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US20030146526A1 - Compression molding of optical lenses - Google Patents

Compression molding of optical lenses Download PDF

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Publication number
US20030146526A1
US20030146526A1 US10/368,731 US36873103A US2003146526A1 US 20030146526 A1 US20030146526 A1 US 20030146526A1 US 36873103 A US36873103 A US 36873103A US 2003146526 A1 US2003146526 A1 US 2003146526A1
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Prior art keywords
blank
pressure
lenses
lens
mold
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Abandoned
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US10/368,731
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Vandenberg Mead
Roxanne White
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Individual
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Publication of US20030146526A1 publication Critical patent/US20030146526A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/021Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles characterised by the shape of the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/38Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • B29C33/3828Moulds made of at least two different materials having different thermal conductivities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/565Consisting of shell-like structures supported by backing material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C43/361Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • B29D11/00038Production of contact lenses
    • B29D11/00125Auxiliary operations, e.g. removing oxygen from the mould, conveying moulds from a storage to the production line in an inert atmosphere
    • B29D11/00192Demoulding, e.g. separating lenses from mould halves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • B29D11/00413Production of simple or compound lenses made by moulding between two mould parts which are not in direct contact with one another, e.g. comprising a seal between or on the edges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • B29D11/00432Auxiliary operations, e.g. machines for filling the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C2043/3205Particular pressure exerting means for making definite articles
    • B29C2043/3255Particular pressure exerting means for making definite articles springs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C43/361Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
    • B29C2043/3615Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C43/361Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
    • B29C2043/3615Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices
    • B29C2043/3618Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices plurality of counteracting elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C2043/366Moulds for making articles of definite length, i.e. discrete articles plates pressurized by an actuator, e.g. ram drive, screw, vulcanizing presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/02Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • B29C33/04Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means using liquids, gas or steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/30Mounting, exchanging or centering
    • B29C33/303Mounting, exchanging or centering centering mould parts or halves, e.g. during mounting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2011/00Optical elements, e.g. lenses, prisms
    • B29L2011/0016Lenses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/808Lens mold

Definitions

  • Polycarbonate is a popular material for making ophthalmic lenses. Polycarbonate lenses are often produced by injection and compression molding of liquid resin. The conventional operation causes the lenses to remain with residual stress effects.
  • a preferred mode presses both top and bottom at the same time, and at substantially the same pressures.
  • Another mode uses a mold made of glass to match the coefficient of expansion of the mold more closely to the polycarbonate blank.
  • the mold is heated and cooled using a microgranulated solid that is pressed against the mold. This provides even heating and heat spreading.
  • FIG. 1 shows a flow chart of an overview of the process used according to the present system
  • FIG. 2 shows a diagram of the molding machine used for molding the low stress polycarbonate lenses
  • FIG. 3 shows the machine used for a normal lens
  • FIG. 4 shows the machine used for a prescription lens.
  • the present system preferably operates starting with a solid polycarbonate resin blank. These blanks are commercially available.
  • the operation follows the flowchart of FIG. 1.
  • the resin blank is first preheated at step 110 .
  • the initial preheating brings the blank to a uniform temperature, which is at a point below the deformation point of the plastic.
  • the surface skin of the polycarbonate resin blank is thereafter further softened at step 112 , by increasing the heating to a point above the glass transition point of the plastic.
  • the preheating brings the blank to approximately 270° F., and the supplemental heating is carried out at 305° F.
  • the polycarbonate's internal temperature can therefore be different than its external temperature at this point.
  • the blank with its softened surfaces are then thermoformed at step 114 . This is done by placing the heated blank in a mold cavity 99 that is defined between two glass molds and a cylindrical dam around the edges. The details of the layout of the structure is shown and described with reference to FIG. 2, herein.
  • thermoforming brings the heated external surfaces of the blank into contact with preheated glass molds.
  • the glass molds have been heated to a higher temperature than the external surface temperature of the blank.
  • An exemplary temperature for the molds is, e.g., 390° F.
  • stress orientation is carried out at step 116 .
  • the pressure is increased, e.g., doubled, preferably to a pressure between 272 and 425 psi.
  • the thermoformed lens is allowed to cool under this higher pressure, until the lens reaches a relatively stable temperature, e.g., 235° F. Then pressure is released to leave the finished lens.
  • the heating and cooling of the molds are preferably carried out using a liquefied solid heat transfer medium, e.g., a non-metallic micro-pulverized solid.
  • the heat transfer medium can be used to exert evenly-distributed high pressure of up to 1350 psi on the glass mold set and holding canisters. This helps avoid undercut from the flow of plastic during the thermoforming procedure.
  • the space between a concave mold and a convex mold forms the molding cavity.
  • the thickness of the lens and rate of the viscous flow of the resin are defined by the variable-sized cylindrical dam.
  • the blank that forms the starting product can be, for example, a solid resin blank prepared by injection molding of polycarbonate plastic. These blanks are commercially available.
  • the resin blank is typically disk shaped, and has two planar surfaces that are substantially parallel to one another.
  • the thickness of the blank should be sufficient to allow sufficient resin volume to completely fill out the mold cavity, and yet should not be too thick so as to provide too much resin loss.
  • the blank is also preferably smaller in diameter than the final lens. For example, an 85 mm lens can be molded from a resin blank of 75 mm in diameter.
  • the solid blank is preheated in a normal oven, to a temperature below the deformation point of the blank. Since the preferred polycarbonate material has a deformation point at 270°, the preferred temperature for preheating is 260°.
  • the blank is uniformly heated, it is transferred to a higher-temperature oven which heats at least part of the blank above the glass transition point of the plastic.
  • the glass transition point of polycarbonate is 305°.
  • a suitable amount of time for the heating surfaces step 112 is, for example, 7 to 9 minutes at 370° F. By this time, it is believed that the blank is not completely heated. That is, the surfaces of the blank are more heated than the inside of the blank.
  • Step 114 represents the thermoforming.
  • the preheated solid blank has softened surfaces.
  • This preheated blank is transferred to the mold cavity described herein, which has glass molds that are preheated to 390° F., slightly higher than the supplemental heating temperature.
  • the heat on the molds is substantially immediately cut off upon the transfer.
  • the pressure on the mold cavity is increased from both the upper and lower side thereof. The pressure increase is substantially such that the pressure on the upper matches the pressure on the lower.
  • Floating canisters are preferably used to balance the load on the top and bottom.
  • the pressure is gradually increased from an initial pressure of about 10 psi, to a final pressure near 100 psi.
  • the resin mass viscously flows in the mold cavity.
  • the lens is stress oriented at step 116 .
  • the stress orienting involves increasing the pressure level, e.g., to double the thermoforming level at the end of the viscous flow. Once reaching this pressure level, cooling starts.
  • the preferred pressure level for stress orienting is between 272 and 425 psi. Whatever upper limit is used, the source of heat is removed after reaching that upper limit, and the lenses are cooled to below their glass transition point, a point below their deformation temperature. The preferable level is 235°. At this point, the finished lens is removed from the mold cavity.
  • the combined cycle of thermoforming and stress orienting takes between 22 and 23 minutes.
  • thermoforming is preferably carried out using glass molds.
  • Prior systems taught away from glass molds e.g., because of the high temperatures and pressures involved.
  • the lower temperatures and pressures of the present system enable the use of glass molds.
  • certain advantages, including excessive shrinking is avoided when such a glass mold is used. The inventor postulated that this is due to the closer thermal expansion coefficient of the glass-polycarbonate system as compared with steel-polycarbonate matches used in the prior art.
  • a liquefied/micropulverized solid medium preferably presses again the glass mold. This also provides an improved controlled heating/cooling transfer technique.
