US20070037487A1 - Polishing pad having a sealed pressure relief channel - Google Patents
Polishing pad having a sealed pressure relief channel Download PDFInfo
- Publication number
- US20070037487A1 US20070037487A1 US11/492,409 US49240906A US2007037487A1 US 20070037487 A1 US20070037487 A1 US 20070037487A1 US 49240906 A US49240906 A US 49240906A US 2007037487 A1 US2007037487 A1 US 2007037487A1
- Authority
- US
- United States
- Prior art keywords
- polishing pad
- void
- polishing
- pressure relief
- window
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/20—Lapping pads for working plane surfaces
- B24B37/205—Lapping pads for working plane surfaces provided with a window for inspecting the surface of the work being lapped
Definitions
- the present invention relates to polishing pads for chemical mechanical planarization (CMP), and in particular, relates to polishing pads having reduced stress windows formed therein for performing optical end-point detection. Further, the present invention relates to polishing pads having a sealed pressure relief channel to reduce stress on the windows and prevent contamination of the window area.
- CMP chemical mechanical planarization
- Planarization is useful in removing undesired surface topography and surface defects, such as rough surfaces, agglomerated materials, crystal lattice damage, scratches, and contaminated layers or materials.
- planarization end-point detection methods have been developed, for example, methods involving optical in-situ measurements of the wafer surface.
- the optical technique involves providing the polishing pad with a window for select wavelengths of light. A light beam is directed through the window to the wafer surface, where it reflects and passes back through the window to a detector (e.g., a spectrophotometer). Based on the return signal, properties of the wafer surface (e.g., the thickness of films) can be determined for end-point detection.
- a chemical mechanical polishing pad comprising: a window formed in the polishing pad, the window having a void provided on a side thereof; a pressure relief channel provided in the polishing pad from the void to a periphery of the polishing pad; and a membrane provided in the channel to prevent contamination of the void.
- a chemical mechanical polishing pad comprising: a polishing layer having a window formed therein, the window being exposed to a void on a side thereof; a pressure relief channel provided in the polishing layer from a portion of the void-exposed side of the window to a periphery of the polishing layer; and a membrane provided in the channel to prevent contamination of the void.
- a chemical mechanical polishing pad comprising: a polishing layer overlying a bottom layer, and an adhesive layer disposed between the polishing layer and the bottom layer; a window formed in the polishing layer, the window being exposed to a void on a side thereof; a pressure relief channel provided in the adhesive layer from the void to a periphery of the adhesive layer; and a membrane provided in the channel to prevent contamination of the void.
- FIG. 2B illustrates another embodiment of a sectional view along line I-II of the polishing pad of FIG. 1 ;
- FIG. 3 illustrates another embodiment of a polishing pad having a pressure relief channel of the present invention
- FIG. 4 illustrates another embodiment of a polishing pad having a pressure relief channel of the present invention.
- FIG. 5 illustrates a CMP system utilizing the polishing pad of the present invention.
- Polishing pad 1 comprises a polishing layer 4 and an optional bottom layer 2 .
- polishing layer 4 and bottom layer 2 may individually serve as a polishing pad.
- the present invention may be utilized in the polishing layer 4 alone, or in the polishing layer 4 in conjunction with the bottom layer 2 , as a polishing pad.
- the bottom layer 2 may be made of felted polyurethane, such as SUBA-IVTM pad manufactured by Rohm and Haas Electronic Materials CMP Inc. (“RHEM”), of Newark, Del.
- Polishing layer 4 has a transparent window 14 provided over the bottom layer 2 and the pressure sensitive adhesive 6 .
- Polishing layer 4 may have a thickness T between 0.70 mm to 2.65 mm.
- window 14 is provided over the void 10 that creates a pathway for the signal light utilized during end-point detection. Accordingly, laser light from a laser spectrophotometer (not shown) may be directed through the void 10 and transparent window block 14 , and onto a wafer or substrate to facilitate end-point detection.
- a laser spectrophotometer not shown
- the present invention is described with reference to a polishing pad having an integrally formed window, the invention is not so limited.
- the entire polishing layer 4 may be transparent (“clear pad”) and the void, including pressure, may be created at any point where, for example, the laser spectrophotometer is placed.
- the present invention is applicable to a window-less pad.
- the polishing layer 4 may be suitably adapted to accommodate other end-point detection methods, for example, measuring the resistance across a polishing surface of the wafer.
- polishing pad 1 comprises a pressure relief channel 11 , including a membrane 12 , having an inlet 11 a and an outlet 11 b .
- the pressure relief channel 11 extends from a portion of the window 14 , on side 14 a that is exposed to the pressure created in void 10 , to a periphery 4 a of the polishing pad 1 , in particular, a periphery 4 a of the polishing layer 4 .
- pressure that is generated in the void 10 during the polishing operation may be evacuated through the membrane 12 , and inlet 11 a and outlet 11 b of pressure relief channel 11 .
- any pressure that is generated in void 10 does not materially affect the transparent window 14 since the pressure escapes through the pressure relief channel 11 . Therefore, the transparent window 14 is not stressed or deformed due to the pressure build-up and accurate end-pointing is facilitated.
- the invention is described here as having a single pressure relief channel, the invention is not so limited. For example, there may be more than one pressure relief channel provided in the polishing layer 4 . Alternatively, a single or multiple pressure relief channels may be provided in each of the separate layers (i.e., the adhesive layer and the bottom layer) or any combinations thereof without departing from the scope of the invention.
- membrane 12 prevents contamination (e.g. slurry flow) through the channel and into the void area.
- contamination e.g. slurry flow
- Membrane 12 is impermeable to contaminants, for example, slurry, but allows heat and pressure to escape from the void area and through the channel.
- membrane 12 acts as a filter, allowing certain undesired items to be released while preventing certain other undesired items from entering.
