+

US20060063472A1 - Method for polishing substrate - Google Patents

Method for polishing substrate Download PDF

Info

Publication number
US20060063472A1
US20060063472A1 US11/228,214 US22821405A US2006063472A1 US 20060063472 A1 US20060063472 A1 US 20060063472A1 US 22821405 A US22821405 A US 22821405A US 2006063472 A1 US2006063472 A1 US 2006063472A1
Authority
US
United States
Prior art keywords
substrate
polishing
polished
polishing pad
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/228,214
Inventor
Satoshi Matsumoto
Yuichi Kurimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Assigned to MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD. reassignment MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KURIMOTO, YUICHI, MATSUMOTO, SATOSHI
Publication of US20060063472A1 publication Critical patent/US20060063472A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/005Control means for lapping machines or devices
    • B24B37/015Temperature control

Definitions

  • the present invention relates to a substrate polishing method in which a substrate is polished while the temperature of a surface of a polishing pad is measured.
  • CMP chemical mechanical polishing
  • a polishing time is typically used as a criterion for detecting an end point of polishing. It has been known that when a metal film is polished to form a buried interconnect, a point of change of the temperature of a surface of a polishing pad is used as the criterion (see Japanese Unexamined Patent Publication Nos. 7-94452 and 8-330261).
  • a semiconductor wafer is polished by rotating the platen and the carrier while supplying abrasives to a polishing pad bonded to a platen with a substrate that is supported by a carrier pressed against the polishing pad, the temperature of a surface of the polishing pad is measured by a sensor.
  • the measured temperature of the polishing pad surface is always monitored using a monitoring tool connected to the sensor, thereby detecting a point of change of the measured temperature.
  • a monitoring tool connected to the sensor, thereby detecting a point of change of the measured temperature.
  • the utilization of the point of change of the temperature of the polishing pad surface as an end point of polishing is effective at polishing a metal film to form a buried interconnect but impossible in a polishing process in which a single metal film is to be polished, such as a polishing process for an insulating film.
  • the reason for this is that in the above polishing process, such a significant change in temperature that can be considered as the end point does not occur.
  • the temperature of a surface of a polishing pad at the start of the next process becomes lower than usual.
  • the temperature of the polishing pad surface increases during polishing and then decreases during standby. This is repeated.
  • the standby time becomes longer than usual, the temperature of the polishing pad surface becomes lower.
  • a chemical action of the CMP depends on the temperature of a polishing pad surface.
  • the polishing rate becomes low.
  • polishing is started under the condition that the temperature of the polishing pad surface is low, the polishing rate becomes low. Therefore, even when polishing is carried out for a normally set time, such an abnormality that part of a substrate is unpolished occurs in a product to be processed.
  • a polishing apparatus keeps being operated without checking the state of the polished product and is provided with no sensor for sensing the above abnormality.
  • the present invention has been made to solve the aforementioned problems, and an object of the present invention is to allow reliable elimination of a substrate that has been insufficiently polished in a substrate polishing process.
  • the present invention is configured such that a method for polishing a substrate is carried out while the temperature of a surface of a polishing pad is monitored.
  • a method for polishing a substrate according to a first aspect of the present invention includes the steps of: (a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; (b) calculating an index of the amount of the substrate polished on the basis of the monitored temperature of the polishing pad surface; and (c) detecting an abnormally polished substrate when the calculated index of the amount of the substrate polished is below a previously set value.
  • the substrate polishing method of the first aspect information concerning the amount of the substrate polished can be easily obtained. Since an abnormality in the amount of the substrate polished can therefore be detected immediately after the polishing of the substrate, this makes it possible to remove a substrate having such an abnormality that part of the substrate is unpolished from a fabrication process.
  • the index of the amount of the substrate polished may be a value obtained by integrating the temperature of the polishing pad surface with respect to the time during which the substrate is polished, the average temperature of the polishing pad surface during the time during which the substrate is polished, or a value obtained by differentiating variations in the temperature of the polishing pad surface in the step (a).
  • the method of the first aspect further includes the step (d) of, after the step (a), removing the polished substrate from on the polishing pad and replacing the polished substrate with an unpolished substrate, wherein a cycle of the steps (a), (b), (c), and (d) is carried out a plurality of times.
  • an alarm is preferably raised when the abnormally polished substrate is detected.
  • the substrate is further polished when the abnormally polished substrate is detected.
  • a method for polishing a substrate includes the steps of: (a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; and (b) calculating an index of the amount of the substrate polished on the basis of the monitored temperature of the polishing pad surface, wherein the step (b) is carried out simultaneously with the step (a), and the step (a) is carried out until the index of the amount of the substrate polished that has been calculated in the step (b) reaches a previously set value.
  • the substrate can be polished until the amount of the substrate polished reaches a predetermined value. Since a shortage of the amount of the substrate to be polished is therefore not caused, a substrate having such an abnormality that part of the substrate is unpolished is not transferred to later process steps.
  • the index of the amount of the substrate polished is preferably a value obtained by integrating the temperature of the polishing pad surface with respect to the time during which the substrate is polished and may be the average temperature of the polishing pad surface during the time during which the substrate is polished.
  • the method of the second aspect further includes the step (c) of, after the step (a), removing the polished substrate from on the polishing pad and replacing the polished substrate with an unpolished substrate, wherein a cycle of the steps (a) and (b) and the step (c) are carried out a plurality of times.
  • the method of the second aspect further includes the step of correcting the set value based on the index of the amount of the substrate polished that has been calculated in the step (b) after each completion of the cycle of the steps (a) and (b).
  • a method for polishing a substrate according to a third aspect of the present invention includes the steps of: (a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; and (b) replacing the polished substrate with an unpolished substrate by removing the polished substrate from on the polishing pad, wherein the steps (a) and (b) are successively carried out a plurality of times, the time required for the step (b) is measured, and when the time required for the step (b) is longer than a previously set time, the unpolished substrate is detected as an abnormally polished substrate.
  • the abnormally polished substrate can be easily detected. This can prevent, with reliability, a substrate having such an abnormality that part of the substrate is unpolished from being transferred to later process steps.
  • FIG. 1 is a perspective view showing a polishing apparatus according to a first embodiment of the present invention.
  • FIG. 2 is a graph showing temperature variations at a polishing pad surface when intervals between polishing steps are fixed in a substrate polishing method of the first embodiment of the present invention.
  • FIG. 3 is a graph showing temperature variations at a polishing pad surface when intervals between polishing steps vary in the substrate polishing method of the first embodiment of the present invention.
  • FIG. 4 is a graph showing the comparison on temperature variations at a polishing pad surface between a polishing step after the usual standby time and a polishing step after a prolonged standby time in the substrate polishing method of the first embodiment of the present invention.
  • FIG. 5 is a graph showing the relationship between the average temperature of the polishing pad surface and the polishing rate in the substrate polishing method of the first embodiment of the present invention.
  • FIG. 6 is a schematic view showing another polishing apparatus according to the first embodiment of the present invention.
  • FIG. 7 is a graph showing the comparison on temperature variations at a polishing pad surface between a polishing step after the usual standby time and a polishing step after a prolonged standby time in a substrate polishing method of a first modification of the first embodiment of the present invention.
  • FIG. 8 is a graph showing the relationship between the standby time and the polishing rate in a substrate polishing method of a second modification of the first embodiment of the present invention.
  • FIG. 9 is a graph showing the progression of the temperature of a polishing pad surface in a substrate polishing method of a second embodiment of the present invention.
