US20100075721A1 - Transparent article - Google Patents
Transparent article Download PDFInfo
- Publication number
- US20100075721A1 US20100075721A1 US12/573,908 US57390809A US2010075721A1 US 20100075721 A1 US20100075721 A1 US 20100075721A1 US 57390809 A US57390809 A US 57390809A US 2010075721 A1 US2010075721 A1 US 2010075721A1
- Authority
- US
- United States
- Prior art keywords
- coating
- lamp according
- discharge vessel
- discharge
- arc discharge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 claims description 44
- 239000011248 coating agent Substances 0.000 claims description 35
- 230000004888 barrier function Effects 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 3
- 238000010891 electric arc Methods 0.000 claims 8
- 239000000919 ceramic Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 abstract description 32
- 238000000034 method Methods 0.000 abstract description 17
- 239000011347 resin Substances 0.000 abstract description 12
- 229920005989 resin Polymers 0.000 abstract description 12
- 238000005299 abrasion Methods 0.000 description 7
- 238000001723 curing Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- -1 polyacrylics Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/86—Vessels; Containers; Vacuum locks
- H01J29/89—Optical or photographic arrangements structurally combined or co-operating with the vessel
-
- G02B1/105—
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
Definitions
- the present invention relates to transparent articles and more particularly to a method of producing transparent articles having a coating thereon, e.g. to improve their abrasion resistance and/or optical properties.
- the invention relates particularly, but not exclusively, to the production of transparent articles for use as windows in display devices.
- Display units in articles such as calculators and mobile phones generally have a transparent (usually plastics) window with a thickness of at least 100 microns (e.g. 200 microns) which acts as a protective barrier for the display device yet allows the information displayed to be viewed by the user.
- the coatings have improved the physical and optical properties of the display screens the coating methods themselves have a number of disadvantages associated therewith.
- the methods are capital intensive, requite substantial facilities and services therefor and need highly qualified technical support.
- a method of producing a transparent article comprised of a parent base substrate having a thickness of at least 100 microns and a surface coating of a transparent resin wherein the resin is applied to the base substrate by means of a jet printer.
- a transparent resin coating is applied to the transparent base substrate by means of a jet printer.
- Such printers provide a particularly convenient method of applying the coating (which may be continuous or discontinuous) since they may be operated under computer control to provide the coating on the desired areas of the substrate. Furthermore such printers are readily available and provide a relatively cheap means for the accurate application of the coating in the mass production of transparent articles.
- the substrate will have a thickness of at least 125 microns preferably at least 150 microns, more preferably at least 175 microns and most preferably at cast 200 microns. Typically the thickness will be at least 300 and more preferably at least 400 microns. Generally the thickness of the substrate will be at most 20 mm, preferably at most 15 mm more preferably at most 12 mm and most preferably at most 10 mm. Typically the thickness of the substrate will be at most 8 mm, more preferably at most 6 mm, even more preferably at most 5 mm and typically at most 4 mm.
- the thickness will be in the range 750 microns to 3 mm.
- the coating that is applied may for example be one which improves the abrasion resistance of the base substrate (a so-called “hardcoat”) and/or the optical properties thereof (e.g. an anti-fog coating).
- the coating may incorporate a dye or pigment whilst still retaining its transparency.
- the jet printer is an ink-jet printer or a bubble jet printer. Most preferably the printer is an ink-jet printer. A particularly suitable printer is available from WEBER, model ML 500.
- An ink-jet printer has a plurality (e.g. 96) of ink-jets.
- the jets may be operated continuously or may be operated in accordance with a particular programmed pate for applying the coating.
- By operating the jets in accordance with such a program coating of selective areas of the substrate may be achieved For example portions of the substrate that need to be affixed to other members in order to form an assembled device can be selectively left uncoated, e.g. edge portions.
- the invention may be used for the coating of transparent substrates of relatively small size, e.g. having a longitudinal dimension of up to 20 cm and a transverse dimension of up to 15 cm. Such substrates may be fed in succession to the jet printer for the coating operation to be effected so that relatively small coated articles may be produced at a high rate.
