US20070187734A1 - A cmos imager photodiode with enhanced capacitance - Google Patents
A cmos imager photodiode with enhanced capacitance Download PDFInfo
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- US20070187734A1 US20070187734A1 US11/276,085 US27608506A US2007187734A1 US 20070187734 A1 US20070187734 A1 US 20070187734A1 US 27608506 A US27608506 A US 27608506A US 2007187734 A1 US2007187734 A1 US 2007187734A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F39/00—Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
- H10F39/10—Integrated devices
- H10F39/12—Image sensors
- H10F39/18—Complementary metal-oxide-semiconductor [CMOS] image sensors; Photodiode array image sensors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F39/00—Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
- H10F39/011—Manufacture or treatment of image sensors covered by group H10F39/12
- H10F39/014—Manufacture or treatment of image sensors covered by group H10F39/12 of CMOS image sensors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F39/00—Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
- H10F39/80—Constructional details of image sensors
- H10F39/807—Pixel isolation structures
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/14—Shape of semiconductor bodies; Shapes, relative sizes or dispositions of semiconductor regions within semiconductor bodies
- H10F77/147—Shapes of bodies
Definitions
- the present invention relates to semiconductor optical image sensors, and particularly, to a novel CMOS (complementary metal oxide semiconductor) image sensor photodiode structure having a deep trench with a diode all along its sidewall to increase the capacitance of the structure without increasing the area of the cell.
- This trench structure can be designed in such a way that the trench will be fully depleted during the reset phase of operation and can hold a larger charge due to its larger capacitance than a conventional photodiode.
- CMOS image sensors are now replacing conventional CCD sensors for applications requiring image pick-up such as digital cameras, cellular phones, PDA (personal digital assistant), personal computers, and the like.
- CMOS image sensors are fabricated by applying present CMOS fabricating process for semiconductor devices such as photodiodes or the like, at low costs.
- CMOS image sensors can be operated by a single power supply so that the power consumption for that can be restrained lower than that of CCD sensors, and further, CMOS logic circuits and like logic processing devices are easily integrated in the sensor chip and therefore the CMOS image sensors can be miniaturized.
- CMOS imagers As the pixel size in CMOS imagers continue to scale down, to reduce costs, several problems arise: First, the smaller area reduces the total amount of electrons that can be stored in a given cell due to the reduced cell capacitance. Second, the smaller area increases the crosstalk between cells because electron diffusion is primarily responsible for the transport of the electrons from deep into the substrate to the surface photodiode. Third, the signal to noise ratio degrades because of a smaller number of electrons that are being measured and the noise sources (which primarily come from the periphery of the photodiode and its support circuits) that have not scaled. Current trench-type CMOS imager photosensor devices are described in U.S. Pat. Nos. 6,232,626; 6,500,692; 2004/0195600 and additionally, U.S. Pat. Nos. 6,611,037; 6,767,759; 6,730,980 and 6,838,742.
- FIG. 1 depicts a typical photosensor cell 10 having a trench-type configuration such as shown in prior art U.S. Pat. No. 6,232,626.
- photosensor cell 10 is formed on a semiconductor substrate that includes an epitaxial layer or well surface layer 15 of a first conductivity type, e.g., p-doped.
- the photosensor cell 10 includes an overlying conductive layer 18 that is transparent to radiant energy and may comprise polysilicon.
- Element 25 comprises a transfer gate and includes diffusion regions 20 and 30 doped with material of a second conductivity type, e.g., n-doped. According to the prior art, the doped diffusion regions 20 and 30 are performed by ion implantation.
- the diffusion region 30 that is a floating diffusion region of the second conductivity-type serves as the source for a further reset transistor (not shown).
- the combined n-doped diffusion region 20 and p-type substrate 15 comprises a photodiode sensor for converting the photon energy into accumulating image charge for the photosensor cell pixel 10 .
- the charge transfer transistor gate 25 is shown surrounded by thin spacer structures 23 a,b .
- An STI region 40 is formed proximate the pixel imager cell for isolating the cell 10 from an adjacent pixel cell. In operation, light coming from the pixel is focused onto the photodiode where electrons collect at the n-type region 20 .
- the transfer gate 25 is operated, i.e., turned on by applying a voltage to the transfer gate comprising, for example, an n-type doped polysilicon layer or conducting layer 70 , the photo-generated charge 24 is transferred from the charge accumulating n-type doped region 20 via a transfer device surface channel 16 to the floating diffusion region 30 , e.g., doped n+ type, as shown by arrow A.
- CMOS imager photosensor devices a characteristic of these trench type CMOS imager photosensor devices is the existence of large dark current, i.e., leakage current, which discharges the pixel capacitance when there is no light over the pixel.
- the dark current measured at the pixel output depends on the photodiode, the transistors, and the interconnectivity in the pixel. None of the above-indicated prior art references teach isolating the charge collection region thus, and do not address dark current performance.
- CMOS imager having the photodetector diode formed on the sidewall of a deep trench, resulting in collector isolation, and, a simplified process therefore.
- CMOS imager having a photodetector diode formed on the sidewall of a deep trench, the photodiode thus exhibiting increased electron capacity by increasing the photodiode capacitance without adding to the cell size, or to the cell leakage.
- CMOS image sensor having a photodetector diode formed on the sidewall of a deep trench, resulting in collector isolation, and, a simplified process therefore.
- a pixel sensor cell comprising a non-lateral (e.g., vertical) collection region which is isolated from a physical boundary (e.g., substrate surfaces such as top surface or sidewalls/bottom of trench).
- a trench is formed in a substrate of a first conductivity type (p type); a first doped layer of a second conductivity type (n type) is formed surrounding the trench walls to form a collection region; a second doped layer of the first conductivity type (p type) is formed between the first doped layer and the trench walls, and a third doped layer of the first conductivity type is formed on a surface of the substrate coupled to the second doped layer, wherein the second and third doped layers form a “pinning layer” for the sensor cell and isolate the collection region (e.g. first doped layer) from the trench walls and substrate surface.
- the isolating of the deep trench photodiode collection region (e.g. first doped layer) from the trench walls and substrate surface of the pixel sensor cell enables improved dark current performance with the same or smaller pinning voltage.
- a number of embodiments are described that include a pixel sensor cell structure having a semiconductor substrate having a surface; a photosensitive element formed in a substrate having a non-laterally disposed charge collection region, the non-lateral charge collection region being entirely isolated from a physical boundary including the substrate surface.
- the photosensitive element comprises a trench having sidewalls formed in the substrate of a first conductivity type material; a first doped layer of a second conductivity type material formed adjacent to at least one of the sidewalls; and a second doped layer of the first conductivity type material formed between the first doped layer and the at least one trench sidewall and formed at a surface of the substrate, the second doped layer isolating the first doped layer from the at least one trench sidewall and said substrate surface.
- an additional photosensitive element includes a laterally disposed charge collection region including a layer of second conductivity type material that contacts the first layer of the second conductivity type material of the non-laterally disposed charge collection region of the first photosensitive element.
- This layer of second conductivity type material underlies the second doped layer of the first conductivity type material formed at the substrate surface.
- the additional photosensitive element is formed adjacent a transfer gate device enabled for transferring charge carriers from both the laterally disposed charge collection region of the additional photosensitive element and charge carriers from the non-laterally disposed charge collection region of the photosensitive element across a gate channel to a formed diffusion region.
- the second conductivity type material of the first layer of the non-laterally disposed charge collection region of the photosensitive element is of a concentration such that the photosensitive element is fully depleted of accumulated charge carriers prior to depletion of charge carriers accumulated at the laterally disposed charge collection region of the additional photosensitive element.
- a method for fabricating a pixel sensor cell including a photosensitive element having a non-laterally disposed charge collection region comprising:
- a collection region of the trench-type photosensitive element is formed of the outdiffused second conductivity type material and is isolated from the substrate surface.
- a further step is performed whereby first conductivity type material is diffused out of the filled trench material to form a layer of first conductvity type material in a substrate region surrounding the trench sidewalls and bottom and between the non-laterally disposed charge collection region of the photosensitive element
- a second photosensitive element is formed having a charge collection region that is laterally disposed and abuts the non-laterally disposed charge collection region of the first photosensitive element.
- This step entails implanting second conductivity type material underneath the surface implant layer having the first conductivity type material, wherein the implanted second conductivity type material forms a charge collection region that is isolated from the substrate surface.
- FIG. 1 illustrates, through a cross-sectional view, the CMOS image sensor 10 including a photodiode element according to the prior art
- FIG. 2 depicts, through a cross-sectional view, one CMOS image sensor cell 100 including a photodiode element 120 according to a first embodiment of the invention
- FIG. 3 illustrates, through a cross-sectional view, the CMOS image sensor cell 200 including a photodiode element 220 according to a second embodiment of the invention.
- FIGS. 4A-4H depict processing steps for forming the trench photodiode element according to the first embodiment of the invention.
- FIGS. 5A-5D depict processing steps for forming the trench photodiode element according to the second embodiment of the invention.
- FIG. 2 depicts, through a cross-sectional view, one CMOS image sensor cell 100 including a photosensor element 120 (e.g., photodiode) according to a first embodiment of the invention. While only a single CMOS image sensor cell 100 is depicted for exemplary purposes, it is understood that the pixel cell structure depicted is contemplated for inclusion in an array of pixels arranged in rows and columns with rows and columns of pixels addressable by pixel select circuitry not shown. Each cell in such an array of pixels may be isolated from an adjacent cell by a Shallow Trench Isolation (STI) structure not shown in the drawings.
- STI Shallow Trench Isolation
- the CMOS image sensor cell 100 including the trench-type photodiode element 120 is formed on a semiconductor substrate 105 of a first conductivity type, typically p-type silicon.
- the substrate 105 may be a bulk semiconductor including, for example, Si, SiGe, SiC, SiGeC, GaAs, InP, InAs and other III-V compound semiconductors, II-V compound semiconductors, or layered semiconductors such as silicon-on-insulators (SOI), SiC-on-insulator (SiCOI) or silicon germanium-on-insulators (SGOI).
- substrate 105 is a Si-containing semiconductor substrate of a first conductivity type, e.g., lightly doped with p-type dopant material such as boron or indium (beryllium or magnesium for a ITT-V semiconductor), to a standard concentration ranging between, for example, 1 e 14 to 1 e 16 cm ⁇ 3 .
- p-type dopant material such as boron or indium (beryllium or magnesium for a ITT-V semiconductor
- the photosensor device itself e.g., photodiode 120
- a non-lateral (e.g. vertical) collection region, typically of a second conductivity type, e.g., n-type doped layer 112 is formed immediately adjacent and surrounding the p-type region 118 .
- photocarriers are generated in a photoactive collection area 106 of the p-type substrate and are collected in the n-type region 112 surrounding the p-type polysilicon filled trench 121 .
- the n-type doped region 112 surrounding the trench couples in to the transfer gate directly.That is, as shown in FIG. 2 , formed adjacent to the photodiode element 120 is a transfer gate 125 that operates to transfer photo-generated charge from the charge accumulating n-type doped region 112 of photodiode element 120 through channel 160 to a floating diffusion region 140 , e.g., doped n+ type as in current photosensor cell designs.
- characteristic of the photosensor (photodiode) element 120 of the invention is that the charge collection region 112 is isolated from a physical boundary such as, for example, the top substrate surface or sidewalls/bottom of trench surface.
- a p-type surface layer 130 a,b is formed that functions as a pinning layer for the sensor cell and isolates the collection region 112 from surface boundaries.
- the p-type dopant material outdiffused past the trench boundary and forming the p-type boundary layer 118 isolates the collection region 112 from the trench sidewall and bottom surface boundaries.
- surface layer 130 b is typically doped lower and shallower than 130 a.
- FIG. 3 illustrates, through a cross-sectional view, the CMOS image sensor cell 200 including a photosensor element 220 (e.g., photodiode) according to a second embodiment of the invention.
- a photosensor element 220 e.g., photodiode
- CMOS image sensor cell 200 While only a single CMOS image sensor cell 200 is depicted for exemplary purposes, it is understood that the pixel cell structure depicted is contemplated for inclusion in an array of pixels arranged in rows and columns with rows and columns of pixels addressable by pixel select circuitry not shown.
- the CMOS image sensor cell 200 includes a first conventional photodiode 250 and a second trench-type photodiode element 220 formed adjacent the photodiode 250 .
- the first conventional photodiode 250 is oriented laterally (horizontally) and abuts the trench-type photodiode element 220 such that a charge collection region of the conventional photodiode 250 connects to the charge collection region of the trench-type photodiode element 220 .
- Both first lateral photodiode 250 and second trench-type photodiode element 220 are formed on a semiconductor substrate 205 of a first conductivity type, typically p-type silicon, as in the first embodiment and underlie a p-type surface layer 230 a,b for enhanced isolation.
- a first conductivity type typically p-type silicon
- the total capacitance of the sensor cell structure 200 according to the second embodiment of the invention is increased without increasing the area of the photodiode.
- the second photosensor device itself e.g., photodiode 220
- a non-lateral (e.g. vertical) collection region, typically of a second conductivity type, e.g., n-type doped layer 212 is formed immediately adjacent and surrounding the p-type region 218 .
- photocarriers are generated in a photoactive collection area 206 of the p-type substrate and are collected both in the n-type doped region forming photodiode 250 and in the n-type region 212 surrounding the p-type polysilicon filled trench 221 .
- the n-type doped region forming photodiode 250 couples its collected charge and charge collected from the n-type doped region 212 surrounding the trench to the transfer gate directly. That is, as shown in FIG.
- a transfer gate 225 that operates to transfer photo-generated charge from the charge accumulating n-type doped photodiode 250 and the charge accumulating n-type doped region 212 of photodiode element 220 through channel 260 to a floating diffusion region 240 , e.g., doped n+ type as in current photosensor cell designs.
- characteristic of the photosensor (photodiode) element 220 of the second embodiment is that the charge collection regions 212 and 250 are isolated from a physical boundary such as, for example, the top substrate surface or sidewalls/bottom of trench surface.
- a p-type surface layer 230 a,b is formed that functions as a pinning layer for the sensor cell and isolates the collection region 212 , 250 from surface boundaries.
- the depth of p-type layer 230 b formed under the transfer gate is shallower than the remaining portion of the p-type layer 230 b .
- the pinning potential is determined by photodiode parameters.
- the trench photodiode element 220 is designed to be fully depleted before the lateral photodiode 250 . That is, the doping level of the n-type charge collection region 212 is lower than the doping level of the n-type charge collection region of the lateral photodiode 250 .
- a trench 321 is formed in a substrate of a first conductivity type (e.g., p-type).
- substrate 305 is a Si-containing semiconductor substrate of a first conductivity type, e.g., lightly doped with p-type dopant material such as boron or indium (beryllium or magnesium for a III-V semiconductor), to a standard concentration ranging between, e.g., 1 e 14 atoms/cm 3 to 1 e 16 atoms/cm 3 .
- the trench recess 321 is formed in the substrate. That is, utilizing a trench lithography, a photoresist mask (not shown) is applied, patterned and developed to expose an open region for forming a trench etch.
- an etch process e.g., reactive ion etching
- an etch process is performed through the opening in the mask to form the trench recess 321 that extends down below the substrate surface to a depth of about 0.2 ⁇ m to 6 ⁇ m.
- the shape of the opened trench may be vertical (box like), or tapered, or “v”-like shaped.
- the trench recess 321 is filled with a material 331 doped with material of a second conductivity type, e.g., n-type dopant material.
- such a glass material may comprise PSG (phosphor silicateglass) for sourcing n-type doped material, and may be deposited within the trench by a well-known CVD process, or alternately a SOG, (spun on glass) process may be used.
- a etch-back or chemical-mechanical planarization technique is implemented to remove any excess PSG filler material and planarize the substrate surface.
- a thermal treatment e.g., anneal, is conducted as to drive out the n-type dopant from the glass source 331 into the trench walls.
- the n-type impurity from the PSG trench fill 331 is outdiffused to the substrate region surrounding the trench sidewalls and bottom to form the n-type photocarrier collection region 312 of the resulting photodiode element.
- the n-type photocarrier collection region 312 ranges in thickness between 20 nm and 400 nm, and includes n-type carriers of a concentration ranging between 1 ⁇ 10 16 atoms/cm 3 and 1 ⁇ 10 18 atoms/cm 3 .
- the PSG trench fill 331 is etched out, e.g., by a selective hydrofluoric acid (HF) etch, or potentially a fluorine based RIE (Reactive Ion Etch) process, or a combination of wet and dry processing, to result in the structure depicted in FIG. 4C .
- HF selective hydrofluoric acid
- RIE reactive Ion Etch
- the now open photosensor device trench 321 is again filled this time with poly-Silicon in-situ doped with first conductivity type material, e.g., p-type polysilicon 315 with any excess poly-Si material 315 being planarized by CMP as shown in FIG. 4D .
- the process includes an isolation step e.g., forming trenches 340 a , 340 b to become (SROX or STI) isolation structures 345 a , 345 b , as shown in FIG. 4F followed by Nwell, Pwell implants and other well implants. Additionally formed are the p-type doped material layer 330 a , 330 b .
- a Vt tailor implant for the transfer gate comprises implantation of a p-type doped material to form layer 330 b in FIG. 4F ).
- the dopant concentration for the Vt tailor implant for the transfer gate is typically greater than e16 cm 3 ).
- the gate processing, the extension, and source/drain implants 340 as shown in FIG. 4H are followed by the gate processing, the extension, and source/drain implants 340 as shown in FIG. 4H .
- the pinning layer implants are also performed.
- a surface oxide layer 348 typically an oxide such as SiO 2 or like dielectric oxide, nitride or oxynitride
- a gate conducting layer or gate stack 325 e.g., of polysilicon material.
- the transfer gate may comprise a doped layer or a conductive layer, e.g., doped polysilicon, tungsten or other suitable material over the insulating gate dielectric layer 72 , e.g., silicon dioxide or silicon nitride, and may include insulating sidewall spacers 23 a,b as shown in FIG. 1 .
- a doped layer or a conductive layer e.g., doped polysilicon, tungsten or other suitable material over the insulating gate dielectric layer 72 , e.g., silicon dioxide or silicon nitride, and may include insulating sidewall spacers 23 a,b as shown in FIG. 1 .
- FIG. 4H there is depicted in greater detail an additional step of implanting p-type dopant material to the surface of the structure to form the p-type surface implant layer 330 a ′, i.e., to keep electrons away from surface generation/recombination sites.
- This step is typically performed at (shortly before or after) the source/drain implant steps.
- This step entails implanting dopant material onto the substrate surface at openings formed in a prior photolithography step (not shown) corresponding to surface location indicated at 330 a ′.
- p-type dopant material is implanted at suitable energies and concentrations to ensure electrical conductivity to the underlying lightly-doped substrate.
- the thickness of p-type surface layer 330 a ranges between 10 nm and 200 nm and preferably has a concentration greater than 1 ⁇ 10 18 atoms/cm 3 to ensure that the collection region is isolated from the surface and subsequently formed transfer gate device.
- FIGS. 5A and 5B the resultant structure photosensor cell structure formed after applying similar processing steps such as described herein with respect to FIGS. 4E-4G is shown in FIGS. 5A and 5B .
- FIGS. 5A-5D particularly depict the method steps performed after the vertical photodiode processing (having polysilicon conductor 415 ) is complete. These steps include standard CMOS imager processing steps starting at the isolation level followed by the N photodiode implant, Nwell, Pwell, and other well implants, the gate processing, the extensions, source/drain implants, and the pinning layer implants etc . . . as is done in a industry standard CMOS imager process flow.
- a resultant structure after forming the trench (e.g., STI) isolation structures 445 a , 445 b , and implantation of the p-type doped material layer 430 a , 430 b .
- a Vt tailor implant for the transfer gate comprises implantation of a p-type doped material to form layer 430 b in FIG. 5A ). Then, as shown in FIG.
- a surface oxide layer 448 typically an oxide such as SiO 2 or like dielectric oxide, nitride or oxynitride
- a gate conducting layer or gate stack 425 of a doped layer or a conductive layer e.g., doped polysilicon, tungsten or other suitable material over the insulating gate dielectric layer.
- the N photodiode implant 450 is depicted, as is depicted the extension, and source/drain implants 440 in FIG. 5D .
- the pinning layer implants are also performed
- the photodiode device is exposed to a suitable amount of temperature as a result of the thermal budgets employed during the subsequent CMOS imager processing flow at durations suitable to enable a second outdiffusion of the in-situ doped first conductivity type material, e.g., p-type polysilicon 315 , to form an outdiffused p-type layer 118 ( FIG. 2 ) and outdiffused p-type layer 218 ( FIG. 3 ) of the respective photodiodes 100 , 200 of the invention between the respective first n-type doped regions 112 , 212 and the trench bottom/sidewalls.
- the in-situ doped first conductivity type material e.g., p-type polysilicon 315
- the respective doped surface layers 130 a , 130 b and 230 a , 230 b of the first conductivity type formed on a surface of the substrate are coupled to the outdiffused p-type layers 118 , 218 of the respective photodiodes 100 , 200 , such that they form a “pinning layer” for the sensor cell and isolate the collection region (e.g., first n-type doped layer) from the trench walls and substrate surface.
- the additional step of forming the second out-diffused layers 118 , 218 of the respective photodiodes 100 , 200 is such that the concentration of outdiffused first conductivity type (p-type) material in layers 118 , 218 is greater than the concentration of the respective outdiffused second conductivity type (n-type) material forming the respective photocarrier collection regions 112 , 212 .
- the benefits of the CMOS photosensor cell of the invention include: 1) increased cell capacity; 2) the ability to be fully depleted; 3) a pinned structure (no oxide interfaces with n-type dopant abutting); 4) reduced crosstalk (That is, the deep trench structure creates a lateral field deep in the silicon which preferentially collects charge generated close to this cell (and adjacent cells will collect their charge preferentially as well)); 5) no increase in cell area needed to get higher capacity (which would occur if capacity was designed to be increased by making the photodiode larger); 6) small increase in dark current (That is, dark current increase would be very large if capacity was designed to be increased by increasing dopant concentrations; and, 7) no change in pinning potential (which would occur if capacity was designed to be increased by increasing dopant concentration).
- the trench photodiode 220 is of such n-type dopant concentrations and is suitably biased in operation to ensure that it becomes fully depleted before the lateral photodiode 250 becomes depleted, i.e., all electrons are driven out of the transfer gate of the deep trench photodiode 220 .
- the n-type doped region 212 is fully depleted at a pinning voltage which is supplied by the floating diffusion through the transfer gate in order to cut down on dark current.
- the pinned photodiode is termed “pinned” because the potential in the photodiode is pinned to a constant value, Vp, when the photodiode is fully depleted.
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Abstract
Description
- The present invention relates to semiconductor optical image sensors, and particularly, to a novel CMOS (complementary metal oxide semiconductor) image sensor photodiode structure having a deep trench with a diode all along its sidewall to increase the capacitance of the structure without increasing the area of the cell. This trench structure can be designed in such a way that the trench will be fully depleted during the reset phase of operation and can hold a larger charge due to its larger capacitance than a conventional photodiode.
- CMOS image sensors are now replacing conventional CCD sensors for applications requiring image pick-up such as digital cameras, cellular phones, PDA (personal digital assistant), personal computers, and the like. Advantageously, CMOS image sensors are fabricated by applying present CMOS fabricating process for semiconductor devices such as photodiodes or the like, at low costs. Furthermore, CMOS image sensors can be operated by a single power supply so that the power consumption for that can be restrained lower than that of CCD sensors, and further, CMOS logic circuits and like logic processing devices are easily integrated in the sensor chip and therefore the CMOS image sensors can be miniaturized.
- As the pixel size in CMOS imagers continue to scale down, to reduce costs, several problems arise: First, the smaller area reduces the total amount of electrons that can be stored in a given cell due to the reduced cell capacitance. Second, the smaller area increases the crosstalk between cells because electron diffusion is primarily responsible for the transport of the electrons from deep into the substrate to the surface photodiode. Third, the signal to noise ratio degrades because of a smaller number of electrons that are being measured and the noise sources (which primarily come from the periphery of the photodiode and its support circuits) that have not scaled. Current trench-type CMOS imager photosensor devices are described in U.S. Pat. Nos. 6,232,626; 6,500,692; 2004/0195600 and additionally, U.S. Pat. Nos. 6,611,037; 6,767,759; 6,730,980 and 6,838,742.
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FIG. 1 depicts atypical photosensor cell 10 having a trench-type configuration such as shown in prior art U.S. Pat. No. 6,232,626. As shown inFIG. 1 ,photosensor cell 10 is formed on a semiconductor substrate that includes an epitaxial layer or wellsurface layer 15 of a first conductivity type, e.g., p-doped. Thephotosensor cell 10 includes an overlyingconductive layer 18 that is transparent to radiant energy and may comprise polysilicon. Aninsulating layer 22 formed of a suitable material, e.g., SiO2, is formed between theconductive layer 18 and underlying dopeddiffusion region 20.Element 25 comprises a transfer gate and includesdiffusion regions doped diffusion regions diffusion region 30 that is a floating diffusion region of the second conductivity-type serves as the source for a further reset transistor (not shown). The combined n-dopeddiffusion region 20 and p-type substrate 15 comprises a photodiode sensor for converting the photon energy into accumulating image charge for thephotosensor cell pixel 10. - The charge
transfer transistor gate 25 is shown surrounded bythin spacer structures 23 a,b. AnSTI region 40 is formed proximate the pixel imager cell for isolating thecell 10 from an adjacent pixel cell. In operation, light coming from the pixel is focused onto the photodiode where electrons collect at the n-type region 20. When thetransfer gate 25 is operated, i.e., turned on by applying a voltage to the transfer gate comprising, for example, an n-type doped polysilicon layer or conductinglayer 70, the photo-generatedcharge 24 is transferred from the charge accumulating n-type dopedregion 20 via a transferdevice surface channel 16 to thefloating diffusion region 30, e.g., doped n+ type, as shown by arrow A. - While touted as providing increased surface area as compared to a flat photosensor element occupying a comparable area on a substrate, thus exhibiting a higher charge capacity and improved dynamic range, there are drawbacks, particularly, in the fact that this prior art photosensor cell of
FIG. 1 teaches forming the charge collection region adjacent to physical boundaries such as trench walls, STI oxide structures, and the surface of the substrate. - Thus, a characteristic of these trench type CMOS imager photosensor devices is the existence of large dark current, i.e., leakage current, which discharges the pixel capacitance when there is no light over the pixel. The dark current measured at the pixel output depends on the photodiode, the transistors, and the interconnectivity in the pixel. None of the above-indicated prior art references teach isolating the charge collection region thus, and do not address dark current performance.
- It would be highly desirable to provide a CMOS imager having the photodetector diode formed on the sidewall of a deep trench, resulting in collector isolation, and, a simplified process therefore.
- It would be highly desirable to provide a CMOS imager having a photodetector diode formed on the sidewall of a deep trench, the photodiode thus exhibiting increased electron capacity by increasing the photodiode capacitance without adding to the cell size, or to the cell leakage.
- It thus an object of the invention to provide a CMOS image sensor having a photodetector diode formed on the sidewall of a deep trench, resulting in collector isolation, and, a simplified process therefore.
- It is a further object of the invention to provide a CMOS imager having a photodetector diode formed on the sidewall of a deep trench, the photodiode having increased electron capacity by increasing the photodiode capacitance without adding to the cell size, or to the cell leakage.
- According to one aspect of the invention, there is provided a pixel sensor cell comprising a non-lateral (e.g., vertical) collection region which is isolated from a physical boundary (e.g., substrate surfaces such as top surface or sidewalls/bottom of trench). In an embodiment of the invention, a trench is formed in a substrate of a first conductivity type (p type); a first doped layer of a second conductivity type (n type) is formed surrounding the trench walls to form a collection region; a second doped layer of the first conductivity type (p type) is formed between the first doped layer and the trench walls, and a third doped layer of the first conductivity type is formed on a surface of the substrate coupled to the second doped layer, wherein the second and third doped layers form a “pinning layer” for the sensor cell and isolate the collection region (e.g. first doped layer) from the trench walls and substrate surface.
- Advantageously, the isolating of the deep trench photodiode collection region (e.g. first doped layer) from the trench walls and substrate surface of the pixel sensor cell enables improved dark current performance with the same or smaller pinning voltage.
- A number of embodiments are described that include a pixel sensor cell structure having a semiconductor substrate having a surface; a photosensitive element formed in a substrate having a non-laterally disposed charge collection region, the non-lateral charge collection region being entirely isolated from a physical boundary including the substrate surface. The photosensitive element comprises a trench having sidewalls formed in the substrate of a first conductivity type material; a first doped layer of a second conductivity type material formed adjacent to at least one of the sidewalls; and a second doped layer of the first conductivity type material formed between the first doped layer and the at least one trench sidewall and formed at a surface of the substrate, the second doped layer isolating the first doped layer from the at least one trench sidewall and said substrate surface.
- In a further embodiment, an additional photosensitive element is provided that includes a laterally disposed charge collection region including a layer of second conductivity type material that contacts the first layer of the second conductivity type material of the non-laterally disposed charge collection region of the first photosensitive element. This layer of second conductivity type material underlies the second doped layer of the first conductivity type material formed at the substrate surface.
- In accordance with this further embodiment, the additional photosensitive element is formed adjacent a transfer gate device enabled for transferring charge carriers from both the laterally disposed charge collection region of the additional photosensitive element and charge carriers from the non-laterally disposed charge collection region of the photosensitive element across a gate channel to a formed diffusion region. The second conductivity type material of the first layer of the non-laterally disposed charge collection region of the photosensitive element is of a concentration such that the photosensitive element is fully depleted of accumulated charge carriers prior to depletion of charge carriers accumulated at the laterally disposed charge collection region of the additional photosensitive element.
- According to another aspect of the invention, there is provided a method for fabricating a pixel sensor cell including a photosensitive element having a non-laterally disposed charge collection region. The method comprises:
- forming a trench recess in a substrate of a first conductivity type material, the trench having sidewall and bottom portions;
- filling the trench recess with a material having second conductivity type material;
- outdiffuse second conductivity type material out of the filled trench material to the substrate region surrounding the trench sidewalls and bottom to form the non-laterally disposed charge collection region;
- removing the filled trench material to provide the trench recess;
- filling the trench recess with a material having a first conductivity type material;
- forming a surface implant layer having first conductivity type material, the surface implant layer formed at either side of the trench,
- wherein a collection region of the trench-type photosensitive element is formed of the outdiffused second conductivity type material and is isolated from the substrate surface.
- A further step is performed whereby first conductivity type material is diffused out of the filled trench material to form a layer of first conductvity type material in a substrate region surrounding the trench sidewalls and bottom and between the non-laterally disposed charge collection region of the photosensitive element
- In a further embodiment, a second photosensitive element is formed having a charge collection region that is laterally disposed and abuts the non-laterally disposed charge collection region of the first photosensitive element. This step entails implanting second conductivity type material underneath the surface implant layer having the first conductivity type material, wherein the implanted second conductivity type material forms a charge collection region that is isolated from the substrate surface.
- The objects, features and advantages of the present invention will become apparent to one skilled in the art, in view of the following detailed description taken in combination with the attached drawings, in which:
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FIG. 1 illustrates, through a cross-sectional view, theCMOS image sensor 10 including a photodiode element according to the prior art; -
FIG. 2 depicts, through a cross-sectional view, one CMOSimage sensor cell 100 including aphotodiode element 120 according to a first embodiment of the invention; -
FIG. 3 illustrates, through a cross-sectional view, the CMOSimage sensor cell 200 including aphotodiode element 220 according to a second embodiment of the invention; and, -
FIGS. 4A-4H depict processing steps for forming the trench photodiode element according to the first embodiment of the invention. -
FIGS. 5A-5D depict processing steps for forming the trench photodiode element according to the second embodiment of the invention. -
FIG. 2 depicts, through a cross-sectional view, one CMOSimage sensor cell 100 including a photosensor element 120 (e.g., photodiode) according to a first embodiment of the invention. While only a single CMOSimage sensor cell 100 is depicted for exemplary purposes, it is understood that the pixel cell structure depicted is contemplated for inclusion in an array of pixels arranged in rows and columns with rows and columns of pixels addressable by pixel select circuitry not shown. Each cell in such an array of pixels may be isolated from an adjacent cell by a Shallow Trench Isolation (STI) structure not shown in the drawings. - As shown in
FIG. 2 , the CMOSimage sensor cell 100 including the trench-type photodiode element 120 is formed on asemiconductor substrate 105 of a first conductivity type, typically p-type silicon. Thesubstrate 105 however may be a bulk semiconductor including, for example, Si, SiGe, SiC, SiGeC, GaAs, InP, InAs and other III-V compound semiconductors, II-V compound semiconductors, or layered semiconductors such as silicon-on-insulators (SOI), SiC-on-insulator (SiCOI) or silicon germanium-on-insulators (SGOI). For purposes of description,substrate 105 is a Si-containing semiconductor substrate of a first conductivity type, e.g., lightly doped with p-type dopant material such as boron or indium (beryllium or magnesium for a ITT-V semiconductor), to a standard concentration ranging between, for example, 1 e14 to 1 e16 cm−3. - The photosensor device itself, e.g.,
photodiode 120, comprises atrench structure 121 filled with first conductivity type material, e.g., p-type polysilicon 115, and includes a p-type dopant material outdiffused past the trench boundary forming a p-type boundary layer 118 surrounding thetrench 121. A non-lateral (e.g. vertical) collection region, typically of a second conductivity type, e.g., n-type dopedlayer 112 is formed immediately adjacent and surrounding the p-type region 118. In operation, photocarriers are generated in aphotoactive collection area 106 of the p-type substrate and are collected in the n-type region 112 surrounding the p-type polysilicon filledtrench 121. The n-type dopedregion 112 surrounding the trench couples in to the transfer gate directly.That is, as shown inFIG. 2 , formed adjacent to thephotodiode element 120 is atransfer gate 125 that operates to transfer photo-generated charge from the charge accumulating n-type dopedregion 112 ofphotodiode element 120 throughchannel 160 to a floatingdiffusion region 140, e.g., doped n+ type as in current photosensor cell designs. - Referring to
FIG. 2 , characteristic of the photosensor (photodiode)element 120 of the invention is that thecharge collection region 112 is isolated from a physical boundary such as, for example, the top substrate surface or sidewalls/bottom of trench surface. For instance, in the first embodiment of the invention, a p-type surface layer 130 a,b is formed that functions as a pinning layer for the sensor cell and isolates thecollection region 112 from surface boundaries. Moreover, the p-type dopant material outdiffused past the trench boundary and forming the p-type boundary layer 118 isolates thecollection region 112 from the trench sidewall and bottom surface boundaries. As shown in the Figure,surface layer 130 b is typically doped lower and shallower than 130 a. -
FIG. 3 illustrates, through a cross-sectional view, the CMOSimage sensor cell 200 including a photosensor element 220 (e.g., photodiode) according to a second embodiment of the invention. - While only a single CMOS
image sensor cell 200 is depicted for exemplary purposes, it is understood that the pixel cell structure depicted is contemplated for inclusion in an array of pixels arranged in rows and columns with rows and columns of pixels addressable by pixel select circuitry not shown. - As shown in
FIG. 3 , the CMOSimage sensor cell 200 includes a firstconventional photodiode 250 and a second trench-type photodiode element 220 formed adjacent thephotodiode 250. As shown inFIG. 3 , the firstconventional photodiode 250 is oriented laterally (horizontally) and abuts the trench-type photodiode element 220 such that a charge collection region of theconventional photodiode 250 connects to the charge collection region of the trench-type photodiode element 220. Both firstlateral photodiode 250 and second trench-type photodiode element 220 are formed on asemiconductor substrate 205 of a first conductivity type, typically p-type silicon, as in the first embodiment and underlie a p-type surface layer 230 a,b for enhanced isolation. As will be described in greater detail, the total capacitance of thesensor cell structure 200 according to the second embodiment of the invention is increased without increasing the area of the photodiode. - The second photosensor device itself, e.g.,
photodiode 220, comprises atrench structure 221 filled with first conductivity type material, e.g., p-type polysilicon 215, and includes a p-type dopant material outdiffused past the trench boundary forming a p-type boundary layer 218 surrounding thetrench 221. A non-lateral (e.g. vertical) collection region, typically of a second conductivity type, e.g., n-type dopedlayer 212 is formed immediately adjacent and surrounding the p-type region 218. - In operation, photocarriers are generated in a
photoactive collection area 206 of the p-type substrate and are collected both in the n-type dopedregion forming photodiode 250 and in the n-type region 212 surrounding the p-type polysilicon filledtrench 221. The n-type dopedregion forming photodiode 250 couples its collected charge and charge collected from the n-type dopedregion 212 surrounding the trench to the transfer gate directly. That is, as shown inFIG. 3 , formed adjacent to thephotodiode element 250 is atransfer gate 225 that operates to transfer photo-generated charge from the charge accumulating n-type dopedphotodiode 250 and the charge accumulating n-type dopedregion 212 ofphotodiode element 220 throughchannel 260 to a floatingdiffusion region 240, e.g., doped n+ type as in current photosensor cell designs. - As in the first embodiment of the invention, characteristic of the photosensor (photodiode)
element 220 of the second embodiment is that thecharge collection regions type surface layer 230 a,b is formed that functions as a pinning layer for the sensor cell and isolates thecollection region FIG. 3 , the depth of p-type layer 230 b formed under the transfer gate is shallower than the remaining portion of the p-type layer 230 b. Moreover, the p-type dopant material outdiffused past the trench boundary and forming the p-type boundary layer 218 isolates thecollection region 212 from the trench sidewall and bottom surface boundaries. According to the second embodiment of the invention, the pinning potential is determined by photodiode parameters. Moreover, thetrench photodiode element 220 is designed to be fully depleted before thelateral photodiode 250. That is, the doping level of the n-typecharge collection region 212 is lower than the doping level of the n-type charge collection region of thelateral photodiode 250. - The method 300 to create the trench-
type photodiode structures FIGS. 4A-4E . Generally, according to the method of the invention, as shown inFIG. 4A , atrench 321 is formed in a substrate of a first conductivity type (e.g., p-type). For purposes of description,substrate 305 is a Si-containing semiconductor substrate of a first conductivity type, e.g., lightly doped with p-type dopant material such as boron or indium (beryllium or magnesium for a III-V semiconductor), to a standard concentration ranging between, e.g., 1 e14 atoms/cm3 to 1 e16 atoms/cm3. Next, using standard processing techniques, thetrench recess 321 is formed in the substrate. That is, utilizing a trench lithography, a photoresist mask (not shown) is applied, patterned and developed to expose an open region for forming a trench etch. Subsequently, an etch process, e.g., reactive ion etching, is performed through the opening in the mask to form thetrench recess 321 that extends down below the substrate surface to a depth of about 0.2 μm to 6 μm. It is understood that the shape of the opened trench may be vertical (box like), or tapered, or “v”-like shaped. In a second step shown inFIG. 4B , thetrench recess 321 is filled with a material 331 doped with material of a second conductivity type, e.g., n-type dopant material. For purposes of explanation, such a glass material may comprise PSG (phosphor silicateglass) for sourcing n-type doped material, and may be deposited within the trench by a well-known CVD process, or alternately a SOG, (spun on glass) process may be used. Subsequent to the deposition of n type doped glass material, an etch-back or chemical-mechanical planarization technique is implemented to remove any excess PSG filler material and planarize the substrate surface. Then, as shown inFIG. 4C , a thermal treatment, e.g., anneal, is conducted as to drive out the n-type dopant from theglass source 331 into the trench walls. Particularly, the n-type impurity from the PSG trench fill 331 is outdiffused to the substrate region surrounding the trench sidewalls and bottom to form the n-typephotocarrier collection region 312 of the resulting photodiode element. The n-typephotocarrier collection region 312 ranges in thickness between 20 nm and 400 nm, and includes n-type carriers of a concentration ranging between 1×1016 atoms/cm3 and 1×1018 atoms/cm3. Subsequently, the PSG trench fill 331 is etched out, e.g., by a selective hydrofluoric acid (HF) etch, or potentially a fluorine based RIE (Reactive Ion Etch) process, or a combination of wet and dry processing, to result in the structure depicted inFIG. 4C . The now openphotosensor device trench 321 is again filled this time with poly-Silicon in-situ doped with first conductivity type material, e.g., p-type polysilicon 315 with any excess poly-Si material 315 being planarized by CMP as shown inFIG. 4D . - With respect to the first embodiment of the invention with just a vertical photodiode as depicted in
FIG. 2 , the processing continues as now described with respect toFIGS. 4E-4H . At this point, the unique vertical photodiode processing is now complete. The process now continues with stand CMOS processing with only a few exceptions. The process includes an isolation step e.g., formingtrenches isolation structures FIG. 4F followed by Nwell, Pwell implants and other well implants. Additionally formed are the p-type dopedmaterial layer layer 330 b inFIG. 4F ). Preferably, the dopant concentration for the Vt tailor implant for the transfer gate is typically greater than e16 cm3). This is followed by the gate processing, the extension, and source/drain implants 340 as shown inFIG. 4H . At this point, typically in CMOS imager processing, the pinning layer implants are also performed. - Referring now to
FIG. 4G , there is depicted in greater detail the resulting structure after surface processing and lithography steps for applying a surface oxide layer 348 (typically an oxide such as SiO2 or like dielectric oxide, nitride or oxynitride) that will be suitably be patterned and etched to form the transfer gate dielectric, and a gate conducting layer orgate stack 325, e.g., of polysilicon material. As known, the transfer gate may comprise a doped layer or a conductive layer, e.g., doped polysilicon, tungsten or other suitable material over the insulatinggate dielectric layer 72, e.g., silicon dioxide or silicon nitride, and may include insulatingsidewall spacers 23 a,b as shown inFIG. 1 . - Referring now to
FIG. 4H , there is depicted in greater detail an additional step of implanting p-type dopant material to the surface of the structure to form the p-typesurface implant layer 330 a′, i.e., to keep electrons away from surface generation/recombination sites. This step is typically performed at (shortly before or after) the source/drain implant steps. This step entails implanting dopant material onto the substrate surface at openings formed in a prior photolithography step (not shown) corresponding to surface location indicated at 330 a′. Preferably, p-type dopant material is implanted at suitable energies and concentrations to ensure electrical conductivity to the underlying lightly-doped substrate. The thickness of p-type surface layer 330 a ranges between 10 nm and 200 nm and preferably has a concentration greater than 1×1018 atoms/cm3 to ensure that the collection region is isolated from the surface and subsequently formed transfer gate device. - With respect to the second embodiment of the invention (depicted in
FIG. 3 ) having both the lateral and vertical photodiodes, the resultant structure photosensor cell structure formed after applying similar processing steps such as described herein with respect toFIGS. 4E-4G is shown inFIGS. 5A and 5B .FIGS. 5A-5D particularly depict the method steps performed after the vertical photodiode processing (having polysilicon conductor 415) is complete. These steps include standard CMOS imager processing steps starting at the isolation level followed by the N photodiode implant, Nwell, Pwell, and other well implants, the gate processing, the extensions, source/drain implants, and the pinning layer implants etc . . . as is done in a industry standard CMOS imager process flow. For example, as shown inFIG. 5A , there is depicted a resultant structure after forming the trench (e.g., STI)isolation structures material layer layer 430 b inFIG. 5A ). Then, as shown inFIG. 5B , there is depicted the resulting structure after performing further surface processing and lithography steps for applying a surface oxide layer 448 (typically an oxide such as SiO2 or like dielectric oxide, nitride or oxynitride) that will be suitably be patterned and etched to form the transfer gate dielectric, and a gate conducting layer orgate stack 425 of a doped layer or a conductive layer, e.g., doped polysilicon, tungsten or other suitable material over the insulating gate dielectric layer. The lateral photodiode and transfer gate processes would now proceed as in a standard CMOS imager process flow. Thus, as shown inFIG. 5C , theN photodiode implant 450 is depicted, as is depicted the extension, and source/drain implants 440 inFIG. 5D . At this point, typically in CMOS imager processing, the pinning layer implants are also performed - It should be understood that in both first and second embodiments, the photodiode device is exposed to a suitable amount of temperature as a result of the thermal budgets employed during the subsequent CMOS imager processing flow at durations suitable to enable a second outdiffusion of the in-situ doped first conductivity type material, e.g., p-
type polysilicon 315, to form an outdiffused p-type layer 118 (FIG. 2 ) and outdiffused p-type layer 218 (FIG. 3 ) of therespective photodiodes regions FIGS. 2 and 3 , the respective doped surface layers 130 a, 130 b and 230 a, 230 b of the first conductivity type formed on a surface of the substrate are coupled to the outdiffused p-type layers respective photodiodes - It is understood that the additional step of forming the second out-diffused
layers respective photodiodes layers photocarrier collection regions - The benefits of the CMOS photosensor cell of the invention include: 1) increased cell capacity; 2) the ability to be fully depleted; 3) a pinned structure (no oxide interfaces with n-type dopant abutting); 4) reduced crosstalk (That is, the deep trench structure creates a lateral field deep in the silicon which preferentially collects charge generated close to this cell (and adjacent cells will collect their charge preferentially as well)); 5) no increase in cell area needed to get higher capacity (which would occur if capacity was designed to be increased by making the photodiode larger); 6) small increase in dark current (That is, dark current increase would be very large if capacity was designed to be increased by increasing dopant concentrations; and, 7) no change in pinning potential (which would occur if capacity was designed to be increased by increasing dopant concentration).
- As mentioned, the total capacitance of the structure is increased without increasing the area of the photodiode. The pinning potential is still determined by the current photodiode parameters. In connection with the second embodiment of the invention, as depicted in
FIG. 2 , thetrench photodiode 220 is of such n-type dopant concentrations and is suitably biased in operation to ensure that it becomes fully depleted before thelateral photodiode 250 becomes depleted, i.e., all electrons are driven out of the transfer gate of thedeep trench photodiode 220. As is appreciated by skilled artisans, the n-type dopedregion 212 is fully depleted at a pinning voltage which is supplied by the floating diffusion through the transfer gate in order to cut down on dark current. The pinned photodiode is termed “pinned” because the potential in the photodiode is pinned to a constant value, Vp, when the photodiode is fully depleted. - While there has been shown and described what is considered to be preferred embodiments of the invention, it will, of course, be understood that various modifications and changes in form or detail could readily be made without departing from the spirit of the invention. It is therefore intended that the invention be not limited to the exact forms described and illustrated, but should be constructed to cover all modifications that may fall within the scope of the appended claims.
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Also Published As
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US20120122261A1 (en) | 2012-05-17 |
JP2007221121A (en) | 2007-08-30 |
US7659564B2 (en) | 2010-02-09 |
JP5254553B2 (en) | 2013-08-07 |
US20100084690A1 (en) | 2010-04-08 |
CN101022118B (en) | 2010-09-15 |
CN101022118A (en) | 2007-08-22 |
US8106432B2 (en) | 2012-01-31 |
US8440490B2 (en) | 2013-05-14 |
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