US20080070092A1 - Metal/composite hybrid fuel cell assembly - Google Patents
Metal/composite hybrid fuel cell assembly Download PDFInfo
- Publication number
- US20080070092A1 US20080070092A1 US11/532,344 US53234406A US2008070092A1 US 20080070092 A1 US20080070092 A1 US 20080070092A1 US 53234406 A US53234406 A US 53234406A US 2008070092 A1 US2008070092 A1 US 2008070092A1
- Authority
- US
- United States
- Prior art keywords
- fuel cell
- cell assembly
- assembly
- composite
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0215—Glass; Ceramic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0213—Gas-impermeable carbon-containing materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0226—Composites in the form of mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present application relates generally to fuel cells, and more particularly to methods and materials for forming fuel cell assemblies.
- Bi-polar fuel cell assemblies typically consist of two electrode plates, i.e., a cathode and an anode, and a separator plate disposed between the two electrode plates.
- Conventional electrode plates are formed of metal or composite materials.
- fuel cell assemblies formed using purely metal electrodes are durable, such plates can be heavy and quite susceptible to corrosion due to oxidation and the electrochemical environment produced by the fuel cell assembly.
- Composite materials aid to reduce the overall weight and susceptibility to corrosion of fuel cell assemblies but lack strength and are susceptible to cracking during handling.
- the present invention provides a fuel cell assembly having a cathode plate formed from a metallic material, an anode plate formed of a composite material, and a separator disposed between the two plates.
- the composite anode plate is corrosion resistant and is preferably formed from a non-metallic material.
- FIG. 1 is an exploded view of a fuel cell assembly.
- FIG. 1 shows an exploded cross sectional view (not to scale) of a representative fuel cell assembly 10 .
- the fuel cell assembly 10 includes a cathode plate 12 , an anode plate 14 and a separator 16 disposed between the cathode 12 and anode 14 plates.
- Each plate is made of an electron conducting material.
- the cathode plate 12 is formed of a metallic material suitable for use in a fuel cell environment.
- the cathode plate 12 may be formed of various metallic materials including, but not limited to, graphite, aluminum or other metals.
- the cathode plate 12 is configured to provide strength and durability to the fuel cell assembly 10 to reduce the risk of damage caused during handling and/or shipping.
- Other materials known to those skilled in the art, or may become known in the future, may be suitable for use in forming the cathode plate 12 which provide similar levels of strength and durability as metal.
- the anode plate 14 is formed of a composite material that is configured to provide corrosion resistance to the harsh anode environment which can be highly acidic. Also, forming the anode plate 14 from a composite material helps to reduce the oxidative damage caused to the fuel call assembly 10 from the electrochemical environment.
- the anode plate 14 is formed of a non-metallic material such as, for example, BMC940 sold by Bulk Molding Corporation. It is understood that other suitable non-metallic material may also be used without departing from the aims of the invention.
- the anode plate 14 may be formed of various composite materials including, but not limited to, graphite particles imbedded in a thermosetting or thermoplastic polymer matrix.
- the separator 16 is disposed between the cathode 12 and anode 14 plates prior to bonding of the fuel cell assembly 10 .
- the separator 16 may be impregnated or coated with an adhesive prior to bonding.
- the separator 16 may be formed of a reinforcing material including, but not limited to, carbon fiber cloth, paper, cardboard, fiberglass or combinations thereof. It is appreciated that several techniques are known to those skilled in the art which are suitable for bonding the fuel assembly 10 and use of either of such techniques would not exceed the scope of the invention.
- the anode environment is the most damaging, since not only is the metal subject to an acidic environment, but the metal can be oxidized by the cell potential.
- the metal cathode plate 12 provides strength to the composite anode plate 14 while the composite anode plate 14 provides corrosion resistance to the harsh anode environment.
- the resulting fuel cell assembly 10 of the metal anode plate 12 and the composite cathode plate 14 may provide less weight than a purely metal fuel cell assembly while being thinner than a composite only assembly. Also, the feature tolerance that can be obtained on the anode plate 14 is not possible with the metal only fuel cell assembly. Further, the fuel cell assembly 10 also has an increased power density resulting from the bonded assembly being able to be made thinner.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Fuel Cell (AREA)
Abstract
Description
- 1. Field
- The present application relates generally to fuel cells, and more particularly to methods and materials for forming fuel cell assemblies.
- 2. Background
- Bi-polar fuel cell assemblies typically consist of two electrode plates, i.e., a cathode and an anode, and a separator plate disposed between the two electrode plates. Conventional electrode plates are formed of metal or composite materials. Although fuel cell assemblies formed using purely metal electrodes are durable, such plates can be heavy and quite susceptible to corrosion due to oxidation and the electrochemical environment produced by the fuel cell assembly. Composite materials aid to reduce the overall weight and susceptibility to corrosion of fuel cell assemblies but lack strength and are susceptible to cracking during handling.
- The subject matter herein helps overcome, or at least mitigate one or more of the problems described above associated with fell cell assemblies.