  • Polycarbonate lenses have been produced by this process, and they exhibit excellent geometric curves and optical power, improved dimensional stability, low stress patterns, and superior impact strength. The comparison follows, with lenses produced by the present process being labelled as “stress oriented polycarbonate: Injection Molded Stress Oriented Test Procedures Polycarbonate (1) Polycarbonate (2) Geometric Curves 9 to 23 ⁇ 10 ⁇ 4 in 4 to 5 ⁇ 10 ⁇ 4 in Spherometer Deviation Optical Powers weakening of powers constant powers up to Lensometer Reading toward the edges the edges Internal Stress appreciable stress minimized stress Polaroscope Pattern Impact Strength Surface Hardness (4) 22 to 25 19 to 22 Extreme Impact (5) fracture with tear surface deformation propagation
  • a preferable value for molding a finished ophthalmic lens is between 1.5 to 5 mm in its center.
  • the system formed by the present specification can produce finished polycarbonate ophthalmic lenses that are 0.4 mm or possibly even less thick.
  • Such devices can also have 1.0 mm edges with excellent geometric curves.
  • any central thickness between 1 and 4 mm is preferred according to this process.
  • Higher diopter lenses may require thicker edges relative to the centers. Cylindrical dams, as described herein, define the molding cavity. These higher diopter lenses may require insulation to prevent heat loss at the edges of the lens.
  • FIG. 2 The specific equipment used to carry out the process described above is shown in FIG. 2.
  • This system uses two floating canisters 200 , 202 .
  • the floating canisters are effectively pistons which can be separately controlled.
  • a glass mold 204 is held by the floating canister 200
  • another glass mold 206 is held by the other canister 202 respectively at the end of the floating canister.
  • the glass molds 204 and 206 can hence be moved towards one another and pressurized relative to one another.
  • Cylindrical dam 210 defines the edge of the molding cavity of the lower canister 202 .
  • the cylindrical dam 210 rests on a ledge 212 to hold the molded lens into place.
  • the pressures exerted by respective platform pistons 220 and 222 on the floating convex mold 206 , and the floating concave mold 204 are equal.
  • the thrust cylinders, e.g., 224 transmit the pressure from the associated platform pistons 220 .
  • the walls of the canisters 228 are preferably formed of stainless steel.
  • the thrust cylinders 224 preferably include stainless steel or other heat conducting parts. These walls and cylinders allow transmittance of heat through the conductor material.
  • the pressure plates 234 , 236 are preferably planar plates that are respectively but symmetrically driven by the pressures P 1 and P 2 .
  • the plates press against a liquefied heat conductance medium 240 to press that medium against the molds.
  • the heat conductance medium is micro-pulverized salt, corundum, or another non-metallic, free-flowing solid that has a suitable heat conductance and compressiveness.
  • the material must be held within the chamber between the glass mold 204 and the pressure plate 234 .
  • An O-ring 242 rests between the pressure plate 234 and walls 228 and seals off the edges of the chamber.
  • the top glass mold 204 is held by a holding lip 244 .
  • a lower lip 246 can be provided to hold the lower glass mold in place.
  • the resin mask could be lodged under the holding lips 244 , 246 .
  • the solid medium 240 needs to be pressurized against the glass molds 204 , 206 .
  • a spring is preferably used to maintain this constant pressure.
  • a Bellevue spring 250 may be pre-tensioned into place to provide a constant pressure, e.g., 1350 psi, on the pressure plate 234 .
  • the spring may be held in place relative to the threaded rod 224 , by screwing a screw plate 252 on the threaded rod 224 and threading to the point where it presses against the spring of the floating canisters.
  • the cylindrical dam 210 controls the rate of viscous flow and hence controls the lens thickness.
  • the molding cavity 99 is hence defined by outer surfaces of the glass molds 204 , 206 , and the inner surfaces of cylindrical dam 210 .
  • a cross-section of the cylindrical dam is preferably slanted at approximately 35° in order to facilitate removal of the finally-molded lens.
  • the glass molds 204 , 206 are preferably formed of tempered glass. This improves the resistance of the mold to temperature and pressure.
  • the solid blank is first preheated, and then supplementally heated, as noted above.
  • the blank is placed into the molding cavity 99 .
  • Pressure is substantially equally applied through both the top and bottom platform pistons, 234 , 236 .
