US20030124845A1 - Local interconnect structures and methods for making the same - Google Patents
Local interconnect structures and methods for making the same Download PDFInfo
- Publication number
- US20030124845A1 US20030124845A1 US10/326,716 US32671602A US2003124845A1 US 20030124845 A1 US20030124845 A1 US 20030124845A1 US 32671602 A US32671602 A US 32671602A US 2003124845 A1 US2003124845 A1 US 2003124845A1
- Authority
- US
- United States
- Prior art keywords
- silicon source
- source layer
- forming
- layer
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 81
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 168
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 168
- 239000010703 silicon Substances 0.000 claims abstract description 168
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims abstract description 99
- 229910021332 silicide Inorganic materials 0.000 claims abstract description 97
- 239000003870 refractory metal Substances 0.000 claims abstract description 78
- 239000000758 substrate Substances 0.000 claims abstract description 77
- 239000000463 material Substances 0.000 claims abstract description 35
- 238000000151 deposition Methods 0.000 claims abstract description 30
- 239000004020 conductor Substances 0.000 claims abstract description 27
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 22
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 19
- 229920005591 polysilicon Polymers 0.000 claims abstract description 17
- 238000000137 annealing Methods 0.000 claims abstract 4
- 229910052751 metal Inorganic materials 0.000 claims description 31
- 239000002184 metal Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 22
- 239000010936 titanium Substances 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 238000002161 passivation Methods 0.000 claims description 17
- 239000010941 cobalt Substances 0.000 claims description 13
- 229910017052 cobalt Inorganic materials 0.000 claims description 13
- 239000004065 semiconductor Substances 0.000 claims description 13
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 239000010409 thin film Substances 0.000 claims description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- -1 cobalt nitride Chemical class 0.000 claims description 8
- 229910020776 SixNy Inorganic materials 0.000 claims description 7
- 206010010144 Completed suicide Diseases 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- 238000000059 patterning Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 12
- 239000010410 layer Substances 0.000 description 92
- 238000002955 isolation Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 125000006850 spacer group Chemical group 0.000 description 9
- 235000012431 wafers Nutrition 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
- 239000011810 insulating material Substances 0.000 description 5
- 150000004767 nitrides Chemical class 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000005380 borophosphosilicate glass Substances 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 239000005360 phosphosilicate glass Substances 0.000 description 4
- 238000005498 polishing Methods 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910021341 titanium silicide Inorganic materials 0.000 description 3
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 229910008486 TiSix Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 229910021344 molybdenum silicide Inorganic materials 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 229910052594 sapphire Inorganic materials 0.000 description 2
- 239000010980 sapphire Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 description 1
- 150000001793 charged compounds Chemical class 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 description 1
- 229910021342 tungsten silicide Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/32051—Deposition of metallic or metal-silicide layers
- H01L21/32053—Deposition of metallic or metal-silicide layers of metal-silicide layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28512—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
- H01L21/28518—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table the conductive layers comprising silicides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76895—Local interconnects; Local pads, as exemplified by patent document EP0896365
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Definitions
- the present invention relates to local interconnect structures in an integrated circuit, and methods for making the same.
- a continuing trend in semiconductor technology is to build integrated circuits with more and faster semiconductor devices.
- the drive toward this ultra large-scale integration has resulted in a continued shrinking of device and circuit features.
- Ultra-large scale integrated circuit technology includes the formation of isolated semiconductor devices formed within the surface of silicon wafers and interconnecting these devices with wiring layers above the surface.
- the interconnection system typically consists of two or more levels of interconnection metallurgy, separated by insulation layers.
- the first level of interconnection is used to define small fundamental circuits, e.g., a basic CMOS inverter requiring that the gates on NMOS and PMOS devices are connected together.
- Memory cells such as 6T SRAM, in particular, require several such local interconnections.
- a local interconnect is typically used within an integrated circuit to provide an electrical connection between two or more conducting or semiconducting regions (e.g., active regions of one or more devices). More specifically, local interconnects are routing-restricted interconnect levels used for the short metallization runs, such as those that locally interconnect gates and drains in NMOS and CMOS circuits and those that connect a given metallization layer to a particular structure within the integrated circuit.
- Local interconnects are typically formed of low resistance material, such as a conductor or a doped semiconductor that is formed to electrically couple selected regions.
- a commonly used technique for forming local interconnects is the Damascene process. In this process a first metal is inlaid into a dielectric layer. This involves first depositing the dielectric layer and then polishing via chemical mechanical polishing (CMP) to make the layer planar. The structure is then patterned and etched to form recessed trenches in the dielectric layer where conductive metal lines are to be deposited. Contact to the underlying devices is made where the trenches pass over the active device regions; elsewhere the dielectric layer insulates the metal from the substrate.
- CMP chemical mechanical polishing
- a sandwich structure of titanium (Ti), titanium nitride (TiN), and tungsten is next deposited in the trench and onto the dielectric surface.
- a second CMP is then used to remove the conductive materials from the dielectric surface, leaving metal in the trench.
- the CMP step is followed by a next level of interlevel dielectric (ILD) deposition, contact patterning and etching, and a filling with a conductive metal. Due to time and associated costs, it is undesirable to require two CMP processes to form a local interconnect structure.
- ILD interlevel dielectric
- this process allows formation of self-aligned local interconnects.
- titanium that does not overly the polysilicon source layer nonetheless typically leaches silicon (i.e., reacts with free silicon) from those portions of the polysilicon source layer that are adjacent the titanium resulting in the formation of stringers. Stringers cause electrical shorting between devices.
- the present invention provides local interconnect structures that are free of stringers.
- the present invention also provides methods for making such local interconnect structures wherein the methods do not require two or more CMP processing steps. Because local interconnect structures form electrical connections of relatively short distances (typically about 0.5 ⁇ m to about 10 ⁇ m), the material forming the local interconnects need not possess a low resistance value (as compared to materials forming electrical interconnections of greater distances (i.e., typically distances greater than 10 ⁇ m)). Accordingly, materials other than polycrystalline silicon are used in the present invention to form a silicon source layer for fabrication of local interconnect structures.
- the present invention provides methods for forming a local interconnect structures for integrated circuits.
- a substrate having a surface and including at least one topographical structure thereon (such that a region of the surface of the substrate is exposed) is provided.
- An active area is preferably formed in the substrate prior to formation of the topographical structure.
- a thin silicon source layer is then deposited over at least a portion of the active area.
- the silicon source layer preferably comprises silicon rich silicon nitride, silicon oxynitride or other silicon source having sufficient free silicon to form a silicide but not so much free silicon as to result in formation of stringers (as occurs with the use of polysilicon).
- a silicide forming material such as a refractory metal, is deposited directly upon selected regions of the silicon source layer and over the topographical structure.
- the structure is then preferably annealed to form a silicide layer from the refractory metal and silicon source layer.
- the silicide layer creates a portion of the local interconnect structure.
- Remaining non-reacted silicide forming material e.g., regions of the silicon source layer not in direct, intimate contact with the silicide forming material
- an interlevel dielectric is deposited over the suicide layer.
- the interlevel dielectric includes at least one recess defined substantially over the active area. An electrically conductive material is deposited in the recess to complete the local interconnect structure.
- a method of forming a local interconnect structure for an integrated circuit wherein a silicide forming material, e.g., a refractory metal, is deposited prior to deposition of a silicon source layer.
- the silicon source layer preferably comprises silicon rich silicon nitride, silicon oxynitride or other silicon source having sufficient free silicon to form a silicide but not so much free silicon as to result in formation of stringers.
- the silicon source layer is deposited over the refractory metal and is patterned and etched to form a hard mask. The remainder of the method is essentially identical to the representative embodiment set forth above.
- a representative embodiment of the local interconnect structure preferably includes a substrate having at least one topographical structure, such as a gate stack. At least one active area is adjacent to the topographical structure. Silicon source overlays a portion of the substrate and a portion of the topographical structure. A suicide layer covers at least a portion of the active area and extends over a portion of the topographical structure thereby forming a portion of the local interconnect structure. An oxide layer preferably overlays the silicon source but not the silicide layer. A passivation layer covers the oxide layer and the silicide layer. The passivation layer includes at least one recess that extends through the passivation layer and terminates substantially at the active area. An electrically conductive material substantially fills the recess to form an electrical contact with the silicide layer and the active area.
- FIGS. 1 a - 1 e show, in cross-section, a method of manufacture and a resulting local interconnect structure according to an embodiment of the present invention.
- FIG. 2 is a process flow diagram of the method shown in FIGS. 1 a - 1 e.
- FIG. 3 is a cross-sectional view of an embodiment of the local interconnect structure of the present invention.
- FIGS. 4 a - 4 f show, in cross-section, another method of manufacture and a resulting local interconnect structure according to another embodiment of the present invention.
- FIG. 5 is a process flow diagram of the method shown in FIGS. 4 a - 4 f.
- FIG. 6 is a cross-sectional view of another embodiment of the local interconnect structure of the present invention.
- FIGS. 1 a - 1 e and FIG. 2 A first method of manufacture of an embodiment of a local interconnect structure according to the present invention is described with reference to FIGS. 1 a - 1 e and FIG. 2.
- the present invention is described primarily with reference to transistors as forming a part of the local interconnect structure, it should be understood that the local interconnect structures and manufacturing methods of the present invention apply equally well to any semiconductor device or integrated circuit requiring one or more local interconnects.
- one application of the local interconnect structure of the present invention may be the formation of electrical interconnection between a transistor gate stack and a contact to an adjacent active area in a semiconductor substrate.
- FIG. 1 a illustrates a typical beginning structure for making a local interconnection structure 10 (FIG. 3) of the present invention.
- the beginning structure may include a semiconductor or wafer substrate 18 with at least one active region 14 defined in the substrate 18 .
- the substrate 18 may comprise silicon, gallium arsenide, glass, an insulating material such as sapphire, or any other substrate material upon which an integrated circuit wafer may be fabricated.
- Active regions 14 are typically formed by doping specific portions of the wafer substrate 18 by conventional methods, such as ion implantion or diffusion.
- a field oxide or isolation region 20 is formed in the substrate 18 .
- the field oxide or isolation region 20 may be formed by conventional means known to persons skilled in the art, such as by local oxidation of a silicon substrate or isolation diffusion of the substrate 18 . Isolation region 20 forms p-n junctions that separate areas of the substrate 18 . In other words, the isolation region 20 , in part, serves the function of a dielectric to electrically isolate regions of the substrate 18 .
- Gate stack 25 may comprise a gate oxide 22 having a transistor gate 24 that typically comprises a polysilicon layer. Overlying the transistor gate 24 may be a metal silicide layer 28 (or some other conductor layer).
- the refractory metal silicide 24 of the gate stack 25 typically comprises any refractory metal silicide including but not limited to titanium, cobalt, tungsten, tantalum, or molybdenum silicides.
- Each gate stack 25 may include one or more spacers 32 .
- Spacers 32 are typically oriented perpendicular to the substrate 18 on either side of the gate stack 25 . Spacers 32 may be formed by subjecting a layer of silicon nitride (not shown) deposited over the gate stack 25 to an anisotropic etch (a technique well known to persons skilled in the art). Alternatively, spacers 32 may be made of undoped silicon dioxide.
- a selected portion of the cap 36 may be removed (e.g., by dry etch) to allow access to the transistor gate 24 via the metal silicide layer 28 .
- the cap 36 may be initially deposited such that a portion of the metal silicide layer 28 is exposed to allow access to the transistor gate 24 .
- Silicon source layer 42 is deposited uniformly over the structure.
- Silicon source layer 42 preferably comprises silicon-rich silicon nitride or silicon oxynitride.
- Silicon-rich silicon nitride may be deposited by any method, but is preferably deposited by LPCVD.
- silicon oxynitride may be deposited as a silicon source layer 42 by any method, but is preferably deposited by PECVD using a reactant gas mixture of silane, nitrous oxide, ammonia, and nitrogen.
- the silicon source layer 42 preferably has a thickness of from about 150 ⁇ to about 400 ⁇ and more preferably from about 150 ⁇ to about 200 ⁇ .
- Stoichiometric silicon is Si 3 N 4 .
- stoichiometric means that the composition is such that the ratio of elements forms a neutrally charged compound.
- Silicon-rich silicon nitride and silicon oxynitride are examples of nonstoichiometric materials. It is preferable that the silicon source layer 42 have sufficient silicon concentration to form the necessary silicide (i.e., so that the silicide is sufficiently electrically conductive) but not too much silicon as to cause stringer formation during the silicide process.
- the approximate stoichiometries for the silicon-rich silicon nitride or silicon oxynitride are preferably equal to Si x N y O z wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
- a thin film 44 is uniformly deposited over the silicon source layer 42 .
- Thin film 44 will be selectively removed to form a hard mask 46 as shown in FIG. 1 c (discussed below).
- Thin film 44 may comprise any suitable insulating material that is not rich in silicon (i.e., without free silicon).
- Thin film 44 preferably comprises TEOS, Si 3 N 4 or silicon oxynitride rich in oxygen and may be deposited by any suitable manner, such as by CVD.
- Thin film 44 preferably has a thickness of from about 200 ⁇ to about 400 ⁇ .
- the thin film 44 is patterned such that portions of thin film 44 are exposed for removal to form hard mask 46 .
- Patterned thin film 44 is etched using conventional etching techniques.
- Hard mask 46 assists in the selective removal of material during later etching processes (discussed below) and defines the local interconnect.
- the hard mask 46 is formed by etching the patterned thin film 44 , portions of the silicon source layer 42 are left exposed.
- the hard mask 46 only covers portions of the silicon source layer 42 where local interconnects will not be formed and exposes portions of silicon source layer 42 where local interconnects are to be formed.
- a uniform layer of a refractory metal 48 (or other electrically conductive, preferably silicide-forming material) is deposited on the hard mask 46 and on the exposed portions of the silicon source layer 42 .
- Refractory metal 48 may be sputter deposited or may be deposited by any other suitable method.
- Refractory metal 48 preferably comprises titanium, titanium nitride (Ti x N y , wherein y is from about 0.01 to about 0.15), cobalt, or colbalt nitride.
- Refractory metal 48 is preferably deposited at a thickness of from about 300 ⁇ to about 500 ⁇ . The resulting structure is then annealed such that a metal silicide is formed.
- the structure as shown in FIG. 1 c is preferably annealed using rapid thermal processing (RTP) in an N 2 /NH 3 atmosphere at a temperature of from about 700° C. to about 850° C., and more preferably from about 700° C. to about 750° C.
- RTP rapid thermal processing
- refractory metal 48 that is in intimate, direct contact with the exposed portions of the silicon source layer 42 .form metal silicide regions 52 (as shown in FIG. 1 d ).
- the portions of the silicon source layer 42 underlying the hard mask 46 do not react to form a silicide compound (but remain as silicon source layer material).
- the portions of refractory metal 48 overlying the hard mask 46 do not react to form a silicide compound.
- titanium nitride (wherein the titanium nitride is Ti x N y , y being equal to from about 0.01 to about 0.15) is deposited as refractory metal 48 , those portions of the Ti x N y layer in contact with the silicon source layer 42 will react during the anneal process to form a titanium silicide (e.g., TiSi x N y ). Thus metal silicide regions 52 are formed only in those areas where the local interconnects are to be formed.
- non-reacted refractory metal 48 is then removed from hard mask 46 using an etchant that is selective to the particular metal silicide.
- an etchant that is selective to titanium silicide.
- non-reacted refractory metal 48 is preferably removed using a wet etch process, such as an etchant mixture comprising NH 4 OH/H 2 O 2 /H 2 O (at a ratio of about 0.5:0.5:1).
- a preferred etchant may comprise HNO 3 /H 2 O 2 /H 2 O (at a ratio of about 0.5:0.5:1).
- Such an etchant mixture is selective to cobalt silicide.
- the remaining silicon source layer 42 need not be removed as it is not a conductive material.
- the hard mask 46 need not be removed. In some devices, it is preferable to have the hard mask 46 remain, as the hard mask may act as a protective layer for the active areas of the device.
- ILD 56 is deposited over hard mask 46 and metal silicide regions 52 .
- ILD 56 is typically a silica substantially comprising materials selected from a group consisting of silicon dioxide, borophosphosilicate glass (BPSG), phosphosilicate glass (PSG), doped or undoped oxides, and mixtures thereof.
- BPSG borophosphosilicate glass
- PSG phosphosilicate glass
- CMP chemical mechanical polishing
- a recess 60 is then patterned on the ILD 56 and the ILD is removed as illustrated by phantom lines in FIG. 1 e .
- Recess 60 i.e., an electrical contact hole
- “generally aligned with a selected active area” is intended to mean positioned substantially perpendicular to a location where the active area 14 is situated within the substrate 18 .
- multiple recesses may be formed in the passivation layer to form electrical connection to a selected active area 14 .
- the etchant used to remove selected portions of ILD 56 to form recess 60 may be isotropic or anisotropic, but is preferably selective to the metal silicide 52 .
- a typical etchant comprises CHF 3 , CF 4 , Ar, or a mixture thereof.
- Electrical contact 64 typically comprises suitable electrically conductive materials, such as aluminum, copper, tungsten, or other suitable conductor materials.
- the local interconnect structure 10 made according to the above-described method comprises a substrate 18 having active areas 14 and isolation region 20 formed therein. Topographical sub-structures, such as gate stacks 25 for formation of MOSFETs, are included according to the specific needs of the ultimate device to be made (e.g., a memory device).
- the local interconnect structure 10 of the present invention further includes metal silicide regions 52 forming electrical connecting portions of the local interconnects. Non-conductive silicon source layer portions 42 are located immediately adjacent the metal silicide regions 52 .
- Hard mask 46 covers the silicon source layer portions 42 and ILD 56 covers the hard mask 46 and metal silicide regions 52 with the exception of those metal silicide regions located directly above active areas 14 at the electrical contact 64 . Electrical contact 64 extends from the uppermost surface 68 of the local interconnect structure 10 to the metal silicide region 52 overlying the active area 14 .
- Local interconnect structure 10 (as shown in FIG. 3) of the present invention is complete. Local interconnect structure 10 of the present invention may now undergo conventional processing depending upon specific needs, such as further processing to form a memory device.
- FIG. 6 Another method of manufacture of another embodiment of the local interconnect structure 110 (as shown in FIG. 6) of the present invention is described with reference to FIGS. 4 a - 4 f and FIG. 5.
- a semiconductor or wafer substrate 118 includes one or more active regions 114 defined in the substrate.
- the substrate 118 may comprise silicon, gallium arsenide, glass, an insulating material such as sapphire, or any other substrate material upon which an integrated circuit wafer may be fabricated.
- Active regions 114 are typically formed by doping specific portions of the substrate 118 , as described above.
- One or more field oxide or isolation regions 120 are formed in the substrate 118 , also as described above with reference to the first method.
- Gate stack 125 may comprise a gate oxide 122 having a transistor gate 124 , typically comprising a polysilicon layer.
- a conductive layer 128 Overlying the transistor gate 124 is a conductive layer 128 , e.g., a refractory metal silicide layer.
- the conductive layer 128 typically comprises a refractory metal silicide including but not limited to titanium, tungsten, tantalum, or molybdenum silicide, e.g., tungsten silicide (WSi x ).
- Insulating cap 136 typically comprises an oxide or nitride such as a tetraethoxysilane (TEOS) oxide layer.
- TEOS tetraethoxysilane
- Each gate stack 125 may include one or more spacers 132 formed immediately adjacent the stacks, as described above and as shown in FIG. 4 a and FIG. 6.
- a selected portion of the cap 136 may be removed (e.g., by dry etch) to allow access to the transistor gate 124 via the conductive layer 128 .
- the cap 136 may be initially deposited such that a portion of the conductive layer 128 is exposed to allow access to the transistor gate 124 .
- a uniform layer of a refractory metal 148 (or other material capable of forming a silicide) is deposited over exposed portions of substrate 118 , exposed portions of isolation regions 120 , spacers 132 , and caps 136 .
- the refractory metal 148 may be sputter deposited or may be deposited by any other suitable method.
- the refractory metal 148 preferably comprises titanium, titanium nitride (Ti x N y ), cobalt, or colbalt nitride.
- the refractory metal 148 is preferably deposited at a thickness of from about 300 ⁇ to about 500 ⁇ .
- Silicon source layer 142 is deposited uniformly over the refractory metal 148 .
- Silicon source layer 142 preferably comprises a silicon-rich silicon nitride film or a silicon oxynitride film (each compound having stoichiometries substantially as described above in reference to the embodiment shown in FIGS. 1 b - 1 e ).
