US20080043087A1 - Digital transfer method for printing on a target surface - Google Patents
Digital transfer method for printing on a target surface Download PDFInfo
- Publication number
- US20080043087A1 US20080043087A1 US11/879,744 US87974407A US2008043087A1 US 20080043087 A1 US20080043087 A1 US 20080043087A1 US 87974407 A US87974407 A US 87974407A US 2008043087 A1 US2008043087 A1 US 2008043087A1
- Authority
- US
- United States
- Prior art keywords
- image
- release layer
- transfer
- pressure
- transfer film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N15/00—Mutation or genetic engineering; DNA or RNA concerning genetic engineering, vectors, e.g. plasmids, or their isolation, preparation or purification; Use of hosts therefor
- C12N15/09—Recombinant DNA-technology
- C12N15/63—Introduction of foreign genetic material using vectors; Vectors; Use of hosts therefor; Regulation of expression
- C12N15/79—Vectors or expression systems specially adapted for eukaryotic hosts
- C12N15/82—Vectors or expression systems specially adapted for eukaryotic hosts for plant cells, e.g. plant artificial chromosomes (PACs)
- C12N15/8241—Phenotypically and genetically modified plants via recombinant DNA technology
- C12N15/8242—Phenotypically and genetically modified plants via recombinant DNA technology with non-agronomic quality (output) traits, e.g. for industrial processing; Value added, non-agronomic traits
- C12N15/8243—Phenotypically and genetically modified plants via recombinant DNA technology with non-agronomic quality (output) traits, e.g. for industrial processing; Value added, non-agronomic traits involving biosynthetic or metabolic pathways, i.e. metabolic engineering, e.g. nicotine, caffeine
- C12N15/8247—Phenotypically and genetically modified plants via recombinant DNA technology with non-agronomic quality (output) traits, e.g. for industrial processing; Value added, non-agronomic traits involving biosynthetic or metabolic pathways, i.e. metabolic engineering, e.g. nicotine, caffeine involving modified lipid metabolism, e.g. seed oil composition
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/0004—Oxidoreductases (1.)
- C12N9/0071—Oxidoreductases (1.) acting on paired donors with incorporation of molecular oxygen (1.14)
- C12N9/0083—Miscellaneous (1.14.99)
Definitions
- the present invention relates to digital printing and, more specifically, to a method for transferring digitally created images from film to a target surface via heat and/or pressure transfer.
- Xeikon Current purveyors of digital printing equipment include Xeikon, Kodak, Dotrix, HP and Xerox.
- Xeikon in particular targets the high-end segment of the digital printing market with printing presses that deliver excellent print quality and cost-effectiveness.
- Xeikon caters to an “on demand” business model, print shops that cater to customers who order large quantities of color documents that require delivery by the next day.
- the Xeikon digital printer in combination with the Xeikon Digital Front End software, offers a print quality with superb color matching and perfect front to back registration. The result is a consistent high-quality, full-color print with astonishing richness and depth of color that sets the standard for the rest of the market.
- the Xeikon print series are configured for successive application of four colors plus white, if required, to a medium as it travels across the printing cylinders.
- there are four colors (Cyan, Magenta, Yellow, and Black, the combinations of which recreate any photograph or color in a desired spectrum.
- Cyan, Magenta, Yellow, and Black the combinations of which recreate any photograph or color in a desired spectrum.
- a full color photograph of a child in a red dress would be broken down into millions of small pixels-each pixel has a 4-color value assigned to it.
- a pixel that is in the position in the child's face would have a value of Cyan-5%, Magenta-42%, Yellow-34%, and Black-10%.
- a fifth color can be used as a specialty toner color or white.
- a layer of white can be applied as the fifth color to enhance the colors and give the print opacity. This way, the substrate doesn't show through the image. There is the potential for even more colors or additional specialty toners simply
- a plurality of rotating cylinders are statically charged by charging electrodes, and LEDs remove the charge selectively according to a color-separated pattern.
- the pattern is typically generated by the front end of the print engine taking the image file sent to the front ends and converting into a digital format that the engine will print
- the color-separated pattern is then imparted to the surface of the respective cylinders by the cylinder being completely charged with static charge and the this charge being removed by exposure to LEDs as the cylinder rotates past these LEDs.
- the LEDs are switched on and off according to the pattern required.
- the charged cylinders continue to rotate past a toner applicator that deposits toner on the pattern.
- Toner is attracted and transferred, according to the charged pattern or image, from the toner applicator onto the cylinder.
- a print media is run across the cylinders and the toner is deposited onto the media according to the pattern, e.g., the pattern or image is printed on the material.
- the foregoing process can be adapted to a variety of different print media at speeds of 100 images per minute or faster.
- rub-on image transfers are well-known and include letters and numerals in different type faces which can be transferred from the face of the film on to the target surface (e.g. a drawing on paper) by placing the image face against the paper and rubbing down or burnishing the back of the film so that the letter or numeral becomes attached to the target surface and detached from the film.
- the target surface e.g. a drawing on paper
- U.S. Pat. No. 6,656,306 to Mabbott issued Dec. 2, 2003 shows a method for the preparation and application of pressure and heat applied image transfers.
- An image layer is applied to an image area of an image release surface, and a pressure and/or heat activated adhesive layer is overcoated.
- the adhesive layer adheres more strongly to the image layer than the image layer does to the release surface, and so with the application of pressure and/or heat, the dried adhesive layer attaches only in the image area to the target surface and the adhesive layer is peeled off except for the image area which is left attached to the target surface.
- the dried adhesive layer attaches only in the image area to the target surface and the adhesive layer is peeled off except for the image area which is left attached to the target surface. This produces a high-resolution four color graphic with white: a cleaner, clearer more eye-catching graphic than previously possible.
- the present invention is a method for creating and transferring digitally created images on a film to a target surface via heat and/or pressure transfer using a modified large-format digital printer.
- the method generally comprises the steps of modifying a digital printer to convert it from a front and back heat fused toner printer, to a back fuser toner printer, preparing a transfer film, creating a digital image, applying a release layer onto the transfer film, printing the image onto the release layer on the transfer film in a reverse mirror-image manner, applying an adhesive overtop said image, heat and/or pressure transferring the image onto the target substrate and peeling away the transfer film to selectively leave the image on the target substrate.
- the present method results in a cleaner, clearer more eye-catching graphic deposited in a more robust, wear-tolerant manner on a wider variety of substrates including rough and porous materials such as leather.
- FIG. 1 is an exploded diagram showing the layers of an exemplary image transfer 2 according to the present invention.
- FIG. 2 is a block diagram of the process steps for making and applying the above-described transfer 2 .
- FIG. 3 is a diagram of the components of an exemplary Xeikon digital printer that are removed as per the necessary modification of the present invention.
- the present invention is a digitally-printed transfer bearing a digitally created image that can be heat and/or pressure-applied to a target surface, and a method for transferring the digitally created images from film to a target surface via digital printing and heat and/or pressure transfer.
- the process employs a modified digital printer (converted from a double sided fusing printing process to a back fusing web printing process) to create an image on transfer film subsequently coated with adhesive that is then heat and/or pressure-applied to a substrate to yield a high-resolution four color graphic with white.
- a modified digital printer converted from a double sided fusing printing process to a back fusing web printing process
- the basic fabrication steps comprise 1) coating one side of a disposable base transfer film (or carrier) with a releasable coating; 2) digitally printing one or more images overtop the base transfer film in reverse-image format; and 3) applying an adhesive coating over the image.
- the base transfer film is indexed over a target substrate (image down and showing through the film) and heat and/or pressure is applied to the base transfer film to adhere the image to the target substrate.
- the base transfer film is peeled from the target substrate and is discarded, leaving a high-resolution color graphic image on the target substrate.
- the method is described in detail below with various options, and in all cases the method is unique because when the image is transferred there is “selective release”, meaning that there is transfer to the target substrate only in a pre-determined area (most commonly in the specific area of the print image, though for some applications it may be desirable to have a release that includes non-imaged areas), despite the adhesive coating which may, and indeed, usually exceeds the borders of the printed image.