  • FIG. 1 illustrates a polishing apparatus according to the first embodiment.
  • the polishing apparatus of this embodiment includes a platen 11 to which a polishing pad 12 is bonded and a carrier 14 for supporting a substrate 13 .
  • the substrate 13 is polished by rotating the platen 11 and the carrier 14 while supplying abrasives 15 to the polishing pad 12 with the substrate 13 pressed against the polishing pad 12 .
  • the polishing apparatus further includes a sensor 16 for measuring the temperature of a surface of the polishing pad 12 and a monitoring tool 18 connected to the sensor 16 . Therefore, the temperature of the polishing pad 12 surface can always be monitored.
  • a part 17 of the polishing pad 12 to be measured in its surface temperature (hereinafter, referred to as “to-be-temperature-measured part 17 ”) is preferably set to overlap with a path through which the center of the substrate 13 travels on the polishing pad 12 during polishing.
  • a non-contact radiation thermometer or the like is used as the sensor 16 .
  • FIG. 2 illustrates the progression of the temperature of the polishing pad 12 surface.
  • polishing steps 21 and standby steps 22 are alternately carried out. In each polishing step 21 , the temperature of the polishing pad 12 surface increases, and in each standby step 22 , the temperature of the polishing pad 12 surface decreases.
  • the polishing steps 21 are carried out at regular intervals, and the respective times required for each polishing step 21 and each standby step 22 are fixed.
  • the temperatures of the polishing pad 12 surface at the starts of the polishing steps 21 become substantially equal to one another, and those at the completion of the polishing steps 21 become substantially equal to one another.
  • the processing time for the previous step is not fixed so that the intervals between polishing steps are not originally regular.
  • FIG. 3 illustrates the progression of the temperature of the polishing pad 12 surface when the intervals between polishing steps are not regular.
  • a standby step 24 in which the standby time becomes longer than usual due to troubles, the temperature of the polishing pad 12 surface becomes lower than usual.
  • the next polishing step 23 is started under the condition that the temperature of the polishing pad 12 surface is lower than usual.
  • FIG. 4 illustrates, in the same coordinate plane, temperature variations at the polishing pad 12 surface in the polishing step 21 after a normal standby step 22 and temperature variations at the polishing pad 12 surface in the polishing step 23 after the standby step 24 in which the standby time is longer than usual.
  • FIG. 5 illustrates the relationship between the average temperature of the polishing pad 12 surface during polishing and the polishing rate.
  • the polishing rate is decreasing. Therefore, when the polishing time is fixed, the amount of the substrate 13 polished decreases with reduction in the average temperature of the polishing pad 12 surface.
  • the standby time becomes longer than usual so that polishing is started under the condition that the temperature of the polishing pad 12 surface is lower than usual, there is a high possibility that a surface of the substrate 13 is not sufficiently polished, leading to such a quality abnormality that part of the substrate 13 is unpolished.
  • the average temperature of the polishing pad 12 surface during polishing is used as an index of the amount of the substrate 13 polished.
  • the average temperature of the polishing pad 12 surface during polishing is calculated, as an index of the amount of the substrate 13 polished, by constantly monitoring the temperature of the polishing pad 12 surface.
  • the calculated index is smaller than a previously set threshold value, the processed substrate 13 is identified and eliminated.
  • the substrate 13 that may have such a quality abnormality that part of the substrate 13 is unpolished can be eliminated from a fabrication line with reliability. After the eliminated substrate 13 is separately checked for unpolished part of the substrate 13 or other abnormalities, necessary handling is carried out.
  • the substrate 13 is manually eliminated most simply by displaying the presence of an abnormality on a screen of a polishing apparatus or by raising an alarm or the like utilizing a communication line or the like.
  • the substrate 13 may be eliminated by an automatic substrate transport apparatus or other apparatuses.
  • a value obtained by integrating the temperature of the polishing pad 12 surface with respect to the polishing time may be used as all index of the amount of the substrate 13 polished.
  • the polishing method of this embodiment can be applied also to a polishing apparatus of a linear polishing system shown in FIG. 6 .
  • the polishing apparatus of the linear polishing system polishes a substrate in the following manner. While abrasives 64 are supplied to a polishing pad 61 bonded to a belt with a substrate 62 that is supported by a carrier 63 pressed against the polishing pad 61 , the belt is driven to horizontally move the polishing pad 61 and the carrier 63 is rotated. The temperature of the polishing pad 61 surface is measured by a sensor 65 . The measured surface temperature is always monitored using a monitoring tool 67 connected to the sensor 65 .
  • a to-be-temperature-measured part 66 of the polishing pad 61 to be measured in its surface temperature is preferably set to overlap with a path through which the center of the substrate 62 travels on the polishing pad 61 during polishing.
  • a non-contact radiation thermometer or the like need be used as the sensor 65 .
  • a first modification of the first embodiment of the present invention will be described hereinafter.
  • the rate of change of the temperature of a polishing pad 12 surface is used as an index of the amount of a substrate polished.
  • FIG. 7 is a graph showing the comparison on temperature variations at a polishing pad surface between a polishing step after the usual standby time and a polishing step after a prolonged standby time in a substrate polishing method of a first modification of the first embodiment of the present invention.
  • the temperature variations at the polishing pad surface in the polishing step after the usual standby time and those at the polishing pad surface in the polishing step after the prolonged standby time are shown by a solid line and broken lines, respectively.
  • the rate of change in the temperature of the polishing pad 12 surface in the polishing step after the usual standby time becomes smaller than that in the polishing step after the prolonged standby time Therefore, a substrate that may have been insufficiently polished can be detected in the following manner: In a time interval 93 in which the temperature of the polishing pad 12 surface is increasing immediately after the start of polishing, the slope of the rise in the temperature of the polishing pad 12 surface, i.e., a differential value, is calculated in real time, and the calculated slope of the temperature variations is compared with a previously set threshold value.
  • FIG. 8 illustrates the relationship between the standby time between polishing steps and the polishing rate. As shown in FIG. 8 , with an increase in the standby time, the polishing rate is reduced.
  • a standby time beyond which an abnormality is caused is determined as a threshold value of the standby time on the basis of correlation data between the polishing rate and the standby time.
  • a second embodiment of the present invention will be described hereinafter.
  • a substrate is polished by the same polishing apparatus as in the first embodiment until an index of the amount of the substrate polished reaches a previously set value, thereby preventing a substrate with an abnormality from being produced.
  • FIG. 9 illustrates temperature variations of the polishing pad 12 surface according to this embodiment.
  • a polishing step 74 executed after the prolonged standby time the temperature of the polishing pad 12 surface at the start of the polishing step 74 becomes lower than in a polishing step 73 executed after the usual standby time and the temperature rise also becomes slower than in the polishing step 73 .
  • a substrate is polished until the integral of the temperature of the polishing pad 12 surface with respect to the polishing time reaches a previously set value. Therefore, the amount of the substrate 13 polished in the polishing step 73 after the usual standby time becomes substantially equal to the amount of the substrate 13 polished in the polishing step 74 after the prolonged standby time.
  • an end point at which polishing is completed is detected using, as an index of the amount of a substrate polished, the integral of the temperature of a polishing pad surface during polishing with respect to the polishing time.
  • This method is effective as a method for detecting an end point of polishing when a single film is to be polished and therefore temperature variations of the polishing pad surface during polishing is small, such as when an insulating film is to be polished.
  • a target index of the amount of the substrate polished may be previously set, it may be set by feeding forward indices for several products processed in recent polishing steps.
  • the end point can be detected according to the type of a semiconductor device to be fabricated and the process step by using, for a program and recording medium for detecting an end point, a method for determining the polishing time of the present invention.
  • the average temperature of the polishing pad surface during polishing may be used as an index of the amount of a substrate polished.
  • the method for polishing a substrate of the present invention is useful as a method in which a substrate is polished while the temperature of a polishing pad surface is measured, thereby certainly eliminating a substrate with such an abnormality that part of the substrate is unpolished.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)