- Silicon source layer 142 should have sufficient free silicon concentration to form the necessary silicide (i.e., so that the silicide is sufficiently electrically conductive) but not so much free silicon as to cause stringer formation during the silicide process (such as occurs when using polysilicon).
- Silicon-rich silicon nitride or silicon oxynitride may be deposited as described above in relation to the first embodiment or by any other suitable deposition techniques as known to persons skilled in the art.
- the silicon source layer 142 preferably has a thickness of from about 150 ⁇ to about 400 ⁇ and more preferably from about 150 ⁇ to about 200 ⁇ .
- Silicon source layer 142 is patterned and selectively removed (as shown in FIG. 4 c ) to form partial source layer 146 . That is, silicon source layer 142 is patterned such that removal of portions of the source layer forms partial source layer 146 (i.e., a hard mask), which in turn defines the location(s) of the local interconnect. Referring to FIG. 4 c , the portions of silicon source layer 142 that are then removed are those portions where local interconnection is not needed.
- the selected portions of the silicon source layer 142 may he removed using conventional etchants and etch methods, but are preferably removed using an etchant that is selective to the refractory metal 148 (e.g., by dry etch).
- the structure as shown in FIG. 4 d is preferably annealed using RTP in an N 2 /NH 3 atmosphere at a temperature of from about 700° C. to about 850° C., and more preferably at from about 700° C. to about 750° C.
- refractory metal 148 in contact with the partial source layer 146 form metal silicide regions 152 (as shown in FIG. 4 e ).
- the portions of the exposed refractory metal 148 do not form a silicide compound (i.e., remain as refractory metal and refractory metal nitride) except those portions in direct contact with the silicon substrate 118 (i.e., at the active areas and local interconnect areas).
- titanium x N y is deposited as refractory metal 148 , those portions of the titanium or titanium nitride layer in intimate and direct contact with the partial source layer 146 will form a titanium suicide (e.g., TiSi x N y ) while those portions not directly in contact with partial source layer 146 will remain as titanium or titanium nitride.
- metal silicide regions 152 are formed only in those areas in which the local interconnects are to be formed.
- non-reacted refractory metal 148 is then etched from the structure.
- the etchant used is selective to the materials comprising exposed portions of the topographical structures (i.e., spacers 132 , cap 136 , isolation regions 120 , and substrate 118 ).
- An oxide cap 170 is deposited uniformly over exposed portions of the topographical structures (i.e., spacers 132 , cap 136 , isolation regions 120 , and substrate 118 ) and over metal silicide regions 152 .
- Oxide cap 170 may comprise a layer of oxide that provides a protective cap and is preferably from about 300 ⁇ to about 400 ⁇ in thickness.
- ILD 156 typically comprises a silica substantially comprising materials selected from a group consisting of silicon dioxide, borophosphosilicate glass (BPSG), phosphosilicate glass (PSG), doped or undoped oxides, and mixtures thereof, although other passivation materials may be used.
- BPSG borophosphosilicate glass
- PSG phosphosilicate glass
- doped or undoped oxides and mixtures thereof, although other passivation materials may be used.
- CMP a suitable process
- the structure may be annealed at a temperature of about 750° C. to about 900° C. to reflow ILD 156 , resulting in a relatively smooth top layer.
- a recess 160 is then patterned on ILD 156 and the selected portion of ILD 156 is removed as illustrated by phantom lines in FIG. 4 f .
- Recess 160 i.e., contact hole
- ILD 156 adjacent to gate stack 125 and is generally aligned with one or more selected active areas 114 . That is, although only a single recess 160 is illustrated in FIG. 4 f , multiple recesses may be formed in ILD 156 to form electrical connection to multiple selected active areas 114 .
- the etchant used to remove selected portions of ILD 156 to form recess 160 may be isotropic or anisotropic but is preferably selective to the exposed portions of the structure described above.
- a typical etchant comprises CHF 3 , CHF 4 , or a mixture thereof.
- Electrical contact 164 typically comprises an electrically conductive material, such as aluminum, copper, tungsten, or any other suitable conductor materials.
- the local interconnect structure 110 made according to the above-described method comprises a substrate 118 having active areas 114 and isolation regions 120 formed therein. Topographical substructures, such as gate stacks 125 of MOSFETs, are included according to the specific needs for the ultimate device to be made (e.g., a memory device).
- the local interconnect structure 110 of the present invention further includes metal silicide regions 152 forming electrical connecting portions of the local interconnects.
- Oxide cap 170 covers metal silicide regions 152 and the exposed portions of spacers 132 , cap 136 , isolation region 120 , and substrate 118 . Electrical contact 164 extends from the uppermost portion 168 of the local interconnect structure 110 to the metal silicide region 152 overlying the selected active area 114 .
- Local interconnect structure 110 (as shown in FIG. 6) of the present invention is complete. Local interconnect structure 110 of the present invention may now undergo conventional processing depending upon specific needs, such as further processing to form a memory device.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Abstract
The present invention provides methods of forming local interconnect structures for integrated circuits. A representative embodiment includes depositing a silicon source layer over a substrate having at least one topographical structure thereon. The silicon source layer preferably comprising silicon rich silicon nitride, silicon oxynitride or other silicon source having sufficient free silicon to form a silicide but not so much free silicon as to result in formation of stringers (i.e., does not comprise polysilicon). The silicon source layer is preferably deposited over an active area in the substrate and at least a portion of the topographical structure. A silicide forming material, e.g., a refractory metal, is deposited directly on selected regions of the silicon source layer and over the topographical structure. A silicide layer is made from the silicide forming material and the silicon source layer preferably by annealing the structure. The silicide layer defines a portion of the local interconnect structure, unreacted silicide forming material is removed and an interlevel dielectric is formed over the silicide layer. The interlevel dielectric includes a recess defined substantially over the active area and an electrically conductive material is deposited in the recess. The present invention also provides local interconnect structures.
Description
- The present invention relates to local interconnect structures in an integrated circuit, and methods for making the same.
- A continuing trend in semiconductor technology is to build integrated circuits with more and faster semiconductor devices. The drive toward this ultra large-scale integration has resulted in a continued shrinking of device and circuit features. To take advantage of an increasing number of devices and to form the devices into one or more circuits, the various devices must be interconnected.
- Ultra-large scale integrated circuit technology includes the formation of isolated semiconductor devices formed within the surface of silicon wafers and interconnecting these devices with wiring layers above the surface. The interconnection system typically consists of two or more levels of interconnection metallurgy, separated by insulation layers. The first level of interconnection is used to define small fundamental circuits, e.g., a basic CMOS inverter requiring that the gates on NMOS and PMOS devices are connected together. Memory cells such as 6T SRAM, in particular, require several such local interconnections.
- To accomplish interconnection on such a small scale, a local interconnect is typically used within an integrated circuit to provide an electrical connection between two or more conducting or semiconducting regions (e.g., active regions of one or more devices). More specifically, local interconnects are routing-restricted interconnect levels used for the short metallization runs, such as those that locally interconnect gates and drains in NMOS and CMOS circuits and those that connect a given metallization layer to a particular structure within the integrated circuit.
- Local interconnects are typically formed of low resistance material, such as a conductor or a doped semiconductor that is formed to electrically couple selected regions. A commonly used technique for forming local interconnects is the Damascene process. In this process a first metal is inlaid into a dielectric layer. This involves first depositing the dielectric layer and then polishing via chemical mechanical polishing (CMP) to make the layer planar. The structure is then patterned and etched to form recessed trenches in the dielectric layer where conductive metal lines are to be deposited. Contact to the underlying devices is made where the trenches pass over the active device regions; elsewhere the dielectric layer insulates the metal from the substrate. Generally, a sandwich structure of titanium (Ti), titanium nitride (TiN), and tungsten is next deposited in the trench and onto the dielectric surface. A second CMP is then used to remove the conductive materials from the dielectric surface, leaving metal in the trench. The CMP step is followed by a next level of interlevel dielectric (ILD) deposition, contact patterning and etching, and a filling with a conductive metal. Due to time and associated costs, it is undesirable to require two CMP processes to form a local interconnect structure.
- Other methods for forming local interconnects have been used in effort to avoid the multiple CMP processing steps required by the Damascene technique. Such methods use a polycrystalline silicon (polysilicon) layer as a silicon source layer. Typically, titanium (or titanium nitride, TixNy, wherein y is less than about 0.12) is deposited over a device. Polysilicon is then deposited as a uniform layer over the titanium. An interconnect pattern is formed thereon and portions of the polysilicon layer are removed. The device is then annealed so that the titanium in contact with the polysilicon forms a titanium silicide. The remaining titanium (that did not react with the polysilicon) is removed. Theoretically, this process allows formation of self-aligned local interconnects. In practice, however, titanium that does not overly the polysilicon source layer nonetheless typically leaches silicon (i.e., reacts with free silicon) from those portions of the polysilicon source layer that are adjacent the titanium resulting in the formation of stringers. Stringers cause electrical shorting between devices.
- To overcome the deficiencies in the prior art, the present invention provides local interconnect structures that are free of stringers. The present invention also provides methods for making such local interconnect structures wherein the methods do not require two or more CMP processing steps. Because local interconnect structures form electrical connections of relatively short distances (typically about 0.5 μm to about 10 μm), the material forming the local interconnects need not possess a low resistance value (as compared to materials forming electrical interconnections of greater distances (i.e., typically distances greater than 10 μm)). Accordingly, materials other than polycrystalline silicon are used in the present invention to form a silicon source layer for fabrication of local interconnect structures.
- The present invention provides methods for forming a local interconnect structures for integrated circuits. In a representative method, a substrate having a surface and including at least one topographical structure thereon (such that a region of the surface of the substrate is exposed) is provided. An active area is preferably formed in the substrate prior to formation of the topographical structure. A thin silicon source layer is then deposited over at least a portion of the active area. The silicon source layer preferably comprises silicon rich silicon nitride, silicon oxynitride or other silicon source having sufficient free silicon to form a silicide but not so much free silicon as to result in formation of stringers (as occurs with the use of polysilicon). A silicide forming material, such as a refractory metal, is deposited directly upon selected regions of the silicon source layer and over the topographical structure. The structure is then preferably annealed to form a silicide layer from the refractory metal and silicon source layer. The silicide layer creates a portion of the local interconnect structure. Remaining non-reacted silicide forming material (e.g., regions of the silicon source layer not in direct, intimate contact with the silicide forming material) is removed and an interlevel dielectric is deposited over the suicide layer. The interlevel dielectric includes at least one recess defined substantially over the active area. An electrically conductive material is deposited in the recess to complete the local interconnect structure.
- According to another representative embodiment a method of forming a local interconnect structure for an integrated circuit is provided wherein a silicide forming material, e.g., a refractory metal, is deposited prior to deposition of a silicon source layer. The silicon source layer preferably comprises silicon rich silicon nitride, silicon oxynitride or other silicon source having sufficient free silicon to form a silicide but not so much free silicon as to result in formation of stringers. The silicon source layer is deposited over the refractory metal and is patterned and etched to form a hard mask. The remainder of the method is essentially identical to the representative embodiment set forth above.
- According to another aspect of the present invention, local interconnect structures are provided. A representative embodiment of the local interconnect structure preferably includes a substrate having at least one topographical structure, such as a gate stack. At least one active area is adjacent to the topographical structure. Silicon source overlays a portion of the substrate and a portion of the topographical structure. A suicide layer covers at least a portion of the active area and extends over a portion of the topographical structure thereby forming a portion of the local interconnect structure. An oxide layer preferably overlays the silicon source but not the silicide layer. A passivation layer covers the oxide layer and the silicide layer. The passivation layer includes at least one recess that extends through the passivation layer and terminates substantially at the active area. An electrically conductive material substantially fills the recess to form an electrical contact with the silicide layer and the active area.
- FIGS. 1a-1 e show, in cross-section, a method of manufacture and a resulting local interconnect structure according to an embodiment of the present invention.
- FIG. 2 is a process flow diagram of the method shown in FIGS. 1a-1 e.
- FIG. 3 is a cross-sectional view of an embodiment of the local interconnect structure of the present invention.
- FIGS. 4a-4 f show, in cross-section, another method of manufacture and a resulting local interconnect structure according to another embodiment of the present invention.
- FIG. 5 is a process flow diagram of the method shown in FIGS. 4a-4 f.
- FIG. 6 is a cross-sectional view of another embodiment of the local interconnect structure of the present invention.
- A first method of manufacture of an embodiment of a local interconnect structure according to the present invention is described with reference to FIGS. 1a-1 e and FIG. 2.
- Although the present invention is described primarily with reference to transistors as forming a part of the local interconnect structure, it should be understood that the local interconnect structures and manufacturing methods of the present invention apply equally well to any semiconductor device or integrated circuit requiring one or more local interconnects. For example, one application of the local interconnect structure of the present invention may be the formation of electrical interconnection between a transistor gate stack and a contact to an adjacent active area in a semiconductor substrate.
- FIG. 1a illustrates a typical beginning structure for making a local interconnection structure 10 (FIG. 3) of the present invention. The beginning structure may include a semiconductor or
wafer substrate 18 with at least oneactive region 14 defined in thesubstrate 18. Thesubstrate 18 may comprise silicon, gallium arsenide, glass, an insulating material such as sapphire, or any other substrate material upon which an integrated circuit wafer may be fabricated.Active regions 14 are typically formed by doping specific portions of thewafer substrate 18 by conventional methods, such as ion implantion or diffusion. A field oxide orisolation region 20 is formed in thesubstrate 18. - The field oxide or
isolation region 20 may be formed by conventional means known to persons skilled in the art, such as by local oxidation of a silicon substrate or isolation diffusion of thesubstrate 18.Isolation region 20 forms p-n junctions that separate areas of thesubstrate 18. In other words, theisolation region 20, in part, serves the function of a dielectric to electrically isolate regions of thesubstrate 18. - Materials are deposited on the
substrate 18 and selectively removed to form the desired topographical structure, such as atransistor gate stack 25. Although two complete gate stacks 25 are illustrated in FIGS. 1a-1 e, there can be any number of gate stacks 25 or other various topographical structures formed upon thesubstrate 18.Gate stack 25 may comprise agate oxide 22 having atransistor gate 24 that typically comprises a polysilicon layer. Overlying thetransistor gate 24 may be a metal silicide layer 28 (or some other conductor layer). Therefractory metal silicide 24 of thegate stack 25 typically comprises any refractory metal silicide including but not limited to titanium, cobalt, tungsten, tantalum, or molybdenum silicides. - Overlying the refractory
metal silicide layer 28 is an insulatingmaterial cap 36, typically an oxide or nitride such as a tetraethoxysilane (TEOS) oxide. Eachgate stack 25 may include one ormore spacers 32.Spacers 32 are typically oriented perpendicular to thesubstrate 18 on either side of thegate stack 25.Spacers 32 may be formed by subjecting a layer of silicon nitride (not shown) deposited over thegate stack 25 to an anisotropic etch (a technique well known to persons skilled in the art). Alternatively, spacers 32 may be made of undoped silicon dioxide. - As shown with the
gate stack 25 positioned on the right side of the structure shown in FIG. 1a, a selected portion of thecap 36 may be removed (e.g., by dry etch) to allow access to thetransistor gate 24 via themetal silicide layer 28. Alternatively, thecap 36 may be initially deposited such that a portion of themetal silicide layer 28 is exposed to allow access to thetransistor gate 24. - Referring to FIG. 1b, a
silicon source layer 42 is deposited uniformly over the structure.Silicon source layer 42 preferably comprises silicon-rich silicon nitride or silicon oxynitride. Silicon-rich silicon nitride may be deposited by any method, but is preferably deposited by LPCVD. Likewise, silicon oxynitride may be deposited as asilicon source layer 42 by any method, but is preferably deposited by PECVD using a reactant gas mixture of silane, nitrous oxide, ammonia, and nitrogen. Thesilicon source layer 42 preferably has a thickness of from about 150 Å to about 400 Å and more preferably from about 150 Å to about 200 Å. - Stoichiometric silicon is Si3N4. As used herein, stoichiometric means that the composition is such that the ratio of elements forms a neutrally charged compound. Silicon-rich silicon nitride and silicon oxynitride are examples of nonstoichiometric materials. It is preferable that the
silicon source layer 42 have sufficient silicon concentration to form the necessary silicide (i.e., so that the silicide is sufficiently electrically conductive) but not too much silicon as to cause stringer formation during the silicide process. Accordingly, the approximate stoichiometries for the silicon-rich silicon nitride or silicon oxynitride are preferably equal to SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33. - Continuing to refer to FIG. 1b, a
thin film 44 is uniformly deposited over thesilicon source layer 42.Thin film 44 will be selectively removed to form ahard mask 46 as shown in FIG. 1c (discussed below).Thin film 44 may comprise any suitable insulating material that is not rich in silicon (i.e., without free silicon).Thin film 44 preferably comprises TEOS, Si3N4 or silicon oxynitride rich in oxygen and may be deposited by any suitable manner, such as by CVD.Thin film 44 preferably has a thickness of from about 200 Å to about 400 Å. - After deposition, the
thin film 44 is patterned such that portions ofthin film 44 are exposed for removal to formhard mask 46. Patternedthin film 44 is etched using conventional etching techniques.Hard mask 46 assists in the selective removal of material during later etching processes (discussed below) and defines the local interconnect. - Referring to FIG. 1c, after the
hard mask 46 is formed by etching the patternedthin film 44, portions of thesilicon source layer 42 are left exposed. Thehard mask 46 only covers portions of thesilicon source layer 42 where local interconnects will not be formed and exposes portions ofsilicon source layer 42 where local interconnects are to be formed. - Continuing to refer to FIG. 1c, a uniform layer of a refractory metal 48 (or other electrically conductive, preferably silicide-forming material) is deposited on the
hard mask 46 and on the exposed portions of thesilicon source layer 42.Refractory metal 48 may be sputter deposited or may be deposited by any other suitable method.Refractory metal 48 preferably comprises titanium, titanium nitride (TixNy, wherein y is from about 0.01 to about 0.15), cobalt, or colbalt nitride.Refractory metal 48 is preferably deposited at a thickness of from about 300 Å to about 500 Å. The resulting structure is then annealed such that a metal silicide is formed. - The structure as shown in FIG. 1c is preferably annealed using rapid thermal processing (RTP) in an N2/NH3 atmosphere at a temperature of from about 700° C. to about 850° C., and more preferably from about 700° C. to about 750° C. When the structure is annealed,
refractory metal 48 that is in intimate, direct contact with the exposed portions of the silicon source layer 42.form metal silicide regions 52 (as shown in FIG. 1d). The portions of thesilicon source layer 42 underlying thehard mask 46 do not react to form a silicide compound (but remain as silicon source layer material). Likewise the portions ofrefractory metal 48 overlying thehard mask 46 do not react to form a silicide compound. For example, if titanium nitride (wherein the titanium nitride is TixNy, y being equal to from about 0.01 to about 0.15) is deposited asrefractory metal 48, those portions of the TixNy layer in contact with thesilicon source layer 42 will react during the anneal process to form a titanium silicide (e.g., TiSixNy). Thusmetal silicide regions 52 are formed only in those areas where the local interconnects are to be formed. - Referring to FIG. 1d, non-reacted
refractory metal 48 is then removed fromhard mask 46 using an etchant that is selective to the particular metal silicide. For example, when use of an etchant selective to titanium silicide is appropriate, non-reactedrefractory metal 48 is preferably removed using a wet etch process, such as an etchant mixture comprising NH4OH/H2O2/H2O (at a ratio of about 0.5:0.5:1). Ifrefractory metal 48 comprises cobalt or a cobalt compound, a preferred etchant may comprise HNO3/H2O2/H2O (at a ratio of about 0.5:0.5:1). Such an etchant mixture is selective to cobalt silicide. - Referring to FIG. 1d, the remaining
silicon source layer 42 need not be removed as it is not a conductive material. Likewise, thehard mask 46 need not be removed. In some devices, it is preferable to have thehard mask 46 remain, as the hard mask may act as a protective layer for the active areas of the device. - As illustrated in FIG. 1e, a passivation layer or interlevel dielectric (ILD) 56 is deposited over
hard mask 46 andmetal silicide regions 52.ILD 56 is typically a silica substantially comprising materials selected from a group consisting of silicon dioxide, borophosphosilicate glass (BPSG), phosphosilicate glass (PSG), doped or undoped oxides, and mixtures thereof. Once theILD 56 is deposited, it is preferable to planarize theuppermost surface 68 of the local interconnect structure 10 by a suitable process, such as chemical mechanical polishing (CMP). - A
recess 60 is then patterned on theILD 56 and the ILD is removed as illustrated by phantom lines in FIG. 1e. Recess 60 (i.e., an electrical contact hole) is formed in theILD 56 adjacent to thegate stack 25 and is generally aligned with theactive area 14. As used herein, “generally aligned with a selected active area” is intended to mean positioned substantially perpendicular to a location where theactive area 14 is situated within thesubstrate 18. Although only asingle recess 60 is illustrated in FIG. 1e, multiple recesses may be formed in the passivation layer to form electrical connection to a selectedactive area 14. The etchant used to remove selected portions ofILD 56 to formrecess 60 may be isotropic or anisotropic, but is preferably selective to themetal silicide 52. A typical etchant comprises CHF3, CF4, Ar, or a mixture thereof. - An electrically conductive layer is then applied to fill
recess 60 and complete anelectrical contact 64 to the correspondingactive area 14 through the corresponding metal silicide region 52 (FIG. 3).Electrical contact 64 typically comprises suitable electrically conductive materials, such as aluminum, copper, tungsten, or other suitable conductor materials. - As shown in FIG. 3, the local interconnect structure10 made according to the above-described method comprises a
substrate 18 havingactive areas 14 andisolation region 20 formed therein. Topographical sub-structures, such as gate stacks 25 for formation of MOSFETs, are included according to the specific needs of the ultimate device to be made (e.g., a memory device). The local interconnect structure 10 of the present invention further includesmetal silicide regions 52 forming electrical connecting portions of the local interconnects. Non-conductive siliconsource layer portions 42 are located immediately adjacent themetal silicide regions 52.Hard mask 46 covers the siliconsource layer portions 42 andILD 56 covers thehard mask 46 andmetal silicide regions 52 with the exception of those metal silicide regions located directly aboveactive areas 14 at theelectrical contact 64.Electrical contact 64 extends from theuppermost surface 68 of the local interconnect structure 10 to themetal silicide region 52 overlying theactive area 14. - At this point, local interconnect structure10 (as shown in FIG. 3) of the present invention is complete. Local interconnect structure 10 of the present invention may now undergo conventional processing depending upon specific needs, such as further processing to form a memory device.
- Another method of manufacture of another embodiment of the local interconnect structure110 (as shown in FIG. 6) of the present invention is described with reference to FIGS. 4a-4 f and FIG. 5.
- Referring to FIG. 4a, as with the above-described embodiment, a semiconductor or
wafer substrate 118 includes one or moreactive regions 114 defined in the substrate. Thesubstrate 118 may comprise silicon, gallium arsenide, glass, an insulating material such as sapphire, or any other substrate material upon which an integrated circuit wafer may be fabricated.Active regions 114 are typically formed by doping specific portions of thesubstrate 118, as described above. One or more field oxide orisolation regions 120 are formed in thesubstrate 118, also as described above with reference to the first method. - Materials are deposited on the
substrate 118 and selectively removed to form a desired topographical structure, such as one or more transistor gate stacks 125. Although two complete gate stacks 125 are illustrated in FIGS. 4a-4 f and FIG. 6, there may be any number ofgate stacks 125 or any number of a variety of topographical structures formed upon thesubstrate 118.Gate stack 125 may comprise agate oxide 122 having atransistor gate 124, typically comprising a polysilicon layer. Overlying thetransistor gate 124 is aconductive layer 128, e.g., a refractory metal silicide layer. Theconductive layer 128 typically comprises a refractory metal silicide including but not limited to titanium, tungsten, tantalum, or molybdenum silicide, e.g., tungsten silicide (WSix). - Overlying the
conductive layer 128 of thegate stack 125 is an insulating-material cap 136. Insulatingcap 136 typically comprises an oxide or nitride such as a tetraethoxysilane (TEOS) oxide layer. Eachgate stack 125 may include one ormore spacers 132 formed immediately adjacent the stacks, as described above and as shown in FIG. 4a and FIG. 6. - As shown with the
gate stack 125 positioned on the right side of the structure shown in FIG. 4, a selected portion of thecap 136 may be removed (e.g., by dry etch) to allow access to thetransistor gate 124 via theconductive layer 128. Alternatively, thecap 136 may be initially deposited such that a portion of theconductive layer 128 is exposed to allow access to thetransistor gate 124. - Continuing to refer to FIG. 4a, a uniform layer of a refractory metal 148 (or other material capable of forming a silicide) is deposited over exposed portions of
substrate 118, exposed portions ofisolation regions 120,spacers 132, and caps 136. Therefractory metal 148 may be sputter deposited or may be deposited by any other suitable method. Therefractory metal 148 preferably comprises titanium, titanium nitride (TixNy), cobalt, or colbalt nitride. Therefractory metal 148 is preferably deposited at a thickness of from about 300 Å to about 500 Å. - Referring to FIG. 4b, a
silicon source layer 142 is deposited uniformly over therefractory metal 148.Silicon source layer 142 preferably comprises a silicon-rich silicon nitride film or a silicon oxynitride film (each compound having stoichiometries substantially as described above in reference to the embodiment shown in FIGS. 1b-1 e).Silicon source layer 142 should have sufficient free silicon concentration to form the necessary silicide (i.e., so that the silicide is sufficiently electrically conductive) but not so much free silicon as to cause stringer formation during the silicide process (such as occurs when using polysilicon). Silicon-rich silicon nitride or silicon oxynitride may be deposited as described above in relation to the first embodiment or by any other suitable deposition techniques as known to persons skilled in the art. Thesilicon source layer 142 preferably has a thickness of from about 150 Å to about 400 Å and more preferably from about 150 Å to about 200 Å. -
Silicon source layer 142 is patterned and selectively removed (as shown in FIG. 4c) to formpartial source layer 146. That is,silicon source layer 142 is patterned such that removal of portions of the source layer forms partial source layer 146 (i.e., a hard mask), which in turn defines the location(s) of the local interconnect. Referring to FIG. 4c, the portions ofsilicon source layer 142 that are then removed are those portions where local interconnection is not needed. The selected portions of thesilicon source layer 142 may he removed using conventional etchants and etch methods, but are preferably removed using an etchant that is selective to the refractory metal 148 (e.g., by dry etch). - The structure as shown in FIG. 4d is preferably annealed using RTP in an N2/NH3 atmosphere at a temperature of from about 700° C. to about 850° C., and more preferably at from about 700° C. to about 750° C. When the structure is annealed,
refractory metal 148 in contact with thepartial source layer 146 form metal silicide regions 152 (as shown in FIG. 4e). The portions of the exposed refractory metal 148 (i.e., those portions ofrefractory metal 148 wherein thesilicon source layer 142 overlying it was removed as described above) do not form a silicide compound (i.e., remain as refractory metal and refractory metal nitride) except those portions in direct contact with the silicon substrate 118 (i.e., at the active areas and local interconnect areas). For example, if TixNy is deposited asrefractory metal 148, those portions of the titanium or titanium nitride layer in intimate and direct contact with thepartial source layer 146 will form a titanium suicide (e.g., TiSixNy) while those portions not directly in contact withpartial source layer 146 will remain as titanium or titanium nitride. Thus,metal silicide regions 152 are formed only in those areas in which the local interconnects are to be formed. - Referring to FIG. 4f, non-reacted
refractory metal 148 is then etched from the structure. The etchant used is selective to the materials comprising exposed portions of the topographical structures (i.e.,spacers 132,cap 136,isolation regions 120, and substrate 118). Anoxide cap 170 is deposited uniformly over exposed portions of the topographical structures (i.e.,spacers 132,cap 136,isolation regions 120, and substrate 118) and overmetal silicide regions 152.Oxide cap 170 may comprise a layer of oxide that provides a protective cap and is preferably from about 300 Å to about 400 Å in thickness. - As illustrated in FIG. 4f, a passivation layer or interlevel dielectric (ILD) 156 is deposited over
oxide cap 170.ILD 156 typically comprises a silica substantially comprising materials selected from a group consisting of silicon dioxide, borophosphosilicate glass (BPSG), phosphosilicate glass (PSG), doped or undoped oxides, and mixtures thereof, although other passivation materials may be used. Once theILD 156 is deposited, it is preferable to planarize theuppermost surface 168 of the local interconnect structure 110 by a suitable process, such as CMP. Prior to or instead of CMP, the structure may be annealed at a temperature of about 750° C. to about 900° C. to reflowILD 156, resulting in a relatively smooth top layer. - A
recess 160 is then patterned onILD 156 and the selected portion ofILD 156 is removed as illustrated by phantom lines in FIG. 4f. Recess 160 (i.e., contact hole) is formed inILD 156 adjacent togate stack 125 and is generally aligned with one or more selectedactive areas 114. That is, although only asingle recess 160 is illustrated in FIG. 4f, multiple recesses may be formed inILD 156 to form electrical connection to multiple selectedactive areas 114. The etchant used to remove selected portions ofILD 156 to formrecess 160 may be isotropic or anisotropic but is preferably selective to the exposed portions of the structure described above. A typical etchant comprises CHF3, CHF4, or a mixture thereof. - An electrically conductive material is then deposited into
recess 160 to complete formation of anelectrical contact 164 to theactive area 114 through the corresponding metal silicide region 152 (FIG. 6).Electrical contact 164 typically comprises an electrically conductive material, such as aluminum, copper, tungsten, or any other suitable conductor materials. - As shown in FIG. 6, the local interconnect structure110 made according to the above-described method comprises a
substrate 118 havingactive areas 114 andisolation regions 120 formed therein. Topographical substructures, such as gate stacks 125 of MOSFETs, are included according to the specific needs for the ultimate device to be made (e.g., a memory device). The local interconnect structure 110 of the present invention further includesmetal silicide regions 152 forming electrical connecting portions of the local interconnects.Oxide cap 170 coversmetal silicide regions 152 and the exposed portions ofspacers 132,cap 136,isolation region 120, andsubstrate 118.Electrical contact 164 extends from theuppermost portion 168 of the local interconnect structure 110 to themetal silicide region 152 overlying the selectedactive area 114. - At this point, local interconnect structure110 (as shown in FIG. 6) of the present invention is complete. Local interconnect structure 110 of the present invention may now undergo conventional processing depending upon specific needs, such as further processing to form a memory device.
- Whereas the invention has been described with reference to multiple embodiments of the local interconnect structure and representative methods, it will be understood that the invention is not limited to those embodiments. On the contrary, the invention is intended to encompass all modifications, alternatives, and equivalents as may be included within the spirit and scope of the invention as defined by the appended claims.
Claims (45)
1. A method of forming a local interconnect structure for an integrated circuit comprising:
providing a substrate having a surface and including at least one topographical structure thereon such that a region of the surface of the substrate is exposed;
forming at least one active area in the substrate;
forming a silicon source layer over the at least one active area and at least a portion of the at least one topographical structure;
depositing a refractory metal directly on selected regions of the silicon source layer and over the at least one topographical structure;
forming a silicide layer from the refractory metal and silicon source layer, the suicide layer defining a portion of the local interconnect structure;
removing the refractory metal;
forming an interlevel dielectric over the silicide layer, the interlevel dielectric having a recess defined substantially over the at least one active area; and
depositing an electrically conductive material in the recess.
2. The method of claim 1 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
3. The method of claim 1 , wherein the silicon source layer comprises SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
4. The method of claim 1 , wherein the silicon source layer does not comprise polysilicon.
5. The method of claim 1 , wherein the refractory metal is selected from the group consisting essentially of titanium, titanium nitride, cobalt, cobalt nitride, and mixtures thereof.
6. The method of claim 5 , wherein the refractory metal is TixNy, wherein y is from about 0.01 to about 0.15.
7. The method of claim 1 , wherein the refractory metal is removed using an etchant that is selective to the refractory metal silicide.
8. A method of forming a local interconnect structure for an integrated circuit comprising:
providing a substrate having an exposed surface portion and an exposed active area;
depositing a silicon source layer over the active area and exposed surface portion;
forming a thin film over the silicon source layer;
patterning and removing selected regions of the thin layer to expose regions of the silicon source layer to define a local interconnect pattern on the silicon source layer;
depositing a silicide forming material on exposed regions of the silicon source layer;
reacting the silicide forming material with the exposed regions of the silicon source layer to form a silicide layer as part of the local interconnect structure;
removing the silicide forming material;
forming an interlevel dielectric over the silicide layer, the interlevel dielectric having a recess defined therein and substantially aligned with and extending to the active area; and
depositing an electrically conductive material in the recess.
9. The method of claim 8 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
10. The method of claim 8 , wherein the silicon source layer comprises SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
11. The method of claim 8 , wherein the thin film comprises a hard mask.
12. A method of forming a local interconnect structure for an integrated circuit comprising:
providing a substrate having a principal surface including at least one topographical structure thereon such that a substrate region of the principal surface is exposed;
forming at least one active area in the substrate adjacent the at least one topographical structure;
forming a silicon source layer over the substrate region of the principal surface;
forming a hard mask on selected silicon source layer regions such that the silicon source layer regions that form part of the local interconnect structure remain exposed;
forming a refractory metal over the hard mask and on the silicon source layer regions;
annealing to form a portion of the local interconnect structure;
removing refractory metal from the hard mask;
forming an interlevel dielectric over the portion of the local interconnect structure and the hard mask, the interlevel dielectric having a recess defined therein and substantially aligned with the active area or the topographical structure; and
depositing an electrically conductive material in the recess.
13. The method of claim 12 , wherein the silicon sources layer does not comprise polysilicon.
14. The method of claim 12 , wherein the resulting local interconnect structure is substantially free of stringers.
15. A method of manufacturing a semiconductor device comprising:
providing a substrate having a principal surface including at least one gate stack formed thereon such that a region of the principal surface of the substrate is exposed;
forming an active area in the substrate immediately adjacent the gate stack;
forming a silicon source layer over at least a portion of the active area and over at least a portion of the gate stack;
depositing a refractory metal on selected regions of the silicon source layer;
creating a silicide layer from the refractory metal and silicon source layer, the silicide layer forming a portion of a local interconnect structure;
forming a passivation layer on the silicide layer and silicon source layer, the passivation layer having a recess formed therein, the recess being substantially aligned with a portion of the silicide layer; and
depositing an electrically conductive material in the recess.
16. The method of claim 15 , wherein the silicide layer is formed by an annealing process.
17. A method of manufacturing an integrated circuit comprising:
forming an active area in a substrate;
forming a topographical device on the substrate;
forming a silicon source layer over a surface of the substrate and over at least a portion of the topographical structure, the silicon source layer comprising a material selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof;
forming a hard mask on the silicon source layer to define a local interconnect pattern thereon;
depositing a uniform layer of a refractory metal on the silicon source layer and on the hard mask;
forming a refractory metal silicide layer;
removing refractory metal overlying the hard mask;
forming an interlevel dielectric over the silicide layer and hard mask, the interlevel dielectric having a recess defined substantially over the active area or a portion of the topographical structure; and
depositing an electrically conductive material in the recess.
18. The method of claim 17 , wherein the refractory metal is selected from the group consisting essentially of titanium, titanium nitride, cobalt, cobalt nitride, and mixtures thereof.
19. The method of claim 17 , wherein the refractory metal is TixNy, wherein y is equal to about 0.01 to about 0.15.
20. The method of claim 17 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
21. A method of manufacturing a semiconductor device comprising:
providing a substrate having at least one gate stack formed thereon such that a region of the substrate is exposed;
forming at least one active area in the substrate adjacent the at least one gate stack;
removing a portion of the at least one gate stack to provide electrical access to a gate in the at least one gate stack;
forming a silicon source layer over the at least one active area and over at least a portion of the at least one gate stack;
depositing a refractory metal on selected regions of the silicon source layer;
creating a silicide layer from the refractory metal and silicon source layer, the silicide layer forming a portion of a local interconnect structure;
forming a passivation layer on the silicide layer, the passivation layer having recesses formed therein, the recesses being substantially aligned with the at least one active area or the at least one gate stack; and
depositing an electrically conductive material in the recesses.
22. The method of claim 21 , wherein a hard mask is deposited on selected portions of the silicon source layer prior to deposition of the refractory metal.
23. The method of claim 21 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
24. A method of forming a local interconnect structure for an integrated circuit comprising:
providing a substrate on which a surface of the substrate and an active area are exposed;
depositing a refractory metal over at least a portion of the active area and the exposed surface of the substrate;
depositing a silicon source layer over the refractory metal;
patterning and removing selected regions of the silicon source layer to expose regions of the refractory metal defining a local interconnect pattern;
reacting regions of the silicon source layer with the refractory metal creating a local interconnect structure;
removing un-reacted refractory metal;
forming an interlevel dielectric having a recess defined therein and substantially aligned with the active area; and
depositing an electrically conductive material in the recess.
25. The method of claim 24 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
26. The method of claim 24 , wherein the silicon source layer comprises SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
27. The method of claim 24 , wherein the silicon source layer does not comprise polysilicon.
28. The method of claim 24 , wherein the refractory metal is selected from the group consisting essentially of titanium, titanium nitride, cobalt, cobalt nitride, and mixtures thereof.
29. The method of claim 24 , wherein the refractory metal is removed using an etchant that is selective to a refractory metal silicide.
30. A method of forming a local interconnect structure for an integrated circuit comprising:
providing a substrate having a surface and including at least one topographical structure thereon such that a region of the surface of the substrate is exposed;
forming an active area in the substrate;
depositing a silicide forming material over the active area and at least a portion of the topographical structure;
depositing a silicon source layer on selected regions of the silicide forming material;
making a silicide layer from the silicide forming material and silicon source layer, the silicide layer creating a portion of the local interconnect structure;
removing un-reacted silicide forming material;
forming an oxide cap over the silicide layer, exposed portions of the topographical structure, and the substrate;
forming a passivation layer over the oxide cap;
defining at least one recess extending through the passivation layer and the oxide cap, the recess substantially aligned over the active area or a portion of the topographical structure; and
depositing an electrically conductive material in the recess.
31. The method of claim 30 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
32. The method of claim 30 , wherein the silicon source layer comprises SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
33. The method of claim 30 , wherein the silicon source layer does not comprise polysilicon.
34. A method of manufacturing an integrated circuit device comprising:
providing a substrate having a surface including at least one topographical structure thereon such that a region of the surface of the substrate is exposed;
forming at least one active area in the substrate adjacent the at least one topographical structure;
forming a refractory metal over the exposed region of the substrate, at least a portion of the at least one active area, and at least a portion of the at least one topographical structure;
forming a silicon source layer over the refractory metal;
patterning and removing selected portions of the silicon source layer such that selected regions of the refractory metal structure are exposed;
annealing to form a refractory metal silicide;
removing un-reacted refractory metal after the refractory metal silicide is formed;
forming an interlevel dielectric having a recess defined therein and substantially aligned with at least a portion of the at least one active area or at least a portion of the at least one topographical structure; and
depositing an electrically conductive material in the recess.
35. The method of claim 34 , wherein the silicon source layer comprises SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
36. The method of claim 34 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
37. A method of manufacturing a semiconductor device comprising:
providing a substrate having at least one gate stack thereon;
forming at least one active area in the substrate immediately adjacent the at least one gate stack;
forming a refractory metal over a portion of the at least one active area and over at least a portion of the at least one gate stack;
depositing a silicon source layer on the refractory metal;
removing selected regions of the silicon source layer to define a local interconnect structure over a portion of the at least one active area or the at least one gate stack;
reacting refractory metal covered by the silicon source layer with the silicon source layer to form a silicide layer;
forming an oxide cap over the silicide layer, exposed portions of the at least one gate stack and the substrate;
forming a passivation layer over the oxide cap;
defining at least one recess extending through the passivation layer and the oxide cap, the recess substantially aligned over a portion of the at least one active area or the at least one gate stack; and
depositing an electrically conductive material in the recess.
38. A method of manufacturing an integrated circuit comprising:
forming an active area in a substrate;
forming a topographical device on the substrate;
depositing a layer of a refractory metal over a surface of the substrate and over the topographical structure
forming a silicon source layer over the refractory metal, the silicon source layer comprising a material selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof;
removing selected regions of the silicon source layer to define a local interconnect pattern on the refractory metal;
forming a refractory metal silicide layer from the refractory metal and the silicon source layer to form a portion of a local interconnect structure;
removing refractory metal after the refractory metal silicide is formed;
forming an interlevel dielectric over the silicide layer, the interlevel dielectric having recesses defined substantially over a portion of the active area and a portion of the topographical structure; and
depositing an electrically conductive material in the recesses.
39. An integrated circuit formed on a substrate, the integrated circuit having at least one local interconnect structure comprising:
at least one gate stack on the substrate;
at least one active area adjacent the at least one gate stack;
a silicon source layer overlying a portion of the substrate and a portion of the at least one gate stack;
a silicide layer overlying the at least one active area and extending over a portion of the at least one gate stack;
an oxide layer overlying the silicon source layer but not the silicide layer;
a passivation layer overlying the oxide layer and the silicide layer, the passivation layer having at least one recess defined therein, the at least one recess terminating substantially at the at least one active area or the at least one gate stack; and
an electrically conductive material disposed in and substantially filling the recess, the electrically conductive material forming an electrical contact with the silicide layer and the at least one active area or the at least one gate stack.
40. The method of claim 39 , wherein the silicon source layer is selected from the group consisting essentially of silicon rich silicon nitride, silicon oxynitride, and mixtures thereof.
41. The method of claim 39 , wherein the silicon source layer comprises SixNyOz wherein x is about 0.39 to about 0.65, y is about 0.02 to about 0.56, and z is about 0.05 to about 0.33.
42. The method of claim 39 , wherein the silicon source layer does not comprise polysilicon.
43. The method of claim 39 , wherein the refractory metal is selected from the group consisting essentially of titanium, titanium nitride, cobalt, cobalt nitride, and mixtures thereof.
44. The method of claim 39 , wherein the refractory metal is TixNy, wherein y is from about 0.01 to about 0.15.
45. A local interconnect structure comprising:
a semiconductor substrate having at least one topographical structure thereon;
at least one active area adjacent the at least one topographical structure;
a silicon source layer overlying a portion of the semiconductor substrate and a portion of the at least one topographical structure;
a metal silicide layer overlying the at least one active area and extending over a portion of the at least one topographical structure;
a hard mask layer overlying the silicon source layer but not overlying the metal silicide layer;
an interlevel dielectric overlying the hard mask layer and the metal silicide layer, the interlevel dielectric having a recess defined therein extending substantially to the at least one active area; and
an electrically conductive material disposed in and substantially filling the recess, the electrically conductive material forming an electrical contact with the metal silicide and the at least one active area.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/326,716 US20030124845A1 (en) | 1999-09-01 | 2002-12-20 | Local interconnect structures and methods for making the same |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/388,832 US6436805B1 (en) | 1999-09-01 | 1999-09-01 | Local interconnect structures and methods for making the same |
US10/024,256 US6522001B2 (en) | 1999-09-01 | 2001-12-17 | Local interconnect structures and methods for making the same |
US10/326,716 US20030124845A1 (en) | 1999-09-01 | 2002-12-20 | Local interconnect structures and methods for making the same |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/024,256 Continuation US6522001B2 (en) | 1999-09-01 | 2001-12-17 | Local interconnect structures and methods for making the same |
Publications (1)
Publication Number | Publication Date |
---|---|
US20030124845A1 true US20030124845A1 (en) | 2003-07-03 |
Family
ID=23535710
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/388,832 Expired - Lifetime US6436805B1 (en) | 1999-09-01 | 1999-09-01 | Local interconnect structures and methods for making the same |
US10/024,256 Expired - Lifetime US6522001B2 (en) | 1999-09-01 | 2001-12-17 | Local interconnect structures and methods for making the same |
US10/326,716 Abandoned US20030124845A1 (en) | 1999-09-01 | 2002-12-20 | Local interconnect structures and methods for making the same |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/388,832 Expired - Lifetime US6436805B1 (en) | 1999-09-01 | 1999-09-01 | Local interconnect structures and methods for making the same |
US10/024,256 Expired - Lifetime US6522001B2 (en) | 1999-09-01 | 2001-12-17 | Local interconnect structures and methods for making the same |
Country Status (1)
Country | Link |
---|---|
US (3) | US6436805B1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030049936A1 (en) * | 2001-09-07 | 2003-03-13 | Samsung Electronics Co., Ltd. | Semiconductor device having local interconnection layer and method for manufacturing the same |
US20050130417A1 (en) * | 2003-12-16 | 2005-06-16 | Korea Advanced Institute Of Science And Technology | Method for fabricating epitaxial cobalt-disilicide layers using cobalt-nitride thin film |
US20090047762A1 (en) * | 2004-07-20 | 2009-02-19 | Satoshi Torii | Apparatus and method for a memory array with shallow trench isolation regions between bit lines for increased process margins |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6555455B1 (en) | 1998-09-03 | 2003-04-29 | Micron Technology, Inc. | Methods of passivating an oxide surface subjected to a conductive material anneal |
US6429124B1 (en) * | 1999-04-14 | 2002-08-06 | Micron Technology, Inc. | Local interconnect structures for integrated circuits and methods for making the same |
US6630718B1 (en) | 1999-07-26 | 2003-10-07 | Micron Technology, Inc. | Transistor gate and local interconnect |
US6765269B2 (en) * | 2001-01-26 | 2004-07-20 | Integrated Device Technology, Inc. | Conformal surface silicide strap on spacer and method of making same |
US6503844B2 (en) * | 2001-06-06 | 2003-01-07 | Infineon Technologies, Ag | Notched gate configuration for high performance integrated circuits |
KR100408743B1 (en) * | 2001-09-21 | 2003-12-11 | 삼성전자주식회사 | Method of forming a quantum dot and method of forming a gate electrode using the same |
US7538029B2 (en) * | 2005-07-06 | 2009-05-26 | International Business Machines Corporation | Method of room temperature growth of SiOx on silicide as an etch stop layer for metal contact open of semiconductor devices |
US8225239B2 (en) | 2006-03-09 | 2012-07-17 | Tela Innovations, Inc. | Methods for defining and utilizing sub-resolution features in linear topology |
US8245180B2 (en) | 2006-03-09 | 2012-08-14 | Tela Innovations, Inc. | Methods for defining and using co-optimized nanopatterns for integrated circuit design and apparatus implementing same |
US7943967B2 (en) | 2006-03-09 | 2011-05-17 | Tela Innovations, Inc. | Semiconductor device and associated layouts including diffusion contact placement restriction based on relation to linear conductive segments |
US7908578B2 (en) | 2007-08-02 | 2011-03-15 | Tela Innovations, Inc. | Methods for designing semiconductor device with dynamic array section |
US9230910B2 (en) | 2006-03-09 | 2016-01-05 | Tela Innovations, Inc. | Oversized contacts and vias in layout defined by linearly constrained topology |
US7446352B2 (en) * | 2006-03-09 | 2008-11-04 | Tela Innovations, Inc. | Dynamic array architecture |
US9035359B2 (en) | 2006-03-09 | 2015-05-19 | Tela Innovations, Inc. | Semiconductor chip including region including linear-shaped conductive structures forming gate electrodes and having electrical connection areas arranged relative to inner region between transistors of different types and associated methods |
US7763534B2 (en) | 2007-10-26 | 2010-07-27 | Tela Innovations, Inc. | Methods, structures and designs for self-aligning local interconnects used in integrated circuits |
US9563733B2 (en) | 2009-05-06 | 2017-02-07 | Tela Innovations, Inc. | Cell circuit and layout with linear finfet structures |
US8653857B2 (en) | 2006-03-09 | 2014-02-18 | Tela Innovations, Inc. | Circuitry and layouts for XOR and XNOR logic |
US8448102B2 (en) | 2006-03-09 | 2013-05-21 | Tela Innovations, Inc. | Optimizing layout of irregular structures in regular layout context |
US8839175B2 (en) | 2006-03-09 | 2014-09-16 | Tela Innovations, Inc. | Scalable meta-data objects |
US9009641B2 (en) | 2006-03-09 | 2015-04-14 | Tela Innovations, Inc. | Circuits with linear finfet structures |
US8225261B2 (en) | 2006-03-09 | 2012-07-17 | Tela Innovations, Inc. | Methods for defining contact grid in dynamic array architecture |
US7956421B2 (en) | 2008-03-13 | 2011-06-07 | Tela Innovations, Inc. | Cross-coupled transistor layouts in restricted gate level layout architecture |
US8247846B2 (en) | 2006-03-09 | 2012-08-21 | Tela Innovations, Inc. | Oversized contacts and vias in semiconductor chip defined by linearly constrained topology |
US7932545B2 (en) * | 2006-03-09 | 2011-04-26 | Tela Innovations, Inc. | Semiconductor device and associated layouts including gate electrode level region having arrangement of six linear conductive segments with side-to-side spacing less than 360 nanometers |
US8541879B2 (en) | 2007-12-13 | 2013-09-24 | Tela Innovations, Inc. | Super-self-aligned contacts and method for making the same |
US8658542B2 (en) | 2006-03-09 | 2014-02-25 | Tela Innovations, Inc. | Coarse grid design methods and structures |
US7979829B2 (en) | 2007-02-20 | 2011-07-12 | Tela Innovations, Inc. | Integrated circuit cell library with cell-level process compensation technique (PCT) application and associated methods |
US8286107B2 (en) | 2007-02-20 | 2012-10-09 | Tela Innovations, Inc. | Methods and systems for process compensation technique acceleration |
US8667443B2 (en) | 2007-03-05 | 2014-03-04 | Tela Innovations, Inc. | Integrated circuit cell library for multiple patterning |
US7910418B2 (en) * | 2008-01-30 | 2011-03-22 | International Business Machines Corporation | Complementary metal gate dense interconnect and method of manufacturing |
US8453094B2 (en) | 2008-01-31 | 2013-05-28 | Tela Innovations, Inc. | Enforcement of semiconductor structure regularity for localized transistors and interconnect |
US7939443B2 (en) | 2008-03-27 | 2011-05-10 | Tela Innovations, Inc. | Methods for multi-wire routing and apparatus implementing same |
KR101749351B1 (en) | 2008-07-16 | 2017-06-20 | 텔라 이노베이션스, 인코포레이티드 | Methods for cell phasing and placement in dynamic array architecture and implementation of the same |
US9122832B2 (en) | 2008-08-01 | 2015-09-01 | Tela Innovations, Inc. | Methods for controlling microloading variation in semiconductor wafer layout and fabrication |
CN101777518B (en) * | 2009-01-13 | 2012-06-27 | 中芯国际集成电路制造(上海)有限公司 | Method for improving integral parameter of gate oxide layer |
US8661392B2 (en) | 2009-10-13 | 2014-02-25 | Tela Innovations, Inc. | Methods for cell boundary encroachment and layouts implementing the Same |
US9159627B2 (en) | 2010-11-12 | 2015-10-13 | Tela Innovations, Inc. | Methods for linewidth modification and apparatus implementing the same |
US9711402B1 (en) * | 2016-03-08 | 2017-07-18 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of forming contact metal |
CN106024893B (en) * | 2016-05-30 | 2019-03-19 | 上海华力微电子有限公司 | High-K metal gate device and preparation method thereof |
US9748281B1 (en) * | 2016-09-15 | 2017-08-29 | International Business Machines Corporation | Integrated gate driver |
CN116504717B (en) * | 2023-06-29 | 2023-09-12 | 合肥晶合集成电路股份有限公司 | Preparation method of metal silicide |
Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5340774A (en) * | 1993-02-04 | 1994-08-23 | Paradigm Technology, Inc. | Semiconductor fabrication technique using local planarization with self-aligned transistors |
US5512516A (en) * | 1988-05-27 | 1996-04-30 | Fujitsu Limited | Contact structure for connecting an electrode to a semiconductor device and a method of forming the same |
US5573980A (en) * | 1996-04-22 | 1996-11-12 | Taiwan Semiconductor Manufacturing Company Ltd. | Method of forming salicided self-aligned contact for SRAM cells |
US5721146A (en) * | 1996-04-29 | 1998-02-24 | Taiwan Semiconductor Manufacturing Company Ltd | Method of forming buried contact architecture within a trench |
US5756394A (en) * | 1995-08-23 | 1998-05-26 | Micron Technology, Inc. | Self-aligned silicide strap connection of polysilicon layers |
US5847463A (en) * | 1997-08-22 | 1998-12-08 | Micron Technology, Inc. | Local interconnect comprising titanium nitride barrier layer |
US5888894A (en) * | 1997-11-07 | 1999-03-30 | Integrated Silicon Solution, Inc. | Method for reducing stray conductive material near vertical surfaces in semiconductor manufacturing processes |
US5893741A (en) * | 1997-02-07 | 1999-04-13 | National Science Council | Method for simultaneously forming local interconnect with silicided elevated source/drain MOSFET's |
US5895961A (en) * | 1995-10-11 | 1999-04-20 | Paradigm Technology, Inc. | Semiconductor device with a planarized interconnect with poly-plug and self-aligned contacts |
US5897372A (en) * | 1995-11-01 | 1999-04-27 | Micron Technology, Inc. | Formation of a self-aligned integrated circuit structure using silicon-rich nitride as a protective layer |
US5913139A (en) * | 1996-12-26 | 1999-06-15 | Fujitsu Limited | Method of manufacturing a semiconductor device with local interconnect of metal silicide |
US5918147A (en) * | 1995-03-29 | 1999-06-29 | Motorola, Inc. | Process for forming a semiconductor device with an antireflective layer |
US5920796A (en) * | 1997-09-05 | 1999-07-06 | Advanced Micro Devices, Inc. | In-situ etch of BARC layer during formation of local interconnects |
US5928732A (en) * | 1993-12-28 | 1999-07-27 | Applied Materials, Inc. | Method of forming silicon oxy-nitride films by plasma-enhanced chemical vapor deposition |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6046098A (en) * | 1998-02-23 | 2000-04-04 | Micron Technology, Inc. | Process of forming metal silicide interconnects |
GB2358079B (en) | 2000-01-07 | 2004-02-18 | Seiko Epson Corp | Thin-film transistor |
-
1999
- 1999-09-01 US US09/388,832 patent/US6436805B1/en not_active Expired - Lifetime
-
2001
- 2001-12-17 US US10/024,256 patent/US6522001B2/en not_active Expired - Lifetime
-
2002
- 2002-12-20 US US10/326,716 patent/US20030124845A1/en not_active Abandoned
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5512516A (en) * | 1988-05-27 | 1996-04-30 | Fujitsu Limited | Contact structure for connecting an electrode to a semiconductor device and a method of forming the same |
US5477074A (en) * | 1993-02-04 | 1995-12-19 | Paradigm Technology, Inc. | Semiconductor structure using local planarization with self-aligned transistors |
US5340774A (en) * | 1993-02-04 | 1994-08-23 | Paradigm Technology, Inc. | Semiconductor fabrication technique using local planarization with self-aligned transistors |
US5928732A (en) * | 1993-12-28 | 1999-07-27 | Applied Materials, Inc. | Method of forming silicon oxy-nitride films by plasma-enhanced chemical vapor deposition |
US5918147A (en) * | 1995-03-29 | 1999-06-29 | Motorola, Inc. | Process for forming a semiconductor device with an antireflective layer |
US5756394A (en) * | 1995-08-23 | 1998-05-26 | Micron Technology, Inc. | Self-aligned silicide strap connection of polysilicon layers |
US5895961A (en) * | 1995-10-11 | 1999-04-20 | Paradigm Technology, Inc. | Semiconductor device with a planarized interconnect with poly-plug and self-aligned contacts |
US5897372A (en) * | 1995-11-01 | 1999-04-27 | Micron Technology, Inc. | Formation of a self-aligned integrated circuit structure using silicon-rich nitride as a protective layer |
US5573980A (en) * | 1996-04-22 | 1996-11-12 | Taiwan Semiconductor Manufacturing Company Ltd. | Method of forming salicided self-aligned contact for SRAM cells |
US5721146A (en) * | 1996-04-29 | 1998-02-24 | Taiwan Semiconductor Manufacturing Company Ltd | Method of forming buried contact architecture within a trench |
US5913139A (en) * | 1996-12-26 | 1999-06-15 | Fujitsu Limited | Method of manufacturing a semiconductor device with local interconnect of metal silicide |
US5893741A (en) * | 1997-02-07 | 1999-04-13 | National Science Council | Method for simultaneously forming local interconnect with silicided elevated source/drain MOSFET's |
US5847463A (en) * | 1997-08-22 | 1998-12-08 | Micron Technology, Inc. | Local interconnect comprising titanium nitride barrier layer |
US5920796A (en) * | 1997-09-05 | 1999-07-06 | Advanced Micro Devices, Inc. | In-situ etch of BARC layer during formation of local interconnects |
US5888894A (en) * | 1997-11-07 | 1999-03-30 | Integrated Silicon Solution, Inc. | Method for reducing stray conductive material near vertical surfaces in semiconductor manufacturing processes |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030049936A1 (en) * | 2001-09-07 | 2003-03-13 | Samsung Electronics Co., Ltd. | Semiconductor device having local interconnection layer and method for manufacturing the same |
US7122850B2 (en) * | 2001-09-07 | 2006-10-17 | Samsung Electronics Co., Ltd. | Semiconductor device having local interconnection layer and etch stopper pattern for preventing leakage of current |
US20070010090A1 (en) * | 2001-09-07 | 2007-01-11 | Dong-Kyun Nam | Semiconductor device having local interconnection layer and etch stopper pattern for preventing leakage of current |
US7704892B2 (en) | 2001-09-07 | 2010-04-27 | Samsung Electronics Co., Ltd. | Semiconductor device having local interconnection layer and etch stopper pattern for preventing leakage of current |
US20050130417A1 (en) * | 2003-12-16 | 2005-06-16 | Korea Advanced Institute Of Science And Technology | Method for fabricating epitaxial cobalt-disilicide layers using cobalt-nitride thin film |
US7105443B2 (en) * | 2003-12-16 | 2006-09-12 | Korea Advanced Institute Of Science And Technology | Method for fabricating epitaxial cobalt-disilicide layers using cobalt-nitride thin film |
US20090047762A1 (en) * | 2004-07-20 | 2009-02-19 | Satoshi Torii | Apparatus and method for a memory array with shallow trench isolation regions between bit lines for increased process margins |
US8507971B2 (en) * | 2004-07-20 | 2013-08-13 | Spansion Llc | Apparatus and method for a memory array with shallow trench isolation regions between bit lines for increased process margins |
Also Published As
Publication number | Publication date |
---|---|
US6436805B1 (en) | 2002-08-20 |
US20020068429A1 (en) | 2002-06-06 |
US6522001B2 (en) | 2003-02-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6436805B1 (en) | Local interconnect structures and methods for making the same | |
US5723893A (en) | Method for fabricating double silicide gate electrode structures on CMOS-field effect transistors | |
US6410984B1 (en) | Conductive structure in an integrated circuit | |
US4821085A (en) | VLSI local interconnect structure | |
EP0279588B1 (en) | Contact in a contact hole in a semiconductor and method of producing same | |
US5792703A (en) | Self-aligned contact wiring process for SI devices | |
US6160296A (en) | Titanium nitride interconnects | |
US5130267A (en) | Split metal plate capacitor and method for making the same | |
JPH0797571B2 (en) | Method for forming a contact window in a semiconductor structure | |
US6235627B1 (en) | Semiconductor device and method for manufacturing the same | |
US20040183111A1 (en) | Semiconductor device and semiconductor device manufacturing method | |
US6531749B1 (en) | Field effect transistor having a two layered gate electrode | |
JP2720796B2 (en) | Method for manufacturing semiconductor device | |
US6228761B1 (en) | Method of forming a local interconnect with improved etch selectivity of silicon dioxide/silicide | |
US5518961A (en) | Semiconductor integrated circuit device with wiring microstructure formed on gates and method of manufacturing the same | |
JPH10223770A (en) | Semiconductor device and manufacture thereof | |
US20030042607A1 (en) | Diffusion barrier layer for semiconductor wafer fabrication | |
US6638843B1 (en) | Method for forming a silicide gate stack for use in a self-aligned contact etch | |
US6054385A (en) | Elevated local interconnect and contact structure | |
US6534393B1 (en) | Method for fabricating local metal interconnections with low contact resistance and gate electrodes with improved electrical conductivity | |
US5471094A (en) | Self-aligned via structure | |
US6225222B1 (en) | Diffusion barrier enhancement for sub-micron aluminum-silicon contacts | |
US6225216B1 (en) | Method of forming a local interconnect with improved etch selectivity of silicon dioxide/silicide | |
US6239015B1 (en) | Semiconductor device having polysilicon interconnections and method of making same | |
US6020259A (en) | Method of forming a tungsten-plug contact for a semiconductor device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: MICRON TECHNOLOGY, INC., IDAHO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:TRIVEDI, JIGISH D.;REEL/FRAME:013607/0400 Effective date: 19990830 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |