US20110016788A1 - Methods and system for heat recovery in a gasification system - Google Patents
Methods and system for heat recovery in a gasification system Download PDFInfo
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- US20110016788A1 US20110016788A1 US12/508,329 US50832909A US2011016788A1 US 20110016788 A1 US20110016788 A1 US 20110016788A1 US 50832909 A US50832909 A US 50832909A US 2011016788 A1 US2011016788 A1 US 2011016788A1
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- syngas
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- 238000002309 gasification Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 23
- 238000011084 recovery Methods 0.000 title description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 25
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 14
- 239000001569 carbon dioxide Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 7
- 230000005465 channeling Effects 0.000 claims description 4
- 238000005201 scrubbing Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 37
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- 238000000926 separation method Methods 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
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- 229910052760 oxygen Inorganic materials 0.000 description 9
- 238000010248 power generation Methods 0.000 description 9
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Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/86—Other features combined with waste-heat boilers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/067—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
- F22B1/1838—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
- F22B1/1846—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations the hot gas being loaded with particles, e.g. waste heat boilers after a coal gasification plant
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
- C10J2300/1653—Conversion of synthesis gas to energy integrated in a gasification combined cycle [IGCC]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
- C10J2300/1815—Recycle loops, e.g. gas, solids, heating medium, water for carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/466—Entrained flow processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0075—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for syngas or cracked gas cooling systems
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Definitions
- the field of the invention relates generally to integrated gasification combined-cycle (IGCC) power generation systems, and more specifically to methods and systems for heat recovery in IGCC systems.
- IGCC integrated gasification combined-cycle
- At least some known IGCC systems include a gasification system that is integrated with at least one power producing turbine system.
- known gasifiers convert a mixture of fuel, air or oxygen, steam, limestone, and/or other additives into an output of partially combusted gas, sometimes referred to as “syngas.”
- the hot combustion gases are supplied to the combustor of a gas turbine engine, which powers a generator that supplies electrical power to a power grid.
- Exhaust from at least some known gas turbine engines is supplied to a heat recovery steam generator that generates steam for driving a steam turbine. Power generated by the steam turbine also drives an electrical generator that provides electrical power to the power grid.
- hydro-carbonaceous feeds that include coal, petroleum coke and high-ash residual oils, are reacted with high purity oxygen (typically 95% oxygen purity) to produce syngas in a temperature range of 2200° F. to 2700° F.
- high purity oxygen typically 95% oxygen purity
- Most of the heat in this syngas is recovered as the syngas is channeled from a radiant syngas cooler (RSC) to a convective syngas cooler (CSC).
- Known radiant syngas coolers wherein the primary heat transfer mechanism is by radiation, cool the syngas to a range of about 1000° F. to about 1300° F. and generate high pressure steam thereform.
- Known convective syngas coolers where the primary heat transfer mechanism is by convection, generate high-pressure and some medium-pressure steam.
- Some known IGCC plants include a cooled connection line that couples the two syngas coolers to one another for use in generating medium-pressure steam.
- IGCC plants have experienced a tendency for fouling with particulate matter at some hot surfaces, particularly in the region of the entrance to the CSC.
- the presence of hot surfaces results in the particulate within the fuel gas impacting and adhering to the hot surfaces along the interiors of the connection lines.
- a tube and shell heat exchanger for a gasification system includes a first shell-side inlet positioned proximate to a heat exchanger inlet.
- the first shell-side inlet is configured to receive a first portion of a scrubbed syngas flow therethrough. This first scrubbed syngas portion facilitates substantially preventing fouling at the heat exchanger inlet.
- the heat exchanger also includes a second shell-side inlet positioned proximate to a heat exchanger outlet. The second shell-side inlet is configured to receive a second portion of a scrubbed syngas flow therethrough.
- a gasification system in another aspect, includes a gasifier configured to produce a flow of syngas, a syngas cooler configured to receive said flow of syngas from said gasifier and reduce a temperature associated with said flow of syngas; and a tube and shell heat exchanger.
- the heat exchanger includes a first shell-side inlet positioned proximate to a heat exchanger inlet.
- the first shell-side inlet is configured to receive a first portion of a scrubbed syngas flow therethrough. This first scrubbed syngas portion facilitates substantially preventing fouling at the heat exchanger inlet.
- the heat exchanger also includes a second shell-side inlet positioned proximate to a heat exchanger outlet.
- the second shell-side inlet is configured to receive a second portion of a scrubbed syngas flow therethrough.
- a method for operating a gasification system includes scrubbing a first stream of raw syngas to facilitate removing impurities therefrom, producing a stream of scrubbed syngas from the scrubbed first stream, transferring heat from a second stream of raw syngas to the stream of scrubbed syngas to produce a cooled raw syngas stream and a heated scrubbed syngas stream.
- the method also includes channeling at least a portion of the stream of scrubbed syngas to facilitate substantially preventing fouling from the first stream of raw syngas.
- FIG. 1 is a schematic diagram of an exemplary integrated gasification combined-cycle (IGCC) power generation system.
- IGCC integrated gasification combined-cycle
- FIG. 2 is a schematic illustration of an exemplary raw syngas/scrubbed syngas heat exchanger used with the IGCC power generation system shown in FIG. 1 .
- FIG. 3 is a schematic illustration of an asymmetrical split-flow heat exchanger used with the IGCC power generation system shown in FIG. 2 .
- FIG. 4 is a schematic illustration of an alternative split flow heat exchanger with an isolated entrance section that may be used with the IGCC power generation system shown in FIG. 2 .
- FIG. 1 is a schematic diagram of an exemplary integrated gasification combined-cycle (IGCC) power generation system 50 .
- IGCC system 50 generally includes a main air compressor 52 , an air separation unit 54 coupled in flow communication to compressor 52 , a gasifier 56 coupled in flow communication to air separation unit 54 , a gas turbine engine 10 coupled in flow communication to gasifier 56 , and a steam turbine 58 .