- This selective release improves the quality of the transfer because there are no unsightly borders or margins around the image, and holes and gaps in fairly complex images are not filled in.
- FIG. 1 is an exploded diagram showing the layers of an exemplary image transfer 2 according to the present invention.
- the image transfer 2 includes a disposable base transfer film 11 .
- This can be any suitable transfer carrier formed of plastic or non-woven material and that is capable of being passed as a web through the production machinery.
- the presently preferred transfer film 11 is polyester teraphthlate (PET).
- PET polyester teraphthlate
- the transfer film 11 may be preformed with distinct surface patterns or texture to give the final transfer a textured aesthetic.
- Image release layer 12 is uniformly applied onto the base transfer film 1 1 .
- Image release layer 12 may be, for example, a wax, lacquer, or combination of wax and lacquer, with or without specific additives.
- the application of the image release layer 12 may be attained by applying the wax and/or lacquer onto the base transfer film 11 in individual coats from either solvent or waterborne solutions or suspensions. It is known from experience that the final parameters of the coating can be adapted to any requirement by the changing coating weights, the addition or substitution of resins, waxes and wax solutions, and there are many conventional coating methods that can be used to achieving a desired coat weight.
- the appearance of the final coating can be full gloss or be matted down to the required level by the addition of matting agents.
- the presently-preferred release layer 12 comprises a lacquer mixture of commercially available polymethyl methacrylate resin with a commercially available wax suspension (BYK 151 ex-Samual Banner).
- the ratio of resin to wax is on the order of 80% to 95% resin to 5% to 20% wax.
- These two components are provided in a 5% to 15% solid solution (depending on method of application) in a butanone and toluene solvent blend (of which toluene is around 10% of the total solvent).
- the release layer coating is then forced air-dried giving a dry coat weight coat weight of 1.15 to 1.35 grams per square meter.
- the image 13 itself is then digitally printed with a four color graphic (as will be described) on the transfer film 11 (overtop release layer 12 ).
- the digital printer may employ either electro-ink or dry powder toner, and otherwise conventional print techniques.
- a registration mark is printed at this same time, and when desired the four-color image 13 (and registration mark) is then overprinted with a white background 14 .
- a pressure and/or heat activated adhesive layer 15 may be applied evenly over the whole of the web, both where there is image and no image, or may be selectively applied only in the image area.
- the adhesive layer 15 is applied in line directly after the printing step using a 3.5% to 4% solution of commercially available polyamide (Lioseal V 7036 ex-Henkel) in a solvent system, which is predominately Isopropyl alcohol. This solution is then coated onto the image 13 and/or transfer film 11 by a wire wound rod at a dry coating weight of 0.2 to 0.3 grams per square meter, the applied coating being forced air-dried.
- the base transfer film 11 is placed on a target substrate and is indexed in position using the index lines (image down and showing through the film).
- the adhesive layer is then heat and/or pressure-fused to a subject material and the image itself 13 adheres more strongly to the material than does the image release layer 12 .
- the image transfer film 11 is applied image-down to a target substrate by application of pressure and/or heat (as will be described)
- the dried adhesive layer 15 attaches to the target substrate only in the image 12 area but is otherwise retained by the transfer film 11 (“selective release”).
- the image transfer film 11 is peeled off the target substrate together with the dried adhesive layer 15 except for the image area which is left attached to the target substrate by the pressure and/or heat activated adhesive layer 15 .
- the thickness of the non-printed areas of release layer 12 and adhesive layer 15 must be thinner than printed areas containing the release layer 12 , image 13 and adhesive layer 15 such that more pressure is exerted where there is image to the target substrate than where there is no image.
- the characteristics of the image release layer 12 , the adhesive layer 15 and the image layers 13 , 14 are selected so as to work with a wide variety of target substrates, including textured and porous materials such as leather to give this selectivity.
- FIG. 2 is a block diagram of all necessary process steps for making and applying the above-described transfer 2 .
- Step 1 Modify Digital Printer
- This printer can be any conventional digital printer that uses either ElectroInkTM or dry powder toner, or other conventional print techniques.
- a XeikonTM large format digital printer is suitable.
- This and most other large format digital printers employ heater roller assemblies and fusers generally contained within a protective housing.
- a toner image is transferred to a sheet or web and is then fixed to the web by heat and/or pressure.
- the paper is transported in a nip between the fuser and pressure roller, which are rotating. Thermal radiation from a lamp heats the fuser roller, causing the toner on the web to melt and press into the web fibers.
- the printer is modified to essentially convert it from a front and back fuser system to a back fusing web printing process.
- the modification initially entails disabling the heaters in the infeed module removal of the front fusers (substep 22 ) and removal of the GEM rollers 24 .
- the front fusers and part nos. CNS-1262-01 5208 32D would be removed as seen in FIG. 3 .
- the print color order is changed from the conventional CMYK to KMCY
- Step 2 Prepare Web
- the current process uses a plastic web in roll form for the base transfer film 11 of FIG. 1 and pre-coats this with the release layer 12 which may be a releasing lacquer, a wax, a release coating, or a combination of any of these as described above.
- the release layer 12 may be a releasing lacquer, a wax, a release coating, or a combination of any of these as described above.
- the releasing layer lacquer, wax, coating, or combination of any of these.
- the lacquer, wax and release coating are custom-mixed to create the correct release factor for a range of heat and pressure used.
- a suitable wax release can be mixed with a combined acrylic nitrocellulose overlacquer for this purpose.
- the release layer 12 may be texturized or mixed with specific additives, such as UV absorbers or biocides, to give the release layer specific properties.
- the release layer 12 may be texturized with a distinct carrier surface pattern (matte or scratch). Since the image is printed onto the release layer 12 and is then transferred, the net effect is to impart the surface pattern onto the surface of the transfer. Most any texture or pattern that can be made to the surface of the release layer 12 , for example, embossing, etching or addition of a solid component, e.g. silica. In each case this is transferred when it is applied to the target substrate. These changes can be aesthetic for example, matte, brushed effect, geometric pattern, regular pattern or random pattern. The effect can also be subtle such as wording, images or patterns that are only visible with light shining on the surface at a particular angle, thereby serving as a simple security device.
- a distinct carrier surface pattern mimatte or scratch
- the release layer 12 may contain a functional additive that confers a property to the transfer 2 that is not present in the transfer without the additive.
- a functional additive that confers a property to the transfer 2 that is not present in the transfer without the additive.
- an anti-microbial additive such as the transfer surface as applied to a target will inhibit bacteria.
- Inorganic, silver-based antimicrobials are generally recognized as safe and are well suited for this purpose.
- UV absorber a small percentage (less than 10%) of a UV absorber will protect the toner image from degradation in color intensity due to prolonged exposure to direct sunlight.
- Step 3 Prepare Image
- the image is designed into a vector image file, or scanned into a raster image file, in both cases using four color CMYK pixilation.
- the emblem graphic design may be generated using computer drawing software. This is generally accomplished using graphics programs such as well-known Adobe IllustratorTM, PhotoshopTM, etc. Such software is capable of calculating the image dimensions from the design, and colors are chosen from a selectable palette. Photoshop software developed by Adobe uses a palette technique in which the image data is coded and compressed to a prescribed number of colors (a range of from 256 to 16M colors depending on the selected palette). The image file can be manipulated as desired to resize/rescale, redraw or alter the coloration. The final image is then saved as a CMYK raster image file.
- Step 4 Print Image
- the image is printed directly from the raster image file and at substep 46 an additional toner drum of white toner (W) is used to print a white overprint.
- W white toner
- the process imprints electrostatically charged toner or inkjet images onto the base transfer film 11 .
- the process prints the desired image, laying on colors in registration patterns in the order Black, Magenta, Cyan, Yellow (KMCY), and finally White, instead of the CMYK patterns that are applied by an unmodified Xeikon.
- the printing of a white layer of color at substep 66 is unique to the invention and this improves contrast by filling in blank areas. When working on the design computer white is seen as black. White cannot be seen on the screen.
