+

US20070163238A1 - Method for metering a reagent into the exhaust gas flow of an internal combustion engine - Google Patents

Method for metering a reagent into the exhaust gas flow of an internal combustion engine Download PDF

Info

Publication number
US20070163238A1
US20070163238A1 US10/552,864 US55286404A US2007163238A1 US 20070163238 A1 US20070163238 A1 US 20070163238A1 US 55286404 A US55286404 A US 55286404A US 2007163238 A1 US2007163238 A1 US 2007163238A1
Authority
US
United States
Prior art keywords
reagent
temperature
component
threshold value
signal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/552,864
Inventor
Michael Gerlach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Assigned to ROBERT BOSCH GMBH reassignment ROBERT BOSCH GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GERLACH, MICHAEL
Publication of US20070163238A1 publication Critical patent/US20070163238A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9431Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9495Controlling the catalytic process
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • German Patent Application No. DE 101 39 142 a measuring device is described for ascertaining a concentration of a urea-water solution, which is applied as a reagent for an NOx adsorption catalyst in the exhaust gas flow of an internal combustion engine. From the urea-water solution ammonia is obtained which, in a regeneration phase of the NOx adsorption catalyst, brings about a reduction of nitrogen oxides. An ascertainment of the concentration of the urea-water solution is provided, whereby a precise metering of the reducing agent into the exhaust gas flow may be implemented. An indirect measuring method for ascertaining the concentration is provided, in which the vapor pressure of the urea-water solution, that is stored in a storage vessel, is measured, using a pressure sensor.
  • the vapor pressure is created by the ammonia generated because of the hydrolysis of the urea plus the vapor pressure of the solvent water, so that because of the layout, an evaluation unit is able to ascertain the correspondingly reduced urea quantity or the urea concentration in the urea-water solution.
  • a temperature sensor for registering the temperature of the urea-water solution. Using the signal of the temperature sensor, the dependence of the pressure on the temperature may be taken into consideration.
  • the urea-water solution has a freezing point which is approximately ⁇ 11 degrees C. To the extent that the previously known metering device is exposed to environmental conditions, the freezing of the urea-water solution cannot be excluded. The sudden change in density in connection with the freezing mechanically stresses the components that are filled with the urea-water solution.
  • An object of the present invention is to provide a method for metering a reagent into the exhaust gas flow of an internal combustion engine, which increases reliability.
  • the method according to the present invention for metering a reagent into the exhaust gas flow of an internal combustion engine, in which the reagent is guided in at least one component and in which a measure of the temperature of the component is recorded, provides that the measure for the temperature is compared to a predefined temperature threshold value, that the number of the threshold exceedings are counted in a counter, that the count threshold value for the number of threshold exceedings is specified, and that a service signal is made available when the count threshold value is exceeded.
  • the method according to the present invention makes it possible to detect a one-time, or, preferably a multiple exceeding of the temperature threshold value, and thereupon to make available the service signal.
  • the measure for the temperature of the component similarly reflects the temperature of the reagent.
  • the temperature threshold value is, for example, established at a value at which one property of the reagent changes.
  • the service signal then indicates that the property of the reagent has changed once or several times.
  • the service signal may be used as notice that, for example, the component in which the reagent is carried, or the reagent itself should be exchanged.
  • the method according to the present invention thereby increases the reliability of metering the reagent into the exhaust gas flow of the internal combustion engine.
  • the temperature threshold value is equivalent to the freezing temperature of the reagent. Using this embodiment, freezing of the reagent or, for instance, a possible icing up of the component is detected by the reagent possibly contained therein.
  • One embodiment provides that, after the shutting down of the internal combustion engine, it is ascertained during coasting whether the component is filled with the reagent. Using this measure, the additional decisions may be made dependent on whether there is still reagent in the component after the shutting down of the internal combustion engine.
  • the counter is designed as an ice counter.
  • the ice counter counts an exceeding of the temperature threshold value only when the component is filled with the frozen reagent. Thereby it may be reliably detected how often the component filled with the reagent has frozen, and whether the number of freezing episodes has exceeded the counter threshold value.
  • the service signal may be seen as a notice, to test the component, and, if necessary, to exchange it.
  • One embodiment provides that, during the ascertainment as to whether the component is filled with the reagent, an air pressure signal is analyzed.
  • an air pressure signal is analyzed.
  • purging (blowing out) the reagent by compressed air may be provided. Thereby it may be ensured that, for instance, after the shutting down of the internal combustion engine, there is no longer any reagent in the component.
  • Another embodiment provides that, during the ascertainment as to whether the component is filled with the reagent, the operation of an emergency stop switch is taken into consideration.
  • the operation of an emergency stop switch will prevent coasting, so that one may assume that the component is filled with the reagent.
  • One embodiment provides that an exceeding of the temperature threshold value is counted only at the starting of the internal combustion engine. Using this measure, the point in time of counting the individual exceedings of the temperature threshold value is established exactly. To the extent that in the exceeding of the temperature threshold value an exceeding towards lower temperatures is involved, one may assume that the coldest temperature is present at the starting procedure.
  • the measure for the temperature of the component is obtained from the signal of at least one temperature sensor.
  • the temperature sensor may, for instance, record the temperature of the component or the air temperature.
  • the FIGURE shows a technical environment in which a method according to the present invention proceeds.
  • the Figure shows an internal combustion engine 10 , that has a catalytic converter 11 post-connected to it for exhaust gas purification.
  • a metering valve 14 is provided for adding a reagent 13 into exhaust gas flow 12 of internal combustion engine 10 .
  • Reagent 13 is made available by a reagent pump 15 , which obtains reagent 13 from a reagent storage tank 16 .
  • Both reagent pump 15 and metering valve 14 may be purged using compressed air that is supplied by a compressor 17 .
  • First comparator 28 compares temperature signal 27 to a temperature threshold value 29 , and, as a function of the comparison result, emits a temperature warning signal 30 both to a first AND operation 31 and to a second AND operation 32 .
  • the two AND operations 31 , 32 also receive clamp- 15 (terminal- 15 ) signal 34 supplied by key switch 33 .
  • Second AND operation 32 also receives a purging error signal 36 stored by a memory 35 .
  • a vehicle electrical system 37 is connected both to key switch 33 and a coasting control 39 via an emergency stop switch 38 .
  • Coasting control 39 is also connected to clamp- 15 signal 34 .
  • Coasting control 39 emits a coasting signal 40 both to compressor 17 and to a purging detector 41 .
