfort, sizing and/or safety. Cushioning elements according to the invention may also be applied to surfaces which come in contact with body parts to provide protection from injury such as, e.g., chairs, desks, cabinets, tables, doors and door frames, among others. Depending on the size and shape of the object to which the cushioning element is applied, certain shapes will better protect different areas of the body from contact with the object. In certain example embodiments the products are molded in the shape of, e.g., circles, parabolas, stars, squares, rectangles, rounded rectangles, half-moon, among others. The appropriate shape of the cushioning element can be determined based on the size and surface of the object to which the cushioning element will be applied. In alternative example embodiments, the cushioning element can be provided as a sheet of material that the user can cut to a desired shape. The sheet of material can also be provided with preformed shapes that can be removed as desired for the appropriate protection from contact with the object.

EXPERIMENTAL

A human wear test was conducted to compare the unmodified polyurethane gel cushion containing a sticky gel surface with a modified polyurethane gel cushion of the present invention containing a pressure sensitive adhesive. The test was run to determine if a cushioning device according to the invention would provide appropriate adhesion performance when compared to the unmodified polyurethane gel heel liner. Prior to the wear test, a probe tack test was conducted on both devices according to ASTM D 2979-01 to measure the force required to separate an adhesive and adherend shortly after they have been contacted under a defined load of known duration and at a specified temperature. The devices were also tested for shear hold according to PSTC-107 A, which measures the adhesive material's ability to remain adhered under a constant load applied parallel to the surface of the material and substrate, in particular measuring the shear adhesion when applied to a vertical standard steel panel. The two devices were determined to have the following adhesion tack and shear hold:


	PU gel without PSA	PU gel with PSA

Probe Tack (g)	449 +/− 9	422 +/− 39
Shear Hold (min)	445 +/− 220	325 +/− 173

Based on the results of the probe tack test and the shear hold test, those of ordinary skill in the art would recognize that the two heel liner devices have essentially the same adhesion tack and shear hold, and would be expected to have the same adhesion performance in use, i.e., the ability to stay in place in a shoe under normal wear.
The adhesion performance of heel liner cushions formed according to the invention was then evaluated in a wear test by volunteers who inserted the devices into their shoes and wore them for three days of normal use. The test subjects were divided such that 23 subjects evaluated the unmodified heel liners while 22 subjects evaluated the heel liner modified with PSA. Both the unmodified heel liners and the modified heel liners were similar in appearance so the test subjects did not know which device they were wearing. After three days, the test subjects were asked to rate their agreement or disagreement with whether the cushion stayed in place during normal use, rating according to a seven point scale:
Answer Rating

agree extremely 1

agree moderately 2

agree slightly 3

neither agree or disagree 4

disagree slightly 5

disagree moderately 6

disagree extremely 7

The sum of the top three rating answers indicated a positive feedback of the performance of the heel liner cushion adhesion and the sum of the bottom three rating answers indicated the negative feedback to the performance of the heel liner cushion. The results were as follows:


	Unmodified	Modified

Top 3 box	13	21
Bottom 3 box	10	1

As shown, the modified heel liners produced according to the subject invention containing the PSA produced an overwhelmingly positive feed back from users. Conversely, the unmodified heel liners showed equivocal results of positive and negative feed back. The statistical analysis (p of 0.0041) of the wear test results indicated that the liners modified with PSA according to the invention provide a better adhesion performance during wear than the unmodified version, which result was unexpected based on the probe tack and shear hold tests on the cushions.
Several embodiments of the present invention are specifically described herein. However, it will be appreciated that modifications and variations of the present invention are covered by the above teachings and within the purview of the appended claims without departing from the spirit and intended scope of the invention.

Claims

1.-58. (canceled)

59. A method for providing enhanced adhesion performance of a heel cushioning device in a shoe, which method comprises attaching to the inside of a shoe opposite the heel of a user a polyurethane gel cushioning device comprising an adhesive surface, the device comprising a layer of polyurethane gel material having an upper and lower surface and two layers of thermoplastic polyurethane film material, each layer of said thermoplastic polyurethane film material comprising upper and lower surfaces, wherein the upper surface of the polyurethane gel material is bonded with the lower surface of one of said layers of thermoplastic polyurethane film material and the lower surface of the polyurethane gel material is bonded with the upper surface of the other of said layer of thermoplastic polyurethane film material, wherein at least one of the layers of thermoplastic polyurethane film material comprises a pressure sensitive adhesive on a surface opposite the surface bonded to the polyurethane gel material thereby providing the adhesive surface of the heel cushioning device, wherein the adhesive surface of the heel cushioning device is positioned to attach the heel cushioning device to the inside of the shoe.

60. The method of claim 59, wherein the pressure sensitive adhesive comprises acrylic adhesives, methacrylate adhesives, rubber-based adhesives,

61. The method of claim 59, wherein the pressure sensitive adhesive is an adhesive based on styrene copolymers or silicones and combinations thereof.

62. The method of claim 61, wherein the styrene copolymers comprise styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, or combinations thereof.

63. The method of claim 59, wherein the acrylic adhesive comprises ethylene ethyl acrylate (EEA), ethylene methyl acrylate (EMA) copolymers, or combinations thereof.

64. The method of claim 59, wherein the pressure sensitive adhesive has a thickness of between about 0.0125 mm and about 0.25 mm.

65. The method of claim 59, wherein the polyurethane gel material has a Shore 00 hardness of between about 10 and about 80

66. The method of claim 59, wherein the polyurethane gel material has a Shore 00 hardness of between about 30 and about 60.

67. The method of claim 59, wherein the polyurethane gel material has a Shore 00 hardness of Shore 00 hardness of about 50.

68. The method of claim 59, wherein the polyurethane gel material has a thickness of between 0.3 and 3 mm.

69. The method of claim 59, wherein the thermoplastic polyurethane film material has a Shore A hardness of between about 40 to about 95.

70. The method of claim 59, wherein the thermoplastic polyurethane film material has a thickness of between 0.025 mm and 0.25 mm.

71. The method of claim 59, wherein said thermoplastic polyurethane film material has a thickness of at least 0.025 mm.

72. A method for providing enhanced adhesion performance of a cushioning device in a shoe, comprising providing a cushioning device comprising a gel material comprising top and bottom surfaces and at least one layer of thermoplastic film material comprising a top and bottom surface bonded to one or both of said top and bottom surfaces of said gel material, wherein at least one of said at least one layer of thermoplastic film material comprises a pressure sensitive adhesive opposite to the surface contacting said gel material thereby providing an adhesive surface of the cushioning device, wherein the adhesive surface of the device is positioned so as to attach the device to the inside of the shoe.

73. The method of claim 72, wherein the gel material is a polyurethane gel material.

74. The method of claim 72, wherein the thermoplastic film material is a polyurethane material.

75. The method of claim 72, wherein the gel material is SEBS gel material.

76. The method of claim 72, wherein the thermoplastic film material is SEBS material.

77. The method of claim 72, wherein the pressure sensitive adhesive comprises acrylic adhesives, methacrylate adhesives, rubber-based adhesives,

73. The method of claim 72, wherein the pressure sensitive adhesive is an adhesive based on styrene copolymers or silicones and combinations thereof.

74. The method of claim 73, wherein the styrene copolymers comprise styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, or combinations thereof.

75. The method of claim 72, wherein the acrylic adhesive comprises ethylene ethyl acrylate (EEA), ethylene methyl acrylate (EMA) copolymers, or combinations thereof.

76. The method of claim 72, wherein the pressure sensitive adhesive has a thickness of between about 0.0125 mm and about 0.25 mm.

77. The method of claim 72, wherein the polyurethane gel material has a Shore 00 hardness of between about 10 and about 80

78. The method of claim 72, wherein the polyurethane gel material has a Shore 00 hardness of between about 30 and about 60.

79. The method of claim 72, wherein the polyurethane gel material has a Shore 00 hardness of Shore 00 hardness of about 50.

80. The method of claim 72, wherein the polyurethane gel material has a thickness of between 0.3 and 3 mm.

81. The method of claim 72, wherein the thermoplastic polyurethane film material has a Shore A hardness of between about 40 to about 95.

82. The method of claim 72, wherein the thermoplastic polyurethane film material has a thickness of between 0.025 mm and 0.25 mm.

83. The method of claim 72, wherein said thermoplastic polyurethane film material has a thickness of at least 0.025 mm.