  • the pressure applied to the top substantially equals the pressure applied to the bottom. These pressures are applied at equal rate and from opposite directions. Once the lens is thermoformed in this way, pressure is increased, and temperature is decreased. The pressure remains until the lens cools sufficiently to be removed from the mold.
  • the preferred system uses glass molds which are formed from tempered glass for improved operation. While glass molds are preferred, molds of other materials may alternatively be used. Preferable materials for the molds include those materials which have a similar coefficient of expansion and contraction to that of the material being molded. One other preferred material for the mold is nickel. Nickel can be formed electrolytically. Other metals can alternatively be used if the liquefied solid medium can be sufficiently held in heat transfer contact with the canisters 200 , 202 , such that differences in the resulting shrinkage control at the metal-polycarbonate interface can be minimized. Hence, this alternative system can prevents stresses in the molded lens even with a metal mold.
  • edges of the metal molds are preferably adequately tensioned in order to exclude undercutting from the viscous flow of the resin mask.
  • An alternative embodiment accommodates certain prescription lenses, herein Rx lenses, through prisming of the ophthalmic lenses.
  • Prisming represents the act of moving the optical centers of the lens to a non-central location. This is typically necessitated by the anatomy of the wearer of the lenses.
  • Prismed lenses have an optical center which is no longer its geometrical center.
  • Proper geometric centering of commercial lenses can be accomplished using a finished lens blank. The overall size of the lens blank allows the geometric center to be positioned to meet the prescription while cutting and mounting the lens into a selected frame. Prisming needs to be accomplished, however, typically by additional grinding and polishing.
  • FIGS. 3 and 4 show the operation of prisming the thrust cylinder and the cylindrical dam.
  • FIG. 3 shows the thrust cylinder with and without prisming
  • FIG. 4 shows the cylindrical with and without prisming.
  • the molding can be prismed for prescription lenses.
  • One-half of the optical device is tilted relative to the other half, thereby forming a finished polycarbonate lens that does not require grinding and polishing of the lenses.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

A lens molding system which uses glass molds to mold polycarbonate blanks. The blanks are preheated, then additionally surface heated, molded, and cooled under pressure.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a continuation of U.S. application Ser. No. 09/687,264, filed Oct. 12, 2000, which is a continuation of U.S. application Ser. No. 09/257,231, filed Feb. 24, 1999.[0001]
  • BACKGROUND
  • Polycarbonate is a popular material for making ophthalmic lenses. Polycarbonate lenses are often produced by injection and compression molding of liquid resin. The conventional operation causes the lenses to remain with residual stress effects. [0002]
  • These residual stress effects can affect the dimensional stability of the lenses, and lead to other problems. For example, overly-stressed polycarbonate lenses can warp upon storage or wear. The edges of such lenses can have varied optical powers. A phenomena known as cold creep can also cause problems in the lenses. [0003]
  • SUMMARY
  • The presently-described system teaches a new method and apparatus for forming low stress polycarbonate lenses. [0004]
  • The machine and process that is described herein produces finished ophthalmic lenses by simultaneously molding both the concave and convex surfaces of these lenses under controlled pressure and even heating. [0005]
  • A preferred mode presses both top and bottom at the same time, and at substantially the same pressures. [0006]
  • Another mode uses a mold made of glass to match the coefficient of expansion of the mold more closely to the polycarbonate blank. The mold is heated and cooled using a microgranulated solid that is pressed against the mold. This provides even heating and heat spreading.[0007]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • These and other aspects of the invention and embodiments will now be described in detail with respect to the accompanying drawings, in which: [0008]
  • FIG. 1 shows a flow chart of an overview of the process used according to the present system; [0009]
  • FIG. 2 shows a diagram of the molding machine used for molding the low stress polycarbonate lenses; [0010]
  • FIG. 3 shows the machine used for a normal lens; and [0011]
  • FIG. 4 shows the machine used for a prescription lens. [0012]
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • The present system preferably operates starting with a solid polycarbonate resin blank. These blanks are commercially available. The operation follows the flowchart of FIG. 1. The resin blank is first preheated at [0013] step 110. The initial preheating brings the blank to a uniform temperature, which is at a point below the deformation point of the plastic. The surface skin of the polycarbonate resin blank is thereafter further softened at step 112, by increasing the heating to a point above the glass transition point of the plastic. In particularly preferred embodiments, the preheating brings the blank to approximately 270° F., and the supplemental heating is carried out at 305° F. The polycarbonate's internal temperature can therefore be different than its external temperature at this point.