- In one embodiment, the present invention provides a fuel cell assembly having a cathode plate formed from a metallic material, an anode plate formed of a composite material, and a separator disposed between the two plates. The composite anode plate is corrosion resistant and is preferably formed from a non-metallic material.
-
FIG. 1 is an exploded view of a fuel cell assembly. - Although described herein as a single fuel cell assembly, it is appreciated that several assemblies can be combined to form a fuel cell stack without exceeding the scope of the invention.
-
FIG. 1 shows an exploded cross sectional view (not to scale) of a representativefuel cell assembly 10. As illustrated, thefuel cell assembly 10 includes acathode plate 12, ananode plate 14 and aseparator 16 disposed between thecathode 12 andanode 14 plates. Each plate is made of an electron conducting material. - The
cathode plate 12 is formed of a metallic material suitable for use in a fuel cell environment. Illustratively, thecathode plate 12 may be formed of various metallic materials including, but not limited to, graphite, aluminum or other metals. Thecathode plate 12 is configured to provide strength and durability to thefuel cell assembly 10 to reduce the risk of damage caused during handling and/or shipping. Other materials known to those skilled in the art, or may become known in the future, may be suitable for use in forming thecathode plate 12 which provide similar levels of strength and durability as metal. - The
anode plate 14 is formed of a composite material that is configured to provide corrosion resistance to the harsh anode environment which can be highly acidic. Also, forming theanode plate 14 from a composite material helps to reduce the oxidative damage caused to thefuel call assembly 10 from the electrochemical environment. Preferably, theanode plate 14 is formed of a non-metallic material such as, for example, BMC940 sold by Bulk Molding Corporation. It is understood that other suitable non-metallic material may also be used without departing from the aims of the invention. Indeed, theanode plate 14 may be formed of various composite materials including, but not limited to, graphite particles imbedded in a thermosetting or thermoplastic polymer matrix. - The
separator 16 is disposed between thecathode 12 andanode 14 plates prior to bonding of thefuel cell assembly 10. Theseparator 16 may be impregnated or coated with an adhesive prior to bonding. To increase the strength and durability of thefuel cell assembly 10, theseparator 16 may be formed of a reinforcing material including, but not limited to, carbon fiber cloth, paper, cardboard, fiberglass or combinations thereof. It is appreciated that several techniques are known to those skilled in the art which are suitable for bonding thefuel assembly 10 and use of either of such techniques would not exceed the scope of the invention. - For metallic plates, the anode environment is the most damaging, since not only is the metal subject to an acidic environment, but the metal can be oxidized by the cell potential. By replacing the metallic anode with a
composite anode plate 14 and bonding it to themetallic cathode plate 12, the worst features of the purely composite or metal fuel cell assemblies are avoided. Themetal cathode plate 12 provides strength to thecomposite anode plate 14 while thecomposite anode plate 14 provides corrosion resistance to the harsh anode environment. The resultingfuel cell assembly 10 of themetal anode plate 12 and thecomposite cathode plate 14 may provide less weight than a purely metal fuel cell assembly while being thinner than a composite only assembly. Also, the feature tolerance that can be obtained on theanode plate 14 is not possible with the metal only fuel cell assembly. Further, thefuel cell assembly 10 also has an increased power density resulting from the bonded assembly being able to be made thinner. - It is to be understood that the above description is intended to be illustrative and not limiting. Many embodiments will be apparent to those of skill in the art upon reading the above description. Therefore, the scope of the invention should be determined, not with reference to the above description, but instead with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled.
Claims (10)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/532,344 US20080070092A1 (en) | 2006-09-15 | 2006-09-15 | Metal/composite hybrid fuel cell assembly |
DE102007043924A DE102007043924A1 (en) | 2006-09-14 | 2007-09-14 | Metal / composite hybrid fuel cell arrangement |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/532,344 US20080070092A1 (en) | 2006-09-15 | 2006-09-15 | Metal/composite hybrid fuel cell assembly |
Publications (1)
Publication Number | Publication Date |
---|---|
US20080070092A1 true US20080070092A1 (en) | 2008-03-20 |
Family
ID=39105402
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/532,344 Abandoned US20080070092A1 (en) | 2006-09-14 | 2006-09-15 | Metal/composite hybrid fuel cell assembly |