- Membrane 12 of the polishing pad of the present invention may be manufactured from polyester, polyethylene, polypropylene, fluoropolymers, polyurethane foamed films, silicone, nylon, silk, woven materials and polyethylene terephthalate (PET), or any other biocompatible material.
- the membrane material is a fluoropolymer, in particular, polytetrafluoroethylene (PTFE). More preferably, the membrane material is expanded polytetrafluoroethylene (ePTFE) having a node-fibril structure (e.g., GORE-TEX® membrane vents, manufactured by W. L. Gore and Associates, Inc., Elkton, Md.).
- membranes include modified acrylic copolymer membranes (VERSAPOR® R membranes, manufactured by Gelman Sciences, Ann Arbor, Mich.), modified polyvinylidene fluoride (DURAPEL® membranes, manufactured by the Millipore Corporation, Bedford, Mass.) and other microporous materials that are commonly used to relieve pressure from enclosures.
- VERSAPOR® R membranes manufactured by Gelman Sciences, Ann Arbor, Mich.
- DURAPEL® membranes manufactured by the Millipore Corporation, Bedford, Mass.
- microporous materials that are commonly used to relieve pressure from enclosures.
- the pressure relief channel 11 may be formed by, for example, milling the channel utilizing a computer-numerically controlled tool (“cnc tool”), laser cutting, knife cutting, pre-molding the pad with the channel in place or melting/burning the channel into the pad. Most preferably, the pressure relief channel 11 is formed by milling or laser cutting the channel. Thereafter, membrane 12 may be inserted into the channel, as desired. Depending on the location of the channel (i.e., polishing layer, adhesive layer or the bottom layer) the membrane 12 may be provided in the channel 11 at various steps during the manufacturing process of the polishing pad. In addition, the membrane 12 may be located anywhere along the channel 11 , as desired.
- the pressure relief channel 11 has a semi-circular profile. Note, however, that the particular shape of the profile of the pressure relief channel 11 may be varied without departing from the scope of the invention. For example, the profile of the pressure relief channel 11 may be semi-square or semi-rectangular.
- the pressure relief channel 11 has a predetermined width W and depth D. Preferably, the width W is between 0.70 mm to 6.50 mm. More preferably, the width W is between 0.80 mm to 4.00 mm. Most preferably, the width W is between 0.85 mm to 3.50 mm.
- the pressure relief channel 11 preferably has a depth D between 0.38 mm to 1.53 mm. More preferably, the depth D is between 0.50 mm to 1.27 mm. Most preferably, the depth D is between 0.55 mm to 0.90 mm.
- the width W and depth D may be varied along the length of the pressure relief channel 11 to facilitate pressure evacuation. For example, the width W may be narrower near the window 14 as compared to the periphery 4 a, creating a capillary action to prevent slurry contamination.
- FIG. 2B an alternative embodiment of the pressure relief channel 11 of the present invention is provided. Similar features as in FIG. 2A are denoted by the same numerals.
- the profile of the pressure relief channel 11 is semi-rectangular.
- the pressure relief channel 11 has a predetermined width W and depth D.
- the width W and depth D may be varied along the length of the pressure relief channel 11 to facilitate pressure evacuation.
- a polishing pad 3 is provided comprising a pressure relief channel 31 , having an inlet 31 a and an outlet 31 b , formed in the adhesive 6 .
- the pressure relief channel 31 extends from the void 10 , to a periphery 6 a of the polishing pad 3 . More particularly, the pressure relief channel 31 extends from the void 10 , to a periphery 6 a of the adhesive 6 .
- pressure that is generated in the void 10 during the polishing operation may be evacuated through inlet 31 a and outlet 31 b of pressure relief channel 31 .
- any pressure that is generated in void 10 does not materially affect the transparent window 14 since the pressure escapes through the pressure relief channel 31 . Therefore, the transparent window 14 is not stressed or deformed due to the pressure build-up and accurate end-pointing is facilitated, including reduced defectivity and wafer slippage.
- a polishing pad 5 is provided comprising a pressure relief channel 51 , having an inlet 51 a and an outlet 51 b , formed in the bottom layer 2 .
- the pressure relief channel 51 extends from the void 10 , to a periphery 2 a of the polishing pad 5 . More particularly, the pressure relief channel 51 extends from the void 10 , to a periphery 2 a of the bottom layer 2 .
- the present invention provides a chemical mechanical polishing pad having reduced stress windows.
- a chemical mechanical polishing pad comprising, a window formed in the polishing pad, the window having a void provided on a side thereof.
- the polishing pad further comprises a pressure relief channel provided from the void to a periphery of the polishing pad to relieve undue stress on the window.
- a membrane is provided in the channel to prevent contamination of the void.
- the pressure relief channel may be formed in the adhesive layer or the bottom layer.
- one or more pressure relief channels may be formed in the polishing layer, adhesive layer and the bottom layer together or any combination thereof.
- the transparent material of window 14 is made from a polyisocyanate-containing material (“prepolymer”).
- the prepolymer is a reaction product of a polyisocyanate (e.g., diisocyanate) and a hydroxyl-containing material.
- the polyisocyanate may be aliphatic or aromatic.
- the prepolymer is then cured with a curing agent.
- Preferred polyisocyanates include, but are not limited to, methlene bis 4,4′ cyclohexylisocyanate, cyclohexyl diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, propylene-1,2-diisocyanate, tetramethylene-1,4-diisocyanate, 1,6-hexamethylene-diisocyanate, dodecane-1,12-diisocyanate, cyclobutane-1,3-diisocyanate, cyclohexane-1,3-diisocyanate, cyclohexane-1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane, methyl cyclohexylene diisocyanate, triisocyanate of hexamethylene diisocyanate, triisocyanate of 2,4,4-trimethyl-1
- the hydroxyl-containing material is a polyol.
- exemplary polyols include, but are not limited to, polyether polyols, hydroxy-terminated polybutadiene (including partially/fully hydrogenated derivatives), polyester polyols, polycaprolactone polyols, polycarbonate polyols, and mixtures thereof.
- the polyol includes polyether polyol.
- examples include, but are not limited to, polytetramethylene ether glycol (“PTMEG”), polyethylene propylene glycol, polyoxypropylene glycol, and mixtures thereof.
- the hydrocarbon chain can have saturated or unsaturated bonds and substituted or unsubstituted aromatic and cyclic groups.
- the polyol of the present invention includes PTMEG.
- Suitable polyester polyols include, but are not limited to, polyethylene adipate glycol, polybutylene adipate glycol, polyethylene propylene adipate glycol, o-phthalate-1,6-hexanediol, poly(hexamethylene adipate) glycol, and mixtures thereof.
- the hydrocarbon chain can have saturated or unsaturated bonds, or substituted or unsubstituted aromatic and cyclic groups.
- Suitable polycaprolactone polyols include, but are not limited to, 1,6-hexanediol-initiated polycaprolactone, diethylene glycol initiated polycaprolactone, trimethylol propane initiated polycaprolactone, neopentyl glycol initiated polycaprolactone, 1,4-butanediol-initiated polycaprolactone, PTMEG-initiated polycaprolactone, and mixtures thereof.
- the hydrocarbon chain can have saturated or unsaturated bonds, or substituted or unsubstituted aromatic and cyclic groups.
- Suitable polycarbonates include, but are not limited to, polyphthalate carbonate and poly(hexamethylene carbonate) glycol.
- the curing agent is a polydiamine.
- Preferred polydiamines include, but are not limited to, diethyl toluene diamine (“DETDA”), 3,5-dimethylthio-2,4-toluenediamine and isomers thereof, 3,5-diethyltoluene-2,4-diamine and isomers thereof, such as 3,5-diethyltoluene-2,6-diamine, 4,4′-bis-(sec-butylamino)-diphenylmethane, 1,4-bis-(sec-butylamino)-benzene, 4,4′-methylene-bis-(2-chloroaniline), 4,4′-methylene-bis-(3-chloro- 2 , 6 -diethylaniline) (“MCDEA”), polytetramethyleneoxide-di-p-aminobenzoate, N,N′-dialkyldiamino diphenyl methane, p,p
- Suitable diol, triol, and tetraol groups include ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, lower molecular weight polytetramethylene ether glycol, 1,3-bis(2-hydroxyethoxy) benzene, 1,3-bis-[2-(2-hydroxyethoxy) ethoxy]benzene, 1,3-bis- ⁇ 2-[2-(2-hydroxyethoxy) ethoxy]ethoxy ⁇ benzene, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, resorcinol-di-(beta-hydroxyethyl) ether, hydroquinone-di-(beta-hydroxyethyl)
- window 14 may be formed of, for example, polyurethanes, both thermoset and thermoplastic, polycarbonates, polyesters, silicones, polyimides and polysulfone.
- Example materials for window 14 include, but are not limited to, polyvinyl chloride, polyacrylonitrile, polymethylmethacrylate, polyvinylidene fluoride, polyethylene terephthalate, polyetheretherketone, polyetherketone, polyetherimide, ethylvinyl acetate, polyvinyl butyrate, polyvinyl acetate, acrylonitrile butadiene styrene, fluorinated ethylene propylene and perfluoralkoxy polymers.
- a CMP apparatus 20 utilizing the polishing pad of the present invention, including the pressure relief channel with membrane 12 (not shown) is provided.
- Apparatus 20 includes a wafer carrier 22 for holding or pressing the semiconductor wafer 24 against the polishing platen 26 .
- the polishing platen 26 is provided with pad 1 , including window 14 , pressure relief channel 11 and membrane 12 , of the present invention.
- pad 1 has a bottom layer 2 that interfaces with the surface of the platen 26 , and a polishing layer 4 that is used in conjunction with a chemical polishing slurry to polish the wafer 24 .
- any means for providing a polishing fluid or slurry can be utilized with the present apparatus.
- the platen 26 is usually rotated about its central axis 27 .
- the wafer carrier 22 is usually rotated about its central axis 28 , and translated across the surface of the platen 26 via a translation arm 30 .
- CMP apparatuses may have more than one spaced circumferentially around the polishing platen.
- a transparent hole 32 is provided in the platen 26 and overlies the void 10 and the window 14 of pad 1 . Accordingly, transparent hole 32 provides access to the surface of the wafer 24 , via window 14 , during polishing of the wafer 24 for accurate end-point detection.
- a laser spectrophotometer 34 is provided below the platen 26 that projects a laser beam 36 to pass and return through the transparent hole 32 and high transmission window 14 for accurate end-point detection during polishing of the wafer 24 .
- the present invention provides a chemical mechanical polishing pad having reduced stress windows.
- a chemical mechanical polishing pad comprising, a window formed in the polishing pad, the window having a void provided on a side thereof.
- the polishing pad further comprises a pressure relief channel provided from the void to a periphery of the polishing pad to relieve undue stress on the window.
- a membrane is provided in the channel to prevent contamination of the void.
- the pressure relief channel may be formed in the adhesive layer or the bottom layer.
- one or more pressure relief channels may be formed in the polishing layer, adhesive layer and the bottom layer together or any combination thereof.
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- Engineering & Computer Science (AREA)
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Abstract
The present invention provides a chemical mechanical polishing pad comprising a window formed in the polishing pad, the window having a void provided on a side thereof. The invention further provides a pressure relief channel provided in the polishing pad from the void to a periphery of the polishing pad. In addition, a membrane is provided in the channel to prevent contamination of the void.
Description
- This application claims the benefit of U.S. Provisional Application Ser. No. 60/706,873 filed Aug. 10, 2005.
- The present invention relates to polishing pads for chemical mechanical planarization (CMP), and in particular, relates to polishing pads having reduced stress windows formed therein for performing optical end-point detection. Further, the present invention relates to polishing pads having a sealed pressure relief channel to reduce stress on the windows and prevent contamination of the window area.
- In the fabrication of integrated circuits and other electronic devices, multiple layers of conducting, semiconducting and dielectric materials are deposited on or removed from a surface of a semiconductor wafer. Thin layers of conducting, semiconducting, and dielectric materials may be deposited by a number of deposition techniques. Common deposition techniques in modem processing include physical vapor deposition (PVD), also known as sputtering, chemical vapor deposition (CVD), plasma-enhanced chemical vapor deposition (PECVD), and electrochemical plating (ECP).
- As layers of materials are sequentially deposited and removed, the uppermost surface of the wafer becomes non-planar. Because subsequent semiconductor processing (e.g., metallization) requires the wafer to have a flat surface, the wafer needs to be planarized. Planarization is useful in removing undesired surface topography and surface defects, such as rough surfaces, agglomerated materials, crystal lattice damage, scratches, and contaminated layers or materials.
- Chemical mechanical planarization, or chemical mechanical polishing (CMP), is a common technique used to planarize substrates, such as semiconductor wafers. In conventional CMP, a wafer carrier is mounted on a carrier assembly and positioned in contact with a polishing pad in a CMP apparatus. The carrier assembly provides a controllable pressure to the wafer, pressing it against the polishing pad. The pad is moved (e.g., rotated) relative to the wafer by an external driving force. Simultaneously therewith, a chemical composition (“slurry”) or other polishing solution is provided between the wafer and the polishing pad. Thus, the wafer surface is thus polished and made planar by the chemical and mechanical action of the pad surface and slurry.
- An important step in planarizing a wafer is determining an end-point to the process. Accordingly, a variety of planarization end-point detection methods have been developed, for example, methods involving optical in-situ measurements of the wafer surface. The optical technique involves providing the polishing pad with a window for select wavelengths of light. A light beam is directed through the window to the wafer surface, where it reflects and passes back through the window to a detector (e.g., a spectrophotometer). Based on the return signal, properties of the wafer surface (e.g., the thickness of films) can be determined for end-point detection.
- Roberts, in U.S. Pat. No. 5,605,760, discloses a polishing pad having a window formed therein. In Roberts, a window is cast and inserted into a flowable polishing pad polymer. This polishing pad may be utilized in a stacked configuration (i.e., with a subpad) or used alone, directly adhered on the platen of a polishing apparatus with an adhesive. In either case, there is a “void” or space that is created between the window and the platen. Unfortunately, during polishing, undue stress is applied to the window from the pressure that is generated in the void and may cause unwanted residual stress deformations (e.g., “bulges” or “caving-in”) in the window. These stress deformations may result in non-planar windows and cause poor end-point detection, defectivity and wafer slippage.
- Hence, what is needed is a polishing pad having a reduced stress window for robust end-point detection or measurement during CMP over a wide range of wavelengths.
- In a first aspect of the present invention, there is provided a chemical mechanical polishing pad comprising: a window formed in the polishing pad, the window having a void provided on a side thereof; a pressure relief channel provided in the polishing pad from the void to a periphery of the polishing pad; and a membrane provided in the channel to prevent contamination of the void.
- In another aspect of the present invention, there is provided a chemical mechanical polishing pad comprising: a polishing layer having a window formed therein, the window being exposed to a void on a side thereof; a pressure relief channel provided in the polishing layer from a portion of the void-exposed side of the window to a periphery of the polishing layer; and a membrane provided in the channel to prevent contamination of the void.
- In another aspect of the present invention, there is provided a chemical mechanical polishing pad comprising: a polishing layer overlying a bottom layer, and an adhesive layer disposed between the polishing layer and the bottom layer; a window formed in the polishing layer, the window being exposed to a void on a side thereof; a pressure relief channel provided in the adhesive layer from the void to a periphery of the adhesive layer; and a membrane provided in the channel to prevent contamination of the void.
- In another aspect of the present invention, there is provided a chemical mechanical polishing pad comprising: a polishing layer overlying a bottom layer, and an adhesive layer disposed between the polishing layer and the bottom layer; a window formed in the polishing layer, the window being exposed to a void on a side thereof; a pressure relief channel provided in the bottom layer from the void to a periphery of the bottom layer; and a membrane provided in the channel to prevent contamination of the void.
-
FIG. 1 illustrates a polishing pad having a pressure relief channel of the present invention including a membrane; -
FIG. 2A illustrates a sectional view along line I-II of the polishing pad ofFIG. 1 ; -
FIG. 2B illustrates another embodiment of a sectional view along line I-II of the polishing pad ofFIG. 1 ; -
FIG. 3 illustrates another embodiment of a polishing pad having a pressure relief channel of the present invention; -
FIG. 4 illustrates another embodiment of a polishing pad having a pressure relief channel of the present invention; and -
FIG. 5 illustrates a CMP system utilizing the polishing pad of the present invention. - Referring now to
FIG. 1 , apolishing pad 1 of the present invention is shown.Polishing pad 1 comprises apolishing layer 4 and anoptional bottom layer 2. Note,polishing layer 4 andbottom layer 2 may individually serve as a polishing pad. In other words, the present invention may be utilized in thepolishing layer 4 alone, or in thepolishing layer 4 in conjunction with thebottom layer 2, as a polishing pad. Thebottom layer 2 may be made of felted polyurethane, such as SUBA-IV™ pad manufactured by Rohm and Haas Electronic Materials CMP Inc. (“RHEM”), of Newark, Del. Thepolishing layer 4 may comprise a polyurethane pad (e.g., a pad filled with microspheres), such as, IC 1000™ pad by RHEM.Polishing layer 4 may optionally be texturized as desired. A thin layer of pressuresensitive adhesive 6 may hold thepolishing layer 4 and thebottom layer 2 together. Theadhesive 6 may be commercially available from 3M Innovative Properties Company of St, Paul, Minn. -
Polishing layer 4 has atransparent window 14 provided over thebottom layer 2 and the pressuresensitive adhesive 6.Polishing layer 4 may have a thickness T between 0.70 mm to 2.65 mm. Note,window 14 is provided over thevoid 10 that creates a pathway for the signal light utilized during end-point detection. Accordingly, laser light from a laser spectrophotometer (not shown) may be directed through thevoid 10 andtransparent window block 14, and onto a wafer or substrate to facilitate end-point detection. Note, although the present invention is described with reference to a polishing pad having an integrally formed window, the invention is not so limited. For example, theentire polishing layer 4 may be transparent (“clear pad”) and the void, including pressure, may be created at any point where, for example, the laser spectrophotometer is placed. In other words, the present invention is applicable to a window-less pad. Also, although the present invention is described with respect to end-point detection through awindow 14 utilizing a laser spectrophotometer, the invention is not so limited. For example, thepolishing layer 4 may be suitably adapted to accommodate other end-point detection methods, for example, measuring the resistance across a polishing surface of the wafer. - In an exemplary embodiment of the invention, polishing
pad 1 comprises apressure relief channel 11, including a membrane 12, having aninlet 11 a and anoutlet 11 b. Thepressure relief channel 11 extends from a portion of thewindow 14, onside 14 a that is exposed to the pressure created invoid 10, to aperiphery 4 a of thepolishing pad 1, in particular, aperiphery 4 a of thepolishing layer 4. Hence, pressure that is generated in the void 10 during the polishing operation may be evacuated through the membrane 12, andinlet 11 a andoutlet 11 b ofpressure relief channel 11. In other words, any pressure that is generated invoid 10 does not materially affect thetransparent window 14 since the pressure escapes through thepressure relief channel 11. Therefore, thetransparent window 14 is not stressed or deformed due to the pressure build-up and accurate end-pointing is facilitated. Note, although the invention is described here as having a single pressure relief channel, the invention is not so limited. For example, there may be more than one pressure relief channel provided in thepolishing layer 4. Alternatively, a single or multiple pressure relief channels may be provided in each of the separate layers (i.e., the adhesive layer and the bottom layer) or any combinations thereof without departing from the scope of the invention. In addition, although the invention is described as having a pressure relief channel that extends to the periphery of the polishing pad, the invention is equally applicable to a polishing pad having a pressure relief channel that extends from the void 10 to the polishing surface of thepolishing layer 4. Alternatively, the polishing pad may have a pressure relief channel (including membrane 12) that extends from the void 10, through thewindow 14, to the polishing surface of thepolishing layer 4. - Advantageously, membrane 12 prevents contamination (e.g. slurry flow) through the channel and into the void area. Membrane 12 is impermeable to contaminants, for example, slurry, but allows heat and pressure to escape from the void area and through the channel. In essence, membrane 12 acts as a filter, allowing certain undesired items to be released while preventing certain other undesired items from entering.
- Membrane 12 of the polishing pad of the present invention may be manufactured from polyester, polyethylene, polypropylene, fluoropolymers, polyurethane foamed films, silicone, nylon, silk, woven materials and polyethylene terephthalate (PET), or any other biocompatible material. In one embodiment of the present invention, the membrane material is a fluoropolymer, in particular, polytetrafluoroethylene (PTFE). More preferably, the membrane material is expanded polytetrafluoroethylene (ePTFE) having a node-fibril structure (e.g., GORE-TEX® membrane vents, manufactured by W. L. Gore and Associates, Inc., Elkton, Md.). Other commercially available membranes include modified acrylic copolymer membranes (VERSAPOR® R membranes, manufactured by Gelman Sciences, Ann Arbor, Mich.), modified polyvinylidene fluoride (DURAPEL® membranes, manufactured by the Millipore Corporation, Bedford, Mass.) and other microporous materials that are commonly used to relieve pressure from enclosures.
- The membrane used in the present invention may be manufactured from thin films of ePTFE that are each approximately 0.0025 to 0.025 mm thick. From 1 to about 200 plys (layers) of ePTFE film may be stacked up and laminated to one another to obtain a membrane with the desired mechanical and structural properties. An even number of layers are preferably stacked together (e.g., 2, 4, 6, 8, 10, etc.), with approximately 2 to 20 layers being desirable. Cross-lamination occurs by placing superimposed sheets on one another such that the film drawing direction, or stretching direction, of each sheet is angularly offset by angles between 0 degrees and 180 degrees from adjacent layers or plies. Since the base ePTFE is thin, as thin as 0.0025 mm thick, superimposed films can be rotated relative to one another to improve the mechanical properties of the membrane. In one embodiment of the present invention the membrane is manufactured by laminating 8 plies of ePTFE film, each film ply being 0.0125 mm thick. In another embodiment of the present invention the membrane is manufactured by laminating 4 plies of ePTFE film, each film ply being 0.0125 mm thick. The laminated ePTFE sheets are then sintered together at temperatures of about 370° C., under vacuum to adhere the film layers to one another.
- Advantageously, the
pressure relief channel 11 may be formed by, for example, milling the channel utilizing a computer-numerically controlled tool (“cnc tool”), laser cutting, knife cutting, pre-molding the pad with the channel in place or melting/burning the channel into the pad. Most preferably, thepressure relief channel 11 is formed by milling or laser cutting the channel. Thereafter, membrane 12 may be inserted into the channel, as desired. Depending on the location of the channel (i.e., polishing layer, adhesive layer or the bottom layer) the membrane 12 may be provided in thechannel 11 at various steps during the manufacturing process of the polishing pad. In addition, the membrane 12 may be located anywhere along thechannel 11, as desired. - Referring now to
FIG. 2A , a sectional view along line I-II of polishinglayer 4 ofFIG. 1 is provided. In this embodiment, thepressure relief channel 11 has a semi-circular profile. Note, however, that the particular shape of the profile of thepressure relief channel 11 may be varied without departing from the scope of the invention. For example, the profile of thepressure relief channel 11 may be semi-square or semi-rectangular. In addition, thepressure relief channel 11 has a predetermined width W and depth D. Preferably, the width W is between 0.70 mm to 6.50 mm. More preferably, the width W is between 0.80 mm to 4.00 mm. Most preferably, the width W is between 0.85 mm to 3.50 mm. In addition, thepressure relief channel 11 preferably has a depth D between 0.38 mm to 1.53 mm. More preferably, the depth D is between 0.50 mm to 1.27 mm. Most preferably, the depth D is between 0.55 mm to 0.90 mm. Also, the width W and depth D may be varied along the length of thepressure relief channel 11 to facilitate pressure evacuation. For example, the width W may be narrower near thewindow 14 as compared to theperiphery 4 a, creating a capillary action to prevent slurry contamination. - Referring now to
FIG. 2B , an alternative embodiment of thepressure relief channel 11 of the present invention is provided. Similar features as inFIG. 2A are denoted by the same numerals. Here, the profile of thepressure relief channel 11 is semi-rectangular. As discussed above with reference toFIG. 2A , thepressure relief channel 11 has a predetermined width W and depth D. In addition, the width W and depth D may be varied along the length of thepressure relief channel 11 to facilitate pressure evacuation. - Referring now to
FIG. 3 , there is provided another embodiment of a polishing pad having a pressure relief channel of the present invention. Similar features as inFIG. 1 are denoted by the same numerals. Here, a polishing pad 3 is provided comprising apressure relief channel 31, having aninlet 31 a and anoutlet 31 b, formed in the adhesive 6. Thepressure relief channel 31 extends from the void 10, to aperiphery 6 a of the polishing pad 3. More particularly, thepressure relief channel 31 extends from the void 10, to aperiphery 6 a of the adhesive 6. Hence, pressure that is generated in the void 10 during the polishing operation may be evacuated throughinlet 31 a andoutlet 31 b ofpressure relief channel 31. In other words, any pressure that is generated invoid 10 does not materially affect thetransparent window 14 since the pressure escapes through thepressure relief channel 31. Therefore, thetransparent window 14 is not stressed or deformed due to the pressure build-up and accurate end-pointing is facilitated, including reduced defectivity and wafer slippage. - Referring now to
FIG. 4 , there is provided another embodiment of a polishing pad having a pressure relief channel of the present invention. Similar features as inFIG. 1 are denoted by the same numerals. Here, a polishing pad 5 is provided comprising apressure relief channel 51, having aninlet 51 a and anoutlet 51 b, formed in thebottom layer 2. Thepressure relief channel 51 extends from the void 10, to aperiphery 2 a of the polishing pad 5. More particularly, thepressure relief channel 51 extends from the void 10, to aperiphery 2 a of thebottom layer 2. Hence, pressure that is generated in the void 10 during the polishing operation may be evacuated throughinlet 51 a andoutlet 51 b ofpressure relief channel 51. In other words, any pressure that is generated invoid 10 does not materially affect thetransparent window 14 since the pressure escapes through thepressure relief channel 51. Therefore, thetransparent window 14 is not stressed or deformed due to the pressure build-up and accurate end-pointing is facilitated. - Accordingly, the present invention provides a chemical mechanical polishing pad having reduced stress windows. In addition, the present invention provides a chemical mechanical polishing pad comprising, a window formed in the polishing pad, the window having a void provided on a side thereof. The polishing pad further comprises a pressure relief channel provided from the void to a periphery of the polishing pad to relieve undue stress on the window. In addition, a membrane is provided in the channel to prevent contamination of the void. Also, the pressure relief channel may be formed in the adhesive layer or the bottom layer. Similarly, one or more pressure relief channels may be formed in the polishing layer, adhesive layer and the bottom layer together or any combination thereof.
- Additionally, in an exemplary embodiment of the present invention, the transparent material of
window 14 is made from a polyisocyanate-containing material (“prepolymer”). The prepolymer is a reaction product of a polyisocyanate (e.g., diisocyanate) and a hydroxyl-containing material. The polyisocyanate may be aliphatic or aromatic. The prepolymer is then cured with a curing agent. Preferred polyisocyanates include, but are not limited to,methlene bis - Advantageously, the hydroxyl-containing material is a polyol. Exemplary polyols include, but are not limited to, polyether polyols, hydroxy-terminated polybutadiene (including partially/fully hydrogenated derivatives), polyester polyols, polycaprolactone polyols, polycarbonate polyols, and mixtures thereof.
- In one preferred embodiment, the polyol includes polyether polyol. Examples include, but are not limited to, polytetramethylene ether glycol (“PTMEG”), polyethylene propylene glycol, polyoxypropylene glycol, and mixtures thereof. The hydrocarbon chain can have saturated or unsaturated bonds and substituted or unsubstituted aromatic and cyclic groups. Preferably, the polyol of the present invention includes PTMEG. Suitable polyester polyols include, but are not limited to, polyethylene adipate glycol, polybutylene adipate glycol, polyethylene propylene adipate glycol, o-phthalate-1,6-hexanediol, poly(hexamethylene adipate) glycol, and mixtures thereof. The hydrocarbon chain can have saturated or unsaturated bonds, or substituted or unsubstituted aromatic and cyclic groups. Suitable polycaprolactone polyols include, but are not limited to, 1,6-hexanediol-initiated polycaprolactone, diethylene glycol initiated polycaprolactone, trimethylol propane initiated polycaprolactone, neopentyl glycol initiated polycaprolactone, 1,4-butanediol-initiated polycaprolactone, PTMEG-initiated polycaprolactone, and mixtures thereof. The hydrocarbon chain can have saturated or unsaturated bonds, or substituted or unsubstituted aromatic and cyclic groups. Suitable polycarbonates include, but are not limited to, polyphthalate carbonate and poly(hexamethylene carbonate) glycol.
- Advantageously, the curing agent is a polydiamine. Preferred polydiamines include, but are not limited to, diethyl toluene diamine (“DETDA”), 3,5-dimethylthio-2,4-toluenediamine and isomers thereof, 3,5-diethyltoluene-2,4-diamine and isomers thereof, such as 3,5-diethyltoluene-2,6-diamine, 4,4′-bis-(sec-butylamino)-diphenylmethane, 1,4-bis-(sec-butylamino)-benzene, 4,4′-methylene-bis-(2-chloroaniline), 4,4′-methylene-bis-(3-chloro-2,6-diethylaniline) (“MCDEA”), polytetramethyleneoxide-di-p-aminobenzoate, N,N′-dialkyldiamino diphenyl methane, p,p′-methylene dianiline (“MDA”), m-phenylenediamine (“MPDA”), methylene-bis 2-chloroaniline (“MBOCA”), 4,4′-methylene-bis-(2-chloroaniline) (“MOCA”), 4,4′-methylene-bis-(2,6-diethylaniline) (“MDEA”), 4,4′-methylene-bis-(2,3-dichloroaniline) (“MDCA”), 4,4′-diamino-3,3′-diethyl-5,5′-dimethyl diphenylmethane, 2,2′,3,3′-tetrachloro diamino diphenylmethane, trimethylene glycol di-p-aminobenzoate, and mixtures thereof. Preferably, the curing agent of the present invention includes 3,5-dimethylthio-2,4-toluenediamine and isomers thereof. Suitable polyamine curatives include both primary and secondary amines.
- In addition, other curatives such as, a diol, triol, tetraol, or hydroxy-terminated curative may be added to the aforementioned polyurethane composition. Suitable diol, triol, and tetraol groups include ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, lower molecular weight polytetramethylene ether glycol, 1,3-bis(2-hydroxyethoxy) benzene, 1,3-bis-[2-(2-hydroxyethoxy) ethoxy]benzene, 1,3-bis-{2-[2-(2-hydroxyethoxy) ethoxy]ethoxy}benzene, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, resorcinol-di-(beta-hydroxyethyl) ether, hydroquinone-di-(beta-hydroxyethyl) ether, and mixtures thereof. Preferred hydroxy-terminated curatives include 1,3-bis(2-hydroxyethoxy) benzene, 1,3-bis-[2-(2-hydroxyethoxy) ethoxy]benzene, 1,3-bis-{2-[2-(2-hydroxyethoxy) ethoxy]ethoxy}benzene, 1,4-butanediol, and mixtures thereof. Both the hydroxy-terminated and amine curatives can include one or more saturated, unsaturated, aromatic, and cyclic groups. Additionally, the hydroxy-terminated and amine curatives can include one or more halogen groups. The polyurethane composition can be formed with a blend or mixture of curing agents. If desired, however, the polyurethane composition may be formed with a single curing agent.
- In a preferred embodiment of the invention,
window 14 may be formed of, for example, polyurethanes, both thermoset and thermoplastic, polycarbonates, polyesters, silicones, polyimides and polysulfone. Example materials forwindow 14 include, but are not limited to, polyvinyl chloride, polyacrylonitrile, polymethylmethacrylate, polyvinylidene fluoride, polyethylene terephthalate, polyetheretherketone, polyetherketone, polyetherimide, ethylvinyl acetate, polyvinyl butyrate, polyvinyl acetate, acrylonitrile butadiene styrene, fluorinated ethylene propylene and perfluoralkoxy polymers. - Referring now to
FIG. 5 , aCMP apparatus 20 utilizing the polishing pad of the present invention, including the pressure relief channel with membrane 12 (not shown) is provided.Apparatus 20 includes awafer carrier 22 for holding or pressing thesemiconductor wafer 24 against the polishingplaten 26. The polishingplaten 26 is provided withpad 1, includingwindow 14,pressure relief channel 11 and membrane 12, of the present invention. As discussed above,pad 1 has abottom layer 2 that interfaces with the surface of theplaten 26, and apolishing layer 4 that is used in conjunction with a chemical polishing slurry to polish thewafer 24. Note, although not pictured, any means for providing a polishing fluid or slurry can be utilized with the present apparatus. Theplaten 26 is usually rotated about itscentral axis 27. In addition, thewafer carrier 22 is usually rotated about itscentral axis 28, and translated across the surface of theplaten 26 via atranslation arm 30. Note, although a single wafer carrier is shown inFIG. 5 , CMP apparatuses may have more than one spaced circumferentially around the polishing platen. In addition, atransparent hole 32 is provided in theplaten 26 and overlies the void 10 and thewindow 14 ofpad 1. Accordingly,transparent hole 32 provides access to the surface of thewafer 24, viawindow 14, during polishing of thewafer 24 for accurate end-point detection. Namely, alaser spectrophotometer 34 is provided below theplaten 26 that projects alaser beam 36 to pass and return through thetransparent hole 32 andhigh transmission window 14 for accurate end-point detection during polishing of thewafer 24. - Accordingly, the present invention provides a chemical mechanical polishing pad having reduced stress windows. In addition, the present invention provides a chemical mechanical polishing pad comprising, a window formed in the polishing pad, the window having a void provided on a side thereof. The polishing pad further comprises a pressure relief channel provided from the void to a periphery of the polishing pad to relieve undue stress on the window. In addition, a membrane is provided in the channel to prevent contamination of the void. Also, the pressure relief channel may be formed in the adhesive layer or the bottom layer. Similarly, one or more pressure relief channels may be formed in the polishing layer, adhesive layer and the bottom layer together or any combination thereof.
Claims (10)
1. A chemical mechanical polishing pad comprising:
a window formed in the polishing pad, the window having a void provided on a side thereof;
a pressure relief channel provided in the polishing pad from the void to a periphery of the polishing pad; and
a membrane provided in the channel to prevent contamination of the void.
2. The polishing pad of claim 1 wherein the membrane is selected from the group comprising polyester, polyethylene, polypropylene, fluoropolymers, polyurethane foamed films, silicone, nylon, silk, woven materials and polyethylene terephthalate.
3. The polishing pad of claim 2 wherein the membrane is polytetrafluoroethylene.
4. The polishing pad of claim 3 wherein the membrane is expanded polytetrafluoroethylene.
5. The polishing pad of claim 1 wherein the pressure relief channel has a width between 0.70 mm to 6.50 mm.
6. The polishing pad of claim 5 wherein the width varies between the void to the periphery of the polishing pad.
7. The polishing pad of claim 1 wherein the pressure relief channel has a depth between 0.38 mm to 1.53 mm.
8. A chemical mechanical polishing pad comprising:
a polishing layer having a window formed therein, the window being exposed to a void on a side thereof;
a pressure relief channel provided in the polishing layer from a portion of the void-exposed side of the window to a periphery of the polishing layer; and
a membrane provided in the channel to prevent contamination of the void.
9. A chemical mechanical polishing pad comprising:
a polishing layer overlying a bottom layer, and an adhesive layer disposed between the polishing layer and the bottom layer;
a window formed in the polishing layer, the window being exposed to a void on a side thereof;
a pressure relief channel provided in the adhesive layer from the void to a periphery of the adhesive layer; and
a membrane provided in the channel to prevent contamination of the void.
10. A chemical mechanical polishing pad comprising:
a polishing layer overlying a bottom layer, and an adhesive layer disposed between the polishing layer and the bottom layer;
a window formed in the polishing layer, the window being exposed to a void on a side thereof;
a pressure relief channel provided in the bottom layer from the void to a periphery of the bottom layer; and
a membrane provided in the channel to prevent contamination of the void.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/492,409 US20070037487A1 (en) | 2005-08-10 | 2006-07-25 | Polishing pad having a sealed pressure relief channel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US70687305P | 2005-08-10 | 2005-08-10 | |
US11/492,409 US20070037487A1 (en) | 2005-08-10 | 2006-07-25 | Polishing pad having a sealed pressure relief channel |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070037487A1 true US20070037487A1 (en) | 2007-02-15 |
Family
ID=37743126
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/492,409 Abandoned US20070037487A1 (en) | 2005-08-10 | 2006-07-25 | Polishing pad having a sealed pressure relief channel |
Country Status (1)
Country | Link |
---|---|
US (1) | US20070037487A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7455571B1 (en) | 2007-06-20 | 2008-11-25 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Window polishing pad |
US20090258588A1 (en) * | 2008-04-11 | 2009-10-15 | Innopad, Inc. | Chemical Mechanical Planarization Pad With Void Network |
US9017140B2 (en) | 2010-01-13 | 2015-04-28 | Nexplanar Corporation | CMP pad with local area transparency |
US9156124B2 (en) | 2010-07-08 | 2015-10-13 | Nexplanar Corporation | Soft polishing pad for polishing a semiconductor substrate |
CN107452663A (en) * | 2016-05-30 | 2017-12-08 | 中芯国际集成电路制造(北京)有限公司 | Wafer carrying film |
JP2018199212A (en) * | 2017-04-19 | 2018-12-20 | ローム アンド ハース エレクトロニック マテリアルズ シーエムピー ホウルディングス インコーポレイテッド | Aliphatic polyurethane optical endpoint detection windows and cmp polishing pads containing them |
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US5605760A (en) * | 1995-08-21 | 1997-02-25 | Rodel, Inc. | Polishing pads |
US5725420A (en) * | 1995-10-25 | 1998-03-10 | Nec Corporation | Polishing device having a pad which has grooves and holes |
US6623331B2 (en) * | 2001-02-16 | 2003-09-23 | Cabot Microelectronics Corporation | Polishing disk with end-point detection port |
-
2006
- 2006-07-25 US US11/492,409 patent/US20070037487A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5605760A (en) * | 1995-08-21 | 1997-02-25 | Rodel, Inc. | Polishing pads |
US5725420A (en) * | 1995-10-25 | 1998-03-10 | Nec Corporation | Polishing device having a pad which has grooves and holes |
US6623331B2 (en) * | 2001-02-16 | 2003-09-23 | Cabot Microelectronics Corporation | Polishing disk with end-point detection port |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7455571B1 (en) | 2007-06-20 | 2008-11-25 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Window polishing pad |
US20090258588A1 (en) * | 2008-04-11 | 2009-10-15 | Innopad, Inc. | Chemical Mechanical Planarization Pad With Void Network |
US8684794B2 (en) | 2008-04-11 | 2014-04-01 | Fns Tech Co., Ltd. | Chemical mechanical planarization pad with void network |
US9017140B2 (en) | 2010-01-13 | 2015-04-28 | Nexplanar Corporation | CMP pad with local area transparency |
US9156124B2 (en) | 2010-07-08 | 2015-10-13 | Nexplanar Corporation | Soft polishing pad for polishing a semiconductor substrate |
CN107452663A (en) * | 2016-05-30 | 2017-12-08 | 中芯国际集成电路制造(北京)有限公司 | Wafer carrying film |
JP2018199212A (en) * | 2017-04-19 | 2018-12-20 | ローム アンド ハース エレクトロニック マテリアルズ シーエムピー ホウルディングス インコーポレイテッド | Aliphatic polyurethane optical endpoint detection windows and cmp polishing pads containing them |
JP7176854B2 (en) | 2017-04-19 | 2022-11-22 | ローム アンド ハース エレクトロニック マテリアルズ シーエムピー ホウルディングス インコーポレイテッド | Aliphatic polyurethane optical endpoint detection windows and CMP polishing pads containing them |
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Legal Events
Date | Code | Title | Description |
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STCB | Information on status: application discontinuation |
Free format text: EXPRESSLY ABANDONED -- DURING EXAMINATION |