  • The blank with its softened surfaces are then thermoformed at [0014] step 114. This is done by placing the heated blank in a mold cavity 99 that is defined between two glass molds and a cylindrical dam around the edges. The details of the layout of the structure is shown and described with reference to FIG. 2, herein.
  • The thermoforming brings the heated external surfaces of the blank into contact with preheated glass molds. The glass molds have been heated to a higher temperature than the external surface temperature of the blank. An exemplary temperature for the molds is, e.g., 390° F. [0015]
  • These glass molds then press against the blank to effect the thermoforming. The pressing is carried out at relatively low pressures, e.g., between 8½ and 140 psi. A special cylindrical dam is used to control the lens thickness and the resin flow. [0016]
  • After thermoforming, stress orientation is carried out at [0017] step 116. The pressure is increased, e.g., doubled, preferably to a pressure between 272 and 425 psi. The thermoformed lens is allowed to cool under this higher pressure, until the lens reaches a relatively stable temperature, e.g., 235° F. Then pressure is released to leave the finished lens.
  • The heating and cooling of the molds are preferably carried out using a liquefied solid heat transfer medium, e.g., a non-metallic micro-pulverized solid. The heat transfer medium can be used to exert evenly-distributed high pressure of up to 1350 psi on the glass mold set and holding canisters. This helps avoid undercut from the flow of plastic during the thermoforming procedure. [0018]
  • The space between a concave mold and a convex mold forms the molding cavity. The thickness of the lens and rate of the viscous flow of the resin are defined by the variable-sized cylindrical dam. [0019]
  • Describing this in further detail, the blank that forms the starting product can be, for example, a solid resin blank prepared by injection molding of polycarbonate plastic. These blanks are commercially available. The resin blank is typically disk shaped, and has two planar surfaces that are substantially parallel to one another. [0020]
  • The thickness of the blank should be sufficient to allow sufficient resin volume to completely fill out the mold cavity, and yet should not be too thick so as to provide too much resin loss. The blank is also preferably smaller in diameter than the final lens. For example, an 85 mm lens can be molded from a resin blank of 75 mm in diameter. [0021]
  • The solid blank is preheated in a normal oven, to a temperature below the deformation point of the blank. Since the preferred polycarbonate material has a deformation point at 270°, the preferred temperature for preheating is 260°. Once the blank is uniformly heated, it is transferred to a higher-temperature oven which heats at least part of the blank above the glass transition point of the plastic. The glass transition point of polycarbonate is 305°. A suitable amount of time for the [0022] heating surfaces step 112 is, for example, 7 to 9 minutes at 370° F. By this time, it is believed that the blank is not completely heated. That is, the surfaces of the blank are more heated than the inside of the blank.
  • [0023] Step 114 represents the thermoforming. The preheated solid blank has softened surfaces. This preheated blank is transferred to the mold cavity described herein, which has glass molds that are preheated to 390° F., slightly higher than the supplemental heating temperature. The heat on the molds is substantially immediately cut off upon the transfer. The pressure on the mold cavity is increased from both the upper and lower side thereof. The pressure increase is substantially such that the pressure on the upper matches the pressure on the lower. Floating canisters are preferably used to balance the load on the top and bottom.
  • The pressure is gradually increased from an initial pressure of about 10 psi, to a final pressure near 100 psi. During the thermoforming, the resin mass viscously flows in the mold cavity. After the lens thermoforming is finished, the lens is stress oriented at [0024] step 116. The stress orienting involves increasing the pressure level, e.g., to double the thermoforming level at the end of the viscous flow. Once reaching this pressure level, cooling starts. The preferred pressure level for stress orienting is between 272 and 425 psi. Whatever upper limit is used, the source of heat is removed after reaching that upper limit, and the lenses are cooled to below their glass transition point, a point below their deformation temperature. The preferable level is 235°. At this point, the finished lens is removed from the mold cavity. The combined cycle of thermoforming and stress orienting takes between 22 and 23 minutes.
  • The thermoforming is preferably carried out using glass molds. Prior systems taught away from glass molds, e.g., because of the high temperatures and pressures involved. The lower temperatures and pressures of the present system enable the use of glass molds. Moreover, it has been found that certain advantages, including excessive shrinking is avoided when such a glass mold is used. The inventor postulated that this is due to the closer thermal expansion coefficient of the glass-polycarbonate system as compared with steel-polycarbonate matches used in the prior art. [0025]
  • A liquefied/micropulverized solid medium preferably presses again the glass mold. This also provides an improved controlled heating/cooling transfer technique. [0026]
  • Another important feature is that the pressure exerted by the glass mold on the resin mass be even and sustained during the entire cooling period. This causes stress relaxation as well as stress orientation, during the cooling between 320 and 235° F. [0027]
  • Polycarbonate lenses have been produced by this process, and they exhibit excellent geometric curves and optical power, improved dimensional stability, low stress patterns, and superior impact strength. The comparison follows, with lenses produced by the present process being labelled as “stress oriented polycarbonate: [0028]
    Injection Molded Stress Oriented
    Test Procedures Polycarbonate (1) Polycarbonate (2)
    Geometric Curves 9 to 23 × 10−4 in 4 to 5 × 10−4 in
    Spherometer Deviation
    Optical Powers weakening of powers constant powers up to
    Lensometer Reading toward the edges the edges
    Internal Stress appreciable stress minimized stress
    Polaroscope Pattern
    Impact Strength
    Surface Hardness (4) 22 to 25 19 to 22
    Extreme Impact (5) fracture with tear surface deformation
    propagation
  • A preferable value for molding a finished ophthalmic lens is between 1.5 to 5 mm in its center. However, unlike this typical value, the system formed by the present specification can produce finished polycarbonate ophthalmic lenses that are 0.4 mm or possibly even less thick. Such devices can also have 1.0 mm edges with excellent geometric curves. However, any central thickness between 1 and 4 mm is preferred according to this process. [0029]
  • Higher diopter lenses may require thicker edges relative to the centers. Cylindrical dams, as described herein, define the molding cavity. These higher diopter lenses may require insulation to prevent heat loss at the edges of the lens. [0030]
  • The specific equipment used to carry out the process described above is shown in FIG. 2. This system uses two floating [0031] canisters 200, 202. The floating canisters are effectively pistons which can be separately controlled. A glass mold 204 is held by the floating canister 200, and another glass mold 206 is held by the other canister 202 respectively at the end of the floating canister. The glass molds 204 and 206 can hence be moved towards one another and pressurized relative to one another.
  • [0032] Cylindrical dam 210 defines the edge of the molding cavity of the lower canister 202. The cylindrical dam 210 rests on a ledge 212 to hold the molded lens into place.
  • According to a specifically preferred embodiment, the pressures exerted by [0033] respective platform pistons 220 and 222 on the floating convex mold 206, and the floating concave mold 204, are equal. The thrust cylinders, e.g., 224, transmit the pressure from the associated platform pistons 220.
  • The walls of the [0034] canisters 228 are preferably formed of stainless steel. Similarly, the thrust cylinders 224 preferably include stainless steel or other heat conducting parts. These walls and cylinders allow transmittance of heat through the conductor material. The pressure plates 234, 236 are preferably planar plates that are respectively but symmetrically driven by the pressures P1 and P 2.
  • The plates, e.g., [0035] 234, press against a liquefied heat conductance medium 240 to press that medium against the molds. In a most particularly preferred mode, the heat conductance medium is micro-pulverized salt, corundum, or another non-metallic, free-flowing solid that has a suitable heat conductance and compressiveness.
  • The material must be held within the chamber between the [0036] glass mold 204 and the pressure plate 234. An O-ring 242 rests between the pressure plate 234 and walls 228 and seals off the edges of the chamber.
