US20060100111A1 - Method for producing a solution having lubricating properties intended to be used as an additive to a liquid - Google Patents
Method for producing a solution having lubricating properties intended to be used as an additive to a liquid Download PDFInfo
- Publication number
- US20060100111A1 US20060100111A1 US10/526,501 US52650105A US2006100111A1 US 20060100111 A1 US20060100111 A1 US 20060100111A1 US 52650105 A US52650105 A US 52650105A US 2006100111 A1 US2006100111 A1 US 2006100111A1
- Authority
- US
- United States
- Prior art keywords
- solution
- additive
- boric
- liquid
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 239000000654 additive Substances 0.000 title claims abstract description 15
- 230000000996 additive effect Effects 0.000 title claims abstract description 15
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 239000000446 fuel Substances 0.000 claims abstract description 13
- 239000004327 boric acid Substances 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000005260 corrosion Methods 0.000 claims abstract description 9
- 230000007797 corrosion Effects 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 230000001603 reducing effect Effects 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000002401 inhibitory effect Effects 0.000 claims abstract description 4
- 239000012141 concentrate Substances 0.000 claims abstract description 3
- 238000005461 lubrication Methods 0.000 claims abstract description 3
- -1 borate ions Chemical class 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical class O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 239000000314 lubricant Substances 0.000 description 6
- 239000012530 fluid Substances 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910011255 B2O3 Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000000452 restraining effect Effects 0.000 description 2
- 230000004931 aggregating effect Effects 0.000 description 1
- 239000002551 biofuel Substances 0.000 description 1
- 238000005885 boration reaction Methods 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010902 jet-milling Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/02—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
- C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1291—Silicon and boron containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Definitions
- the present invention refers to a method for producing a solution having lubrication properties intended to be used as an additive to a liquid preferably a liquid fuel or a lubricant and a solution made according to said method, which when blended gives the liquid friction-reducing, lubricating and corrosion ihibiting characteristics.
- boron can establish a complex ligand bond to other metals. This occurs after an exposure over time, from hours to days.
- the boron compounds in question are aligned to two dimensional pallets, that slides on each other, which causes a reduced friction.
- boron acts as a corrosion ihibitor for metals as the boric acid bonds to a thin layer on the underlying metal surface and prevents oxidation due to the electro negativity, which makes boron an effective reduction substance that prevents corrosion of exposed surfaces.
- oil is blended with a high concentration of boric acid, and the blend is diluted at a ratio of approximately 10% to different lubricating oils.
- boric acid can be used as an additive to fuels to accomplish a friction reducing effect.
- the method is to mix boric acid in a base oil or a concentrate based on a diesel fuel.
- the particle size of the boric compound normally in the range of 0.5 to 20 micron, is made by “jet-milling”, a method in doing so.
- an additive, diesel additive as example, made by this method over time has a limited stability.
- the boric acid particles are aggregating and are falling out and gathered on the bottom of the container. This happens within a period of months or less. This could lead to severe consequences for any engine, as example a diesel engine. Even when the boric acid particles are mixed in a base oil and thereafter eventually are diluted in fuel or the like, the same risk exists.
- the object of the present invention is to eliminate the disadvantages as mentioned above, and to make an additive to a fluid or liquid, preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect.
- a fluid or liquid preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect.
- a method for producing a solution having lubricating properties of the kind mentioned above which in a distinguishing way fulfils its purpose and also an application of the mentioned solution as an additive to a liquid, such as fluid fuel or a lubricant to give the liquid friction reducing, lubricating and corrosion restraining characteristics.
- the invention means that a boric compound with lubricating characteristics exits in the form of a solution.
- the borat ions will at that consist of a homogenous phase together with the solvent, and which solution, under stable conditions at that may consist of a high concentration of borate, thanks to the used solvent, and preferably an alcohols hydrogen bonds, counteracts the elctro negativity of the boric compound and it's tendency to covalent bonds.
- the boric compounds which according to an example, are dissolved according to the foregoing invention are preferably Boric BOH 3 or dibortrioxide B 2 O 3 (boric oxide), which offers good friction reducing characteristics.
- the solvent can consist of water and/or an alcohol, individually or blended to a mixture.
- the solvent should also be a liquid hydrogen.
- the most alcohols should be used, as example ethanol, methanol etc. and the solution is made by shaking boric acid or bortrioxide together with alcohol or water, eventuially also by adding small mechanical elements to further increase the mechanical work.
- the boric compound may be in a concentration of up to 250,000 ppm or more if necessary.
- the fuel mixture should consist of a concentration of boric compound in the range of 10 to 1,000 ppm, preferably in the range of 100 to 200 ppm.
- the composition consisting lubricant and the solution should have a concentration of boric compounds of around 400 ppm/4%.
- the solution is used as an additive, which is added in a proportion to a lubricant, hydro carbon fuel or a bio fuel such as the boric compound is bonded on surfaces exposed by friction at which the friction is reduced.
- the solution allows for an optimal dissolvement in the fluid and thereby the mentioned advantages of a stable solution which is friction reducing, lubricating and corrosion inhibiting.
- the fluid may be as example hydro carbon fuels such as diesel or gasoline or other and the solution may also be injected separately in an combustion machine such as an hydrogen engine or other engine where friction reduction and corrosion inhibiting is needed.
- the invention also incorporates a solution as such made as an additive by dissolving a boric compound, a boric acid and/or bortrioxide.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Lubricants (AREA)
Abstract
The present invention refers to a method for producing a solution having lubrication properties intended to be used preferably as an additive as a concentrate blended to a liquid, such as a liquid fuel. A boric compound such as boric acid and/or bortrioxide is dissolved in a solvent and the borate ions are in a homogene phase together with the solvent, which as a solution in stable conditions is made to have a high concentration of borate thanks to the hydrogen bonds counteraction to the electro negativity of the boric compound and its tendency to covalent bonding, the solution being used as and additive to the actual liquid, which in this way receive friction reducing, lubricating and corrosion inhibiting characteristics.
Description
- The present invention refers to a method for producing a solution having lubrication properties intended to be used as an additive to a liquid preferably a liquid fuel or a lubricant and a solution made according to said method, which when blended gives the liquid friction-reducing, lubricating and corrosion ihibiting characteristics.
- It is previously known, as example from U.S. Pat. No. 5,431,830, that boron can establish a complex ligand bond to other metals. This occurs after an exposure over time, from hours to days. The boron compounds in question are aligned to two dimensional pallets, that slides on each other, which causes a reduced friction. Furthermore, boron acts as a corrosion ihibitor for metals as the boric acid bonds to a thin layer on the underlying metal surface and prevents oxidation due to the electro negativity, which makes boron an effective reduction substance that prevents corrosion of exposed surfaces.
- According to previously known technique, oil is blended with a high concentration of boric acid, and the blend is diluted at a ratio of approximately 10% to different lubricating oils.
- According to U.S. Pat. No. 6,368,369, it's stated that boric acid can be used as an additive to fuels to accomplish a friction reducing effect. The method is to mix boric acid in a base oil or a concentrate based on a diesel fuel. The particle size of the boric compound, normally in the range of 0.5 to 20 micron, is made by “jet-milling”, a method in doing so. Experiments have shown that an additive, diesel additive as example, made by this method over time has a limited stability. The boric acid particles are aggregating and are falling out and gathered on the bottom of the container. This happens within a period of months or less. This could lead to severe consequences for any engine, as example a diesel engine. Even when the boric acid particles are mixed in a base oil and thereafter eventually are diluted in fuel or the like, the same risk exists.
- The object of the present invention is to eliminate the disadvantages as mentioned above, and to make an additive to a fluid or liquid, preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect. The characterizing features of the invention are stated in the following claims.
- Thanks to the invention, a method for producing a solution having lubricating properties of the kind mentioned above, which in a distinguishing way fulfils its purpose and also an application of the mentioned solution as an additive to a liquid, such as fluid fuel or a lubricant to give the liquid friction reducing, lubricating and corrosion restraining characteristics. The invention means that a boric compound with lubricating characteristics exits in the form of a solution. The borat ions will at that consist of a homogenous phase together with the solvent, and which solution, under stable conditions at that may consist of a high concentration of borate, thanks to the used solvent, and preferably an alcohols hydrogen bonds, counteracts the elctro negativity of the boric compound and it's tendency to covalent bonds.
- The invention is described further below by aid of some preferable embodiment examples.