- the black image (the part we want to be white) is given a specific reference, for example, pantone 100 .
- This specific reference number is added as a 5 th color that the Xeikon combines with the normal CMYK colors of the design, and yet printing this reference color as white as it has been programmed to do.
- Step 5 Apply Release Layer
- the mixed release layer 12 is applied to the plastic transfer film 11 .
- the release layer 12 is applied over the whole surface of the base transfer film 11 using conventional coating machine.
- Step 6 Apply Adhesive
- a water or solvent based adhesive is applied over both the image (with nor without white) and the areas that do not contain a printed image. These areas may include parts of the image that have intentionally been left clear of print for example between numbers, backgrounds to let the substrate be seen through the print, etc.
- the transfer 2 is now complete.
- Step 7 Apply finished Transfer 2
- the image transfer 2 may be applied to a wide variety of materials including rough and/or porous materials such as leather.
- the image 13 may be transferred to the substrate material by a roller-to-substrate process, or through a heat-stamping process, in both cases using conventional presses. In both cases the differential pressure of the transfer film 11 with toner versus the transfer film 11 without toner is the factor that controls the selective release according to the present invention.
- the dried adhesive on the printed area of the image 13 encounters more pressure due to the additional thickness added by the toner, and thus the printed areas of image 13 attach to the target material. After the transfer film 11 contacts the target substrate, the transfer film 11 may be peeled away.
- the printed image 13 transfers to the target substrate as the web separates.
- the adhesive on the printed area attaches to the target surface and pulls the printed image off the transfer film 11 and onto the target substrate.
- the process does not leave a “lacquer halo” around the printed images as in conventional transfer processes.
- the stamping press may be used a second time directly onto the transferred image to imbed the printed image into the selected substrate.
- This differential pressure is obtained by the difference in thickness between the areas of the film that are imprinted with the image 13 and areas where there is no image. Although it is imperceptible to the naked eye, the transfer 2 is thicker in the areas where the toner has been applied.
- the image is transferred selectively through the interaction of the release layer, image and adhesive and the target substrate.
- the release layer and adhesives being specifically formulated to exploit this differential pressure.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Genetics & Genomics (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Zoology (AREA)
- Organic Chemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Biotechnology (AREA)
- Wood Science & Technology (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- General Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Medicinal Chemistry (AREA)
- Cell Biology (AREA)
- Physics & Mathematics (AREA)
- Biophysics (AREA)
- Plant Pathology (AREA)
- Breeding Of Plants And Reproduction By Means Of Culturing (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Enzymes And Modification Thereof (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
A method for creating and transferring digitally created images on a film to a target surface via heat and/or pressure transfer using a modified large-format digital printer. The method generally comprises the steps of modifying a large-format digital printer to convert it from heat fused toner printing to cold toner printing, preparing a transfer film, creating a digital image, applying a release layer onto the transfer film, printing the image onto the release layer on the transfer film in a reverse mirror-image manner, applying an adhesive overtop said image, and pressure transferring the image onto the target substrate and peeling away the transfer film to selectively leave the image on the target substrate. The present method results in a cleaner, clearer more eye-catching graphic deposited in a more robust, wear-tolerant manner on a wider variety of substrates including rough and porous materials such as leather.
Description
- The present application derives priority from U.S. Provisional Application Serial No. 60/831,838 filed 19 Jul. 2006.
- 1. Field of the Invention
- The present invention relates to digital printing and, more specifically, to a method for transferring digitally created images from film to a target surface via heat and/or pressure transfer.
- 2. Description of the Background
- Traditional offset printing processes involve a number of expensive and time-consuming steps, such as plate imaging and mounting. A number of manufacturers are now selling digital printers that print documents directly from electronic files to paper, or a variety of other substrates. These digital printers greatly simplify the printing process. Other than buying a digital printer and preparing a design to be printed, there are no other start-up costs or steps involved in the digital printing process. Thus, these printers allow cost-effective high quality shorter print runs. Both the form and content of each consecutive print can be different. Currently, only digital printing technology can provide the level of personalization and customization demanded by many manufacturers.
- Current purveyors of digital printing equipment include Xeikon, Kodak, Dotrix, HP and Xerox. Xeikon in particular targets the high-end segment of the digital printing market with printing presses that deliver excellent print quality and cost-effectiveness. Xeikon caters to an “on demand” business model, print shops that cater to customers who order large quantities of color documents that require delivery by the next day. The Xeikon digital printer, in combination with the Xeikon Digital Front End software, offers a print quality with superb color matching and perfect front to back registration. The result is a consistent high-quality, full-color print with astounding richness and depth of color that sets the standard for the rest of the market.
- The Xeikon print series are configured for successive application of four colors plus white, if required, to a medium as it travels across the printing cylinders. When printing to a 4 color-process toner based output printing system, there are four colors (Cyan, Magenta, Yellow, and Black, the combinations of which recreate any photograph or color in a desired spectrum. For example, a full color photograph of a child in a red dress would be broken down into millions of small pixels-each pixel has a 4-color value assigned to it. A pixel that is in the position in the child's face would have a value of Cyan-5%, Magenta-42%, Yellow-34%, and Black-10%. The typical shade of black will be Cyan-75%, Magenta-68%, Yellow-67%, and Black-90%. In a five color press a fifth color can be used as a specialty toner color or white. For example, a layer of white can be applied as the fifth color to enhance the colors and give the print opacity. This way, the substrate doesn't show through the image. There is the potential for even more colors or additional specialty toners simply
- In a conventional direct electrostatic color printing system, a plurality of rotating cylinders are statically charged by charging electrodes, and LEDs remove the charge selectively according to a color-separated pattern. The pattern is typically generated by the front end of the print engine taking the image file sent to the front ends and converting into a digital format that the engine will print The color-separated pattern is then imparted to the surface of the respective cylinders by the cylinder being completely charged with static charge and the this charge being removed by exposure to LEDs as the cylinder rotates past these LEDs. The LEDs are switched on and off according to the pattern required. The charged cylinders continue to rotate past a toner applicator that deposits toner on the pattern. Toner is attracted and transferred, according to the charged pattern or image, from the toner applicator onto the cylinder. Next, a print media is run across the cylinders and the toner is deposited onto the media according to the pattern, e.g., the pattern or image is printed on the material. The foregoing process can be adapted to a variety of different print media at speeds of 100 images per minute or faster.
- On the other hand, rub-on image transfers are well-known and include letters and numerals in different type faces which can be transferred from the face of the film on to the target surface (e.g. a drawing on paper) by placing the image face against the paper and rubbing down or burnishing the back of the film so that the letter or numeral becomes attached to the target surface and detached from the film.
- There have been several attempts to extend the digital printing process as described above to transfers, though such attempts have involved more or less complicated procedures and the use of particular materials with limitations as to the nature of the final target surface.
- U.S. Pat. No. 6,656,306 to Mabbott issued Dec. 2, 2003 shows a method for the preparation and application of pressure and heat applied image transfers. An image layer is applied to an image area of an image release surface, and a pressure and/or heat activated adhesive layer is overcoated. The adhesive layer adheres more strongly to the image layer than the image layer does to the release surface, and so with the application of pressure and/or heat, the dried adhesive layer attaches only in the image area to the target surface and the adhesive layer is peeled off except for the image area which is left attached to the target surface.
- It would be greatly advantageous to extend the Mabbott concept to provide a cleaner, clearer more eye-catching graphic.
- It is therefore an object of the present invention to provide a method for the preparation and application of pressure and heat applied image transfers by modifying a large-format digital printer to convert it from heat fused toner printing to cold toner printing, utilizing a very narrow dye range for all coatings, and further making use of the differential thickness between the areas of a release layer where there is toner present and where there is no toner such that adhesive applied to the release layer over the image adheres more strongly to the image than the image does to the release layer. Thus, when transferred to a target surface with the application of pressure and/or heat, the dried adhesive layer attaches only in the image area to the target surface and the adhesive layer is peeled off except for the image area which is left attached to the target surface. This produces a high-resolution four color graphic with white: a cleaner, clearer more eye-catching graphic than previously possible.
- In accordance with the foregoing objects, the present invention is a method for creating and transferring digitally created images on a film to a target surface via heat and/or pressure transfer using a modified large-format digital printer. The method generally comprises the steps of modifying a digital printer to convert it from a front and back heat fused toner printer, to a back fuser toner printer, preparing a transfer film, creating a digital image, applying a release layer onto the transfer film, printing the image onto the release layer on the transfer film in a reverse mirror-image manner, applying an adhesive overtop said image, heat and/or pressure transferring the image onto the target substrate and peeling away the transfer film to selectively leave the image on the target substrate. The present method results in a cleaner, clearer more eye-catching graphic deposited in a more robust, wear-tolerant manner on a wider variety of substrates including rough and porous materials such as leather.
- Other objects, features, and advantages of the present invention will become more apparent from the following detailed description of the preferred embodiment and certain modifications thereof when taken together with the accompanying drawings in which:
-
FIG. 1 is an exploded diagram showing the layers of anexemplary image transfer 2 according to the present invention. -
FIG. 2 is a block diagram of the process steps for making and applying the above-describedtransfer 2. -
FIG. 3 is a diagram of the components of an exemplary Xeikon digital printer that are removed as per the necessary modification of the present invention. - The present invention is a digitally-printed transfer bearing a digitally created image that can be heat and/or pressure-applied to a target surface, and a method for transferring the digitally created images from film to a target surface via digital printing and heat and/or pressure transfer.
- The process employs a modified digital printer (converted from a double sided fusing printing process to a back fusing web printing process) to create an image on transfer film subsequently coated with adhesive that is then heat and/or pressure-applied to a substrate to yield a high-resolution four color graphic with white.
- The basic fabrication steps comprise 1) coating one side of a disposable base transfer film (or carrier) with a releasable coating; 2) digitally printing one or more images overtop the base transfer film in reverse-image format; and 3) applying an adhesive coating over the image.
- The result is a roll of pre-printed transfers. In accordance with the present method for transferring the digitally created images from film to a target surface, 4) the base transfer film is indexed over a target substrate (image down and showing through the film) and heat and/or pressure is applied to the base transfer film to adhere the image to the target substrate. The base transfer film is peeled from the target substrate and is discarded, leaving a high-resolution color graphic image on the target substrate.
- The method is described in detail below with various options, and in all cases the method is unique because when the image is transferred there is “selective release”, meaning that there is transfer to the target substrate only in a pre-determined area (most commonly in the specific area of the print image, though for some applications it may be desirable to have a release that includes non-imaged areas), despite the adhesive coating which may, and indeed, usually exceeds the borders of the printed image. This selective release improves the quality of the transfer because there are no unsightly borders or margins around the image, and holes and gaps in fairly complex images are not filled in.
-
FIG. 1 is an exploded diagram showing the layers of anexemplary image transfer 2 according to the present invention. Theimage transfer 2 includes a disposablebase transfer film 11. This can be any suitable transfer carrier formed of plastic or non-woven material and that is capable of being passed as a web through the production machinery. For example, the presently preferredtransfer film 11 is polyester teraphthlate (PET). In accordance with one optional feature of the present invention, thetransfer film 11 may be preformed with distinct surface patterns or texture to give the final transfer a textured aesthetic. - An
image release layer 12 is uniformly applied onto thebase transfer film 1 1.Image release layer 12 may be, for example, a wax, lacquer, or combination of wax and lacquer, with or without specific additives. The application of theimage release layer 12 may be attained by applying the wax and/or lacquer onto thebase transfer film 11 in individual coats from either solvent or waterborne solutions or suspensions. It is known from experience that the final parameters of the coating can be adapted to any requirement by the changing coating weights, the addition or substitution of resins, waxes and wax solutions, and there are many conventional coating methods that can be used to achieving a desired coat weight. The appearance of the final coating can be full gloss or be matted down to the required level by the addition of matting agents. When applied therelease layer 12 must be uniform, and free from all coating defects and application patterns (except where a coating pattern is an intended aspect). The presently-preferredrelease layer 12 comprises a lacquer mixture of commercially available polymethyl methacrylate resin with a commercially available wax suspension (BYK 151 ex-Samual Banner). The ratio of resin to wax is on the order of 80% to 95% resin to 5% to 20% wax. These two components are provided in a 5% to 15% solid solution (depending on method of application) in a butanone and toluene solvent blend (of which toluene is around 10% of the total solvent). The release layer coating is then forced air-dried giving a dry coat weight coat weight of 1.15 to 1.35 grams per square meter. - The
image 13 itself is then digitally printed with a four color graphic (as will be described) on the transfer film 11 (overtop release layer 12). The digital printer may employ either electro-ink or dry powder toner, and otherwise conventional print techniques. Preferably, a registration mark is printed at this same time, and when desired the four-color image 13 (and registration mark) is then overprinted with awhite background 14. - Finally, a pressure and/or heat activated
adhesive layer 15 may be applied evenly over the whole of the web, both where there is image and no image, or may be selectively applied only in the image area. Presently, theadhesive layer 15 is applied in line directly after the printing step using a 3.5% to 4% solution of commercially available polyamide (Lioseal V 7036 ex-Henkel) in a solvent system, which is predominately Isopropyl alcohol. This solution is then coated onto theimage 13 and/ortransfer film 11 by a wire wound rod at a dry coating weight of 0.2 to 0.3 grams per square meter, the applied coating being forced air-dried. - To then transfer the digitally created image from the
transfer film 11 to a target surface, thebase transfer film 11 is placed on a target substrate and is indexed in position using the index lines (image down and showing through the film). The adhesive layer is then heat and/or pressure-fused to a subject material and the image itself 13 adheres more strongly to the material than does theimage release layer 12. Thus, when theimage transfer film 11 is applied image-down to a target substrate by application of pressure and/or heat (as will be described), the driedadhesive layer 15 attaches to the target substrate only in theimage 12 area but is otherwise retained by the transfer film 11 (“selective release”). To then apply thetransfer 2, theimage transfer film 11 is peeled off the target substrate together with the driedadhesive layer 15 except for the image area which is left attached to the target substrate by the pressure and/or heat activatedadhesive layer 15. For this to happen, the thickness of the non-printed areas ofrelease layer 12 andadhesive layer 15 must be thinner than printed areas containing therelease layer 12,image 13 andadhesive layer 15 such that more pressure is exerted where there is image to the target substrate than where there is no image. The characteristics of theimage release layer 12, theadhesive layer 15 and the image layers 13, 14 are selected so as to work with a wide variety of target substrates, including textured and porous materials such as leather to give this selectivity. -
FIG. 2 is a block diagram of all necessary process steps for making and applying the above-describedtransfer 2. - Step 1: Modify Digital Printer
- This printer can be any conventional digital printer that uses either ElectroInk™ or dry powder toner, or other conventional print techniques. For example, a Xeikon™ large format digital printer is suitable. This and most other large format digital printers employ heater roller assemblies and fusers generally contained within a protective housing. A toner image is transferred to a sheet or web and is then fixed to the web by heat and/or pressure. Typically the paper is transported in a nip between the fuser and pressure roller, which are rotating. Thermal radiation from a lamp heats the fuser roller, causing the toner on the web to melt and press into the web fibers. In accordance with the present invention, the printer is modified to essentially convert it from a front and back fuser system to a back fusing web printing process. The modification initially entails disabling the heaters in the infeed module removal of the front fusers (substep 22) and removal of the
GEM rollers 24. Specifically, for a Xeikon digital printer, the front fusers and part nos. CNS-1262-01 5208 32D (Gem Roller) would be removed as seen inFIG. 3 . In addition, the print color order is changed from the conventional CMYK to KMCY - Step 2: Prepare Web
- The current process uses a plastic web in roll form for the
base transfer film 11 ofFIG. 1 and pre-coats this with therelease layer 12 which may be a releasing lacquer, a wax, a release coating, or a combination of any of these as described above. Atsubstep 42 it is necessary to mix the releasing layer (lacquer, wax, coating, or combination of any of these). The lacquer, wax and release coating are custom-mixed to create the correct release factor for a range of heat and pressure used. A suitable wax release can be mixed with a combined acrylic nitrocellulose overlacquer for this purpose. - If desired, the
release layer 12 may be texturized or mixed with specific additives, such as UV absorbers or biocides, to give the release layer specific properties. - For example, the
release layer 12 may be texturized with a distinct carrier surface pattern (matte or scratch). Since the image is printed onto therelease layer 12 and is then transferred, the net effect is to impart the surface pattern onto the surface of the transfer. Most any texture or pattern that can be made to the surface of therelease layer 12, for example, embossing, etching or addition of a solid component, e.g. silica. In each case this is transferred when it is applied to the target substrate. These changes can be aesthetic for example, matte, brushed effect, geometric pattern, regular pattern or random pattern. The effect can also be subtle such as wording, images or patterns that are only visible with light shining on the surface at a particular angle, thereby serving as a simple security device. - As another example, the
release layer 12 may contain a functional additive that confers a property to thetransfer 2 that is not present in the transfer without the additive. For example the addition of 1% of an anti-microbial additive such the transfer surface as applied to a target will inhibit bacteria. Inorganic, silver-based antimicrobials are generally recognized as safe and are well suited for this purpose. - The addition of a small percentage (less than 10%) of a UV absorber will protect the toner image from degradation in color intensity due to prolonged exposure to direct sunlight.