  • Purging detector 41 which emits purging error signal 36 to memory 35 , also receives a compressed air signal 43 made available by compressed air sensor 42 that is assigned to compressor 17 .
  • First AND operation 31 emits a freezing count signal 44 to a freezing counter 45 , to which is also supplied a diagnosis signal 48 made available by a diagnosis unit 46 via a diagnosis interface 47 , and which makes available a freezing counter signal 49 .
  • Second AND operation 32 emits an ice count signal 50 to an ice counter 51 , which passes on an ice counter signal 52 to a second comparator 53 .
  • Second comparator 53 compares ice counter signal 52 to a count threshold value 54 and emits a service signal 55 to a service signal memory 56 , as a function of the comparison.
  • Diagnosis signal 48 is supplied both to service signal memory 56 and to ice counter 51 .
  • Service signal memory 56 emits a switching signal 57 to a service indicator 58 .
  • the method according to the present invention functions as follows:
  • Catalytic converter 11 situated in the exhaust gas flow 12 of internal combustion engine 10 cleans the at least one component of the exhaust gases of internal combustion engine 10 .
  • Catalytic converter 11 is preferably developed as an SCR (selective catalytic reduction) catalytic converter, which, in cooperation with reagent 13 renders harmless to a great extent at least one exhaust gas component, preferably NOx.
  • Reagent 13 is, for instance, a urea-water solution, which metering valve 14 introduces into exhaust gas flow 12 .
  • ammonia is obtained from the urea-water solution, which is used as a reducing agent in the SCR catalytic converter.
  • Reagent 13 is accommodated in reagent tank 16 , from which it is conveyed to metering valve 14 by reagent pump 15 .
  • Metering valve 14 may be designed with or without air support. In the case of an air-supported metering valve 14 , the required compressed air is made available by compressor 17 . The compressed air then preferably reaches metering valve 14 directly.
  • purging reagent 13 is provided from metering valve 14 , from reagent pump 15 and from further components not shown in greater detail.
  • the components such as, for instance, metering valve 14 and/or reagent pump 15 are protected after the shutting down of internal combustion engine 10 . If there were longer action, it is possible that corrosion or embrittlement might occur. However, in particular, using this measure, freezing may be prevented of components 14 , 15 when filled with reagent 13 .
  • Temperature sensor 24 preferably records the air temperature. Temperature sensor 24 may be situated, for example, in an intake region of internal combustion engine 10 that is not shown in greater detail, or in an air conditioner that is also not shown, provided internal combustion engine 10 is situated in a motor vehicle.
  • the at least one temperature sensor 18 , 20 , 22 , 24 preferably records a measure for the temperature of the most sensitive component 14 , 15 .
  • the measure for the temperature of component 14 , 15 is similarly a measure for the temperature of reagent 13 .
  • Temperature signals 19 , 21 , 23 , 25 made available by temperature sensors 18 , 20 , 22 , 24 are supplied to temperature selection 26 , which passes on one of temperature signals 19 , 21 , 23 , 25 as temperature signal 27 to first comparator 28 .
  • the first comparator emits temperature warning signal 30 via temperature signal 27 , in response to each exceeding or undershooting of temperature threshold value 29 .
  • Temperature selection 26 may pass on, for example, the highest or the lowest temperature as temperature signal 27 . If necessary, a particular selection may be fixed.
  • each undershooting or exceeding of temperature threshold value 29 by temperature signal 27 may be counted, and, upon the exceeding of count threshold value 54 , service signal 55 may be issued.
  • Temperature signals 19 , 21 , 23 , 25 especially make possible the detection of freezing of at least one component 14 , 15 , that is filled with reagent 13 .
  • the freezing point of a urea-water solution that may be provided as reagent 13 is at least approximately around ⁇ 11 degrees C. This temperature may easily be reached or undershot in wintertime. We next look only at such an undershooting of the freezing point of reagent 13 .
  • Freezing counter 45 counts each appearance of freezing count signal 44 , which appears in response to each appearance of temperature warning signal 30 , provided the AND condition in first AND operation 31 is satisfied.
  • the AND condition designates that, simultaneously with the appearance of temperature warning signal 30 , clamp- 15 signal 34 has to be present, which key switch 33 makes available.
  • the clamp- 15 signal means that an operating person has operated key switch 33 for starting internal combustion engine 10 , and that key switch 33 is connected to vehicle electrical supply 37 for the energy supply of the entire installation, via emergency stop switch 38 . Using this measure, it is achieved that freezing count signal 44 is able to appear at first AND operation 31 only after the starting of internal combustion engine 10 .
  • Freezing counter 45 counts the appearance of freezing count signal 44 and emits freezing counter signal 49 . Freezing counter signal 49 may, for instance, be compared to a predefined boundary value, a specified measure being able to be taken if the boundary value is exceeded.
  • freezing counter signal 49 may remain stored in freezing counter 45 , and be read out for diagnosis purposes by a diagnosis unit 46 that may, perhaps, be connected via diagnosis interface 47 . Furthermore, freezing counter 45 may be canceled using diagnosis signal 48 .
  • temperature warning signal 30 is counted only if component 14 , 15 is filled with reagent 13 , so that, upon the appearance of temperature warning signal 30 , one may assume icing up of component 14 , 15 . Because of the sudden change in density of reagent 13 , that appears in response to icing up, component 14 , 15 may be damaged.
  • count threshold value 54 may be set to the number one. That means that each individual exceeding of count threshold value 54 leads to the appearance of service signal 45 .
  • count threshold value 54 it was determined that, in practice, more than one icing up, for example, 50 icing up occurrences may be gotten through before a breakdown must be expected.
  • Metering valve 14 has proven to be especially at risk. Similarly, it has been shown that it is sufficient to draw upon reagent pump temperature signal 21 , supplied by reagent pump temperature sensor 20 , as a measure for the temperature of metering valve 14 or reagent 13 in metering valve 14 .
  • compressed air signal 43 is evaluated for this.
  • coasting control 39 still activates compressor 17 , using coasting signal 40 , for a specified time, in which component 14 , 15 is flushed by the compressed air and reagent 13 is purged.
  • emergency stop switch 38 completely separates, from vehicle electrical supply 37 , not only key switch 33 but also coasting control 39 , so that purging of components 14 , 15 using compressed air cannot take place. This state may be determined in purge detector 40 with the aid of coasting signal 40 and clamp- 15 signal 34 . If no coasting signal 40 appears when clamp- 15 signal 34 is present, purge error signal 36 is emitted to memory 35 .
  • second AND operation 32 In response to the satisfied AND condition, second AND operation 32 emits ice count signal 50 to ice counter 51 . Ice counter signal 52 supplied by ice counter 51 is compared by second comparator 53 to count threshold value 54 . When count threshold value 54 is exceeded, service signal 55 is made available and stored in service signal memory 56 . At the same time, service indicator 58 is able to be activated by switching signal 57 .
  • Stored service signal 55 may be read out during a diagnosis by diagnosis unit 46 using diagnosis signal 48 .
  • stored service signal 55 as well as ice counter 51 may be canceled using diagnosis signal 48 , and service indicator 58 may be reset.
  • the appearance of service signal 55 gives notice that component 14 , 15 should be tested based on the exceeding of the specified number of freezing occurrences and exchanged if necessary.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Combined Controls Of Internal Combustion Engines (AREA)

Abstract

A method for metering a reagent into the exhaust gas flow of an internal combustion engine is provided, in which the reagent is guided in at least one component and in which a measure for the temperature of the component is recorded. The measure for the temperature is compared to a predefined temperature threshold value. A counter counts the number of times the threshold is exceeded. If the counter state exceeds a predefined count threshold value, a service signal is emitted. The temperature threshold value is fixed, for example, at the freezing temperature of the reagent. One embodiment provides that the counter counts an exceeding of the temperature threshold value only when the component is filled with the reagent.

Description

    BACKGROUND INFORMATION
  • In German Patent Application No. DE 101 39 142, a measuring device is described for ascertaining a concentration of a urea-water solution, which is applied as a reagent for an NOx adsorption catalyst in the exhaust gas flow of an internal combustion engine. From the urea-water solution ammonia is obtained which, in a regeneration phase of the NOx adsorption catalyst, brings about a reduction of nitrogen oxides. An ascertainment of the concentration of the urea-water solution is provided, whereby a precise metering of the reducing agent into the exhaust gas flow may be implemented. An indirect measuring method for ascertaining the concentration is provided, in which the vapor pressure of the urea-water solution, that is stored in a storage vessel, is measured, using a pressure sensor. The vapor pressure is created by the ammonia generated because of the hydrolysis of the urea plus the vapor pressure of the solvent water, so that because of the layout, an evaluation unit is able to ascertain the correspondingly reduced urea quantity or the urea concentration in the urea-water solution.
  • Also provided is a temperature sensor for registering the temperature of the urea-water solution. Using the signal of the temperature sensor, the dependence of the pressure on the temperature may be taken into consideration. The urea-water solution has a freezing point which is approximately −11 degrees C. To the extent that the previously known metering device is exposed to environmental conditions, the freezing of the urea-water solution cannot be excluded. The sudden change in density in connection with the freezing mechanically stresses the components that are filled with the urea-water solution.
  • An object of the present invention is to provide a method for metering a reagent into the exhaust gas flow of an internal combustion engine, which increases reliability.
  • SUMMARY OF THE INVENTION
  • The method according to the present invention, for metering a reagent into the exhaust gas flow of an internal combustion engine, in which the reagent is guided in at least one component and in which a measure of the temperature of the component is recorded, provides that the measure for the temperature is compared to a predefined temperature threshold value, that the number of the threshold exceedings are counted in a counter, that the count threshold value for the number of threshold exceedings is specified, and that a service signal is made available when the count threshold value is exceeded.
  • The method according to the present invention makes it possible to detect a one-time, or, preferably a multiple exceeding of the temperature threshold value, and thereupon to make available the service signal. The measure for the temperature of the component similarly reflects the temperature of the reagent. The temperature threshold value is, for example, established at a value at which one property of the reagent changes. The service signal then indicates that the property of the reagent has changed once or several times. The service signal may be used as notice that, for example, the component in which the reagent is carried, or the reagent itself should be exchanged. The method according to the present invention thereby increases the reliability of metering the reagent into the exhaust gas flow of the internal combustion engine.
  • One embodiment provides that the temperature threshold value is equivalent to the freezing temperature of the reagent. Using this embodiment, freezing of the reagent or, for instance, a possible icing up of the component is detected by the reagent possibly contained therein.
  • One embodiment provides that, after the shutting down of the internal combustion engine, it is ascertained during coasting whether the component is filled with the reagent. Using this measure, the additional decisions may be made dependent on whether there is still reagent in the component after the shutting down of the internal combustion engine.
  • This embodiment forms the basis for the further embodiment of the present invention, according to which the counter is designed as an ice counter. The ice counter counts an exceeding of the temperature threshold value only when the component is filled with the frozen reagent. Thereby it may be reliably detected how often the component filled with the reagent has frozen, and whether the number of freezing episodes has exceeded the counter threshold value. The service signal may be seen as a notice, to test the component, and, if necessary, to exchange it.
  • One embodiment provides that, during the ascertainment as to whether the component is filled with the reagent, an air pressure signal is analyzed. As a function of a definite embodiment of the metering of the reagent, purging (blowing out) the reagent by compressed air may be provided. Thereby it may be ensured that, for instance, after the shutting down of the internal combustion engine, there is no longer any reagent in the component.
  • Another embodiment provides that, during the ascertainment as to whether the component is filled with the reagent, the operation of an emergency stop switch is taken into consideration. In general, the operation of an emergency stop switch will prevent coasting, so that one may assume that the component is filled with the reagent.
  • One embodiment provides that an exceeding of the temperature threshold value is counted only at the starting of the internal combustion engine. Using this measure, the point in time of counting the individual exceedings of the temperature threshold value is established exactly. To the extent that in the exceeding of the temperature threshold value an exceeding towards lower temperatures is involved, one may assume that the coldest temperature is present at the starting procedure.
  • One embodiment provides that the measure for the temperature of the component is obtained from the signal of at least one temperature sensor. The temperature sensor may, for instance, record the temperature of the component or the air temperature.
  • BRIEF DESCRIPTION OF THE DRAWING
  • The FIGURE shows a technical environment in which a method according to the present invention proceeds.
  • DETAILED DESCRIPTION
  • The Figure shows an internal combustion engine 10, that has a catalytic converter 11 post-connected to it for exhaust gas purification. A metering valve 14 is provided for adding a reagent 13 into exhaust gas flow 12 of internal combustion engine 10. Reagent 13 is made available by a reagent pump 15, which obtains reagent 13 from a reagent storage tank 16. Both reagent pump 15 and metering valve 14 may be purged using compressed air that is supplied by a compressor 17.
  • Metering valve temperature signal 19 made available by a metering valve temperature sensor 18 that is assigned to metering valve 14, reagent pump temperature signal 21 made available by a reagent pump temperature sensor 20 that is assigned to reagent pump 15, reagent tank temperature signal 23 made available by a reagent tank temperature sensor 22 that is assigned to reagent tank 16, as well as temperature sensor signal 25 made available by a temperature sensor 24 are supplied to a temperature selection 26, which emits a temperature signal 27 to a first comparator 28.
  • First comparator 28 compares temperature signal 27 to a temperature threshold value 29, and, as a function of the comparison result, emits a temperature warning signal 30 both to a first AND operation 31 and to a second AND operation 32. The two AND operations 31, 32 also receive clamp-15 (terminal-15) signal 34 supplied by key switch 33. Second AND operation 32 also receives a purging error signal 36 stored by a memory 35.
  • A vehicle electrical system 37 is connected both to key switch 33 and a coasting control 39 via an emergency stop switch 38. Coasting control 39 is also connected to clamp-15 signal 34. Coasting control 39 emits a coasting signal 40 both to compressor 17 and to a purging detector 41. Purging detector 41, which emits purging error signal 36 to memory 35, also receives a compressed air signal 43 made available by compressed air sensor 42 that is assigned to compressor 17.
  • First AND operation 31 emits a freezing count signal 44 to a freezing counter 45, to which is also supplied a diagnosis signal 48 made available by a diagnosis unit 46 via a diagnosis interface 47, and which makes available a freezing counter signal 49.
  • Second AND operation 32 emits an ice count signal 50 to an ice counter 51, which passes on an ice counter signal 52 to a second comparator 53. Second comparator 53 compares ice counter signal 52 to a count threshold value 54 and emits a service signal 55 to a service signal memory 56, as a function of the comparison. Diagnosis signal 48 is supplied both to service signal memory 56 and to ice counter 51. Service signal memory 56 emits a switching signal 57 to a service indicator 58.
  • The method according to the present invention functions as follows:
  • Catalytic converter 11 situated in the exhaust gas flow 12 of internal combustion engine 10 cleans the at least one component of the exhaust gases of internal combustion engine 10. Catalytic converter 11 is preferably developed as an SCR (selective catalytic reduction) catalytic converter, which, in cooperation with reagent 13 renders harmless to a great extent at least one exhaust gas component, preferably NOx. Reagent 13 is, for instance, a urea-water solution, which metering valve 14 introduces into exhaust gas flow 12. In exhaust gas flow 12, or at a component not shown, ammonia is obtained from the urea-water solution, which is used as a reducing agent in the SCR catalytic converter.
  • Reagent 13 is accommodated in reagent tank 16, from which it is conveyed to metering valve 14 by reagent pump 15. Metering valve 14 may be designed with or without air support. In the case of an air-supported metering valve 14, the required compressed air is made available by compressor 17. The compressed air then preferably reaches metering valve 14 directly.
  • According to one advantageous embodiment, after the shutting down of internal combustion engine 10, purging reagent 13 is provided from metering valve 14, from reagent pump 15 and from further components not shown in greater detail. Using this measure, one may achieve that the components, such as, for instance, metering valve 14 and/or reagent pump 15 are protected after the shutting down of internal combustion engine 10. If there were longer action, it is possible that corrosion or embrittlement might occur. However, in particular, using this measure, freezing may be prevented of components 14, 15 when filled with reagent 13.
  • In order to record the temperature of components 14, 15, preferably at least one temperature sensor is provided. In the exemplary embodiment shown, metering valve temperature sensor 18 assigned to metering valve 14, reagent pump temperature sensor 20 assigned to reagent pump 15, reagent tank temperature sensor 22 assigned to reagent tank 16 as well as temperature sensor 24 are provided. Temperature sensor 24 preferably records the air temperature. Temperature sensor 24 may be situated, for example, in an intake region of internal combustion engine 10 that is not shown in greater detail, or in an air conditioner that is also not shown, provided internal combustion engine 10 is situated in a motor vehicle.
  • The at least one temperature sensor 18, 20, 22, 24 preferably records a measure for the temperature of the most sensitive component 14, 15. The measure for the temperature of component 14, 15 is similarly a measure for the temperature of reagent 13. Temperature signals 19, 21, 23, 25 made available by temperature sensors 18, 20, 22, 24 are supplied to temperature selection 26, which passes on one of temperature signals 19, 21, 23, 25 as temperature signal 27 to first comparator 28. The first comparator emits temperature warning signal 30 via temperature signal 27, in response to each exceeding or undershooting of temperature threshold value 29. Temperature selection 26 may pass on, for example, the highest or the lowest temperature as temperature signal 27. If necessary, a particular selection may be fixed.