- compressor 52 compresses ambient air that is then channeled to air separation unit 54 .
- compressed air from gas turbine engine compressor 12 is supplied to air separation unit 54 .
- Air separation unit 54 uses the compressed air to generate oxygen for use by gasifier 56 .
- air separation unit 54 separates the compressed air into separate flows of oxygen and a gas by-product, sometimes referred to as a “process gas”.
- the process gas generated by air separation unit 54 includes nitrogen and is referred to herein as “nitrogen process gas”.
- the nitrogen process gas may also include other gases such as, but not limited to, oxygen and/or argon.
- the nitrogen process gas includes between about 95% and about 100% nitrogen.
- the oxygen flow from air separation unit 54 is channeled to gasifier 56 for use in generating partially combusted gases, referred to herein as “syngas” for use by gas turbine engine 10 as fuel, as is described in more detail herein.
- gasifier 56 for use in generating partially combusted gases, referred to herein as “syngas” for use by gas turbine engine 10 as fuel, as is described in more detail herein.
- at least some of the nitrogen process gas flow, a by-product of air separation unit 54 is vented to the atmosphere.
- some of the nitrogen process gas flow is injected into a combustion zone (not shown) within gas turbine engine combustor 14 to facilitate controlling emissions generated within engine 10 , and more specifically to facilitate reducing the combustion temperature and nitrous oxide emissions from engine 10 .
- IGCC system 50 also includes a compressor 60 for compressing the nitrogen process gas flow before it is injected into the combustion zone.
- Gasifier 56 converts a mixture of fuel, the oxygen supplied by air separation unit 54 , and recycle solids, and/or liquid water and/or steam, and/or a slag additive into an output of syngas for use by gas turbine engine 10 as fuel.
- gasifier 56 may use any fuel, in some embodiments, gasifier 56 uses coal, petroleum coke, residual oil, oil emulsions, tar sands, and/or other similar fuels.
- the syngas generated by gasifier 56 includes carbon dioxide.
- the syngas generated by gasifier 56 is cleaned in a clean-up device 62 before being channeled to gas turbine engine combustor 14 for combustion thereof. Carbon dioxide may be separated from the syngas during clean-up and, in the exemplary embodiment, the carbon dioxide is vented to the atmosphere.
- a gasifier blowdown connection is coupled to a waste treatment system (not shown in FIG. 1 ).
- Power output from gas turbine engine 10 is used to drive a generator 64 that supplies electrical power to a power grid (not shown).
- Exhaust gases from gas turbine engine 10 are supplied to a heat recovery steam generator 66 that generates steam for use by steam turbine 58 .
- Power generated by steam turbine 58 drives an electrical generator 68 that supplies electrical power to a power grid.
- steam from heat recovery steam generator 66 is supplied to gasifier 56 for generating the syngas.
- IGCC system 50 includes a syngas condensate stripper 76 that receives condensate from a stream of syngas discharged from gasifier 56 .
- the condensate typically includes a quantity of ammonia that is dissolved in the condensate. At least a portion of the dissolved ammonia is formed in gasifier 56 from a combination of nitrogen gas and hydrogen in gasifier 56 . To remove the dissolved ammonia from the condensate the condensate is boiled. Stripped ammonia is discharged from stripper 76 and is channeled to a waste treatment system (not shown in FIG. 1 ).
- the stripped ammonia is returned to gasifier 56 , at a pressure that is higher than that of the gasifier, to be decomposed in a high temperature region of the gasifier 56 proximate a nozzle tip 72 .
- the ammonia is injected into the gasifier 56 such that the flow of ammonia in the vicinity of the high temperature region proximate nozzle tip 72 facilitates cooling nozzle tip 72 .
- FIG. 2 is a schematic of an exemplary raw syngas/scrubbed syngas heat exchanger assembly 100 used with the IGCC power generation system 50 , shown in FIG. 1 .
- a gasifier 102 is provided that is configured to receive a flow of oxygen 104 , a flow of feedstock 106 , e.g. a coal slurry, and a flow of recycled carbon dioxide within conduit 108 .
- syngas produced in gasifier 102 is channeled via conduit 110 to a radiant syngas cooler (RSC) 112 .
- the temperature of the syngas upon entry to RSC 112 ranges from about 2300° F. to about 2500° F., but may range from about 2100° F. to about 2700° F.
- the syngas is cooled in RSC 112 and upon exiting RSC 112 is about 1100° F., but may range from about 1000° F. to about 1300° F.
- heat exchanger 114 is a convective syngas cooler (CSC) used for transferring heat from the raw syngas exiting RSC 112 to a recycled scrubbed syngas stream, as described herein. More specifically, in the exemplary embodiment, heat exchanger 114 includes a tube and shell configuration, as described in more detail herein.
- CSC convective syngas cooler
- the raw syngas stream is then channeled to a syngas scrubber 116 wherein any remaining particulate material (not shown) within the raw syngas stream is removed, forming a scrubbed syngas stream.
- scrubbed syngas is formed when raw syngas from heat exchanger 114 has been contacted with a flow of water 118 in scrubber 116 to wet and remove any contained particulates.
- the scrubbing water is separated from the syngas, and the scrubbed syngas is channeled through a recycling conduit 120 into heat exchanger 114 to cool heat exchanger internal surfaces (not shown in FIG. 2 ) and facilitate reducing the potential for fouling caused by the deposit of particulate material, as described in more detail herein.
- heat exchanger 114 further facilitates heating the recycled, scrubbed syngas received from conduit 120 before the syngas is channeled combustor 14 of gas turbine engine 10 (shown in FIG. 1 ) via a conduit 122 , which powers a generator that supplies electrical power to a power grid (not shown).
- the scrubbed syngas temperature will be increased to a temperature of about 850° F., but may range from about 700° F. to about 900° F.
- This reheated stream of scrubbed syngas is next channeled in parallel with two cooler streams in the IGCC plant to recover heat from the syngas flow to obtain a higher overall IGCC efficiency via conduits 150 , 152 .