- The addition of a phosphorescent or fluorescent additive will make the transfer “glow” when UV light is shined onto it. This addition can be used in conjunction with the above-described surface pattern, making the effect easier to detect.
- Step 3: Prepare Image
- The image is designed into a vector image file, or scanned into a raster image file, in both cases using four color CMYK pixilation.
- As seen at substep 32, the emblem graphic design may be generated using computer drawing software. This is generally accomplished using graphics programs such as well-known Adobe Illustrator™, Photoshop™, etc. Such software is capable of calculating the image dimensions from the design, and colors are chosen from a selectable palette. Photoshop software developed by Adobe uses a palette technique in which the image data is coded and compressed to a prescribed number of colors (a range of from 256 to 16M colors depending on the selected palette). The image file can be manipulated as desired to resize/rescale, redraw or alter the coloration. The final image is then saved as a CMYK raster image file.
- Step 4: Print Image
- Given a prepared image, at
substep 44 the image is printed directly from the raster image file and at substep 46 an additional toner drum of white toner (W) is used to print a white overprint. The process imprints electrostatically charged toner or inkjet images onto thebase transfer film 11. The process prints the desired image, laying on colors in registration patterns in the order Black, Magenta, Cyan, Yellow (KMCY), and finally White, instead of the CMYK patterns that are applied by an unmodified Xeikon. The printing of a white layer of color at substep 66 is unique to the invention and this improves contrast by filling in blank areas. When working on the design computer white is seen as black. White cannot be seen on the screen. The black image (the part we want to be white) is given a specific reference, for example, pantone 100. This specific reference number is added as a 5th color that the Xeikon combines with the normal CMYK colors of the design, and yet printing this reference color as white as it has been programmed to do. - Step 5: Apply Release Layer
- Next, at step 5, the
mixed release layer 12 is applied to theplastic transfer film 11. Therelease layer 12 is applied over the whole surface of thebase transfer film 11 using conventional coating machine. - Step 6: Apply Adhesive
- At step 6 a water or solvent based adhesive is applied over both the image (with nor without white) and the areas that do not contain a printed image. These areas may include parts of the image that have intentionally been left clear of print for example between numbers, backgrounds to let the substrate be seen through the print, etc. The
transfer 2 is now complete. - Step 7: Apply finished
Transfer 2 - Finally, at step 7, the
image transfer 2 may be applied to a wide variety of materials including rough and/or porous materials such as leather. At substep 72 theimage 13 may be transferred to the substrate material by a roller-to-substrate process, or through a heat-stamping process, in both cases using conventional presses. In both cases the differential pressure of thetransfer film 11 with toner versus thetransfer film 11 without toner is the factor that controls the selective release according to the present invention. More specifically, at substep 74 the dried adhesive on the printed area of theimage 13 encounters more pressure due to the additional thickness added by the toner, and thus the printed areas ofimage 13 attach to the target material. After thetransfer film 11 contacts the target substrate, thetransfer film 11 may be peeled away. The printedimage 13 transfers to the target substrate as the web separates. The adhesive on the printed area attaches to the target surface and pulls the printed image off thetransfer film 11 and onto the target substrate. The process does not leave a “lacquer halo” around the printed images as in conventional transfer processes. - Where a heat-stamping process is used, the stamping press may be used a second time directly onto the transferred image to imbed the printed image into the selected substrate.
- This differential pressure is obtained by the difference in thickness between the areas of the film that are imprinted with the
image 13 and areas where there is no image. Although it is imperceptible to the naked eye, thetransfer 2 is thicker in the areas where the toner has been applied. The image is transferred selectively through the interaction of the release layer, image and adhesive and the target substrate. The release layer and adhesives being specifically formulated to exploit this differential pressure. - Having now fully set forth the preferred embodiments and certain modifications of the concept underlying the present invention, various other embodiments as well as certain variations and modifications thereto may obviously occur to those skilled in the art upon becoming familiar with the underlying concept. It is to be understood, therefore, that the invention may be practiced otherwise than as specifically set forth herein.
Claims (20)
1. A method for creating images on a film for transfer to a target surface via heat and/or pressure transfer, comprising the steps of:
loading a transfer film coated with a release layer into a digital printer;
printing a digital image onto said release layer;
applying an adhesive overtop said printed image; and
heat and/or pressure transferring said image onto a target substrate, peeling away said transfer film selectively leaving only the image adhered to said target substrate.
2. The method for creating images on a film according to claim 1 , wherein said step of loading a transfer film coated with a release layer into a digital printer comprises loading a transfer film coated with a textured-surface release layer into said digital printer.
3. The method for creating images on a film according to claim 1 , wherein said step of loading a transfer film coated with a release layer into a digital printer comprises loading a transfer film coated with an anti-microbial release layer into said digital printer.
4. The method for creating images on a film according to claim 1 , wherein said step of loading a transfer film coated with a release layer into a digital printer comprises loading a transfer film coated with a UV-absorbent release layer into said digital printer.
5. The method for creating images on a film according to claim 1 , wherein said step of loading a transfer film coated with a release layer into a digital printer comprises loading a transfer film coated with a phosphorescent release layer into said digital printer.
6. The method for creating images on a film according to claim 1 , wherein said step of loading a transfer film coated with a release layer into a digital printer comprises loading a transfer film coated with a fluorescent release layer into said digital printer.
7. The method for creating images on a film according to claim 1 , wherein said step of heat and/or pressure transferring said image onto a target substrate loading a transfer film coated with a release layer into a digital printer comprises applying a differential pressure to the transfer film in an image area versus outside an image area to effect selective release of said image.
8. The method for creating images on a film according to claim 7 , wherein said step of applying a differential pressure comprises applying pressure to said transfer and relying on a differential thickness of image toner in an image area versus outside an image area to effect selective release of said image.
9. A method for creating and transferring digitally created images on a film to a target surface via heat and/or pressure transfer using a digital printer, comprising the steps of:
modifying the digital printer to convert from double fused toner printing to single fused toner printing;
preparing a transfer film;
creating a digital image;
applying a release layer onto said transfer film;
printing the image onto the release layer on said transfer film;
applying an adhesive overtop said image; and
heat and/or pressure transferring said image onto a target substrate, peeling away said transfer film selectively leaving said image only on said target substrate.
10. The method for creating images on a film according to claim 9 , wherein said step of heat and/or pressure transferring said image onto a target substrate loading a transfer film coated with a release layer into a digital printer comprises applying a differential pressure to the transfer film in an image area versus outside an image area to effect selective release of said image.
11. The method for creating images on a film according to claim 10 , wherein said step of applying a differential pressure comprises applying pressure to said transfer and relying on a differential thickness of image toner in an image area versus outside an image area to effect selective release of said image.
12. A heat and/or pressure transfer, comprising:
a disposable transfer substrate;
an image release coating on the substrate;
a digitally printed ink image on the image release coating; and
a pressure and/or heat activated adhesive applied over said printed image;
wherein said transfer is differentially thicker in an area of said digitally printed ink image than outside side image area.
13. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises wax.
14. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises lacquer.
15. The heat and/or pressure transfer according to claim 13 , wherein said release layer comprises wax.
16. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises a textured-surface release layer.
17. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises an anti-microbial ingredient.
18. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises a UV-absorbent ingredient.
19. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises a phosphorescent ingredient.
20. The heat and/or pressure transfer according to claim 12 , wherein said release layer comprises a fluorescent ingredient.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/879,744 US20080043087A1 (en) | 2006-07-19 | 2007-07-18 | Digital transfer method for printing on a target surface |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US83183806P | 2006-07-19 | 2006-07-19 | |
US11/879,744 US20080043087A1 (en) | 2006-07-19 | 2007-07-18 | Digital transfer method for printing on a target surface |
Publications (1)
Publication Number | Publication Date |
---|---|
US20080043087A1 true US20080043087A1 (en) | 2008-02-21 |
Family
ID=38957587
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/779,761 Active 2029-08-15 US7919685B2 (en) | 2006-07-19 | 2007-07-18 | Fatty acid desaturases from Tetraselmis suecica |
US11/879,744 Abandoned US20080043087A1 (en) | 2006-07-19 | 2007-07-18 | Digital transfer method for printing on a target surface |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/779,761 Active 2029-08-15 US7919685B2 (en) | 2006-07-19 | 2007-07-18 | Fatty acid desaturases from Tetraselmis suecica |
Country Status (13)
Country | Link |
---|---|
US (2) | US7919685B2 (en) |
EP (1) | EP2041275B1 (en) |
AR (1) | AR062001A1 (en) |
AT (1) | ATE508186T1 (en) |
AU (1) | AU2007275316B2 (en) |
BR (1) | BRPI0714390B1 (en) |
CA (1) | CA2651402C (en) |
DE (1) | DE602007014370D1 (en) |
DK (1) | DK2041275T3 (en) |
ES (1) | ES2366297T3 (en) |
MX (1) | MX2009000757A (en) |
PT (1) | PT2041275E (en) |
WO (1) | WO2008011468A2 (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140108205A1 (en) * | 2011-10-17 | 2014-04-17 | Schneur Minsky | Method For A Canvassed Self Healing Bulletin Board |
US20150047522A1 (en) * | 2013-08-13 | 2015-02-19 | Crayola Llc | Stamp-Making Methods and Devices |
US9072396B1 (en) | 2009-03-31 | 2015-07-07 | Bellamat Llc | Antimicrobial screening runner and mat |
US9505199B1 (en) * | 2016-06-03 | 2016-11-29 | Abbas Sadriwalla | Method of applying a graphic image on a substrate |
WO2017160313A1 (en) * | 2016-03-18 | 2017-09-21 | Hewlett-Packard Development Company, L.P. | Transferring images |
CN108385410A (en) * | 2016-05-19 | 2018-08-10 | 浙江丽丰服装科技有限公司 | The jeans of the easy-operating digital cold-transfer printing of production method |
US10486368B2 (en) | 2015-12-28 | 2019-11-26 | The Procter & Gamble Company | Method for transferring material with adhesive onto articles with a difference in degree of curing between the material and adhesive |
US10752795B2 (en) | 2017-11-17 | 2020-08-25 | The Procter & Gamble Company | Compositions and methods for applying a material onto articles |
US10940685B2 (en) | 2015-12-28 | 2021-03-09 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles using a transfer component that deflects on both sides |
US11141995B2 (en) | 2015-12-28 | 2021-10-12 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles with a pre-distorted transfer component |
US11491803B2 (en) | 2019-02-12 | 2022-11-08 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles using a transfer component |
US11752792B2 (en) | 2020-03-09 | 2023-09-12 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles using a transfer component |
JP7492907B2 (en) | 2020-11-30 | 2024-05-30 | シャープ株式会社 | Printing system, printing device, and method for printing test patterns |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0413786B1 (en) | 2003-08-21 | 2019-12-24 | Monsanto Technology Llc | recombinant vector with desaturase activity and methods of producing omega-3 fatty acid seed oil, producing omega-3 fatty acid and producing plant comprising seed oil with altered levels of omega-3 fatty acids |
JP2007533310A (en) | 2004-04-16 | 2007-11-22 | モンサント テクノロジー エルエルシー | Expression of fatty acid desaturase in maize |
PT2337791E (en) * | 2008-10-14 | 2013-11-29 | Monsanto Technology Llc | Utilization of fatty acid desaturases from hemiselmis spp |
EP2521440A4 (en) * | 2010-01-05 | 2013-10-23 | Univ Ben Gurion | DEATURASES OF A GREEN MICROALGUE AND USES THEREOF |
CN109536519B (en) * | 2018-12-21 | 2021-11-02 | 广西壮族自治区水牛研究所 | Method for regulating and controlling content of triglyceride in mammary cells of buffalo at molecular level |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5451560A (en) * | 1986-04-11 | 1995-09-19 | Dai Nippon Insatsu Kabushiki Kaisha | Image formation on objective bodies |
US6277229B1 (en) * | 1995-08-25 | 2001-08-21 | Avery Dennison Corporation | Image transfer sheets and a method of manufacturing the same |
US6296901B1 (en) * | 1997-01-24 | 2001-10-02 | Hewlett-Packard Company | Method for producing a multi-layer ink transfer sheet |
US6497781B1 (en) * | 1998-09-10 | 2002-12-24 | American Coating Technology, Inc. | Image transfer sheet |
US6874421B2 (en) * | 2001-04-20 | 2005-04-05 | 3M Innovative Properties Company | Ink jet transfer printing process |
Family Cites Families (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4792523A (en) | 1984-08-31 | 1988-12-20 | Cetus Corporation | 3'Expression enhancing fragments and method |
US4957748A (en) | 1987-03-23 | 1990-09-18 | The Board Of Regents Of The University Of Nebraska | Ruminant feed, method of making and method of using |
US5990387A (en) | 1988-06-10 | 1999-11-23 | Pioneer Hi-Bred International, Inc. | Stable transformation of plant cells |
US6451567B1 (en) | 1988-09-07 | 2002-09-17 | Omegatech, Inc. | Fermentation process for producing long chain omega-3 fatty acids with euryhaline microorganisms |
US5057419A (en) | 1988-09-22 | 1991-10-15 | Rutgers University | Genetically engineered plasmid and organisms for the production of specialized oils |
ATE206462T1 (en) | 1989-02-24 | 2001-10-15 | Monsanto Technology Llc | SYNTHETIC PLANT GENES AND METHOD FOR THEIR PRODUCTION |
US7705215B1 (en) | 1990-04-17 | 2010-04-27 | Dekalb Genetics Corporation | Methods and compositions for the production of stably transformed, fertile monocot plants and cells thereof |
US6803499B1 (en) | 1989-08-09 | 2004-10-12 | Dekalb Genetics Corporation | Methods and compositions for the production of stably transformed, fertile monocot plants and cells thereof |
US5097093A (en) | 1989-08-30 | 1992-03-17 | Pioneer Hi-Bred International, Inc. | Inbred corn line PHJ33 |
US5484956A (en) | 1990-01-22 | 1996-01-16 | Dekalb Genetics Corporation | Fertile transgenic Zea mays plant comprising heterologous DNA encoding Bacillus thuringiensis endotoxin |
US7037692B1 (en) | 1990-03-16 | 2006-05-02 | Calgene, Inc. | Plant desaturases compositions and uses |
CA2077896C (en) | 1990-03-16 | 2008-02-19 | Gregory A. Thompson | Plant desaturases - compositions and uses |
US6117677A (en) | 1990-03-16 | 2000-09-12 | Thompson; Gregory A. | Plant stearoyl-ACP desaturases genes |
CA2083259C (en) | 1990-05-25 | 2007-05-15 | William D. Hitz | Nucleotide sequence of soybean stearoyl-acp desaturase gene |
US5349123A (en) | 1990-12-21 | 1994-09-20 | Calgene, Inc. | Glycogen biosynthetic enzymes in plants |
US5498830A (en) | 1990-06-18 | 1996-03-12 | Monsanto Company | Decreased oil content in plant seeds |
US5219596A (en) | 1990-08-24 | 1993-06-15 | Cargill, Incorporated | Composition and method thereof for increasing milk production in dairy cattle |
US5100679A (en) | 1990-10-03 | 1992-03-31 | Cargill B.V. | Method of making a modified proteinaceous product and composition thereof |
US5405765A (en) | 1991-08-23 | 1995-04-11 | University Of Florida | Method for the production of transgenic wheat plants |
JPH0591886A (en) | 1991-09-30 | 1993-04-16 | Suntory Ltd | 8, 11-eicosadienoic acid and production of lipid containing the same |
US6355861B1 (en) | 1991-10-10 | 2002-03-12 | Rhone-Poulenc Agrochimie | Production of gamma linolenic acid by a Δ6-desaturase |
PH31293A (en) | 1991-10-10 | 1998-07-06 | Rhone Poulenc Agrochimie | Production of y-linolenic acid by a delta6-desaturage. |
US5614393A (en) | 1991-10-10 | 1997-03-25 | Rhone-Poulenc Agrochimie | Production of γ-linolenic acid by a Δ6-desaturase |
DE69233118T2 (en) | 1991-12-04 | 2004-04-15 | E.I. Du Pont De Nemours And Co., Wilmington | FATTY ACID DESATURASE GENES FROM PLANTS |
CA2084348A1 (en) | 1991-12-31 | 1993-07-01 | David F. Hildebrand | Fatty acid alteration by a d9 desaturase in transgenic plant tissue |
ATE242815T1 (en) | 1992-03-13 | 2003-06-15 | Agrigenetics Inc | MODIFICATION OF VEGETABLE OILS BY USING DESATURASE |
US5591616A (en) | 1992-07-07 | 1997-01-07 | Japan Tobacco, Inc. | Method for transforming monocotyledons |
AU5407594A (en) | 1992-11-17 | 1994-06-08 | E.I. Du Pont De Nemours And Company | Genes for microsomal delta-12 fatty acid desaturases and related enzymes from plants |
CA2150133A1 (en) | 1993-02-05 | 1994-08-18 | Vincent Jean-Marie Armel Arondel | Altered linolenic and linoleic acid content in plants |
US5639645A (en) | 1993-09-22 | 1997-06-17 | Mitsubishi Corporation | Recombinant Δ9 desaturase and a gene encoding the same |
ATE273395T1 (en) | 1993-12-28 | 2004-08-15 | Kirin Brewery | FATTY ACID DESATURASE GENE, VECTOR CONTAINING SAID GENE, A PLANT INTO WHICH SAID GENE IS INTRODUCED, AND A METHOD FOR CREATING SAID PLANT |
US6310194B1 (en) | 1994-09-26 | 2001-10-30 | Carnegie Institution Of Washington | Plant fatty acid hydroxylases |
US5545553A (en) | 1994-09-26 | 1996-08-13 | The Rockefeller University | Glycosyltransferases for biosynthesis of oligosaccharides, and genes encoding them |
US5668292A (en) | 1994-09-26 | 1997-09-16 | Carnegie Institution Of Washington | Use of plant fatty acyl hydroxylases to produce hydroxylated fatty acids and derivatives in plants |
US5654402A (en) | 1994-10-26 | 1997-08-05 | Michigan State University | Methods and compositions relating to plant Δ6 palmitoyl-acyl carrier protein desaturase |
US5583019A (en) | 1995-01-24 | 1996-12-10 | Omegatech Inc. | Method for production of arachidonic acid |
US5936069A (en) | 1995-12-06 | 1999-08-10 | Iowa State University Research Foundation | Process for producing improved soy protein concentrate from genetically-modified soybeans |
AU1293297A (en) | 1995-12-14 | 1997-07-03 | Cargill Incorporated | Plants having mutant sequences that confer altered fatty acid profiles |
US5844086A (en) | 1996-01-31 | 1998-12-01 | Stilts Corporation | Oil seed protein extraction |
AU2972497A (en) | 1996-06-03 | 1998-01-05 | Croda International Plc | Treatment of oils |
US5959175A (en) | 1997-04-09 | 1999-09-28 | Thomas; Terry L. | Sunflower albumin 5' regulatory region for the modification of plant seed lipid composition |
US6075183A (en) | 1997-04-11 | 2000-06-13 | Abbott Laboratories | Methods and compositions for synthesis of long chain poly-unsaturated fatty acids in plants |
US5972664A (en) | 1997-04-11 | 1999-10-26 | Abbott Laboratories | Methods and compositions for synthesis of long chain poly-unsaturated fatty acids |
US5968809A (en) | 1997-04-11 | 1999-10-19 | Abbot Laboratories | Methods and compositions for synthesis of long chain poly-unsaturated fatty acids |
US6051754A (en) | 1997-04-11 | 2000-04-18 | Abbott Laboratories | Methods and compositions for synthesis of long chain poly-unsaturated fatty acids in plants |
US6146669A (en) | 1998-05-14 | 2000-11-14 | Cargill Incorporated | Method for processing oilseed material |
EP2816116B1 (en) | 1998-06-12 | 2016-02-03 | Calgene LLC | Polyunsaturated fatty acids in plants |
JP2002534129A (en) | 1999-01-14 | 2002-10-15 | モンサント テクノロジー エルエルシー | Soybean transformation method |
US6156227A (en) | 1999-03-01 | 2000-12-05 | Cargill, Incorporated | Deicer composition which includes a plant material which is a corrosion inhibitor |
US6603061B1 (en) | 1999-07-29 | 2003-08-05 | Monsanto Company | Agrobacterium-mediated plant transformation method |
EP1392823B1 (en) | 2001-01-25 | 2011-11-30 | Abbott Laboratories | Desaturase genes and uses thereof |
CA2446059C (en) * | 2001-05-14 | 2010-03-23 | Martek Biosciences Corporation | Production and use of a polar lipid-rich fraction containing stearidonic acid and gamma linolenic acid from plant seeds and microbes |
GB2385852A (en) | 2002-02-27 | 2003-09-03 | Rothamsted Ex Station | Delta 6-desaturases from Primulaceae |
AU2003225692A1 (en) | 2002-03-08 | 2003-09-22 | Monsanto Technology Llc | Treatment and prevention of inflammatory disorders |
CA2883729C (en) | 2002-05-22 | 2017-03-07 | Virginia M. Ursin | Fatty acid desaturases from fungi |
BRPI0413786B1 (en) | 2003-08-21 | 2019-12-24 | Monsanto Technology Llc | recombinant vector with desaturase activity and methods of producing omega-3 fatty acid seed oil, producing omega-3 fatty acid and producing plant comprising seed oil with altered levels of omega-3 fatty acids |
AU2004290052B2 (en) | 2003-11-12 | 2008-12-04 | Corteva Agriscience Llc | Delta-15 desaturases suitable for altering levels of polyunsaturated fatty acids in oleaginous plants and yeast |
JP2007533310A (en) | 2004-04-16 | 2007-11-22 | モンサント テクノロジー エルエルシー | Expression of fatty acid desaturase in maize |
ATE479757T1 (en) * | 2004-06-04 | 2010-09-15 | Fluxome Sciences As | CELLS MANUFACTURED BY METABOLIC TECHNOLOGY FOR THE PRODUCTION OF POLYUNSATURATED FATTY ACIDS |
-
2007
- 2007-07-18 EP EP07799684A patent/EP2041275B1/en active Active
- 2007-07-18 AT AT07799684T patent/ATE508186T1/en not_active IP Right Cessation
- 2007-07-18 WO PCT/US2007/073793 patent/WO2008011468A2/en active Application Filing
- 2007-07-18 BR BRPI0714390-7A patent/BRPI0714390B1/en active IP Right Grant
- 2007-07-18 DE DE602007014370T patent/DE602007014370D1/en active Active
- 2007-07-18 PT PT07799684T patent/PT2041275E/en unknown
- 2007-07-18 US US11/779,761 patent/US7919685B2/en active Active
- 2007-07-18 MX MX2009000757A patent/MX2009000757A/en active IP Right Grant
- 2007-07-18 DK DK07799684.1T patent/DK2041275T3/en active
- 2007-07-18 ES ES07799684T patent/ES2366297T3/en active Active
- 2007-07-18 CA CA2651402A patent/CA2651402C/en active Active
- 2007-07-18 US US11/879,744 patent/US20080043087A1/en not_active Abandoned
- 2007-07-18 AU AU2007275316A patent/AU2007275316B2/en not_active Ceased
- 2007-07-19 AR ARP070103225A patent/AR062001A1/en not_active Application Discontinuation
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5451560A (en) * | 1986-04-11 | 1995-09-19 | Dai Nippon Insatsu Kabushiki Kaisha | Image formation on objective bodies |
US6277229B1 (en) * | 1995-08-25 | 2001-08-21 | Avery Dennison Corporation | Image transfer sheets and a method of manufacturing the same |
US6506445B2 (en) * | 1995-08-25 | 2003-01-14 | Avery Dennison Corporation | Image transfer sheets and a method of manufacturing the same |
US6296901B1 (en) * | 1997-01-24 | 2001-10-02 | Hewlett-Packard Company | Method for producing a multi-layer ink transfer sheet |
US6677009B2 (en) * | 1997-01-24 | 2004-01-13 | Hewlett-Packard Development Company, L.P. | Method and apparatus for applying a stable printed image onto a fabric substrate |
US6497781B1 (en) * | 1998-09-10 | 2002-12-24 | American Coating Technology, Inc. | Image transfer sheet |
US6874421B2 (en) * | 2001-04-20 | 2005-04-05 | 3M Innovative Properties Company | Ink jet transfer printing process |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9072396B1 (en) | 2009-03-31 | 2015-07-07 | Bellamat Llc | Antimicrobial screening runner and mat |
US9652795B2 (en) * | 2011-10-17 | 2017-05-16 | Schner Minsky | Method for a canvassed self healing bulletin board |
US20140108205A1 (en) * | 2011-10-17 | 2014-04-17 | Schneur Minsky | Method For A Canvassed Self Healing Bulletin Board |
US20150047522A1 (en) * | 2013-08-13 | 2015-02-19 | Crayola Llc | Stamp-Making Methods and Devices |
US10940685B2 (en) | 2015-12-28 | 2021-03-09 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles using a transfer component that deflects on both sides |
US10486368B2 (en) | 2015-12-28 | 2019-11-26 | The Procter & Gamble Company | Method for transferring material with adhesive onto articles with a difference in degree of curing between the material and adhesive |
US10668667B2 (en) | 2015-12-28 | 2020-06-02 | The Procter & Gamble Company | Method for transferring material with adhesive onto articles with a difference in degree of curing between the material and adhesive |
US11141995B2 (en) | 2015-12-28 | 2021-10-12 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles with a pre-distorted transfer component |
WO2017160313A1 (en) * | 2016-03-18 | 2017-09-21 | Hewlett-Packard Development Company, L.P. | Transferring images |
US10414154B2 (en) | 2016-03-18 | 2019-09-17 | Hewlett-Packard Development Company, L.P. | Transferring images |
CN108385410A (en) * | 2016-05-19 | 2018-08-10 | 浙江丽丰服装科技有限公司 | The jeans of the easy-operating digital cold-transfer printing of production method |
CN108570862A (en) * | 2016-05-19 | 2018-09-25 | 浙江丽丰服装科技有限公司 | A kind of jeans of digit printing |
US9505199B1 (en) * | 2016-06-03 | 2016-11-29 | Abbas Sadriwalla | Method of applying a graphic image on a substrate |
US10752795B2 (en) | 2017-11-17 | 2020-08-25 | The Procter & Gamble Company | Compositions and methods for applying a material onto articles |
US11491803B2 (en) | 2019-02-12 | 2022-11-08 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles using a transfer component |
US11752792B2 (en) | 2020-03-09 | 2023-09-12 | The Procter & Gamble Company | Method and apparatus for applying a material onto articles using a transfer component |
JP7492907B2 (en) | 2020-11-30 | 2024-05-30 | シャープ株式会社 | Printing system, printing device, and method for printing test patterns |
Also Published As
Publication number | Publication date |
---|---|
DE602007014370D1 (en) | 2011-06-16 |
WO2008011468A2 (en) | 2008-01-24 |
US7919685B2 (en) | 2011-04-05 |
WO2008011468A3 (en) | 2008-08-21 |
US20080020122A1 (en) | 2008-01-24 |
AR062001A1 (en) | 2008-08-10 |
ES2366297T3 (en) | 2012-01-13 |
EP2041275A2 (en) | 2009-04-01 |
EP2041275B1 (en) | 2011-05-04 |
AU2007275316A1 (en) | 2008-01-24 |
ATE508186T1 (en) | 2011-05-15 |
CA2651402A1 (en) | 2008-01-24 |
PT2041275E (en) | 2011-08-18 |
CA2651402C (en) | 2016-04-05 |
BRPI0714390A2 (en) | 2014-06-24 |
WO2008011468A8 (en) | 2008-10-16 |
DK2041275T3 (en) | 2011-08-22 |
MX2009000757A (en) | 2009-03-09 |
BRPI0714390B1 (en) | 2018-05-15 |
AU2007275316B2 (en) | 2012-09-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20080043087A1 (en) | Digital transfer method for printing on a target surface | |
US7720421B2 (en) | Apparatus and method for printing a scratch-off document | |
US8735320B2 (en) | Method of transfer printing using white toner | |
CN101378912B (en) | Ink, ink cartridge, ink jet recording apparatus and method, and fixation temperature control apparatus | |
US20100086753A1 (en) | Foiled articles and methods of making same | |
US20110193336A1 (en) | Method and system of printing a scratch-off document | |
DE69319224T2 (en) | IMAGE IMPROVEMENT | |
KR20010023897A (en) | Image transfer method | |
KR100973562B1 (en) | Image display medium and thermal transfer sheet having metallic images | |
JP2008173980A (en) | Transfer film for curved surface printing and its manufacturing method | |
JP2012066530A (en) | Thermal transfer sheet and image forming method using the same | |
JP2000141992A (en) | Transfer film for printing curved face and manufacture thereof | |
WO2005062978A3 (en) | Optically variable personalized indicia for identification documents | |
JP2002019390A (en) | Thermal transfer label for fiber product | |
Mumby | Printing for packaging | |
US20020121333A1 (en) | Applying digitally created graphic images to leather (Cow hide, Calf, Pig, Goat, Kid, and sheep skin) | |
Tagansky | HP-indigo technology and its application to photo printing | |
CN110303784A (en) | A kind of printing technology with flocking effect | |
JP2011201180A (en) | Thermal transfer sheet and image forming method using the same | |
JP2009145901A (en) | Receptive layer transfer material and transfer sheet | |
JP2009154496A (en) | Image forming method, and intermediate transfer recording medium | |
KR20190049807A (en) | Apparatus and method for optically variable printing | |
JP2011524996A (en) | Non-impact printing method and article by this method | |
Parraman | Colour printing techniques and new developments in colour printing | |
JPH1134594A (en) | Thermal transfer texture printing sheet and its manufacture |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO PAY ISSUE FEE |