US20080150002A1 - Simultaneous Formation of a Top Oxide Layer in a Silicon-Oxide-Nitride-Oxide-Silicon (SONOS) Transistor and a Gate Oxide in a Metal Oxide Semiconductor (MOS) - Google Patents
Simultaneous Formation of a Top Oxide Layer in a Silicon-Oxide-Nitride-Oxide-Silicon (SONOS) Transistor and a Gate Oxide in a Metal Oxide Semiconductor (MOS) Download PDFInfo
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- US20080150002A1 US20080150002A1 US11/615,683 US61568306A US2008150002A1 US 20080150002 A1 US20080150002 A1 US 20080150002A1 US 61568306 A US61568306 A US 61568306A US 2008150002 A1 US2008150002 A1 US 2008150002A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/30—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/40—EEPROM devices comprising charge-trapping gate insulators characterised by the peripheral circuit region
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/69—IGFETs having charge trapping gate insulators, e.g. MNOS transistors
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/661—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/68—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
- H10D64/681—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator having a compositional variation, e.g. multilayered
- H10D64/685—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator having a compositional variation, e.g. multilayered being perpendicular to the channel plane
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/68—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
- H10D64/693—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator the insulator comprising nitrogen, e.g. nitrides, oxynitrides or nitrogen-doped materials
Definitions
- the present invention relates to the field of microelectronic integrated circuits. Specifically, the present invention relates to simultaneous formation of the top oxide in a nonvolatile silicon oxide nitride oxide silicon (SONOS) based nonvolatile memory transistor and a gate oxide for a metal oxide semiconductor (MOS) transistor included within control circuits.
- SONOS nonvolatile silicon oxide nitride oxide silicon
- MOS metal oxide semiconductor
- Some semiconductor chips include SONOS based nonvolatile memory transistors, and MOS transistors in various configurations.
- the MOS transistors are located within control circuits, which can be located in the nonvolatile memory array, volatile memory array, or a peripheral control circuit.
- the MOS transistors in the control circuits include, in part, pass gate transistors in the nonvolatile memory array for controlling access to SONOS based nonvolatile memory transistors, peripheral MOS transistors in the peripheral control circuit, and volatile transistors in the volatile memory array.
- a current process flow for fabricating a nonvolatile memory device separately forms the top oxide in a oxide-nitride-oxide (ONO) structure and a gate oxide of a MOS transistor used in a control circuit.
- the tunnel oxide, nitride, and the top oxide are sequentially formed on a silicon substrate for the ONO structure.
- the top oxide layer is typically a deposited oxide which is not dense and easily etched during subsequent cleaning processes. As such, the top oxide layer may be further densified to minimize losses to the top oxide layer processing steps.
- the ONO layers are patterned and etched from the silicon surface except for areas where the SONOS memory transistors are formed. Also, the gate oxides of MOS transistors located on the semiconductor chip are formed separately through thermal oxidation. Unfortunately, even after densification, the top oxide of the ONO structure is susceptible to etching during subsequent cleaning steps, which results in a non-uniform top oxide layer of the ONO structure. As a result, the thickness of the top oxide layer in the ONO structure is hard to control, which can lead to lower yields.
- a method for semiconductor fabrication includes providing a silicon substrate and forming a tunnel oxide layer over the silicon substrate. Thereafter, a nitride layer is formed over the tunnel oxide layer. The nitride layer and the tunnel oxide layer are etched except where at least one nonvolatile silicon oxide nitride oxide silicon (SONOS) transistor is formed. Additionally, oxide layers are simultaneously formed over the nitride layer corresponding to where at least one SONOS memory transistor is formed and over the exposed silicon substrate corresponding to where at least one metal oxide semiconductor (MOS) transistor is formed.
- SONOS nonvolatile silicon oxide nitride oxide silicon
- a semiconductor chip in an alternate configuration, includes a silicon-oxide-nitride-oxide-silicon (SONOS) nonvolatile memory transistor.
- the SONOS based nonvolatile memory transistor comprises an oxide-nitride-oxide (ONO) structure, wherein the ONO structure comprises a top oxide layer.
- the semiconductor chip also includes at least one MOS transistor, wherein the MOS transistor includes a gate oxide formed from a gate oxide layer, wherein a quality of the top oxide layer is substantially similar to a quality of the gate oxide layer of the at least one MOS transistor.
- FIG. 1 is a simplified block diagram illustrating a semiconductor chip implementing the simultaneous formation of oxide layers, in accordance with one embodiment of the present invention.
- FIG. 2 is a flow diagram illustrating the process flow for simultaneously forming oxide layers in a semiconductor chip, in accordance with one embodiment of the present invention.
- FIG. 3A is a simplified depiction of multiple transistors in cross section showing the formation of the nitride and tunnel oxide layers, in accordance with one embodiment of the present invention.
- FIG. 3B is a simplified depiction of multiple transistors in cross section showing the isolation of the SONOS memory transistor, in accordance with one embodiment of the present invention.
- FIG. 3C is a simplified depiction of multiple transistors in cross section showing the simultaneous formation of the top oxide of the SONOS transistor and the gate oxide of a MOS transistor in a control circuit, in accordance with one embodiment of the present invention.
- FIG. 4 is a flow diagram illustrating the process flow for simultaneous formation of oxide layers for a SONOS based nonvolatile memory transistor and at least one corresponding pass-gate MOS transistor, in accordance with one embodiment of the present invention.
- FIG. 5 is simplified depiction of tri-gate structure in cross section for a nonvolatile memory cell as a specific example of the simultaneous formation of oxide layers for a SONOS based nonvolatile memory transistor and at least one corresponding pass-gate MOS transistor, in accordance with one embodiment of the present invention.
- embodiments of the present invention provide for simultaneous fabrication of the top oxide of the SONOS based nonvolatile memory transistor and a gate oxide of at least one MOS transistor, located in a control circuit.
- the SONOS based nonvolatile memory device has a more uniform thickness for the top oxide layer of the ONO structure of the SONOS based nonvolatile memory transistor.
- simultaneous fabrication of the top oxide of the SONOS based nonvolatile memory transistor and a gate oxide of at least one MOS transistor, located in a control circuit reduces the number of processing steps which saves the overall process costs for manufacturing, for example of a nonvolatile static random access memory (nvSRAM) memory device.
- nvSRAM nonvolatile static random access memory
- FIG. 2 in combination with FIGS. 3A-C illustrate the simultaneous formation of a top oxide layer in at least one SONOS based transistor and a gate oxide of at least one MOS transistor for a control circuit, in accordance with one embodiment of the present invention.
- FIG. 2 is a flow chart illustrating a manufacturing process for the simultaneous formation of the top oxide layer in the SONOS based nonvolatile memory transistor and the gate oxide layer that forms the gate oxide of a MOS transistor of a control circuit, in accordance with one embodiment of the present invention.
- the multiple transistors shown in FIG. 3A that are formed on the silicon substrate can be located in the semiconductor chip 100 of FIG. 1 , in accordance with one embodiment of the present invention.
- the SONOS based nonvolatile memory transistors are located in the nonvolatile memory 117 , in one embodiment.
- the MOS transistors are located in the control circuits of the semiconductor chip.
- the control circuits include, in part, the nonvolatile memory 117 , the volatile memory 115 , and the peripheral circuit 120 .
- the process of FIG. 2 can be implemented to form any configuration of circuit elements comprising at least one SONOS based transistor and at least one MOS transistor of a control circuit on a semiconductor chip.
- a SONOS based transistor 320 is located in the region to the right of line A-A.
- the SONOS based transistor 320 comprises a nonvolatile memory transistor, in one embodiment.
- MOS transistor 310 is formed in the region to the left of line A-A.
- MOS transistor 310 can be formed adjacent to SONOS based transistor 320 , in one embodiment.
- MOS transistor 310 and SONOS based transistor 320 are configured as an nonvolatile memory (NVM) cell, for example in an nvSRAM architecture, in one embodiment.
- NVM nonvolatile memory
- the densification step is not required since the O2 plasma oxidation technique forms a top oxide layer of sufficient density such that subsequent process steps do not significantly erode the top oxide layer.
- the quality of the top oxide formed through O2 plasma oxidation is of higher quality than the top oxide formed through deposition using conventional techniques.
- the present embodiment provides a silicon substrate upon which circuit elements can be formed.
- the present embodiment forms a tunnel oxide layer over the silicon substrate.
- the present embodiment forms a nitride layer over the tunnel oxide layer.
- the operation at 410 is analogous to the operation 210 of FIG. 2 .
- the operations at 420 and 430 are analogous to the operations at 220 and 230 , respectively, of FIG. 2 .
- a full discussion of the formation of the tunnel oxide layer and the nitride layer is presented in relation to operations 220 and 230 and will not be repeated here.
- the present embodiment isolates a first area in the nitride layer.
- the first area corresponds to the formation of a SONOS based nonvolatile memory transistor.
- a resist layer can be formed to isolate the region where the SONOS based nonvolatile memory transistor is subsequently formed.
- a second area in the nitride layer corresponds to where a first pass-gate MOS transistor is formed, wherein the first pass-gate MOS transistor is adjacent to where the SONOS based nonvolatile memory transistor is formed, and a third area in the nitride layer corresponds to where a second pass-gate MOS transistor is formed adjacent to SONOS based nonvolatile memory transistor.
- the SONOS based nonvolatile memory transistor and the first and second pass-gate MOS transistors are configured in a tri-gate SONOS based NVM configuration
- the present embodiment patterns and etches the nitride layer and the tunnel oxide layer in the second and third areas. Specifically, the tunnel oxide layer and the nitride layer are etched in the second and third areas corresponding to the formation of the first and second pass-gate MOS transistors. For purposes of embodiments of the present invention, etching the tunnel oxide layer and the nitride layer is analogous to removing the tunnel oxide layer and the nitride layer. As such, the silicon substrate is exposed in the second and third areas corresponding to the formation of the first and second pass-gate MOS transistors.
- the present embodiment simultaneously forms oxide layers over remaining portions of the nitride layer over the first area, and over exposed areas of the silicon substrate corresponding to the second area and the third area. Specifically, a top oxide layer is formed over the nitride layer in the region corresponding to the formation of the SONOS based nonvolatile memory transistor. In addition, a gate oxide layer for the MOS transistors is simultaneously formed over the exposed silicon substrate.
- FIG. 5 is a simplified illustration depicting a SONOS based NVM configuration 500 in cross section, in accordance with one embodiment of the present invention.
- the SONOS based NVM configuration 500 shown in FIG. 5 results from the process steps described in FIG. 2 , and more particularly from FIG. 4 , in accordance with one embodiment of the present invention.
- the SONOS based NVM configuration 500 is fabricated such that the top oxide layer in at least one SONOS based nonvolatile memory transistor is formed simultaneously with the gate oxide layer over a silicon substrate from which is formed a gate oxide for at least one corresponding pass-gate MOS transistor.
- the at least one corresponding pass-gate MOS transistor controls access to the SONOS based nonvolatile memory transistor.
- NVM configuration 500 shown in FIG. 5 can be implemented within an nvSRAM memory array, in one embodiment.
- Other embodiments are well suited to using the NVM configuration 500 in other memory structures.
- FIG. 5 shows n-channel MOS transistors 520 , 540 and an n-channel SONOS based transistor 530 formed over a p-type silicon substrate 510 for the NVM configuration 500 .
- the NVM configuration 500 can comprise any combination of n-channel and p-channel transistors built over n-type or p-type substrates.
- the SONOS based NVM configuration 500 comprises a SONOS based nonvolatile memory transistor 530 .
- the SONOS based nonvolatile memory transistor 530 comprises an ONO structure 535 which includes a tunnel oxide layer, a nitride layer, and a top oxide layer.
- the SONOS based NVM configuration 500 comprises a first pass-gate MOS transistor 520 adjacent the SONOS based nonvolatile memory transistor 530 .
- the first pass-gate MOS transistor 520 comprises a first gate oxide 523 that is formed simultaneously with the top oxide layer in the ONO structure 535 .
- the oxidation rates for forming the top oxide layer of the SONOS based nonvolatile memory transistor and the first gate oxide 523 are different, which is reflected in the relative sizes of each layer.
- the density of the top oxide layer in the ONO structure 535 is substantially similar to the density of the first gate oxide 523 , in one embodiment.
- the quality of top oxide layer in the ONO structure 535 formed through plasma oxidation is better than the quality of a top oxide layer formed through conventional deposition techniques.
- conventional deposition techniques will introduce more impurities into the top oxide layer than a top oxide layer that is formed through plasma oxidation techniques, in embodiments of the present invention.
- the SONOS based nonvolatile memory cell 500 comprises a second pass-gate MOS transistor 540 adjacent the SONOS based nonvolatile memory transistor 530 .
- the second pass-gate MOS transistor 525 comprises a second gate oxide 543 that is formed simultaneously with the top oxide layer in the ONO structure 535 .
- the oxidation rates for forming the top oxide layer of the SONOS based nonvolatile memory transistor 530 and the second gate oxide 543 are different, which is reflected in the relative sizes of each layer.
- the second gate oxide 543 is basically the same as the first gate oxide 523 .
- the density of the top oxide layer in the ONO structure 535 is substantially similar to the density of the second gate oxide 543 , in one embodiment.
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Abstract
Description
- 1. Field of Invention
- The present invention relates to the field of microelectronic integrated circuits. Specifically, the present invention relates to simultaneous formation of the top oxide in a nonvolatile silicon oxide nitride oxide silicon (SONOS) based nonvolatile memory transistor and a gate oxide for a metal oxide semiconductor (MOS) transistor included within control circuits.
- 2. The Relevant Technology
- Some semiconductor chips include SONOS based nonvolatile memory transistors, and MOS transistors in various configurations. In particular, the MOS transistors are located within control circuits, which can be located in the nonvolatile memory array, volatile memory array, or a peripheral control circuit. The MOS transistors in the control circuits include, in part, pass gate transistors in the nonvolatile memory array for controlling access to SONOS based nonvolatile memory transistors, peripheral MOS transistors in the peripheral control circuit, and volatile transistors in the volatile memory array.
- A current process flow for fabricating a nonvolatile memory device separately forms the top oxide in a oxide-nitride-oxide (ONO) structure and a gate oxide of a MOS transistor used in a control circuit. Specifically, the tunnel oxide, nitride, and the top oxide are sequentially formed on a silicon substrate for the ONO structure. The top oxide layer is typically a deposited oxide which is not dense and easily etched during subsequent cleaning processes. As such, the top oxide layer may be further densified to minimize losses to the top oxide layer processing steps.
- The ONO layers are patterned and etched from the silicon surface except for areas where the SONOS memory transistors are formed. Also, the gate oxides of MOS transistors located on the semiconductor chip are formed separately through thermal oxidation. Unfortunately, even after densification, the top oxide of the ONO structure is susceptible to etching during subsequent cleaning steps, which results in a non-uniform top oxide layer of the ONO structure. As a result, the thickness of the top oxide layer in the ONO structure is hard to control, which can lead to lower yields.