- the invention may, however, also be used for the coating of larger substrates.
- a digital ink-jet printer having a number of printing heads is particularly suitable for the coating of larger substrates.
- the invention is particularly applicable to the application of coatings onto base substrates of a plastics material which may be a thermoplastics or thermoset material.
- plastics material which may be a thermoplastics or thermoset material.
- suitable plastics include polycarbonates, polyacrylics, polyesters and allyl carbonate (CR39).
- the transparent substrate may be of glass.
- the resin to be applied by the jet printer is preferably formulated as a solution or suspension in an appropriate carrier liquid. It is particularly preferred that the solution or suspension has a viscosity of 50 to 500 cP as measured on a Brookfield RVT Viscometer, Spindle No. RV2, 20 rpm at 25.degree. C. Solutions or suspension of such viscosity are particularly suitable for formation of a coating by a jet printing technique
- resin may be applied by the technique of the invention, e.g. polyurethanes, acrylates siloxanes, acrylics and combinations thereof. It is particularly preferred that the resin is cross-linkable so as to be capable of forming a cured coating on the base substrate.
- Cross linking may, for example, be by means of air drying, uv curing or thermal curing.
- Hardcoats will generally be based on either acrylate or siloxane chemistry and cured using either uv or thermal means. Anti-fog coatings may for example be based on hydrophilic polyurethanes.
- a particularly preferred embodiment of the method of the invention comprises feeding transparent articles in succession to the jet printer and then through a drying tunnel and a curing station.
- the coating is applied at the printer and residual solvent is removed on passage of the substrates through the drying tunnel Finally the curing station effects cross-linking of the resin (preferably by uv curing) to form a coherent coating thereof on the transparent substrate.
- the thickness of the rein coating will depend on the intended application of the substrate and/or the nature of the coating but will generally be in the range of 5 to 100 microns, more preferably 5 to 50 microns. In the case of a “hardcoat” for improving abrasion resistance the coating thickness will typically be 5-8 microns since increasing the thickness does not have any beneficial effects on the coating performance and may in fact be counter productive. In contrast the performance of anti-fog coatings is improved by increasing coating thickness so that values in the range 10 to 20 microns or higher may be most beneficial.
- the method of the invention is performed in a “clan” environment, i.e. an environment that is substantially free from dust and other atmospheric components which may detrimentally affect the coating process by affecting the binding of the resin to the base substrate and/or its subsequent curing.
- a “clan” environment i.e. an environment that is substantially free from dust and other atmospheric components which may detrimentally affect the coating process by affecting the binding of the resin to the base substrate and/or its subsequent curing.
- the method of the invention is carried out in an environment separated from the ambient atmosphere.
- This may be achieved by opening the method of the invention in a “tent”, particularly a tent which has its own integral air/gas supply.
- the tent atmosphere may be modified, e.g. to provide an inert atmosphere for the coating process and/or a positive tent pressure (i.e. a pressure above atmospheric) to exclude contaminants.
- the resin may be one which is intended to provide an abrasion reset coating on the transparent base substrate and/or improve the optical properties thereof e.g. by way of being an anti-glare or anti-mist coating.
- the invention is particularly applicable to the application of abrasion resistant coatings to plastics substrates.
- Abrasion resistance may be measured in accordance with ASIM D-1044 in which a CS10F standard wheel having a 500 gram load is rotated 1000 times on a sample. The HAZE value of the abraded substrate may then be measured.
- Uncoated acrylic and uncoated polycarbonates substrates give HAZE values of around 30% and 33% respectively (the exact value depending on thickness and source of supply).
- Use of the invention to apply a “hardcoat” to these substrates mikes it possible to reduce these HAZE values to less than the 10% maximum permitted by the ASTM specification. It is possible, for example, to reduce the HAZE values to and typically to 24% and even lower in certain cases, e.g. 1-1.5%.
- a display device having a display window which is a transparent article in accordance with the second aspect of the invention.
- the method of the invention may for example be used to produce a window (for a mobile phone or other item with a display device) from a pre-moulded transparent substrate to which is then applied a transparent coating in accordance with the method of the invention.
- the transparent substrate may also be provided with an opaque boarder formed of appropriately pigmented resin.
- the boarder may be applied to the same side as, or opposite side to, that to which the transparent coating has been applied.
- the opaque border may be applied by pad coating or by means of a jet printer. The use of a jet printer will be particularly convenient when the opaque boarder is applied to the same side of the substrate as the transparent coating.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Glass Compositions (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
- This application is a continuation of U.S. Ser. No. 10/484,190 filed May 24, 2004, which is a national stage entry of PCT/GB02/03308 filed Jul. 19, 2002, which claims the benefit of GB 0117568.6 filed Jul. 19, 2001.
- The present invention relates to transparent articles and more particularly to a method of producing transparent articles having a coating thereon, e.g. to improve their abrasion resistance and/or optical properties. The invention relates particularly, but not exclusively, to the production of transparent articles for use as windows in display devices.
- Display units in articles such as calculators and mobile phones generally have a transparent (usually plastics) window with a thickness of at least 100 microns (e.g. 200 microns) which acts as a protective barrier for the display device yet allows the information displayed to be viewed by the user.
- For many applications it may be desired to improve the surface characteristics of the window to avoid factors such as abrasion, glare in strong or direct sunlight and fogging in cold and/or humid conditions and for this purpose various coats have been employed These coatings have been applied to the screen by techniques including May coating dip coating and flow coating.
- Whilst the coatings have improved the physical and optical properties of the display screens the coating methods themselves have a number of disadvantages associated therewith. In particular, the methods are capital intensive, requite substantial facilities and services therefor and need highly qualified technical support.
- In addition it is very labour intensive using the above methods to coat selected areas of the surf as this can only be achieved by masking of the areas of the surfaces that are to remain uncoated.
- It is an object of the present invention to obviate or mitigate the problems outlined above.
- According to a first aspect of the present invention there is provided a method of producing a transparent article comprised of a parent base substrate having a thickness of at least 100 microns and a surface coating of a transparent resin wherein the resin is applied to the base substrate by means of a jet printer.
- According to a second aspect of the invention there is provided a transparent article produced by the method of the preceding paragraph.
- Thus in accordance with the invention a transparent resin coating is applied to the transparent base substrate by means of a jet printer. Such printers provide a particularly convenient method of applying the coating (which may be continuous or discontinuous) since they may be operated under computer control to provide the coating on the desired areas of the substrate. Furthermore such printers are readily available and provide a relatively cheap means for the accurate application of the coating in the mass production of transparent articles.
- Generally the substrate will have a thickness of at least 125 microns preferably at least 150 microns, more preferably at least 175 microns and most preferably at cast 200 microns. Typically the thickness will be at least 300 and more preferably at least 400 microns. Generally the thickness of the substrate will be at most 20 mm, preferably at most 15 mm more preferably at most 12 mm and most preferably at most 10 mm. Typically the thickness of the substrate will be at most 8 mm, more preferably at most 6 mm, even more preferably at most 5 mm and typically at most 4 mm.
- Most usually, the thickness will be in the range 750 microns to 3 mm.
- The coating that is applied may for example be one which improves the abrasion resistance of the base substrate (a so-called “hardcoat”) and/or the optical properties thereof (e.g. an anti-fog coating). The coating may incorporate a dye or pigment whilst still retaining its transparency.
- It is preferred that the jet printer is an ink-jet printer or a bubble jet printer. Most preferably the printer is an ink-jet printer. A particularly suitable printer is available from WEBER, model ML 500.
- An ink-jet printer has a plurality (e.g. 96) of ink-jets. The jets may be operated continuously or may be operated in accordance with a particular programmed pate for applying the coating. By operating the jets in accordance with such a program coating of selective areas of the substrate may be achieved For example portions of the substrate that need to be affixed to other members in order to form an assembled device can be selectively left uncoated, e.g. edge portions.
- The invention may be used for the coating of transparent substrates of relatively small size, e.g. having a longitudinal dimension of up to 20 cm and a transverse dimension of up to 15 cm. Such substrates may be fed in succession to the jet printer for the coating operation to be effected so that relatively small coated articles may be produced at a high rate. The invention may, however, also be used for the coating of larger substrates. A digital ink-jet printer having a number of printing heads is particularly suitable for the coating of larger substrates.
- The invention is particularly applicable to the application of coatings onto base substrates of a plastics material which may be a thermoplastics or thermoset material. Examples of suitable plastics include polycarbonates, polyacrylics, polyesters and allyl carbonate (CR39). Alternatively the transparent substrate may be of glass.
- The resin to be applied by the jet printer is preferably formulated as a solution or suspension in an appropriate carrier liquid. It is particularly preferred that the solution or suspension has a viscosity of 50 to 500 cP as measured on a Brookfield RVT Viscometer, Spindle No. RV2, 20 rpm at 25.degree. C. Solutions or suspension of such viscosity are particularly suitable for formation of a coating by a jet printing technique
- Various types of resin may be applied by the technique of the invention, e.g. polyurethanes, acrylates siloxanes, acrylics and combinations thereof. It is particularly preferred that the resin is cross-linkable so as to be capable of forming a cured coating on the base substrate. Cross linking may, for example, be by means of air drying, uv curing or thermal curing.
- “Hardcoats” will generally be based on either acrylate or siloxane chemistry and cured using either uv or thermal means. Anti-fog coatings may for example be based on hydrophilic polyurethanes.
- A particularly preferred embodiment of the method of the invention comprises feeding transparent articles in succession to the jet printer and then through a drying tunnel and a curing station. The coating is applied at the printer and residual solvent is removed on passage of the substrates through the drying tunnel Finally the curing station effects cross-linking of the resin (preferably by uv curing) to form a coherent coating thereof on the transparent substrate.
- The thickness of the rein coating will depend on the intended application of the substrate and/or the nature of the coating but will generally be in the range of 5 to 100 microns, more preferably 5 to 50 microns. In the case of a “hardcoat” for improving abrasion resistance the coating thickness will typically be 5-8 microns since increasing the thickness does not have any beneficial effects on the coating performance and may in fact be counter productive. In contrast the performance of anti-fog coatings is improved by increasing coating thickness so that values in the range 10 to 20 microns or higher may be most beneficial.
- For preference the method of the invention is performed in a “clan” environment, i.e. an environment that is substantially free from dust and other atmospheric components which may detrimentally affect the coating process by affecting the binding of the resin to the base substrate and/or its subsequent curing.
- Preferably the method of the invention is carried out in an environment separated from the ambient atmosphere. This may be achieved by opening the method of the invention in a “tent”, particularly a tent which has its own integral air/gas supply. In this way the tent atmosphere may be modified, e.g. to provide an inert atmosphere for the coating process and/or a positive tent pressure (i.e. a pressure above atmospheric) to exclude contaminants.
- As indicted above, the resin may be one which is intended to provide an abrasion reset coating on the transparent base substrate and/or improve the optical properties thereof e.g. by way of being an anti-glare or anti-mist coating.
- The invention is particularly applicable to the application of abrasion resistant coatings to plastics substrates. Abrasion resistance may be measured in accordance with ASIM D-1044 in which a CS10F standard wheel having a 500 gram load is rotated 1000 times on a sample. The HAZE value of the abraded substrate may then be measured. Uncoated acrylic and uncoated polycarbonates substrates give HAZE values of around 30% and 33% respectively (the exact value depending on thickness and source of supply). Use of the invention to apply a “hardcoat” to these substrates mikes it possible to reduce these HAZE values to less than the 10% maximum permitted by the ASTM specification. It is possible, for example, to reduce the HAZE values to and typically to 24% and even lower in certain cases, e.g. 1-1.5%.
- The advantages obtained in accordance with the method of the invention render it particularly suitable for the production of transparent substrates for use in a display device (e.g. LCD device) in a mobile phone or calculator.
- Therefore in accordance with a third aspect of the present invention there is provided a display device having a display window which is a transparent article in accordance with the second aspect of the invention.
- The method of the invention may for example be used to produce a window (for a mobile phone or other item with a display device) from a pre-moulded transparent substrate to which is then applied a transparent coating in accordance with the method of the invention.
- Optionally the transparent substrate may also be provided with an opaque boarder formed of appropriately pigmented resin. The boarder may be applied to the same side as, or opposite side to, that to which the transparent coating has been applied. In either case the opaque border may be applied by pad coating or by means of a jet printer. The use of a jet printer will be particularly convenient when the opaque boarder is applied to the same side of the substrate as the transparent coating.
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/573,908 US8722139B2 (en) | 2001-07-19 | 2009-10-06 | Transparent article |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0117568.6 | 2001-07-19 | ||
GBGB0117568.6A GB0117568D0 (en) | 2001-07-19 | 2001-07-19 | Transparent article |
US10/484,190 US20040191414A1 (en) | 2001-07-19 | 2002-07-19 | Transparent article |
PCT/GB2002/003308 WO2003009013A2 (en) | 2001-07-19 | 2002-07-19 | Transparent article |
US12/573,908 US8722139B2 (en) | 2001-07-19 | 2009-10-06 | Transparent article |
Related Parent Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10484190 Continuation | 2002-07-19 | ||
PCT/GB2002/003308 Continuation WO2003009013A2 (en) | 2001-07-19 | 2002-07-19 | Transparent article |
US10/484,190 Continuation US20040191414A1 (en) | 2001-07-19 | 2002-07-19 | Transparent article |
Publications (3)
Publication Number | Publication Date |
---|---|
US20100075721A1 true US20100075721A1 (en) | 2010-03-25 |
US20110086672A9 US20110086672A9 (en) | 2011-04-14 |
US8722139B2 US8722139B2 (en) | 2014-05-13 |
Family
ID=9918777
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/484,190 Abandoned US20040191414A1 (en) | 2001-07-19 | 2002-07-19 | Transparent article |
US12/573,908 Expired - Lifetime US8722139B2 (en) | 2001-07-19 | 2009-10-06 | Transparent article |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/484,190 Abandoned US20040191414A1 (en) | 2001-07-19 | 2002-07-19 | Transparent article |
Country Status (13)
Country | Link |
---|---|
US (2) | US20040191414A1 (en) |
EP (1) | EP1410075B1 (en) |
JP (1) | JP2004536338A (en) |
CN (1) | CN1246707C (en) |
AT (1) | ATE320612T1 (en) |
AU (1) | AU2002313530A1 (en) |
DE (1) | DE60209914T2 (en) |
DK (1) | DK1410075T3 (en) |
ES (1) | ES2260466T3 (en) |
GB (1) | GB0117568D0 (en) |
HK (1) | HK1069210A1 (en) |
PT (1) | PT1410075E (en) |
WO (1) | WO2003009013A2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101024916B1 (en) | 2004-03-19 | 2011-03-31 | 엘지전자 주식회사 | Method and device for recording data of high-density optical disc |
TWI257274B (en) * | 2005-04-27 | 2006-06-21 | Garmin Corp | Frosting-resistant panel structure |
FI121061B (en) * | 2007-07-04 | 2010-06-30 | Reate Oy | Method and apparatus for manufacturing an optical object |
AU2008203290C1 (en) * | 2008-07-23 | 2016-01-28 | Staffarena Corporation Pty Ltd | Steriliser Unit |
CN102019268A (en) * | 2010-12-31 | 2011-04-20 | 深圳创维-Rgb电子有限公司 | Injection sealed screen shell surface antifogging processing technology and product and video electronic device |
CN103897371B (en) * | 2012-12-30 | 2017-07-21 | 比亚迪股份有限公司 | Thermoset composition, mobile terminal form and preparation method thereof and the mobile terminal with the form |
WO2016128418A1 (en) * | 2015-02-10 | 2016-08-18 | The Trustees Of The Selectacoat Pension Scheme | Methods and apparatus for producing coated articles |
ES2677730B2 (en) * | 2017-02-06 | 2019-05-23 | Maier S Coop Ltda | MANUFACTURING PROCEDURE OF A EMBELLISHER WITH A PRINTED DECORATIVE PART FOR A VEHICLE, A SYSTEM FOR THE EXECUTION OF THE PROCEDURE AND EMBELLISHER WITH A PRINTED DECORATIVE PART. |
WO2022051624A1 (en) | 2020-09-04 | 2022-03-10 | Shanghai Yanfeng Jinqiao Automotive Trim Systems Co. Ltd. | Vehicle interior component |
Citations (14)
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US3935367A (en) * | 1972-11-24 | 1976-01-27 | Arthur D. Little, Inc. | Method of rendering surfaces nonfogging and resulting articles |
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US4348456A (en) * | 1977-09-28 | 1982-09-07 | Teijin Limited | Abrasion-resistant laminated film |
US5619288A (en) * | 1995-01-23 | 1997-04-08 | Essilor Of America, Inc. | Impact resistant plastic ophthalmic lens |
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US5693422A (en) * | 1990-10-02 | 1997-12-02 | Ppg Industries, Inc. | Silica-free UV-absorbing abrasion resistant coatings |
US5902648A (en) * | 1995-05-24 | 1999-05-11 | Matsushita Electric Industrial Co., Ltd. | Liquid application method and method of manufacturing electronic devices using the same liquid application method |
US6207728B1 (en) * | 1998-06-18 | 2001-03-27 | Jsr Corporation | Photo-curable composition and photo-cured product |
US6250760B1 (en) * | 1999-08-20 | 2001-06-26 | The Walman Optical Company | Silane-based coating composition |
US20010005942A1 (en) * | 1998-01-27 | 2001-07-05 | Patton David L. | Apparatus and method for marking a contoured surface having complex topology |
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- 2001-07-19 GB GBGB0117568.6A patent/GB0117568D0/en not_active Ceased
-
2002
- 2002-07-19 WO PCT/GB2002/003308 patent/WO2003009013A2/en active IP Right Grant
- 2002-07-19 AT AT02753124T patent/ATE320612T1/en active
- 2002-07-19 CN CNB02814399XA patent/CN1246707C/en not_active Expired - Fee Related
- 2002-07-19 ES ES02753124T patent/ES2260466T3/en not_active Expired - Lifetime
- 2002-07-19 PT PT02753124T patent/PT1410075E/en unknown
- 2002-07-19 DE DE60209914T patent/DE60209914T2/en not_active Expired - Lifetime
- 2002-07-19 JP JP2003514298A patent/JP2004536338A/en active Pending
- 2002-07-19 AU AU2002313530A patent/AU2002313530A1/en not_active Abandoned
- 2002-07-19 DK DK02753124T patent/DK1410075T3/en active
- 2002-07-19 US US10/484,190 patent/US20040191414A1/en not_active Abandoned
- 2002-07-19 EP EP02753124A patent/EP1410075B1/en not_active Revoked
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Also Published As
Publication number | Publication date |
---|---|
PT1410075E (en) | 2006-08-31 |
DE60209914D1 (en) | 2006-05-11 |
WO2003009013A3 (en) | 2003-05-08 |
US20040191414A1 (en) | 2004-09-30 |
ES2260466T3 (en) | 2006-11-01 |
GB0117568D0 (en) | 2001-09-12 |
US8722139B2 (en) | 2014-05-13 |
HK1069210A1 (en) | 2005-05-13 |
US20110086672A9 (en) | 2011-04-14 |
DK1410075T3 (en) | 2006-07-24 |
JP2004536338A (en) | 2004-12-02 |
WO2003009013A2 (en) | 2003-01-30 |
EP1410075A2 (en) | 2004-04-21 |
AU2002313530A1 (en) | 2003-03-03 |
DE60209914T2 (en) | 2006-12-14 |
CN1533510A (en) | 2004-09-29 |
CN1246707C (en) | 2006-03-22 |
EP1410075B1 (en) | 2006-03-15 |
ATE320612T1 (en) | 2006-04-15 |
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