Abstract

In a method for polishing a substrate, a substrate placed on a polishing pad bonded onto a platen is polished while the temperature of a surface of the polishing pad is monitored. An index of the amount of the substrate polished is calculated based on the monitored temperature of the polishing pad surface. When the calculated index of the amount of the substrate polished is below a previously set value, the substrate is detected as an abnormally polished substrate.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application claims priority under 35 U.S.C. §119 on Patent Application No. 2004-272852 filed in Japan on Sep. 21, 2004, the entire contents of which are hereby incorporated by reference.
  • BACKGROUND OF THE INVENTION
  • (1) Field of the Invention
  • The present invention relates to a substrate polishing method in which a substrate is polished while the temperature of a surface of a polishing pad is measured.
  • (2) Description of Related Art
  • In a known chemical mechanical polishing (CMP) technique in which a surface of a semiconductor wafer is polished, semiconductor wafers to be polished are subjected one after another to a polishing process and the polishing process is repeated at regular intervals. Even when trouble with equipment or variations of the time during which a semiconductor wafer is transferred make the interval between one polishing process and the next polishing process longer than usual, the next process is often successively carried out as long as the trouble with equipment is minor and the polishing processes are interrupted only for a short time of a few minutes.
  • In the CMP technique, a polishing time is typically used as a criterion for detecting an end point of polishing. It has been known that when a metal film is polished to form a buried interconnect, a point of change of the temperature of a surface of a polishing pad is used as the criterion (see Japanese Unexamined Patent Publication Nos. 7-94452 and 8-330261). When a semiconductor wafer is polished by rotating the platen and the carrier while supplying abrasives to a polishing pad bonded to a platen with a substrate that is supported by a carrier pressed against the polishing pad, the temperature of a surface of the polishing pad is measured by a sensor. The measured temperature of the polishing pad surface is always monitored using a monitoring tool connected to the sensor, thereby detecting a point of change of the measured temperature. When a metal film is polished to form a buried interconnect, the temperature of the polishing pad surface varies according to the type of the metal film to be polished. Therefore, the point of change of the surface temperature can be utilized as the criterion of end-point detection.
  • The utilization of the point of change of the temperature of the polishing pad surface as an end point of polishing is effective at polishing a metal film to form a buried interconnect but impossible in a polishing process in which a single metal film is to be polished, such as a polishing process for an insulating film. The reason for this is that in the above polishing process, such a significant change in temperature that can be considered as the end point does not occur.
  • Meanwhile, when the time interval between one polishing process and the next polishing process becomes longer than usual due to troubles with equipment and the transfer of semiconductor wafers, the temperature of a surface of a polishing pad at the start of the next process becomes lower than usual. The temperature of the polishing pad surface increases during polishing and then decreases during standby. This is repeated. In view of the above, as the standby time becomes longer than usual, the temperature of the polishing pad surface becomes lower.
  • In the CMP technique, a chemical action of the CMP depends on the temperature of a polishing pad surface. When the temperature is low, the polishing rate becomes low. Thus, when polishing is started under the condition that the temperature of the polishing pad surface is low, the polishing rate becomes low. Therefore, even when polishing is carried out for a normally set time, such an abnormality that part of a substrate is unpolished occurs in a product to be processed. Conventionally, in the case where the time during which polishing is interrupted is short, a polishing apparatus keeps being operated without checking the state of the polished product and is provided with no sensor for sensing the above abnormality.
  • SUMMARY OF THE INVENTION
  • The present invention has been made to solve the aforementioned problems, and an object of the present invention is to allow reliable elimination of a substrate that has been insufficiently polished in a substrate polishing process.
  • In order to achieve the above object, the present invention is configured such that a method for polishing a substrate is carried out while the temperature of a surface of a polishing pad is monitored.
  • A method for polishing a substrate according to a first aspect of the present invention includes the steps of: (a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; (b) calculating an index of the amount of the substrate polished on the basis of the monitored temperature of the polishing pad surface; and (c) detecting an abnormally polished substrate when the calculated index of the amount of the substrate polished is below a previously set value.
  • According to the substrate polishing method of the first aspect, information concerning the amount of the substrate polished can be easily obtained. Since an abnormality in the amount of the substrate polished can therefore be detected immediately after the polishing of the substrate, this makes it possible to remove a substrate having such an abnormality that part of the substrate is unpolished from a fabrication process.
  • In the method of the first aspect, the index of the amount of the substrate polished may be a value obtained by integrating the temperature of the polishing pad surface with respect to the time during which the substrate is polished, the average temperature of the polishing pad surface during the time during which the substrate is polished, or a value obtained by differentiating variations in the temperature of the polishing pad surface in the step (a).
  • Preferably, the method of the first aspect further includes the step (d) of, after the step (a), removing the polished substrate from on the polishing pad and replacing the polished substrate with an unpolished substrate, wherein a cycle of the steps (a), (b), (c), and (d) is carried out a plurality of times.
  • In the method of the first aspect, an alarm is preferably raised when the abnormally polished substrate is detected.
  • It is preferable that, in the method of the first aspect, the substrate is further polished when the abnormally polished substrate is detected.
  • A method for polishing a substrate according to a second aspect includes the steps of: (a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; and (b) calculating an index of the amount of the substrate polished on the basis of the monitored temperature of the polishing pad surface, wherein the step (b) is carried out simultaneously with the step (a), and the step (a) is carried out until the index of the amount of the substrate polished that has been calculated in the step (b) reaches a previously set value.
  • According to the method of the second aspect, the substrate can be polished until the amount of the substrate polished reaches a predetermined value. Since a shortage of the amount of the substrate to be polished is therefore not caused, a substrate having such an abnormality that part of the substrate is unpolished is not transferred to later process steps.
  • In the method of the second aspect, the index of the amount of the substrate polished is preferably a value obtained by integrating the temperature of the polishing pad surface with respect to the time during which the substrate is polished and may be the average temperature of the polishing pad surface during the time during which the substrate is polished.