- A method for semiconductor fabrication includes providing a silicon substrate and forming a tunnel oxide layer over the silicon substrate. Thereafter, a nitride layer is formed over the tunnel oxide layer. The nitride layer and the tunnel oxide layer are etched except where at least one nonvolatile silicon oxide nitride oxide silicon (SONOS) transistor is formed. Additionally, oxide layers are simultaneously formed over the nitride layer corresponding to where at least one SONOS memory transistor is formed and over the exposed silicon substrate corresponding to where at least one metal oxide semiconductor (MOS) transistor is formed.
- In an alternate configuration, a semiconductor chip includes a silicon-oxide-nitride-oxide-silicon (SONOS) nonvolatile memory transistor. The SONOS based nonvolatile memory transistor comprises an oxide-nitride-oxide (ONO) structure, wherein the ONO structure comprises a top oxide layer. The semiconductor chip also includes at least one MOS transistor, wherein the MOS transistor includes a gate oxide formed from a gate oxide layer, wherein a quality of the top oxide layer is substantially similar to a quality of the gate oxide layer of the at least one MOS transistor.
- Exemplary embodiments are illustrated in referenced figures of the drawings which illustrate what is regarded as the preferred embodiments presently contemplated. It is intended that the embodiments and figures disclosed herein are to be considered illustrative rather than limiting.
-
FIG. 1 is a simplified block diagram illustrating a semiconductor chip implementing the simultaneous formation of oxide layers, in accordance with one embodiment of the present invention. -
FIG. 2 is a flow diagram illustrating the process flow for simultaneously forming oxide layers in a semiconductor chip, in accordance with one embodiment of the present invention. -
FIG. 3A is a simplified depiction of multiple transistors in cross section showing the formation of the nitride and tunnel oxide layers, in accordance with one embodiment of the present invention. -
FIG. 3B is a simplified depiction of multiple transistors in cross section showing the isolation of the SONOS memory transistor, in accordance with one embodiment of the present invention. -
FIG. 3C is a simplified depiction of multiple transistors in cross section showing the simultaneous formation of the top oxide of the SONOS transistor and the gate oxide of a MOS transistor in a control circuit, in accordance with one embodiment of the present invention. -
FIG. 4 is a flow diagram illustrating the process flow for simultaneous formation of oxide layers for a SONOS based nonvolatile memory transistor and at least one corresponding pass-gate MOS transistor, in accordance with one embodiment of the present invention. -
FIG. 5 is simplified depiction of tri-gate structure in cross section for a nonvolatile memory cell as a specific example of the simultaneous formation of oxide layers for a SONOS based nonvolatile memory transistor and at least one corresponding pass-gate MOS transistor, in accordance with one embodiment of the present invention. - Reference will now be made in detail to the preferred embodiments of the present invention, a method for simultaneous formation of the top oxide of a SONOS transistor and a gate oxide of at least one MOS transistor located in a control circuit. While the invention will be described in conjunction with the preferred embodiments, it will be understood that they are not intended to limit the invention to these embodiments. On the contrary, the invention is intended to cover alternatives, modifications and equivalents which may be included within the spirit and scope of the invention as defined by the appended claims.
- Accordingly, embodiments of the present invention provide for simultaneous fabrication of the top oxide of the SONOS based nonvolatile memory transistor and a gate oxide of at least one MOS transistor, located in a control circuit. In particular, in one embodiment, the SONOS based nonvolatile memory device has a more uniform thickness for the top oxide layer of the ONO structure of the SONOS based nonvolatile memory transistor. Also, in other embodiments, simultaneous fabrication of the top oxide of the SONOS based nonvolatile memory transistor and a gate oxide of at least one MOS transistor, located in a control circuit, reduces the number of processing steps which saves the overall process costs for manufacturing, for example of a nonvolatile static random access memory (nvSRAM) memory device. In addition, in other embodiments simultaneous formation of the top oxide layer in the ONO structure of the SONOS based nonvolatile memory transistor and the gate oxide of the MOS transistor, located in a control circuit, improves the overall quality of the top oxide layer of the SONOS based nonvolatile memory transistor to as good as the gate oxide of the MOS transistors. These characteristics can lead to increased yields for the semiconductor chip.
- For illustration,
FIG. 1 illustrates a simplified functional block diagram of ageneral semiconductor chip 100 implementing the simultaneous formation of a top oxide layer of a SONOS based nonvolatile memory transistor and a gate oxide layer for MOS transistors located in control circuits, in accordance with one embodiment of the present invention. In particular, thesemiconductor chip 100 includes amemory array 110, and aperipheral control circuit 120 for supporting and controlling, in part, thememory array 110. - The
memory array 110 includes two different memory arrays comprising avolatile memory 115 and anonvolatile memory 117.Peripheral circuit 120 controls thevolatile memory 115,nonvolatile memory 117, and any other chip functions. Theperipheral circuit 120 is partly comprised of MOS transistors, for example in any of a variety of complementary metal oxide semiconductor (CMOS) configurations, each of which includes a pair of n-channel MOS and p-channel MOS transistors. - The
volatile memory 115 includes a plurality of volatile memory cells, such as static random access memory (SRAM) cells, each of which is capable of storing and communicating a single bit of data to and from an external environment that is outside of thememory array 110, or communicating internally with thenonvolatile memory 117. More particularly, each volatile memory cell in thevolatile portion 115 is capable, as long as power is being supplied, of receiving a bit of data from the exterior environment, including thenonvolatile memory 117 andperipheral control circuit 120, retaining the bit of data, and transmitting the bit of data back to the exterior environment. - The
nonvolatile memory 117 includes a plurality of nonvolatile memory cells for providing backup storage to the plurality of volatile memory cells in thevolatile memory 115. The nonvolatile cells each comprises a SONOS based memory transistor, wherein the ONO layer comprises a top oxide layer. In general, thenonvolatile memory 117 includes a combination of a plurality of SONOS based nonvolatile memory transistors and pass-gate MOS transistors. - More particularly, each volatile memory cell can be associated with at least one corresponding nonvolatile memory cell that prevents the loss of data from the plurality of volatile memory cells due to a loss of power, for example.
- Embodiments of the present invention are implemented for the simultaneous formation of the top oxide layer in each of the SONOS based nonvolatile memory transistors included within the
nonvolatile memory 117 ofFIG. 1 and the gate oxide layer that is used to form the gate oxides of a plurality of MOS transistors found both within thememory array 110 and theperipheral circuit 120. -
FIG. 2 in combination withFIGS. 3A-C illustrate the simultaneous formation of a top oxide layer in at least one SONOS based transistor and a gate oxide of at least one MOS transistor for a control circuit, in accordance with one embodiment of the present invention. In particular,FIG. 2 is a flow chart illustrating a manufacturing process for the simultaneous formation of the top oxide layer in the SONOS based nonvolatile memory transistor and the gate oxide layer that forms the gate oxide of a MOS transistor of a control circuit, in accordance with one embodiment of the present invention.FIGS. 3A , 3B, and 3C are cross-sections of the SONOS based transistor and at least one MOS transistor during the fabrication of a semiconductor chip (e.g., an nvSRAM memory), in accordance with one embodiment of the present invention.FIGS. 3A , 3B, and 3C are not drawn to scale. - Turning now to
FIG. 2 , at 210, the present embodiment provides a silicon substrate upon which various circuit elements can be formed. At 220, the present embodiment forms a tunnel oxide layer over the silicon substrate. For example, inFIG. 3A , across-section 300A of intermediate formations of multiple transistors is shown, in accordance with one embodiment of the present invention. Specifically, thetunnel oxide layer 340 is formed on thebare silicon substrate 305. Thetunnel oxide layer 340 is conventionally formed by thermal oxidation. Other techniques can also be used to form thetunnel oxide layer 340, in other embodiments - The multiple transistors shown in
FIG. 3A that are formed on the silicon substrate can be located in thesemiconductor chip 100 ofFIG. 1 , in accordance with one embodiment of the present invention. In particular, the SONOS based nonvolatile memory transistors are located in thenonvolatile memory 117, in one embodiment. In still other embodiments, the MOS transistors are located in the control circuits of the semiconductor chip. The control circuits include, in part, thenonvolatile memory 117, thevolatile memory 115, and theperipheral circuit 120. In other embodiments, the process ofFIG. 2 can be implemented to form any configuration of circuit elements comprising at least one SONOS based transistor and at least one MOS transistor of a control circuit on a semiconductor chip. - As shown in
FIG. 3A , a SONOS basedtransistor 320 is located in the region to the right of line A-A. The SONOS basedtransistor 320 comprises a nonvolatile memory transistor, in one embodiment. - Also, at least one MOS transistor of a control circuit is formed. For instance, in
FIG. 3A ,MOS transistor 310 is formed in the region to the left of line A-A.MOS transistor 310 can be formed adjacent to SONOS basedtransistor 320, in one embodiment. For instance,MOS transistor 310 and SONOS basedtransistor 320 are configured as an nonvolatile memory (NVM) cell, for example in an nvSRAM architecture, in one embodiment. - In another embodiment, as represented in
FIG. 3A MOS transistor 310 is formed peripherally from SONOS basedtransistor 320. For instance,MOS transistor 310 is formed in theperipheral circuit 120 ofFIG. 1 . Also in another instance,MOS transistor 310 can be formed in thevolatile memory 115 ofFIG. 1 . - Returning to
FIG. 2 , at 230, a nitride layer is formed over the tunnel oxide layer, in the present embodiment. In one embodiment, the nitride layer comprises an oxynitride. In the example provided inFIG. 3A , anitride layer 350 is formed on the top oftunnel oxide layer 340.Nitride layer 350 can be formed using any number of techniques, such as chemical vapor deposition techniques, in embodiments of the present invention. - At 240, the nitride layer and the tunnel oxide layer are selectively etched. For purposes of embodiments of the present invention, etching of the nitride layer and the tunnel oxide layer is analogous with removing the nitride layer and the tunnel oxide layer, in one embodiment. Specifically, the nitride layer and the tunnel oxide layer are etched except where at least one SONOS based nonvolatile memory transistor is formed. In one embodiment, the etching is accomplished after patterning of a masking layer (e.g., photoresist) over a region where the at least one SONOS based nonvolatile memory transistor is formed.
-
FIG. 3B is across section 300B showing the continued formation fromFIG. 3A of the semiconductor chip. In the example provided inFIG. 3B , thetunnel oxide layer 340 andnitride layer 350 are etched in the regions corresponding to the formation ofMOS transistor 310. That is, resistlayer 307 outlines the regions wherenitride layer 350 andtunnel oxide layer 340 are etched. In particular,tunnel oxide layer 340 andnitride layer 350 are etched in the region to the left of line A-A, as shown in FIG. A. In this region, thetunnel oxide layer 340 andnitride layer 350 are etched to expose thebare silicon substrate 305. - At 250, oxide layers are simultaneously formed over the nitride layer of at least one SONOS based transistor and over the exposed silicon substrate. That is, the oxide layers are simultaneously formed over the region corresponding to the formation of the SONOS based transistor and the regions where at least one MOS transistor for control circuitry is formed. Specifically, the top oxide layer is formed over the nitride layer of the SONOS based transistor and the gate oxide layer is formed over the exposed silicon substrate corresponding to the formation of at least one MOS transistor located in control circuitry.
- In one embodiment, the oxide layers are formed using an oxygen (O2) plasma oxidation technique. As such, the plasma oxidation for the formation of the top oxide layer over the nitride layer in the SONOS based transistor and the gate oxide layer over the exposed silicon substrate used to form the gate oxide of the at least one MOS transistor can be formed at lower temperatures than conventional thermal oxidation techniques, in one embodiment. In still other embodiments, the simultaneous formation of the top oxide layer over the nitride layer in the SONOS based transistor and the gate oxide layer over the exposed silicon substrate that forms the gate oxide of the at least one MOS transistor for control circuitry can be formed by other methods, such as high pressure wet oxidation.
-
FIG. 3C is across section 300C showing the continued formation fromFIG. 3B of the transistors of the semiconductor chip. In the example provided inFIG. 3C , atop oxide layer 365 is formed over thenitride layer 350 of the SONOS basedtransistor 320. In addition, agate oxide layer 360 is formed simultaneously over the exposedsilicon substrate 305. In particular, thegate oxide layer 360 is formed in the regions corresponding to the formation of MOS transistors. In one embodiment, themasking layer 307 is removed prior to the simultaneous formation of thegate oxide layer 360 and thetop oxide layer 365. As such, the exposed nitride, in the region corresponding to the formation ofSONOS transistor 320, and the exposed silicon substrate in the regions corresponding to the formation of the at least one MOS transistor (e.g., MOS transistor 310) are simultaneously oxidized. That is,nitride layer 350 is effectively oxidized using an O2 plasma oxidation technique at relatively low temperatures, in one embodiment. In addition, the O2 plasma oxidation technique is capable of oxidizing the exposedsilicon substrate 305 in the region corresponding toMOS transistor 310. -
FIG. 3C illustrates the simultaneous oxidation ofnitride layer 350 and thesilicon substrate 305. For example, the oxidation rates are different for thetop oxide layer 365 and thegate oxide layer 360. As shown inFIG. 3C , the oxidation of silicon occurs at a faster rate than the oxidation of thenitride layer 350. As such, thegate oxide layer 360 is thicker than thetop oxide layer 365, in one embodiment. - As provided in the process steps of FIGS. 2 and 3A-3C, in embodiments of the present invention, fewer process steps are needed to form a SONOS based nonvolatile memory transistor and at least one MOS transistor (e.g., MOS transistor 310) in the control circuitry in comparison to chips made prior to embodiments of this invention, thereby simplifying the manufacturing process and saving time, for example. In particular, conventional techniques separately formed the ONO structure for the SONOS based transistor and the gate oxides for the MOS transistor in the control circuitry. This required at least one additional top oxide layer formation step, and an additional densification step of the top oxide layer. Densification using a conventional high temperature furnace process may be required since the top oxide in the ONO structure of the SONOS based transistor is not dense and easily etched during subsequent process steps (e.g., cleaning steps). These subsequent process steps lead to non-uniformity of the top oxide layer in the ONO structure. Additionally, the thickness of the top oxide layer in the ONO structure is not easily controlled because of the etching of the top oxide layer during subsequent process steps.
- These densification and separate top oxide formation steps are not required by embodiments of the present invention, which lead to improved top oxide quality of the ONO structure and a more uniform thickness of the top oxide in the ONO structure of the SONOS based nonvolatile memory transistor. For instance, the densification step is not required since the O2 plasma oxidation technique forms a top oxide layer of sufficient density such that subsequent process steps do not significantly erode the top oxide layer. In addition, the quality of the top oxide formed through O2 plasma oxidation is of higher quality than the top oxide formed through deposition using conventional techniques.
-
FIG. 4 is a flow chart illustrating steps in a method for the simultaneous formation of a top oxide layer in a SONOS based nonvolatile memory transistor and the gate oxides of corresponding pass-gate MOS transistors that comprise a tri-gate SONOS based nonvolatile memory cell, in accordance with one embodiment of the present invention. For illustrative purposes, the process described inFIG. 4 can be used to form the tri-gate SONOS based NVM shown inFIG. 5 . The embodiment as provided in the method ofFIG. 4 provides similar advantages previously described in relation toFIG. 2 . - At 410, the present embodiment provides a silicon substrate upon which circuit elements can be formed. At 420, the present embodiment forms a tunnel oxide layer over the silicon substrate. At 430, the present embodiment forms a nitride layer over the tunnel oxide layer. The operation at 410 is analogous to the
operation 210 ofFIG. 2 . In addition, the operations at 420 and 430 are analogous to the operations at 220 and 230, respectively, ofFIG. 2 . For purposes of brevity and clarity, a full discussion of the formation of the tunnel oxide layer and the nitride layer is presented in relation tooperations - At 440, the present embodiment isolates a first area in the nitride layer. The first area corresponds to the formation of a SONOS based nonvolatile memory transistor. For example, a resist layer can be formed to isolate the region where the SONOS based nonvolatile memory transistor is subsequently formed. In particular, a second area in the nitride layer corresponds to where a first pass-gate MOS transistor is formed, wherein the first pass-gate MOS transistor is adjacent to where the SONOS based nonvolatile memory transistor is formed, and a third area in the nitride layer corresponds to where a second pass-gate MOS transistor is formed adjacent to SONOS based nonvolatile memory transistor. The SONOS based nonvolatile memory transistor and the first and second pass-gate MOS transistors are configured in a tri-gate SONOS based NVM configuration
- At 450, the present embodiment patterns and etches the nitride layer and the tunnel oxide layer in the second and third areas. Specifically, the tunnel oxide layer and the nitride layer are etched in the second and third areas corresponding to the formation of the first and second pass-gate MOS transistors. For purposes of embodiments of the present invention, etching the tunnel oxide layer and the nitride layer is analogous to removing the tunnel oxide layer and the nitride layer. As such, the silicon substrate is exposed in the second and third areas corresponding to the formation of the first and second pass-gate MOS transistors.
- At 460, the present embodiment simultaneously forms oxide layers over remaining portions of the nitride layer over the first area, and over exposed areas of the silicon substrate corresponding to the second area and the third area. Specifically, a top oxide layer is formed over the nitride layer in the region corresponding to the formation of the SONOS based nonvolatile memory transistor. In addition, a gate oxide layer for the MOS transistors is simultaneously formed over the exposed silicon substrate.
-
FIG. 5 is a simplified illustration depicting a SONOS basedNVM configuration 500 in cross section, in accordance with one embodiment of the present invention. The SONOS basedNVM configuration 500 shown inFIG. 5 results from the process steps described inFIG. 2 , and more particularly fromFIG. 4 , in accordance with one embodiment of the present invention. As such, the SONOS basedNVM configuration 500 is fabricated such that the top oxide layer in at least one SONOS based nonvolatile memory transistor is formed simultaneously with the gate oxide layer over a silicon substrate from which is formed a gate oxide for at least one corresponding pass-gate MOS transistor. The at least one corresponding pass-gate MOS transistor controls access to the SONOS based nonvolatile memory transistor. - For example,
NVM configuration 500 shown inFIG. 5 can be implemented within an nvSRAM memory array, in one embodiment. Other embodiments are well suited to using theNVM configuration 500 in other memory structures. - In one embodiment,
FIG. 5 shows n-channel MOS transistors transistor 530 formed over a p-type silicon substrate 510 for theNVM configuration 500. In other embodiments, theNVM configuration 500 can comprise any combination of n-channel and p-channel transistors built over n-type or p-type substrates. - The SONOS based
NVM configuration 500 comprises a SONOS basednonvolatile memory transistor 530. The SONOS basednonvolatile memory transistor 530 comprises anONO structure 535 which includes a tunnel oxide layer, a nitride layer, and a top oxide layer. - In addition, the SONOS based
NVM configuration 500 comprises a firstpass-gate MOS transistor 520 adjacent the SONOS basednonvolatile memory transistor 530. The firstpass-gate MOS transistor 520 comprises afirst gate oxide 523 that is formed simultaneously with the top oxide layer in theONO structure 535. The oxidation rates for forming the top oxide layer of the SONOS based nonvolatile memory transistor and thefirst gate oxide 523 are different, which is reflected in the relative sizes of each layer. Specifically, the nitride layer in theONO structure 535 of the SONOS based nonvolatile memory transistor is oxidized at a slower rate than the oxidation of thesilicon substrate 510 that forms thegate oxide 523 of thepass-gate MOS transistor 520. As such, thegate oxide 523 is thicker than the top oxide layer in theONO structure 535 over its distributed length. For instance, the thickness of thegate oxide 523 is approximately greater than or equal to twice the thickness of the top oxide layer in theONO structure 535. - Since the
first gate oxide 523 is formed simultaneously with the top oxide layer in theONO structure 535 of the SONOS basednonvolatile memory transistor 530, the density of the top oxide layer in theONO structure 535 is substantially similar to the density of thefirst gate oxide 523, in one embodiment. - Further, in another embodiment, the quality of top oxide layer in the
ONO structure 535 formed through plasma oxidation is better than the quality of a top oxide layer formed through conventional deposition techniques. In particular, conventional deposition techniques will introduce more impurities into the top oxide layer than a top oxide layer that is formed through plasma oxidation techniques, in embodiments of the present invention. - In addition, the SONOS based
nonvolatile memory cell 500 comprises a secondpass-gate MOS transistor 540 adjacent the SONOS basednonvolatile memory transistor 530. The second pass-gate MOS transistor 525 comprises asecond gate oxide 543 that is formed simultaneously with the top oxide layer in theONO structure 535. The oxidation rates for forming the top oxide layer of the SONOS basednonvolatile memory transistor 530 and thesecond gate oxide 543 are different, which is reflected in the relative sizes of each layer. Specifically, the nitride layer in theONO structure 535 in the SONOS based nonvolatile memory transistor is oxidized at a slower rate than the oxidation of thesilicon substrate 510 that forms thesecond gate oxide 543 of thepass-gate MOS transistor 540. As such, thegate oxide 543 is thicker than the top oxide layer in theONO structure 535. For instance, the thickness of thegate oxide 543 is approximately greater than or equal to twice the thickness of the top oxide layer in theONO structure 535. - More particularly, the
second gate oxide 543 is basically the same as thefirst gate oxide 523. As such, the density of the top oxide layer in theONO structure 535 is substantially similar to the density of thesecond gate oxide 543, in one embodiment. - Accordingly, embodiments of the present invention provide for improved fabrication of a semiconductor chip comprising a SONOS based transistor and MOS transistors located in control circuitry. In particular, in one embodiment, the top oxide layer of the SONOS based nonvolatile memory transistor has a more uniform thickness. Also, in other embodiments, simultaneous fabrication of the top oxide layer of the SONOS based nonvolatile memory transistor and a gate oxide of at least one MOS transistor located in control circuitry reduces the number of processing steps, which saves the overall process costs for a semiconductor chip platform (e.g., a nonvolatile SRAM memory). In addition, in other embodiments, simultaneous formation of the top oxide layer in the ONO structure of the SONOS based nonvolatile memory transistor and the gate oxide of MOS transistor in the control circuitry improves the overall quality of the top oxide layer.
- While the methods of embodiments illustrated in flow charts 2 and 4 show specific sequences and quantity of operations, the present invention is suitable to alternative embodiments. For example, not all the operations provided for in the methods presented above are required for the present invention. Furthermore, additional operations can be added to the operations presented in the present embodiments. Likewise the sequences of operations can be modified depending upon the application.
- A method and apparatus illustrating the simultaneous formation of a top oxide layer in a SONOS based memory transistor and a gate oxide of at least one MOS transistor for control circuitry, is thus described. While the invention has been illustrated and described by means of specific embodiments, it is to be understood that numerous changes and modifications may be made therein without departing from the spirit and scope of the invention as defined in the appended claims and equivalents thereof. Furthermore, while the present invention has been described in particular embodiments, it should be appreciated that the present invention should not be construed as limited by such embodiments, but rather construed according to the below claims.
Claims (21)
Priority Applications (3)
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US11/615,683 US20080150002A1 (en) | 2006-12-22 | 2006-12-22 | Simultaneous Formation of a Top Oxide Layer in a Silicon-Oxide-Nitride-Oxide-Silicon (SONOS) Transistor and a Gate Oxide in a Metal Oxide Semiconductor (MOS) |
US12/782,699 US8222111B1 (en) | 2006-12-22 | 2010-05-18 | Simultaneous formation of a top oxide layer in a silicon-oxide-nitride-oxide-silicon (SONOS) transistor and a gate oxide in a metal oxide semiconductor (MOS) |
US14/599,157 US9583501B1 (en) | 2006-12-22 | 2015-01-16 | Simultaneous formation of a top oxide layer in a silicon-oxide-nitride-oxide-silicon (SONOS) transistor and a gate oxide in a metal oxide semiconductor (MOS) |
Applications Claiming Priority (1)
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US11/615,683 US20080150002A1 (en) | 2006-12-22 | 2006-12-22 | Simultaneous Formation of a Top Oxide Layer in a Silicon-Oxide-Nitride-Oxide-Silicon (SONOS) Transistor and a Gate Oxide in a Metal Oxide Semiconductor (MOS) |
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US12/782,699 Active US8222111B1 (en) | 2006-12-22 | 2010-05-18 | Simultaneous formation of a top oxide layer in a silicon-oxide-nitride-oxide-silicon (SONOS) transistor and a gate oxide in a metal oxide semiconductor (MOS) |
US14/599,157 Expired - Fee Related US9583501B1 (en) | 2006-12-22 | 2015-01-16 | Simultaneous formation of a top oxide layer in a silicon-oxide-nitride-oxide-silicon (SONOS) transistor and a gate oxide in a metal oxide semiconductor (MOS) |
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US14/599,157 Expired - Fee Related US9583501B1 (en) | 2006-12-22 | 2015-01-16 | Simultaneous formation of a top oxide layer in a silicon-oxide-nitride-oxide-silicon (SONOS) transistor and a gate oxide in a metal oxide semiconductor (MOS) |
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US9331184B2 (en) | 2013-06-11 | 2016-05-03 | United Microelectronics Corp. | Sonos device and method for fabricating the same |
US8883624B1 (en) | 2013-09-27 | 2014-11-11 | Cypress Semiconductor Corporation | Integration of a memory transistor into high-K, metal gate CMOS process flow |
US20150171104A1 (en) | 2013-12-12 | 2015-06-18 | Cypress Semiconductor Corporation | Complementary sonos integration into cmos flow |
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