- The boric compounds, which according to an example, are dissolved according to the foregoing invention are preferably Boric BOH3 or dibortrioxide B2O3 (boric oxide), which offers good friction reducing characteristics. The solvent can consist of water and/or an alcohol, individually or blended to a mixture. The solvent should also be a liquid hydrogen. The most alcohols should be used, as example ethanol, methanol etc. and the solution is made by shaking boric acid or bortrioxide together with alcohol or water, eventuially also by adding small mechanical elements to further increase the mechanical work.
- In the solution, the boric compound may be in a concentration of up to 250,000 ppm or more if necessary. When blended to fuel such as diesel or gasoline, the fuel mixture should consist of a concentration of boric compound in the range of 10 to 1,000 ppm, preferably in the range of 100 to 200 ppm.
- When the solution is added to a lubricant, the composition consisting lubricant and the solution should have a concentration of boric compounds of around 400 ppm/4%.
- In another application, the solution is used as an additive, which is added in a proportion to a lubricant, hydro carbon fuel or a bio fuel such as the boric compound is bonded on surfaces exposed by friction at which the friction is reduced. The solution allows for an optimal dissolvement in the fluid and thereby the mentioned advantages of a stable solution which is friction reducing, lubricating and corrosion inhibiting. The fluid may be as example hydro carbon fuels such as diesel or gasoline or other and the solution may also be injected separately in an combustion machine such as an hydrogen engine or other engine where friction reduction and corrosion inhibiting is needed. When mixing a boric acid solution with hydrogen, a thermic reaction is achieved, which further increases the tendency to covalent bond.
- The invention also incorporates a solution as such made as an additive by dissolving a boric compound, a boric acid and/or bortrioxide.
Claims (5)
1. A method for producing a solution having lubrication properties intended to be used preferably as an additive as a concentrate blended to a liquid, such as a liquid fuel, characterized in that a boric compound such as boric acid and/or bortrioxide is dissolved in a solvent in the form of an alcohol and/or water or liquid hydrogen, the borate ions being in a homogene phase together with the solvent, which as a solution in stable conditions is made to have a high concentration of borate and that the mixture is stirred and/or shaken to dissolve the boric compounds at the same time as the dissolving time is accelerated by using heat, whereby the alcohol content exceeds 96%, the solution being used as and additive to the actual liquid, which in this way receive friction reducing, lubricating and corrosion inhibiting characteristics.
2. A method according to claim 1 , characterized in that the mixture is shaken with mechanical elements added to further accelerate the dissolving of the boric compound in the solution by warming up or with aid of a combination thereof.
3. A method according to claim 1 , characterized in that the addition of the boric compound in the solution makes a solution with a borate concentration exceeding 250,000 ppm or more.
4. The use of a solution made according to claim 1 as an additive to a fuel in a blending, depending to the type of fuel, gives a concentration of boric compound in the range of 10 to 1,000 ppm.
5. A solution made as an additive according to claim 1 , characterized in that a boric compound in the form of a boric acid and/or bortrioxide is brought into a solvent.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0202659A SE0202659D0 (en) | 2002-09-09 | 2002-09-09 | Lubricants and lubricants additives |
SE0202659-9 | 2002-09-09 | ||
SE0302070-8 | 2003-07-14 | ||
SE0302070A SE524898C3 (en) | 2002-09-09 | 2003-07-14 | Process for preparing a solution having lubricating properties intended to be used as additive to a liquid, use of the solution and solution |
PCT/SE2003/001366 WO2004022676A1 (en) | 2002-09-09 | 2003-09-08 | A method for producing a solution having lubricating properties intended to be used as an additive to a liquid |
Publications (1)
Publication Number | Publication Date |
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US20060100111A1 true US20060100111A1 (en) | 2006-05-11 |
Family
ID=27767292
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/526,501 Abandoned US20060100111A1 (en) | 2002-09-09 | 2003-09-08 | Method for producing a solution having lubricating properties intended to be used as an additive to a liquid |
Country Status (7)
Country | Link |
---|---|
US (1) | US20060100111A1 (en) |
EP (1) | EP1539904A1 (en) |
JP (1) | JP2005538209A (en) |
AU (1) | AU2003261686A1 (en) |
BR (1) | BR0314167A (en) |
SE (1) | SE524898C3 (en) |
WO (1) | WO2004022676A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011008131A3 (en) * | 2009-07-16 | 2011-03-10 | Naumov, Vladimir Nikolaevich | Water-soluble conveyor lubricant |
US20130239463A1 (en) * | 2012-03-15 | 2013-09-19 | William E. Olliges | Use Of Hexylene Glycol Fuel Additive Containing Boric Oxide |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005083042A1 (en) * | 2004-03-02 | 2005-09-09 | Mats Selin | Additive for two stroke fuel with lubrificating properties adapted to replace traditional two stroke oil and two stroke fuel |
US7494959B2 (en) * | 2005-08-10 | 2009-02-24 | Advanced Lubrication Technology Inc. | Multi-phase lubricant compositions containing emulsified boric acid |
US7419515B2 (en) * | 2005-08-10 | 2008-09-02 | Advanced Lubrication Technology, Inc. | Multi-phase distillate fuel compositions and concentrates containing emulsified boric acid |
CN100526444C (en) * | 2005-12-20 | 2009-08-12 | 中国科学院兰州化学物理研究所 | Preparing method of superfine borate grain as lubricant additive |
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US4539126A (en) * | 1983-11-15 | 1985-09-03 | Shell Oil Company | Borated basic metal salt and lubricating oil composition |
US4557844A (en) * | 1984-01-30 | 1985-12-10 | Mobil Oil Corporation | Aminated boron- and phosphorus-containing compounds and lubricant or fuel compositions containing same |
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US5033415A (en) * | 1987-06-22 | 1991-07-23 | Mobil Oil Corporation | Friction reducing additives and compositions thereof |
-
2003
- 2003-07-14 SE SE0302070A patent/SE524898C3/en unknown
- 2003-09-08 JP JP2004533938A patent/JP2005538209A/en active Pending
- 2003-09-08 EP EP03794394A patent/EP1539904A1/en not_active Withdrawn
- 2003-09-08 AU AU2003261686A patent/AU2003261686A1/en not_active Abandoned
- 2003-09-08 BR BR0314167-5A patent/BR0314167A/en not_active Application Discontinuation
- 2003-09-08 WO PCT/SE2003/001366 patent/WO2004022676A1/en not_active Application Discontinuation
- 2003-09-08 US US10/526,501 patent/US20060100111A1/en not_active Abandoned
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US4440656A (en) * | 1981-11-23 | 1984-04-03 | Mobil Oil Corporation | Borated alkoxylated alcohols and lubricants and liquid fuels containing same |
US4524004A (en) * | 1983-10-28 | 1985-06-18 | Mobil Oil Corporation | Borated N-hydrocarbyl-hydrocarbylene diamines as multifunctional lubricant/fuel additives and compositions thereof |
US4539126A (en) * | 1983-11-15 | 1985-09-03 | Shell Oil Company | Borated basic metal salt and lubricating oil composition |
US4557844A (en) * | 1984-01-30 | 1985-12-10 | Mobil Oil Corporation | Aminated boron- and phosphorus-containing compounds and lubricant or fuel compositions containing same |
US4741848A (en) * | 1986-03-13 | 1988-05-03 | The Lubrizol Corporation | Boron-containing compositions, and lubricants and fuels containing same |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011008131A3 (en) * | 2009-07-16 | 2011-03-10 | Naumov, Vladimir Nikolaevich | Water-soluble conveyor lubricant |
US20130239463A1 (en) * | 2012-03-15 | 2013-09-19 | William E. Olliges | Use Of Hexylene Glycol Fuel Additive Containing Boric Oxide |
US9212329B2 (en) * | 2012-03-15 | 2015-12-15 | William E. Olliges | Use of hexylene glycol fuel additive containing boric oxide |
Also Published As
Publication number | Publication date |
---|---|
SE0302070L (en) | 2004-03-10 |
AU2003261686A1 (en) | 2004-03-29 |
SE524898C3 (en) | 2005-06-01 |
BR0314167A (en) | 2005-07-19 |
EP1539904A1 (en) | 2005-06-15 |
SE0302070D0 (en) | 2003-07-14 |
JP2005538209A (en) | 2005-12-15 |
SE524898C2 (en) | 2004-10-19 |
WO2004022676A1 (en) | 2004-03-18 |
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