  • The [0037] top glass mold 204 is held by a holding lip 244. A lower lip 246 can be provided to hold the lower glass mold in place. However, while the resin mass is viscously flowing, the resin mask could be lodged under the holding lips 244, 246. In order to avoid this, the solid medium 240 needs to be pressurized against the glass molds 204, 206. A spring is preferably used to maintain this constant pressure. For example, a Bellevue spring 250 may be pre-tensioned into place to provide a constant pressure, e.g., 1350 psi, on the pressure plate 234. The spring may be held in place relative to the threaded rod 224, by screwing a screw plate 252 on the threaded rod 224 and threading to the point where it presses against the spring of the floating canisters.
  • The [0038] cylindrical dam 210 controls the rate of viscous flow and hence controls the lens thickness. The molding cavity 99 is hence defined by outer surfaces of the glass molds 204, 206, and the inner surfaces of cylindrical dam 210. A cross-section of the cylindrical dam is preferably slanted at approximately 35° in order to facilitate removal of the finally-molded lens.
  • The [0039] glass molds 204, 206 are preferably formed of tempered glass. This improves the resistance of the mold to temperature and pressure.
  • In operation, the solid blank is first preheated, and then supplementally heated, as noted above. The blank is placed into the molding cavity [0040] 99. Pressure is substantially equally applied through both the top and bottom platform pistons, 234, 236. The pressure applied to the top substantially equals the pressure applied to the bottom. These pressures are applied at equal rate and from opposite directions. Once the lens is thermoformed in this way, pressure is increased, and temperature is decreased. The pressure remains until the lens cools sufficiently to be removed from the mold.
  • The preferred system uses glass molds which are formed from tempered glass for improved operation. While glass molds are preferred, molds of other materials may alternatively be used. Preferable materials for the molds include those materials which have a similar coefficient of expansion and contraction to that of the material being molded. One other preferred material for the mold is nickel. Nickel can be formed electrolytically. Other metals can alternatively be used if the liquefied solid medium can be sufficiently held in heat transfer contact with the [0041] canisters 200, 202, such that differences in the resulting shrinkage control at the metal-polycarbonate interface can be minimized. Hence, this alternative system can prevents stresses in the molded lens even with a metal mold.
  • The edges of the metal molds are preferably adequately tensioned in order to exclude undercutting from the viscous flow of the resin mask. [0042]
  • An alternative embodiment accommodates certain prescription lenses, herein Rx lenses, through prisming of the ophthalmic lenses. Prisming represents the act of moving the optical centers of the lens to a non-central location. This is typically necessitated by the anatomy of the wearer of the lenses. Prismed lenses have an optical center which is no longer its geometrical center. Proper geometric centering of commercial lenses can be accomplished using a finished lens blank. The overall size of the lens blank allows the geometric center to be positioned to meet the prescription while cutting and mounting the lens into a selected frame. Prisming needs to be accomplished, however, typically by additional grinding and polishing. [0043]
  • The preferred system of this embodiment can accommodate additional prisming by changing the position of the thrust cylinder. FIGS. 3 and 4 show the operation of prisming the thrust cylinder and the cylindrical dam. FIG. 3 shows the thrust cylinder with and without prisming, and FIG. 4 shows the cylindrical with and without prisming. The molding can be prismed for prescription lenses. One-half of the optical device is tilted relative to the other half, thereby forming a finished polycarbonate lens that does not require grinding and polishing of the lenses. [0044]
  • Although only a few embodiments have been described in detail above, those of skill in the art recognize that many modifications are intended and predictable from the disclosed embodiments. For example, [0045]
  • All such modifications are intended to be encompassed within the following claims. [0046]

Claims (1)

What is claimed is:
1. A device and/or method substantially as shown and described.
US10/368,731 1999-02-24 2003-02-18 Compression molding of optical lenses Abandoned US20030146526A1 (en)

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US10/368,731 US20030146526A1 (en) 1999-02-24 2003-02-18 Compression molding of optical lenses

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KR20020011367A (en) 2002-02-08
CN1345267A (en) 2002-04-17

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