- the first stream is processed to remove sulfur, and the second stream channels carbon dioxide recovered from the syngas to be recycled for use by gasifier 102 .
- Syngas is channeled via conduit 150 to a first heat exchanger 156 having a tube and shell configuration.
- Clean syngas is then channeled from first heat exchanger 156 via conduit 164 to a combustion turbine 166 for use as a fuel source.
- CO 2 produced as a waste product within sulfur removal system 160 is via a conduit 168 to a shell side of a second heat exchanger 170 , as described in more detail herein.
- syngas exiting heat exchanger 114 is channeled via conduits 122 and 152 to second heat exchanger 170 . More specifically, conduit 152 is coupled to a tube side 171 of second heat exchanger 170 and syngas is channeled therethrough. Waste CO 2 is channeled through a shell side 173 of second heat exchanger 170 and heated therein, which further cools syngas being channeled through tube side 171 . Waste CO 2 exits shell side 173 of second heat exchanger 170 and is channel via conduit 108 to gasifier 102 , as described in more detail herein. Syngas exiting tube side 171 of second heat exchanger 170 is channeled via a conduit 172 and mixes with syngas in conduit 158 at a junction 174 .
- syngas exiting heat exchanger 114 is channeled via conduit 122 to a third heat exchanger 180 .
- a temperature of syngas being channeled through a tube side 181 of third heat exchanger 180 produces a medium pressure steam 182 that may channeled via a conduit 184 to a steam turbine 186 for use in powering steam turbine 186 .
- Syngas exiting tube side 181 of third heat exchanger 180 is channeled via a conduit 188 to join syngas being channeled within conduit 172 at a junction 190 .
- FIG. 3 is a schematic of an asymmetrical split-flow heat exchanger 200 used with the IGCC power generation system 50 shown in FIG. 1 .
- heat exchanger 200 includes a tube and shell configuration including a shell 202 , a split-feed shell-side tube system 210 and a single-pass tube-side system 212 .
- Exchanger also includes a plurality of baffles 214 positioned within shell 202 that are configured to channel airflow therethrough, e.g. along a path 216 .
- Low temperature scrubbed syngas (in the temperature range of about 350° F. to about 400° F., as described herein) is channeled via a conduit 218 from scrubber 116 (shown in FIG.
- first flow conduit 222 A portion of the low temperature scrubbed syngas stream is channeled via first flow conduit 222 to a heat exchanger shell-side inlet on the hot gas end (tube-side) 226 .
- a restriction orifice 228 positioned along first flow conduit 222 regulates the flow of scrubbed syngas therethrough.
- about 10% of the scrubbed syngas that is channeled from scrubber 116 via conduit 218 is channeled to the shell-side inlet on the hot gas end 226 .
- about 5% to about 25% of the scrubbed syngas may be channeled to the shell-side inlet on the hot gas end 226 .
- the remaining portion of the low temperature scrubbed syngas stream is then channeled via second flow conduit 224 to a shell side entrance on the tube-side outlet end 230 of heat exchanger 200 .
- about 90% of the scrubbed syngas flow is channeled to shell side entrance 230 of heat exchanger 200 .
- about 75% to about 95% of the scrubbed syngas may be channeled to shell side entrance 230 , dependent upon the amount of syngas channeled via first flow conduit 222 to the shell-side inlet on the hot gas end 226 as regulated by restriction orifice 228 .
- the syngas stream within second flow conduit 224 is channeled counter to the flow of hot syngas within the tube-side system 212 .
- Such a flow maximizes the counter-current flow effect, resulting in a lower raw syngas outlet temperature, i.e. the scrubbed syngas exit temperature may be substantially higher than the hot syngas exit temperature.
- the hot scrubbed syngas exit nozzle positioned downstream at a location 233 where the flow pattern inside the tubes has become streamlined.
- an interior surface 234 of an inlet area of heat exchanger 200 is particularly prone to fouling as particulate within the raw syngas stream impacts and adheres to interior surface 234 due to a turbulent flow pattern of the hot syngas flowing into heat exchanger 200 .
- the insertion of a flow of relatively cooler scrubbed syngas, i.e., through heat exchanger hot gas end 226 cools the heat exchanger inlet tube surfaces substantially prevents the accumulation of particulate within heat exchanger inlet tube walls, and facilitates streamlining the syngas flow pattern immediately downstream from inlet area 236 so that particles no longer impinge against the tube wall surface.
- FIG. 4 is a schematic illustration of an alternative split flow heat exchanger 300 with an isolated entrance section 302 that may be used with the IGCC power generation system 50 , shown in FIG. 2 .
- heat exchanger 300 includes a tube and shell configuration including a shell 304 , a split-feed shell-side tube system 310 and a single-pass tube side system 312 .
- Exchanger also includes a plurality of baffles 314 positioned within shell 304 that are configured to channel airflow therethrough, e.g. along a path 316 .
- Low temperature scrubbed syngas (in the temperature range of about 350° F. to about 400° F, as described herein) is channeled via a conduit 318 from scrubber 116 (shown in FIG.
- Scrubbed syngas flow is divided therein at a junction 320 that includes a first flow conduit 322 and a second flow conduit 324 downstream from junction 320 .
- a portion of the low temperature scrubbed syngas stream is channeled via first flow conduit 322 to a heat exchanger hot gas end 326 .
- a control valve 328 positioned along first flow conduit 322 regulates the flow of scrubbed syngas therethrough.
- about 10% of the scrubbed syngas that is channeled from scrubber 116 via conduit 318 is channeled to hot gas end 326 .
- about 5% to about 25% of the scrubbed syngas may be channeled to hot gas end 326 .
- the remaining portion of the low temperature scrubbed syngas stream is then channeled via second flow conduit 324 to a shell-side, cold-end entrance 330 of heat exchanger 300 .
- Control valve 329 that is positioned along first flow conduit 324 regulates the flow of scrubbed syngas therethrough.
- about 90% of the scrubbed syngas flow is channeled to shell side cold end entrance 330 of heat exchanger 300 .
- about 75% to about 95% of the scrubbed syngas may be channeled along conduit 324 to shell-side entrance 330 , dependent upon the amount of syngas channeled via first flow conduit 322 to hot gas end 326 .
- the syngas stream within second flow conduit 324 is channeled counter to the flow of hot syngas along path 316 within tube side system 312 .
- syngas that is channeled to hot gas end 326 traverses a plurality of baffles 340 within isolated entrance section 302 and exits heat exchanger 300 at an outlet 344 .
- the syngas is then channeled via a conduit 346 to second flow conduit 324 , wherein the flow within conduit 346 remixes with the syngas flow within second flow conduit 324 at a junction 348 .
- Syngas channeled along path 316 exits heat exchanger at an outlet and is channel downstream therefrom via conduit 122 . This arrangement allows the total scrubbed syngas stream to be in counter-current flow, increasing the possible temperature exchange.
- the temperature on the shell side matches the temperature of the first portion after it has been preheated.
- a heat exchanger that may be utilized in IGCC plants that provides a highly efficient and reliable means facilitating lowering tube wall temperatures in the proximity of the heat exchanger inlet by recycling a quantity of scrubbed, cooled syngas.
- the heat exchanger system diverts a small portion of the cooler, scrubbed syngas from the syngas cooler back to the heat exchanger inlet. Since the flow pattern in the hot syngas is turbulent and the interior surface of the inlet tube is prone to fouling, this action facilitates the prevention of particulate impingement of the heat exchanger inlet tube wall. Further, in each embodiment, the reheated clean syngas produced following this recycling leads to a direct reduction in the syngas rate required by the gas turbine.
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Abstract
A tube and shell heat exchanger for a gasification system is provided. The heat exchanger includes a first shell-side inlet positioned proximate to a heat exchanger tube-side inlet. The first shell-side inlet is configured to receive a first portion of a scrubbed syngas flow therethrough. This first scrubbed syngas portion facilitates substantially preventing fouling at the heat exchanger inlet. The heat exchanger also includes a second shell-side inlet positioned proximate to a heat exchanger tube-side outlet. The second shell-side inlet is configured to receive a second portion of a scrubbed syngas flow therethrough.
Description
- The field of the invention relates generally to integrated gasification combined-cycle (IGCC) power generation systems, and more specifically to methods and systems for heat recovery in IGCC systems.
- At least some known IGCC systems include a gasification system that is integrated with at least one power producing turbine system. For example, known gasifiers convert a mixture of fuel, air or oxygen, steam, limestone, and/or other additives into an output of partially combusted gas, sometimes referred to as “syngas.” The hot combustion gases are supplied to the combustor of a gas turbine engine, which powers a generator that supplies electrical power to a power grid. Exhaust from at least some known gas turbine engines is supplied to a heat recovery steam generator that generates steam for driving a steam turbine. Power generated by the steam turbine also drives an electrical generator that provides electrical power to the power grid.
- In some known IGCC plants, hydro-carbonaceous feeds that include coal, petroleum coke and high-ash residual oils, are reacted with high purity oxygen (typically 95% oxygen purity) to produce syngas in a temperature range of 2200° F. to 2700° F. Most of the heat in this syngas is recovered as the syngas is channeled from a radiant syngas cooler (RSC) to a convective syngas cooler (CSC). Known radiant syngas coolers, wherein the primary heat transfer mechanism is by radiation, cool the syngas to a range of about 1000° F. to about 1300° F. and generate high pressure steam thereform. Known convective syngas coolers, where the primary heat transfer mechanism is by convection, generate high-pressure and some medium-pressure steam. Some known IGCC plants include a cooled connection line that couples the two syngas coolers to one another for use in generating medium-pressure steam.
- However, some known IGCC plants have experienced a tendency for fouling with particulate matter at some hot surfaces, particularly in the region of the entrance to the CSC. In such IGCC plants, the presence of hot surfaces results in the particulate within the fuel gas impacting and adhering to the hot surfaces along the interiors of the connection lines.
- In one aspect, a tube and shell heat exchanger for a gasification system is provided. The heat exchanger includes a first shell-side inlet positioned proximate to a heat exchanger inlet. The first shell-side inlet is configured to receive a first portion of a scrubbed syngas flow therethrough. This first scrubbed syngas portion facilitates substantially preventing fouling at the heat exchanger inlet. The heat exchanger also includes a second shell-side inlet positioned proximate to a heat exchanger outlet. The second shell-side inlet is configured to receive a second portion of a scrubbed syngas flow therethrough.
- In another aspect, a gasification system is provided. The system includes a gasifier configured to produce a flow of syngas, a syngas cooler configured to receive said flow of syngas from said gasifier and reduce a temperature associated with said flow of syngas; and a tube and shell heat exchanger. The heat exchanger includes a first shell-side inlet positioned proximate to a heat exchanger inlet. The first shell-side inlet is configured to receive a first portion of a scrubbed syngas flow therethrough. This first scrubbed syngas portion facilitates substantially preventing fouling at the heat exchanger inlet. The heat exchanger also includes a second shell-side inlet positioned proximate to a heat exchanger outlet. The second shell-side inlet is configured to receive a second portion of a scrubbed syngas flow therethrough.
- In yet another aspect, a method for operating a gasification system is provided. The method includes scrubbing a first stream of raw syngas to facilitate removing impurities therefrom, producing a stream of scrubbed syngas from the scrubbed first stream, transferring heat from a second stream of raw syngas to the stream of scrubbed syngas to produce a cooled raw syngas stream and a heated scrubbed syngas stream. The method also includes channeling at least a portion of the stream of scrubbed syngas to facilitate substantially preventing fouling from the first stream of raw syngas.
- Various refinements exist of the features noted in relation to the above-mentioned aspects of the present invention. Further features may also be incorporated in the above-mentioned aspects of the present invention as well. These refinements and additional features may exist individually or in any combination. For instance, various features discussed below in relation to any of the illustrated embodiments of the present invention may be incorporated into any of the above-described aspects of the present invention, alone or in any combination.
- Non-limiting and non-exhaustive embodiments are described with reference to the following figures, wherein like reference numerals refer to like parts throughout the various views unless otherwise specified.
-
FIG. 1 is a schematic diagram of an exemplary integrated gasification combined-cycle (IGCC) power generation system. -
FIG. 2 is a schematic illustration of an exemplary raw syngas/scrubbed syngas heat exchanger used with the IGCC power generation system shown inFIG. 1 . -
FIG. 3 is a schematic illustration of an asymmetrical split-flow heat exchanger used with the IGCC power generation system shown inFIG. 2 . -
FIG. 4 is a schematic illustration of an alternative split flow heat exchanger with an isolated entrance section that may be used with the IGCC power generation system shown inFIG. 2 . -
FIG. 1 is a schematic diagram of an exemplary integrated gasification combined-cycle (IGCC)power generation system 50. In the exemplary embodiment,IGCC system 50 generally includes amain air compressor 52, anair separation unit 54 coupled in flow communication tocompressor 52, agasifier 56 coupled in flow communication toair separation unit 54, agas turbine engine 10 coupled in flow communication to gasifier 56, and asteam turbine 58. In operation,compressor 52 compresses ambient air that is then channeled toair separation unit 54. In some embodiments, in addition to or in the alternative tocompressor 52, compressed air from gasturbine engine compressor 12 is supplied toair separation unit 54.Air separation unit 54 uses the compressed air to generate oxygen for use bygasifier 56. More specifically,air separation unit 54 separates the compressed air into separate flows of oxygen and a gas by-product, sometimes referred to as a “process gas”. The process gas generated byair separation unit 54 includes nitrogen and is referred to herein as “nitrogen process gas”. The nitrogen process gas may also include other gases such as, but not limited to, oxygen and/or argon. For example, in some embodiments, the nitrogen process gas includes between about 95% and about 100% nitrogen. - The oxygen flow from
air separation unit 54 is channeled to gasifier 56 for use in generating partially combusted gases, referred to herein as “syngas” for use bygas turbine engine 10 as fuel, as is described in more detail herein. In some embodiments, at least some of the nitrogen process gas flow, a by-product ofair separation unit 54, is vented to the atmosphere. Moreover, in other embodiments, some of the nitrogen process gas flow is injected into a combustion zone (not shown) within gasturbine engine combustor 14 to facilitate controlling emissions generated withinengine 10, and more specifically to facilitate reducing the combustion temperature and nitrous oxide emissions fromengine 10. In the exemplary embodiment, IGCCsystem 50 also includes acompressor 60 for compressing the nitrogen process gas flow before it is injected into the combustion zone. -
Gasifier 56 converts a mixture of fuel, the oxygen supplied byair separation unit 54, and recycle solids, and/or liquid water and/or steam, and/or a slag additive into an output of syngas for use bygas turbine engine 10 as fuel. Althoughgasifier 56 may use any fuel, in some embodiments,gasifier 56 uses coal, petroleum coke, residual oil, oil emulsions, tar sands, and/or other similar fuels. In the exemplary embodiment, the syngas generated bygasifier 56 includes carbon dioxide. As such, in the exemplary embodiment, the syngas generated bygasifier 56 is cleaned in a clean-updevice 62 before being channeled to gasturbine engine combustor 14 for combustion thereof. Carbon dioxide may be separated from the syngas during clean-up and, in the exemplary embodiment, the carbon dioxide is vented to the atmosphere. In the exemplary embodiment, a gasifier blowdown connection is coupled to a waste treatment system (not shown inFIG. 1 ). - Power output from
gas turbine engine 10 is used to drive agenerator 64 that supplies electrical power to a power grid (not shown). Exhaust gases fromgas turbine engine 10 are supplied to a heatrecovery steam generator 66 that generates steam for use bysteam turbine 58. Power generated bysteam turbine 58 drives anelectrical generator 68 that supplies electrical power to a power grid. In the exemplary embodiment, steam from heatrecovery steam generator 66 is supplied to gasifier 56 for generating the syngas. - In the exemplary embodiment, IGCC
system 50 includes asyngas condensate stripper 76 that receives condensate from a stream of syngas discharged fromgasifier 56. The condensate typically includes a quantity of ammonia that is dissolved in the condensate. At least a portion of the dissolved ammonia is formed ingasifier 56 from a combination of nitrogen gas and hydrogen ingasifier 56. To remove the dissolved ammonia from the condensate the condensate is boiled. Stripped ammonia is discharged fromstripper 76 and is channeled to a waste treatment system (not shown inFIG. 1 ). In an alternative embodiment, the stripped ammonia is returned togasifier 56, at a pressure that is higher than that of the gasifier, to be decomposed in a high temperature region of thegasifier 56 proximate anozzle tip 72. The ammonia is injected into thegasifier 56 such that the flow of ammonia in the vicinity of the high temperature regionproximate nozzle tip 72 facilitates coolingnozzle tip 72. -
FIG. 2 is a schematic of an exemplary raw syngas/scrubbed syngasheat exchanger assembly 100 used with the IGCCpower generation system 50, shown inFIG. 1 . In the exemplary embodiment, agasifier 102 is provided that is configured to receive a flow ofoxygen 104, a flow offeedstock 106, e.g. a coal slurry, and a flow of recycled carbon dioxide withinconduit 108. As described in more detail herein, syngas produced ingasifier 102 is channeled viaconduit 110 to a radiant syngas cooler (RSC) 112. The temperature of the syngas upon entry toRSC 112 ranges from about 2300° F. to about 2500° F., but may range from about 2100° F. to about 2700° F. The syngas is cooled inRSC 112 and upon exitingRSC 112 is about 1100° F., but may range from about 1000° F. to about 1300° F. - Upon exiting
RSC 112, syngas is then channeled via aconduit 113 through aheat exchanger 114 where it is cooled and facilitates forming a raw syngas stream (not shown) at a temperature of about 350° F., but may range from about 350° F. to about 500° F. In the exemplary embodiment,heat exchanger 114 is a convective syngas cooler (CSC) used for transferring heat from the rawsyngas exiting RSC 112 to a recycled scrubbed syngas stream, as described herein. More specifically, in the exemplary embodiment,heat exchanger 114 includes a tube and shell configuration, as described in more detail herein. The raw syngas stream is then channeled to asyngas scrubber 116 wherein any remaining particulate material (not shown) within the raw syngas stream is removed, forming a scrubbed syngas stream. More specifically, scrubbed syngas is formed when raw syngas fromheat exchanger 114 has been contacted with a flow ofwater 118 inscrubber 116 to wet and remove any contained particulates. The scrubbing water is separated from the syngas, and the scrubbed syngas is channeled through arecycling conduit 120 intoheat exchanger 114 to cool heat exchanger internal surfaces (not shown inFIG. 2 ) and facilitate reducing the potential for fouling caused by the deposit of particulate material, as described in more detail herein. - More specifically, and in the exemplary embodiment,
heat exchanger 114 further facilitates heating the recycled, scrubbed syngas received fromconduit 120 before the syngas is channeledcombustor 14 of gas turbine engine 10 (shown inFIG. 1 ) via aconduit 122, which powers a generator that supplies electrical power to a power grid (not shown). In this embodiment, following heat transfer from the entering raw syngas stream, the scrubbed syngas temperature will be increased to a temperature of about 850° F., but may range from about 700° F. to about 900° F. This reheated stream of scrubbed syngas is next channeled in parallel with two cooler streams in the IGCC plant to recover heat from the syngas flow to obtain a higher overall IGCC efficiency viaconduits 150, 152. The first stream is processed to remove sulfur, and the second stream channels carbon dioxide recovered from the syngas to be recycled for use bygasifier 102. - Syngas exits
heat exchanger 114 viaconduit 122 and, in the exemplary embodiment, is channeled to adownstream cooling system 154 that recovers heat from the syngas and further increases the overall efficiency of theIGCC system 50. Syngas is channeled viaconduit 150 to afirst heat exchanger 156 having a tube and shell configuration. The syngas exitsfirst heat exchanger 156 and is channeled via a conduit 158 to asulfur removal system 160 that further cleans the syngas stream. Clean syngas exitssulfur removal system 160 and is channeled via aconduit 162 to the shell side offirst heat exchanger 156 and is further heated therein by heat transferred from the syngas being channeled through the tube side offirst heat exchanger 156. Clean syngas is then channeled fromfirst heat exchanger 156 via conduit 164 to acombustion turbine 166 for use as a fuel source. In the exemplary embodiment, CO2 produced as a waste product withinsulfur removal system 160 is via aconduit 168 to a shell side of asecond heat exchanger 170, as described in more detail herein. - More specifically and in the exemplary embodiment, syngas exiting
heat exchanger 114 is channeled viaconduits 122 and 152 tosecond heat exchanger 170. More specifically, conduit 152 is coupled to atube side 171 ofsecond heat exchanger 170 and syngas is channeled therethrough. Waste CO2 is channeled through ashell side 173 ofsecond heat exchanger 170 and heated therein, which further cools syngas being channeled throughtube side 171. Waste CO2 exitsshell side 173 ofsecond heat exchanger 170 and is channel viaconduit 108 togasifier 102, as described in more detail herein. Syngas exitingtube side 171 ofsecond heat exchanger 170 is channeled via aconduit 172 and mixes with syngas in conduit 158 at a junction 174. - In the exemplary embodiment, syngas exiting
heat exchanger 114 is channeled viaconduit 122 to athird heat exchanger 180. A temperature of syngas being channeled through atube side 181 ofthird heat exchanger 180 produces amedium pressure steam 182 that may channeled via aconduit 184 to asteam turbine 186 for use in poweringsteam turbine 186. Syngas exitingtube side 181 ofthird heat exchanger 180 is channeled via aconduit 188 to join syngas being channeled withinconduit 172 at ajunction 190. -
FIG. 3 is a schematic of an asymmetrical split-flow heat exchanger 200 used with the IGCCpower generation system 50 shown inFIG. 1 . In the exemplary embodiment,heat exchanger 200 includes a tube and shell configuration including ashell 202, a split-feed shell-side tube system 210 and a single-pass tube-side system 212. Exchanger also includes a plurality ofbaffles 214 positioned withinshell 202 that are configured to channel airflow therethrough, e.g. along apath 216. Low temperature scrubbed syngas (in the temperature range of about 350° F. to about 400° F., as described herein) is channeled via aconduit 218 from scrubber 116 (shown inFIG. 2 ) into shell-side tube system 210. Scrubbed gas flow is divided therein at ajunction 220 that includes afirst flow conduit 222 and asecond flow conduit 224 downstream fromjunction 220. A portion of the low temperature scrubbed syngas stream is channeled viafirst flow conduit 222 to a heat exchanger shell-side inlet on the hot gas end (tube-side) 226. Arestriction orifice 228 positioned alongfirst flow conduit 222 regulates the flow of scrubbed syngas therethrough. In the exemplary embodiment, about 10% of the scrubbed syngas that is channeled fromscrubber 116 viaconduit 218 is channeled to the shell-side inlet on thehot gas end 226. Alternatively, about 5% to about 25% of the scrubbed syngas may be channeled to the shell-side inlet on thehot gas end 226. - The remaining portion of the low temperature scrubbed syngas stream is then channeled via
second flow conduit 224 to a shell side entrance on the tube-side outlet end 230 ofheat exchanger 200. In the exemplary embodiment, about 90% of the scrubbed syngas flow is channeled to shellside entrance 230 ofheat exchanger 200. Alternatively, about 75% to about 95% of the scrubbed syngas may be channeled to shellside entrance 230, dependent upon the amount of syngas channeled viafirst flow conduit 222 to the shell-side inlet on thehot gas end 226 as regulated byrestriction orifice 228. In the exemplary embodiment, the syngas stream withinsecond flow conduit 224 is channeled counter to the flow of hot syngas within the tube-side system 212. Such a flow maximizes the counter-current flow effect, resulting in a lower raw syngas outlet temperature, i.e. the scrubbed syngas exit temperature may be substantially higher than the hot syngas exit temperature. The hot scrubbed syngas exit nozzle positioned downstream at alocation 233 where the flow pattern inside the tubes has become streamlined. - During operation, an
interior surface 234 of an inlet area ofheat exchanger 200 is particularly prone to fouling as particulate within the raw syngas stream impacts and adheres tointerior surface 234 due to a turbulent flow pattern of the hot syngas flowing intoheat exchanger 200. The insertion of a flow of relatively cooler scrubbed syngas, i.e., through heat exchangerhot gas end 226, cools the heat exchanger inlet tube surfaces substantially prevents the accumulation of particulate within heat exchanger inlet tube walls, and facilitates streamlining the syngas flow pattern immediately downstream frominlet area 236 so that particles no longer impinge against the tube wall surface. -
FIG. 4 is a schematic illustration of an alternative splitflow heat exchanger 300 with anisolated entrance section 302 that may be used with the IGCCpower generation system 50, shown inFIG. 2 . In the illustrated embodiment,heat exchanger 300 includes a tube and shell configuration including ashell 304, a split-feed shell-side tube system 310 and a single-passtube side system 312. Exchanger also includes a plurality ofbaffles 314 positioned withinshell 304 that are configured to channel airflow therethrough, e.g. along apath 316. Low temperature scrubbed syngas (in the temperature range of about 350° F. to about 400° F, as described herein) is channeled via aconduit 318 from scrubber 116 (shown inFIG. 2 ) into shell-side tube system 310. Scrubbed syngas flow is divided therein at ajunction 320 that includes afirst flow conduit 322 and asecond flow conduit 324 downstream fromjunction 320. A portion of the low temperature scrubbed syngas stream is channeled viafirst flow conduit 322 to a heat exchangerhot gas end 326. Acontrol valve 328 positioned alongfirst flow conduit 322 regulates the flow of scrubbed syngas therethrough. In the exemplary embodiment, about 10% of the scrubbed syngas that is channeled fromscrubber 116 viaconduit 318 is channeled tohot gas end 326. Alternatively, about 5% to about 25% of the scrubbed syngas may be channeled tohot gas end 326. - The remaining portion of the low temperature scrubbed syngas stream is then channeled via
second flow conduit 324 to a shell-side, cold-end entrance 330 ofheat exchanger 300.Control valve 329 that is positioned alongfirst flow conduit 324 regulates the flow of scrubbed syngas therethrough. In the exemplary embodiment, about 90% of the scrubbed syngas flow is channeled to shell side cold end entrance 330 ofheat exchanger 300. Alternatively, about 75% to about 95% of the scrubbed syngas may be channeled alongconduit 324 to shell-side entrance 330, dependent upon the amount of syngas channeled viafirst flow conduit 322 tohot gas end 326. In the exemplary embodiment, the syngas stream withinsecond flow conduit 324 is channeled counter to the flow of hot syngas alongpath 316 withintube side system 312. - In the illustrated alternative embodiment, syngas that is channeled to
hot gas end 326 traverses a plurality ofbaffles 340 withinisolated entrance section 302 and exitsheat exchanger 300 at anoutlet 344. The syngas is then channeled via aconduit 346 tosecond flow conduit 324, wherein the flow withinconduit 346 remixes with the syngas flow withinsecond flow conduit 324 at ajunction 348. Syngas channeled alongpath 316 exits heat exchanger at an outlet and is channel downstream therefrom viaconduit 122. This arrangement allows the total scrubbed syngas stream to be in counter-current flow, increasing the possible temperature exchange. - During operation, depending on the amount of heating of the first portion of scrubbed syngas, it may be beneficial to feed this stream into a separate nozzle in the counter-current portion of the shell side of the exchanger. Optimally, the temperature on the shell side matches the temperature of the first portion after it has been preheated.
- Described herein is a heat exchanger that may be utilized in IGCC plants that provides a highly efficient and reliable means facilitating lowering tube wall temperatures in the proximity of the heat exchanger inlet by recycling a quantity of scrubbed, cooled syngas. In each embodiment, the heat exchanger system diverts a small portion of the cooler, scrubbed syngas from the syngas cooler back to the heat exchanger inlet. Since the flow pattern in the hot syngas is turbulent and the interior surface of the inlet tube is prone to fouling, this action facilitates the prevention of particulate impingement of the heat exchanger inlet tube wall. Further, in each embodiment, the reheated clean syngas produced following this recycling leads to a direct reduction in the syngas rate required by the gas turbine. As a result, an increase in the overall efficiency of the IGCC plant is realized. Moreover, the heating of carbon dioxide prior to recycling to the gasifier increases the amount of carbon dioxide that can be recycled, thereby substantially reducing adverse cooling of the reactor effluent. This higher carbon dioxide recycle maximizes the beneficial effects on carbon conversion and cold gas efficiency. Accordingly, the beneficial effects on carbon conversion and cold syngas efficiency are maximized.
- Although the foregoing description contains many specifics, these should not be construed as limiting the scope of the present invention, but merely as providing illustrations of some of the presently preferred embodiments. Similarly, other embodiments of the invention may be devised which do not depart from the spirit or scope of the present invention. Features from different embodiments may be employed in combination. The scope of the invention is, therefore, indicated and limited only by the appended claims and their legal equivalents, rather than by the foregoing description. All additions, deletions and modifications to the invention as disclosed herein which fall within the meaning and scope of the claims are to be embraced thereby.
- Although the apparatus and methods described herein are described in the context of IGCC plant heat exchangers, it is understood that the apparatus and methods are not limited to such systems. Likewise, the system components illustrated are not limited to the specific embodiments described herein, but rather, system components can be utilized independently and separately from other components described herein.
- As used herein, an element or step recited in the singular and proceeded with the word “a” or “an” should be understood as not excluding plural elements or steps, unless such exclusion is explicitly recited. Furthermore, references to “one embodiment” of the present invention are not intended to be interpreted as excluding the existence of additional embodiments that also incorporate the recited features.
- This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.
Claims (20)
1. A tube and shell heat exchanger for a gasification system, said heat exchanger comprising:
a first shell-side inlet positioned proximate to a heat exchanger tube-side inlet, said first shell-side inlet configured to receive a first portion of a scrubbed syngas flow therethrough, wherein said first scrubbed syngas portion facilitates substantially preventing fouling at said heat exchanger tube-side inlet; and
a second shell-side inlet positioned proximate to a heat exchanger tube-side outlet, said second shell-side inlet configured to receive a second portion of a scrubbed syngas flow therethrough.
2. A tube and shell heat exchanger in accordance with claim 1 , further comprising a plurality of shell-side baffles positioned within said heat exchanger configured to channel said first and second syngas flow portions to a shell side outlet.
3. A tube and shell heat exchanger in accordance with claim 2 , wherein said heat exchanger comprises at least one of a convective syngas cooler and an asymmetrical split flow exchanger.
4. A tube and shell heat exchanger in accordance with claim 2 , further comprising a split-feed shell-side tube system comprising a first flow path for channeling said first portion of a scrubbed syngas to said first shell-side inlet.
5. A tube and shell heat exchanger in accordance with claim 4 , wherein said split-feed shell-side tube system further comprises a second flow path configured to channel said second portion of a scrubbed syngas to said second shell-side inlet.
6. A tube and shell heat exchanger in accordance with claim 2 , further comprising a conduit configured to channel a quantity of carbon dioxide into said heat exchanger to facilitate subsequent cooling of at least a portion of the scrubbed syngas and facilitate recovering heat from the gasification system.
7. A tube and shell heat exchanger in accordance with claim 2 , wherein said heat exchanger is configured to produce a cooled raw syngas stream and a heated scrubbed syngas stream.
8. A gasification system comprising:
a gasifier configured to produce a flow of syngas;
a syngas cooler configured to receive said flow of syngas from said gasifier and reduce a temperature associated with said flow of syngas; and
a tube and shell heat exchanger comprising:
a first shell-side inlet positioned proximate to a heat exchanger tube-side inlet, said first shell-side inlet configured to receive a first portion of a scrubbed syngas flow therethrough, wherein said first scrubbed syngas portion facilitates substantially preventing fouling at said heat exchanger tube-side inlet; and
a second shell-side inlet positioned proximate to a heat exchanger tube-side outlet, said second shell-side inlet configured to receive a second portion of a scrubbed syngas flow therethrough.
9. A gasification system in accordance with claim 8 , further comprising a split-feed shell-side tube system comprising a first flow path for channeling said first portion of a scrubbed syngas to said first shell-side inlet.
10. A gasification system in accordance with claim 9 , wherein said split-feed shell-side tube system further comprises a second flow path configured to channel said second portion of a scrubbed syngas to said second shell-side inlet.
11. A gasification system in accordance with claim 10 , further comprising a syngas scrubber configured to channel a stream of scrubbed syngas to said split-feed shell-side tube system for distribution into said heat exchanger.
12. A gasification system in accordance with claim 8 , further comprising a plurality of shell-side baffles positioned within said heat exchanger to channel said first and second syngas flow portions to a shell side outlet.
13. The gasification system in accordance with claim 8 , further comprising a conduit configured to channel a quantity of carbon dioxide into said heat exchanger to facilitate subsequent cooling of at least a portion of the scrubbed syngas and facilitate recovering heat from said gasification system.
14. A method for operating a gasification system comprising:
scrubbing a first stream of raw syngas to facilitate removing impurities therefrom;
producing a stream of scrubbed syngas from said scrubbed first stream;
transferring heat from a second stream of raw syngas to the stream of scrubbed syngas to produce a cooled raw syngas stream and a heated scrubbed syngas stream; and
channeling at least a portion of said stream of scrubbed syngas to facilitate substantially preventing fouling from the first stream of raw syngas.
15. The method in accordance with claim 14 wherein the first and second raw syngas streams are raw syngas.
16. The method in accordance with claim 15 further comprising:
producing the first stream of raw syngas in a gasifier; and
cooling the first stream of raw syngas in a radiant syngas cooler prior to scrubbing.
17. The method in accordance with claim 14 wherein transferring heat is carried out in a convective syngas cooler.
18. The method in accordance with claim 17 wherein transferring heat is carried out in an asymmetrical split flow exchanger.
19. The method in accordance with claim 17 wherein transferring heat is carried out in a split flow exchanger with an isolated entrance section.
20. The method in accordance with claim 14 further comprising subsequently cooling of at least a portion of the scrubbed syngas heated in said tube and shell heat exchanger by heat exchange with recycled carbon dioxide to facilitate recovering heat from said gasification system.
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US12/508,329 US20110016788A1 (en) | 2009-07-23 | 2009-07-23 | Methods and system for heat recovery in a gasification system |
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US12/508,329 US20110016788A1 (en) | 2009-07-23 | 2009-07-23 | Methods and system for heat recovery in a gasification system |
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US12/508,329 Abandoned US20110016788A1 (en) | 2009-07-23 | 2009-07-23 | Methods and system for heat recovery in a gasification system |
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