  • Preferably, the method of the second aspect further includes the step (c) of, after the step (a), removing the polished substrate from on the polishing pad and replacing the polished substrate with an unpolished substrate, wherein a cycle of the steps (a) and (b) and the step (c) are carried out a plurality of times.
  • It is preferable that the method of the second aspect further includes the step of correcting the set value based on the index of the amount of the substrate polished that has been calculated in the step (b) after each completion of the cycle of the steps (a) and (b).
  • A method for polishing a substrate according to a third aspect of the present invention includes the steps of: (a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; and (b) replacing the polished substrate with an unpolished substrate by removing the polished substrate from on the polishing pad, wherein the steps (a) and (b) are successively carried out a plurality of times, the time required for the step (b) is measured, and when the time required for the step (b) is longer than a previously set time, the unpolished substrate is detected as an abnormally polished substrate.
  • According to the method of the third aspect, the abnormally polished substrate can be easily detected. This can prevent, with reliability, a substrate having such an abnormality that part of the substrate is unpolished from being transferred to later process steps.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a perspective view showing a polishing apparatus according to a first embodiment of the present invention.
  • FIG. 2 is a graph showing temperature variations at a polishing pad surface when intervals between polishing steps are fixed in a substrate polishing method of the first embodiment of the present invention.
  • FIG. 3 is a graph showing temperature variations at a polishing pad surface when intervals between polishing steps vary in the substrate polishing method of the first embodiment of the present invention.
  • FIG. 4 is a graph showing the comparison on temperature variations at a polishing pad surface between a polishing step after the usual standby time and a polishing step after a prolonged standby time in the substrate polishing method of the first embodiment of the present invention.
  • FIG. 5 is a graph showing the relationship between the average temperature of the polishing pad surface and the polishing rate in the substrate polishing method of the first embodiment of the present invention.
  • FIG. 6 is a schematic view showing another polishing apparatus according to the first embodiment of the present invention.
  • FIG. 7 is a graph showing the comparison on temperature variations at a polishing pad surface between a polishing step after the usual standby time and a polishing step after a prolonged standby time in a substrate polishing method of a first modification of the first embodiment of the present invention.
  • FIG. 8 is a graph showing the relationship between the standby time and the polishing rate in a substrate polishing method of a second modification of the first embodiment of the present invention.
  • FIG. 9 is a graph showing the progression of the temperature of a polishing pad surface in a substrate polishing method of a second embodiment of the present invention.
  • DETAILED DESCRIPTION OF THE INVENTION Embodiment 1
  • A first embodiment of the present invention will be described with reference to the drawings. FIG. 1 illustrates a polishing apparatus according to the first embodiment. As shown in FIG. 1, the polishing apparatus of this embodiment includes a platen 11 to which a polishing pad 12 is bonded and a carrier 14 for supporting a substrate 13. The substrate 13 is polished by rotating the platen 11 and the carrier 14 while supplying abrasives 15 to the polishing pad 12 with the substrate 13 pressed against the polishing pad 12.
  • The polishing apparatus further includes a sensor 16 for measuring the temperature of a surface of the polishing pad 12 and a monitoring tool 18 connected to the sensor 16. Therefore, the temperature of the polishing pad 12 surface can always be monitored. A part 17 of the polishing pad 12 to be measured in its surface temperature (hereinafter, referred to as “to-be-temperature-measured part 17”) is preferably set to overlap with a path through which the center of the substrate 13 travels on the polishing pad 12 during polishing. A non-contact radiation thermometer or the like is used as the sensor 16.
  • During polishing, the temperature of the polishing pad 12 surface increases due to the friction between the substrate 13 and the polishing pad 12. FIG. 2 illustrates the progression of the temperature of the polishing pad 12 surface. As shown in FIG. 2, polishing steps 21 and standby steps 22 are alternately carried out. In each polishing step 21, the temperature of the polishing pad 12 surface increases, and in each standby step 22, the temperature of the polishing pad 12 surface decreases.
  • When equipment operates normally, the polishing steps 21 are carried out at regular intervals, and the respective times required for each polishing step 21 and each standby step 22 are fixed. The temperatures of the polishing pad 12 surface at the starts of the polishing steps 21 become substantially equal to one another, and those at the completion of the polishing steps 21 become substantially equal to one another.
  • However, when the next substrate is transferred later than usual due to troubles with equipment or the like, this increases the standby time and the intervals between polishing steps. In some of processes for fabricating a semiconductor device, the processing time for the previous step is not fixed so that the intervals between polishing steps are not originally regular.
  • FIG. 3 illustrates the progression of the temperature of the polishing pad 12 surface when the intervals between polishing steps are not regular. In a standby step 24 in which the standby time becomes longer than usual due to troubles, the temperature of the polishing pad 12 surface becomes lower than usual. The next polishing step 23 is started under the condition that the temperature of the polishing pad 12 surface is lower than usual.
  • FIG. 4 illustrates, in the same coordinate plane, temperature variations at the polishing pad 12 surface in the polishing step 21 after a normal standby step 22 and temperature variations at the polishing pad 12 surface in the polishing step 23 after the standby step 24 in which the standby time is longer than usual.
  • When the standby time is longer than usual, the temperature of the polishing pad 12 surface at the beginning of polishing becomes lower than usual. As a result, the average temperature of the polishing pad 12 surface during polishing becomes lower than usual.
  • FIG. 5 illustrates the relationship between the average temperature of the polishing pad 12 surface during polishing and the polishing rate. As shown in FIG. 5, with reduction in the average temperature of the polishing pad 12 surface, the polishing rate is decreasing. Therefore, when the polishing time is fixed, the amount of the substrate 13 polished decreases with reduction in the average temperature of the polishing pad 12 surface. In view of the above, when the standby time becomes longer than usual so that polishing is started under the condition that the temperature of the polishing pad 12 surface is lower than usual, there is a high possibility that a surface of the substrate 13 is not sufficiently polished, leading to such a quality abnormality that part of the substrate 13 is unpolished. As seen from the above, the average temperature of the polishing pad 12 surface during polishing is used as an index of the amount of the substrate 13 polished.
  • In this embodiment, the average temperature of the polishing pad 12 surface during polishing is calculated, as an index of the amount of the substrate 13 polished, by constantly monitoring the temperature of the polishing pad 12 surface. When the calculated index is smaller than a previously set threshold value, the processed substrate 13 is identified and eliminated. In this way, the substrate 13 that may have such a quality abnormality that part of the substrate 13 is unpolished can be eliminated from a fabrication line with reliability. After the eliminated substrate 13 is separately checked for unpolished part of the substrate 13 or other abnormalities, necessary handling is carried out.
  • The substrate 13 is manually eliminated most simply by displaying the presence of an abnormality on a screen of a polishing apparatus or by raising an alarm or the like utilizing a communication line or the like. Alternatively, the substrate 13 may be eliminated by an automatic substrate transport apparatus or other apparatuses.
  • Instead of the average temperature of the polishing pad 12 surface, a value obtained by integrating the temperature of the polishing pad 12 surface with respect to the polishing time may be used as all index of the amount of the substrate 13 polished.
  • Although in this embodiment an apparatus for polishing a substrate by rotating a pad and the substrate is used as an example, the polishing method of this embodiment can be applied also to a polishing apparatus of a linear polishing system shown in FIG. 6.
  • As shown in FIG. 6, the polishing apparatus of the linear polishing system polishes a substrate in the following manner. While abrasives 64 are supplied to a polishing pad 61 bonded to a belt with a substrate 62 that is supported by a carrier 63 pressed against the polishing pad 61, the belt is driven to horizontally move the polishing pad 61 and the carrier 63 is rotated. The temperature of the polishing pad 61 surface is measured by a sensor 65. The measured surface temperature is always monitored using a monitoring tool 67 connected to the sensor 65. A to-be-temperature-measured part 66 of the polishing pad 61 to be measured in its surface temperature is preferably set to overlap with a path through which the center of the substrate 62 travels on the polishing pad 61 during polishing. A non-contact radiation thermometer or the like need be used as the sensor 65.
  • Modification 1 of Embodiment 1
  • A first modification of the first embodiment of the present invention will be described hereinafter. In this modification, the rate of change of the temperature of a polishing pad 12 surface is used as an index of the amount of a substrate polished.
  • FIG. 7 is a graph showing the comparison on temperature variations at a polishing pad surface between a polishing step after the usual standby time and a polishing step after a prolonged standby time in a substrate polishing method of a first modification of the first embodiment of the present invention. In FIG. 7, the temperature variations at the polishing pad surface in the polishing step after the usual standby time and those at the polishing pad surface in the polishing step after the prolonged standby time are shown by a solid line and broken lines, respectively. The rate of change in the temperature of the polishing pad 12 surface in the polishing step after the usual standby time becomes smaller than that in the polishing step after the prolonged standby time Therefore, a substrate that may have been insufficiently polished can be detected in the following manner: In a time interval 93 in which the temperature of the polishing pad 12 surface is increasing immediately after the start of polishing, the slope of the rise in the temperature of the polishing pad 12 surface, i.e., a differential value, is calculated in real time, and the calculated slope of the temperature variations is compared with a previously set threshold value.
  • Modification 2 of Embodiment 1
  • A second modification of the first embodiment of the present invention will be described hereinafter. With an increase in the intervals between polishing steps, the temperature of the polishing pad 12 surface is reduced. This increases the possibility of such an abnormality that part of a substrate is unpolished. FIG. 8 illustrates the relationship between the standby time between polishing steps and the polishing rate. As shown in FIG. 8, with an increase in the standby time, the polishing rate is reduced.
  • In view of the above, when the standby time between polishing steps is always monitored and a substrate processed after the standby time exceeding a previously set threshold value is eliminated, this can prevent a substrate that may have such an abnormality that part of the substrate is unpolished from being transferred to the next step.
  • A standby time beyond which an abnormality is caused is determined as a threshold value of the standby time on the basis of correlation data between the polishing rate and the standby time.
  • Embodiment 2
  • A second embodiment of the present invention will be described hereinafter. In a polishing method of the second embodiment, a substrate is polished by the same polishing apparatus as in the first embodiment until an index of the amount of the substrate polished reaches a previously set value, thereby preventing a substrate with an abnormality from being produced.
  • FIG. 9 illustrates temperature variations of the polishing pad 12 surface according to this embodiment. In a polishing step 74 executed after the prolonged standby time, the temperature of the polishing pad 12 surface at the start of the polishing step 74 becomes lower than in a polishing step 73 executed after the usual standby time and the temperature rise also becomes slower than in the polishing step 73. However, in this embodiment, a substrate is polished until the integral of the temperature of the polishing pad 12 surface with respect to the polishing time reaches a previously set value. Therefore, the amount of the substrate 13 polished in the polishing step 73 after the usual standby time becomes substantially equal to the amount of the substrate 13 polished in the polishing step 74 after the prolonged standby time. Thus, in such cases that the standby time becomes longer than usual due to minor troubles or the like or the standby time is not originally fixed because of an inconstant processing time of the previous step, even if the temperature of the polishing pad 12 surface becomes low so that the polishing rate becomes low, such an abnormality that part of the substrate is unpolished is not caused.
  • According to the method of this embodiment, an end point at which polishing is completed is detected using, as an index of the amount of a substrate polished, the integral of the temperature of a polishing pad surface during polishing with respect to the polishing time. This method is effective as a method for detecting an end point of polishing when a single film is to be polished and therefore temperature variations of the polishing pad surface during polishing is small, such as when an insulating film is to be polished. Although a target index of the amount of the substrate polished may be previously set, it may be set by feeding forward indices for several products processed in recent polishing steps. Furthermore, the end point can be detected according to the type of a semiconductor device to be fabricated and the process step by using, for a program and recording medium for detecting an end point, a method for determining the polishing time of the present invention.
  • Instead of the integral of the temperature of a polishing pad surface with respect to the polishing time, the average temperature of the polishing pad surface during polishing may be used as an index of the amount of a substrate polished.
  • As described above, the method for polishing a substrate of the present invention is useful as a method in which a substrate is polished while the temperature of a polishing pad surface is measured, thereby certainly eliminating a substrate with such an abnormality that part of the substrate is unpolished.

Claims (13)

1. A method for polishing a substrate, said method comprising the steps of:
(a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad;
(b) calculating an index of the amount of the substrate polished on the basis of the monitored temperature of the polishing pad surface; and
(c) detecting an abnormally polished substrate when the calculated index of the amount of the substrate polished is below a previously set value.
2. The method of claim 1, wherein
the index of the amount of the substrate polished is a value obtained by integrating the temperature of the polishing pad surface with respect to the time during which the substrate is polished.
3. The method of claim 1, wherein
the index of the amount of the substrate polished is the average temperature of the polishing pad surface during the time during which the substrate is polished.
4. The method of claim 1, wherein
the index of the amount of the substrate polished is a value obtained by differentiating variations in the temperature of the polishing pad surface in the step (a).
5. The method of claim 1 further comprising the step (d) of, after the step (a), removing the polished substrate from on the polishing pad and replacing the polished substrate with an unpolished substrate,
wherein a cycle of the steps (a), (b), (c), and (d) is carried out a plurality of times.
6. The method of claim 1, wherein
an alarm is raised when the abnormally polished substrate is detected.
7. The method of claim 1, wherein
the substrate is further polished when the abnormally polished substrate is detected.
8. A method for polishing a substrate, said method comprising the steps of:
(a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; and
(b) calculating an index of the amount of the substrate polished on the basis of the monitored temperature of the polishing pad surface,
wherein the step (b) is carried out simultaneously with the step (a), and
the step (a) is carried out until the index of the amount of the substrate polished that has been calculated in the step (b) reaches a previously set value.
9. The method of claim 8, wherein
the index of the amount of the substrate polished is a value obtained by integrating the temperature of the polishing pad surface with respect to the time during which the substrate is polished.
10. The method of claim 8, wherein
the index of the amount of the substrate polished is the average temperature of the polishing pad surface during the time during which the substrate is polished.
11. The method of claim 8 further comprising the step (c) of, after the step (a), removing the polished substrate from on the polishing pad and replacing the polished substrate with an unpolished substrate,
wherein a cycle of the steps (a) and (b) and the step (c) are carried out a plurality of times.
12. The method of claim 11 further comprising the step of correcting the set value based on the index of the amount of the substrate polished that has been calculated in the step (b) after each completion of the cycle of the steps (a) and (b).
13. A method for polishing a substrate, said method comprising the steps of:
(a) polishing a substrate placed on a polishing pad bonded onto a platen while monitoring the temperature of a surface of the polishing pad; and
(b) replacing the polished substrate with an unpolished substrate by removing the polished substrate from on the polishing pad,
wherein the steps (a) and (b) are successively carried out a plurality of times,
the time required for the step (b) is measured, and
when the time required for the step (b) is longer than a previously set time, the unpolished substrate is detected as an abnormally polished substrate.
US11/228,214 2004-09-21 2005-09-19 Method for polishing substrate Abandoned US20060063472A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004272852A JP2006093180A (en) 2004-09-21 2004-09-21 Method of manufacturing semiconductor device
JP2004-272852 2004-09-21

Publications (1)

Publication Number Publication Date
US20060063472A1 true US20060063472A1 (en) 2006-03-23

Family

ID=36074678

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/228,214 Abandoned US20060063472A1 (en) 2004-09-21 2005-09-19 Method for polishing substrate

Country Status (2)

Country Link
US (1) US20060063472A1 (en)
JP (1) JP2006093180A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080176403A1 (en) * 2006-11-16 2008-07-24 Samsung Electronics Co., Ltd. Method of polishing a layer and method of manufacturing a semiconductor device using the same
US20110084403A1 (en) * 2009-10-08 2011-04-14 International Business Machines Corporation Pad bonding employing a self-aligned plated liner for adhesion enhancement
WO2014164360A1 (en) * 2013-03-13 2014-10-09 Applied Materials, Inc. Laser pad conditioning process control
US20140323016A1 (en) * 2013-04-25 2014-10-30 Ebara Corporation Polishing method and polishing apparatus
US20150290764A1 (en) * 2014-04-10 2015-10-15 Apple Inc. Thermographic characterization for surface finishing process development
CN110303423A (en) * 2018-03-20 2019-10-08 胜高股份有限公司 The grinding method and grinding device of workpiece
TWI689373B (en) * 2014-01-23 2020-04-01 日商荏原製作所股份有限公司 Polishing method and polishing apparatus
CN113344308A (en) * 2020-02-17 2021-09-03 华晨宝马汽车有限公司 Quality monitoring method, system, equipment and medium based on polishing operation data
CN113766994A (en) * 2019-05-09 2021-12-07 信越半导体株式会社 Single-side polishing method
US20220016739A1 (en) * 2020-07-14 2022-01-20 Applied Materials, Inc. Methods of detecting non-conforming substrate processing events during chemical mechanical polishing

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5446192B2 (en) * 2008-09-24 2014-03-19 日本電気株式会社 Polishing apparatus, polishing rate estimation method and program
JP5547472B2 (en) * 2009-12-28 2014-07-16 株式会社荏原製作所 Substrate polishing apparatus, substrate polishing method, and polishing pad surface temperature control apparatus for substrate polishing apparatus
TWI565559B (en) 2011-07-19 2017-01-11 荏原製作所股份有限公司 Polishing device and method
JP5791987B2 (en) * 2011-07-19 2015-10-07 株式会社荏原製作所 Polishing apparatus and method
JP6730337B2 (en) 2018-02-01 2020-07-29 ファナック株式会社 Abnormality discrimination device, program, abnormality discrimination system, and abnormality discrimination method

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5643050A (en) * 1996-05-23 1997-07-01 Industrial Technology Research Institute Chemical/mechanical polish (CMP) thickness monitor
US5647952A (en) * 1996-04-01 1997-07-15 Industrial Technology Research Institute Chemical/mechanical polish (CMP) endpoint method
US5851846A (en) * 1994-12-22 1998-12-22 Nippondenso Co., Ltd. Polishing method for SOI
US5882244A (en) * 1995-07-20 1999-03-16 Ebara Corporation Polishing apparatus
US20010019895A1 (en) * 1998-09-03 2001-09-06 Robinson Karl M. Methods, apparatuses, and substrate assembly structures for fabricating microelectronic components using mechanical and chemical-mechanical planarization processes
US20040157531A1 (en) * 2000-06-30 2004-08-12 Lam Research Corporation End-point detection apparatus
US20050048875A1 (en) * 2003-09-03 2005-03-03 Ja-Eung Koo Chemical mechanical polishing apparatus
US6872662B1 (en) * 2003-10-27 2005-03-29 Hong Hocheng Method for detecting the endpoint of a chemical mechanical polishing (CMP) process
US20050118839A1 (en) * 1999-04-23 2005-06-02 Industrial Technology Research Institute Chemical mechanical polish process control method using thermal imaging of polishing pad

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5851846A (en) * 1994-12-22 1998-12-22 Nippondenso Co., Ltd. Polishing method for SOI
US5882244A (en) * 1995-07-20 1999-03-16 Ebara Corporation Polishing apparatus
US5647952A (en) * 1996-04-01 1997-07-15 Industrial Technology Research Institute Chemical/mechanical polish (CMP) endpoint method
US5643050A (en) * 1996-05-23 1997-07-01 Industrial Technology Research Institute Chemical/mechanical polish (CMP) thickness monitor
US20010019895A1 (en) * 1998-09-03 2001-09-06 Robinson Karl M. Methods, apparatuses, and substrate assembly structures for fabricating microelectronic components using mechanical and chemical-mechanical planarization processes
US20050118839A1 (en) * 1999-04-23 2005-06-02 Industrial Technology Research Institute Chemical mechanical polish process control method using thermal imaging of polishing pad
US20040157531A1 (en) * 2000-06-30 2004-08-12 Lam Research Corporation End-point detection apparatus
US20050048875A1 (en) * 2003-09-03 2005-03-03 Ja-Eung Koo Chemical mechanical polishing apparatus
US6872662B1 (en) * 2003-10-27 2005-03-29 Hong Hocheng Method for detecting the endpoint of a chemical mechanical polishing (CMP) process

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080176403A1 (en) * 2006-11-16 2008-07-24 Samsung Electronics Co., Ltd. Method of polishing a layer and method of manufacturing a semiconductor device using the same
US20110084403A1 (en) * 2009-10-08 2011-04-14 International Business Machines Corporation Pad bonding employing a self-aligned plated liner for adhesion enhancement
US8482132B2 (en) 2009-10-08 2013-07-09 International Business Machines Corporation Pad bonding employing a self-aligned plated liner for adhesion enhancement
US8492265B2 (en) 2009-10-08 2013-07-23 International Business Machines Corporation Pad bonding employing a self-aligned plated liner for adhesion enhancement
TWI625197B (en) * 2013-03-13 2018-06-01 應用材料股份有限公司 Laser pad conditioning process control
WO2014164360A1 (en) * 2013-03-13 2014-10-09 Applied Materials, Inc. Laser pad conditioning process control
US20140323016A1 (en) * 2013-04-25 2014-10-30 Ebara Corporation Polishing method and polishing apparatus
US9604337B2 (en) 2013-04-25 2017-03-28 Ebara Corporation Polishing method
US9266214B2 (en) * 2013-04-25 2016-02-23 Ebara Corporation Polishing method and polishing apparatus
TWI689373B (en) * 2014-01-23 2020-04-01 日商荏原製作所股份有限公司 Polishing method and polishing apparatus
US9855637B2 (en) * 2014-04-10 2018-01-02 Apple Inc. Thermographic characterization for surface finishing process development
US20150290764A1 (en) * 2014-04-10 2015-10-15 Apple Inc. Thermographic characterization for surface finishing process development
CN110303423A (en) * 2018-03-20 2019-10-08 胜高股份有限公司 The grinding method and grinding device of workpiece
CN113766994A (en) * 2019-05-09 2021-12-07 信越半导体株式会社 Single-side polishing method
CN113344308A (en) * 2020-02-17 2021-09-03 华晨宝马汽车有限公司 Quality monitoring method, system, equipment and medium based on polishing operation data
US20220016739A1 (en) * 2020-07-14 2022-01-20 Applied Materials, Inc. Methods of detecting non-conforming substrate processing events during chemical mechanical polishing
WO2022015441A1 (en) 2020-07-14 2022-01-20 Applied Materials, Inc. Methods of detecting non-conforming substrate processing events during chemical mechanical polishing
KR20230035651A (en) * 2020-07-14 2023-03-14 어플라이드 머티어리얼스, 인코포레이티드 Methods for Detecting Nonconforming Substrate Processing Events During Chemical Mechanical Polishing
US12036635B2 (en) * 2020-07-14 2024-07-16 Applied Materials, Inc. Methods of detecting non-conforming substrate processing events during chemical mechanical polishing
EP4182119A4 (en) * 2020-07-14 2024-08-07 Applied Materials, Inc. Methods of detecting non-conforming substrate processing events during chemical mechanical polishing
KR102746464B1 (en) 2020-07-14 2024-12-23 어플라이드 머티어리얼스, 인코포레이티드 Methods for detecting unsuitable substrate processing events during chemical mechanical polishing

Also Published As

Publication number Publication date
JP2006093180A (en) 2006-04-06

Similar Documents

Publication Publication Date Title
US20060063472A1 (en) Method for polishing substrate
US6939198B1 (en) Polishing system with in-line and in-situ metrology
US8388409B2 (en) Substrate polishing apparatus
US7175505B1 (en) Method for adjusting substrate processing times in a substrate polishing system
US6976902B2 (en) Chemical mechanical polishing apparatus
US20080031510A1 (en) Method of and apparatus for inspecting wafers in chemical mechanical polishing equipment
US20150017745A1 (en) Polishing method and polishing apparatus
US6375540B1 (en) End-point detection system for chemical mechanical posing applications
US7751609B1 (en) Determination of film thickness during chemical mechanical polishing
CN112824040A (en) Control device and computer-readable recording medium
US9524913B2 (en) Polishing method and polishing apparatus
CN112355886A (en) Chemical mechanical polishing machine, method and defect detection method
US6547637B1 (en) Chemical/mechanical polishing endpoint detection device and method
US11279001B2 (en) Method and apparatus for monitoring chemical mechanical polishing process
US20070123046A1 (en) Continuous in-line monitoring and qualification of polishing rates
US6198294B1 (en) In-situ backgrind wafer thickness monitor
US7169019B2 (en) Method of monitoring surface status and life of pad by detecting temperature of polishing interface during chemical mechanical process
KR101952840B1 (en) System and Method for Detecting Degradation Trend of Arm Blade for Wafer Transfer Robot
US20060245871A1 (en) Wafer transfer system, wafer transfer method, cassette exchange system and cassette exchange method
US6673634B2 (en) Wafer protection method
JPH06270053A (en) Automatic measuring method and automatic measuring device for double-side polishing work quantity and automatic double-side polishing work method and work device
US11227778B2 (en) Wafer cleaning apparatus and operation method of the same
WO2002017381A2 (en) Method for preventing damage to wafers in a sequential multiple steps polishing process
US7090563B2 (en) Polishing method
KR20070043280A (en) Transfer system for semiconductor substrate and apparatus for polishing semiconductor substrate comprising same

Legal Events

Date Code Title Description
AS Assignment

Owner name: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD., JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MATSUMOTO, SATOSHI;KURIMOTO, YUICHI;REEL/FRAME:016840/0929;SIGNING DATES FROM 20050822 TO 20050824

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION

点击 这是indexloc提供的php浏览器服务,不要输入任何密码和下载