  • Using the measure provided according to the present invention, each undershooting or exceeding of temperature threshold value 29 by temperature signal 27 may be counted, and, upon the exceeding of count threshold value 54, service signal 55 may be issued. Temperature signals 19, 21, 23, 25 especially make possible the detection of freezing of at least one component 14, 15, that is filled with reagent 13. The freezing point of a urea-water solution that may be provided as reagent 13 is at least approximately around −11 degrees C. This temperature may easily be reached or undershot in wintertime. We next look only at such an undershooting of the freezing point of reagent 13.
  • Freezing counter 45 counts each appearance of freezing count signal 44, which appears in response to each appearance of temperature warning signal 30, provided the AND condition in first AND operation 31 is satisfied. The AND condition designates that, simultaneously with the appearance of temperature warning signal 30, clamp-15 signal 34 has to be present, which key switch 33 makes available. The clamp-15 signal means that an operating person has operated key switch 33 for starting internal combustion engine 10, and that key switch 33 is connected to vehicle electrical supply 37 for the energy supply of the entire installation, via emergency stop switch 38. Using this measure, it is achieved that freezing count signal 44 is able to appear at first AND operation 31 only after the starting of internal combustion engine 10. Freezing counter 45 counts the appearance of freezing count signal 44 and emits freezing counter signal 49. Freezing counter signal 49 may, for instance, be compared to a predefined boundary value, a specified measure being able to be taken if the boundary value is exceeded.
  • For example, freezing counter signal 49 may remain stored in freezing counter 45, and be read out for diagnosis purposes by a diagnosis unit 46 that may, perhaps, be connected via diagnosis interface 47. Furthermore, freezing counter 45 may be canceled using diagnosis signal 48.
  • Of special advantage is the measure that temperature warning signal 30 is counted only if component 14, 15 is filled with reagent 13, so that, upon the appearance of temperature warning signal 30, one may assume icing up of component 14, 15. Because of the sudden change in density of reagent 13, that appears in response to icing up, component 14, 15 may be damaged.
  • Inasmuch as even a one-time freezing up of components 14, 15 is critical, count threshold value 54 may be set to the number one. That means that each individual exceeding of count threshold value 54 leads to the appearance of service signal 45. In test series it was determined that, in practice, more than one icing up, for example, 50 icing up occurrences may be gotten through before a breakdown must be expected. Metering valve 14 has proven to be especially at risk. Similarly, it has been shown that it is sufficient to draw upon reagent pump temperature signal 21, supplied by reagent pump temperature sensor 20, as a measure for the temperature of metering valve 14 or reagent 13 in metering valve 14.
  • Since it may be assumed that, during the operation of internal combustion engine 10, freezing of reagent 13 does not occur by heating at least one of component 14, 15 or reagent 13 directly, one may assume that freezing of component 14, 15 occurs only in the shut-down state of internal combustion engine 10.
  • It is therefore advantageously determined whether component 14, 15 is filled with reagent 13 in the shut down state of internal combustion engine 10. According to a first exemplary embodiment, compressed air signal 43 is evaluated for this. After the operation of key switch 33 for shutting down internal combustion engine 10, coasting control 39 still activates compressor 17, using coasting signal 40, for a specified time, in which component 14, 15 is flushed by the compressed air and reagent 13 is purged.
  • First of all, the case may occur that, during coasting time, the air pressure is not sufficient, or no compressed air at all is available. This state is recorded by compressed air sensor 42, which may be assigned, for example, to compressor 17. Purge detector 40 determines, with the aid of compressed air signal 43, that an error has occurred, and emits purge error signal 36 to memory 35. Memory 35 has the task of storing purge error signal 36 until the next operation of key switch 33.
  • According to another exemplary embodiment, the operation of emergency stop switch 38 is taken into consideration. Emergency stop switch 38 completely separates, from vehicle electrical supply 37, not only key switch 33 but also coasting control 39, so that purging of components 14, 15 using compressed air cannot take place. This state may be determined in purge detector 40 with the aid of coasting signal 40 and clamp-15 signal 34. If no coasting signal 40 appears when clamp-15 signal 34 is present, purge error signal 36 is emitted to memory 35.
  • In response to the satisfied AND condition, second AND operation 32 emits ice count signal 50 to ice counter 51. Ice counter signal 52 supplied by ice counter 51 is compared by second comparator 53 to count threshold value 54. When count threshold value 54 is exceeded, service signal 55 is made available and stored in service signal memory 56. At the same time, service indicator 58 is able to be activated by switching signal 57.
  • Stored service signal 55 may be read out during a diagnosis by diagnosis unit 46 using diagnosis signal 48. At the same time, stored service signal 55 as well as ice counter 51 may be canceled using diagnosis signal 48, and service indicator 58 may be reset. In this connection, the appearance of service signal 55 gives notice that component 14, 15 should be tested based on the exceeding of the specified number of freezing occurrences and exchanged if necessary.

Claims (11)

1-10. (canceled)
11. A method for metering a reagent into an exhaust gas flow of an internal combustion engine, the method comprising:
guiding the reagent in at least one component;
recording a measure for a temperature of the component;
comparing the measure for the temperature to a predefined temperature threshold value;
counting a number of times the temperature threshold value is exceeded in a counter;
predefining a count threshold value for the number of times the temperature threshold value is exceeded; and
making available a service signal in response to an exceeding of the count threshold value.
12. The method according to claim 11, wherein the temperature threshold value is equivalent to a freezing temperature of the reagent.
13. The method according to claim 12, further comprising, after shutting down the internal combustion engine, during coasting, ascertaining whether the component is filled with the reagent.
14. The method according to claim 13, wherein the counter is an ice counter, and the ice counter counts an exceeding of the temperature threshold value only when the component is filled with the frozen reagent.
15. The method according to claim 13, wherein, during the ascertaining of whether the component is filled with the reagent, a compressed air signal is evaluated.
16. The method according to claim 13, wherein, during the ascertaining of whether the component is filled with the reagent, an operation of an emergency stop switch is taken into consideration.
17. The method according to claim 11, further comprising counting an exceeding of the temperature threshold value only at a start of the internal combustion engine.
18. The method according to claim 11, further comprising obtaining the measure for the temperature of the component from a signal of at least one temperature sensor.
19. The method according to claim 18, wherein the temperature sensor records the temperature of the component.
20. The method according to claim 18, wherein the temperature sensor records an air temperature.
US10/552,864 2003-04-09 2004-03-11 Method for metering a reagent into the exhaust gas flow of an internal combustion engine Abandoned US20070163238A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10316184A DE10316184A1 (en) 2003-04-09 2003-04-09 Method for metering a reagent into the exhaust gas stream of an internal combustion engine
DE10316184.8 2003-04-09
PCT/EP2004/050287 WO2004089516A1 (en) 2003-04-09 2004-03-11 Method for dosing a reagent in the waste gas flow of an internal combustion engine

Publications (1)

Publication Number Publication Date
US20070163238A1 true US20070163238A1 (en) 2007-07-19

Family

ID=33038954

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/552,864 Abandoned US20070163238A1 (en) 2003-04-09 2004-03-11 Method for metering a reagent into the exhaust gas flow of an internal combustion engine

Country Status (5)

Country Link
US (1) US20070163238A1 (en)
EP (1) EP1615714B1 (en)
JP (1) JP4287436B2 (en)
DE (2) DE10316184A1 (en)
WO (1) WO2004089516A1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060051276A1 (en) * 2002-11-06 2006-03-09 Johannes Schaller Device for treatment of exhaust of an internal combustion engine
US20080034733A1 (en) * 2006-08-14 2008-02-14 Miller Robert L Fuel supply component purging system
US20100122521A1 (en) * 2008-11-19 2010-05-20 Caterpillar Inc. Method for purging a dosing system
US20100236220A1 (en) * 2004-12-24 2010-09-23 Nissan Diesel Motor Co., Ltd. Exhaust emission purifying apparatus for engine
US20110146247A1 (en) * 2009-12-23 2011-06-23 Caterpillar Inc. Method for introducing a reductant into an exhaust stream
US20140174548A1 (en) * 2011-05-23 2014-06-26 Inergy Automotive Systems Research (Societe Anonyme) Additive delivery system and method for controlling said system
WO2022023852A1 (en) * 2020-07-29 2022-02-03 Robert Bosch Gmbh A device and a method for measuring concentration of a reductant solution in a selective catalytic reduction (scr) system of a vehicle

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004001331A1 (en) 2004-01-08 2005-07-28 Robert Bosch Gmbh Introducing ammonia into engine exhaust system containing selective catalytic reduction catalyst reduce nitrogen oxide emissions comprises introducing ammonia after switching off the engine
AT500849B8 (en) * 2004-11-15 2007-02-15 Pankl Emission Control Systems urea dosing
AT501091B1 (en) * 2004-11-15 2006-12-15 Pankl Emission Control Systems EMISSION CONTROL DEVICE
DE102004061259B4 (en) * 2004-12-20 2016-12-15 Robert Bosch Gmbh Method and device for thaw detection in a reagent dosing device of an SCR catalytic converter, in particular an internal combustion engine
FR2972489B1 (en) * 2011-03-10 2013-04-12 Peugeot Citroen Automobiles Sa METHOD FOR ESTIMATING REDUCING CONCENTRATION IN A NITROGEN OXIDE REDUCTION SOLUTION AND SCR SYSTEM
KR101490947B1 (en) 2013-11-22 2015-02-06 현대자동차 주식회사 Leak detection method of reducing agent pumping system
DE102015203865A1 (en) * 2015-03-04 2016-09-08 Bayerische Motoren Werke Aktiengesellschaft Method for checking an injector for a reducing agent in the exhaust system of an internal combustion engine

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5884475A (en) * 1994-09-13 1999-03-23 Siemens Aktiengesellschaft Method and device for introducing liquid into an exhaust-gas purification system
US6063350A (en) * 1997-04-02 2000-05-16 Clean Diesel Technologies, Inc. Reducing nox emissions from an engine by temperature-controlled urea injection for selective catalytic reduction
US6519935B2 (en) * 1999-07-19 2003-02-18 Siemens Aktiengesellschaft Device and method for exhaust-gas aftertreatment in an internal-combustion engine
US6550250B2 (en) * 2001-03-02 2003-04-22 Haldor Topsoe A/S Process for the reduction of SCR NOx emissions and apparatus therefor
US6810661B2 (en) * 2002-08-09 2004-11-02 Ford Global Technologies, Llc Method and system for freeze protecting liquid NOx reductants for vehicle application
US7067319B2 (en) * 2004-06-24 2006-06-27 Cummins, Inc. System for diagnosing reagent solution quality and emissions catalyst degradation
US7578321B2 (en) * 2005-10-13 2009-08-25 Ford Global Technologies, Llc Freeze protection for on-board vehicle emissions treatment system

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4432577A1 (en) * 1994-09-13 1996-03-14 Siemens Ag Assembly for introduction of liq. into selective catalytic redn. assembly
DE60044558D1 (en) * 2000-10-25 2010-07-29 Jaguar Cars A diagnostic arrangement for a charge air cooler

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5884475A (en) * 1994-09-13 1999-03-23 Siemens Aktiengesellschaft Method and device for introducing liquid into an exhaust-gas purification system
US6063350A (en) * 1997-04-02 2000-05-16 Clean Diesel Technologies, Inc. Reducing nox emissions from an engine by temperature-controlled urea injection for selective catalytic reduction
US6519935B2 (en) * 1999-07-19 2003-02-18 Siemens Aktiengesellschaft Device and method for exhaust-gas aftertreatment in an internal-combustion engine
US6550250B2 (en) * 2001-03-02 2003-04-22 Haldor Topsoe A/S Process for the reduction of SCR NOx emissions and apparatus therefor
US6810661B2 (en) * 2002-08-09 2004-11-02 Ford Global Technologies, Llc Method and system for freeze protecting liquid NOx reductants for vehicle application
US7067319B2 (en) * 2004-06-24 2006-06-27 Cummins, Inc. System for diagnosing reagent solution quality and emissions catalyst degradation
US7578321B2 (en) * 2005-10-13 2009-08-25 Ford Global Technologies, Llc Freeze protection for on-board vehicle emissions treatment system

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7449162B2 (en) * 2002-11-06 2008-11-11 Robert Bosch Gmbh Device for treatment of exhaust of an internal combustion engine
US20060051276A1 (en) * 2002-11-06 2006-03-09 Johannes Schaller Device for treatment of exhaust of an internal combustion engine
US7842267B2 (en) 2004-12-24 2010-11-30 Nissan Diesel Motor Co., Ltd. Exhaust emission purifying apparatus for engine
US20100236220A1 (en) * 2004-12-24 2010-09-23 Nissan Diesel Motor Co., Ltd. Exhaust emission purifying apparatus for engine
EP1830040A4 (en) * 2004-12-24 2010-10-20 Nissan Diesel Motor Co Engine exhaust purification apparatus
US20080034733A1 (en) * 2006-08-14 2008-02-14 Miller Robert L Fuel supply component purging system
US20100122521A1 (en) * 2008-11-19 2010-05-20 Caterpillar Inc. Method for purging a dosing system
US8459012B2 (en) 2008-11-19 2013-06-11 Caterpillar Inc. Method for purging a dosing system
US20110146247A1 (en) * 2009-12-23 2011-06-23 Caterpillar Inc. Method for introducing a reductant into an exhaust stream
US8359833B2 (en) 2009-12-23 2013-01-29 Caterpillar Inc. Method for introducing a reductant into an exhaust stream
US20140174548A1 (en) * 2011-05-23 2014-06-26 Inergy Automotive Systems Research (Societe Anonyme) Additive delivery system and method for controlling said system
US9582013B2 (en) * 2011-05-23 2017-02-28 Inergy Automotive Systems Research (Societe Anonyme) Additive delivery system and method for controlling said system
WO2022023852A1 (en) * 2020-07-29 2022-02-03 Robert Bosch Gmbh A device and a method for measuring concentration of a reductant solution in a selective catalytic reduction (scr) system of a vehicle

Also Published As

Publication number Publication date
EP1615714A1 (en) 2006-01-18
DE502004001736D1 (en) 2006-11-23
EP1615714B1 (en) 2006-10-11
WO2004089516A1 (en) 2004-10-21
JP4287436B2 (en) 2009-07-01
DE10316184A1 (en) 2004-10-28
JP2006521488A (en) 2006-09-21

Similar Documents

Publication Publication Date Title
US20070163238A1 (en) Method for metering a reagent into the exhaust gas flow of an internal combustion engine
US10145285B2 (en) Method and apparatus for monitoring fluid reductant for internal combustion engine exhaust
RU2267619C2 (en) Method of checking serviceability of exhaust gas catalytic converter
ES2549430T3 (en) Device and method for detecting abnormality of the exhaust gas temperature sensor
US9194268B2 (en) Exhaust gas treatment system including an enhanced SCR diagnostic unit
US7651262B2 (en) Apparatus for discriminating liquid reducing agent
JP4490913B2 (en) Method for inspecting at least three sensors for detecting measurement variables within the range of an internal combustion engine
US20060218895A1 (en) Method for operating an internal combustion engine and device for executing the method
US9416715B2 (en) Method for monitoring an exhaust system of an internal combustion engine
US20140366515A1 (en) Enhanced diagnostic signal to detect pressure condition of a particulate filter
CN113187638B (en) Method for diagnosing high sulfur content in fuel oil
US6883307B2 (en) Diagnosis apparatus for internal combustion engine
GB2508667A (en) Exhaust condition diagnosis
KR100442162B1 (en) Operation monitoring method and monitoring device of catalytic converter
US8041501B2 (en) Method and system for monitoring an active hydrocarbon adsorber
US20230193807A1 (en) Obd sensor response diagnostics and anti tamper device
KR20130038858A (en) Method and device for detecting the blockage of a gasoline vapor filter bleed valve
CN113417726B (en) Method for detecting ammonia leakage of aftertreatment system and controller of aftertreatment system
US8538661B2 (en) Exhaust treatment methods and systems
JP4275154B2 (en) Exhaust temperature sensor inspection device
US10815834B2 (en) Method for detecting an unsealed location in a heat recovery system
Tsinoglou et al. Potential of thermal methods for catalyst on-board diagnosis
CN118979803A (en) A single nitrogen and oxygen sensor SDPF system based on a calibrator and its control, calibration and diagnosis method
CN118757252A (en) A multi-stage SCR control system and method based on calibrator
CN115461614A (en) Electronic detector for water and pollutant in fuel

Legal Events

Date Code Title Description
AS Assignment

Owner name: ROBERT BOSCH GMBH, GERMANY

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:GERLACH, MICHAEL;REEL/FRAME:017981/0084

Effective date: 20051118

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION

点击 这是indexloc提供的php浏览器服务,不要输入任何密码和下载