Country Status (2)
Country | Link |
---|---|
US (1) | US20080070092A1 (en) |
DE (1) | DE102007043924A1 (en) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4297419A (en) * | 1980-09-24 | 1981-10-27 | United Technologies Corporation | Anode-matrix composite for molten carbonate fuel cell |
US4339322A (en) * | 1980-04-21 | 1982-07-13 | General Electric Company | Carbon fiber reinforced fluorocarbon-graphite bipolar current collector-separator |
US20030228510A1 (en) * | 2002-06-05 | 2003-12-11 | Hiromichi Nakata | Separator of a fuel cell and a manufacturing method thereof |
US6753672B2 (en) * | 2002-06-20 | 2004-06-22 | Yung-Jen Lin | Anode structure having increased contact surface area for metal-air fuel cell battery |
US20050062251A1 (en) * | 2003-09-22 | 2005-03-24 | Ramsey John E. | Vehicle frame having air tank cross member |
US6875536B2 (en) * | 2000-10-13 | 2005-04-05 | Texaco Ovonic Fuel Cell Llc | Catalytic hydrogen storage composite material and fuel cell employing same |
US20050106444A1 (en) * | 2003-11-19 | 2005-05-19 | Hiroshi Yamauchi | Fuel cell and separator for cooling used therein |
US20050123819A1 (en) * | 2003-10-27 | 2005-06-09 | Mitsubishi Denki Kabushiki Kaisha | Fuel cell and method for manufacture thereof |
US20060073385A1 (en) * | 2004-05-28 | 2006-04-06 | Peter Andrin | Novel sealant material for electrochemical cell components |
US20070048588A1 (en) * | 2005-08-30 | 2007-03-01 | Abd Elhamid Mahmoud H | Hybrid electrically conductive fluid distribution separator plate assembly for fuel cells |
-
2006
- 2006-09-15 US US11/532,344 patent/US20080070092A1/en not_active Abandoned
-
2007
- 2007-09-14 DE DE102007043924A patent/DE102007043924A1/en not_active Withdrawn
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4339322A (en) * | 1980-04-21 | 1982-07-13 | General Electric Company | Carbon fiber reinforced fluorocarbon-graphite bipolar current collector-separator |
US4297419A (en) * | 1980-09-24 | 1981-10-27 | United Technologies Corporation | Anode-matrix composite for molten carbonate fuel cell |
US6875536B2 (en) * | 2000-10-13 | 2005-04-05 | Texaco Ovonic Fuel Cell Llc | Catalytic hydrogen storage composite material and fuel cell employing same |
US20030228510A1 (en) * | 2002-06-05 | 2003-12-11 | Hiromichi Nakata | Separator of a fuel cell and a manufacturing method thereof |
US6753672B2 (en) * | 2002-06-20 | 2004-06-22 | Yung-Jen Lin | Anode structure having increased contact surface area for metal-air fuel cell battery |
US20050062251A1 (en) * | 2003-09-22 | 2005-03-24 | Ramsey John E. | Vehicle frame having air tank cross member |
US20050123819A1 (en) * | 2003-10-27 | 2005-06-09 | Mitsubishi Denki Kabushiki Kaisha | Fuel cell and method for manufacture thereof |
US20050106444A1 (en) * | 2003-11-19 | 2005-05-19 | Hiroshi Yamauchi | Fuel cell and separator for cooling used therein |
US20060073385A1 (en) * | 2004-05-28 | 2006-04-06 | Peter Andrin | Novel sealant material for electrochemical cell components |
US20070048588A1 (en) * | 2005-08-30 | 2007-03-01 | Abd Elhamid Mahmoud H | Hybrid electrically conductive fluid distribution separator plate assembly for fuel cells |
Also Published As
Publication number | Publication date |
---|---|
DE102007043924A1 (en) | 2008-03-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: DANA CORPORATION, OHIO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:KUMMEROW, JACK A.C.;REEL/FRAME:018276/0918 Effective date: 20060828 |
|
AS | Assignment |
Owner name: DANA AUTOMOTIVE SYSTEMS GROUP, LLC, OHIO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DANA CORPORATION;REEL/FRAME:020540/0476 Effective date: 20080131 Owner name: DANA AUTOMOTIVE SYSTEMS GROUP, LLC,OHIO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DANA CORPORATION;REEL/FRAME:020540/0476 Effective date: 20080131 |
|
AS | Assignment |
Owner name: CITICORP USA, INC., NEW YORK Free format text: INTELLECTUAL PROPERTY REVOLVING FACILITY SECURITY AGREEMENT;ASSIGNORS:DANA HOLDING CORPORATION;DANA LIMITED;DANA AUTOMOTIVE SYSTEMS GROUP, LLC;AND OTHERS;REEL/FRAME:020859/0249 Effective date: 20080131 Owner name: CITICORP USA, INC.,NEW YORK Free format text: INTELLECTUAL PROPERTY REVOLVING FACILITY SECURITY AGREEMENT;ASSIGNORS:DANA HOLDING CORPORATION;DANA LIMITED;DANA AUTOMOTIVE SYSTEMS GROUP, LLC;AND OTHERS;REEL/FRAME:020859/0249 Effective date: 20080131 Owner name: CITICORP USA, INC., NEW YORK Free format text: INTELLECTUAL PROPERTY TERM FACILITY SECURITY AGREEMENT;ASSIGNORS:DANA HOLDING CORPORATION;DANA LIMITED;DANA AUTOMOTIVE SYSTEMS GROUP, LLC;AND OTHERS;REEL/FRAME:020859/0359 Effective date: 20080131 Owner name: CITICORP USA, INC.,NEW YORK Free format text: INTELLECTUAL PROPERTY TERM FACILITY SECURITY AGREEMENT;ASSIGNORS:DANA HOLDING CORPORATION;DANA LIMITED;DANA AUTOMOTIVE SYSTEMS GROUP, LLC;AND OTHERS;REEL/FRAME:020859/0359 Effective date: 20080131 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |