US20090054236A1 - Herbicidally active composition - Google Patents
Herbicidally active composition Download PDFInfo
- Publication number
- US20090054236A1 US20090054236A1 US12/201,115 US20111508A US2009054236A1 US 20090054236 A1 US20090054236 A1 US 20090054236A1 US 20111508 A US20111508 A US 20111508A US 2009054236 A1 US2009054236 A1 US 2009054236A1
- Authority
- US
- United States
- Prior art keywords
- esters
- methyl
- safener
- salts
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 87
- 229940100389 Sulfonylurea Drugs 0.000 claims abstract description 52
- 150000002148 esters Chemical class 0.000 claims abstract description 45
- 150000003839 salts Chemical class 0.000 claims abstract description 38
- 239000005496 Chlorsulfuron Substances 0.000 claims abstract description 12
- VJYIFXVZLXQVHO-UHFFFAOYSA-N chlorsulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)Cl)=N1 VJYIFXVZLXQVHO-UHFFFAOYSA-N 0.000 claims abstract description 12
- ICJSJAJWTWPSBD-UHFFFAOYSA-N cloquintocet Chemical compound C1=CN=C2C(OCC(=O)O)=CC=C(Cl)C2=C1 ICJSJAJWTWPSBD-UHFFFAOYSA-N 0.000 claims abstract description 8
- UWHURBUBIHUHSU-UHFFFAOYSA-N 2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 UWHURBUBIHUHSU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000005626 Tribenuron Substances 0.000 claims abstract description 6
- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 claims abstract description 6
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000002363 herbicidal effect Effects 0.000 claims description 63
- -1 alkali metal salts Chemical class 0.000 claims description 61
- 241000196324 Embryophyta Species 0.000 claims description 45
- 150000001875 compounds Chemical class 0.000 claims description 44
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 claims description 29
- 239000012141 concentrate Substances 0.000 claims description 26
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 21
- 244000038559 crop plants Species 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000012053 oil suspension Substances 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000003960 organic solvent Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 239000005584 Metsulfuron-methyl Substances 0.000 claims description 9
- 239000012669 liquid formulation Substances 0.000 claims description 9
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 claims description 9
- 230000009261 transgenic effect Effects 0.000 claims description 9
- 239000005623 Thifensulfuron-methyl Substances 0.000 claims description 8
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 claims description 8
- 239000004495 emulsifiable concentrate Substances 0.000 claims description 7
- COYBRKAVBMYYSF-UHFFFAOYSA-N heptan-2-yl [(5-chloroquinolin-8-yl)oxy]acetate Chemical group C1=CN=C2C(OCC(=O)OC(C)CCCCC)=CC=C(Cl)C2=C1 COYBRKAVBMYYSF-UHFFFAOYSA-N 0.000 claims description 7
- 240000005979 Hordeum vulgare Species 0.000 claims description 6
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 6
- 235000021307 Triticum Nutrition 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 6
- 239000000729 antidote Substances 0.000 claims description 6
- 235000005822 corn Nutrition 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 claims description 6
- 240000007594 Oryza sativa Species 0.000 claims description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims description 5
- 239000004530 micro-emulsion Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 235000009566 rice Nutrition 0.000 claims description 5
- 239000004548 suspo-emulsion Substances 0.000 claims description 4
- 235000007319 Avena orientalis Nutrition 0.000 claims description 3
- 244000075850 Avena orientalis Species 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 3
- 244000068988 Glycine max Species 0.000 claims description 3
- 235000010469 Glycine max Nutrition 0.000 claims description 3
- 244000299507 Gossypium hirsutum Species 0.000 claims description 3
- 235000007238 Secale cereale Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 235000011684 Sorghum saccharatum Nutrition 0.000 claims description 2
- 238000009394 selective breeding Methods 0.000 claims description 2
- 244000082988 Secale cereale Species 0.000 claims 1
- 240000006394 Sorghum bicolor Species 0.000 claims 1
- 244000098338 Triticum aestivum Species 0.000 claims 1
- XEJNEDVTJPXRSM-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-5-methyl-4,5-dihydro-1H-pyrazole-3,5-dicarboxylic acid Chemical compound OC(=O)C1(C)CC(C(O)=O)=NN1C1=CC=C(Cl)C=C1Cl XEJNEDVTJPXRSM-UHFFFAOYSA-N 0.000 abstract description 6
- ITGSCCPVERXFGN-UHFFFAOYSA-N isoxadifen Chemical compound C1C(C(=O)O)=NOC1(C=1C=CC=CC=1)C1=CC=CC=C1 ITGSCCPVERXFGN-UHFFFAOYSA-N 0.000 abstract description 5
- HKELWJONQIFBPO-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1,2,4-triazole-3-carboxylic acid Chemical compound N1=C(C(=O)O)N=C(C(Cl)(Cl)Cl)N1C1=CC=C(Cl)C=C1Cl HKELWJONQIFBPO-UHFFFAOYSA-N 0.000 abstract description 3
- 101100377706 Escherichia phage T5 A2.2 gene Proteins 0.000 description 825
- 239000004009 herbicide Substances 0.000 description 54
- 239000000194 fatty acid Substances 0.000 description 41
- 235000014113 dietary fatty acids Nutrition 0.000 description 22
- 229930195729 fatty acid Natural products 0.000 description 22
- 238000009472 formulation Methods 0.000 description 20
- 229910052708 sodium Inorganic materials 0.000 description 20
- 239000011734 sodium Substances 0.000 description 20
- 239000003995 emulsifying agent Substances 0.000 description 18
- 239000004480 active ingredient Substances 0.000 description 17
- 239000002270 dispersing agent Substances 0.000 description 17
- 235000019484 Rapeseed oil Nutrition 0.000 description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 14
- 150000004702 methyl esters Chemical class 0.000 description 14
- 239000008187 granular material Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 239000002562 thickening agent Substances 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
- 239000002253 acid Substances 0.000 description 11
- 235000015112 vegetable and seed oil Nutrition 0.000 description 11
- 239000008158 vegetable oil Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 150000001768 cations Chemical class 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 8
- OPGCOAPTHCZZIW-UHFFFAOYSA-N diethyl 1-(2,4-dichlorophenyl)-5-methyl-4h-pyrazole-3,5-dicarboxylate Chemical compound CCOC(=O)C1(C)CC(C(=O)OCC)=NN1C1=CC=C(Cl)C=C1Cl OPGCOAPTHCZZIW-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000000227 grinding Methods 0.000 description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 238000005809 transesterification reaction Methods 0.000 description 7
- 239000004562 water dispersible granule Substances 0.000 description 7
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 125000004494 ethyl ester group Chemical group 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- MWKVXOJATACCCH-UHFFFAOYSA-N isoxadifen-ethyl Chemical compound C1C(C(=O)OCC)=NOC1(C=1C=CC=CC=1)C1=CC=CC=C1 MWKVXOJATACCCH-UHFFFAOYSA-N 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 241000209140 Triticum Species 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920000151 polyglycol Polymers 0.000 description 5
- 239000010695 polyglycol Substances 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000013008 thixotropic agent Substances 0.000 description 5
- 239000000443 aerosol Substances 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 239000003337 fertilizer Substances 0.000 description 4
- FOUWCSDKDDHKQP-UHFFFAOYSA-N flumioxazin Chemical compound FC1=CC=2OCC(=O)N(CC#C)C=2C=C1N(C1=O)C(=O)C2=C1CCCC2 FOUWCSDKDDHKQP-UHFFFAOYSA-N 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000002075 main ingredient Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 229940124530 sulfonamide Drugs 0.000 description 4
- 150000003456 sulfonamides Chemical class 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- 108010000700 Acetolactate synthase Proteins 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 3
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000010775 animal oil Substances 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 235000020778 linoleic acid Nutrition 0.000 description 3
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 3
- 229960004488 linolenic acid Drugs 0.000 description 3
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 235000021313 oleic acid Nutrition 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 239000002798 polar solvent Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 238000009331 sowing Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 3
- 239000004546 suspension concentrate Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- BHZWBQPHPLFZSV-UHFFFAOYSA-N (2,6-dibromo-4-cyanophenyl) heptanoate Chemical compound CCCCCCC(=O)OC1=C(Br)C=C(C#N)C=C1Br BHZWBQPHPLFZSV-UHFFFAOYSA-N 0.000 description 2
- DQKWXTIYGWPGOO-UHFFFAOYSA-N (2,6-dibromo-4-cyanophenyl) octanoate Chemical compound CCCCCCCC(=O)OC1=C(Br)C=C(C#N)C=C1Br DQKWXTIYGWPGOO-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 description 2
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- RBSXHDIPCIWOMG-UHFFFAOYSA-N 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea Chemical compound CCS(=O)(=O)C=1N=C2C=CC=CN2C=1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 RBSXHDIPCIWOMG-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- BXKKQFGRMSOANI-UHFFFAOYSA-N 1-methoxy-3-[4-[(2-methoxy-2,4,4-trimethyl-3h-chromen-7-yl)oxy]phenyl]-1-methylurea Chemical compound C1=CC(NC(=O)N(C)OC)=CC=C1OC1=CC=C2C(C)(C)CC(C)(OC)OC2=C1 BXKKQFGRMSOANI-UHFFFAOYSA-N 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 description 2
- MAYMYMXYWIVVOK-UHFFFAOYSA-N 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoic acid Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(CNS(C)(=O)=O)C=2)C(O)=O)=N1 MAYMYMXYWIVVOK-UHFFFAOYSA-N 0.000 description 2
- MPPOHAUSNPTFAJ-UHFFFAOYSA-N 2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 MPPOHAUSNPTFAJ-UHFFFAOYSA-N 0.000 description 2
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 description 2
- QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 description 2
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- ZOGDSYNXUXQGHF-UHFFFAOYSA-N 5-(3-butanoyl-2,4,6-trimethylphenyl)-2-[(Z)-N-ethoxy-C-ethylcarbonimidoyl]-3-hydroxycyclohex-2-en-1-one Chemical compound C(C)ON=C(CC)/C=1C(CC(CC1O)C1=C(C(=C(C=C1C)C)C(CCC)=O)C)=O ZOGDSYNXUXQGHF-UHFFFAOYSA-N 0.000 description 2
- DVOODWOZJVJKQR-UHFFFAOYSA-N 5-tert-butyl-3-(2,4-dichloro-5-prop-2-ynoxyphenyl)-1,3,4-oxadiazol-2-one Chemical group O=C1OC(C(C)(C)C)=NN1C1=CC(OCC#C)=C(Cl)C=C1Cl DVOODWOZJVJKQR-UHFFFAOYSA-N 0.000 description 2
- MDBGGTQNNUOQRC-UHFFFAOYSA-N Allidochlor Chemical compound ClCC(=O)N(CC=C)CC=C MDBGGTQNNUOQRC-UHFFFAOYSA-N 0.000 description 2
- 239000005489 Bromoxynil Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000005493 Chloridazon (aka pyrazone) Chemical class 0.000 description 2
- 239000005499 Clomazone Substances 0.000 description 2
- 239000005504 Dicamba Substances 0.000 description 2
- QNXAVFXEJCPCJO-UHFFFAOYSA-N Diclosulam Chemical compound N=1N2C(OCC)=NC(F)=CC2=NC=1S(=O)(=O)NC1=C(Cl)C=CC=C1Cl QNXAVFXEJCPCJO-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- FDNBWBAHQKZDSN-UHFFFAOYSA-N F5231 Chemical compound C1=C(Cl)C(NS(=O)(=O)CC)=CC(N2C(N(CCCF)N=N2)=O)=C1F FDNBWBAHQKZDSN-UHFFFAOYSA-N 0.000 description 2
- GMBRUAIJEFRHFQ-UHFFFAOYSA-N Fenchlorazole-ethyl Chemical compound N1=C(C(=O)OCC)N=C(C(Cl)(Cl)Cl)N1C1=CC=C(Cl)C=C1Cl GMBRUAIJEFRHFQ-UHFFFAOYSA-N 0.000 description 2
- PQKBPHSEKWERTG-UHFFFAOYSA-N Fenoxaprop ethyl Chemical group C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 PQKBPHSEKWERTG-UHFFFAOYSA-N 0.000 description 2
- QZXATCCPQKOEIH-UHFFFAOYSA-N Florasulam Chemical compound N=1N2C(OC)=NC=C(F)C2=NC=1S(=O)(=O)NC1=C(F)C=CC=C1F QZXATCCPQKOEIH-UHFFFAOYSA-N 0.000 description 2
- AOQMRUTZEYVDIL-UHFFFAOYSA-N Flupoxam Chemical compound C=1C=C(Cl)C(COCC(F)(F)C(F)(F)F)=CC=1N1N=C(C(=O)N)N=C1C1=CC=CC=C1 AOQMRUTZEYVDIL-UHFFFAOYSA-N 0.000 description 2
- 239000005560 Foramsulfuron Substances 0.000 description 2
- 239000005562 Glyphosate Substances 0.000 description 2
- PMAAYIYCDXGUAP-UHFFFAOYSA-N Indanofan Chemical compound O=C1C2=CC=CC=C2C(=O)C1(CC)CC1(C=2C=C(Cl)C=CC=2)CO1 PMAAYIYCDXGUAP-UHFFFAOYSA-N 0.000 description 2
- JUJFQMPKBJPSFZ-UHFFFAOYSA-M Iodosulfuron-methyl-sodium Chemical compound [Na+].COC(=O)C1=CC=C(I)C=C1S(=O)(=O)[N-]C(=O)NC1=NC(C)=NC(OC)=N1 JUJFQMPKBJPSFZ-UHFFFAOYSA-M 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 239000005574 MCPA Substances 0.000 description 2
- 239000005577 Mesosulfuron Substances 0.000 description 2
- VGHPMIFEKOFHHQ-UHFFFAOYSA-N Metosulam Chemical compound N1=C2N=C(OC)C=C(OC)N2N=C1S(=O)(=O)NC1=C(Cl)C=CC(C)=C1Cl VGHPMIFEKOFHHQ-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- IUFUITYPUYMIHI-UHFFFAOYSA-N N-[1-(3,5-dimethylphenoxy)propan-2-yl]-6-(2-fluoropropan-2-yl)-1,3,5-triazine-2,4-diamine Chemical compound N=1C(N)=NC(C(C)(C)F)=NC=1NC(C)COC1=CC(C)=CC(C)=C1 IUFUITYPUYMIHI-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000005601 Propoxycarbazone Substances 0.000 description 2
- LTUNNEGNEKBSEH-UHFFFAOYSA-N Prosulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)CCC(F)(F)F)=N1 LTUNNEGNEKBSEH-UHFFFAOYSA-N 0.000 description 2
- 241000209056 Secale Species 0.000 description 2
- 244000062793 Sorghum vulgare Species 0.000 description 2
- XJCLWVXTCRQIDI-UHFFFAOYSA-N Sulfallate Chemical compound CCN(CC)C(=S)SCC(Cl)=C XJCLWVXTCRQIDI-UHFFFAOYSA-N 0.000 description 2
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- PNRAZZZISDRWMV-UHFFFAOYSA-N Terbucarb Chemical compound CNC(=O)OC1=C(C(C)(C)C)C=C(C)C=C1C(C)(C)C PNRAZZZISDRWMV-UHFFFAOYSA-N 0.000 description 2
- KDWQYMVPYJGPHS-UHFFFAOYSA-N Thenylchlor Chemical compound C1=CSC(CN(C(=O)CCl)C=2C(=CC=CC=2C)C)=C1OC KDWQYMVPYJGPHS-UHFFFAOYSA-N 0.000 description 2
- YIJZJEYQBAAWRJ-UHFFFAOYSA-N Thiazopyr Chemical compound N1=C(C(F)F)C(C(=O)OC)=C(CC(C)C)C(C=2SCCN=2)=C1C(F)(F)F YIJZJEYQBAAWRJ-UHFFFAOYSA-N 0.000 description 2
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 239000007798 antifreeze agent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- XOEMATDHVZOBSG-UHFFFAOYSA-N azafenidin Chemical compound C1=C(OCC#C)C(Cl)=CC(Cl)=C1N1C(=O)N2CCCCC2=N1 XOEMATDHVZOBSG-UHFFFAOYSA-N 0.000 description 2
- MAHPNPYYQAIOJN-UHFFFAOYSA-N azimsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C2=NN(C)N=N2)C)=N1 MAHPNPYYQAIOJN-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 235000012216 bentonite Nutrition 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 2
- FUHMZYWBSHTEDZ-UHFFFAOYSA-M bispyribac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C([O-])=O)=N1 FUHMZYWBSHTEDZ-UHFFFAOYSA-M 0.000 description 2
- HFEJHAAIJZXXRE-UHFFFAOYSA-N cafenstrole Chemical compound CCN(CC)C(=O)N1C=NC(S(=O)(=O)C=2C(=CC(C)=CC=2C)C)=N1 HFEJHAAIJZXXRE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- WYKYKTKDBLFHCY-UHFFFAOYSA-N chloridazon Chemical class O=C1C(Cl)=C(N)C=NN1C1=CC=CC=C1 WYKYKTKDBLFHCY-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- KIEDNEWSYUYDSN-UHFFFAOYSA-N clomazone Chemical compound O=C1C(C)(C)CON1CC1=CC=CC=C1Cl KIEDNEWSYUYDSN-UHFFFAOYSA-N 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- MZZBPDKVEFVLFF-UHFFFAOYSA-N cyanazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 MZZBPDKVEFVLFF-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- PQKBPHSEKWERTG-LLVKDONJSA-N ethyl (2r)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoate Chemical group C1=CC(O[C@H](C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 PQKBPHSEKWERTG-LLVKDONJSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- ZCNQYNHDVRPZIH-UHFFFAOYSA-N fluthiacet-methyl Chemical group C1=C(Cl)C(SCC(=O)OC)=CC(N=C2N3CCCCN3C(=O)S2)=C1F ZCNQYNHDVRPZIH-UHFFFAOYSA-N 0.000 description 2
- PXDNXJSDGQBLKS-UHFFFAOYSA-N foramsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(NC=O)C=2)C(=O)N(C)C)=N1 PXDNXJSDGQBLKS-UHFFFAOYSA-N 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical compound C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- NIFKBBMCXCMCAO-UHFFFAOYSA-N methyl 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoate Chemical group COC(=O)C1=CC=C(CNS(C)(=O)=O)C=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 NIFKBBMCXCMCAO-UHFFFAOYSA-N 0.000 description 2
- JTHMVYBOQLDDIY-UHFFFAOYSA-N methyl 2-[(4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carbonyl)sulfamoyl]benzoate Chemical compound O=C1N(C)C(OCCC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1C(=O)OC JTHMVYBOQLDDIY-UHFFFAOYSA-N 0.000 description 2
- VWGAYSCWLXQJBQ-UHFFFAOYSA-N methyl 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoate Chemical compound COC(=O)C1=CC=C(I)C=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 VWGAYSCWLXQJBQ-UHFFFAOYSA-N 0.000 description 2
- DDDGRPLHUZOASC-UHFFFAOYSA-N methyl 5-[carbamoyl-(4,6-dimethylpyrimidin-2-yl)sulfamoyl]-1-pyridin-2-ylpyrazole-4-carboxylate Chemical compound COC(=O)C=1C=NN(C=2N=CC=CC=2)C=1S(=O)(=O)N(C(N)=O)C1=NC(C)=CC(C)=N1 DDDGRPLHUZOASC-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- HZDIJTXDRLNTIS-DAXSKMNVSA-N n-[[(z)-but-2-enoxy]methyl]-2-chloro-n-(2,6-diethylphenyl)acetamide Chemical compound CCC1=CC=CC(CC)=C1N(COC\C=C/C)C(=O)CCl HZDIJTXDRLNTIS-DAXSKMNVSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- UCDPMNSCCRBWIC-UHFFFAOYSA-N orthosulfamuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)NC=2C(=CC=CC=2)C(=O)N(C)C)=N1 UCDPMNSCCRBWIC-UHFFFAOYSA-N 0.000 description 2
- IOXAXYHXMLCCJJ-UHFFFAOYSA-N oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC2COC2)=N1 IOXAXYHXMLCCJJ-UHFFFAOYSA-N 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 229910052615 phyllosilicate Inorganic materials 0.000 description 2
- 230000000885 phytotoxic effect Effects 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229920000867 polyelectrolyte Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 239000011814 protection agent Substances 0.000 description 2
- APTZNLHMIGJTEW-UHFFFAOYSA-N pyraflufen-ethyl Chemical group C1=C(Cl)C(OCC(=O)OCC)=CC(C=2C(=C(OC(F)F)N(C)N=2)Cl)=C1F APTZNLHMIGJTEW-UHFFFAOYSA-N 0.000 description 2
- USSIUIGPBLPCDF-KEBDBYFISA-N pyriminobac-methyl Chemical group CO\N=C(/C)C1=CC=CC(OC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC USSIUIGPBLPCDF-KEBDBYFISA-N 0.000 description 2
- PETSAYFQSGAEQY-UHFFFAOYSA-N ricinine Chemical compound COC=1C=CN(C)C(=O)C=1C#N PETSAYFQSGAEQY-UHFFFAOYSA-N 0.000 description 2
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- WQQPDTLGLVLNOH-UHFFFAOYSA-M sodium;4-hydroxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].OC(=O)CC(C([O-])=O)S(O)(=O)=O WQQPDTLGLVLNOH-UHFFFAOYSA-M 0.000 description 2
- JRQGDDUXDKCWRF-UHFFFAOYSA-M sodium;n-(2-methoxycarbonylphenyl)sulfonyl-4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carboximidate Chemical compound [Na+].O=C1N(C)C(OCCC)=NN1C(=O)[N-]S(=O)(=O)C1=CC=CC=C1C(=O)OC JRQGDDUXDKCWRF-UHFFFAOYSA-M 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000002600 sunflower oil Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- RJKCKKDSSSRYCB-UHFFFAOYSA-N tebutam Chemical compound CC(C)(C)C(=O)N(C(C)C)CC1=CC=CC=C1 RJKCKKDSSSRYCB-UHFFFAOYSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 239000010496 thistle oil Substances 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- VIXCLRUCUMWJFF-KGLIPLIRSA-N (1R,5S)-benzobicyclon Chemical compound CS(=O)(=O)c1ccc(C(=O)C2=C(Sc3ccccc3)[C@H]3CC[C@H](C3)C2=O)c(Cl)c1 VIXCLRUCUMWJFF-KGLIPLIRSA-N 0.000 description 1
- GXEKYRXVRROBEV-FBXFSONDSA-N (1r,2s,3r,4s)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1C[C@@H]2[C@@H](C(O)=O)[C@@H](C(=O)O)[C@H]1O2 GXEKYRXVRROBEV-FBXFSONDSA-N 0.000 description 1
- HTBQOINACZOEPC-UHFFFAOYSA-N (2,4-dichlorophenyl)-(1-methyl-5-phenylmethoxypyrazol-4-yl)methanone Chemical compound C=1C=CC=CC=1COC=1N(C)N=CC=1C(=O)C1=CC=C(Cl)C=C1Cl HTBQOINACZOEPC-UHFFFAOYSA-N 0.000 description 1
- PGMZYNZXIYOOHJ-UHFFFAOYSA-N (2,6-dibromo-4-cyanophenyl) butanoate Chemical compound CCCC(=O)OC1=C(Br)C=C(C#N)C=C1Br PGMZYNZXIYOOHJ-UHFFFAOYSA-N 0.000 description 1
- IPPAUTOBDWNELX-UHFFFAOYSA-N (2-ethoxy-2-oxoethyl) 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate Chemical group C1=C([N+]([O-])=O)C(C(=O)OCC(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 IPPAUTOBDWNELX-UHFFFAOYSA-N 0.000 description 1
- ROBSGBGTWRRYSK-SNVBAGLBSA-N (2r)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propanoic acid Chemical class C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=CC=C(C#N)C=C1F ROBSGBGTWRRYSK-SNVBAGLBSA-N 0.000 description 1
- MPPOHAUSNPTFAJ-SECBINFHSA-N (2r)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoic acid Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 MPPOHAUSNPTFAJ-SECBINFHSA-N 0.000 description 1
- NYHLMHAKWBUZDY-QMMMGPOBSA-N (2s)-2-[2-chloro-5-[2-chloro-4-(trifluoromethyl)phenoxy]benzoyl]oxypropanoic acid Chemical compound C1=C(Cl)C(C(=O)O[C@@H](C)C(O)=O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 NYHLMHAKWBUZDY-QMMMGPOBSA-N 0.000 description 1
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- LNGRZPZKVUBWQV-UHFFFAOYSA-N (4-chloro-2-methylsulfonylphenyl)-(5-cyclopropyl-1,2-oxazol-4-yl)methanone Chemical compound CS(=O)(=O)C1=CC(Cl)=CC=C1C(=O)C1=C(C2CC2)ON=C1 LNGRZPZKVUBWQV-UHFFFAOYSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 1
- MZHCENGPTKEIGP-RXMQYKEDSA-N (R)-dichlorprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-RXMQYKEDSA-N 0.000 description 1
- WNTGYJSOUMFZEP-SSDOTTSWSA-N (R)-mecoprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-SSDOTTSWSA-N 0.000 description 1
- WVQBLGZPHOPPFO-LBPRGKRZSA-N (S)-metolachlor Chemical compound CCC1=CC=CC(C)=C1N([C@@H](C)COC)C(=O)CCl WVQBLGZPHOPPFO-LBPRGKRZSA-N 0.000 description 1
- OVXMBIVWNJDDSM-UHFFFAOYSA-N (benzhydrylideneamino) 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate Chemical compound COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C(=O)ON=C(C=2C=CC=CC=2)C=2C=CC=CC=2)=N1 OVXMBIVWNJDDSM-UHFFFAOYSA-N 0.000 description 1
- GVROBYMTUJVBJZ-UHFFFAOYSA-N 1-(3-methylphenyl)-5-phenyl-1,2,4-triazole-3-carboxamide Chemical compound CC1=CC=CC(N2C(=NC(=N2)C(N)=O)C=2C=CC=CC=2)=C1 GVROBYMTUJVBJZ-UHFFFAOYSA-N 0.000 description 1
- JXXAENOFMXLHMD-UHFFFAOYSA-N 1-(4-ethoxy-6-ethyl-1,3,5-triazin-2-yl)-3-[(2-methyl-1,1-dioxo-2,3-dihydro-1-benzothiophen-7-yl)sulfonyl]urea Chemical compound CCOC1=NC(CC)=NC(NC(=O)NS(=O)(=O)C=2C=3S(=O)(=O)C(C)CC=3C=CC=2)=N1 JXXAENOFMXLHMD-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- JLUPSFKBYGTZJQ-UHFFFAOYSA-N 1-tert-butyl-5-cyano-n-methylpyrazole-4-carboxamide Chemical compound CNC(=O)C=1C=NN(C(C)(C)C)C=1C#N JLUPSFKBYGTZJQ-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- JMWHUPNEZGZRGE-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol;2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1.C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 JMWHUPNEZGZRGE-UHFFFAOYSA-N 0.000 description 1
- 239000002794 2,4-DB Substances 0.000 description 1
- YOYAIZYFCNQIRF-UHFFFAOYSA-N 2,6-dichlorobenzonitrile Chemical compound ClC1=CC=CC(Cl)=C1C#N YOYAIZYFCNQIRF-UHFFFAOYSA-N 0.000 description 1
- KGKGSIUWJCAFPX-UHFFFAOYSA-N 2,6-dichlorothiobenzamide Chemical class NC(=S)C1=C(Cl)C=CC=C1Cl KGKGSIUWJCAFPX-UHFFFAOYSA-N 0.000 description 1
- HSUOFZJUZZRIOL-LBPRGKRZSA-N 2,6-dimethyl-n-[(1s)-1-phenylethyl]-5-propanoylpyridine-3-carboxamide Chemical compound N1=C(C)C(C(=O)CC)=CC(C(=O)N[C@@H](C)C=2C=CC=CC=2)=C1C HSUOFZJUZZRIOL-LBPRGKRZSA-N 0.000 description 1
- BDQWWOHKFDSADC-UHFFFAOYSA-N 2-(2,4-dichloro-3-methylphenoxy)-n-phenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C)OC1=CC=C(Cl)C(C)=C1Cl BDQWWOHKFDSADC-UHFFFAOYSA-N 0.000 description 1
- IUQJDHJVPLLKFL-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetate;dimethylazanium Chemical compound CNC.OC(=O)COC1=CC=C(Cl)C=C1Cl IUQJDHJVPLLKFL-UHFFFAOYSA-N 0.000 description 1
- MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 description 1
- YNTJKQDWYXUTLZ-UHFFFAOYSA-N 2-(3-chlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=CC(Cl)=C1 YNTJKQDWYXUTLZ-UHFFFAOYSA-N 0.000 description 1
- QXQHMMGSXSAAAY-UHFFFAOYSA-N 2-(4-chloro-2-fluoro-5-prop-2-ynoxyphenyl)-4,5,6,7-tetrahydroindazole Chemical compound FC1=CC(Cl)=C(OCC#C)C=C1N1N=C2CCCCC2=C1 QXQHMMGSXSAAAY-UHFFFAOYSA-N 0.000 description 1
- PKAUICCNAWQPAU-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)acetic acid;n-methylmethanamine Chemical compound CNC.CC1=CC(Cl)=CC=C1OCC(O)=O PKAUICCNAWQPAU-UHFFFAOYSA-N 0.000 description 1
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 description 1
- CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 description 1
- GOCUAJYOYBLQRH-UHFFFAOYSA-N 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl GOCUAJYOYBLQRH-UHFFFAOYSA-N 0.000 description 1
- YUVKUEAFAVKILW-UHFFFAOYSA-N 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 YUVKUEAFAVKILW-UHFFFAOYSA-N 0.000 description 1
- OWZPCEFYPSAJFR-UHFFFAOYSA-N 2-(butan-2-yl)-4,6-dinitrophenol Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O OWZPCEFYPSAJFR-UHFFFAOYSA-N 0.000 description 1
- ISERORSDFSDMDV-UHFFFAOYSA-N 2-(n-(2-chloroacetyl)-2,6-diethylanilino)acetic acid Chemical compound CCC1=CC=CC(CC)=C1N(CC(O)=O)C(=O)CCl ISERORSDFSDMDV-UHFFFAOYSA-N 0.000 description 1
- YRTAHOYMHHXQPH-UHFFFAOYSA-N 2-[(3-carboxy-3-sulfopropanoyl)-octadecylamino]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCCN(C(CC(O)=O)C(O)=O)C(=O)CC(C(O)=O)S(O)(=O)=O YRTAHOYMHHXQPH-UHFFFAOYSA-N 0.000 description 1
- YXBDMGSFNUJTBR-NFSGWXFISA-N 2-[(E)-N-[(E)-3-chloroprop-2-enoxy]-C-propylcarbonimidoyl]-5-(2-ethylsulfanylpropyl)-3-hydroxycyclohex-2-en-1-one Chemical compound Cl/C=C/CO\N=C(/CCC)C1=C(O)CC(CC(C)SCC)CC1=O YXBDMGSFNUJTBR-NFSGWXFISA-N 0.000 description 1
- KRQUFUKTQHISJB-YYADALCUSA-N 2-[(E)-N-[2-(4-chlorophenoxy)propoxy]-C-propylcarbonimidoyl]-3-hydroxy-5-(thian-3-yl)cyclohex-2-en-1-one Chemical compound CCC\C(=N/OCC(C)OC1=CC=C(Cl)C=C1)C1=C(O)CC(CC1=O)C1CCCSC1 KRQUFUKTQHISJB-YYADALCUSA-N 0.000 description 1
- IRJQWZWMQCVOLA-DNTJNYDQSA-N 2-[(e)-n-[(3,5-difluorophenyl)carbamoylamino]-c-methylcarbonimidoyl]pyridine-3-carboxylic acid Chemical compound N=1C=CC=C(C(O)=O)C=1C(/C)=N/NC(=O)NC1=CC(F)=CC(F)=C1 IRJQWZWMQCVOLA-DNTJNYDQSA-N 0.000 description 1
- KWVPFECTOKLOBL-KTKRTIGZSA-N 2-[(z)-octadec-9-enoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCO KWVPFECTOKLOBL-KTKRTIGZSA-N 0.000 description 1
- OVQJTYOXWVHPTA-UHFFFAOYSA-N 2-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-nitropyrazol-3-amine Chemical compound NC1=C([N+]([O-])=O)C=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl OVQJTYOXWVHPTA-UHFFFAOYSA-N 0.000 description 1
- GQQIAHNFBAFBCS-UHFFFAOYSA-N 2-[2-chloro-5-(1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)-4-fluorophenoxy]acetic acid Chemical compound C1=C(Cl)C(OCC(=O)O)=CC(N2C(C3=C(CCCC3)C2=O)=O)=C1F GQQIAHNFBAFBCS-UHFFFAOYSA-N 0.000 description 1
- OOLBCHYXZDXLDS-UHFFFAOYSA-N 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(Cl)C=C1Cl OOLBCHYXZDXLDS-UHFFFAOYSA-N 0.000 description 1
- CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 description 1
- ONNQFZOZHDEENE-UHFFFAOYSA-N 2-[5-(but-3-yn-2-yloxy)-4-chloro-2-fluorophenyl]-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione Chemical compound C1=C(Cl)C(OC(C)C#C)=CC(N2C(C3=C(CCCC3)C2=O)=O)=C1F ONNQFZOZHDEENE-UHFFFAOYSA-N 0.000 description 1
- IZYLQXRDYNBRIT-UHFFFAOYSA-N 2-[7-[2-chloro-4-(trifluoromethyl)phenoxy]naphthalen-2-yl]oxypropanoic acid Chemical compound C=1C2=CC(OC(C)C(O)=O)=CC=C2C=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl IZYLQXRDYNBRIT-UHFFFAOYSA-N 0.000 description 1
- IOYNQIMAUDJVEI-ZFNPBRLTSA-N 2-[N-[(E)-3-chloroprop-2-enoxy]-C-ethylcarbonimidoyl]-3-hydroxy-5-(oxan-4-yl)cyclohex-2-en-1-one Chemical compound C1C(=O)C(C(=NOC\C=C\Cl)CC)=C(O)CC1C1CCOCC1 IOYNQIMAUDJVEI-ZFNPBRLTSA-N 0.000 description 1
- CAPZMPOPNQPBFS-UHFFFAOYSA-N 2-[[1-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl]-2-methoxyethylidene]amino]oxyacetic acid Chemical compound C1=C([N+]([O-])=O)C(C(=NOCC(O)=O)COC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 CAPZMPOPNQPBFS-UHFFFAOYSA-N 0.000 description 1
- WUZNHSBFPPFULJ-UHFFFAOYSA-N 2-[[4-chloro-6-(cyclopropylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropanenitrile Chemical compound N#CC(C)(C)NC1=NC(Cl)=NC(NC2CC2)=N1 WUZNHSBFPPFULJ-UHFFFAOYSA-N 0.000 description 1
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 description 1
- ZMWGIGHRZQTQRE-UHFFFAOYSA-N 2-butoxyethyl 2-(2,4-dichlorophenoxy)acetate Chemical group CCCCOCCOC(=O)COC1=CC=C(Cl)C=C1Cl ZMWGIGHRZQTQRE-UHFFFAOYSA-N 0.000 description 1
- WKGKFWXGAHXMCE-UHFFFAOYSA-N 2-butoxyethyl 2-(4-chloro-2-methylphenoxy)acetate Chemical group CCCCOCCOC(=O)COC1=CC=C(Cl)C=C1C WKGKFWXGAHXMCE-UHFFFAOYSA-N 0.000 description 1
- ZGGSVBWJVIXBHV-UHFFFAOYSA-N 2-chloro-1-(4-nitrophenoxy)-4-(trifluoromethyl)benzene Chemical compound C1=CC([N+](=O)[O-])=CC=C1OC1=CC=C(C(F)(F)F)C=C1Cl ZGGSVBWJVIXBHV-UHFFFAOYSA-N 0.000 description 1
- QCTALYCTVMUWPT-UHFFFAOYSA-N 2-chloro-3-(4-chlorophenyl)propanoic acid Chemical compound OC(=O)C(Cl)CC1=CC=C(Cl)C=C1 QCTALYCTVMUWPT-UHFFFAOYSA-N 0.000 description 1
- QEGVVEOAVNHRAA-UHFFFAOYSA-N 2-chloro-6-(4,6-dimethoxypyrimidin-2-yl)sulfanylbenzoic acid Chemical compound COC1=CC(OC)=NC(SC=2C(=C(Cl)C=CC=2)C(O)=O)=N1 QEGVVEOAVNHRAA-UHFFFAOYSA-N 0.000 description 1
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 description 1
- KZNDFYDURHAESM-UHFFFAOYSA-N 2-chloro-n-(2-ethyl-6-methylphenyl)-n-(propan-2-yloxymethyl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(COC(C)C)C(=O)CCl KZNDFYDURHAESM-UHFFFAOYSA-N 0.000 description 1
- IRCMYGHHKLLGHV-UHFFFAOYSA-N 2-ethoxy-3,3-dimethyl-2,3-dihydro-1-benzofuran-5-yl methanesulfonate Chemical compound C1=C(OS(C)(=O)=O)C=C2C(C)(C)C(OCC)OC2=C1 IRCMYGHHKLLGHV-UHFFFAOYSA-N 0.000 description 1
- MIJLZGZLQLAQCM-UHFFFAOYSA-N 2-ethoxyethyl 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate Chemical group C1=CC(OC(C)C(=O)OCCOCC)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl MIJLZGZLQLAQCM-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- QZSFJRIWRPJUOH-UHFFFAOYSA-N 2-ethylhexyl 2-(2,4-dichlorophenoxy)acetate Chemical group CCCCC(CC)COC(=O)COC1=CC=C(Cl)C=C1Cl QZSFJRIWRPJUOH-UHFFFAOYSA-N 0.000 description 1
- IDGRPSMONFWWEK-UHFFFAOYSA-N 2-ethylhexyl 2-(4-chloro-2-methylphenoxy)acetate Chemical group CCCCC(CC)COC(=O)COC1=CC=C(Cl)C=C1C IDGRPSMONFWWEK-UHFFFAOYSA-N 0.000 description 1
- LLWADFLAOKUBDR-UHFFFAOYSA-N 2-methyl-4-chlorophenoxybutyric acid Chemical compound CC1=CC(Cl)=CC=C1OCCCC(O)=O LLWADFLAOKUBDR-UHFFFAOYSA-N 0.000 description 1
- ABOOPXYCKNFDNJ-UHFFFAOYSA-N 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 ABOOPXYCKNFDNJ-UHFFFAOYSA-N 0.000 description 1
- JDRFUUBRGGDEIZ-UHFFFAOYSA-N 3,6-dichloro-2-methoxybenzoate;dimethylazanium Chemical compound CNC.COC1=C(Cl)C=CC(Cl)=C1C(O)=O JDRFUUBRGGDEIZ-UHFFFAOYSA-N 0.000 description 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 1
- AMVYOVYGIJXTQB-UHFFFAOYSA-N 3-[4-(4-methoxyphenoxy)phenyl]-1,1-dimethylurea Chemical compound C1=CC(OC)=CC=C1OC1=CC=C(NC(=O)N(C)C)C=C1 AMVYOVYGIJXTQB-UHFFFAOYSA-N 0.000 description 1
- WYJOEQHHWHAJRB-UHFFFAOYSA-N 3-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenoxy]oxolane Chemical compound C1=C(OC2COCC2)C([N+](=O)[O-])=CC=C1OC1=CC=C(C(F)(F)F)C=C1Cl WYJOEQHHWHAJRB-UHFFFAOYSA-N 0.000 description 1
- DXBQEHHOGRVYFF-UHFFFAOYSA-N 3-pyridin-4-ylpentane-2,4-dione Chemical group CC(=O)C(C(C)=O)C1=CC=NC=C1 DXBQEHHOGRVYFF-UHFFFAOYSA-N 0.000 description 1
- NEFZKJCNHBXWLP-UHFFFAOYSA-N 4,5-dimethoxy-2-phenylpyridazin-3-one Chemical compound O=C1C(OC)=C(OC)C=NN1C1=CC=CC=C1 NEFZKJCNHBXWLP-UHFFFAOYSA-N 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- ADZSGNDOZREKJK-UHFFFAOYSA-N 4-amino-6-tert-butyl-3-ethylsulfanyl-1,2,4-triazin-5-one Chemical compound CCSC1=NN=C(C(C)(C)C)C(=O)N1N ADZSGNDOZREKJK-UHFFFAOYSA-N 0.000 description 1
- MBFHUWCOCCICOK-UHFFFAOYSA-N 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(I)C=2)C(O)=O)=N1 MBFHUWCOCCICOK-UHFFFAOYSA-N 0.000 description 1
- NYRMIJKDBAQCHC-UHFFFAOYSA-N 5-(methylamino)-2-phenyl-4-[3-(trifluoromethyl)phenyl]furan-3(2H)-one Chemical compound O1C(NC)=C(C=2C=C(C=CC=2)C(F)(F)F)C(=O)C1C1=CC=CC=C1 NYRMIJKDBAQCHC-UHFFFAOYSA-N 0.000 description 1
- QQOGZMUZAZWLJH-UHFFFAOYSA-N 5-[2-chloro-6-fluoro-4-(trifluoromethyl)phenoxy]-n-ethylsulfonyl-2-nitrobenzamide Chemical compound C1=C([N+]([O-])=O)C(C(=O)NS(=O)(=O)CC)=CC(OC=2C(=CC(=CC=2F)C(F)(F)F)Cl)=C1 QQOGZMUZAZWLJH-UHFFFAOYSA-N 0.000 description 1
- CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 description 1
- KPKRDNDXPAJNQS-UHFFFAOYSA-N 5-fluoro-2-phenyl-3,1-benzoxazin-4-one Chemical compound O1C(=O)C=2C(F)=CC=CC=2N=C1C1=CC=CC=C1 KPKRDNDXPAJNQS-UHFFFAOYSA-N 0.000 description 1
- PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 description 1
- YIRZOVGSKSAOEK-UHFFFAOYSA-N 5-phenoxy-1-[3-(trifluoromethyl)phenyl]tetrazole Chemical compound FC(F)(F)C1=CC=CC(N2C(=NN=N2)OC=2C=CC=CC=2)=C1 YIRZOVGSKSAOEK-UHFFFAOYSA-N 0.000 description 1
- HZKBYBNLTLVSPX-UHFFFAOYSA-N 6-[(6,6-dimethyl-5,7-dihydropyrrolo[2,1-c][1,2,4]thiadiazol-3-ylidene)amino]-7-fluoro-4-prop-2-ynyl-1,4-benzoxazin-3-one Chemical compound C#CCN1C(=O)COC(C=C2F)=C1C=C2N=C1SN=C2CC(C)(C)CN21 HZKBYBNLTLVSPX-UHFFFAOYSA-N 0.000 description 1
- ZUSHSDOEVHPTCU-UHFFFAOYSA-N 6-chloro-3-phenyl-1h-pyridazin-4-one Chemical compound N1C(Cl)=CC(=O)C(C=2C=CC=CC=2)=N1 ZUSHSDOEVHPTCU-UHFFFAOYSA-N 0.000 description 1
- OOHIAOSLOGDBCE-UHFFFAOYSA-N 6-chloro-4-n-cyclopropyl-2-n-propan-2-yl-1,3,5-triazine-2,4-diamine Chemical compound CC(C)NC1=NC(Cl)=NC(NC2CC2)=N1 OOHIAOSLOGDBCE-UHFFFAOYSA-N 0.000 description 1
- IFUWJMZLOGBPRG-UHFFFAOYSA-N 6-chloro-n-(3-chloroprop-2-enyl)-5-methyl-n-phenylpyridazin-3-amine Chemical compound N1=C(Cl)C(C)=CC(N(CC=CCl)C=2C=CC=CC=2)=N1 IFUWJMZLOGBPRG-UHFFFAOYSA-N 0.000 description 1
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 1
- 239000002890 Aclonifen Substances 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 description 1
- 239000003666 Amidosulfuron Substances 0.000 description 1
- CTTHWASMBLQOFR-UHFFFAOYSA-N Amidosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)N(C)S(C)(=O)=O)=N1 CTTHWASMBLQOFR-UHFFFAOYSA-N 0.000 description 1
- 239000005468 Aminopyralid Substances 0.000 description 1
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- NXQDBZGWYSEGFL-UHFFFAOYSA-N Anilofos Chemical compound COP(=S)(OC)SCC(=O)N(C(C)C)C1=CC=C(Cl)C=C1 NXQDBZGWYSEGFL-UHFFFAOYSA-N 0.000 description 1
- 235000003911 Arachis Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 239000005469 Azimsulfuron Substances 0.000 description 1
- AFIIBUOYKYSPKB-UHFFFAOYSA-N Aziprotryne Chemical compound CSC1=NC(NC(C)C)=NC(N=[N+]=[N-])=N1 AFIIBUOYKYSPKB-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000005470 Beflubutamid Substances 0.000 description 1
- 239000005471 Benfluralin Substances 0.000 description 1
- QGQSRQPXXMTJCM-UHFFFAOYSA-N Benfuresate Chemical compound CCS(=O)(=O)OC1=CC=C2OCC(C)(C)C2=C1 QGQSRQPXXMTJCM-UHFFFAOYSA-N 0.000 description 1
- 239000005472 Bensulfuron methyl Substances 0.000 description 1
- RRNIZKPFKNDSRS-UHFFFAOYSA-N Bensulide Chemical compound CC(C)OP(=S)(OC(C)C)SCCNS(=O)(=O)C1=CC=CC=C1 RRNIZKPFKNDSRS-UHFFFAOYSA-N 0.000 description 1
- 239000005476 Bentazone Substances 0.000 description 1
- JDWQITFHZOBBFE-UHFFFAOYSA-N Benzofenap Chemical compound C=1C=C(Cl)C(C)=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OCC(=O)C1=CC=C(C)C=C1 JDWQITFHZOBBFE-UHFFFAOYSA-N 0.000 description 1
- DTCJYIIKPVRVDD-UHFFFAOYSA-N Benzthiazuron Chemical compound C1=CC=C2SC(NC(=O)NC)=NC2=C1 DTCJYIIKPVRVDD-UHFFFAOYSA-N 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 239000005484 Bifenox Substances 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- XTFNPKDYCLFGPV-OMCISZLKSA-N Bromofenoxim Chemical compound C1=C(Br)C(O)=C(Br)C=C1\C=N\OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O XTFNPKDYCLFGPV-OMCISZLKSA-N 0.000 description 1
- OEYOMNZEMCPTKN-UHFFFAOYSA-N Butamifos Chemical compound CCC(C)NP(=S)(OCC)OC1=CC(C)=CC=C1[N+]([O-])=O OEYOMNZEMCPTKN-UHFFFAOYSA-N 0.000 description 1
- SWMGXKSQWDSBKV-UHFFFAOYSA-N Buthidazole Chemical compound O=C1N(C)CC(O)N1C1=NN=C(C(C)(C)C)S1 SWMGXKSQWDSBKV-UHFFFAOYSA-N 0.000 description 1
- SPNQRCTZKIBOAX-UHFFFAOYSA-N Butralin Chemical compound CCC(C)NC1=C([N+]([O-])=O)C=C(C(C)(C)C)C=C1[N+]([O-])=O SPNQRCTZKIBOAX-UHFFFAOYSA-N 0.000 description 1
- BMTAFVWTTFSTOG-UHFFFAOYSA-N Butylate Chemical compound CCSC(=O)N(CC(C)C)CC(C)C BMTAFVWTTFSTOG-UHFFFAOYSA-N 0.000 description 1
- 239000005490 Carbetamide Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DXXVCXKMSWHGTF-UHFFFAOYSA-N Chlomethoxyfen Chemical compound C1=C([N+]([O-])=O)C(OC)=CC(OC=2C(=CC(Cl)=CC=2)Cl)=C1 DXXVCXKMSWHGTF-UHFFFAOYSA-N 0.000 description 1
- HSSBORCLYSCBJR-UHFFFAOYSA-N Chloramben Chemical compound NC1=CC(Cl)=CC(C(O)=O)=C1Cl HSSBORCLYSCBJR-UHFFFAOYSA-N 0.000 description 1
- NLYNUTMZTCLNOO-UHFFFAOYSA-N Chlorbromuron Chemical class CON(C)C(=O)NC1=CC=C(Br)C(Cl)=C1 NLYNUTMZTCLNOO-UHFFFAOYSA-N 0.000 description 1
- ULBXWWGWDPVHAO-UHFFFAOYSA-N Chlorbufam Chemical class C#CC(C)OC(=O)NC1=CC=CC(Cl)=C1 ULBXWWGWDPVHAO-UHFFFAOYSA-N 0.000 description 1
- 239000005494 Chlorotoluron Chemical class 0.000 description 1
- 239000005647 Chlorpropham Chemical class 0.000 description 1
- WMLPCIHUFDKWJU-UHFFFAOYSA-N Cinosulfuron Chemical class COCCOC1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC)=NC(OC)=N1 WMLPCIHUFDKWJU-UHFFFAOYSA-N 0.000 description 1
- 239000005497 Clethodim Chemical class 0.000 description 1
- 239000005498 Clodinafop Chemical class 0.000 description 1
- 239000005500 Clopyralid Substances 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- VYNOULHXXDFBLU-UHFFFAOYSA-N Cumyluron Chemical compound C=1C=CC=CC=1C(C)(C)NC(=O)NCC1=CC=CC=C1Cl VYNOULHXXDFBLU-UHFFFAOYSA-N 0.000 description 1
- DFCAFRGABIXSDS-UHFFFAOYSA-N Cycloate Chemical compound CCSC(=O)N(CC)C1CCCCC1 DFCAFRGABIXSDS-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OFSLKOLYLQSJPB-UHFFFAOYSA-N Cyclosulfamuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)NC=2C(=CC=CC=2)C(=O)C2CC2)=N1 OFSLKOLYLQSJPB-UHFFFAOYSA-N 0.000 description 1
- 239000005501 Cycloxydim Chemical class 0.000 description 1
- DQZCVNGCTZLGAQ-UHFFFAOYSA-N Cycluron Chemical class CN(C)C(=O)NC1CCCCCCC1 DQZCVNGCTZLGAQ-UHFFFAOYSA-N 0.000 description 1
- FMGYKKMPNATWHP-UHFFFAOYSA-N Cyperquat Chemical compound C1=C[N+](C)=CC=C1C1=CC=CC=C1 FMGYKKMPNATWHP-UHFFFAOYSA-N 0.000 description 1
- NPOJQCVWMSKXDN-UHFFFAOYSA-N Dacthal Chemical class COC(=O)C1=C(Cl)C(Cl)=C(C(=O)OC)C(Cl)=C1Cl NPOJQCVWMSKXDN-UHFFFAOYSA-N 0.000 description 1
- NNYRZQHKCHEXSD-UHFFFAOYSA-N Daimuron Chemical compound C1=CC(C)=CC=C1NC(=O)NC(C)(C)C1=CC=CC=C1 NNYRZQHKCHEXSD-UHFFFAOYSA-N 0.000 description 1
- NDUPDOJHUQKPAG-UHFFFAOYSA-N Dalapon Chemical compound CC(Cl)(Cl)C(O)=O NDUPDOJHUQKPAG-UHFFFAOYSA-N 0.000 description 1
- 239000005503 Desmedipham Substances 0.000 description 1
- HCRWJJJUKUVORR-UHFFFAOYSA-N Desmetryn Chemical compound CNC1=NC(NC(C)C)=NC(SC)=N1 HCRWJJJUKUVORR-UHFFFAOYSA-N 0.000 description 1
- SPANOECCGNXGNR-UITAMQMPSA-N Diallat Chemical compound CC(C)N(C(C)C)C(=O)SC\C(Cl)=C\Cl SPANOECCGNXGNR-UITAMQMPSA-N 0.000 description 1
- 239000005505 Dichlorprop-P Substances 0.000 description 1
- 239000005506 Diclofop Substances 0.000 description 1
- LBGPXIPGGRQBJW-UHFFFAOYSA-N Difenzoquat Chemical compound C[N+]=1N(C)C(C=2C=CC=CC=2)=CC=1C1=CC=CC=C1 LBGPXIPGGRQBJW-UHFFFAOYSA-N 0.000 description 1
- 239000005507 Diflufenican Substances 0.000 description 1
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
- DHWRNDJOGMTCPB-UHFFFAOYSA-N Dimefuron Chemical compound ClC1=CC(NC(=O)N(C)C)=CC=C1N1C(=O)OC(C(C)(C)C)=N1 DHWRNDJOGMTCPB-UHFFFAOYSA-N 0.000 description 1
- 239000005508 Dimethachlor Substances 0.000 description 1
- IKYICRRUVNIHPP-UHFFFAOYSA-N Dimethametryn Chemical compound CCNC1=NC(NC(C)C(C)C)=NC(SC)=N1 IKYICRRUVNIHPP-UHFFFAOYSA-N 0.000 description 1
- 239000005509 Dimethenamid-P Substances 0.000 description 1
- PHVNLLCAQHGNKU-UHFFFAOYSA-N Dimethipin Chemical compound CC1=C(C)S(=O)(=O)CCS1(=O)=O PHVNLLCAQHGNKU-UHFFFAOYSA-N 0.000 description 1
- OFDYMSKSGFSLLM-UHFFFAOYSA-N Dinitramine Chemical compound CCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C(N)=C1[N+]([O-])=O OFDYMSKSGFSLLM-UHFFFAOYSA-N 0.000 description 1
- IIPZYDQGBIWLBU-UHFFFAOYSA-N Dinoterb Chemical compound CC(C)(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O IIPZYDQGBIWLBU-UHFFFAOYSA-N 0.000 description 1
- QAHFOPIILNICLA-UHFFFAOYSA-N Diphenamid Chemical compound C=1C=CC=CC=1C(C(=O)N(C)C)C1=CC=CC=C1 QAHFOPIILNICLA-UHFFFAOYSA-N 0.000 description 1
- NPWMZOGDXOFZIN-UHFFFAOYSA-N Dipropetryn Chemical compound CCSC1=NC(NC(C)C)=NC(NC(C)C)=N1 NPWMZOGDXOFZIN-UHFFFAOYSA-N 0.000 description 1
- 239000005630 Diquat Substances 0.000 description 1
- YUBJPYNSGLJZPQ-UHFFFAOYSA-N Dithiopyr Chemical compound CSC(=O)C1=C(C(F)F)N=C(C(F)(F)F)C(C(=O)SC)=C1CC(C)C YUBJPYNSGLJZPQ-UHFFFAOYSA-N 0.000 description 1
- 239000005510 Diuron Substances 0.000 description 1
- GUVLYNGULCJVDO-UHFFFAOYSA-N EPTC Chemical compound CCCN(CCC)C(=O)SCC GUVLYNGULCJVDO-UHFFFAOYSA-N 0.000 description 1
- 241000402754 Erythranthe moschata Species 0.000 description 1
- BXEHUCNTIZGSOJ-UHFFFAOYSA-N Esprocarb Chemical compound CC(C)C(C)N(CC)C(=O)SCC1=CC=CC=C1 BXEHUCNTIZGSOJ-UHFFFAOYSA-N 0.000 description 1
- PTFJIKYUEPWBMS-UHFFFAOYSA-N Ethalfluralin Chemical compound CC(=C)CN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O PTFJIKYUEPWBMS-UHFFFAOYSA-N 0.000 description 1
- KCOCSOWTADCKOL-UHFFFAOYSA-N Ethidimuron Chemical compound CCS(=O)(=O)C1=NN=C(N(C)C(=O)NC)S1 KCOCSOWTADCKOL-UHFFFAOYSA-N 0.000 description 1
- 239000005512 Ethofumesate Substances 0.000 description 1
- UWVKRNOCDUPIDM-UHFFFAOYSA-N Ethoxysulfuron Chemical compound CCOC1=CC=CC=C1OS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 UWVKRNOCDUPIDM-UHFFFAOYSA-N 0.000 description 1
- ICWUMLXQKFTJMH-UHFFFAOYSA-N Etobenzanid Chemical compound C1=CC(OCOCC)=CC=C1C(=O)NC1=CC=CC(Cl)=C1Cl ICWUMLXQKFTJMH-UHFFFAOYSA-N 0.000 description 1
- ZLSWBLPERHFHIS-UHFFFAOYSA-N Fenoprop Chemical compound OC(=O)C(C)OC1=CC(Cl)=C(Cl)C=C1Cl ZLSWBLPERHFHIS-UHFFFAOYSA-N 0.000 description 1
- 239000005513 Fenoxaprop-P Substances 0.000 description 1
- LLQPHQFNMLZJMP-UHFFFAOYSA-N Fentrazamide Chemical compound N1=NN(C=2C(=CC=CC=2)Cl)C(=O)N1C(=O)N(CC)C1CCCCC1 LLQPHQFNMLZJMP-UHFFFAOYSA-N 0.000 description 1
- YQVMVCCFZCMYQB-SNVBAGLBSA-N Flamprop-M Chemical compound C=1C=C(F)C(Cl)=CC=1N([C@H](C)C(O)=O)C(=O)C1=CC=CC=C1 YQVMVCCFZCMYQB-SNVBAGLBSA-N 0.000 description 1
- 239000005514 Flazasulfuron Substances 0.000 description 1
- HWATZEJQIXKWQS-UHFFFAOYSA-N Flazasulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(F)(F)F)=N1 HWATZEJQIXKWQS-UHFFFAOYSA-N 0.000 description 1
- 239000005529 Florasulam Substances 0.000 description 1
- 239000005530 Fluazifop-P Substances 0.000 description 1
- FICWGWVVIRLNRB-UHFFFAOYSA-N Flucetosulfuron Chemical compound COCC(=O)OC(C(C)F)C1=NC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 FICWGWVVIRLNRB-UHFFFAOYSA-N 0.000 description 1
- MNFMIVVPXOGUMX-UHFFFAOYSA-N Fluchloralin Chemical compound CCCN(CCCl)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O MNFMIVVPXOGUMX-UHFFFAOYSA-N 0.000 description 1
- 239000005531 Flufenacet Substances 0.000 description 1
- RXCPQSJAVKGONC-UHFFFAOYSA-N Flumetsulam Chemical compound N1=C2N=C(C)C=CN2N=C1S(=O)(=O)NC1=C(F)C=CC=C1F RXCPQSJAVKGONC-UHFFFAOYSA-N 0.000 description 1
- HHMCAJWVGYGUEF-UHFFFAOYSA-N Fluorodifen Chemical compound C1=CC([N+](=O)[O-])=CC=C1OC1=CC=C(C(F)(F)F)C=C1[N+]([O-])=O HHMCAJWVGYGUEF-UHFFFAOYSA-N 0.000 description 1
- 239000005534 Flupyrsulfuron-methyl Substances 0.000 description 1
- YWBVHLJPRPCRSD-UHFFFAOYSA-N Fluridone Chemical compound O=C1C(C=2C=C(C=CC=2)C(F)(F)F)=CN(C)C=C1C1=CC=CC=C1 YWBVHLJPRPCRSD-UHFFFAOYSA-N 0.000 description 1
- 239000005559 Flurtamone Substances 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005561 Glufosinate Substances 0.000 description 1
- LXKOADMMGWXPJQ-UHFFFAOYSA-N Halosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=C(Cl)C=2C(O)=O)C)=N1 LXKOADMMGWXPJQ-UHFFFAOYSA-N 0.000 description 1
- 239000005565 Haloxyfop-P Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- 239000005566 Imazamox Substances 0.000 description 1
- 239000005981 Imazaquin Substances 0.000 description 1
- XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 description 1
- 239000005567 Imazosulfuron Substances 0.000 description 1
- NAGRVUXEKKZNHT-UHFFFAOYSA-N Imazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N3C=CC=CC3=NC=2Cl)=N1 NAGRVUXEKKZNHT-UHFFFAOYSA-N 0.000 description 1
- 239000005568 Iodosulfuron Substances 0.000 description 1
- SBYAVOHNDJTVPA-UHFFFAOYSA-N Isocarbamid Chemical compound CC(C)CNC(=O)N1CCNC1=O SBYAVOHNDJTVPA-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- NEKOXWSIMFDGMA-UHFFFAOYSA-N Isopropalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(C)C)C=C1[N+]([O-])=O NEKOXWSIMFDGMA-UHFFFAOYSA-N 0.000 description 1
- JLLJHQLUZAKJFH-UHFFFAOYSA-N Isouron Chemical compound CN(C)C(=O)NC=1C=C(C(C)(C)C)ON=1 JLLJHQLUZAKJFH-UHFFFAOYSA-N 0.000 description 1
- 239000005570 Isoxaben Substances 0.000 description 1
- 239000005571 Isoxaflutole Substances 0.000 description 1
- ANFHKXSOSRDDRQ-UHFFFAOYSA-N Isoxapyrifop Chemical compound C1CCON1C(=O)C(C)OC(C=C1)=CC=C1OC1=NC=C(Cl)C=C1Cl ANFHKXSOSRDDRQ-UHFFFAOYSA-N 0.000 description 1
- UQVYUTAMNICZNI-UHFFFAOYSA-N Karbutilate Chemical compound CN(C)C(=O)NC1=CC=CC(NC(=O)OC(C)(C)C)=C1 UQVYUTAMNICZNI-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000005572 Lenacil Substances 0.000 description 1
- 239000005573 Linuron Substances 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- SUSRORUBZHMPCO-UHFFFAOYSA-N MC-4379 Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC)=CC(OC=2C(=CC(Cl)=CC=2)Cl)=C1 SUSRORUBZHMPCO-UHFFFAOYSA-N 0.000 description 1
- AZFKQCNGMSSWDS-UHFFFAOYSA-N MCPA-thioethyl Chemical group CCSC(=O)COC1=CC=C(Cl)C=C1C AZFKQCNGMSSWDS-UHFFFAOYSA-N 0.000 description 1
- 239000005575 MCPB Substances 0.000 description 1
- 101150039283 MCPB gene Proteins 0.000 description 1
- 239000005983 Maleic hydrazide Substances 0.000 description 1
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 description 1
- 239000005576 Mecoprop-P Substances 0.000 description 1
- 239000005578 Mesotrione Substances 0.000 description 1
- 239000005579 Metamitron Substances 0.000 description 1
- 239000005580 Metazachlor Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- RRVIAQKBTUQODI-UHFFFAOYSA-N Methabenzthiazuron Chemical compound C1=CC=C2SC(N(C)C(=O)NC)=NC2=C1 RRVIAQKBTUQODI-UHFFFAOYSA-N 0.000 description 1
- LRUUNMYPIBZBQH-UHFFFAOYSA-N Methazole Chemical compound O=C1N(C)C(=O)ON1C1=CC=C(Cl)C(Cl)=C1 LRUUNMYPIBZBQH-UHFFFAOYSA-N 0.000 description 1
- BWPYBAJTDILQPY-UHFFFAOYSA-N Methoxyphenone Chemical compound C1=C(C)C(OC)=CC=C1C(=O)C1=CC=CC(C)=C1 BWPYBAJTDILQPY-UHFFFAOYSA-N 0.000 description 1
- FMINYZXVCTYSNY-UHFFFAOYSA-N Methyldymron Chemical compound C=1C=CC=CC=1N(C)C(=O)NC(C)(C)C1=CC=CC=C1 FMINYZXVCTYSNY-UHFFFAOYSA-N 0.000 description 1
- 239000005581 Metobromuron Substances 0.000 description 1
- WLFDQEVORAMCIM-UHFFFAOYSA-N Metobromuron Chemical compound CON(C)C(=O)NC1=CC=C(Br)C=C1 WLFDQEVORAMCIM-UHFFFAOYSA-N 0.000 description 1
- 239000005582 Metosulam Substances 0.000 description 1
- 239000005583 Metribuzin Substances 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- KXGYBSNVFXBPNO-UHFFFAOYSA-N Monalide Chemical compound CCCC(C)(C)C(=O)NC1=CC=C(Cl)C=C1 KXGYBSNVFXBPNO-UHFFFAOYSA-N 0.000 description 1
- LKJPSUCKSLORMF-UHFFFAOYSA-N Monolinuron Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C=C1 LKJPSUCKSLORMF-UHFFFAOYSA-N 0.000 description 1
- WXZVAROIGSFCFJ-UHFFFAOYSA-N N,N-diethyl-2-(naphthalen-1-yloxy)propanamide Chemical compound C1=CC=C2C(OC(C)C(=O)N(CC)CC)=CC=CC2=C1 WXZVAROIGSFCFJ-UHFFFAOYSA-N 0.000 description 1
- ZJMZZNVGNSWOOM-UHFFFAOYSA-N N-(butan-2-yl)-N'-ethyl-6-methoxy-1,3,5-triazine-2,4-diamine Chemical compound CCNC1=NC(NC(C)CC)=NC(OC)=N1 ZJMZZNVGNSWOOM-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- FFQPZWRNXKPNPX-UHFFFAOYSA-N N-benzyl-2-[4-fluoro-3-(trifluoromethyl)phenoxy]butanamide Chemical compound C=1C=CC=CC=1CNC(=O)C(CC)OC1=CC=C(F)C(C(F)(F)F)=C1 FFQPZWRNXKPNPX-UHFFFAOYSA-N 0.000 description 1
- NTBVTCXMRYKRTB-UHFFFAOYSA-N N-{2-[(4,6-dimethoxypyrimidin-2-yl)(hydroxy)methyl]-6-(methoxymethyl)phenyl}-1,1-difluoromethanesulfonamide Chemical compound COCC1=CC=CC(C(O)C=2N=C(OC)C=C(OC)N=2)=C1NS(=O)(=O)C(F)F NTBVTCXMRYKRTB-UHFFFAOYSA-N 0.000 description 1
- LVKTWOXHRYGDMM-UHFFFAOYSA-N Naproanilide Chemical compound C=1C=C2C=CC=CC2=CC=1OC(C)C(=O)NC1=CC=CC=C1 LVKTWOXHRYGDMM-UHFFFAOYSA-N 0.000 description 1
- 239000005585 Napropamide Substances 0.000 description 1
- CCGPUGMWYLICGL-UHFFFAOYSA-N Neburon Chemical compound CCCCN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 CCGPUGMWYLICGL-UHFFFAOYSA-N 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000005586 Nicosulfuron Substances 0.000 description 1
- UMKANAFDOQQUKE-UHFFFAOYSA-N Nitralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(C)(=O)=O)C=C1[N+]([O-])=O UMKANAFDOQQUKE-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005587 Oryzalin Substances 0.000 description 1
- 239000005588 Oxadiazon Substances 0.000 description 1
- CHNUNORXWHYHNE-UHFFFAOYSA-N Oxadiazon Chemical compound C1=C(Cl)C(OC(C)C)=CC(N2C(OC(=N2)C(C)(C)C)=O)=C1Cl CHNUNORXWHYHNE-UHFFFAOYSA-N 0.000 description 1
- 239000005589 Oxasulfuron Substances 0.000 description 1
- FCOHEOSCARXMMS-UHFFFAOYSA-N Oxaziclomefone Chemical compound C1OC(C)=C(C=2C=CC=CC=2)C(=O)N1C(C)(C)C1=CC(Cl)=CC(Cl)=C1 FCOHEOSCARXMMS-UHFFFAOYSA-N 0.000 description 1
- 239000005590 Oxyfluorfen Substances 0.000 description 1
- OQMBBFQZGJFLBU-UHFFFAOYSA-N Oxyfluorfen Chemical compound C1=C([N+]([O-])=O)C(OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 OQMBBFQZGJFLBU-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- SGEJQUSYQTVSIU-UHFFFAOYSA-N Pebulate Chemical compound CCCCN(CC)C(=O)SCCC SGEJQUSYQTVSIU-UHFFFAOYSA-N 0.000 description 1
- 239000005591 Pendimethalin Substances 0.000 description 1
- 239000005592 Penoxsulam Substances 0.000 description 1
- SYJGKVOENHZYMQ-UHFFFAOYSA-N Penoxsulam Chemical compound N1=C2C(OC)=CN=C(OC)N2N=C1NS(=O)(=O)C1=C(OCC(F)F)C=CC=C1C(F)(F)F SYJGKVOENHZYMQ-UHFFFAOYSA-N 0.000 description 1
- WHTBVLXUSXVMEV-UHFFFAOYSA-N Perfluidone Chemical compound C1=C(NS(=O)(=O)C(F)(F)F)C(C)=CC(S(=O)(=O)C=2C=CC=CC=2)=C1 WHTBVLXUSXVMEV-UHFFFAOYSA-N 0.000 description 1
- 239000005593 Pethoxamid Substances 0.000 description 1
- PWEOEHNGYFXZLI-UHFFFAOYSA-N Phenisopham Chemical compound C=1C=CC=CC=1N(CC)C(=O)OC1=CC=CC(NC(=O)OC(C)C)=C1 PWEOEHNGYFXZLI-UHFFFAOYSA-N 0.000 description 1
- 239000005594 Phenmedipham Substances 0.000 description 1
- 239000005595 Picloram Substances 0.000 description 1
- 239000005596 Picolinafen Substances 0.000 description 1
- 239000005597 Pinoxaden Substances 0.000 description 1
- UNLYSVIDNRIVFJ-UHFFFAOYSA-N Piperophos Chemical compound CCCOP(=S)(OCCC)SCC(=O)N1CCCCC1C UNLYSVIDNRIVFJ-UHFFFAOYSA-N 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- YLPGTOIOYRQOHV-UHFFFAOYSA-N Pretilachlor Chemical compound CCCOCCN(C(=O)CCl)C1=C(CC)C=CC=C1CC YLPGTOIOYRQOHV-UHFFFAOYSA-N 0.000 description 1
- RSVPPPHXAASNOL-UHFFFAOYSA-N Prodiamine Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C(N)=C1[N+]([O-])=O RSVPPPHXAASNOL-UHFFFAOYSA-N 0.000 description 1
- ITVQAKZNYJEWKS-UHFFFAOYSA-N Profluralin Chemical compound [O-][N+](=O)C=1C=C(C(F)(F)F)C=C([N+]([O-])=O)C=1N(CCC)CC1CC1 ITVQAKZNYJEWKS-UHFFFAOYSA-N 0.000 description 1
- 239000005599 Profoxydim Substances 0.000 description 1
- 239000005600 Propaquizafop Substances 0.000 description 1
- 239000005602 Propyzamide Substances 0.000 description 1
- 239000005603 Prosulfocarb Substances 0.000 description 1
- 239000005604 Prosulfuron Substances 0.000 description 1
- IHHMUBRVTJMLQO-UHFFFAOYSA-N Pyraclonil Chemical compound C#CCN(C)C1=C(C#N)C=NN1C1=NN(CCCC2)C2=C1Cl IHHMUBRVTJMLQO-UHFFFAOYSA-N 0.000 description 1
- 239000005605 Pyraflufen-ethyl Substances 0.000 description 1
- BGNQYGRXEXDAIQ-UHFFFAOYSA-N Pyrazosulfuron-ethyl Chemical group C1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OCC BGNQYGRXEXDAIQ-UHFFFAOYSA-N 0.000 description 1
- 239000005606 Pyridate Substances 0.000 description 1
- JTZCTMAVMHRNTR-UHFFFAOYSA-N Pyridate Chemical compound CCCCCCCCSC(=O)OC1=CC(Cl)=NN=C1C1=CC=CC=C1 JTZCTMAVMHRNTR-UHFFFAOYSA-N 0.000 description 1
- RRKHIAYNPVQKEF-UHFFFAOYSA-N Pyriftalid Chemical compound COC1=CC(OC)=NC(SC=2C=3C(=O)OC(C)C=3C=CC=2)=N1 RRKHIAYNPVQKEF-UHFFFAOYSA-N 0.000 description 1
- CNILNQMBAHKMFS-UHFFFAOYSA-M Pyrithiobac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(SC=2C(=C(Cl)C=CC=2)C([O-])=O)=N1 CNILNQMBAHKMFS-UHFFFAOYSA-M 0.000 description 1
- 239000005608 Quinmerac Substances 0.000 description 1
- 239000005609 Quizalofop-P Substances 0.000 description 1
- 239000005614 Quizalofop-P-ethyl Substances 0.000 description 1
- 239000005615 Quizalofop-P-tefuryl Substances 0.000 description 1
- 239000005616 Rimsulfuron Substances 0.000 description 1
- 239000005617 S-Metolachlor Substances 0.000 description 1
- OKUGPJPKMAEJOE-UHFFFAOYSA-N S-propyl dipropylcarbamothioate Chemical compound CCCSC(=O)N(CCC)CCC OKUGPJPKMAEJOE-UHFFFAOYSA-N 0.000 description 1
- CSPPKDPQLUUTND-NBVRZTHBSA-N Sethoxydim Chemical compound CCO\N=C(/CCC)C1=C(O)CC(CC(C)SCC)CC1=O CSPPKDPQLUUTND-NBVRZTHBSA-N 0.000 description 1
- JXVIIQLNUPXOII-UHFFFAOYSA-N Siduron Chemical compound CC1CCCCC1NC(=O)NC1=CC=CC=C1 JXVIIQLNUPXOII-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- 239000005618 Sulcotrione Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005619 Sulfosulfuron Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HBPDKDSFLXWOAE-UHFFFAOYSA-N Tebuthiuron Chemical compound CNC(=O)N(C)C1=NN=C(C(C)(C)C)S1 HBPDKDSFLXWOAE-UHFFFAOYSA-N 0.000 description 1
- NBQCNZYJJMBDKY-UHFFFAOYSA-N Terbacil Chemical compound CC=1NC(=O)N(C(C)(C)C)C(=O)C=1Cl NBQCNZYJJMBDKY-UHFFFAOYSA-N 0.000 description 1
- 239000005621 Terbuthylazine Substances 0.000 description 1
- BBJPZPLAZVZTGR-UHFFFAOYSA-N Thiazafluron Chemical compound CNC(=O)N(C)C1=NN=C(C(F)(F)F)S1 BBJPZPLAZVZTGR-UHFFFAOYSA-N 0.000 description 1
- HFCYZXMHUIHAQI-UHFFFAOYSA-N Thidiazuron Chemical compound C=1C=CC=CC=1NC(=O)NC1=CN=NS1 HFCYZXMHUIHAQI-UHFFFAOYSA-N 0.000 description 1
- QHTQREMOGMZHJV-UHFFFAOYSA-N Thiobencarb Chemical compound CCN(CC)C(=O)SCC1=CC=C(Cl)C=C1 QHTQREMOGMZHJV-UHFFFAOYSA-N 0.000 description 1
- 239000005624 Tralkoxydim Substances 0.000 description 1
- 239000005625 Tri-allate Substances 0.000 description 1
- MWBPRDONLNQCFV-UHFFFAOYSA-N Tri-allate Chemical compound CC(C)N(C(C)C)C(=O)SCC(Cl)=C(Cl)Cl MWBPRDONLNQCFV-UHFFFAOYSA-N 0.000 description 1
- IBZHOAONZVJLOB-UHFFFAOYSA-N Tridiphane Chemical compound ClC1=CC(Cl)=CC(C2(CC(Cl)(Cl)Cl)OC2)=C1 IBZHOAONZVJLOB-UHFFFAOYSA-N 0.000 description 1
- 239000005628 Triflusulfuron Substances 0.000 description 1
- 241000013033 Triso Species 0.000 description 1
- 239000005629 Tritosulfuron Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 235000019498 Walnut oil Nutrition 0.000 description 1
- AMRQXHFXNZFDCH-SECBINFHSA-N [(2r)-1-(ethylamino)-1-oxopropan-2-yl] n-phenylcarbamate Chemical compound CCNC(=O)[C@@H](C)OC(=O)NC1=CC=CC=C1 AMRQXHFXNZFDCH-SECBINFHSA-N 0.000 description 1
- SSBRSHIQIANGKS-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;hydrogen sulfate Chemical compound NC(N)=O.OS(O)(=O)=O SSBRSHIQIANGKS-UHFFFAOYSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- NUFNQYOELLVIPL-UHFFFAOYSA-N acifluorfen Chemical compound C1=C([N+]([O-])=O)C(C(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 NUFNQYOELLVIPL-UHFFFAOYSA-N 0.000 description 1
- DDBMQDADIHOWIC-UHFFFAOYSA-N aclonifen Chemical compound C1=C([N+]([O-])=O)C(N)=C(Cl)C(OC=2C=CC=CC=2)=C1 DDBMQDADIHOWIC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000006177 alkyl benzyl group Chemical group 0.000 description 1
- ORFLOUYIJLPLPL-WOJGMQOQSA-N alloxydim Chemical compound CCC\C(=N/OCC=C)C1=C(O)CC(C)(C)C(C(=O)OC)C1=O ORFLOUYIJLPLPL-WOJGMQOQSA-N 0.000 description 1
- RQVYBGPQFYCBGX-UHFFFAOYSA-N ametryn Chemical compound CCNC1=NC(NC(C)C)=NC(SC)=N1 RQVYBGPQFYCBGX-UHFFFAOYSA-N 0.000 description 1
- ORFPWVRKFLOQHK-UHFFFAOYSA-N amicarbazone Chemical compound CC(C)C1=NN(C(=O)NC(C)(C)C)C(=O)N1N ORFPWVRKFLOQHK-UHFFFAOYSA-N 0.000 description 1
- NIXXQNOQHKNPEJ-UHFFFAOYSA-N aminopyralid Chemical compound NC1=CC(Cl)=NC(C(O)=O)=C1Cl NIXXQNOQHKNPEJ-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229940075522 antidotes Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- VGPYEHKOIGNJKV-UHFFFAOYSA-N asulam Chemical compound COC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 VGPYEHKOIGNJKV-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- OTSAMNSACVKIOJ-UHFFFAOYSA-N azane;carbamoyl(ethoxy)phosphinic acid Chemical compound [NH4+].CCOP([O-])(=O)C(N)=O OTSAMNSACVKIOJ-UHFFFAOYSA-N 0.000 description 1
- MCOQHIWZJUDQIC-UHFFFAOYSA-N barban Chemical compound ClCC#CCOC(=O)NC1=CC=CC(Cl)=C1 MCOQHIWZJUDQIC-UHFFFAOYSA-N 0.000 description 1
- SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical compound CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 1
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 1
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 description 1
- GINJFDRNADDBIN-FXQIFTODSA-N bilanafos Chemical compound OC(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O GINJFDRNADDBIN-FXQIFTODSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WZDDLAZXUYIVMU-UHFFFAOYSA-N bromobutide Chemical compound CC(C)(C)C(Br)C(=O)NC(C)(C)C1=CC=CC=C1 WZDDLAZXUYIVMU-UHFFFAOYSA-N 0.000 description 1
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 1
- JEDYYFXHPAIBGR-UHFFFAOYSA-N butafenacil Chemical compound O=C1N(C)C(C(F)(F)F)=CC(=O)N1C1=CC=C(Cl)C(C(=O)OC(C)(C)C(=O)OCC=C)=C1 JEDYYFXHPAIBGR-UHFFFAOYSA-N 0.000 description 1
- UQMRAFJOBWOFNS-UHFFFAOYSA-N butyl 2-(2,4-dichlorophenoxy)acetate Chemical group CCCCOC(=O)COC1=CC=C(Cl)C=C1Cl UQMRAFJOBWOFNS-UHFFFAOYSA-N 0.000 description 1
- VAIZTNZGPYBOGF-UHFFFAOYSA-N butyl 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate Chemical group C1=CC(OC(C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- GGWHBJGBERXSLL-NBVRZTHBSA-N chembl113137 Chemical class C1C(=O)C(C(=N/OCC)/CCC)=C(O)CC1C1CSCCC1 GGWHBJGBERXSLL-NBVRZTHBSA-N 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- QZXCCPZJCKEPSA-UHFFFAOYSA-N chlorfenac Chemical class OC(=O)CC1=C(Cl)C=CC(Cl)=C1Cl QZXCCPZJCKEPSA-UHFFFAOYSA-N 0.000 description 1
- NSWAMPCUPHPTTC-UHFFFAOYSA-N chlorimuron-ethyl Chemical class CCOC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(Cl)=CC(OC)=N1 NSWAMPCUPHPTTC-UHFFFAOYSA-N 0.000 description 1
- XQNAUQUKWRBODG-UHFFFAOYSA-N chlornitrofen Chemical class C1=CC([N+](=O)[O-])=CC=C1OC1=C(Cl)C=C(Cl)C=C1Cl XQNAUQUKWRBODG-UHFFFAOYSA-N 0.000 description 1
- JXCGFZXSOMJFOA-UHFFFAOYSA-N chlorotoluron Chemical class CN(C)C(=O)NC1=CC=C(C)C(Cl)=C1 JXCGFZXSOMJFOA-UHFFFAOYSA-N 0.000 description 1
- IVUXTESCPZUGJC-UHFFFAOYSA-N chloroxuron Chemical class C1=CC(NC(=O)N(C)C)=CC=C1OC1=CC=C(Cl)C=C1 IVUXTESCPZUGJC-UHFFFAOYSA-N 0.000 description 1
- CWJSHJJYOPWUGX-UHFFFAOYSA-N chlorpropham Chemical class CC(C)OC(=O)NC1=CC=CC(Cl)=C1 CWJSHJJYOPWUGX-UHFFFAOYSA-N 0.000 description 1
- NNKKTZOEKDFTBU-YBEGLDIGSA-N cinidon ethyl Chemical class C1=C(Cl)C(/C=C(\Cl)C(=O)OCC)=CC(N2C(C3=C(CCCC3)C2=O)=O)=C1 NNKKTZOEKDFTBU-YBEGLDIGSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- SILSDTWXNBZOGF-JWGBMQLESA-N clethodim Chemical class CCSC(C)CC1CC(O)=C(C(CC)=NOC\C=C\Cl)C(=O)C1 SILSDTWXNBZOGF-JWGBMQLESA-N 0.000 description 1
- YUIKUTLBPMDDNQ-MRVPVSSYSA-N clodinafop Chemical class C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=NC=C(Cl)C=C1F YUIKUTLBPMDDNQ-MRVPVSSYSA-N 0.000 description 1
- JBDHZKLJNAIJNC-LLVKDONJSA-N clodinafop-propargyl Chemical group C1=CC(O[C@H](C)C(=O)OCC#C)=CC=C1OC1=NC=C(Cl)C=C1F JBDHZKLJNAIJNC-LLVKDONJSA-N 0.000 description 1
- HUBANNPOLNYSAD-UHFFFAOYSA-N clopyralid Chemical compound OC(=O)C1=NC(Cl)=CC=C1Cl HUBANNPOLNYSAD-UHFFFAOYSA-N 0.000 description 1
- 239000007931 coated granule Substances 0.000 description 1
- 235000012716 cod liver oil Nutrition 0.000 description 1
- 239000003026 cod liver oil Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- WZJZMXBKUWKXTQ-UHFFFAOYSA-N desmedipham Chemical compound CCOC(=O)NC1=CC=CC(OC(=O)NC=2C=CC=CC=2)=C1 WZJZMXBKUWKXTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- RVJMEWSAFHIEJX-UHFFFAOYSA-M dicamba-potassium Chemical compound [K+].COC1=C(Cl)C=CC(Cl)=C1C([O-])=O RVJMEWSAFHIEJX-UHFFFAOYSA-M 0.000 description 1
- HLZCHRAMVPCKDU-UHFFFAOYSA-M dicamba-sodium Chemical compound [Na+].COC1=C(Cl)C=CC(Cl)=C1C([O-])=O HLZCHRAMVPCKDU-UHFFFAOYSA-M 0.000 description 1
- WYEHFWKAOXOVJD-UHFFFAOYSA-N diflufenican Chemical compound FC1=CC(F)=CC=C1NC(=O)C1=CC=CN=C1OC1=CC=CC(C(F)(F)F)=C1 WYEHFWKAOXOVJD-UHFFFAOYSA-N 0.000 description 1
- 229940031769 diisobutyl adipate Drugs 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- SCCDDNKJYDZXMM-UHFFFAOYSA-N dimethachlor Chemical compound COCCN(C(=O)CCl)C1=C(C)C=CC=C1C SCCDDNKJYDZXMM-UHFFFAOYSA-N 0.000 description 1
- JLYFCTQDENRSOL-VIFPVBQESA-N dimethenamid-P Chemical compound COC[C@H](C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-VIFPVBQESA-N 0.000 description 1
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 description 1
- 231100000676 disease causative agent Toxicity 0.000 description 1
- HWQXBVHZYDELQG-UHFFFAOYSA-L disodium 2,2-bis(6-methylheptyl)-3-sulfobutanedioate Chemical compound C(CCCCC(C)C)C(C(C(=O)[O-])S(=O)(=O)O)(C(=O)[O-])CCCCCC(C)C.[Na+].[Na+] HWQXBVHZYDELQG-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000459 effect on growth Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- ZINJLDJMHCUBIP-UHFFFAOYSA-N ethametsulfuron-methyl Chemical group CCOC1=NC(NC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC)=N1 ZINJLDJMHCUBIP-UHFFFAOYSA-N 0.000 description 1
- YESXTECNXIKUMM-UHFFFAOYSA-N ethyl 2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]acetate Chemical group CCNC1=NC(Cl)=NC(NCC(=O)OCC)=N1 YESXTECNXIKUMM-UHFFFAOYSA-N 0.000 description 1
- QQADVTSTCZBBOE-UHFFFAOYSA-N ethyl 2-[[4-chloro-6-(propan-2-ylamino)-1,3,5-triazin-2-yl]amino]acetate Chemical group CCOC(=O)CNC1=NC(Cl)=NC(NC(C)C)=N1 QQADVTSTCZBBOE-UHFFFAOYSA-N 0.000 description 1
- OSUHJPCHFDQAIT-UHFFFAOYSA-N ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate Chemical group C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 OSUHJPCHFDQAIT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- QMTNOLKHSWIQBE-FGTMMUONSA-N exo-(+)-cinmethylin Chemical class O([C@H]1[C@]2(C)CC[C@@](O2)(C1)C(C)C)CC1=CC=CC=C1C QMTNOLKHSWIQBE-FGTMMUONSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 1
- YUVKUEAFAVKILW-SECBINFHSA-N fluazifop-P Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 YUVKUEAFAVKILW-SECBINFHSA-N 0.000 description 1
- VAIZTNZGPYBOGF-CYBMUJFWSA-N fluazifop-P-butyl Chemical group C1=CC(O[C@H](C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-CYBMUJFWSA-N 0.000 description 1
- GINFBXXYGUODAT-UHFFFAOYSA-N flucarbazone Chemical compound O=C1N(C)C(OC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1OC(F)(F)F GINFBXXYGUODAT-UHFFFAOYSA-N 0.000 description 1
- IANUJLZYFUDJIH-UHFFFAOYSA-N flufenacet Chemical compound C=1C=C(F)C=CC=1N(C(C)C)C(=O)COC1=NN=C(C(F)(F)F)S1 IANUJLZYFUDJIH-UHFFFAOYSA-N 0.000 description 1
- OQZCSNDVOWYALR-UHFFFAOYSA-N flurochloridone Chemical compound FC(F)(F)C1=CC=CC(N2C(C(Cl)C(CCl)C2)=O)=C1 OQZCSNDVOWYALR-UHFFFAOYSA-N 0.000 description 1
- BGZZWXTVIYUUEY-UHFFFAOYSA-N fomesafen Chemical compound C1=C([N+]([O-])=O)C(C(=O)NS(=O)(=O)C)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 BGZZWXTVIYUUEY-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- GOCUAJYOYBLQRH-MRVPVSSYSA-N haloxyfop-P Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl GOCUAJYOYBLQRH-MRVPVSSYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- RUCAXVJJQQJZGU-UHFFFAOYSA-M hydron;2-(phosphonatomethylamino)acetate;trimethylsulfanium Chemical compound C[S+](C)C.OP(O)(=O)CNCC([O-])=O RUCAXVJJQQJZGU-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NRXQIUSYPAHGNM-UHFFFAOYSA-N ioxynil Chemical compound OC1=C(I)C=C(C#N)C=C1I NRXQIUSYPAHGNM-UHFFFAOYSA-N 0.000 description 1
- PUIYMUZLKQOUOZ-UHFFFAOYSA-N isoproturon Chemical compound CC(C)C1=CC=C(NC(=O)N(C)C)C=C1 PUIYMUZLKQOUOZ-UHFFFAOYSA-N 0.000 description 1
- PMHURSZHKKJGBM-UHFFFAOYSA-N isoxaben Chemical compound O1N=C(C(C)(CC)CC)C=C1NC(=O)C1=C(OC)C=CC=C1OC PMHURSZHKKJGBM-UHFFFAOYSA-N 0.000 description 1
- OYIKARCXOQLFHF-UHFFFAOYSA-N isoxaflutole Chemical compound CS(=O)(=O)C1=CC(C(F)(F)F)=CC=C1C(=O)C1=C(C2CC2)ON=C1 OYIKARCXOQLFHF-UHFFFAOYSA-N 0.000 description 1
- 229940088649 isoxaflutole Drugs 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- CONWAEURSVPLRM-UHFFFAOYSA-N lactofen Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC(C)C(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 CONWAEURSVPLRM-UHFFFAOYSA-N 0.000 description 1
- ZTMKADLOSYKWCA-UHFFFAOYSA-N lenacil Chemical compound O=C1NC=2CCCC=2C(=O)N1C1CCCCC1 ZTMKADLOSYKWCA-UHFFFAOYSA-N 0.000 description 1
- XIGAUIHYSDTJHW-UHFFFAOYSA-N mefenacet Chemical compound N=1C2=CC=CC=C2SC=1OCC(=O)N(C)C1=CC=CC=C1 XIGAUIHYSDTJHW-UHFFFAOYSA-N 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- AFCCDDWKHLHPDF-UHFFFAOYSA-M metam-sodium Chemical compound [Na+].CNC([S-])=S AFCCDDWKHLHPDF-UHFFFAOYSA-M 0.000 description 1
- VHCNQEUWZYOAEV-UHFFFAOYSA-N metamitron Chemical compound O=C1N(N)C(C)=NN=C1C1=CC=CC=C1 VHCNQEUWZYOAEV-UHFFFAOYSA-N 0.000 description 1
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- RBNIGDFIUWJJEV-UHFFFAOYSA-N methyl 2-(n-benzoyl-3-chloro-4-fluoroanilino)propanoate Chemical group C=1C=C(F)C(Cl)=CC=1N(C(C)C(=O)OC)C(=O)C1=CC=CC=C1 RBNIGDFIUWJJEV-UHFFFAOYSA-N 0.000 description 1
- GAIFAPDHLCPUMF-IWIPYMOSSA-N methyl 2-[(e)-[1-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl]-2-methoxyethylidene]amino]oxyacetate Chemical compound C1=C([N+]([O-])=O)C(C(=N\OCC(=O)OC)/COC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 GAIFAPDHLCPUMF-IWIPYMOSSA-N 0.000 description 1
- BACHBFVBHLGWSL-UHFFFAOYSA-N methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-UHFFFAOYSA-N 0.000 description 1
- LYPWWQLKWQNQKV-UHFFFAOYSA-N methyl 2-[5-ethyl-2-[[4-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenoxy]methyl]phenoxy]propanoate Chemical compound COC(=O)C(C)OC1=CC(CC)=CC=C1COC1=CC=C(N2C(N(C)C(=CC2=O)C(F)(F)F)=O)C=C1 LYPWWQLKWQNQKV-UHFFFAOYSA-N 0.000 description 1
- ZTYVMAQSHCZXLF-UHFFFAOYSA-N methyl 2-[[4,6-bis(difluoromethoxy)pyrimidin-2-yl]carbamoylsulfamoyl]benzoate Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC(F)F)=CC(OC(F)F)=N1 ZTYVMAQSHCZXLF-UHFFFAOYSA-N 0.000 description 1
- LINPVWIEWJTEEJ-UHFFFAOYSA-N methyl 2-chloro-9-hydroxyfluorene-9-carboxylate Chemical class C1=C(Cl)C=C2C(C(=O)OC)(O)C3=CC=CC=C3C2=C1 LINPVWIEWJTEEJ-UHFFFAOYSA-N 0.000 description 1
- MYURAHUSYDVWQA-UHFFFAOYSA-N methyl n'-(4-chlorophenyl)-n,n-dimethylcarbamimidate Chemical compound COC(N(C)C)=NC1=CC=C(Cl)C=C1 MYURAHUSYDVWQA-UHFFFAOYSA-N 0.000 description 1
- NDNKHWUXXOFHTD-UHFFFAOYSA-N metizoline Chemical compound CC=1SC2=CC=CC=C2C=1CC1=NCCN1 NDNKHWUXXOFHTD-UHFFFAOYSA-N 0.000 description 1
- 229960002939 metizoline Drugs 0.000 description 1
- DSRNRYQBBJQVCW-UHFFFAOYSA-N metoxuron Chemical compound COC1=CC=C(NC(=O)N(C)C)C=C1Cl DSRNRYQBBJQVCW-UHFFFAOYSA-N 0.000 description 1
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 1
- BMLIZLVNXIYGCK-UHFFFAOYSA-N monuron Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C=C1 BMLIZLVNXIYGCK-UHFFFAOYSA-N 0.000 description 1
- LCGPAEGODAEUGN-UHFFFAOYSA-N n,n-diethyl-3-(2-ethyl-6-methylphenyl)sulfonyl-1,2,4-triazole-1-carboxamide Chemical compound CCN(CC)C(=O)N1C=NC(S(=O)(=O)C=2C(=CC=CC=2C)CC)=N1 LCGPAEGODAEUGN-UHFFFAOYSA-N 0.000 description 1
- XESCSVABNVAQQS-UHFFFAOYSA-N n-(3-chloro-4-propan-2-ylphenyl)-2-methylpentanamide Chemical compound CCCC(C)C(=O)NC1=CC=C(C(C)C)C(Cl)=C1 XESCSVABNVAQQS-UHFFFAOYSA-N 0.000 description 1
- AIMMSOZBPYFASU-UHFFFAOYSA-N n-(4,6-dimethoxypyrimidin-2-yl)-n'-[3-(2,2,2-trifluoroethoxy)pyridin-1-ium-2-yl]sulfonylcarbamimidate Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)OCC(F)(F)F)=N1 AIMMSOZBPYFASU-UHFFFAOYSA-N 0.000 description 1
- KGMBZDZHRAFLBY-UHFFFAOYSA-N n-(butoxymethyl)-n-(2-tert-butyl-6-methylphenyl)-2-chloroacetamide Chemical compound CCCCOCN(C(=O)CCl)C1=C(C)C=CC=C1C(C)(C)C KGMBZDZHRAFLBY-UHFFFAOYSA-N 0.000 description 1
- LKVOXDJKFRBRQV-UHFFFAOYSA-N n-(dimethyl-$l^{4}-sulfanylidene)-4-(dipropylamino)-3,5-dinitrobenzenesulfonamide Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(=O)(=O)N=S(C)C)C=C1[N+]([O-])=O LKVOXDJKFRBRQV-UHFFFAOYSA-N 0.000 description 1
- IDFXUDGCYIGBDC-UHFFFAOYSA-N n-[4-ethylsulfanyl-2-(trifluoromethyl)phenyl]methanesulfonamide Chemical compound CCSC1=CC=C(NS(C)(=O)=O)C(C(F)(F)F)=C1 IDFXUDGCYIGBDC-UHFFFAOYSA-N 0.000 description 1
- KDOKZLSGPVBDLS-UHFFFAOYSA-N n-[5-(1-chloro-2-methylpropan-2-yl)-1,3,4-thiadiazol-2-yl]cyclopropanecarboxamide Chemical compound S1C(C(C)(CCl)C)=NN=C1NC(=O)C1CC1 KDOKZLSGPVBDLS-UHFFFAOYSA-N 0.000 description 1
- CHEDHKBPPDKBQF-UPONEAKYSA-N n-[5-[(6s,7ar)-6-fluoro-1,3-dioxo-5,6,7,7a-tetrahydropyrrolo[1,2-c]imidazol-2-yl]-2-chloro-4-fluorophenyl]-1-chloromethanesulfonamide Chemical compound N1([C@@H](C2=O)C[C@@H](C1)F)C(=O)N2C1=CC(NS(=O)(=O)CCl)=C(Cl)C=C1F CHEDHKBPPDKBQF-UPONEAKYSA-N 0.000 description 1
- DGPBHERUGBOSFZ-UHFFFAOYSA-N n-but-3-yn-2-yl-2-chloro-n-phenylacetamide Chemical compound C#CC(C)N(C(=O)CCl)C1=CC=CC=C1 DGPBHERUGBOSFZ-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- JXTHEWSKYLZVJC-UHFFFAOYSA-N naptalam Chemical compound OC(=O)C1=CC=CC=C1C(=O)NC1=CC=CC2=CC=CC=C12 JXTHEWSKYLZVJC-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- XITQUSLLOSKDTB-UHFFFAOYSA-N nitrofen Chemical compound C1=CC([N+](=O)[O-])=CC=C1OC1=CC=C(Cl)C=C1Cl XITQUSLLOSKDTB-UHFFFAOYSA-N 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- NVGOPFQZYCNLDU-UHFFFAOYSA-N norflurazon Chemical compound O=C1C(Cl)=C(NC)C=NN1C1=CC=CC(C(F)(F)F)=C1 NVGOPFQZYCNLDU-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- LLLFASISUZUJEQ-UHFFFAOYSA-N orbencarb Chemical compound CCN(CC)C(=O)SCC1=CC=CC=C1Cl LLLFASISUZUJEQ-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- UNAHYJYOSSSJHH-UHFFFAOYSA-N oryzalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(N)(=O)=O)C=C1[N+]([O-])=O UNAHYJYOSSSJHH-UHFFFAOYSA-N 0.000 description 1
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- JZPKLLLUDLHCEL-UHFFFAOYSA-N pentoxazone Chemical compound O=C1C(=C(C)C)OC(=O)N1C1=CC(OC2CCCC2)=C(Cl)C=C1F JZPKLLLUDLHCEL-UHFFFAOYSA-N 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- CSWIKHNSBZVWNQ-UHFFFAOYSA-N pethoxamide Chemical compound CCOCCN(C(=O)CCl)C(=C(C)C)C1=CC=CC=C1 CSWIKHNSBZVWNQ-UHFFFAOYSA-N 0.000 description 1
- IDOWTHOLJBTAFI-UHFFFAOYSA-N phenmedipham Chemical compound COC(=O)NC1=CC=CC(OC(=O)NC=2C=C(C)C=CC=2)=C1 IDOWTHOLJBTAFI-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 description 1
- CWKFPEBMTGKLKX-UHFFFAOYSA-N picolinafen Chemical compound C1=CC(F)=CC=C1NC(=O)C1=CC=CC(OC=2C=C(C=CC=2)C(F)(F)F)=N1 CWKFPEBMTGKLKX-UHFFFAOYSA-N 0.000 description 1
- MGOHCFMYLBAPRN-UHFFFAOYSA-N pinoxaden Chemical compound CCC1=CC(C)=CC(CC)=C1C(C1=O)=C(OC(=O)C(C)(C)C)N2N1CCOCC2 MGOHCFMYLBAPRN-UHFFFAOYSA-N 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 150000003097 polyterpenes Chemical class 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- HKSBGIRAPYUOPP-UHFFFAOYSA-M potassium;2,6-dibromo-4-cyanophenolate Chemical compound [K+].[O-]C1=C(Br)C=C(C#N)C=C1Br HKSBGIRAPYUOPP-UHFFFAOYSA-M 0.000 description 1
- ORHJUFUQMQEFPQ-UHFFFAOYSA-M potassium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [K+].CC1=CC(Cl)=CC=C1OCC([O-])=O ORHJUFUQMQEFPQ-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- ISEUFVQQFVOBCY-UHFFFAOYSA-N prometon Chemical compound COC1=NC(NC(C)C)=NC(NC(C)C)=N1 ISEUFVQQFVOBCY-UHFFFAOYSA-N 0.000 description 1
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 description 1
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 description 1
- WHOKDONDRZNCBC-UHFFFAOYSA-N propan-2-yl 2-(2,4-dichlorophenoxy)acetate Chemical group CC(C)OC(=O)COC1=CC=C(Cl)C=C1Cl WHOKDONDRZNCBC-UHFFFAOYSA-N 0.000 description 1
- OYJMHAFVOZPIOY-UHFFFAOYSA-N propan-2-yl 2-chloro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]benzoate Chemical compound C1=C(Cl)C(C(=O)OC(C)C)=CC(N2C(N(C)C(=CC2=O)C(F)(F)F)=O)=C1 OYJMHAFVOZPIOY-UHFFFAOYSA-N 0.000 description 1
- FKLQIONHGSFYJY-UHFFFAOYSA-N propan-2-yl 5-[4-bromo-1-methyl-5-(trifluoromethyl)pyrazol-3-yl]-2-chloro-4-fluorobenzoate Chemical compound C1=C(Cl)C(C(=O)OC(C)C)=CC(C=2C(=C(N(C)N=2)C(F)(F)F)Br)=C1F FKLQIONHGSFYJY-UHFFFAOYSA-N 0.000 description 1
- LFULEKSKNZEWOE-UHFFFAOYSA-N propanil Chemical compound CCC(=O)NC1=CC=C(Cl)C(Cl)=C1 LFULEKSKNZEWOE-UHFFFAOYSA-N 0.000 description 1
- FROBCXTULYFHEJ-OAHLLOKOSA-N propaquizafop Chemical compound C1=CC(O[C@H](C)C(=O)OCCON=C(C)C)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 FROBCXTULYFHEJ-OAHLLOKOSA-N 0.000 description 1
- WJNRPILHGGKWCK-UHFFFAOYSA-N propazine Chemical compound CC(C)NC1=NC(Cl)=NC(NC(C)C)=N1 WJNRPILHGGKWCK-UHFFFAOYSA-N 0.000 description 1
- VXPLXMJHHKHSOA-UHFFFAOYSA-N propham Chemical compound CC(C)OC(=O)NC1=CC=CC=C1 VXPLXMJHHKHSOA-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PHNUZKMIPFFYSO-UHFFFAOYSA-N propyzamide Chemical compound C#CC(C)(C)NC(=O)C1=CC(Cl)=CC(Cl)=C1 PHNUZKMIPFFYSO-UHFFFAOYSA-N 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- ASRAWSBMDXVNLX-UHFFFAOYSA-N pyrazolynate Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OS(=O)(=O)C1=CC=C(C)C=C1 ASRAWSBMDXVNLX-UHFFFAOYSA-N 0.000 description 1
- FKERUJTUOYLBKB-UHFFFAOYSA-N pyrazoxyfen Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OCC(=O)C1=CC=CC=C1 FKERUJTUOYLBKB-UHFFFAOYSA-N 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 1
- ALZOLUNSQWINIR-UHFFFAOYSA-N quinmerac Chemical compound OC(=O)C1=C(Cl)C=CC2=CC(C)=CN=C21 ALZOLUNSQWINIR-UHFFFAOYSA-N 0.000 description 1
- ABOOPXYCKNFDNJ-SNVBAGLBSA-N quizalofop-P Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 ABOOPXYCKNFDNJ-SNVBAGLBSA-N 0.000 description 1
- OSUHJPCHFDQAIT-GFCCVEGCSA-N quizalofop-P-ethyl Chemical group C1=CC(O[C@H](C)C(=O)OCC)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 OSUHJPCHFDQAIT-GFCCVEGCSA-N 0.000 description 1
- BBKDWPHJZANJGB-IKJXHCRLSA-N quizalofop-P-tefuryl Chemical group O=C([C@H](OC=1C=CC(OC=2N=C3C=CC(Cl)=CC3=NC=2)=CC=1)C)OCC1CCCO1 BBKDWPHJZANJGB-IKJXHCRLSA-N 0.000 description 1
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- MGLWZSOBALDPEK-UHFFFAOYSA-N simetryn Chemical compound CCNC1=NC(NCC)=NC(SC)=N1 MGLWZSOBALDPEK-UHFFFAOYSA-N 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 description 1
- RFOHRSIAXQACDB-UHFFFAOYSA-M sodium;2-(2,4-dichlorophenoxy)acetate Chemical compound [Na+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl RFOHRSIAXQACDB-UHFFFAOYSA-M 0.000 description 1
- STAPBGVGYWCRTF-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCC([O-])=O STAPBGVGYWCRTF-UHFFFAOYSA-M 0.000 description 1
- JUNDBKFAZXZKRA-MAFYXNADSA-M sodium;2-[(e)-n-[(3,5-difluorophenyl)carbamoylamino]-c-methylcarbonimidoyl]pyridine-3-carboxylate Chemical compound [Na+].N=1C=CC=C(C([O-])=O)C=1C(/C)=N/NC(=O)NC1=CC(F)=CC(F)=C1 JUNDBKFAZXZKRA-MAFYXNADSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- PQTBTIFWAXVEPB-UHFFFAOYSA-N sulcotrione Chemical compound ClC1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O PQTBTIFWAXVEPB-UHFFFAOYSA-N 0.000 description 1
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- BCQMBFHBDZVHKU-UHFFFAOYSA-N terbumeton Chemical compound CCNC1=NC(NC(C)(C)C)=NC(OC)=N1 BCQMBFHBDZVHKU-UHFFFAOYSA-N 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 description 1
- XZPMQCKVOWVETG-UHFFFAOYSA-J tetrasodium;2-[(3-carboxylato-3-sulfonatopropanoyl)-octadecylamino]butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].CCCCCCCCCCCCCCCCCCN(C(CC([O-])=O)C([O-])=O)C(=O)CC(C([O-])=O)S([O-])(=O)=O XZPMQCKVOWVETG-UHFFFAOYSA-J 0.000 description 1
- GHTMQNZCRVHCQP-UHFFFAOYSA-J tetrasodium;4-[1,2-dicarboxyethyl(octadecyl)amino]-4-oxo-2-sulfobutanoate Chemical compound [Na+].[Na+].[Na+].[Na+].CCCCCCCCCCCCCCCCCCN(C(CC(O)=O)C(O)=O)C(=O)CC(C([O-])=O)S(O)(=O)=O.CCCCCCCCCCCCCCCCCCN(C(CC(O)=O)C(O)=O)C(=O)CC(C([O-])=O)S(O)(=O)=O.CCCCCCCCCCCCCCCCCCN(C(CC(O)=O)C(O)=O)C(=O)CC(C([O-])=O)S(O)(=O)=O.CCCCCCCCCCCCCCCCCCN(C(CC(O)=O)C(O)=O)C(=O)CC(C([O-])=O)S(O)(=O)=O GHTMQNZCRVHCQP-UHFFFAOYSA-J 0.000 description 1
- SRVJKTDHMYAMHA-WUXMJOGZSA-N thioacetazone Chemical compound CC(=O)NC1=CC=C(\C=N\NC(N)=S)C=C1 SRVJKTDHMYAMHA-WUXMJOGZSA-N 0.000 description 1
- 229960003231 thioacetazone Drugs 0.000 description 1
- DQFPEYARZIQXRM-LTGZKZEYSA-N tralkoxydim Chemical compound C1C(=O)C(C(/CC)=N/OCC)=C(O)CC1C1=C(C)C=C(C)C=C1C DQFPEYARZIQXRM-LTGZKZEYSA-N 0.000 description 1
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- IMEVJVISCHQJRM-UHFFFAOYSA-N triflusulfuron-methyl Chemical compound COC(=O)C1=CC=CC(C)=C1S(=O)(=O)NC(=O)NC1=NC(OCC(F)(F)F)=NC(N(C)C)=N1 IMEVJVISCHQJRM-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Definitions
- the invention relates to the technical field of crop protection compositions, in particular to herbicidally active compositions which comprise sulfonylurea/safener combinations (combinations of active compound and antidote) and are highly suitable for use against competing harmful plants in crops of useful plants.
- the invention provides a herbicidally active composition, comprising
- the sulfonylureas A) and the safeners B) can also be present in the form of their salts, for example as salts with inorganic and organic counterions.
- These salts are, for example, metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium salts and potassium salts, or else ammonium salts or salts with organic amines. Salt formation may also take place by an acid forming an adduct with basic groups, such as, for example, amino and alkylamino.
- Acids suitable for this purpose are strong inorganic and organic acids, for example HCl, HBr, H 2 SO 4 or HNO 3 .
- Preferred salts are the alkali metal salts, such as the sodium salts and potassium salts.
- the sulfonylureas A) may, for example, form salts in which the hydrogen of the —SO 2 —NH— group is replaced by an agriculturally suitable cation, for example a metal ion such as an alkali metal ion, preferably a sodium ion or potassium ion.
- the sulfonylureas A) and the safeners B) can also be present in the form of their esters, in particular in the form of their alkyl esters, such as C 1 -C 10 -alkyl esters. Methyl esters and ethyl esters are particularly preferred for the sulfonylureas A). Methyl esters, ethyl esters and methylhexyl esters are particularly preferred for the safeners B).
- the sulfonylureas (A) are preferably selected from the group consisting of metsulfuron-methyl (A1.1), thifensulfuron-methyl (A2.1), tribenuron-methyl (A3.1) and chlorsulfuron (A4.1), including the salts customary in agriculture, such as the sodium salts metsulfuron-methyl-sodium (A1.2), thifensulfuron-methyl-sodium (A2.2), tribenuron-methyl-sodium (A3.2) and chlorsulfuron-sodium (A4.2).
- metsulfuron A1.3
- metsulfuron-sodium A1.4
- thifensulfuron A2.3
- thifensulfuron-sodium A2.4
- tribenuron A3.3
- tribenuron-sodium A3.4
- Particularly preferred sulfonylureas are metsulfuron-methyl (A1.1), thifensulfuron-methyl (A2.1), tribenuron-methyl (A3.1) and chlorsulfuron (A4.1).
- the safeners (B) are preferably selected from the group consisting of ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (B1, mefenpyr-diethyl), ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (B2, isoxadifen-ethyl), 1-methylhexyl(5-chloro-8-quinolineoxy)acetate (B3, cloquintocet-mexyl), mefenpyr-dimethyl (B4), mefenpyr (B5), isoxadifen (B6) and cloquintocet (B7), ethyl 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazol-3-carboxylate (B8, fenchlorazole-ethyl) and fench
- Preferred safeners are (B1), (B2), (B3) and (B8), in particular (B1), (B2) and (B3).
- Particularly preferred safeners are (B1) and (B2), and very particular preference is given to mefenpyr-diethyl (B1).
- an a herbicidally effective amount is an amount of one or more herbicides sufficient to have a negative effect on plant growth.
- an antidote-effective amount is an amount of one or more safeners sufficient to neutralize the phytotoxic action of a herbicide or herbicide mixture on a useful plant at least partially.
- Compounds (A) and (B) also embrace all stereoisomers in which the attachment of the atoms is topoiogically the same, and mixtures thereof. Such compounds contain one or more asymmetric carbon atoms or else double bonds which are not specifically shown in the formulae.
- the possible stereoisomers defined by their specific spatial form, such as enantiomers, diastereomers, Z and E isomers, can be obtained by customary methods from the mixtures of the stereoisomers, or else be prepared by stereoselective reactions in combination with the use of stereochemically pure starting materials.
- Sulfonylureas are commercially available and known, for example, from “The Pesticide Manual”, 12. edition (2000), The British Crop Protection Association, and from U.S. Pat. No. 4,370,480, EP 30138, U.S. Pat. No. 4,701,535, EP 30142, EP 202830 and U.S. Pat. No. 4,127,405 which contain detailed information on preparation processes and starting materials. These publications are expressly, by way of reference, incorporated into this description.
- Safeners are commercially available and known, for example, from “The Pesticide Manual”, 12. edition (2000), The British Crop Protection Association, and from WO 91/7874, WO 95/7897, EP-A-94349 and EP-A-174562 which contain detailed information on preparation processes and starting materials. These publications are expressly, by way of reference, incorporated into this description.
- the safeners (antidotes) of group (B) reduce or prevent phytotoxic effects which may occur when using the herbicidally active compounds (A) in crops of useful plants without substantially affecting the activity of these herbicidally active compounds against harmful plants.
- This allows the field of application of conventional crop protection products to be widened quite considerably and to be extended to, for example, crops such as wheat, barley, corn, rice and other crops in which use of the herbicides was hitherto impossible, or of only limited possibility, that is to say at low rates and with a restricted spectrum.
- the sulfonylureas (A) and the safeners (B) of the sulfonylurea/safener combinations according to the invention can be applied together (for example as a readymix or by the tank mix method) or in succession in any desired sequence.
- the weight ratio of safener:sulfonylurea may vary within wide limits and is preferably within the range from 1:100 to 100:1, in particular from 1:10 to 10:1.
- the optimum amounts of sulfonylurea and safener depend on the type of the sulfonylurea used or on the safener used and on the species of the plant stand to be treated and can be determined in each individual case by simple standard preliminary experiments.
- Main fields of application for the herbicidally active combinations according to the invention are, in particular, cereal crops (for example wheat, rye, barley, oats), rice, corn, sorghum, cotton and soybeans, preferably cereals, rice and corn.
- cereal crops for example wheat, rye, barley, oats
- rice, corn, sorghum, cotton and soybeans preferably cereals, rice and corn.
- the safeners contained in the herbicidally active composition according to the invention can be used for pretreating the seed of the crop plant (for example seed dressing), or be incorporated into the seed furrows prior to sowing or applied together with a herbicide, in particular a sulfonylurea (A), before or after emergence of the plants.
- a herbicide in particular a sulfonylurea (A)
- the preemergence treatment includes both the treatment of the area under cultivation prior to sowing and the treatment of the areas under cultivation where the seeds have been planted but the plants have not yet emerged. Joint application with a herbicide is preferred. To this end, tank mixes or readymixes can be employed.
- the application rates of safeners required may vary within wide limits depending on the indication and the herbicidally active compounds used and are generally in the range from 0.001 to 5 kg, preferably 0.005 to 0.5 kg, of active compound per hectare.
- herbicidal compositions according to the invention or sulfonylurea/safener combinations may, if appropriate, also comprise, as additional components:
- Suitable optional organic solvents are, for example:
- fatty acid esters such as C 10 -C 22 -fatty acid esters are glycerol and glycol esters of fatty acids such as C 10 -C 22 -fatty acids, or transesterification products thereof, for example fatty acid alkyl esters such as C 10 -C 22 -fatty acid C 1 -C 20 -alkyl esters, which can be obtained, for example, by transesterification of the abovementioned glycerol or glycol fatty acid esters such as C 10 -C 22 -fatty acid esters with C 1 -C 20 -alcohols (for example methanol, ethanol, propanol or butanol).
- the transesterification can be carried out by known methods, as described, for example, in Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
- Preferred fatty acid alkyl esters such as C 10 -C 22 -fatty acid C 1 -C 20 -alkyl esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethylhexyl esters and dodecyl esters.
- Preferred glycol and glycerol fatty acid esters such as C 10 -C 22 -fatty acid esters are the uniform or mixed glycol esters and glycerol esters of C 10 -C 22 -fatty acids, in particular of such fatty acids having an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C 18 -fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
- Animal oils are generally known and commercially available.
- animal oils is to be understood as meaning, for example, oils of animal origin such as whale oil, cod-liver oil, musk oil or mink oil.
- Vegetable oils are generally known and commercially available.
- the term “vegetable oils” is to be understood as meaning, for example, oils of oleaginous plant species, such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, thistle oil, walnut oil, arachis oil, olive oil or castor oil, in particular rapeseed oil, where the vegetable oils also include their transesterification products, for example alkyl esters, such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
- the vegetable oils are preferably esters of C 10 -C 22 —, preferably C 12 -C 20 —, fatty acids.
- the C 10 -C 22 -fatty acid esters are, for example, esters of unsaturated or saturated C 10 -C 22 -fatty acids having, in particular, an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C 18 -fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
- Examples of vegetable oils are C 10 -C 22 -fatty acid esters of glycerol or glycol with C 10 -C 22 -fatty acids, or C 10 -C 22 -fatty acid C 1 -C 20 -alkyl esters which can be obtained, for example, by transesterification of the glycerol or glycol C 10 -C 22 -fatty acid esters mentioned above with C 1 -C 20 -alcohols (for example methanol, ethanol, propanol or butanol). The transesterification can be carried out by known methods as described, for example, in Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
- the vegetable oils can be contained in the mixtures for example in the form of commercially available vegetable oils, in particular rapeseed oils, such as rapeseed oil methyl ester, for example Phytorob® B (Novance, France), Edenor® MESU and the Agnique® ME series (Cognis, Germany) the Radia® series (ICI), the Prilube® series (Petrofina), or biodiesel or in the form of commercially available plant-oil-containing formulation additives, in particular those based on rapeseed oils, such as rapeseed oil methyl esters, for example Hasten® (Victoria Chemical Company, Australia, hereinbelow referred to as Hasten, main ingredient; rapeseed oil ethyl ester), Actirob® B (Novance, France, hereinbelow referred to as Actirob B, main ingredient: rapeseed oil methyl ester), Rako-Binol® (Bayer AG, Germany, hereinbelow referred
- Examples of synthetic acid esters are, for example, those derived from fatty acids having an odd number of carbon atoms, such as C 11 -C 21 -fatty acid esters.
- Preferred organic solvents are hydrocarbons, in particular aromatic hydrocarbons and/or aliphatic hydrocarbons and fatty acid esters, such as vegetable oils, such as triglycerides of fatty acids having 10 to 22 carbon atoms, which may be saturated or else unsaturated, straight-chain or branched and which may or may not carry further functional groups, such as corn oil, rapeseed oil, sunflower oil, cottonseed oil, linseed oil, soybean oil, coconut oil, palm oil, thistle oil or castor oil, and their transesterification products, such as fatty acid alkyl esters, and mixtures thereof.
- vegetable oils such as triglycerides of fatty acids having 10 to 22 carbon atoms, which may be saturated or else unsaturated, straight-chain or branched and which may or may not carry further functional groups, such as corn oil, rapeseed oil, sunflower oil, cottonseed oil, linseed oil, soybean oil, coconut oil, palm oil, thistle oil or castor oil,
- the solvents may be present on their own or as a mixture.
- the solubilizing power of the solvent or solvent mixture used for the sulfonylurea(s) used (component A) is preferably low.
- the total proportion of solvents in the herbicidal compositions according to the invention is generally between 0 and 95% by weight, preferably in the range between 20 and 80% by weight.
- the proportion of polar solvents such as aprotic polar solvents is generally below 20% by weight, preferably in the range from 0 to 10% by weight.
- the sulfosuccinates (component D) optionally present in the herbicidal compositions according to the invention can, for example, be mono- or diesters of sulfosuccinic acid, preferably those of the formula (III)
- R 1 and R 2 are identical or different and independently of one another are straight-chain, branched or cyclic, saturated or unsaturated C 1 -C 20 —, preferably C 4 -C 18 —, alkyl radicals, such as methyl, ethyl, butyl, hexyl, cyclohexyl, octyl, such as 2-ethylhexyl, decyl, tridecyl or octadecyl radicals, or R 1 and R 2 are C 7 -C 20 -alkylaryl radicals, such as nonylphenyl, 2,4,6-tri-sec-butylphenyl, 2,4,6-tris-(1-phenylethyl)phenyl, alkylbenzyl or a hydroxycinnamic radical,
- polyether units such as polyethylene glycols —(C
- sulfosuccinates are obtainable, for example, as the Aerosol® (Cytec), Agrilan® or Lankropol® (Akzo Nobel), Empimin® (Huntsman), Cropol® (Croda), Lutensit® (BASF), Triton® GR series (UnionCarbide), Imbirol®/Madeol®/Polirol® (Cesalpinia); Geropon® AR series or Geropon® SDS (Rhodia).
- Preferred sulfosuccinates are, for example, the sodium, potassium and ammonium salts of bis(alkyl)sulfosuccinates, where the alkyl radicals may be identical or different and contain 4 to 16 carbon atoms and are preferably butyl, hexyl, octyl, such as 2-ethylhexyl, or decyl radicals which may be straight-chain or branched.
- the total proportion of sulfosuccinate or sulfosuccinates in the herbicidal compositions according to the invention is generally between 0 and 60% by weight, in particular in the range between 0.5 and 30% by weight.
- Suitable optional agrochemically active compounds (E) different from (A) and (B) for the herbicidal compositions according to the invention are, for example, known active compounds, such as herbicides, insecticides or fungicides, as described, for example, in Weed Research 26, 441-445 (1986), or “The Pesticide Manual”, 12th edition, The British Crop Protection Council, 2000, and the literature cited therein, for example in mixed formulations or as a component for a tank mix.
- the following active compounds, for example may be mentioned as herbicides known from the literature which may be present in the herbicidal compositions according to the invention.
- the compounds are referred to either by the “common name” of the International Organization for Standardization (ISO) or by the chemical name, if appropriate together with a customary code number, and include in each case all possible use forms, such as acids, salts, esters and isomers, such as stereoisomers and optical isomers: acetochlor; acifluorfen; aclonifen; AKH 7088, i.e.
- the mixing partners E), the sulfonylureas A) and the safeners B) can be applied together (as a readymix or as a tank mix) or successively in any sequence.
- Preferred mixing partners E) are bromoxynil (E1) in all of its use forms, including the salts and esters, for example bromoxynil-octanoate (E1.1), bromoxynil-heptanoate (E1.2), bromoxynil-butyrate (E1.3), bromoxynil-sodium (E1.4) and bromoxynil-potassium (E1.5); 2,4-D (E2) in all of its use forms, including the salts and esters, for example 2,4-D-butotyl (E2.1), 2,4-D-butyl (E2.2), 2,4-D-dimethylammonium (E2.3), 2,4-D-diethanolamine (E2.4), 2,4-D-2-ethylhexyl (E2.5), 2,4-D-isooctyl (E2.6), 2,4-D-isopropyl (E2.7), 2,4-D-sodium (E2.8) and 2,4-D-triethanolamine (E2.9);
- Preferred combinations (A), (B), (E) according to the invention are, for example:
- All of the combinations mentioned above may also comprise more agrochemically active compounds (E), in particular two or three active compounds (E), preferably selected from the group consisting of (E1), (E1.1), (E1.2), (E1.3), (E1.4), (E1.5), (E2), (E2.1), (E2.2), (E2.3), (E2.4), (E2.5), (E2.6), (E2.7), (E2.8), (E2.9), (E3), (E3.1), (E3.2), (E3.3), (E4), (E4.1), (E4.2), (E5), (E5.1), (E5.2), (E6), (E6.1), (E6.2), (E6.3), (E6.4), (E6.5), (E7), (E7.1), (E7.2), (E8), (E8.1), (E8.2), (E9), (E9.1).
- E1 agrochemically active compounds
- E agrochemically active compounds
- Preferred combinations (A), (B), (E) with two or three active compounds (E) comprise, as component (E), (E1.1)+(E1.2), (E1.1)+(E1.2)+(E6.3), (E1.1)+(E1.2)+(E2.6) or (E5.1)+(E6.3).
- component (E) component (E), (E1.1)+(E1.2), (E1.1)+(E1.2)+(E6.3), (E1.1)+(E1.2)+(E2.6) or (E5.1)+(E6.3).
- Customary auxiliaries and additives which may also be contained in the herbicidal compositions according to the invention are, for example: surfactants, such as emulsifiers and dispersants, thickeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, penetrants, preservatives and antifreeze agents, antioxidants, solubilizers, fillers, carriers and colorants, antifoams, fertilizers, evaporation inhibitors and agents which modify pH and viscosity.
- surfactants such as emulsifiers and dispersants, thickeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, penetrants, preservatives and antifreeze agents, antioxidants, solubilizers, fillers, carriers and colorants, antifoams, fertilizers, evaporation inhibitors and agents which modify pH and viscosity.
- Suitable emulsifiers and dispersants are, for example, nonionic emulsifiers and dispersants, for example:
- Preferred nonionic emulsifiers and dispersants are, for example, polyethoxylated alcohols, polyethoxylated triglycerides which contain hydroxyfatty acids and polyethylene oxide/polypropylene oxide block copolymers.
- the total proportion of nonionic emulsifiers and dispersants in the herbicidal compositions according to the invention is generally between 0 and 20% by weight. If nonionic emulsifiers and dispersants are, in addition to their emulsifying/dispersing properties, also used for increasing the biological effectiveness, for example as penetrants or adhesives, their proportion in the herbicidal compositions according to the invention can be increased to up to 60% by weight.
- ionic emulsifiers and dispersants for example:
- Preferred ionic emulsifiers/dispersants are, for example, salts of alkylarylsulfonic acids and polyelectrolytes from the polycondensation of naphthalenesulfonate and formaldehyde.
- the total proportion of ionic emulsifiers and dispersants in the herbicidal compositions according to the invention is generally between 0 and 20% by weight, in particular between 0 and 8% by weight.
- Suitable thickeners and thixotropic agents are, for example:
- Preferred thickeners and thixotropic agents are, for example, modified phyllosilicates and thickeners based on synthetic polymers.
- the proportion of thickeners and thixotropic agents in the herbicidal compositions according to the invention is generally between 0 and 5% by weight, in particular between 0.2 and 3% by weight.
- herbicidally active compositions or sulfonylurea/safener combinations according to the invention can be prepared by customary processes which are already known, for example by mixing the various components with the help of stirrers, shakers, mills or (static) mixers. In this connection, brief heating of the mixtures may in some cases be advantageous in order to achieve complete dissolution of all of the components involved.
- herbicidally active compositions comprising:
- the present invention also provides a method which comprises applying the components (A) and (B) of the herbicidally active composition according to the invention together or separately to the harmful plants, crop plants, plant seeds or to the area on which the plants grow, if appropriate in combination with further components, for example together or separately with the components (C), (D), (E) and (F).
- one or more safeners of group (B) preferably in an antidote-effective amount
- the herbicidally active compositions according to the invention may also be employed for controlling harmful plants in crops of known genetically modified plants or genetically modified plants yet to be developed.
- the transgenic plants are distinguished by particularly advantageous properties, for example by resistances to certain crop protection agents, resistances to plant diseases or to causative agents of plant diseases such as specific insects or microorganisms such as fungi, bacteria or viruses.
- Other particular properties concern for example the harvested crop with regard to quantity, quality, storability, composition and specific constituents.
- transgenic plants are known with an increased starch content or a modified starch quality, or those with a different fatty acid composition of the harvested crop.
- cereals such as wheat, barley, rye, oats
- millet rice, cassaya and corn
- crops of sugar beet, cotton, soybean, oilseed rape, potato, tomato, pea and other vegetables for example of cereals (such as wheat, barley, rye, oats), millet, rice, cassaya and corn, or else crops of sugar beet, cotton, soybean, oilseed rape, potato, tomato, pea and other vegetables.
- the invention thus also relates to the use of the herbicidally active composition according to the invention for controlling harmful plants in transgenic crop plants or crop plants which are tolerant as a result of selective breeding.
- the safeners of group (B) and the sulfonylureas (A) can be formulated together or separately, if appropriate in combination with further components, for example the components (C), (D), (E) and (F), in various ways, depending on the prevailing biological and/or chemico-physical parameters. Suitable possibilities of formulation are, for example:
- WP wettable powders
- EC emulsifiable concentrates
- SP water-soluble powders
- SL water-soluble concentrates
- BW concentrated emulsions
- CS capsule suspensions
- SC oil- or water-based dispersions
- DP dust
- O oil-miscible solutions
- GR granules in the form of microgranules, spray granules, coated granules and adsorption granules, granules for soil application or broadcasting, water-soluble granules (SG), water-dispersible granules (WG), ULV formulations, microcapsules and waxes.
- formulation auxiliaries which may be required, such as inert materials, surfactants, solvents and further additives are likewise known and described, for example, in: “Handbook of Insecticide Dust Diluents and Carriers”, 2nd Ed., Darland Books, Caldwell N.J., H. v. Olphen, “Introduction to Clay Colloid Chemistry”; 2nd Ed., J. Wiley & Sons, N.Y.; C. Marsden, “Solvents Guide”; 2nd Ed., Interscience, N.Y.
- combinations with other agrochemically active compounds for example crop protectants such as insecticides, acaricides, herbicides, fungicides, or with safeners, fertilizers and/or growth regulators may also be prepared, for example in the form of a readymix or a tank mix.
- Wettable powders are preparations which are uniformly dispersible in water and which, besides the active ingredient, additionally comprise ionic and/or nonionic surfactants (wetters, dispersants), for example polyoxethylated alkylphenols, polyoxethylated fatty alcohols, polyoxethylated fatty amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium lignosulfonates, sodium 2,2′-dinaphthylmethane-6,6′-disulfonate, sodium dibutylnaphthalene-sulfonate, or else sodium oleoylmethyltaurinate, in addition to a diluent or inert substance.
- ionic and/or nonionic surfactants for example polyoxethylated alkylphenols, polyoxethylated fatty alcohols, poly
- the active ingredients for example the herbicidal active ingredients and/or the safeners
- the active ingredients are ground finely, for example in customary apparatuses such as hammer mills, blower mills and air-jet mills, and simultaneously or subsequently mixed with the formulation auxiliaries.
- Emulsifiable concentrates are prepared, for example, by dissolving the active ingredient, for example the herbicidal active ingredient and/or the safener, in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene or else high-boiling hydrocarbons such as saturated or unsaturated aliphatic or alicyclic substances, aromatic substances or mixtures of the organic solvents with addition of one or more ionic and/or nonionic surfactants (emulsifiers).
- an organic solvent for example butanol, cyclohexanone, dimethylformamide, xylene or else high-boiling hydrocarbons such as saturated or unsaturated aliphatic or alicyclic substances, aromatic substances or mixtures of the organic solvents with addition of one or more ionic and/or nonionic surfactants (emulsifiers).
- emulsifiers which may be used: calcium (C 6 -C 18 )-alkylarylsulfonates such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers such as fatty acid polyglycol esters, (C 2 -C 18 )-alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide/ethylene oxide condensates, alkyl polyethers, sorbitan esters such as, for example, sorbitan fatty acid esters or polyoxyethylene sorbitan esters such as polyoxyethylene sorbitan fatty acid esters.
- Dusts are obtained in general by grinding the active ingredient, for example the herbicidal active ingredient and/or the safener, with finely divided solid materials, for example talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
- active ingredient for example the herbicidal active ingredient and/or the safener
- finely divided solid materials for example talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
- Suspension concentrates may be water- or oil-based. They can be prepared for example by wet-milling by means of commercially available bead mills, if appropriate with addition of surfactants as, for example, have already been listed above in the case of the other formulation types.
- Emulsions for example oil-in-water emulsions (EW)
- EW oil-in-water emulsions
- Granules can be produced either by spraying the active ingredient, for example the herbicidal active ingredient and/or the safener, onto absorptive granulated inert material or by applying active ingredient concentrates to the surface of carriers such as sand, kaolinite or of granulated inert material by means of binders, for example polyvinyl alcohol, sodium polyacrylate or else mineral oils.
- Suitable active ingredients may also be granulated in the manner which is conventional for the production of fertilizer granules, if desired as a mixture with fertilizers.
- water-dispersible granules are prepared by the customary method such as spray-drying, fluidized-bed granulation, disk granulation, mixing by means of high-speed mixers, and extrusion without solid inert material.
- Preferred formulations are liquid formulations, such as oil suspensions, oil suspension concentrates, suspoemulsions, suspoemulsion concentrates, emulsions, for example W/O- or O/W-based, emulsion concentrates, microemulsions, microemulsion concentrates, emulsifiable concentrates, and spray liquors obtainable therefrom, preferably aqueous spray liquors.
- a particularly preferred liquid formulation type are oil suspension concentrates, i.e. suspension concentrates based on organic solvents, and formulations obtainable therefrom by dilution, such as solutions, emulsions, suspoemulsions and suspensions.
- oil suspension concentrates one or more active compounds are suspended in the organic solvent; further active compounds may be dissolved in the organic solvent.
- the herbicide (A) is present in suspended form in the organic solvents.
- the main proportion (in % by weight) of sulfonamide is present undissolved in highly disperse form and a minor portion of the sulfonamide may be present in dissolved form.
- more than 80% by weight, particularly preferably more than 90% by weight, of the sulfonamide are suspended in the organic solvent, in each case based on the total amount of sulfonamide in the oil suspension concentrate according to the invention.
- the agrochemical preparations comprise from 0.1 to 99% by weight, in particular from 0.1 to 95% by weight, of active compounds, for example active safener compounds (B), or sulfonylurea (A), or the active herbicide/safener mixture according to the invention comprising sulfonylureas (A) and active safener compounds (B), and from 1 to 99.9% by weight, in particular from 5 to 99.8% by weight, of a solid or liquid additive and from 0 to 25% by weight, in particular from 0.1 to 25% by weight, of a surfactant.
- active compounds for example active safener compounds (B), or sulfonylurea (A), or the active herbicide/safener mixture according to the invention comprising sulfonylureas (A) and active safener compounds (B), and from 1 to 99.9% by weight, in particular from 5 to 99.8% by weight, of a solid or liquid additive and from 0 to 25% by weight, in particular from 0.1 to 25% by weight, of
- the active ingredient concentration is, for example, from approximately 10 to 90% by weight, the remainder to 100% by weight being composed of customary formulation components. In the case of emulsifiable concentrates, the active ingredient concentration amounts to approximately 1 to 80% by weight.
- Formulations in the form of dusts comprise from approximately 1 to 20% by weight of active ingredients, sprayable solutions from approximately 0.2 to 20% by weight of active ingredients.
- the active ingredient content depends partly on whether the active compound is in liquid or solid form. As a rule, the active compound content in the water-dispersible granules is between 10 and 90% by weight.
- the active ingredient formulations mentioned comprise, if appropriate, the adhesives, wetters, dispersants, emulsifiers, penetrants, preservatives, antifreeze agents, solvents, fillers, carriers, colorants, antifoams, evaporation inhibitors, pH regulators and viscosity regulators which are conventional in each case.
- the commercially available formulations are optionally diluted in a conventional manner with water, for example in the case of wettable powders, emulsifable concentrates, dispersions and water-dispersible granules.
- Preferred formulations which are diluted with water are, for example, liquid formulations such as oil suspensions, oil suspension concentrates, suspoemulsions, suspoemulsion concentrates, emulsions, for example W/O- or O/W-based, emulsion concentrates, microemulsions, microemulsion concentrates, and emulsifable concentrates.
- Preparations in the form of dusts, granules for soil application or broadcasting as well as sprayable solutions are customarily not diluted with further inert substances prior to application.
- the necessary application rate of the herbicides (A) varies with the external conditions such as, inter alia, temperature, humidity and the type of the herbicide used, it can be varied within wide limits, for example between 0.001 and 10.0 kg/ha or more of active substance, but it is preferably between 0.005 and 5 kg/ha.
- Damage to the plants is evaluated visually in comparison with control plants, according to a scale from 0 to 100%:
- Seeds of monocotyledonous and dicotyledonous weeds and of crop plants are placed in sandy loam soil in plastic pots, covered with soil and cultivated in a greenhouse under good growth conditions.
- test plants are treated at the 3-4-leaf stage.
- Different dosages of the individual active compounds according to the invention formulated as emulsion concentrates, are sprayed individually or as mixtures in application rates of 300 l of water/ha (converted) onto the green parts of the plants, and after the test plants have spent 3 weeks in the greenhouse under optimum growth conditions, the effect of the preparation is scored visually in comparison with untreated controls.
- the combinations according to the invention of sulfonylureas and safeners are capable of effectively controlling a broad spectrum of weeds, and damage to crop plants is, compared with the use of the individual sulfonylureas without safener, considerably reduced.
- test results for crop plants are compiled in the tables below. Stated is the respective degree of damage to the crop plants and the reduction of the damage by the herbicide/safener combinations according to the invention in percent, compared with the herbicide applied alone.
- cultivar “Kanzler” Application rate Degree of Reduction of Active compound(s) [g of a.i./ha] damage [%] damage [%] herbicide A1.1 25 10 — herbicide A1.1 + safener B3 25 + 100 0 100 herbicide A2.1 25 10 — herbicide A2.1 + safener B1 25 + 100 0 100 herbicide A2.1 + safener B3 25 + 100 0 100 herbicide A3.1 40 20 — herbicide A3.1 + safener B3 40 + 100 0 100 herbicide A1.1: metsulfuron-methyl; herbicide A2.1: thifensulfuron-methyl; herbicide A3.1: tribenuron-methyl; safener B1: mefenpyr-diethyl; safener B2: isoxadifen-ethyl; safener B3: cloquintocet-mexyl.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A herbicidally active composition, comprising
- (A) one or more sulfonylureas from the group consisting of metsulfuron, thifensulfuron, tribenuron, chlorsulfuron and their salts and esters, and
- (B) one or more safeners from the group consisting of mefenpyr, isoxadifen, cloquintocet, fenchlorazole and their salts and esters.
Description
- The invention relates to the technical field of crop protection compositions, in particular to herbicidally active compositions which comprise sulfonylurea/safener combinations (combinations of active compound and antidote) and are highly suitable for use against competing harmful plants in crops of useful plants.
- Combinations of herbicides which inhibit the enzyme acetolactate synthase (ALS) and safeners are known. Thus, EP 0 492 367 A2 describes combinations of different ALS inhibitors with different safeners. However, the specific combinations disclosed in this publication are, with respect to selectivity and activity spectrum, not always satisfactory.
- Accordingly, it was an object of the present invention to provide herbicidally active compositions with increased selectivity in important crop plants and, at the same time, high activity against harmful plants. Surprisingly, this object is achieved by the herbicidally active composition of the present invention.
- Accordingly, the invention provides a herbicidally active composition, comprising
- (A) one or more sulfonylureas from the group consisting of metsulfuron, thifensulfuron, tribenuron, chlorsulfuron and their salts and esters, preferably in a herbicidally effective amount, and
- (B) one or more safeners from the group consisting of mefenpyr, isoxadifen, cloquintocet, fenchlorazole and their salts and esters, preferably in an antidote-effective amount, preferably mefenpyr, isoxadifen, cloquintocet and their salts and esters, particularly preferably mefenpyr, cloquintocet and their salts and esters, very particularly preferably mefenpyr and its salts and esters.
- The sulfonylureas A) and the safeners B) can also be present in the form of their salts, for example as salts with inorganic and organic counterions. These salts are, for example, metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium salts and potassium salts, or else ammonium salts or salts with organic amines. Salt formation may also take place by an acid forming an adduct with basic groups, such as, for example, amino and alkylamino. Acids suitable for this purpose are strong inorganic and organic acids, for example HCl, HBr, H2SO4 or HNO3. Preferred salts are the alkali metal salts, such as the sodium salts and potassium salts. The sulfonylureas A) may, for example, form salts in which the hydrogen of the —SO2—NH— group is replaced by an agriculturally suitable cation, for example a metal ion such as an alkali metal ion, preferably a sodium ion or potassium ion.
- The sulfonylureas A) and the safeners B) can also be present in the form of their esters, in particular in the form of their alkyl esters, such as C1-C10-alkyl esters. Methyl esters and ethyl esters are particularly preferred for the sulfonylureas A). Methyl esters, ethyl esters and methylhexyl esters are particularly preferred for the safeners B).
- The sulfonylureas (A) are preferably selected from the group consisting of metsulfuron-methyl (A1.1), thifensulfuron-methyl (A2.1), tribenuron-methyl (A3.1) and chlorsulfuron (A4.1), including the salts customary in agriculture, such as the sodium salts metsulfuron-methyl-sodium (A1.2), thifensulfuron-methyl-sodium (A2.2), tribenuron-methyl-sodium (A3.2) and chlorsulfuron-sodium (A4.2). Preference is furthermore given to metsulfuron (A1.3), metsulfuron-sodium (A1.4), thifensulfuron (A2.3), thifensulfuron-sodium (A2.4), tribenuron (A3.3) and tribenuron-sodium (A3.4). Particularly preferred sulfonylureas (A) are metsulfuron-methyl (A1.1), thifensulfuron-methyl (A2.1), tribenuron-methyl (A3.1) and chlorsulfuron (A4.1).
- The safeners (B) are preferably selected from the group consisting of ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (B1, mefenpyr-diethyl), ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (B2, isoxadifen-ethyl), 1-methylhexyl(5-chloro-8-quinolineoxy)acetate (B3, cloquintocet-mexyl), mefenpyr-dimethyl (B4), mefenpyr (B5), isoxadifen (B6) and cloquintocet (B7), ethyl 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazol-3-carboxylate (B8, fenchlorazole-ethyl) and fenchlorazole (B9), including the salts customary in agriculture, such as the sodium salts. Preferred safeners are (B1), (B2), (B3) and (B8), in particular (B1), (B2) and (B3). Particularly preferred safeners are (B1) and (B2), and very particular preference is given to mefenpyr-diethyl (B1).
- For the purpose of the invention, an a herbicidally effective amount is an amount of one or more herbicides sufficient to have a negative effect on plant growth.
- For the purpose of the invention, an antidote-effective amount is an amount of one or more safeners sufficient to neutralize the phytotoxic action of a herbicide or herbicide mixture on a useful plant at least partially.
- Compounds (A) and (B) also embrace all stereoisomers in which the attachment of the atoms is topoiogically the same, and mixtures thereof. Such compounds contain one or more asymmetric carbon atoms or else double bonds which are not specifically shown in the formulae. The possible stereoisomers defined by their specific spatial form, such as enantiomers, diastereomers, Z and E isomers, can be obtained by customary methods from the mixtures of the stereoisomers, or else be prepared by stereoselective reactions in combination with the use of stereochemically pure starting materials.
- Sulfonylureas (A) are commercially available and known, for example, from “The Pesticide Manual”, 12. edition (2000), The British Crop Protection Association, and from U.S. Pat. No. 4,370,480, EP 30138, U.S. Pat. No. 4,701,535, EP 30142, EP 202830 and U.S. Pat. No. 4,127,405 which contain detailed information on preparation processes and starting materials. These publications are expressly, by way of reference, incorporated into this description.
- Safeners (B) are commercially available and known, for example, from “The Pesticide Manual”, 12. edition (2000), The British Crop Protection Association, and from WO 91/7874, WO 95/7897, EP-A-94349 and EP-A-174562 which contain detailed information on preparation processes and starting materials. These publications are expressly, by way of reference, incorporated into this description.
- Examples of preferred combinations according to the invention of sulfonylureas (A) and safeners (B) are:
- (A1.1)+(B1), (A1.1)+(B2), (A1.1)+(B3), (A1.1)+(B8), (A2.1)+(B1), (A2.1)+(B2), (A2.1)+(B3), (A2.1)+(B8), (A3.1)+(B1), (A3.1)+(B2), (A3.1)+(B3), (A3.1)+(B8), (A4.1)+(B1), (A4.1)+(B2), (A4.1)+(B3), (A4.1)+(B8), (A1.2)+(B1), (A1.2)+(B2), (A1.2)+(B3), (A1.2)+(B8), (A2.2)+(B1), (A2.2)+(B2), (A2.2)+(B3), (A2.2)+(B8), (A3.2)+(B1), (A3.2)+(B2), (A3.2)+(B3), (A3.2)+(B8), (A4.2)+(B1), (A4.2)+(B2), (A4.2)+(B3), (A4.2)+(B8), (A1.3)+(B1), (A1.3)+(B2), (A1.3)+(B3), (A1.3)+(B8), (A2.3)+(B1), (A2.3)+(B2), (A2.3)+(B3), (A2.3)+(B8), (A3.3)+(B1), (A3.3)+(B2), (A3.3)+(B3), (A3.3)+(B8), (A1.4)+(B1), (A1.4)+(B2), (A1.4)+(B3), (A1.4)+(B8), (A2.4)+(B1), (A2.4)+(B2), (A2.4)+(B3), (A2.4)+(B8), (A3.4)+(B1), (A3.4)+(B2), (A3.4)+(B3), (A3.4)+(B8); (A1.1)+(A1.2)+(B1), (A1.1)+(A2.1)+(B1), (A1.1)+(A2.2)+(B1), (A1.1)+(A3.1)+(B1), (A1.1)+(A3.2)+(B1), (A1.1)+(A4.1)+(B1), (A1.1)+(A4.2)+(B1);
- (A3.1)+(A3.2)+(B1), (A3.1)+(A4.1)+(B1), (A3.1)+(A4.2)+(B1); (A3.2)+(A4.1)+(B1), (A3.2)+(A4.2)+(B1), (A4.1)+(A4.2)+(B1); (A1.1)+(A1.2)+(B2), (A1.1)+(A2.1)+(B2), (A1.1)+(A2.2)+(B2), (A1.1)+(A3.1)+(B2), (A1.1)+(A3.2)+(B2), (A1.1)+(A4.1)+(B2), (A1.1)+(A4.2)+(B2);
- The safeners (antidotes) of group (B) reduce or prevent phytotoxic effects which may occur when using the herbicidally active compounds (A) in crops of useful plants without substantially affecting the activity of these herbicidally active compounds against harmful plants. This allows the field of application of conventional crop protection products to be widened quite considerably and to be extended to, for example, crops such as wheat, barley, corn, rice and other crops in which use of the herbicides was hitherto impossible, or of only limited possibility, that is to say at low rates and with a restricted spectrum.
- The sulfonylureas (A) and the safeners (B) of the sulfonylurea/safener combinations according to the invention can be applied together (for example as a readymix or by the tank mix method) or in succession in any desired sequence. The weight ratio of safener:sulfonylurea may vary within wide limits and is preferably within the range from 1:100 to 100:1, in particular from 1:10 to 10:1. The optimum amounts of sulfonylurea and safener depend on the type of the sulfonylurea used or on the safener used and on the species of the plant stand to be treated and can be determined in each individual case by simple standard preliminary experiments.
- Main fields of application for the herbicidally active combinations according to the invention are, in particular, cereal crops (for example wheat, rye, barley, oats), rice, corn, sorghum, cotton and soybeans, preferably cereals, rice and corn.
- Depending on their properties, the safeners contained in the herbicidally active composition according to the invention can be used for pretreating the seed of the crop plant (for example seed dressing), or be incorporated into the seed furrows prior to sowing or applied together with a herbicide, in particular a sulfonylurea (A), before or after emergence of the plants. The preemergence treatment includes both the treatment of the area under cultivation prior to sowing and the treatment of the areas under cultivation where the seeds have been planted but the plants have not yet emerged. Joint application with a herbicide is preferred. To this end, tank mixes or readymixes can be employed.
- The application rates of safeners required may vary within wide limits depending on the indication and the herbicidally active compounds used and are generally in the range from 0.001 to 5 kg, preferably 0.005 to 0.5 kg, of active compound per hectare.
- The herbicidal compositions according to the invention or sulfonylurea/safener combinations may, if appropriate, also comprise, as additional components:
- (C) one or more solvents, preferably organic solvents,
- (D) one or more sulfosuccinates,
- (E) one or more agrochemically active compounds different from (A) and (B), and/or
- (F) customary auxiliaries and additives.
- Suitable optional organic solvents (component C) are, for example:
- 1) hydrocarbons, which may be unsubstituted or substituted, for example
- 1a) aromatic hydrocarbons, for example
- mono- or polyalkyl-substituted benzenes, such as toluene, xylenes, mesitylene, ethylbenzene, or
- mono- or polyalkyl-substituted naphthalenes, such as 1-methylnaphthalene, 2-methylnaphthalene or dimethylnaphthalene, or
- other benzene-derived aromatic hydrocarbons, such as indane or Tetralin®, or
- mixtures thereof,
- 1b) aliphatic hydrocarbons, for example
- straight-chain or branched aliphatics, for example of the formula CnH2n+2, such as pentane, hexane, octane, 2-methylbutane or 2,2,4-trimethylpentane, or
- cyclic, optionally alkyl-substituted aliphatics, such as cyclohexane or methylcyclopentane, or
- mixtures thereof, such as solvents of the Exxsol® D series, Isopar® series or Bayol® series, for example Bayol® 82 (ExxonMobil Chemicals), or the Isane® IP series or Hydroseal® G series (TotalFinaElf),
- 1c) Mixtures of aromatic and aliphatic hydrocarbons, such as solvents of the Solvesso® series, for example Solvesso® 100, Solvesso® 150 or Solvesso® 200 (ExxonMobil Chemicals), of the Solvarex®/Solvaro® series (TotalFinaEif) or the Caromax® series, for example Caromax® 28 (Petrochem Carless), or
- 1d) halogenated hydrocarbons, such as halogenated aromatic and aliphatic hydrocarbons, such as chlorobenzene or methylene chloride, or
- 2) aprotic polar solvents, such as ethers, esters of C1-C9-alkanoic acids which may be mono-, di- or polyfunctional, such as their mono-, di- or triesters, for example with C1-C18-alkyl alcohols, ketones with a low tendency to tautomerize, phosphoric acid esters, amides, nitriles or sulfones, for example diisobutyl adipate, Rhodiasolv® RPDE (Rhodia), cyclohexanone, Jeffsol® PC (Huntsman), γ-butyrolactone, N-methylpyrrolidone, dimethyl sulfoxide, acetonitrile, tributylphosphatam or the Hostarex® PO series (Clariant), or
- 3) fatty acid esters, for example of natural origin, for example natural oils, such as animal oils or vegetable oils, or of synthetic origin, for example the Edenor® series, for example Edenor® MEPa or Edenor® MESU, or the Agnique® ME series or Agnique® AE series (Cognis), the Salim® ME series (Salim), the Radia® series, for example Radia® 30167 (ICS), the Prilube® series, for example Prilube® 1530 (Petrofina), the Stepan® C series (Stepan) or the Witconol® 23 series (Witco). The fatty acid esters are preferably esters of C10-C22—, with preference C12-C20—, fatty acids. The C10-C22-fatty acid esters are, for example, esters of unsaturated or saturated C10-C22-fatty acids, in particular those having an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid, and in particular C18-fatty acids, such as stearic acid, oleic acid, linoleic acid or linolenic acid.
- Examples of fatty acid esters such as C10-C22-fatty acid esters are glycerol and glycol esters of fatty acids such as C10-C22-fatty acids, or transesterification products thereof, for example fatty acid alkyl esters such as C10-C22-fatty acid C1-C20-alkyl esters, which can be obtained, for example, by transesterification of the abovementioned glycerol or glycol fatty acid esters such as C10-C22-fatty acid esters with C1-C20-alcohols (for example methanol, ethanol, propanol or butanol). The transesterification can be carried out by known methods, as described, for example, in Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
- Preferred fatty acid alkyl esters such as C10-C22-fatty acid C1-C20-alkyl esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethylhexyl esters and dodecyl esters. Preferred glycol and glycerol fatty acid esters such as C10-C22-fatty acid esters are the uniform or mixed glycol esters and glycerol esters of C10-C22-fatty acids, in particular of such fatty acids having an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C18-fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
- Animal oils are generally known and commercially available. For the purpose of the present invention, the term “animal oils” is to be understood as meaning, for example, oils of animal origin such as whale oil, cod-liver oil, musk oil or mink oil.
- Vegetable oils are generally known and commercially available. For the purpose of the present invention, the term “vegetable oils” is to be understood as meaning, for example, oils of oleaginous plant species, such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, thistle oil, walnut oil, arachis oil, olive oil or castor oil, in particular rapeseed oil, where the vegetable oils also include their transesterification products, for example alkyl esters, such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
- The vegetable oils are preferably esters of C10-C22—, preferably C12-C20—, fatty acids. The C10-C22-fatty acid esters are, for example, esters of unsaturated or saturated C10-C22-fatty acids having, in particular, an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C18-fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
- Examples of vegetable oils are C10-C22-fatty acid esters of glycerol or glycol with C10-C22-fatty acids, or C10-C22-fatty acid C1-C20-alkyl esters which can be obtained, for example, by transesterification of the glycerol or glycol C10-C22-fatty acid esters mentioned above with C1-C20-alcohols (for example methanol, ethanol, propanol or butanol). The transesterification can be carried out by known methods as described, for example, in Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
- The vegetable oils can be contained in the mixtures for example in the form of commercially available vegetable oils, in particular rapeseed oils, such as rapeseed oil methyl ester, for example Phytorob® B (Novance, France), Edenor® MESU and the Agnique® ME series (Cognis, Germany) the Radia® series (ICI), the Prilube® series (Petrofina), or biodiesel or in the form of commercially available plant-oil-containing formulation additives, in particular those based on rapeseed oils, such as rapeseed oil methyl esters, for example Hasten® (Victoria Chemical Company, Australia, hereinbelow referred to as Hasten, main ingredient; rapeseed oil ethyl ester), Actirob® B (Novance, France, hereinbelow referred to as Actirob B, main ingredient: rapeseed oil methyl ester), Rako-Binol® (Bayer AG, Germany, hereinbelow referred to as Rako-Binol®, main ingredient: rapeseed oil), Renol® (Stefes, Germany, hereinbelow referred to as Renol, vegetable oil ingredient: rapeseed oil methyl ester) or stefes Mero® (Stefes, Germany, hereinbelow referred to as mero, main ingredient: rapeseed oil methyl ester).
- Examples of synthetic acid esters are, for example, those derived from fatty acids having an odd number of carbon atoms, such as C11-C21-fatty acid esters.
- Preferred organic solvents are hydrocarbons, in particular aromatic hydrocarbons and/or aliphatic hydrocarbons and fatty acid esters, such as vegetable oils, such as triglycerides of fatty acids having 10 to 22 carbon atoms, which may be saturated or else unsaturated, straight-chain or branched and which may or may not carry further functional groups, such as corn oil, rapeseed oil, sunflower oil, cottonseed oil, linseed oil, soybean oil, coconut oil, palm oil, thistle oil or castor oil, and their transesterification products, such as fatty acid alkyl esters, and mixtures thereof.
- The solvents may be present on their own or as a mixture. The solubilizing power of the solvent or solvent mixture used for the sulfonylurea(s) used (component A) is preferably low.
- The total proportion of solvents in the herbicidal compositions according to the invention is generally between 0 and 95% by weight, preferably in the range between 20 and 80% by weight. The proportion of polar solvents such as aprotic polar solvents is generally below 20% by weight, preferably in the range from 0 to 10% by weight.
- The sulfosuccinates (component D) optionally present in the herbicidal compositions according to the invention can, for example, be mono- or diesters of sulfosuccinic acid, preferably those of the formula (III)
-
R1—(X1)n—O—CO—CH2—CH(SO3M)-CO—O—(X2)m—R2 (III) - in which
- R1 is H or an unsubstituted or substituted C1-C30-hydrocarbon radical, such as C1-C30-alkyl or C7-C30-alkylaryl,
- R2 is H or an unsubstituted or substituted C1-C30-hydrocarbon radical, such as C1-C30-alkyl or C7-C30-alkylaryl, or a cation, for example a metal cation, such as an alkali metal or alkaline earth metal cation, or an ammonium cation, such as NH4 or an alkyl, alkylaryl or poly(arylalkyl)phenylammonium cation,
- X1, X2 are identical or different and independently of one another are a spacer unit, such as a polyether unit or a polyester unit,
- n, m are identical or different and independently of one another are zero or 1, preferably zero, and
- M is a cation, for example a metal cation, such as an alkali metal or alkaline earth metal cation, or an ammonium cation, such as NH4 or an alkyl-, alkylaryl- or poly(arylalkyl)phenylammonium cation.
- Preference is given to sulfosuccinates of the formula (III) in which R1 and R2 are identical or different and independently of one another are straight-chain, branched or cyclic, saturated or unsaturated C1-C20—, preferably C4-C18—, alkyl radicals, such as methyl, ethyl, butyl, hexyl, cyclohexyl, octyl, such as 2-ethylhexyl, decyl, tridecyl or octadecyl radicals, or R1 and R2 are C7-C20-alkylaryl radicals, such as nonylphenyl, 2,4,6-tri-sec-butylphenyl, 2,4,6-tris-(1-phenylethyl)phenyl, alkylbenzyl or a hydroxycinnamic radical,
- X1 and X2 are identical or different and independently of one another are polyether units, such as polyethylene glycols —(C2H4O)p— or polypropyleneglycols (C3H6O)p— where p=1 to p=20, in particular p=1 to p=12, or polyester units, such as polyhydroxybutyric acid —(CH[CH3]-CH2—COO)q— or polylactic acid —(CH[CH3]-COO)q— where q=1 to q=15, in particular q=1 to q=8,
n, m are identical or different and independently of one another are zero or 1, preferably zero, and M is a cation, for example a metal cation, such as an alkali metal or alkaline earth metal cation, or an ammonium cation which may be alkyl-substituted. - Examples of sulfosuccinates which are preferably present are
- a1) sulfosuccinate which is esterified once or twice with straight-chain, cyclic or branched aliphatic, cycloaliphatic and/or aromatic alcohols, having, for example, 1 to 22 carbon atoms in the alkyl radical, preferably mono- or dialkali metal sulfosuccinate, in particular mono- or disodium sulfosuccinate, which is esterified once or twice with methanol, ethanol, (iso)propanol, (iso)butanol, (iso)pentanol, (iso)hexanol, cyclohexanol, (iso)heptanol, (iso)octanol (in particular: ethylhexanol), (iso)nonanol, (iso)decanol, (iso)undecanol, (iso)dodecanol or (iso)tridecanol,
- a2) sulfosuccinate which is esterified once or twice with (poly)alkylene oxide adducts of alcohols, having, for example, 1 to 22 carbon atoms in the alkyl radical and 1 to 200, preferably 2 to 200, alkylene oxide units in the (poly)alkylene oxide moiety, preferably mono- or dialkali metal sulfosuccinate, in particular mono- or disodium sulfosuccinate, which is esterified once or twice with dodecyl/tetradecyl alcohol+2-5 mol of ethylene oxide or with i-tridecyl+3 mol of ethylene oxide,
- a3) the dialkali metal salt, preferably the disodium salt, of maleic anhydride which has been reacted with one equivalent of an amine or an amino-terminated (poly)alkylene oxide adduct of an alcohol, an amine, a fatty acid, an ester or an amide and then sulfonated, having, for example, 1 to 22 carbon atoms in the alkyl radical and 1 to 200, preferably 2 to 200, oxyalkylene units in the (poly)alkylene oxide moiety, preferably the disodium salt of maleic anhydride which has been reacted with one equivalent of coconut fatty amine and then sulfonated,
- a4) the dialkali metal salt, preferably the disodium salt, of maleic anhydride which has been reacted with one equivalent of an amide or a (poly)alkylene oxide adduct of an amide and then sulfonated, having, for example, 1 to 22 carbon atoms in the alkyl radical and 1 to 200, preferably 2 to 200, oxyalkylene units in the (poly)alkylene oxide moiety, preferably the disodium salt of maleic anhydride which has been reacted with one equivalent of oleylamide+2 mol of ethylene oxide and then sulfonated, and/or
- a5) the tetraalkali metal salt, preferably the tetrasodium salt, of N-(1,2-dicarboxyethyl)-N-octadecylsulfosuccinamate.
- Examples of sulfosuccinates of groups a1) to a5) which are commercially available and preferred within the context of the present invention are listed below:
- a1) sodium dialkylsulfosuccinate, for example sodium di(C4-C18)alkylsulfosuccinate, such as sodium diisooctylsulfosuccinate, preferably sodium di(2-ethylhexyl)sulfosuccinate, commercially available, for example, in the form of the Aerosol® brands (Cytec), the Agrilan® or Lankropol® brands (Akzo Nobel), the Empimin® brands (Albright&Wilson), the Cropol® brands (Croda), the Lutensit® brands (BASF), the Triton® brands (Union Carbide), the Geropon® brands (Rhodia) or the Imbirol®, Madeol® or Polirol® brands (Cesalpinia),
- a2) sodium alcohol polyethylene glycol ether sulfosuccinate, commercially available, for example, in the form of Geropon® ACR brands (Rhodia),
- a3) disodium alcohol polyethylene glycol ether semisulfosuccinate, commercially available, for example, in the form of the Aerosol® brands (Cytec), the Marlinat® or Sermul® brands (Condea), the Empicol® brands (Albright&Wilson), the Secosol® brands (Stepan), the Geropon® brands (Rhodia), the Disponil® or Texapon® brands (Cognis) or the Rolpon® brands (Cesalpinia),
- a4) disodium N-alkylsulfosuccinamate, commercially available, for example, in the form of the Aerosol® brands (Cytec), the Rewopol® or Rewoderm® brands (Rewo), the Empimin® brands (Albright&Wilson), the Geropon® brands (Rhodia) or the Polirol® brands (Cesalpinia),
- a5) disodium fatty acid amide polyethylene glycol ether semisulfosuccinate, commercially available, for example, in the form of the Elfanol® or Lankropol® brands (Akzo Nobel), the Rewoderm®, Rewocid® or Rewopol® brands (Rewo), the Emcol® brands (Witco), the Standapol® brands (Cognis) or the Rolpon® brands (Cesalpinia), and
- a6) tetrasodium N-(1,2-dicarboxyethyl)-N-octadecylsulfosuccinamate, commercially available, for example, in the form of Aerosol 22® (Cytec).
- Commercially, sulfosuccinates are obtainable, for example, as the Aerosol® (Cytec), Agrilan® or Lankropol® (Akzo Nobel), Empimin® (Huntsman), Cropol® (Croda), Lutensit® (BASF), Triton® GR series (UnionCarbide), Imbirol®/Madeol®/Polirol® (Cesalpinia); Geropon® AR series or Geropon® SDS (Rhodia).
- Preferred sulfosuccinates are, for example, the sodium, potassium and ammonium salts of bis(alkyl)sulfosuccinates, where the alkyl radicals may be identical or different and contain 4 to 16 carbon atoms and are preferably butyl, hexyl, octyl, such as 2-ethylhexyl, or decyl radicals which may be straight-chain or branched.
- The total proportion of sulfosuccinate or sulfosuccinates in the herbicidal compositions according to the invention is generally between 0 and 60% by weight, in particular in the range between 0.5 and 30% by weight.
- Suitable optional agrochemically active compounds (E) different from (A) and (B) for the herbicidal compositions according to the invention are, for example, known active compounds, such as herbicides, insecticides or fungicides, as described, for example, in Weed Research 26, 441-445 (1986), or “The Pesticide Manual”, 12th edition, The British Crop Protection Council, 2000, and the literature cited therein, for example in mixed formulations or as a component for a tank mix. The following active compounds, for example, may be mentioned as herbicides known from the literature which may be present in the herbicidal compositions according to the invention. The compounds are referred to either by the “common name” of the International Organization for Standardization (ISO) or by the chemical name, if appropriate together with a customary code number, and include in each case all possible use forms, such as acids, salts, esters and isomers, such as stereoisomers and optical isomers: acetochlor; acifluorfen; aclonifen; AKH 7088, i.e. [[[1-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl]-2-methoxyethylidene]amino]oxy]-acetic acid and its methyl ester; alachlor; alloxydim; ametryn; amidosulfuron; amitrol; AMS, i.e. ammonium sulfamate; anilofos; asulam; atrazine; azafenidine (DPX-R6447), azimsulfuron (DPX-A8947); aziprotryn; barban; BAS 516 H, i.e. 5-fluoro-2-phenyl-4H-3,1-benzoxazin-4-one; benazolin; benfluralin; benfuresate; bensulfuron-methyl; bensulide; bentazone; benzofluor; benzoylprop-ethyl; benzthiazuron; bialaphos; bifenox; bispyribac-sodium (KIH-2023), bromacil; bromobutide; bromofenoxim; bromoxynil, in particular bromoxynil-octanoate and bromoxynil-heptanoate; butachlor; butamifos; butenachlor; buthidazole; butralin; butroxydim (ICI-0500), butylate; cafenstrole (CH-900); carbetamide; cafentrazone; CDAA, i.e. 2-chloro-N,N-di-2-propenylacetamide; CDEC, i.e. 2-chloroallyl diethyldithiocarbamate; chlomethoxyfen; chloramben; chloransulam-methyl (XDE-565), chlorazifop-butyl, chlorbromuron; chlorbufam; chlorfenac; chlorflurecol-methyl; chloridazon; chlorimuron ethyl; chlornitrofen; chlorotoluron; chloroxuron; chlorpropham; chlorthal-dimethyl; chlorthiamid; cinidon-ethyl, cinmethylin; cinosulfuron; clethodim; clodinafop and its ester derivatives (for example clodinafop-propargyl); clomazone; clomeprop; cloproxydim; clopyralid; cumyluron (JC 940); cyanazine; cycloate; cyclosulfamuron (AC 014); cycloxydim; cycluron; cyhalofop and its ester derivatives (for example butyl ester, DEH-112); cyperquat; cyprazine; cyprazole; 2,4-D; 2,4-DB; dalapon; desmedipham; desmetryn; di-allate; dicamba; dichlobenil; dichlorprop; diclofop and its esters such as diclofop-methyl; diclosulam (XDE-564), diethatyl; difenoxuron; difenzoquat; diflufenican; diflufenzopyr-sodium (SAN-835H), dimefuron; dimethachlor; dimethametryn; dimethenamide (SAN-582H); dimidazon, methyl 5-(4,6-dimethylpyrimidin-2-yl-carbamoylsulfamoyl)-1-(2-pyridyl)pyrazole-4-carboxylate (NC-330); triaziflam (IDH-1105), cinosulfon; dimethipin; dinitramine; dinoseb; dinoterb; diphenamid; dipropetryn; diquat; dithiopyr; diuron; DNOC; eglinazine-ethyl; EL 177, i.e. 5-cyano-1-(1,1-dimethylethyl)-N-methyl-1H-pyrazole-4-carboxamide; endothal; indanofan (MK-243), EPTC; esprocarb; ethalfluralin; ethametsulfuron-methyl; ethidimuron; ethiozin; ethofumesate; F5231, i.e. N-[2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1-yl]phenyl]ethanesulfonamide; ethoxyfen and its ester (for example ethyl ester, HN-252); ethoxysulfuron (from EP 342569); etobenzanid (HW 52); 3-(4-ethoxy-6-ethyl-1,3,5-triazin-2-yl)-1-(2,3-dihydro-1,1-dioxo-2-methylbenzo[b]thiophene-7-sulfonyl)urea (EP-A 079 683); 3-(4-ethyl-6-methoxy-1,3,5-triazin-2-yl)-1-(2,3-dihydro-1,1-dioxo-2-methylbenzo[b]thiophene-7-sulfonylurea (EP-A 079 683); fenoprop; clomazone, fenoxaprop and fenoxaprop-P and their esters, for example fenoxaprop-P-ethyl and fenoxaprop-ethyl; butroxydim; fenuron; flamprop-methyl; flazasulfuron; flufenacet (BAY-FOE-5043), fluazifop and fluazifop-P and their esters, for example fluazifop-butyl and fluazifop-P-butyl, florasulam (DE-570); fluchloralin; flumetsulam; flumeturon; flumiclorac and its esters (for example pentyl ester, S-23031); flumioxazin (S-482); flumipropyn; flupoxam (KNW-739); fluorodifen; fluoroglycofen-ethyl; flupropacil (UBIC-4243); sodium flupyrsulfuron-methyl (DPX-KE459), fluridone; fluorochloridone; fluoroxypyr; flurtamone; fluthiacet-methyl (KIH-9201), fomesafen; fosamine; furyloxyfen; glufosinate; glyphosate; halosafen; halosulfuron and its esters (for example methyl ester, NC-319); haloxyfop and its esters; haloxyfop-P (=R-haloxyfop) and its esters; hexazinone; imazamethabenz-methyl; imazamox (AC-299263), imazapyr; imazaquin and salts such as the ammonium salt; imazapic; imazethapyr; imazosulfuron; iodosulfuron-methyl-sodium (methyl 4-iodo-2-[3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulfonyl]benzoate, sodium salt, WO 92/13845); ioxynil; isocarbamid; isopropalin; isoproturon; isouron; isoxaben; isoxapyrifop; karbutilate; lactofen; lenacil; linuron; MCPA; MCPB; mecoprop; mefenacet; mefluidid; metamitron; metazachlor; methabenzthiazuron; metham; methazole; methoxyphenone; methyldymron; metobenzuron, mesosulfuron-methyl (WO 95/10507); metobenzuron; metobromuron; metolachlor; S-metolachlor, metosulam (XRD 511); metoxuron; metribuzin; maleic hydrazide; molinate; monalide; monocarbamide dihydrogensulfate; monolinuron; monuron; MT 128, i.e. 6-chloro-N-(3-chloro-2-propenyl)-5-methyl-N-phenyl-3-pyridazinamine; MT 5950, i.e. N-[3-chloro-4-(1-methylethyl)phenyl]-2-methylpentanamide; foramsulfuron (WO 95/01344); naproanilide; napropamide; naptalam; NC 310, i.e. 4-(2,4-dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole; neburon; nicosulfuron; nipyraclofen; nitralin; nitrofen; nitrofluorfen; norflurazon; orbencarb; oryzalin; oxadiargyl (RP-020630); oxadiazon; oxaziclomefone (MY-100), oxyfluorfen; oxasulfuron (CGA-277476), paraquat; pebulate; pendimethalin; pentoxazone (KPP-314), perfluidone; phenisopham; phenmedipham; picloram; piperophos; piributicarb; pirifenop-butyl; pretilachlor; primisulfuron-methyl; procyazine; prodiamine; profluralin; proglinazine-ethyl; prometon; prometryn; propachlor; propanil; propaquizafop and its esters; propazine; propham; propisochlor; propoxycarbazone-sodium; propyzamide; prosulfalin; prosulfocarb; prosulfuron (CGA-152005); prynachlor; pyraflufen-ethyl (ET-751), chloridazon; pyrazosulfuron-ethyl; pyrazoxyfen; pyribenzoxim, pyridate; pyriminobac-methyl (KIH-6127), pyrithiobac (KIH-2031); pyroxofop and its esters (for example propargyl ester); quinclorac; quinmerac; quizalofop and quizalofop-P and their ester derivatives, for example quizalofop-ethyl; quizalofop-P-tefuryl and -ethyl; rimsulfuron (DPX-E 9636); S 275, i.e. 2-[4-chloro-2-fluoro-5-(2-propynyloxy)phenyl]-4,5,6,7-tetrahydro-2H-indazole; secbumeton; sethoxydim; siduron; simazine; simetryn; SN 106279, i.e. 2-[[7-[2-chloro-4-(trifluoromethyl)phenoxy]-2-naphthalenyl]oxy]propanoic acid and its methyl ester; sulfentrazone (FMC-97285, F-6285); sulfazuron; sulfometuron-methyl; glyphosate-trimesium (ICI-A0224); sulfosulfuron (MON-37500), TCA; tebutam (GCP-5544); tebuthiuron; tepraloxydim (BAS-620H), terbacil; terbucarb; terbuchlor; terbumeton; terbuthylazine; terbutryn; TFH 450, i.e. N,N-diethyl-3-[(2-ethyl-6-methylphenyl)sulfonyl]-1H-1,2,4-triazole-1-carboxamide; thenylchlor (NSK-850); thiazafluoron; thiazopyr (Mon-13200); thidiazimin (SN-124085); thiobencarb; thiocarbazil; tralkoxydim; tri-allate; triasulfuron; triazofenamide; triciopyr; tridiphane; triefazine; trifluralin; triflusulfuron and esters (for example methyl ester, DPX-66037); trimeturon; tsitodef; vernolate; WL 110547, i.e. 5-phenoxy-1-[3-(trifluoromethyl)phenyl]-1H-tetrazole; UBH-509; D-489; LS 82-556; KPP-300; KPP-421, MT-146, NC-324; butenachlor (KH-218); DPX-N8189; haloxyfop-etotyl (DOWCO-535); DK-8910; flumioxazin (V-53482); PP-600; MBH-001,
- amicarbazone, aminopyralid, beflubutamid, benzobicyclon, benzofenap, benzfendizone, butafenacil, chlorfenprop, cloprop, daimuron, dichlorprop-P, dimepipeate, dimethenamid-P, fentrazamide, flamprop-M, fluazolate, flucarbazone, flucetosulfuron, foramsulfuron, indanofan, isoxachlortole, isoxaflutole, MCPA-thioethyl, mecoprop-P, mesosulfuron, mesotrione, mefamifop, orthosulfamuron (IR-5878), penoxsulam, pethoxamid, picolinafen, pinoxaden, profluazol, profoxydim, propoxycarbazone, pyraclonil, pyrazolynate, pyridafol, pyriftalid, pyrimisulfan, sulcotrione, thidiazuron, topramezons, trifloxysulfuron, tritosulfuron.
- The mixing partners E), the sulfonylureas A) and the safeners B) can be applied together (as a readymix or as a tank mix) or successively in any sequence.
- Preferred mixing partners E) are bromoxynil (E1) in all of its use forms, including the salts and esters, for example bromoxynil-octanoate (E1.1), bromoxynil-heptanoate (E1.2), bromoxynil-butyrate (E1.3), bromoxynil-sodium (E1.4) and bromoxynil-potassium (E1.5); 2,4-D (E2) in all of its use forms, including the salts and esters, for example 2,4-D-butotyl (E2.1), 2,4-D-butyl (E2.2), 2,4-D-dimethylammonium (E2.3), 2,4-D-diethanolamine (E2.4), 2,4-D-2-ethylhexyl (E2.5), 2,4-D-isooctyl (E2.6), 2,4-D-isopropyl (E2.7), 2,4-D-sodium (E2.8) and 2,4-D-triethanolamine (E2.9); dicamba (E3) in all of its use forms, including the salts and esters, for example dicamba-sodium (E3.1), dicamba-potassium (E3.2) and dicamba-dimethylammonium (E3.3); fenoxaprop (E4) in all of its use forms, including the esters, for example fenoxaprop-ethyl (E4.1) and fenoxaprop-P-ethyl (E4.2); fluoroxypyr (E5) in all of its use forms, including the salts and esters, for example fluoroxypyr-meptyl (E5.1) and fluoroxypyr-2-butoxy-1-methylethyl (E5.2); MCPA (E6) in all of its use forms, including the salts and esters, for example MCPA-sodium (E6.1), MCPA-potassium (E6.2), MCPA-2-ethylhexyl (E6.3), MCPA-butotyl (E6.4) and MCPA-dimethylammonium (E6.5); iodosulfuron (E7) in all of its use forms, including the salts and esters, for example iodosulfuron-methyl (E7.1) and iodosulfuron-methyl-sodium (E7.2); mesosulfuron (E8) in all of its use forms, including the salts and esters, for example mesosulfuron-methyl (E8.1) and mesosulfuron-methyl-sodium (E8.2); propoxycarbazone (E9) in all of its use forms, including the salts and esters, for example propoxycarbazone-sodium (E9.1).
- Preferred combinations (A), (B), (E) according to the invention are, for example:
- (E1)+(A1.1)+(B1), (E1)+(A1.1)+(B2), (E1)+(A1.1)+(B3), (E1)+(A2.1)+(B1), (E1)+(A2.1)+(B2), (E1)+(A2.1)+(B3), (E1)+(A3.1)+(B1), (E1)+(A3.1)+(B2), (E1)+(A3.1)+(B3), (E1)+(A4.1)+(B1), (E1)+(A4.1)+(B2), (E1)+(A4.1)+(B3), (E1)+(A1.2)+(B1), (E1)+(A1.2)+(B2), (E1)+(A1.2)+(B3), (E1)+(A2.2)+(B1), (E1)+(A2.2)+(B2), (E1)+(A2.2)+(B3), (E1)+(A3.2)+(B1), (E1)+(A3.2)+(B2), (E1)+(A3.2)+(B3), (E1)+(A4.2)+(B1), (E1)+(A4.2)+(B2), (E1)+(A4.2)+(B3), (E1)+(A1.1)+(A1.2)+(B1), (E1)+(A1.1)+(A2.1)+(B1), (E1)+(A1.1)+(A2.2)+(B1), (E1)+(A1.1)+(A3.1)+(B1), (E1)+(A1.1)+(A3.2)+(B1), (E1)+(A1.1)+(A4.1)+(B1), (E1)+(A1.1)+(A4.2)+(B1);
- (E1.1)+(A1.1)+(B1), (E1.1)+(A1.1)+(B2), (E1.1)+(A1.1)+(B3), (E1.1)+(A2.1)+(B1), (E1.1)+(A2.1)+(B2), (E1.1)+(A2.1)+(B3), (E1.1)+(A3.1)+(B1), (E1.1)+(A3.1)+(B2), (E1.1)+(A3.1)+(B3), (E1.1)+(A4.1)+(B1), (E1.1)+(A4.1)+(B2), (E1.1)+(A4.1)+(B3), (E1.1)+(A1.2)+(B1), (E1.1)+(A1.2)+(B2), (E1.1)+(A1.2)+(B3), (E1.1)+(A2.2)+(B1), (E1.1)+(A2.2)+(B2), (E1.1)+(A2.2)+(B3), (E1.1)+(A3.2)+(B1), (E1.1)+(A3.2)+(B2), (E1.1)+(A3.2)+(B3), (E1.1)+(A4.2)+(B1), (E1.1)+(A4.2)+(B2), (E1.1)+(A4.2)+(B3),
- (E1.2)+(A1.1)+(B1), (E1.2)+(A1.1)+(B2), (E1.2)+(A1.1)+(B3), (E1.2)+(A2.1)+(B1), (E1.2)+(A2.1)+(B2), (E1.2)+(A2.1)+(B3), (E1.2)+(A3.1)+(B1), (E1.2)+(A3.1)+(B2), (E1.2)+(A3.1)+(B3), (E1.2)+(A4.1)+(B1), (E1.2)+(A4.1)+(B2), (E1.2)+(A4.1)+(B3), (E1.2)+(A1.2)+(B1), (E1.2)+(A1.2)+(B2), (E1.2)+(A1.2)+(B3), (E1.2)+(A2.2)+(B1), (E1.2)+(A2.2)+(B2), (E1.2)+(A2.2)+(B3), (E1.2)+(A3.2)+(B1), (E1.2)+(A3.2)+(B2), (E1.2)+(A3.2)+(B3), (E1.2)+(A4.2)+(B1), (E1.2)+(A4.2)+(B2), (E1.2)+(A4.2)+(B3), (E1.2)+(A1.1)+(A1.2)+(B1), (E1.2)+(A1.1)+(A2.1)+(B1), (E1.2)+(A1.1)+(A2.2)+(B1), (E1.2)+(A1.1)+(A3.1)+(B1), (E1.2)+(A1.1)+(A3.2)+(B1), (E1.2)+(A1.1)+(A4.1)+(B1), (E1.2)+(A1.1)+(A4.2)+(B1);
- (E1.3)+(A1.1)+(B1), (E1.3)+(A1.1)+(B2), (E1.3)+(A1.1)+(B3), (E1.3)+(A2.1)+(B1), (E1.3)+(A2.1)+(B2), (E1.3)+(A2.1)+(B3), (E1.3)+(A3.1)+(B1), (E1.3)+(A3.1)+(B2), (E1.3)+(A3.1)+(B3), (E1.3)+(A4.1)+(B1), (E1.3)+(A4.1)+(B2), (E1.3)+(A4.1)+(B3), (E1.3)+(A1.2)+(B1), (E1.3)+(A1.2)+(B2), (E1.3)+(A1.2)+(B3), (E1.3)+(A2.2)+(B1), (E1.3)+(A2.2)+(B2), (E1.3)+(A2.2)+(B3), (E1.3)+(A3.2)+(B1), (E1.3)+(A3.2)+(B2), (E1.3)+(A3.2)+(B3), (E1.3)+(A4.2)+(B1), (E1.3)+(A4.2)+(B2), (E1.3)+(A4.2)+(B3),
- (E1.4)+(A1.1)+(B1), (E1.4)+(A1.1)+(B2), (E1.4)+(A1.1)+(B3), (E1.4)+(A2.1)+(B1), (E1.4)+(A2.1)+(B2), (E1.4)+(A2.1)+(B3), (E1.4)+(A3.1)+(B1), (E1.4)+(A3.1)+(B2), (E1.4)+(A3.1)+(B3), (E1.4)+(A4.1)+(B1), (E1.4)+(A4.1)+(B2), (E1.4)+(A4.1)+(B3), (E1.4)+(A1.2)+(B1), (E1.4)+(A1.2)+(B2), (E1.4)+(A1.2)+(B3), (E1.4)+(A2.2)+(B1), (E1.4)+(A2.2)+(B2), (E1.4)+(A2.2)+(B3), (E1.4)+(A3.2)+(B1), (E1.4)+(A3.2)+(B2), (E1.4)+(A3.2)+(B3), (E1.4)+(A4.2)+(B1), (E1.4)+(A4.2)+(B2), (E1.4)+(A4.2)+(B3),
- (E1.5)+(A1.1)+(B1), (E1.5)+(A1.1)+(B2), (E1.5)+(A1.1)+(B3), (E1.5)+(A2.1)+(B1), (E1.5)+(A2.1)+(B2), (E1.5)+(A2.1)+(B3), (E1.5)+(A3.1)+(B1), (E1.5)+(A3.1)+(B2), (E1.5)+(A3.1)+(B3), (E1.5)+(A4.1)+(B1), (E1.5)+(A4.1)+(B2), (E1.5)+(A4.1)+(B3), (E1.5)+(A1.2)+(B1), (E1.5)+(A1.2)+(B2), (E1.5)+(A1.2)+(B3), (E1.5)+(A2.2)+(B1), (E1.5)+(A2.2)+(B2), (E1.5)+(A2.2)+(B3), (E1.5)+(A3.2)+(B1), (E1.5)+(A3.2)+(B2), (E1.5)+(A3.2)+(B3), (E1.5)+(A4.2)+(B1), (E1.5)+(A4.2)+(B2), (E1.5)+(A4.2)+(B3),
- (E2)+(A1.1)+(B1), (E2)+(A1.1)+(B2), (E2)+(A1.1)+(B3), (E2)+(A2.1)+(B1), (E2)+(A2.1)+(B2), (E2)+(A2.1)+(B3), (E2)+(A3.1)+(B1), (E2)+(A3.1)+(B2), (E2)+(A3.1)+(B3), (E2)+(A4.1)+(B1), (E2)+(A4.1)+(B2), (E2)+(A4.1)+(B3), (E2)+(A1.2)+(B1), (E2)+(A1.2)+(B2), (E2)+(A1.2)+(B3), (E2)+(A2.2)+(B1), (E2)+(A2.2)+(B2), (E2)+(A2.2)+(B3), (E2)+(A3.2)+(B1), (E2)+(A3.2)+(B2), (E2)+(A3.2)+(B3), (E2)+(A4.2)+(B1), (E2)+(A4.2)+(B2), (E2)+(A4.2)+(B3), (E2)+(A1.1)+(A1.2)+(B1), (E2)+(A1.1)+(A2.1)+(B1), (E2)+(A1.1)+(A2.2)+(B1), (E2)+(A1.1)+(A3.1)+(B1), (E2)+(A1.1)+(A3.2)+(B1), (E2)+(A1.1)+(A4.1)+(B1), (E2)+(A1.1)+(A4.2)+(B1);
- (E2.1)+(A1.1)+(B1), (E2.1)+(A1.1)+(B2), (E2.1)+(A1.1)+(B3), (E2.1)+(A2.1)+(B1), (E2.1)+(A2.1)+(B2), (E2.1)+(A2.1)+(B3), (E2.1)+(A3.1)+(B1), (E2.1)+(A3.1)+(B2), (E2.1)+(A3.1)+(B3), (E2.1)+(A4.1)+(B1), (E2.1)+(A4.1)+(B2), (E2.1)+(A4.1)+(B3), (E2.1)+(A1.2)+(B1), (E2.1)+(A1.2)+(B2), (E2.1)+(A1.2)+(B3), (E2.1)+(A2.2)+(B1), (E2.1)+(A2.2)+(B2), (E2.1)+(A2.2)+(B3), (E2.1)+(A3.2)+(B1), (E2.1)+(A3.2)+(B2), (E2.1)+(A3.2)+(B3), (E2.1)+(A4.2)+(B1), (E2.1)+(A4.2)+(B2), (E2.1)+(A4.2)+(B3),
- (E2.2)+(A1.1)+(B1), (E2.2)+(A1.1)+(B2), (E2.2)+(A1.1)+(B3), (E2.2)+(A2.1)+(B1), (E2.2)+(A2.1)+(B2), (E2.2)+(A2.1)+(B3), (E2.2)+(A3.1)+(B1), (E2.2)+(A3.1)+(B2), (E2.2)+(A3.1)+(B3), (E2.2)+(A4.1)+(B1), (E2.2)+(A4.1)+(B2), (E2.2)+(A4.1)+(B3), (E2.2)+(A1.2)+(B1), (E2.2)+(A1.2)+(B2), (E2.2)+(A1.2)+(B3), (E2.2)+(A2.2)+(B1), (E2.2)+(A2.2)+(B2), (E2.2)+(A2.2)+(B3), (E2.2)+(A3.2)+(B1), (E2.2)+(A3.2)+(B2), (E2.2)+(A3.2)+(B3), (E2.2)+(A4.2)+(B1), (E2.2)+(A4.2)+(B2), (E2.2)+(A4.2)+(B3),
- (E2.3)+(A1.1)+(B1), (E2.3)+(A1.1)+(B2), (E2.3)+(A1.1)+(B3), (E2.3)+(A2.1)+(B1), (E2.3)+(A2.1)+(B2), (E2.3)+(A2.1)+(B3), (E2.3)+(A3.1)+(B1), (E2.3)+(A3.1)+(B2), (E2.3)+(A3.1)+(B3), (E2.3)+(A4.1)+(B1), (E2.3)+(A4.1)+(B2), (E2.3)+(A4.1)+(B3), (E2.3)+(A1.2)+(B1), (E2.3)+(A1.2)+(B2), (E2.3)+(A1.2)+(B3), (E2.3)+(A2.2)+(B1), (E2.3)+(A2.2)+(B2), (E2.3)+(A2.2)+(B3), (E2.3)+(A3.2)+(B1), (E2.3)+(A3.2)+(B2), (E2.3)+(A3.2)+(B3), (E2.3)+(A4.2)+(B1), (E2.3)+(A4.2)+(B2), (E2.3)+(A4.2)+(B3),
- (E2.4)+(A1.1)+(B1), (E2.4)+(A1.1)+(B2), (E2.4)+(A1.1)+(B3), (E2.4)+(A2.1)+(B1), (E2.4)+(A2.1)+(B2), (E2.4)+(A2.1)+(B3), (E2.4)+(A3.1)+(B1), (E2.4)+(A3.1)+(B2), (E2.4)+(A3.1)+(B3), (E2.4)+(A4.1)+(B1), (E2.4)+(A4.1)+(B2), (E2.4)+(A4.1)+(B3), (E2.4)+(A1.2)+(B1), (E2.4)+(A1.2)+(B2), (E2.4)+(A1.2)+(B3), (E2.4)+(A2.2)+(B1), (E2.4)+(A2.2)+(B2), (E2.4)+(A2.2)+(B3), (E2.4)+(A3.2)+(B1), (E2.4)+(A3.2)+(B2), (E2.4)+(A3.2)+(B3), (E2.4)+(A4.2)+(B1), (E2.4)+(A4.2)+(B2), (E2.4)+(A4.2)+(B3),
- (E2.5)+(A1.1)+(B1), (E2.5)+(A1.1)+(B2), (E2.5)+(A1.1)+(B3), (E2.5)+(A2.1)+(B1), (E2.5)+(A2.1)+(B2), (E2.5)+(A2.1)+(B3), (E2.5)+(A3.1)+(B1), (E2.5)+(A3.1)+(B2), (E2.5)+(A3.1)+(B3), (E2.5)+(A4.1)+(B1), (E2.5)+(A4.1)+(B2), (E2.5)+(A4.1)+(B3), (E2.5)+(A1.2)+(B1), (E2.5)+(A1.2)+(B2), (E2.5)+(A1.2)+(B3), (E2.5)+(A2.2)+(B1), (E2.5)+(A2.2)+(B2), (E2.5)+(A2.2)+(B3), (E2.5)+(A3.2)+(B1), (E2.5)+(A3.2)+(B2), (E2.5)+(A3.2)+(B3), (E2.5)+(A4.2)+(B1), (E2.5)+(A4.2)+(B2), (E2.5)+(A4.2)+(B3),
- (E2.6)+(A1.1)+(B1), (E2.6)+(A1.1)+(B2), (E2.6)+(A1.1)+(B3), (E2.6)+(A2.1)+(B1), (E2.6)+(A2.1)+(B2), (E2.6)+(A2.1)+(B3), (E2.6)+(A3.1)+(B1), (E2.6)+(A3.1)+(B2), (E2.6)+(A3.1)+(B3), (E2.6)+(A4.1)+(B1), (E2.6)+(A4.1)+(B2), (E2.6)+(A4.1)+(B3), (E2.6)+(A1.2)+(B1), (E2.6)+(A1.2)+(B2), (E2.6)+(A1.2)+(B3), (E2.6)+(A2.2)+(B1), (E2.6)+(A2.2)+(B2), (E2.6)+(A2.2)+(B3), (E2.6)+(A3.2)+(B1), (E2.6)+(A3.2)+(B2), (E2.6)+(A3.2)+(B3), (E2.6)+(A4.2)+(B1), (E2.6)+(A4.2)+(B2), (E2.6)+(A4.2)+(B3),
- (E2.7)+(A1.1)+(B1), (E2.7)+(A1.1)+(B2), (E2.7)+(A1.1)+(B3), (E2.7)+(A2.1)+(B1), (E2.7)+(A2.1)+(B2), (E2.7)+(A2.1)+(B3), (E2.7)+(A3.1)+(B1), (E2.7)+(A3.1)+(B2), (E2.7)+(A3.1)+(B3), (E2.7)+(A4.1)+(B1), (E2.7)+(A4.1)+(B2), (E2.7)+(A4.1)+(B3), (E2.7)+(A1.2)+(B1), (E2.7)+(A1.2)+(B2), (E2.7)+(A1.2)+(B3), (E2.7)+(A2.2)+(B1), (E2.7)+(A2.2)+(B2), (E2.7)+(A2.2)+(B3), (E2.7)+(A3.2)+(B1), (E2.7)+(A3.2)+(B2), (E2.7)+(A3.2)+(B3), (E2.7)+(A4.2)+(B1), (E2.7)+(A4.2)+(B2), (E2.7)+(A4.2)+(B3),
- (E2.8)+(A1.1)+(B1), (E2.8)+(A1.1)+(B2), (E2.8)+(A1.1)+(B3), (E2.8)+(A2.1)+(B1), (E2.8)+(A2.1)+(B2), (E2.8)+(A2.1)+(B3), (E2.8)+(A3.1)+(B1), (E2.8)+(A3.1)+(B2), (E2.8)+(A3.1)+(B3), (E2.8)+(A4.1)+(B1), (E2.8)+(A4.1)+(B2), (E2.8)+(A4.1)+(B3), (E2.8)+(A1.2)+(B1), (E2.8)+(A1.2)+(B2), (E2.8)+(A1.2)+(B3), (E2.8)+(A2.2)+(B1), (E2.8)+(A2.2)+(B2), (E2.8)+(A2.2)+(B3), (E2.8)+(A3.2)+(B1), (E2.8)+(A3.2)+(B2), (E2.8)+(A3.2)+(B3), (E2.8)+(A4.2)+(B1), (E2.8)+(A4.2)+(B2), (E2.8)+(A4.2)+(B3),
- (E2.9)+(A1.1)+(B1), (E2.9)+(A1.1)+(B2), (E2.9)+(A1.1)+(B3), (E2.9)+(A2.1)+(B1), (E2.9)+(A2.1)+(B2), (E2.9)+(A2.1)+(B3), (E2.9)+(A3.1)+(B1), (E2.9)+(A3.1)+(B2), (E2.9)+(A3.1)+(B3), (E2.9)+(A4.1)+(B1), (E2.9)+(A4.1)+(B2), (E2.9)+(A4.1)+(B3), (E2.9)+(A1.2)+(B1), (E2.9)+(A1.2)+(B2), (E2.9)+(A1.2)+(B3), (E2.9)+(A2.2)+(B1), (E2.9)+(A2.2)+(B2), (E2.9)+(A2.2)+(B3), (E2.9)+(A3.2)+(B1), (E2.9)+(A3.2)+(B2), (E2.9)+(A3.2)+(B3), (E2.9)+(A4.2)+(B1), (E2.9)+(A4.2)+(B2), (E2.9)+(A4.2)+(B3),
- (E3)+(A1.1)+(B1), (E3)+(A1.1)+(B2), (E3)+(A1.1)+(B3), (E3)+(A2.1)+(B1), (E3)+(A2.1)+(B2), (E3)+(A2.1)+(B3), (E3)+(A3.1)+(B1), (E3)+(A3.1)+(B2), (E3)+(A3.1)+(B3), (E3)+(A4.1)+(B1), (E3)+(A4.1)+(B2), (E3)+(A4.1)+(B3), (E3)+(A1.2)+(B1), (E3)+(A1.2)+(B2), (E3)+(A1.2)+(B3), (E3)+(A2.2)+(B1), (E3)+(A2.2)+(B2), (E3)+(A2.2)+(B3), (E3)+(A3.2)+(B1), (E3)+(A3.2)+(B2), (E3)+(A3.2)+(B3), (E3)+(A4.2)+(B1), (E3)+(A4.2)+(B2), (E3)+(A4.2)+(B3), (E3)+(A1.1)+(A1.2)+(B1), (E3)+(A1.1)+(A2.1)+(B1), (E3)+(A1.1)+(A2.2)+(B1), (E3)+(A1.1)+(A3.1)+(B1), (E3)+(A1.1)+(A3.2)+(B1), (E3)+(A1.1)+(A4.1)+(B1), (E3)+(A1.1)+(A4.2)+(B1);
- (E3.1)+(A1.1)+(B1), (E3.1)+(A1.1)+(B2), (E3.1)+(A1.1)+(B3), (E3.1)+(A2.1)+(B1), (E3.1)+(A2.1)+(B2), (E3.1)+(A2.1)+(B3), (E3.1)+(A3.1)+(B1), (E3.1)+(A3.1)+(B2), (E3.1)+(A3.1)+(B3), (E3.1)+(A4.1)+(B1), (E3.1)+(A4.1)+(B2), (E3.1)+(A4.1)+(B3), (E3.1)+(A1.2)+(B1), (E3.1)+(A1.2)+(B2), (E3.1)+(A1.2)+(B3), (E3.1)+(A2.2)+(B1), (E3.1)+(A2.2)+(B2), (E3.1)+(A2.2)+(B3), (E3.1)+(A3.2)+(B1), (E3.1)+(A3.2)+(B2), (E3.1)+(A3.2)+(B3), (E3.1)+(A4.2)+(B1), (E3.1)+(A4.2)+(B2), (E3.1)+(A4.2)+(B3),
- (E3.1)+(A2.2)+(A3.1)+(B1), (E3.1)+(A2.2)+(A3.2)+(B1), (E3.1)+(A2.2)+(A4.1)+(B1), (E3.1)+(A2.2)+(A4.2)+(B1); (E3.1)+(A3.1)+(A3.2)+(B1), (E3.1)+(A3.1)+(A4.1)+(B1), (E3.1)+(A3.1)+(A4.2)+(B1); (E3.1)+(A3.2)+(A4.1)+(B1), (E3.1)+(A3.2)+(A4.2)+(B1), (E3.1)+(A4.1)+(A4.2)+(B1);
- (E3.2)+(A1.1)+(B1), (E3.2)+(A1.1)+(B2), (E3.2)+(A1.1)+(B3), (E3.2)+(A2.1)+(B1), (E3.2)+(A2.1)+(B2), (E3.2)+(A2.1)+(B3), (E3.2)+(A3.1)+(B1), (E3.2)+(A3.1)+(B2), (E3.2)+(A3.1)+(B3), (E3.2)+(A4.1)+(B1), (E3.2)+(A4.1)+(B2), (E3.2)+(A4.1)+(B3), (E3.2)+(A1.2)+(B1), (E3.2)+(A1.2)+(B2), (E3.2)+(A1.2)+(B3), (E3.2)+(A2.2)+(B1), (E3.2)+(A2.2)+(B2), (E3.2)+(A2.2)+(B3), (E3.2)+(A3.2)+(B1), (E3.2)+(A3.2)+(B2), (E3.2)+(A3.2)+(B3), (E3.2)+(A4.2)+(B1), (E3.2)+(A4.2)+(B2), (E3.2)+(A4.2)+(B3),
- (E3.3)+(A1.1)+(B1), (E3.3)+(A1.1)+(B2), (E3.3)+(A1.1)+(B3), (E3.3)+(A2.1)+(B1), (E3.3)+(A2.1)+(B2), (E3.3)+(A2.1)+(B3), (E3.3)+(A3.1)+(B1), (E3.3)+(A3.1)+(B2), (E3.3)+(A3.1)+(B3), (E3.3)+(A4.1)+(B1), (E3.3)+(A4.1)+(B2), (E3.3)+(A4.1)+(B3), (E3.3)+(A1.2)+(B1), (E3.3)+(A1.2)+(B2), (E3.3)+(A1.2)+(B3), (E3.3)+(A2.2)+(B1), (E3.3)+(A2.2)+(B2), (E3.3)+(A2.2)+(B3), (E3.3)+(A3.2)+(B1), (E3.3)+(A3.2)+(B2), (E3.3)+(A3.2)+(B3), (E3.3)+(A4.2)+(B1), (E3.3)+(A4.2)+(B2), (E3.3)+(A4.2)+(B3),
- (E4)+(A1.1)+(B1), (E4)+(A1.1)+(B2), (E4)+(A1.1)+(B3), (E4)+(A2.1)+(B1), (E4)+(A2.1)+(B2), (E4)+(A2.1)+(B3), (E4)+(A3.1)+(B1), (E4)+(A3.1)+(B2), (E4)+(A3.1)+(B3), (E4)+(A4.1)+(B1), (E4)+(A4.1)+(B2), (E4)+(A4.1)+(B3),
(E4)+(A1.2)+(B1), (E4)+(A1.2)+(B2), (E4)+(A1.2)+(B3), (E4)+(A2.2)+(B1), (E4)+(A2.2)+(B2), (E4)+(A2.2)+(B3), (E4)+(A3.2)+(B1), (E4)+(A3.2)+(B2), (E4)+(A3.2)+(B3), (E4)+(A4.2)+(B1), (E4)+(A4.2)+(B2), (E4)+(A4.2)+(B3), (E4)+(A1.1)+(A1.2)+(B1), (E4)+(A1.1)+(A2.1)+(B1), (E4)+(A1.1)+(A2.2)+(B1), (E4)+(A1.1)+(A3.1)+(B1), (E4)+(A1.1)+(A3.2)+(B1), (E4)+(A1.1)+(A4.1)+(B1), (E4)+(A1.1)+(A4.2)+(B1); - (E4.1)+(A1.1)+(B1), (E4.1)+(A1.1)+(B2), (E4.1)+(A1.1)+(B3), (E4.1)+(A2.1)+(B1), (E4.1)+(A2.1)+(B2), (E4.1)+(A2.1)+(B3), (E4.1)+(A3.1)+(B1), (E4.1)+(A3.1)+(B2), (E4.1)+(A3.1)+(B3), (E4.1)+(A4.1)+(B1), (E4.1)+(A4.1)+(B2), (E4.1)+(A4.1)+(B3), (E4.1)+(A1.2)+(B1), (E4.1)+(A1.2)+(B2), (E4.1)+(A1.2)+(B3), (E4.1)+(A2.2)+(B1), (E4.1)+(A2.2)+(B2), (E4.1)+(A2.2)+(B3), (E4.1)+(A3.2)+(B1), (E4.1)+(A3.2)+(B2), (E4.1)+(A3.2)+(B3), (E4.1)+(A4.2)+(B1), (E4.1)+(A4.2)+(B2), (E4.1)+(A4.2)+(B3),
- (E4.2)+(A1.1)+(B1), (E4.2)+(A1.1)+(B2), (E4.2)+(A1.1)+(B3), (E4.2)+(A2.1)+(B1), (E4.2)+(A2.1)+(B2), (E4.2)+(A2.1)+(B3), (E4.2)+(A3.1)+(B1), (E4.2)+(A3.1)+(B2), (E4.2)+(A3.1)+(B3), (E4.2)+(A4.1)+(B1), (E4.2)+(A4.1)+(B2), (E4.2)+(A4.1)+(B3), (E4.2)+(A1.2)+(B1), (E4.2)+(A1.2)+(B2), (E4.2)+(A1.2)+(B3), (E4.2)+(A2.2)+(B1), (E4.2)+(A2.2)+(B2), (E4.2)+(A2.2)+(B3), (E4.2)+(A3.2)+(B1), (E4.2)+(A3.2)+(B2), (E4.2)+(A3.2)+(B3), (E4.2)+(A4.2)+(B1), (E4.2)+(A4.2)+(B2), (E4.2)+(A4.2)+(B3),
- (E5)+(A1.1)+(B1), (E5)+(A1.1)+(B2), (E5)+(A1.1)+(B3), (E5)+(A2.1)+(B1), (E5)+(A2.1)+(B2), (E5)+(A2.1)+(B3), (E5)+(A3.1)+(B1), (E5)+(A3.1)+(B2), (E5)+(A3.1)+(B3), (E5)+(A4.1)+(B1), (E5)+(A4.1)+(B2), (E5)+(A4.1)+(B3), (E5)+(A1.2)+(B1), (E5)+(A1.2)+(B2), (E5)+(A1.2)+(B3), (E5)+(A2.2)+(B1), (E5)+(A2.2)+(B2), (E5)+(A2.2)+(B3), (E5)+(A3.2)+(B1), (E5)+(A3.2)+(B2), (E5)+(A3.2)+(B3), (E5)+(A4.2)+(B1), (E5)+(A4.2)+(B2), (E5)+(A4.2)+(B3), (E5)+(A1.1)+(A1.2)+(B1), (E5)+(A1.1)+(A2.1)+(B1), (E5)+(A1.1)+(A2.2)+(B1), (E5)+(A1.1)+(A3.1)+(B1), (E5)+(A1.1)+(A3.2)+(B1), (E5)+(A1.1)+(A4.1)+(B1), (E5)+(A1.1)+(A4.2)+(B1);
- (E5.1)+(A1.1)+(B1), (E5.1)+(A1.1)+(B2), (E5.1)+(A1.1)+(B3), (E5.1)+(A2.1)+(B1), (E5.1)+(A2.1)+(B2), (E5.1)+(A2.1)+(B3), (E5.1)+(A3.1)+(B1), (E5.1)+(A3.1)+(B2), (E5.1)+(A3.1)+(B3), (E5.1)+(A4.1)+(B1), (E5.1)+(A4.1)+(B2), (E5.1)+(A4.1)+(B3), (E5.1)+(A1.2)+(B1), (E5.1)+(A1.2)+(B2), (E5.1)+(A1.2)+(B3), (E5.1)+(A2.2)+(B1), (E5.1)+(A2.2)+(B2), (E5.1)+(A2.2)+(B3), (E5.1)+(A3.2)+(B1), (E5.1)+(A3.2)+(B2), (E5.1)+(A3.2)+(B3), (E5.1)+(A4.2)+(B1), (E5.1)+(A4.2)+(B2), (E5.1)+(A4.2)+(B3),
- (E5.2)+(A1.1)+(B1), (E5.2)+(A1.1)+(B2), (E5.2)+(A1.1)+(B3), (E5.2)+(A2.1)+(B1), (E5.2)+(A2.1)+(B2), (E5.2)+(A2.1)+(B3), (E5.2)+(A3.1)+(B1), (E5.2)+(A3.1)+(B2), (E5.2)+(A3.1)+(B3), (E5.2)+(A4.1)+(B1), (E5.2)+(A4.1)+(B2), (E5.2)+(A4.1)+(B3), (E5.2)+(A1.2)+(B1), (E5.2)+(A1.2)+(B2), (E5.2)+(A1.2)+(B3), (E5.2)+(A2.2)+(B1), (E5.2)+(A2.2)+(B2), (E5.2)+(A2.2)+(B3), (E5.2)+(A3.2)+(B1), (E5.2)+(A3.2)+(B2), (E5.2)+(A3.2)+(B3), (E5.2)+(A4.2)+(B1), (E5.2)+(A4.2)+(B2), (E5.2)+(A4.2)+(B3),
- (E6)+(A1.1)+(B1), (E6)+(A1.1)+(B2), (E6)+(A1.1)+(B3), (E6)+(A2.1)+(B1), (E6)+(A2.1)+(B2), (E6)+(A2.1)+(B3), (E6)+(A3.1)+(B1), (E6)+(A3.1)+(B2), (E6)+(A3.1)+(B3), (E6)+(A4.1)+(B1), (E6)+(A4.1)+(B2), (E6)+(A4.1)+(B3), (E6)+(A1.2)+(B1), (E8)+(A1.2)+(B2), (E6)+(A1.2)+(B3), (E6)+(A2.2)+(B1), (E6)+(A2.2)+(B2), (E6)+(A2.2)+(B3), (E6)+(A3.2)+(B1), (E6)+(A3.2)+(B2), (E6)+(A3.2)+(B3), (E6)+(A4.2)+(B1), (E6)+(A4.2)+(B2), (E6)+(A4.2)+(B3), (E6)+(A1.1)+(A1.2)+(B1), (E8)+(A1.1)+(A2.1)+(B1), (E6)+(A1.1)+(A2.2)+(B1), (E6)+(A1.1)+(A3.1)+(B1), (E6)+(A1.1)+(A3.2)+(B1), (E6)+(A1.1)+(A4.1)+(B1), (E6)+(A1.1)+(A4.2)+(B1);
- (E6.1)+(A1.1)+(B1), (E6.1)+(A1.1)+(B2), (E6.1)+(A1.1)+(B3), (E6.1)+(A2.1)+(B1), (E6.1)+(A2.1)+(B2), (E6.1)+(A2.1)+(B3), (E6.1)+(A3.1)+(B1), (E6.1)+(A3.1)+(B2), (E6.1)+(A3.1)+(B3), (E6.1)+(A4.1)+(B1), (E6.1)+(A4.1)+(B2), (E6.1)+(A4.1)+(B3), (E6.1)+(A1.2)+(B1), (E6.1)+(A1.2)+(B2), (E6.1)+(A1.2)+(B3), (E6.1)+(A2.2)+(B1), (E6.1)+(A2.2)+(B2), (E6.1)+(A2.2)+(B3), (E6.1)+(A3.2)+(B1), (E6.1)+(A3.2)+(B2), (E6.1)+(A3.2)+(B3), (E6.1)+(A4.2)+(B1), (E6.1)+(A4.2)+(B2), (E6.1)+(A4.2)+(B3),
- (E6.2)+(A1.1)+(B1), (E6.2)+(A1.1)+(B2), (E6.2)+(A1.1)+(B3), (E6.2)+(A2.1)+(B1), (E6.2)+(A2.1)+(B2), (E6.2)+(A2.1)+(B3), (E6.2)+(A3.1)+(B1), (E6.2)+(A3.1)+(B2), (E6.2)+(A3.1)+(B3), (E6.2)+(A4.1)+(B1), (E6.2)+(A4.1)+(B2), (E6.2)+(A4.1)+(B3), (E6.2)+(A1.2)+(B1), (E6.2)+(A1.2)+(B2), (E6.2)+(A1.2)+(B3), (E6.2)+(A2.2)+(B1), (E6.2)+(A2.2)+(B2), (E6.2)+(A2.2)+(B3), (E6.2)+(A3.2)+(B1), (E6.2)+(A3.2)+(B2), (E6.2)+(A3.2)+(B3), (E6.2)+(A4.2)+(B1), (E6.2)+(A4.2)+(B2), (E6.2)+(A4.2)+(B3),
- (E6.3)+(A1.1)+(B1), (E6.3)+(A1.1)+(B2), (E6.3)+(A1.1)+(B3), (E6.3)+(A2.1)+(B1), (E6.3)+(A2.1)+(B2), (E6.3)+(A2.1)+(B3), (E6.3)+(A3.1)+(B1), (E6.3)+(A3.1)+(B2), (E6.3)+(A3.1)+(B3), (E6.3)+(A4.1)+(B1), (E6.3)+(A4.1)+(B2), (E6.3)+(A4.1)+(B3), (E6.3)+(A1.2)+(B1), (E6.3)+(A1.2)+(B2), (E6.3)+(A1.2)+(B3), (E6.3)+(A2.2)+(B1), (E6.3)+(A2.2)+(B2), (E6.3)+(A2.2)+(B3), (E6.3)+(A3.2)+(B1), (E6.3)+(A3.2)+(B2), (E6.3)+(A3.2)+(B3), (E6.3)+(A4.2)+(B1), (E6.3)+(A4.2)+(B2), (E6.3)+(A4.2)+(B3),
- (E6.4)+(A1.1)+(B1), (E6.4)+(A1.1)+(B2), (E6.4)+(A1.1)+(B3), (E6.4)+(A2.1)+(B1), (E6.4)+(A2.1)+(B2), (E6.4)+(A2.1)+(B3), (E6.4)+(A3.1)+(B1), (E6.4)+(A3.1)+(B2), (E6.4)+(A3.1)+(B3), (E6.4)+(A4.1)+(B1), (E6.4)+(A4.1)+(B2), (E6.4)+(A4.1)+(B3), (E6.4)+(A1.2)+(B1), (E6.4)+(A1.2)+(B2), (E6.4)+(A1.2)+(B3), (E6.4)+(A2.2)+(B1), (E6.4)+(A2.2)+(B2), (E6.4)+(A2.2)+(B3), (E6.4)+(A3.2)+(B1), (E6.4)+(A3.2)+(B2), (E6.4)+(A3.2)+(B3), (E6.4)+(A4.2)+(B1), (E6.4)+(A4.2)+(B2), (E6.4)+(A4.2)+(B3),
- (E6.5)+(A1.1)+(B1), (E6.5)+(A1.1)+(B2), (E6.5)+(A1.1)+(B3), (E6.5)+(A2.1)+(B1), (E6.5)+(A2.1)+(B2), (E6.5)+(A2.1)+(B3), (E6.5)+(A3.1)+(B1), (E6.5)+(A3.1)+(B2), (E6.5)+(A3.1)+(B3), (E6.5)+(A4.1)+(B1), (E6.5)+(A4.1)+(B2), (E6.5)+(A4.1)+(B3), (E6.5)+(A1.2)+(B1), (E6.5)+(A1.2)+(B2), (E6.5)+(A1.2)+(B3), (E6.5)+(A2.2)+(B1), (E6.5)+(A2.2)+(B2), (E6.5)+(A2.2)+(B3), (E6.5)+(A3.2)+(B1), (E6.5)+(A3.2)+(B2), (E6.5)+(A3.2)+(B3), (E6.5)+(A4.2)+(B1), (E6.5)+(A4.2)+(B2), (E6.5)+(A4.2)+(B3),
- (E7)+(A1.1)+(B1), (E7)+(A1.1)+(B2), (E7)+(A1.1)+(B3), (E7)+(A2.1)+(B1), (E7)+(A2.1)+(B2), (E7)+(A2.1)+(B3), (E7)+(A3.1)+(B1), (E7)+(A3.1)+(B2), (E7)+(A3.1)+(B3), (E7)+(A4.1)+(B1), (E7)+(A4.1)+(B2), (E7)+(A4.1)+(B3), (E7)+(A1.2)+(B1), (E7)+(A1.2)+(B2), (E7)+(A1.2)+(B3), (E7)+(A2.2)+(B1), (E7)+(A2.2)+(B2), (E7)+(A2.2)+(B3), (E7)+(A3.2)+(B1), (E7)+(A3.2)+(B2), (E7>+(A3.2)+(B3), (E7)+(A4.2)+(B1), (E7)+(A4.2)+(B2), (E7)+(A4.2)+(B3), (E7)+(A1.1)+(A1.2)+(B1), (E7)+(A1.1)+(A2.1)+(B1), (E7)+(A1.1)+(A2.2)+(B1), (E7)+(A1.1)+(A3.1)+(B1), (E7)+(A1.1)+(A3.2)+(B1), (E7)+(A1.1)+(A4.1)+(B1), (E7)+(A1.1)+(A4.2)+(B1);
- (E7.1)+(A1.1)+(B1), (E7.1)+(A1.1)+(B2), (E7.1)+(A1.1)+(B3), (E7.1)+(A2.1)+(B1), (E7.1)+(A2.1)+(B2), (E7.1)+(A2.1)+(B3), (E7.1)+(A3.1)+(B1), (E7.1)+(A3.1)+(B2), (E7.1)+(A3.1)+(B3), (E7.1)+(A4.1)+(B1), (E7.1)+(A4.1)+(B2), (E7.1)+(A4.1)+(B3), (E7.1)+(A1.2)+(B1), (E7.1)+(A1.2)+(B2), (E7.1)+(A1.2)+(B3), (E7.1)+(A2.2)+(B1), (E7.1)+(A2.2)+(B2), (E7.1)+(A2.2)+(B3), (E7.1)+(A3.2)+(B1), (E7.1)+(A3.2)+(B2), (E7.1)+(A3.2)+(B3), (E7.1)+(A4.2)+(B1), (E7.1)+(A4.2)+(B2), (E7.1)+(A4.2)+(B3),
- (E7.2)+(A1.1)+(B1), (E7.2)+(A1.1)+(B2), (E7.2)+(A1.1)+(B3), (E7.2)+(A2.1)+(B1), (E7.2)+(A2.1)+(B2), (E7.2)+(A2.1)+(B3), (E7.2)+(A3.1)+(B1), (E7.2)+(A3.1)+(B2), (E7.2)+(A3.1)+(B3), (E7.2)+(A4.1)+(B1), (E7.2)+(A4.1)+(B2), (E7.2)+(A4.1)+(B3), (E7.2)+(A1.2)+(B1), (E7.2)+(A1.2)+(B2), (E7.2)+(A1.2)+(B3), (E7.2)+(A2.2)+(B1), (E7.2)+(A2.2)+(B2), (E7.2)+(A2.2)+(B3), (E7.2)+(A3.2)+(B1), (E7.2)+(A3.2)+(B2), (E7.2)+(A3.2)+(B3), (E7.2)+(A4.2)+(B1), (E7.2)+(A4.2)+(B2), (E7.2)+(A4.2)+(B3),
- (E8)+(A1.1)+(B1), (E8)+(A1.1)+(B2), (E8)+(A1.1)+(B3), (E8)+(A2.1)+(B1), (E8)+(A2.1)+(B2), (E8)+(A2.1)+(B3), (E8)+(A3.1)+(B1), (E8)+(A3.1)+(B2), (E8)+(A3.1)+(B3), (E8)+(A4.1)+(B1), (E8)+(A4.1)+(B2), (E8)+(A4.1)+(B3), (E8)+(A1.2)+(B1), (E8)+(A1.2)+(B2), (E8)+(A1.2)+(B3), (E8)+(A2.2)+(B1), (E8)+(A2.2)+(B2), (E8)+(A2.2)+(B3), (E8)+(A3.2)+(B1), (E8)+(A3.2)+(B2), (E8)+(A3.2)+(B3), (E8)+(A4.2)+(B1), (E8)+(A4.2)+(B2), (E8)+(A4.2)+(B3),
- (E8.1)+(A1.1)+(B1), (E8.1)+(A1.1)+(B2), (E8.1)+(A1.1)+(B3), (E8.1)+(A2.1)+(B1), (E8.1)+(A2.1)+(B2), (E8.1)+(A2.1)+(B3), (E8.1)+(A3.1)+(B1), (E8.1)+(A3.1)+(B2), (E8.1)+(A3.1)+(B3), (E8.1)+(A4.1)+(B1), (E8.1)+(A4.1)+(B2), (E8.1)+(A4.1)+(B3), (E8.1)+(A1.2)+(B1), (E8.1)+(A1.2)+(B2), (E8.1)+(A1.2)+(B3), (E8.1)+(A2.2)+(B1), (E8.1)+(A2.2)+(B2), (E8.1)+(A2.2)+(B3), (E8.1)+(A3.2)+(B1), (E8.1)+(A3.2)+(B2), (E8.1)+(A3.2)+(B3), (E8.1)+(A4.2)+(B1), (E8.1)+(A4.2)+(B2), (E8.1)+(A4.2)+(B3),
- (E8.2)+(A1.1)+(B1), (E8.2)+(A1.1)+(B2), (E8.2)+(A1.1)+(B3), (E8.2)+(A2.1)+(B1), (E8.2)+(A2.1)+(B2), (E8.2)+(A2.1)+(B3), (E8.2)+(A3.1)+(B1), (E8.2)+(A3.1)+(B2), (E8.2)+(A3.1)+(B3), (E8.2)+(A4.1)+(B1), (E8.2)+(A4.1)+(B2), (E8.2)+(A4.1)+(B3), (E8.2)+(A1.2)+(B1), (E8.2)+(A1.2)+(B2), (E8.2)+(A1.2)+(B3), (E8.2)+(A2.2)+(B1), (E8.2)+(A2.2)+(B2), (E8.2)+(A2.2)+(B3), (E8.2)+(A3.2)+(B1), (E8.2)+(A3.2)+(B2), (E8.2)+(A3.2)+(B3), (E8.2)+(A4.2)+(B1), (E8.2)+(A4.2)+(B2), (E8.2)+(A4.2)+(B3),
- (E9)+(A1.1)+(B1), (E9)+(A1.1)+(B2), (E9)+(A1.1)+(B3), (E9)+(A2.1)+(B1), (E9)+(A2.1)+(B2), (E9)+(A2.1)+(B3), (E9)+(A3.1)+(B1), (E9)+(A3.1)+(B2), (E9)+(A3.1)+(B3), (E9)+(A4.1)+(B1), (E9)+(A4.1)+(B2), (E9)+(A4.1)+(B3), (E9)+(A1.2)+(B1), (E9)+(A1.2)+(B2), (E9)+(A1.2)+(B3), (E9)+(A2.2)+(B1), (E9)+(A2.2)+(B2), (E9)+(A2.2)+(B3), (E9)+(A3.2)+(B1), (E9)+(A3.2)+(B2), (E9)+(A3.2)+(B3), (E9)+(A4.2)+(B1), (E9)+(A4.2)+(B2), (E9)+(A4.2)+(B3), (E9)+(A1.1)+(A1.2)+(B1), (E9)+(A1.1)+(A2.1)+(B1), (E9)+(A1.1)+(A2.2)+(B1), (E9)+(A1.1)+(A3.1)+(B1), (E9)+(A1.1)+(A3.2)+(B1), (E9)+(A1.1)+(A4.1)+(B1), (E9)+(A1.1)+(A4.2)+(B1);
- (E9.1)+(A1.1)+(B1), (E9.1)+(A1.1)+(B2), (E9.1)+(A1.1)+(B3), (E9.1)+(A2.1)+(B1), (E9.1)+(A2.1)+(B2), (E9.1)+(A2.1)+(B3), (E9.1)+(A3.1)+(B1), (E9.1)+(A3.1)+(B2), (E9.1)+(A3.1)+(B3), (E9.1)+(A4.1)+(B1), (E9.1)+(A4.1)+(B2), (E9.1)+(A4.1)+(B3), (E9.1)+(A1.2)+(B1), (E9.1)+(A1.2)+(B2), (E9.1)+(A1.2)+(B3), (E9.1)+(A2.2)+(B1), (E9.1)+(A2.2)+(B2), (E9.1)+(A2.2)+(B3), (E9.1)+(A3.2)+(B1), (E9.1)+(A3.2)+(B2), (E9.1)+(A3.2)+(B3), (E9.1)+(A4.2)+(B1), (E9.1)+(A4.2)+(B2), (E9.1)+(A4.2)+(B3),
- All of the combinations mentioned above may also comprise more agrochemically active compounds (E), in particular two or three active compounds (E), preferably selected from the group consisting of (E1), (E1.1), (E1.2), (E1.3), (E1.4), (E1.5), (E2), (E2.1), (E2.2), (E2.3), (E2.4), (E2.5), (E2.6), (E2.7), (E2.8), (E2.9), (E3), (E3.1), (E3.2), (E3.3), (E4), (E4.1), (E4.2), (E5), (E5.1), (E5.2), (E6), (E6.1), (E6.2), (E6.3), (E6.4), (E6.5), (E7), (E7.1), (E7.2), (E8), (E8.1), (E8.2), (E9), (E9.1). Preferred combinations (A), (B), (E) with two or three active compounds (E) comprise, as component (E), (E1.1)+(E1.2), (E1.1)+(E1.2)+(E6.3), (E1.1)+(E1.2)+(E2.6) or (E5.1)+(E6.3). With particular preference, the components (A) and (B) contained in the combinations mentioned above are combined with the components (E) (E1.1)+(E1.2), (E1.1)+(E1.2)+(E6.3), (E1.1)+(E1.2)+(E2.6) or (E5.1)+(E6.3).
- Customary auxiliaries and additives (component F) which may also be contained in the herbicidal compositions according to the invention are, for example: surfactants, such as emulsifiers and dispersants, thickeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, penetrants, preservatives and antifreeze agents, antioxidants, solubilizers, fillers, carriers and colorants, antifoams, fertilizers, evaporation inhibitors and agents which modify pH and viscosity.
- Suitable emulsifiers and dispersants are, for example, nonionic emulsifiers and dispersants, for example:
- 1) polyalkoxylated, preferably polyethoxylated, saturated and unsaturated aliphatic alcohols,
- having 8 to 24 carbon atoms in the alkyl radical, which is derived from the corresponding fatty acids or from petrochemical products, and
- having 1 to 100, preferably 2 to 50, ethylene oxide units (EO), it being possible for the free hydroxyl group to be alkoxylated,
- which are commercially available, for example as Genapol® X and Genapol® O series (Clariant), Crovol® M series (Croda) or as Lutensol® series (BASF),
- 2) polyalkoxylated, preferably polyethoxylated, arylalkylphenols, such as, for example, 2,4,6-tris-(1-phenylethyl)phenol (tristyrylphenol) having an average degree of ethoxylation of between 10 and 80, preferably from 16 to 40, such as, for example Soprophor® BSU (Rhodia) or HOE S 3474 (Clariant),
- 3) polyalkoxylated, preferably polyethoxylated, alkylphenols having one or more alkyl radicals, such as, for example, nonylphenol or tri-seobutylphenol, and a degree of ethoxylation of between 2 and 40, preferably from 4 to 15, such as, for example, Arkopal® N series or Sapogenat® T series (Clariant),
- 4) polyalkoxylated, preferably polyethoxylated, hydroxyfatty acids or glycerides which contain hydroxyfatty acids, such as, for example, ricinine or castor oil, having a degree of ethoxylation of between 10 and 80, preferably from 25 to 40, such as, for example, the Emulsogen® EL series (Clariant) or the Agnique® CSO series (Cognis),
- 5) polyalkoxylated, preferably polyethoxylated, sorbitan esters, such as, for example, Atplus® 309 F (Uniqema) or the Alkamuls series (Rhodia),
- 6) di- and tri-block copolymers, for example from alkylene oxides, for example from ethylene oxide and propylene oxide, having average molar masses between 200 and 10 000, preferably from 1000 to 4000, g/mol, the proportion by mass of the polyethoxylated block varying between 10 and 80%, such as, for example, the Genapol® PF series (Clariant), the Pluronic® series (BASF), or the Synperonic® PE series (Uniqema),
- Preferred nonionic emulsifiers and dispersants are, for example, polyethoxylated alcohols, polyethoxylated triglycerides which contain hydroxyfatty acids and polyethylene oxide/polypropylene oxide block copolymers.
- The total proportion of nonionic emulsifiers and dispersants in the herbicidal compositions according to the invention is generally between 0 and 20% by weight. If nonionic emulsifiers and dispersants are, in addition to their emulsifying/dispersing properties, also used for increasing the biological effectiveness, for example as penetrants or adhesives, their proportion in the herbicidal compositions according to the invention can be increased to up to 60% by weight.
- Also suitable are ionic emulsifiers and dispersants, for example:
- 1) polyalkoxylated, preferably polyethoxylated, emulsifiers/dispersants (cf. component e) which are ionically modified, for example by conversion of the terminal free hydroxyl function of the polyethylene oxide block into a sulfate or phosphate ester (for example as alkali metal and alkaline earth metal salts), such as, for example, Genapol® LRO or dispersant 3618 (Clariant), Emulphor® (BASF) or Crafol® AP (Cognis),
- 2) alkali metal and alkaline earth metal salts of alkylarylsulfonic acids having a straight-chain or branched alkyl chain, such as phenylsulfonate CA or phenylsulfonate CAL (Clariant), Atlox® 3377BM (ICI), or the Empiphos® TM series (Huntsman),
- 3) polyelectrolytes, such as lignosulfonates, condensates of naphthalenesulfonate and formaldehyde, polystyrenesulfonate or sulfonated unsaturated or aromatic polymers (polystyrenes, polybutadienes or polyterpenes), such as the Tamol® series (BASF), Morwet® D425 (Witco), the Kraftsperse® series (Westvaco) or the Borresperse® series (Borregard).
- Preferred ionic emulsifiers/dispersants are, for example, salts of alkylarylsulfonic acids and polyelectrolytes from the polycondensation of naphthalenesulfonate and formaldehyde.
- The total proportion of ionic emulsifiers and dispersants in the herbicidal compositions according to the invention is generally between 0 and 20% by weight, in particular between 0 and 8% by weight.
- Suitable thickeners and thixotropic agents are, for example:
- 1) modified natural silicates, such as chemically modified bentonites, hectorites, attapulgites, montmoriilonites, smectites or other silicate minerals, such as Bentone® (Elementis), Attagel® (Engelhard), Agsorb® (Oil-Dri Corporation) or Hectorite® (Akzo Nobel),
- 2) synthetic silicates, such as silicates of the Sipernat®, Aerosil® or Durosil® series (Degussa), the CAB-O-SIL® series (Cabot) or the Van Gel series (R.T. Vanderbilt),
- 3) thickeners based on synthetic polymers, such as thickeners of the Thixin® or Thixatrol® series (Elementis),
- 4) thickeners based on natural polymers and natural oils, for example from the Thixin® or Thixatrol® series (Elementis).
- Preferred thickeners and thixotropic agents are, for example, modified phyllosilicates and thickeners based on synthetic polymers.
- The proportion of thickeners and thixotropic agents in the herbicidal compositions according to the invention is generally between 0 and 5% by weight, in particular between 0.2 and 3% by weight.
- The herbicidally active compositions or sulfonylurea/safener combinations according to the invention can be prepared by customary processes which are already known, for example by mixing the various components with the help of stirrers, shakers, mills or (static) mixers. In this connection, brief heating of the mixtures may in some cases be advantageous in order to achieve complete dissolution of all of the components involved.
- Preference is given to herbicidally active compositions according to the invention comprising:
- A) 0.1 to 30% by weight of one or more sulfonylureas from the group consisting of (A1.1), (A1.2), (A1.3), (A1.4), (A2.1), (A2.2), (A2.3), A2.4), (A3.1), (A3.2), (A3.3), (A3.4), (A4.1), (A4.2), preferably from the group consisting of (A1.1), (A2.1), (A3.1), (A4.1),
- B) 2 to 40% by weight of one or more safeners from the group consisting of (B1), (B2), (B3), (B4), (B5), (B6), (B7), (B8), (B9), preferably from the group consisting of (B1), (B2), (B3), (B8), particularly preferably (B1), (B2), (B3), very particularly preferably (B1), (B2), especially (B1),
- C) 20 to 80% by weight of one or more solvents, preferably from the group of the aliphatic hydrocarbons, the mixtures of aromatic and aliphatic hydrocarbons and the vegetable oils, such as rapeseed oil methyl ester,
- D) 0.5 to 30% by weight of one or more sulfosuccinates, preferably from the group of the alkali metal di(C4-C18)alkylsulfosuccinates, such as sodium di(C4-C18)alkylsulfosuccinate,
- E) 1 to 20% by weight of one or more agrochemically active compounds different from A) and B),
- F) 0 to 40% by weight of customary auxiliaries and additives, preferably 0 to 20% by weight of one or more nonionic emulsifiers and dispersants, 0 to 8% by weight of one or more ionic emulsifiers and dispersants and 0 to 3% by weight of one or more thickeners and thixotropic agents.
- The present invention also provides a method which comprises applying the components (A) and (B) of the herbicidally active composition according to the invention together or separately to the harmful plants, crop plants, plant seeds or to the area on which the plants grow, if appropriate in combination with further components, for example together or separately with the components (C), (D), (E) and (F). Here, one or more safeners of group (B) (preferably in an antidote-effective amount) can be applied before, after or simultaneously with the sulfonylurea(s) (A) to the plants, plant seeds or the area in which the plants grow.
- The herbicidally active compositions according to the invention may also be employed for controlling harmful plants in crops of known genetically modified plants or genetically modified plants yet to be developed. As a rule, the transgenic plants are distinguished by particularly advantageous properties, for example by resistances to certain crop protection agents, resistances to plant diseases or to causative agents of plant diseases such as specific insects or microorganisms such as fungi, bacteria or viruses. Other particular properties concern for example the harvested crop with regard to quantity, quality, storability, composition and specific constituents. Thus, transgenic plants are known with an increased starch content or a modified starch quality, or those with a different fatty acid composition of the harvested crop.
- Preferred is the use of the combinations according to the invention in economically important transgenic crops of useful plants and ornamentals, for example of cereals (such as wheat, barley, rye, oats), millet, rice, cassaya and corn, or else crops of sugar beet, cotton, soybean, oilseed rape, potato, tomato, pea and other vegetables.
- When the combinations according to the invention are used in transgenic crops, effects in addition to the effects to be observed against harmful plants in other crops are frequently found, which are specific for application in the particular transgenic crop, for example a modified or specifically widened weed spectrum which can be controlled, modified application rates which may be employed for the application, preferably good combinability with the herbicides to which the transgenic crop is resistant, and an effect on growth and yield of the transgenic crop plants.
- The invention thus also relates to the use of the herbicidally active composition according to the invention for controlling harmful plants in transgenic crop plants or crop plants which are tolerant as a result of selective breeding.
- The safeners of group (B) and the sulfonylureas (A) can be formulated together or separately, if appropriate in combination with further components, for example the components (C), (D), (E) and (F), in various ways, depending on the prevailing biological and/or chemico-physical parameters. Suitable possibilities of formulation are, for example:
- wettable powders (WP), emulsifiable concentrates (EC), water-soluble powders (SP), water-soluble concentrates (SL), concentrated emulsions (BW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, capsule suspensions (CS), oil- or water-based dispersions (SC), suspoemulsions, suspension concentrates, dust (DP), oil-miscible solutions (OL), seed-dressing products, granules (GR) in the form of microgranules, spray granules, coated granules and adsorption granules, granules for soil application or broadcasting, water-soluble granules (SG), water-dispersible granules (WG), ULV formulations, microcapsules and waxes.
- These individual formulation types are known in principle and are described, for example, in: Winnacker-Küchler, “Chemische Technologie” [Chemical engineering], Volume 7, C. Hauser Verlag Munich, 4th Ed., 1986; Wade van Valkenburg, “Pesticide Formulations”, Marcel Dekker N.Y., 1973; K. Martens, “Spray Drying Handbook”, 3rd Ed. 1979, G. Goodwin Ltd. London.
- The formulation auxiliaries which may be required, such as inert materials, surfactants, solvents and further additives are likewise known and described, for example, in: “Handbook of Insecticide Dust Diluents and Carriers”, 2nd Ed., Darland Books, Caldwell N.J., H. v. Olphen, “Introduction to Clay Colloid Chemistry”; 2nd Ed., J. Wiley & Sons, N.Y.; C. Marsden, “Solvents Guide”; 2nd Ed., Interscience, N.Y. 1963; McCutcheon's “Detergents and Emulsifiers Annual”, MC Publ, Corp., Ridgewood N.J.; Sisley and Wood, “Encyclopedia of Surface Active Agents”, Chem. Publ. Co. Inc., N.Y. 1964; Schönfeldt, “Grenzflächenaktive Äthylenoxidaddukte” [Surface-active ethylene oxide adducts], Wiss. Verlagsgesell., Stuttgart 1976; Winnacker-Küchler, “Chemische Technologie”, Volume 7, C. Hauser Verlag Munich, 4th Ed. 1985.
- Based on these formulations, combinations with other agrochemically active compounds, for example crop protectants such as insecticides, acaricides, herbicides, fungicides, or with safeners, fertilizers and/or growth regulators may also be prepared, for example in the form of a readymix or a tank mix.
- Wettable powders are preparations which are uniformly dispersible in water and which, besides the active ingredient, additionally comprise ionic and/or nonionic surfactants (wetters, dispersants), for example polyoxethylated alkylphenols, polyoxethylated fatty alcohols, polyoxethylated fatty amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium lignosulfonates, sodium 2,2′-dinaphthylmethane-6,6′-disulfonate, sodium dibutylnaphthalene-sulfonate, or else sodium oleoylmethyltaurinate, in addition to a diluent or inert substance. To prepare the wettable powders, the active ingredients, for example the herbicidal active ingredients and/or the safeners, are ground finely, for example in customary apparatuses such as hammer mills, blower mills and air-jet mills, and simultaneously or subsequently mixed with the formulation auxiliaries.
- Emulsifiable concentrates are prepared, for example, by dissolving the active ingredient, for example the herbicidal active ingredient and/or the safener, in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene or else high-boiling hydrocarbons such as saturated or unsaturated aliphatic or alicyclic substances, aromatic substances or mixtures of the organic solvents with addition of one or more ionic and/or nonionic surfactants (emulsifiers). The following are examples of emulsifiers which may be used: calcium (C6-C18)-alkylarylsulfonates such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers such as fatty acid polyglycol esters, (C2-C18)-alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide/ethylene oxide condensates, alkyl polyethers, sorbitan esters such as, for example, sorbitan fatty acid esters or polyoxyethylene sorbitan esters such as polyoxyethylene sorbitan fatty acid esters.
- Dusts are obtained in general by grinding the active ingredient, for example the herbicidal active ingredient and/or the safener, with finely divided solid materials, for example talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
- Suspension concentrates may be water- or oil-based. They can be prepared for example by wet-milling by means of commercially available bead mills, if appropriate with addition of surfactants as, for example, have already been listed above in the case of the other formulation types.
- Emulsions, for example oil-in-water emulsions (EW), can be prepared for example by means of stirrers, colloid mills and/or static mixers using aqueous organic solvents and, if appropriate, surfactants as, for example, have already been listed above in the case of the other formulation types.
- Granules can be produced either by spraying the active ingredient, for example the herbicidal active ingredient and/or the safener, onto absorptive granulated inert material or by applying active ingredient concentrates to the surface of carriers such as sand, kaolinite or of granulated inert material by means of binders, for example polyvinyl alcohol, sodium polyacrylate or else mineral oils. Suitable active ingredients may also be granulated in the manner which is conventional for the production of fertilizer granules, if desired as a mixture with fertilizers. As a rule, water-dispersible granules are prepared by the customary method such as spray-drying, fluidized-bed granulation, disk granulation, mixing by means of high-speed mixers, and extrusion without solid inert material.
- To prepare disk, fluidized-bed, extruder and spray granules, see, for example, methods in “Spray-Drying Handbook” 3rd ed. 1979, G. Goodwin Ltd., London; J. E. Browning, “Agglomeration”, Chemical and Engineering 1967, pages 147 et seq.; “Perry's Chemical Engineer's Handbook”, 5th Ed., McGraw-Hill, New York 1973, pp. 8-57.
- For further details on the formulation of crop protection agents see, for example, G. C. Klingman, “Weed Control as a Science”, John Wiley and Sons, Inc., New York, 1961, pages 81-96 and J. D. Freyer, S. A. Evans, “Weed Control Handbook”, 5th Ed, Blackwell Scientific Publications, Oxford, 1968, pages 101-103.
- Preferred formulations are liquid formulations, such as oil suspensions, oil suspension concentrates, suspoemulsions, suspoemulsion concentrates, emulsions, for example W/O- or O/W-based, emulsion concentrates, microemulsions, microemulsion concentrates, emulsifiable concentrates, and spray liquors obtainable therefrom, preferably aqueous spray liquors.
- A particularly preferred liquid formulation type are oil suspension concentrates, i.e. suspension concentrates based on organic solvents, and formulations obtainable therefrom by dilution, such as solutions, emulsions, suspoemulsions and suspensions. In the oil suspension concentrates, one or more active compounds are suspended in the organic solvent; further active compounds may be dissolved in the organic solvent. In a preferred oil suspension concentrate, the herbicide (A) is present in suspended form in the organic solvents. This means that the main proportion (in % by weight) of sulfonamide is present undissolved in highly disperse form and a minor portion of the sulfonamide may be present in dissolved form. Preferably, more than 80% by weight, particularly preferably more than 90% by weight, of the sulfonamide are suspended in the organic solvent, in each case based on the total amount of sulfonamide in the oil suspension concentrate according to the invention.
- As a rule, the agrochemical preparations comprise from 0.1 to 99% by weight, in particular from 0.1 to 95% by weight, of active compounds, for example active safener compounds (B), or sulfonylurea (A), or the active herbicide/safener mixture according to the invention comprising sulfonylureas (A) and active safener compounds (B), and from 1 to 99.9% by weight, in particular from 5 to 99.8% by weight, of a solid or liquid additive and from 0 to 25% by weight, in particular from 0.1 to 25% by weight, of a surfactant.
- In wettable powders, the active ingredient concentration is, for example, from approximately 10 to 90% by weight, the remainder to 100% by weight being composed of customary formulation components. In the case of emulsifiable concentrates, the active ingredient concentration amounts to approximately 1 to 80% by weight. Formulations in the form of dusts comprise from approximately 1 to 20% by weight of active ingredients, sprayable solutions from approximately 0.2 to 20% by weight of active ingredients. In the case of granules such as water-dispersible granules, the active ingredient content depends partly on whether the active compound is in liquid or solid form. As a rule, the active compound content in the water-dispersible granules is between 10 and 90% by weight.
- In addition, the active ingredient formulations mentioned comprise, if appropriate, the adhesives, wetters, dispersants, emulsifiers, penetrants, preservatives, antifreeze agents, solvents, fillers, carriers, colorants, antifoams, evaporation inhibitors, pH regulators and viscosity regulators which are conventional in each case.
- For application, the commercially available formulations are optionally diluted in a conventional manner with water, for example in the case of wettable powders, emulsifable concentrates, dispersions and water-dispersible granules. Preferred formulations which are diluted with water are, for example, liquid formulations such as oil suspensions, oil suspension concentrates, suspoemulsions, suspoemulsion concentrates, emulsions, for example W/O- or O/W-based, emulsion concentrates, microemulsions, microemulsion concentrates, and emulsifable concentrates. Preparations in the form of dusts, granules for soil application or broadcasting as well as sprayable solutions are customarily not diluted with further inert substances prior to application.
- The necessary application rate of the herbicides (A) varies with the external conditions such as, inter alia, temperature, humidity and the type of the herbicide used, it can be varied within wide limits, for example between 0.001 and 10.0 kg/ha or more of active substance, but it is preferably between 0.005 and 5 kg/ha.
- The examples which follow illustrate the invention:
-
- a) A dust is obtained by mixing 10 parts by weight of a sulfonylurea (A) or a safener (B) or an active compound mixture of a sulfonylurea (A) and a safener (B) and 90 parts by weight of talc as inert substance and comminuting the mixture in a hammer mill.
- b) A wettable powder which is readily dispersible in water is obtained by mixing 25 parts by weight of a sulfonylurea (A) or a safener (B) or an active compound mixture of a sulfonylurea (A) and a safener (B), 64 parts by weight of kaolin-containing quartz as inert material, 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleoylmethyltaurinate as wetter and dispersant and by grinding the mixture in a pinned-disk mill.
- c) A concentrate which is readily dispersible or suspendible in water is obtained by mixing 20 parts by weight of a sulfonylurea (A) or a safener (B) or an active compound mixture of a sulfonylurea (A) and a safener (B), 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range for example approx. 255 to above 277° C.) and by grinding the mixture in a ball mill to a fineness of below 5 microns.
- d) An emulsifiable concentrate is obtained from 15 parts by weight of a sulfonylurea (A) or a safener (B) or an active compound mixture of a sulfonylurea (A) and a safener (B), 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of oxethylated nonylphenol as emulsifier.
- e) Water-dispersible granules are obtained by mixing
-
75 parts by weight of a sulfonylurea (A) or a safener (B) or an active compound mixture of a sulfonylurea (A) and a safener (B), 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and 7 parts by weight of kaolin, - grinding the mixture on a pinned-disk mill and granulating the powder in a fluidized bed by spraying on water as granulation liquid.
- f) Water-dispersable granules are also obtained by homogenizing and precomminuting
-
25 parts by weight of a sulfonylurea (A) or a safener (B) or an active compound mixture of a sulfonylurea (A) and a safener (B), 5 parts by weight of sodium 2,2′-dinaphthylmethane-6,6′-disulfonate, 2 parts by weight of sodium oleoylmethyltaurinate, 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate and 50 parts by weight of water - in a colloid mill, subsequently milling the mixture in a bead mill and atomizing and drying the resulting suspension in a spray tower by means of a single-substance nozzle.
- g) An oil suspension concentrate is obtained, for example, by mixing the components, for example by preparing a premix where optionally a sulfosuccinate D) is dissolved in the solvent C) and, optionally, further auxiliaries and additives F) are added to this solution. Any soluble safeners B) and agrochemically active compounds E) used are then dissolved in the premix. After the end of the dissolution process, solid sulfonylurea A) and any insoluble safener B) and agrochemically active compounds E) used are then suspended in the mixture. The coarse suspension is, if appropriate after pregrinding, subjected to fine grinding.
- In another embodiment for preparing an oil suspension concentrate, solid sulfonylurea A) and any insoluble components B), E) and F) used are suspended in the solvent C) which optionally contains a sulfosuccinate D) and ground. Any soluble active compounds B) and E) used and also auxiliaries and additives from F) which do not require grinding or are not required for the grinding process are added after grinding.
- In a further embodiment for preparing an oil suspension concentrate, in which thickeners are used as auxiliaries and additives F), the thickener is initially mixed with the solvent C). Active compounds A), B) and optionally E) and any further auxiliaries and additives F) and sulfosuccinates D) are then added, and the mixture is ground, for example in a mill.
- h) Preparation of specific oil suspension concentrates
- Solvesso® 200 ND, Bentone® 34 and propylene carbonate are added into a mill and mixed intensively until a paste is obtained. The other components (auxiliaries and additives and active compounds) are then added successively with stirring, and the resulting mixture is subsequently homogenized in a ball mill. The table below shows the proportions of the components of the formulation (in % by weight) of the oil suspension concentrates prepared in this manner.
-
TABLE Examples 1 2 3 4 5 6 7 metsulfuron-methyl 8.65 — — — — — — metsulfuron-methyl- — 8.65 — — — — — sodium thifensulfuron-methyl — — 15.7 — — — — thifensulfuron-methyl- — — — 15.7 — — — sodium tribenuron-methyl- — — — — 15.7 — — sodium chlorsulfuron — — — — — 15.7 — chlorsulfuron-sodium — — — — — — 15.7 mefenpyr-diethyl 1.74 1.74 3.13 3.13 3.13 3.13 3.13 Triton ® GR-7M-E 28.9 28.9 26.0 26.0 26.0 26.0 26.0 Emulsogen ® EL 400 8.7 8.7 8.0 8.0 8.0 8.0 8.0 Etocas ® 10 7.2 7.2 7.0 7.0 7.0 7.0 7.0 Genapol ® PF 10 4.4 4.4 4.0 4.0 4.0 4.0 4.0 Morwet ® D 425 2.9 2.9 2.7 2.7 2.7 2.7 2.7 Bentone ® 34 0.72 0.72 0.7 0.7 0.7 0.7 0.7 propylene carbonate 0.72 0.72 0.7 0.7 0.78 0.7 0.7 Rhodorsil ® 454 0.07 0.07 0.07 0.07 0.07 0.07 0.07 Solvesso ® 200 ND 36 36 32 32 32 32 32 Notes: Triton ® GR-7M-E is di-2-ethylhexylsulfosuccinate-sodium, Emulsogen ® EL 400 is an ethoxylated castor oil having 40 ethylene oxide units, Etocas ® 10 is an ethoxylated castor oil having 10 ethylene oxide units, Genapol ® PF 10 is a polymeric surfactant (block copolymer of ethylene oxide and propylene oxide), Morwet ® D 425 is a polymeric anionic dispersant, Bentone ® 34 is a thickener (based on modified phyllosilicate), Rhodorsil ® 454 is a silicone antifoam, Solvesso ® 200 ND is an aromatic solvent having a high boiling point. - Damage to the plants is evaluated visually in comparison with control plants, according to a scale from 0 to 100%:
- 0%= no perceptible effect in comparison with the untreated plant,
100%= treated plant dies - Seeds of monocotyledonous and dicotyledonous weeds and of crop plants are placed in sandy loam soil in plastic pots, covered with soil and cultivated in a greenhouse under good growth conditions.
- Three weeks after sowing, the test plants are treated at the 3-4-leaf stage. Different dosages of the individual active compounds according to the invention, formulated as emulsion concentrates, are sprayed individually or as mixtures in application rates of 300 l of water/ha (converted) onto the green parts of the plants, and after the test plants have spent 3 weeks in the greenhouse under optimum growth conditions, the effect of the preparation is scored visually in comparison with untreated controls. As shown by the examples, the combinations according to the invention of sulfonylureas and safeners are capable of effectively controlling a broad spectrum of weeds, and damage to crop plants is, compared with the use of the individual sulfonylureas without safener, considerably reduced.
- The test results for crop plants are compiled in the tables below. Stated is the respective degree of damage to the crop plants and the reduction of the damage by the herbicide/safener combinations according to the invention in percent, compared with the herbicide applied alone.
-
TABLE 1 Corn, cultivar “Lorenzo” Application rate Degree of Reduction of Active compound (s) [g of a.i./ha] damage [%] damage [%] herbicide A1.1 13 50 — herbicide A1.1 + safener B2 13 + 100 10 80 herbicide A2.1 25 20 — herbicide A2.1 + safener B2 25 + 100 0 100 herbicide A3.1 20 10 — herbicide A3.1 + safener B2 20 + 100 0 100 herbicide A4.1 25 70 — herbicide A4.1 + safener B2 25 + 100 40 43 herbicide A1.1: metsulfuron-methyl; herbicide A2.1: thifensulfuron-methyl; herbicide A3.1: tribenuron-methyl; herbicide A4.1: chlorsulfuron; safener B2: isoxadifen-ethyl -
TABLE 2 Barley, cultivar “Baronesse” Application rate Degree of Reduction of Active compound(s) [g of a.i/ha] damage [%] damage [%] herbicide A1.1 25 10 — herbicide A1.1 + safener B2 25 + 100 0 100 herbicide A4.1 25 10 — herbicide A4.1 + safener B1 25 + 100 0 100 herbicide A4.1 + safener B3 25 + 100 0 100 herbicide A1.1: metsulfuron-methyl; herbicide A4.1: chlorsulfuron; safener B1: mefenpyr-diethyl; safener B2: isoxadifen-ethyl; safener B3: cloquintocet-mexyl -
TABLE 3 Barley, cultivar “Duett” Application rate Degree of Reduction of Active compound(s) [g of a.i./ha] damage [%] damage [%] herbicide A2.1 25 20 — herbicide A2.1 + safener B1 25 + 100 10 50 herbicide A2.1 + safener B3 25 + 100 10 50 herbicide A2.1: thifensulfuron-methyl; safener B1: mefenpyr-diethyl; safener B3: cloquintocet-mexyl -
TABLE 4 Wheat, cultivar “Triso” Application rate Degree of Reduction of Active compound(s) [g of a.i./ha] damage [%] damage [%] herbicide A1.1 25 15 — 13 10 — herbicide A1.1 + safener B1 13 + 100 0 100 herbicide A1.1 + safener B2 25 + 100 0 100 herbicide A1.1: metsulfuron-methyl; safener B1: mefenpyr-diethyl; safener B2: isoxadifen-ethyl -
TABLE 5 Wheat, cultivar “Kanzler” Application rate Degree of Reduction of Active compound(s) [g of a.i./ha] damage [%] damage [%] herbicide A1.1 25 10 — herbicide A1.1 + safener B3 25 + 100 0 100 herbicide A2.1 25 10 — herbicide A2.1 + safener B1 25 + 100 0 100 herbicide A2.1 + safener B3 25 + 100 0 100 herbicide A3.1 40 20 — herbicide A3.1 + safener B3 40 + 100 0 100 herbicide A1.1: metsulfuron-methyl; herbicide A2.1: thifensulfuron-methyl; herbicide A3.1: tribenuron-methyl; safener B1: mefenpyr-diethyl; safener B2: isoxadifen-ethyl; safener B3: cloquintocet-mexyl.
Claims (20)
1. A herbicidally active composition, comprising
(A) one or more sulfonylureas from the group consisting of metsulfuron, thifensulfuron, tribenuron, chlorsulfuron and their salts and esters, and
(B) one or more safeners from the group consisting of cloquintocet, and its salts and esters.
2. The herbicidally active composition as claimed in claim 1 , in which the sulfonylureas (A) are selected from the group consisting of metsulfuron-methyl, thifensulfuron-methyl, tribenuron-methyl, chlorsulfuron and their alkali metal salts.
3. The herbicidally active composition as claimed in claim 1 , in which safener (B) is cloquintocet-mexyl.
4. The herbicidally active composition as claimed in claim 1 , in which the weight ratio herbicidal:safener is from 1:100 to 100:1.
5. The herbicidally active composition as claimed in claim 1 , additionally comprising
(C) one or more solvents, preferably organic solvents,
(D) one or more sulfosuccinates,
(E) one or more agrochemically active compounds different from (A) and (B), and/or
(F) customary auxiliaries and additives.
6. The herbicidally active composition as claimed in claim 1 in form of a liquid formulation.
7. A liquid formulation, comprising
(A) one or more sulfonylureas from the group consisting of metsulfuron, thifensulfuron, tribenuron, chlorsulfuron and their salts and esters,
(B) one or more safeners from the group consisting of cloquintocet and its salts and esters,
(C) one or more solvents, preferably organic solvents,
(D) optionally one or more sulfosuccinates,
(E) optionally one or more agrochemically active compounds different from (A) and (B), and
(F) optionally customary auxiliaries and additives.
8. The liquid formulation as claimed in claim 7 , wherein said one or more sulfonylureas (A) are present in a herbicidally effective amount and said one or more safeners (B) are present in an antidote-effective amount.
9. The liquid formulation as claimed in claim 8 in the form of an oil suspension, oil suspension concentrate, suspoemulsion, suspoemulsion concentrates, emulsion, emulsion concentrate, micoemulsion, microemulsion concentrate, emulsifiable concentrate or spray liquors obtainable therefrom.
10. A method for controlling harmful plants in plant crops, which comprises applying the components of the herbicidally active composition as claimed in claim 1 jointly or separately to the harmful plants, crop plants, plant seeds or to the area in which the plants grow.
11. The method as claimed in claim 10 , wherein the crop plants are from the group consisting of corn, wheat, rye, barley, oats, rice, sorghum, cotton and soybeans.
12. The method as claimed in claim 10 , wherein the crop plants are transgenic or tolerant owing to selective breeding.
13. (canceled)
14. A process for preparing a herbicidally active composition as claimed in claim 1 , which process comprises mixing the components.
15. A sulfonylurea/safener combination, comprising
(A) one or more sulfonylureas from the group consisting of metsulfuron, thifensulfuron, tribenuron, chlorsulfuron and their salts and esters, and
(B) one or more safeners from the group consisting of cloquintocet and its salts and esters.
16. The sulfonylurea/safener combination as claimed in claim 15 , in which the sulfonylureas (A) are selected from the group consisting of metsulfuron-methyl, thifensulfuron-methyl, tribenuron-methyl, chlorsulfuron and their alkali metal salts.
17. The sulfonylurea/safener combination as claimed in claim 15 , in which the safener (B) is cloquintocet-mexyl.
18. The sulfonylurea/safener combination as claimed in claim 15 , additionally comprising one or more agrochemically active compounds (E) different from (A) and (B).
19. A method for controlling harmful plants in plant crops, which comprises applying the components of the liquid formulation as claimed in claim 7 jointly or separately to the harmful plants, crop plants, plant seeds or to the area in which the plants grow.
20. A process for preparing a liquid formulation as claimed in claim 7 , which process comprises mixing the components.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/201,115 US20090054236A1 (en) | 2003-11-03 | 2008-08-29 | Herbicidally active composition |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEDE10351234.9 | 2003-11-03 | ||
DE10351234A DE10351234A1 (en) | 2003-11-03 | 2003-11-03 | Herbicidal composition useful for selective weed control in crops comprises a sulfonylurea herbicide and a safener |
DE10355846A DE10355846A1 (en) | 2003-11-26 | 2003-11-26 | Herbicidal composition useful for selective weed control in crops comprises a sulfonylurea herbicide and a safener |
DEDE10355846.2 | 2003-11-26 | ||
US10/976,217 US7432226B2 (en) | 2003-11-03 | 2004-10-28 | Herbicidally active composition |
US12/201,115 US20090054236A1 (en) | 2003-11-03 | 2008-08-29 | Herbicidally active composition |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/976,217 Division US7432226B2 (en) | 2003-11-03 | 2004-10-28 | Herbicidally active composition |
Publications (1)
Publication Number | Publication Date |
---|---|
US20090054236A1 true US20090054236A1 (en) | 2009-02-26 |
Family
ID=34553322
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/976,217 Active 2025-11-18 US7432226B2 (en) | 2003-11-03 | 2004-10-28 | Herbicidally active composition |
US12/201,115 Abandoned US20090054236A1 (en) | 2003-11-03 | 2008-08-29 | Herbicidally active composition |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/976,217 Active 2025-11-18 US7432226B2 (en) | 2003-11-03 | 2004-10-28 | Herbicidally active composition |
Country Status (16)
Country | Link |
---|---|
US (2) | US7432226B2 (en) |
EP (1) | EP1681932B1 (en) |
AR (1) | AR046224A1 (en) |
AT (1) | ATE389327T1 (en) |
AU (1) | AU2004285269B2 (en) |
BR (1) | BRPI0416159A (en) |
CA (1) | CA2544415A1 (en) |
DE (1) | DE502004006612D1 (en) |
DK (1) | DK1681932T3 (en) |
EA (1) | EA012521B1 (en) |
ES (1) | ES2302038T3 (en) |
IL (1) | IL175359A0 (en) |
PL (1) | PL1681932T3 (en) |
TW (1) | TW200517058A (en) |
UA (1) | UA83698C2 (en) |
WO (1) | WO2005041654A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140302990A1 (en) * | 2013-04-03 | 2014-10-09 | Fmc Corporation | Suspoemulsion of Fomesafen and Fluthiacet-Methyl |
WO2015139586A1 (en) * | 2014-03-21 | 2015-09-24 | Rotam Agrochem International Company Limited | A herbicidal composition comprising metsulfuron-methyl, thifensulfuron-methyl and tribenuron-methyl and the use thereof |
WO2021205448A1 (en) | 2020-04-06 | 2021-10-14 | Adama Agan Ltd. | Co-crystals of antioxidants and active ingredients and use of antioxidants as stabilizer |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EA015243B1 (en) * | 2004-12-14 | 2011-06-30 | БАЙЕР КРОПСАЙЕНС ЛПи | Methods for increasing maize yields |
DE102005031787A1 (en) * | 2005-07-07 | 2007-01-18 | Bayer Cropscience Gmbh | Crop-compatible herbicidal compositions containing herbicides safeners |
NZ568867A (en) * | 2005-08-24 | 2010-12-24 | Pioneer Hi Bred Int | Compositions providing tolerance to multiple herbicides and methods of use thereof |
ZA200802442B (en) * | 2005-09-01 | 2010-02-24 | Du Pont | Liquid sulfonylurea herbicide formulations |
EP1836894A1 (en) * | 2006-03-25 | 2007-09-26 | Bayer CropScience GmbH | Novel sulfonamide-containing solid formulations |
CA2622066A1 (en) * | 2005-09-08 | 2007-03-15 | Bayer Cropscience Ag | Novel sulfonamide-containing solid formulations |
LT1928232T (en) * | 2005-09-16 | 2016-09-26 | Bayer Intellectual Property Gmbh | Solid formulation |
US7951995B2 (en) | 2006-06-28 | 2011-05-31 | Pioneer Hi-Bred International, Inc. | Soybean event 3560.4.3.5 and compositions and methods for the identification and detection thereof |
US8609935B2 (en) | 2006-10-31 | 2013-12-17 | E. I. Du Pont De Nemours And Company | Soybean event DP-305423-1 and compositions and methods for the identification and/or detection thereof |
TW200843642A (en) * | 2007-03-08 | 2008-11-16 | Du Pont | Liquid sulfonylurea herbicide formulations |
ES2323399B2 (en) * | 2007-06-19 | 2010-02-26 | Gat Microencapsulation Ag | SUSPENSIONS IN AGRICULTURAL SULFONILE AND COMBINATIONS OILS. |
AR074024A1 (en) | 2008-11-14 | 2010-12-15 | Merial Ltd | COMPOSITE OF ARILAZOL-2-IL-CYANOETHYLAMIN ENANTIOMERICALLY ENRICHED, PESTICIATED COMPOSITION AND ITS USE TO PREVENT PARASITARY INFECTION |
DE102008058642A1 (en) * | 2008-11-22 | 2010-05-27 | Bayer Cropscience Ag | Herbicide combinations containing diflufenican and ALS inhibitors |
EP2376513B1 (en) | 2008-12-04 | 2015-02-25 | Merial Limited | Dimeric avermectin and milbemycin derivatives |
US8791049B2 (en) | 2009-12-17 | 2014-07-29 | Gowan Co. | Plant treatment compositions particularly effective in the control of Heteranthera limosa on rice crops, and methods for their use |
SI2513104T1 (en) | 2009-12-17 | 2016-07-29 | Merial, Inc. | Antiparasitic dihydroazole compounds and compositions comprising same |
US9187762B2 (en) | 2010-08-13 | 2015-11-17 | Pioneer Hi-Bred International, Inc. | Compositions and methods comprising sequences having hydroxyphenylpyruvate dioxygenase (HPPD) activity |
UA122558C2 (en) | 2010-11-24 | 2020-12-10 | Піонер Хай-Бред Інтернешнл, Інк. | Brassica gat event dp-073496-4 and compositions and methods for the identification and/or detection thereof |
CA2818918A1 (en) | 2010-11-24 | 2012-05-31 | Pioneer Hi-Bred International, Inc. | Brassica gat event dp-061061-7 and compositions and methods for the identification and/or detection thereof |
US8946270B2 (en) | 2011-06-27 | 2015-02-03 | Merial Limited | Amido-pyridyl ether compounds and compositions and their use against parasites |
BR112014031260A2 (en) | 2012-06-15 | 2019-08-20 | Du Pont | methods and compositions involving native substrate-preferable als variants |
AU2013361220A1 (en) | 2012-12-21 | 2015-04-02 | Pioneer Hi-Bred International, Inc. | Compositions and methods for auxin-analog conjugation |
CA2905743C (en) | 2013-03-13 | 2021-09-28 | Pioneer Hi-Bred International, Inc. | Glyphosate application for weed control in brassica |
AU2014236162A1 (en) | 2013-03-14 | 2015-09-17 | Arzeda Corp. | Compositions having dicamba decarboxylase activity and methods of use |
US20160053277A1 (en) | 2013-03-14 | 2016-02-25 | Pioneer Hi-Bred International, Inc. | Compositions Having Dicamba Decarboxylase Activity and Methods of Use |
AU2014334590A1 (en) | 2013-10-18 | 2016-04-28 | Pioneer Hi-Bred International, Inc. | Glyphosate-N-acetyltransferase (GLYAT) sequences and methods of use |
KR102341193B1 (en) | 2013-11-01 | 2021-12-17 | 뵈링거 잉겔하임 애니멀 헬스 유에스에이 인코포레이티드 | Antiparasitic and pesticidal isoxazoline compounds |
US12016335B2 (en) | 2013-11-25 | 2024-06-25 | Fmc Corporation | Stabilized low-concentration metsulfuron-methyl liquid composition |
PT3073823T (en) | 2013-11-25 | 2018-02-26 | Du Pont | Stabilized low-concentration metsulfuron-methyl liquid composition |
WO2016102504A1 (en) * | 2014-12-22 | 2016-06-30 | Mitsui Agriscience International S.A./N.V. | Herbicidal oil dispersion |
CN111713504A (en) | 2014-12-22 | 2020-09-29 | 三井农业化学国际有限公司 | Liquid herbicidal composition containing sulfonylurea |
EA033330B1 (en) | 2016-06-21 | 2019-09-30 | Баттелл Юк Лимитед | LIQUID SULFONYLUREA- AND Li-SALT CONTAINING HERBICIDAL COMPOSITIONS |
BR112019007605A2 (en) | 2016-10-14 | 2019-09-17 | Boehringer Ingelheim Animal Health Usa Inc | pesticide and parasiticide compounds of vinyl isoxazoline |
WO2019036407A1 (en) | 2017-08-14 | 2019-02-21 | Merial, Inc. | Pesticidal and parasiticidal pyrazole-isoxazoline compounds |
EP3900535A1 (en) | 2020-04-24 | 2021-10-27 | Battelle UK Limited | Liquid sulfonylurea herbicide composition |
RU2767999C1 (en) * | 2021-08-05 | 2022-03-22 | ООО "Агро Эксперт Груп" | Liquid herbicide composition |
RU2771039C1 (en) * | 2021-08-05 | 2022-04-25 | ООО "Агро Эксперт Груп" | Liquid herbicidal composition |
Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5364832A (en) * | 1990-08-10 | 1994-11-15 | Hoechst Aktiengesellschaft | Water-dispersible granules comprising fenoxaprop-ethyl and/or fenchlorazole |
US5488027A (en) * | 1990-12-21 | 1996-01-30 | Hoechst Aktiengesellschaft | Herbicide-safener combinations containing sulfonylurea or imidazolinone herbicides |
US5504054A (en) * | 1993-03-30 | 1996-04-02 | Osi Specialties, Inc. | Super-spreading, low-foam surfactant for agricultural spray mixtures |
US5521144A (en) * | 1992-09-18 | 1996-05-28 | Central Soya Company, Inc. | Herbicide composition |
US6090750A (en) * | 1996-03-13 | 2000-07-18 | Novartis Ag | Herbicidal combinations |
US20020004457A1 (en) * | 1998-11-10 | 2002-01-10 | Nevill David John | Herbicidal composition |
US20020016263A1 (en) * | 2000-04-27 | 2002-02-07 | Jochen Wurtz | Liquid formulations |
US20020042345A1 (en) * | 2000-05-11 | 2002-04-11 | Jean Kocur | Combination of crop protection agents with hydrogen bond-forming polymers |
US6479432B1 (en) * | 1999-10-26 | 2002-11-12 | Aventis Cropscience Gmbh | Non-aqueous or low-water suspension concentrates of mixtures of active compounds for crop protection |
US6511940B1 (en) * | 1998-06-23 | 2003-01-28 | Hoechst Schering Agrevo Gmbh | Combination of herbicides and safeners |
US20040023803A1 (en) * | 2000-08-31 | 2004-02-05 | Jaeger Karl-Friedrich | Method for producing a solid herbicide formulation |
US20040157737A1 (en) * | 1994-11-11 | 2004-08-12 | Lothar Willms | Combinations of phenylsulfonylurea herbicides and safeners |
US6841517B1 (en) * | 1999-09-30 | 2005-01-11 | Bayer Aktiengesellschaft | Selective herbicides on basis of N-aryl-triazoline(thi)ones |
US6908883B2 (en) * | 1998-06-16 | 2005-06-21 | Basf Ag | Synergistically acting herbicidal mixtures |
US7915199B1 (en) * | 1999-09-07 | 2011-03-29 | Syngenta Crop Protection, Inc. | Herbicidal composition |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19834627A1 (en) * | 1998-07-31 | 1998-12-03 | Novartis Ag | Broad-spectrum pre- or post=emergence herbicidal composition |
DE19834629A1 (en) * | 1998-07-31 | 1998-12-03 | Novartis Ag | Broad-spectrum pre- or post=emergence herbicidal composition |
DE19919951A1 (en) * | 1999-04-30 | 1999-09-16 | Novartis Ag | Herbicidal composition for selective control of weeds and grasses in crops that are resistant to protoporphyrinogen oxidase inhibitors |
DE19960918A1 (en) | 1999-11-18 | 2001-05-23 | Bayer Ag | Synergistic herbicidal combinations of active ingredients |
CA2390570A1 (en) | 1999-11-18 | 2001-05-25 | Bayer Aktiengesellschaft | Synergistic herbicidal active substance combinations |
CN100527959C (en) * | 2002-07-08 | 2009-08-19 | 巴斯福股份公司 | Synergistically acting herbicidal mixtures |
-
2004
- 2004-10-21 AT AT04790700T patent/ATE389327T1/en not_active IP Right Cessation
- 2004-10-21 DE DE502004006612T patent/DE502004006612D1/en not_active Expired - Lifetime
- 2004-10-21 AU AU2004285269A patent/AU2004285269B2/en not_active Ceased
- 2004-10-21 CA CA002544415A patent/CA2544415A1/en not_active Abandoned
- 2004-10-21 WO PCT/EP2004/011893 patent/WO2005041654A2/en active IP Right Grant
- 2004-10-21 ES ES04790700T patent/ES2302038T3/en not_active Expired - Lifetime
- 2004-10-21 PL PL04790700T patent/PL1681932T3/en unknown
- 2004-10-21 EA EA200600856A patent/EA012521B1/en not_active IP Right Cessation
- 2004-10-21 EP EP04790700A patent/EP1681932B1/en not_active Revoked
- 2004-10-21 UA UAA200606174A patent/UA83698C2/en unknown
- 2004-10-21 DK DK04790700T patent/DK1681932T3/en active
- 2004-10-21 BR BRPI0416159-9A patent/BRPI0416159A/en not_active IP Right Cessation
- 2004-10-28 US US10/976,217 patent/US7432226B2/en active Active
- 2004-11-01 TW TW093133238A patent/TW200517058A/en unknown
- 2004-11-01 AR ARP040104023A patent/AR046224A1/en not_active Application Discontinuation
-
2006
- 2006-05-01 IL IL175359A patent/IL175359A0/en unknown
-
2008
- 2008-08-29 US US12/201,115 patent/US20090054236A1/en not_active Abandoned
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5364832A (en) * | 1990-08-10 | 1994-11-15 | Hoechst Aktiengesellschaft | Water-dispersible granules comprising fenoxaprop-ethyl and/or fenchlorazole |
US5488027A (en) * | 1990-12-21 | 1996-01-30 | Hoechst Aktiengesellschaft | Herbicide-safener combinations containing sulfonylurea or imidazolinone herbicides |
US5521144A (en) * | 1992-09-18 | 1996-05-28 | Central Soya Company, Inc. | Herbicide composition |
US5504054A (en) * | 1993-03-30 | 1996-04-02 | Osi Specialties, Inc. | Super-spreading, low-foam surfactant for agricultural spray mixtures |
US20040157737A1 (en) * | 1994-11-11 | 2004-08-12 | Lothar Willms | Combinations of phenylsulfonylurea herbicides and safeners |
US6090750A (en) * | 1996-03-13 | 2000-07-18 | Novartis Ag | Herbicidal combinations |
US6908883B2 (en) * | 1998-06-16 | 2005-06-21 | Basf Ag | Synergistically acting herbicidal mixtures |
US6511940B1 (en) * | 1998-06-23 | 2003-01-28 | Hoechst Schering Agrevo Gmbh | Combination of herbicides and safeners |
US20020004457A1 (en) * | 1998-11-10 | 2002-01-10 | Nevill David John | Herbicidal composition |
US7915199B1 (en) * | 1999-09-07 | 2011-03-29 | Syngenta Crop Protection, Inc. | Herbicidal composition |
US6841517B1 (en) * | 1999-09-30 | 2005-01-11 | Bayer Aktiengesellschaft | Selective herbicides on basis of N-aryl-triazoline(thi)ones |
US6479432B1 (en) * | 1999-10-26 | 2002-11-12 | Aventis Cropscience Gmbh | Non-aqueous or low-water suspension concentrates of mixtures of active compounds for crop protection |
US20020016263A1 (en) * | 2000-04-27 | 2002-02-07 | Jochen Wurtz | Liquid formulations |
US20020042345A1 (en) * | 2000-05-11 | 2002-04-11 | Jean Kocur | Combination of crop protection agents with hydrogen bond-forming polymers |
US20040023803A1 (en) * | 2000-08-31 | 2004-02-05 | Jaeger Karl-Friedrich | Method for producing a solid herbicide formulation |
Non-Patent Citations (1)
Title |
---|
Hackh's Chemical Dictionary, 4th ed., McGraw-Hill Book Co., NY, 1969 (USPTO stamp 1977), page 170. * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140302990A1 (en) * | 2013-04-03 | 2014-10-09 | Fmc Corporation | Suspoemulsion of Fomesafen and Fluthiacet-Methyl |
WO2014163654A1 (en) * | 2013-04-03 | 2014-10-09 | Fmc Corporation | Suspoemulsion of fomesafen and fluthiacet-methyl |
US9770030B2 (en) * | 2013-04-03 | 2017-09-26 | Fmc Corporation | Suspoemulsion of fomesafen and fluthiacet-methyl |
US20180007906A1 (en) * | 2013-04-03 | 2018-01-11 | Fmc Corporation | Suspoemulsion of fomesafen and fluthiacet-methyl |
WO2015139586A1 (en) * | 2014-03-21 | 2015-09-24 | Rotam Agrochem International Company Limited | A herbicidal composition comprising metsulfuron-methyl, thifensulfuron-methyl and tribenuron-methyl and the use thereof |
WO2021205448A1 (en) | 2020-04-06 | 2021-10-14 | Adama Agan Ltd. | Co-crystals of antioxidants and active ingredients and use of antioxidants as stabilizer |
Also Published As
Publication number | Publication date |
---|---|
ATE389327T1 (en) | 2008-04-15 |
WO2005041654A2 (en) | 2005-05-12 |
AU2004285269A1 (en) | 2005-05-12 |
WO2005041654A3 (en) | 2005-07-21 |
TW200517058A (en) | 2005-06-01 |
DK1681932T3 (en) | 2008-07-21 |
AR046224A1 (en) | 2005-11-30 |
AU2004285269B2 (en) | 2010-07-01 |
CA2544415A1 (en) | 2005-05-12 |
ES2302038T3 (en) | 2008-07-01 |
DE502004006612D1 (en) | 2008-04-30 |
IL175359A0 (en) | 2006-09-05 |
US20050113254A1 (en) | 2005-05-26 |
PL1681932T3 (en) | 2008-08-29 |
US7432226B2 (en) | 2008-10-07 |
EP1681932A2 (en) | 2006-07-26 |
UA83698C2 (en) | 2008-08-11 |
EA200600856A1 (en) | 2006-10-27 |
EA012521B1 (en) | 2009-10-30 |
BRPI0416159A (en) | 2007-01-16 |
EP1681932B1 (en) | 2008-03-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7432226B2 (en) | Herbicidally active composition | |
CA2745705C (en) | Dispersions comprising inhibitors of the hydroxyphenylpyruvate-dioxygenase | |
EP1130965B2 (en) | Combinations of herbicides and safeners | |
DK1571908T3 (en) | OIL SUSPENSION CONCENTRATE | |
AU2006319527B2 (en) | Liquid formulations containing dialkyl sulfosuccinate and hydroxyphenylpyruvate dioxygenase inhibitors | |
DK1928232T3 (en) | Fast formulation | |
DE10351234A1 (en) | Herbicidal composition useful for selective weed control in crops comprises a sulfonylurea herbicide and a safener | |
MXPA06004954A (en) | Herbicidally active agent | |
DE10355846A1 (en) | Herbicidal composition useful for selective weed control in crops comprises a sulfonylurea herbicide and a safener | |
DE10351233A1 (en) | Chemically stable oily emulsion herbicide concentrates, useful for selective weed control in crops, comprising sulfonamide herbicide, safener, organic solvent and sulfosuccinate |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |