US20030073274A1 - Compound semiconductor device and method for manufacturing the same - Google Patents
Compound semiconductor device and method for manufacturing the same Download PDFInfo
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- US20030073274A1 US20030073274A1 US10/295,407 US29540702A US2003073274A1 US 20030073274 A1 US20030073274 A1 US 20030073274A1 US 29540702 A US29540702 A US 29540702A US 2003073274 A1 US2003073274 A1 US 2003073274A1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 88
- 150000001875 compounds Chemical class 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title abstract description 23
- 238000004519 manufacturing process Methods 0.000 title abstract description 14
- 229910002601 GaN Inorganic materials 0.000 claims abstract description 85
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000000758 substrate Substances 0.000 claims abstract description 19
- 230000004888 barrier function Effects 0.000 claims abstract description 16
- 239000010936 titanium Substances 0.000 claims description 51
- 239000010931 gold Substances 0.000 claims description 50
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 36
- 229910052737 gold Inorganic materials 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 238000000137 annealing Methods 0.000 abstract description 42
- 230000008569 process Effects 0.000 abstract description 17
- 238000005530 etching Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 15
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 150000004767 nitrides Chemical class 0.000 description 7
- 239000012299 nitrogen atmosphere Substances 0.000 description 7
- 229910052594 sapphire Inorganic materials 0.000 description 7
- 239000010980 sapphire Substances 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 229910019080 Mg-H Inorganic materials 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 239000002019 doping agent Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 229910052790 beryllium Inorganic materials 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- -1 GaN Chemical compound 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- RNQKDQAVIXDKAG-UHFFFAOYSA-N aluminum gallium Chemical compound [Al].[Ga] RNQKDQAVIXDKAG-UHFFFAOYSA-N 0.000 description 1
- AJGDITRVXRPLBY-UHFFFAOYSA-N aluminum indium Chemical compound [Al].[In] AJGDITRVXRPLBY-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/83—Electrodes
- H10H20/832—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28575—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising AIIIBV compounds
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/01—Manufacture or treatment
- H10H20/011—Manufacture or treatment of bodies, e.g. forming semiconductor layers
- H10H20/013—Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials
- H10H20/0133—Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials with a substrate not being Group III-V materials
- H10H20/01335—Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials with a substrate not being Group III-V materials the light-emitting regions comprising nitride materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/32—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
- H01S5/323—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
- H01S5/32308—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm
- H01S5/32341—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm blue laser based on GaN or GaP
Definitions
- the invention relates to a gallium nitride-based III-V group compound semiconductor device and method for manufacturing the same.
- III-V group nitride such as gallium nitride (GaN), aluminum gallium nitride (AlGaN), indium gallium nitride (InGaN), and aluminum indium gallium nitride (AlInGaN) were first grown successfully, they have become promising materials for use in high temperature/high power electronic devices and opotoelectronic devices, due to their high direct band gap, high saturation drift velocity, high breakdown field, and chemical inertness.
- GaN gallium nitride
- AlGaN aluminum gallium nitride
- InGaN indium gallium nitride
- AlInGaN aluminum indium gallium nitride
- III-V group nitride device In general, the performance of III-V group nitride device has been limited by contact resistance. Therefore, a key technology in achieving higher performance for III-V group nitride devices is the realization of more reliable metal contacts. Although a wide group nitride devices is the realization of more reliable metal contacts. Although a wide variety of metals used as contacts with GaN have been reported, the metallic titanium/aluminum (Ti/Al) bilayer has been most widely used as a conventional ohmic contact for n-type GaN. However, such a Ti/Al bilayer is prone to oxidation, which in turn leads to high ohmic resistance during the fabrication process and during operation.
- a low resistivity gold (Au) layer should be effective for passivating the Ti/Al bilayer.
- Au would interdiffuse and penetrate into the GaN semiconductor layer, causing deterioration in thermal stability, and ohmic contact property of the semiconductor device.
- FIG. 1 is a cross-sectional view showing a typical structure of a GaN-based III-V group compound semiconductor light-emitting device (LED) 100 .
- an LED 100 includes an insulated substrate 1 made of such as sapphire.
- the substrate 1 has a first major surface 1 a and a second major surface 1 b.
- a GaN buffer layer 2 is formed on the first major surface 1 a of the substrate 1 .
- An n-type GaN-based III-V group compound semiconductor layer 3 is formed on the buffer layer 2 .
- the n-type semiconductor layer 3 is doped by n-type dopants such as germanium (Ge), selenium (Se), sulfur (S), or tellurium (Te).
- the n-type semiconductor layer 3 can be doped by silicon (Si).
- An n-type AlGaN layer 4 is formed on the n-type semiconductor layer 3 .
- An active layer 5 is formed on the n-type AlGaN layer 4 , and the active layer 5 has a multiple quantum well (MQW) structure, a single quantum well (SQW) structure, or a double-heterostructure (DH) made of such as InGaN/GaN.
- a p-type AlGaN layer 6 is formed on the active layer 5 .
- the p-type AlGaN layer 6 is doped with p-type dopants such as beryllium (Be), strontium (Sr), barium (Ba), zinc (Zn), or magnesium.
- a p-type GaN-based III-V group compound semiconductor layer 7 is formed on the p-type AlGaN layer 6 .
- the p-type semiconductor layer 7 is doped with p-type dopants such as beryllium, strontium, barium, zinc, or magnesium.
- the LED 100 includes an electrode 8 A formed on the n-type semiconductor layer 3 and an electrode 8 B formed on the p-type semiconductor layer 7 .
- the electrode 8 A includes a metal such as titanium, aluminum, or gold as mentioned above.
- the electrode 8 B is a kind of ohmic electrode, it includes a metal such as nickel (Ni), chromium (Cr), gold or platinum.
- the flow chart shows conventional steps for manufacturing a light-emitting device 100 .
- a buffer layer 2 , an n-type semiconductor layer 3 , an n-type AlGaN layer 4 , an active layer 5 , a p-type AlGaN layer 6 , and a p-type semiconductor layer 7 are formed on a substrate 1 in this order.
- a thermal process is performed to activate the p-type AlGaN layer 6 and the p-type semiconductor layer 7 . Since doped magnesium atoms in the p-type AlGaN layer 6 and p-type semiconductor layer 7 form Mg—H bonds, holes are not provided.
- the thermal process is to break the Mg—H bonds and activate the p-type AlGaN layer 6 and p-type semiconductor layer 7 .
- the thermal process is performed at a temperature ranging from 650 to 780° C. for 15 to 60 minutes.
- step 203 the p-type semiconductor layer 7 , p-type AlGaN layer 6 , active layer 5 , and n-type AlGaN layer 4 are partially etched away to expose a surface of the n-type semiconductor layer 3 .
- a part of the n-type semiconductor layer 3 is also etched away.
- electrodes 8 A and SB are formed, wherein the electrode 8 A is formed on the n-type semiconductor layer 3 , and the electrode 8 B is formed on the p-type semiconductor layer 7 .
- the electrodes 8 A and 8 B can be formed by known deposition methods such as evaporation or sputtering.
- step 205 an annealing process is performed.
- the object of this step is to lower the ohmic contact resistance of the electrodes 8 A and 8 B.
- the annealing process is generally performed at a temperature ranging from 300 to 600° C.
- the invention provides a method for manufacturing a gallium nitride-based III-V group compound semiconductor device, includes the following steps: providing a substrate having a first and a second major surfaces; forming a semiconductor stacked structure over the first major surface of the substrate, wherein the semiconductor stacked structure includes an n-type gallium nitride-based III-V group compound semiconductor layer, an active layer, and a p-type gallium nitride-based III-V group compound semiconductor layer; etching the semiconductor stacked structure to expose a part of the n-type semiconductor layer; forming a first electrode on the n-type semiconductor layer, wherein the first electrode includes an ohmic contact layer, a barrier layer over the ohmic contact layer, and a pad layer over the barrier layer; and performing an annealing process for lowering the contact resistance between the first electrode and the n-type semiconductor layer, and activating the p-type semiconductor layer simultaneously; and forming a second electrode on the p-type semiconductor layer.
- a gallium nitride-based III-V group compound semiconductor device in accordance with an embodiment of the invention includes an n-type gallium nitride-based III-V group compound semiconductor layer; and an electrode on the n-type gallium nitride-based III-V group compound semiconductor layer, and the electrode includes an ohmic contact layer, a barrier layer over the ohmic contact layer, and a pad layer over the barrier layer.
- a gallium nitride-based III-V group compound semiconductor device in accordance with another embodiment of the invention includes a substrate having a first and a second major surfaces; a semiconductor stacked structure formed over the first major surface of the substrate and which includes an n-type gallium nitride-based III-V group compound semiconductor layer, an active layer, and a p-type gallium nitride-based III-V group compound semiconductor layer; a first electrode on the n-type semiconductor layer and which includes an ohmic contact layer, a barrier layer over the ohmic contact layer, and a pad layer over the barrier layer; and a second electrode on the p-type semiconductor layer.
- the ohmic contact of the n-type GaN of the invention has thermal stability endurance much better than that of a conventional Ti/Al/Au multilayer. Therefore, the method for manufacturing the compound semiconductor device of the invention is simpler than the conventional method, and can thus lower the costs and increase the yield.
- FIG. 1 is a cross-sectional view showing a GaN-based III-V group compound semiconductor light-emitting device in accordance with the invention
- FIG. 2 is a flow chart showing fabrication steps for a conventional light-emitting device 100 ;
- FIG. 3 is a cross-sectional view showing the structure of electrode of the invention.
- FIG. 4 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/AIPt/Au in contact with n-type GaN;
- FIG. 5 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Pt/Au in contact with unrecovered Si-implanted n-type GaN;
- FIG. 6 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Pt/Au in contact with recovered Si-implanted n-type GaN;
- FIG. 7 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Au in contact with n-type GaN;
- FIG. 8 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Au in contact with unrecovered Si-implanted n-type GaN;
- FIG. 9 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Au in contact with recovered Si-implanted n-type GaN;
- FIG. 10 is a flow chart showing fabrication steps for a light-emitting device of the invention.
- gallium nitride-based III-V group compound semiconductor means a nitride semiconductor of III group element including gallium such as GaN, AlGaN, InGaN, or InAlGaN.
- the invention provides a structure of electrode 8 A which includes an ohmic contact layer including such as nitride titanium, titanium, aluminum, chromium, indium, palladium, or an alloy from above-mentioned metals; a barrier layer over the ohmic contact layer including such as platinum, tungsten (W), or nickel; and a pad layer over the barrier layer including such as gold. Since the electrode 8 A of the invention has a barrier layer, the gold of pad layer is prevented from interdiffusing and penetrating into the semiconductor device.
- an ohmic contact layer including such as nitride titanium, titanium, aluminum, chromium, indium, palladium, or an alloy from above-mentioned metals
- a barrier layer over the ohmic contact layer including such as platinum, tungsten (W), or nickel
- a pad layer over the barrier layer including such as gold. Since the electrode 8 A of the invention has a barrier layer, the gold of pad layer is prevented from interdiffusing and penetrating
- FIG. 3 shows an example of the electrode 8 A of the invention.
- Layers of the structure shown in FIG. 3 are labeled with same reference numerals designating corresponding layers shown in FIG. 1.
- a GaN buffer layer 2 is formed on a substrate 1 .
- An n-type semiconductor layer 3 is formed on the buffer layer 2 .
- the n-type semiconductor layer 3 can be doped with silicon.
- An electrode 8 A is formed on the n-type semiconductor layer 3 .
- the electrode 8 A includes a titanium layer 81 , an aluminum layer 82 formed on the titanium layer 81 , a platinum layer 83 formed on the aluminum layer 82 , and a gold layer 84 formed on the platinum layer 83 .
- the electrode 8 A Ti/Al/Pt/Au
- Ti Ti/Al/Pt/Au
- a 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C.
- a 2 ⁇ m n-type GaN layer is formed on the GaN buffer layer by metal organic chemical vapor deposition (MOCVD) at 1100° C., wherein the carrier concentration and mobility are 6.7 ⁇ 10 17 cm ⁇ 3 and 367 cm 2 /V-S, respectively.
- MOCVD metal organic chemical vapor deposition
- the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the n-type GaN layer.
- samples are annealed in nitrogen (N 2 ) atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances ( ⁇ C ) are measured.
- N 2 nitrogen
- ⁇ C specific contact resistance
- a 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C.
- a 2 ⁇ m n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7 ⁇ 10 17 cm ⁇ 3 and 367 cm 2 /V-S, respectively.
- Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5 ⁇ 10 15 cm ⁇ 2 .
- the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the Si-implanted n-type GaN layer.
- the samples are annealed under N 2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances ( ⁇ C ) are measured.
- Experimental results are shown in FIG. 5.
- a 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C.
- a 2 ⁇ m n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7 ⁇ 10 17 cm ⁇ 3 and 367 cm 2 V-S, respectively.
- Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5 ⁇ 10 15 cm ⁇ 2 .
- the Si-implanted n-type GaN layer is annealed at 1050° C. under N 2 atmosphere for 30 minutes, to aid in the recovery of crystal and to activate implanted Si of the n-type GaN layer.
- the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the Si-implanted and recovered n-type GaN layer.
- the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the Si-implanted and recovered n-type GaN layer.
- samples are annealed under N 2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances ( ⁇ C ) are measured. Experimental results are shown in FIG. 6.
- a 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C.
- a 2 ⁇ m n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7 ⁇ 10 17 cm ⁇ 3 and 367 cm 2 /V-S, respectively.
- a comparative electrode Ti/Al/Au 25/100/200 nm is formed on the n-type GaN layer.
- samples are annealed under N 2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances ( ⁇ C ) are measured.
- Experimental results are shown in FIG. 7.
- a 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C.
- a 2 ⁇ m n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7 ⁇ 10 17 cm ⁇ 3 and 367 cm 2 /V-S, respectively.
- Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5 ⁇ 10 15 cm ⁇ 2 .
- a comparative electrode Ti/Al/Au 25/100/200 nm is formed on the Si-implanted n-type GaN layer.
- samples are annealed under N 2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances ( ⁇ C ) are measured.
- Experimental results are shown in FIG. 8.
- a 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C.
- a 2 ⁇ m n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7 ⁇ 10 17 cm ⁇ 3 and 367 cm 2 /V-S, respectively.
- Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5 ⁇ 10 15 cm ⁇ 2 .
- the Si-implanted n-type GaN layer is annealed at 1050° C. under N 2 atmosphere for 30 minutes, to aid in the recovery of crystal and to activate implanted Si of the n-type GaN layer.
- a comparative electrode Ti/Al/Au 25/100/200 nm is formed on the Si-implanted and recovered n-type GaN layer.
- a comparative electrode Ti/Al/Au 25/100/200 nm is formed on the Si-implanted and recovered n-type GaN layer.
- samples are annealed under N 2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances ( ⁇ C ) are measured. Experimental results are shown in FIG. 9.
- Table 1 below shows details of each of the Examples of the invention. TABLE 1 Example Example Comparative Comparative Comparative 1 2 3 Example 1 Example 2 Example 3 Si-implanted ⁇ ⁇ ⁇ ⁇ Recovery ⁇ ⁇ Ti/Al/Au ⁇ ⁇ ⁇ Ti/Al/Pt/Au ⁇ ⁇ ⁇ Results shown in
- Example 1 is for the electrode Ti/Al/Pt/Au of the invention in contact with n-type GaN
- FIG. 4 is a graph showing the dependence of the specific contact resistance ⁇ C for Ti/Al/Pt/Au in contact with GaN on the annealing time at various annealing temperatures.
- the lowest specific contact resistance ⁇ C is about 8 ⁇ 10 ⁇ 6 ⁇ -cm 2 for 750° C., 7 ⁇ 10 ⁇ 6 ⁇ -cm 2 for 850° C., and 7 ⁇ 10 ⁇ 6 ⁇ -cm 2 for 950° C.
- Comparative Example 1 is for the electrode Ti/Al/Au in contact with n-type GaN, and FIG.
- FIG. 7 is a graph showing he dependence of the specific contact resistance ⁇ C for Ti/Al/Au in contact with GaN on annealing time at various annealing temperatures.
- Example 2 is for the electrode Ti/Al/Pt/Au in contact with unrecovered Si-implanted n-type GaN
- FIG. 5 is a graph showing the dependence of the specific contact resistance ⁇ C for Ti/Al/Pt/Au in contact with Si-implanted GaN on annealing time at various annealing temperatures.
- Comparative Example 2 is for the electrode Ti/Al/Au in contact with unrecovered Si-implanted n-type GaN
- FIG. 8 is a graph showing the dependence of the specific contact resistance ⁇ C for Ti/Al/Au in contact with Si-implanted GaN on annealing time at various annealing temperatures. As shown in FIGS.
- the minimum specific contact resistance ⁇ C is 7 ⁇ 10 ⁇ 4 ⁇ -cm 2 for 750° C. (beyond 600 minutes), 7 ⁇ 10 ⁇ 5 ⁇ -cm 2 for 850° C. (at 540 minutes), and 2 ⁇ 10 ⁇ 5 ⁇ -cm 2 for 950° C. (at 60 minutes).
- the electrode Ti/Al/Pt/Au of the invention has a much better thermal stability than that of the comparative electrode Ti/Al/Au.
- the thermal stability endurance for the ohmic performance of the Ti/Al/Pt/Au multilayer annealed at 850° C. and 950° C. is about 540 minutes and 60 minutes, respectively, but longer than 600 minutes for annealing at 750° C.
- Example 3 is for the electrode Ti/Al/Pt/Au in contact with Si-implanted and recovered n-type GaN
- FIG. 6 is a graph showing the dependence of the specific contact resistance ⁇ C for the Ti/Al/Pt/Au in contact with recovered Si-implanted GaN on annealing time at various annealing temperatures.
- the minimum specific contact resistance ⁇ C is about 3 ⁇ 10 ⁇ 6 ⁇ -cm 2 for annealing temperatures of 750° C., 850° C., and 950° C.
- Comparative Example 3 is for the electrode Ti/Al/Au in contact with Si-implanted and recovered n-type GaN, and FIG.
- FIGS. 9 is a graph showing the dependence of specific contact resistance ⁇ C for the Ti/Al/Au in contact with recovered Si-implanted GaN on annealing time at various annealing temperatures.
- the comparative electrode Ti/Al/Au and the electrode Ti/Al/Pt/Au of the invention have similar minimum specific contact resistance at the same annealing temperature.
- the electrode Ti/Al/Pt/Au of the invention has a much better thermal stability endurance than that of the Ti/Al/Au multilayer.
- a thermal process is performed after forming the p-type semiconductor layer 7 so as to break the Mg—H bonds and activate the p-type AlGaN layer 6 and the p-type semiconductor layer 7 .
- the thermal process is performed generally at a temperature ranging from 700 to 750° C. for 15 to 60 minutes.
- the fabrication process for the light-emitting device of the invention can omit the conventional activation step, and achieve the same effect in a subsequent fabrication step.
- the fabrication process of the light-emitting device in accordance with the invention is described below with reference being made to FIG. 10.
- a buffer layer 2 , an n-type semiconductor layer 3 , an n-type AlGaN layer 4 , an active layer 5 , a p-type AlGaN layer 6 , and a p-type semiconductor layer 7 are formed on the substrate 1 in this order.
- step 102 the p-type semiconductor layer 7 , p-type AlGaN layer 6 , active layer 5 , and n-type AlGaN layer 4 are partially etched away to expose a surface of the n-type semiconductor layer 3 .
- a part of the n-type semiconductor layer 3 is also etched away.
- an electrode 8 A is formed on the n-type semiconductor layer 3 .
- the electrodes 8 A can be formed by known deposition methods such as evaporation or sputtering. Besides, as described in above-mentioned examples, before forming the electrode 8 A on the n-type semiconductor layer 3 , a step of implanting silicon atoms into the n-type semiconductor layer and a recovery of the n-type semiconductor layer can be performed.
- step 104 an annealing process is performed.
- the object of this step is to lower the ohmic contact resistance of the electrode 8 A.
- the annealing process is performed at a temperature ranging from 400 to 950° C. Under this annealing condition, activating effect of the p-type semiconductor layer 7 can be achieved at the same time.
- the electrode 8 B is formed on the p-type semiconductor layer 7 by such as evaporation or sputtering. After forming the electrode 8 B, an annealing at a low-temperature of below 700° C. can be performed to lower the ohmic contact resistance of the electrode 8 B.
- the method for manufacturing a compound semiconductor device provided by the invention is simpler than conventional fabrication processes, which can lower the costs and increase the yield.
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Abstract
The invention provides a method for manufacturing a gallium nitride-based III-V group compound semiconductor device, which comprises the following steps: forming a semiconductor stacked structure over a substrate, wherein the semiconductor stacked structure comprises an n-type semiconductor layer, an active layer, and a p-type semiconductor layer; etching the semiconductor stacked structure to expose a part of the n-type semiconductor layer; forming a first electrode on the n-type semiconductor layer, wherein the first electrode comprises an ohmic contact layer, a barrier layer, and a pad layer; performing an annealing process to lower the contact resistance between the first electrode and the n-type semiconductor layer and activate the p-type semiconductor layer at the same time; and forming a second electrode on the p-type semiconductor layer.
Description
- This is a divisional application of co-pending prior U.S. application Ser. No. 09/671,946, filed on Sep. 27, 2000. This application is hereby incorporated by reference.
- 1. Field of the Invention
- The invention relates to a gallium nitride-based III-V group compound semiconductor device and method for manufacturing the same.
- 2. Description of the Related Art
- Since epitaxial layers of III-V group nitride such as gallium nitride (GaN), aluminum gallium nitride (AlGaN), indium gallium nitride (InGaN), and aluminum indium gallium nitride (AlInGaN) were first grown successfully, they have become promising materials for use in high temperature/high power electronic devices and opotoelectronic devices, due to their high direct band gap, high saturation drift velocity, high breakdown field, and chemical inertness. Recent improvements in crystal quality of epitaxial layers with increased dopant concentrations have led to high quality laser diodes, light-emitting diodes, photodetectors, and microwave field effect transistors having been developed based on these epitaxial III-V group nitride structures.
- In general, the performance of III-V group nitride device has been limited by contact resistance. Therefore, a key technology in achieving higher performance for III-V group nitride devices is the realization of more reliable metal contacts. Although a wide group nitride devices is the realization of more reliable metal contacts. Although a wide variety of metals used as contacts with GaN have been reported, the metallic titanium/aluminum (Ti/Al) bilayer has been most widely used as a conventional ohmic contact for n-type GaN. However, such a Ti/Al bilayer is prone to oxidation, which in turn leads to high ohmic resistance during the fabrication process and during operation.
- To avoid the oxidation propensity at elevated temperatures, a low resistivity gold (Au) layer should be effective for passivating the Ti/Al bilayer. However, gold would interdiffuse and penetrate into the GaN semiconductor layer, causing deterioration in thermal stability, and ohmic contact property of the semiconductor device.
- FIG. 1 is a cross-sectional view showing a typical structure of a GaN-based III-V group compound semiconductor light-emitting device (LED)100.
- As shown in FIG. 1, an
LED 100 includes aninsulated substrate 1 made of such as sapphire. Thesubstrate 1 has a first major surface 1 a and a secondmajor surface 1 b. AGaN buffer layer 2 is formed on the first major surface 1 a of thesubstrate 1. An n-type GaN-based III-V groupcompound semiconductor layer 3 is formed on thebuffer layer 2. The n-type semiconductor layer 3 is doped by n-type dopants such as germanium (Ge), selenium (Se), sulfur (S), or tellurium (Te). In addition, the n-type semiconductor layer 3 can be doped by silicon (Si). - An n-
type AlGaN layer 4 is formed on the n-type semiconductor layer 3. Anactive layer 5 is formed on the n-type AlGaN layer 4, and theactive layer 5 has a multiple quantum well (MQW) structure, a single quantum well (SQW) structure, or a double-heterostructure (DH) made of such as InGaN/GaN. A p-type AlGaN layer 6 is formed on theactive layer 5. The p-type AlGaN layer 6 is doped with p-type dopants such as beryllium (Be), strontium (Sr), barium (Ba), zinc (Zn), or magnesium. - A p-type GaN-based III-V group
compound semiconductor layer 7 is formed on the p-type AlGaN layer 6. The p-type semiconductor layer 7 is doped with p-type dopants such as beryllium, strontium, barium, zinc, or magnesium. - As shown in FIG. 1, the
LED 100 includes anelectrode 8A formed on the n-type semiconductor layer 3 and anelectrode 8B formed on the p-type semiconductor layer 7. Conventionally, theelectrode 8A includes a metal such as titanium, aluminum, or gold as mentioned above. Theelectrode 8B is a kind of ohmic electrode, it includes a metal such as nickel (Ni), chromium (Cr), gold or platinum. - Referring to FIG. 2, the flow chart shows conventional steps for manufacturing a light-
emitting device 100. - First, as shown in
step 201, abuffer layer 2, an n-type semiconductor layer 3, an n-type AlGaN layer 4, anactive layer 5, a p-type AlGaN layer 6, and a p-type semiconductor layer 7 are formed on asubstrate 1 in this order. - Next, as shown in
step 202, a thermal process is performed to activate the p-type AlGaN layer 6 and the p-type semiconductor layer 7. Since doped magnesium atoms in the p-type AlGaN layer 6 and p-type semiconductor layer 7 form Mg—H bonds, holes are not provided. The thermal process is to break the Mg—H bonds and activate the p-type AlGaN layer 6 and p-type semiconductor layer 7. The thermal process is performed at a temperature ranging from 650 to 780° C. for 15 to 60 minutes. - Then, as shown in
step 203, the p-type semiconductor layer 7, p-type AlGaN layer 6,active layer 5, and n-type AlGaN layer 4 are partially etched away to expose a surface of the n-type semiconductor layer 3. Here, a part of the n-type semiconductor layer 3 is also etched away. - Next, as shown in
step 204,electrodes 8A and SB are formed, wherein theelectrode 8A is formed on the n-type semiconductor layer 3, and theelectrode 8B is formed on the p-type semiconductor layer 7. Theelectrodes - Next, as shown in
step 205, an annealing process is performed. The object of this step is to lower the ohmic contact resistance of theelectrodes - It should be noted that besides forming the
electrodes step 204, it can also be first forming theelectrode 8A, and after the annealing process, forming theelectrode 8B. - The invention provides a method for manufacturing a gallium nitride-based III-V group compound semiconductor device, includes the following steps: providing a substrate having a first and a second major surfaces; forming a semiconductor stacked structure over the first major surface of the substrate, wherein the semiconductor stacked structure includes an n-type gallium nitride-based III-V group compound semiconductor layer, an active layer, and a p-type gallium nitride-based III-V group compound semiconductor layer; etching the semiconductor stacked structure to expose a part of the n-type semiconductor layer; forming a first electrode on the n-type semiconductor layer, wherein the first electrode includes an ohmic contact layer, a barrier layer over the ohmic contact layer, and a pad layer over the barrier layer; and performing an annealing process for lowering the contact resistance between the first electrode and the n-type semiconductor layer, and activating the p-type semiconductor layer simultaneously; and forming a second electrode on the p-type semiconductor layer.
- A gallium nitride-based III-V group compound semiconductor device in accordance with an embodiment of the invention includes an n-type gallium nitride-based III-V group compound semiconductor layer; and an electrode on the n-type gallium nitride-based III-V group compound semiconductor layer, and the electrode includes an ohmic contact layer, a barrier layer over the ohmic contact layer, and a pad layer over the barrier layer.
- A gallium nitride-based III-V group compound semiconductor device in accordance with another embodiment of the invention includes a substrate having a first and a second major surfaces; a semiconductor stacked structure formed over the first major surface of the substrate and which includes an n-type gallium nitride-based III-V group compound semiconductor layer, an active layer, and a p-type gallium nitride-based III-V group compound semiconductor layer; a first electrode on the n-type semiconductor layer and which includes an ohmic contact layer, a barrier layer over the ohmic contact layer, and a pad layer over the barrier layer; and a second electrode on the p-type semiconductor layer.
- The ohmic contact of the n-type GaN of the invention has thermal stability endurance much better than that of a conventional Ti/Al/Au multilayer. Therefore, the method for manufacturing the compound semiconductor device of the invention is simpler than the conventional method, and can thus lower the costs and increase the yield.
- FIG. 1 is a cross-sectional view showing a GaN-based III-V group compound semiconductor light-emitting device in accordance with the invention;
- FIG. 2 is a flow chart showing fabrication steps for a conventional light-
emitting device 100; - FIG. 3 is a cross-sectional view showing the structure of electrode of the invention;
- FIG. 4 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/AIPt/Au in contact with n-type GaN;
- FIG. 5 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Pt/Au in contact with unrecovered Si-implanted n-type GaN;
- FIG. 6 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Pt/Au in contact with recovered Si-implanted n-type GaN;
- FIG. 7 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Au in contact with n-type GaN;
- FIG. 8 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Au in contact with unrecovered Si-implanted n-type GaN;
- FIG. 9 is a graph showing the dependence of specific contact resistance on annealing time at various annealing temperatures for the electrode Ti/Al/Au in contact with recovered Si-implanted n-type GaN; and
- FIG. 10 is a flow chart showing fabrication steps for a light-emitting device of the invention.
- In the invention, a term “gallium nitride-based III-V group compound semiconductor” means a nitride semiconductor of III group element including gallium such as GaN, AlGaN, InGaN, or InAlGaN.
- The invention is described in detail below with references being made to relevant drawings.
- The invention provides a structure of
electrode 8A which includes an ohmic contact layer including such as nitride titanium, titanium, aluminum, chromium, indium, palladium, or an alloy from above-mentioned metals; a barrier layer over the ohmic contact layer including such as platinum, tungsten (W), or nickel; and a pad layer over the barrier layer including such as gold. Since theelectrode 8A of the invention has a barrier layer, the gold of pad layer is prevented from interdiffusing and penetrating into the semiconductor device. - Referring to FIG. 3, which shows an example of the
electrode 8A of the invention. Layers of the structure shown in FIG. 3 are labeled with same reference numerals designating corresponding layers shown in FIG. 1. As shown in FIG. 3, aGaN buffer layer 2 is formed on asubstrate 1. An n-type semiconductor layer 3 is formed on thebuffer layer 2. The n-type semiconductor layer 3 can be doped with silicon. Anelectrode 8A is formed on the n-type semiconductor layer 3. Theelectrode 8A includes atitanium layer 81, analuminum layer 82 formed on thetitanium layer 81, aplatinum layer 83 formed on thealuminum layer 82, and agold layer 84 formed on theplatinum layer 83. Theelectrode 8A (Ti/Al/Pt/Au) as an example is illustrated below with its superior property as an ohmic contact for n-type GaN. - A 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C. Next, a 2 μm n-type GaN layer is formed on the GaN buffer layer by metal organic chemical vapor deposition (MOCVD) at 1100° C., wherein the carrier concentration and mobility are 6.7×1017 cm−3 and 367 cm2/V-S, respectively.
- Next, the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the n-type GaN layer. Thus formed samples are annealed in nitrogen (N2) atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances (ρC) are measured. Experimental results are shown in FIG. 4.
- A 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C. Next, a 2 μm n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7×1017 cm−3 and 367 cm2/V-S, respectively. Then, Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5×1015 cm−2.
- Next, the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the Si-implanted n-type GaN layer. Thus formed samples are annealed under N2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances (ρC) are measured. Experimental results are shown in FIG. 5.
- A 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C. Next, a 2 μm n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7×1017 cm−3 and 367 cm2 V-S, respectively. Then, Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5×1015 cm−2. Next, the Si-implanted n-type GaN layer is annealed at 1050° C. under N2 atmosphere for 30 minutes, to aid in the recovery of crystal and to activate implanted Si of the n-type GaN layer.
- Then, the electrode Ti/Al/Pt/Au (25/100/50/200 nm) of the invention is formed on the Si-implanted and recovered n-type GaN layer. Thus formed samples are annealed under N2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances (ρC) are measured. Experimental results are shown in FIG. 6.
- A 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C. Next, a 2 μm n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7×1017 cm−3 and 367 cm2/V-S, respectively.
- Then, a comparative electrode Ti/Al/Au (25/100/200 nm) is formed on the n-type GaN layer. Thus formed samples are annealed under N2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances (ρC) are measured. Experimental results are shown in FIG. 7.
- A 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C. Next, a 2 μm n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7×1017 cm−3 and 367 cm2/V-S, respectively.
- Then, Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5×1015 cm−2.
- Next, a comparative electrode Ti/Al/Au (25/100/200 nm) is formed on the Si-implanted n-type GaN layer. Thus formed samples are annealed under N2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances (ρC) are measured. Experimental results are shown in FIG. 8.
- A 300 nm GaN buffer layer is grown on a sapphire substrate at 520° C. Next, a 2 μm n-type GaN layer is formed on the GaN buffer layer by MOCVD at 1100° C., wherein the carrier concentration and mobility are 6.7×1017 cm−3 and 367 cm2/V-S, respectively. Then, Si is implanted into the n-type GaN layer at an energy of 50 KeV and a dose of 5×1015 cm−2. Next, the Si-implanted n-type GaN layer is annealed at 1050° C. under N2 atmosphere for 30 minutes, to aid in the recovery of crystal and to activate implanted Si of the n-type GaN layer.
- Then, a comparative electrode Ti/Al/Au (25/100/200 nm) is formed on the Si-implanted and recovered n-type GaN layer. Thus formed samples are annealed under N2 atmosphere at various temperatures (750° C., 850° C., and 950° C.) and various times, and specific contact resistances (ρC) are measured. Experimental results are shown in FIG. 9.
- Table 1 below shows details of each of the Examples of the invention.
TABLE 1 Example Example Example Comparative Comparative Comparative 1 2 3 Example 1 Example 2 Example 3 Si-implanted ✓ ✓ ✓ ✓ Recovery ✓ ✓ Ti/Al/Au ✓ ✓ ✓ Ti/Al/Pt/Au ✓ ✓ ✓ Results shown in - Example 1 is for the electrode Ti/Al/Pt/Au of the invention in contact with n-type GaN, and FIG. 4 is a graph showing the dependence of the specific contact resistance ρC for Ti/Al/Pt/Au in contact with GaN on the annealing time at various annealing temperatures. In FIG. 4, the lowest specific contact resistance ρC is about 8×10−6 Ω-cm2 for 750° C., 7×10−6 Ω-cm2 for 850° C., and 7×10−6 Ω-cm2 for 950° C. Comparative Example 1 is for the electrode Ti/Al/Au in contact with n-type GaN, and FIG. 7 is a graph showing he dependence of the specific contact resistance ρC for Ti/Al/Au in contact with GaN on annealing time at various annealing temperatures. When comparing FIG. 4 and FIG. 7 we found that the Ti/Al/Pt/Au and Ti/Al/Au multilayer contacts on n-type GaN exhibit similar values of minimum specific contact resistance. However, the Ti/Al/Pt/Au multilayer has a much better thermal stability endurance than that of the Ti/Al/Au multilayer.
- Example 2 is for the electrode Ti/Al/Pt/Au in contact with unrecovered Si-implanted n-type GaN, and FIG. 5 is a graph showing the dependence of the specific contact resistance ρC for Ti/Al/Pt/Au in contact with Si-implanted GaN on annealing time at various annealing temperatures. Comparative Example 2 is for the electrode Ti/Al/Au in contact with unrecovered Si-implanted n-type GaN, and FIG. 8 is a graph showing the dependence of the specific contact resistance ρC for Ti/Al/Au in contact with Si-implanted GaN on annealing time at various annealing temperatures. As shown in FIGS. 5 and 8, at the annealing temperature of 750° C., the two kinds of electrode have a similar dependence of specific contact resistance on annealing time for 60 minutes. It is to be noted that in Comparative Example 2, a minimum specific contact resistance is obtained at 60 minutes for 750° C., but after 60 minutes the specific contact resistance greatly increases as the time increases. However, in Example 2, as shown in FIG. 5, when annealing at 750° C., the specific contact resistance gradually decreases as the increase of annealing time.
- In FIG. 5, the minimum specific contact resistance ρC is 7×10−4 Ω-cm2 for 750° C. (beyond 600 minutes), 7×10−5 Ω-cm2 for 850° C. (at 540 minutes), and 2×10−5 Ω-cm2 for 950° C. (at 60 minutes). In accordance with the experimental results shown in FIG. 5 and FIG. 8, the electrode Ti/Al/Pt/Au of the invention has a much better thermal stability than that of the comparative electrode Ti/Al/Au. The thermal stability endurance for the ohmic performance of the Ti/Al/Pt/Au multilayer annealed at 850° C. and 950° C. is about 540 minutes and 60 minutes, respectively, but longer than 600 minutes for annealing at 750° C.
- Example 3 is for the electrode Ti/Al/Pt/Au in contact with Si-implanted and recovered n-type GaN, and FIG. 6 is a graph showing the dependence of the specific contact resistance ρC for the Ti/Al/Pt/Au in contact with recovered Si-implanted GaN on annealing time at various annealing temperatures. In FIG. 6, the minimum specific contact resistance ρC is about 3×10−6 Ω-cm2 for annealing temperatures of 750° C., 850° C., and 950° C. Comparative Example 3 is for the electrode Ti/Al/Au in contact with Si-implanted and recovered n-type GaN, and FIG. 9 is a graph showing the dependence of specific contact resistance ρC for the Ti/Al/Au in contact with recovered Si-implanted GaN on annealing time at various annealing temperatures. When comparing the experimental results shown in FIGS. 6 and 9, the comparative electrode Ti/Al/Au and the electrode Ti/Al/Pt/Au of the invention have similar minimum specific contact resistance at the same annealing temperature. However, the electrode Ti/Al/Pt/Au of the invention has a much better thermal stability endurance than that of the Ti/Al/Au multilayer.
- As mentioned above, since the doped magnesium atoms in the p-
type AlGaN layer 6 and the p-type semiconductor layer 7 would form Mg—H bonds and holes are not provided, conventionally a thermal process is performed after forming the p-type semiconductor layer 7 so as to break the Mg—H bonds and activate the p-type AlGaN layer 6 and the p-type semiconductor layer 7. The thermal process is performed generally at a temperature ranging from 700 to 750° C. for 15 to 60 minutes. However, since the Ti/Al/Pt/Au multilayer of the invention has a high thermal stability endurance, it is beyond question that the activating effect of the p-type AlGaN layer 6 and the p-type semiconductor layer 7 can be achieved at the same time when the ohmic contact is formed in the annealing process. Therefore, the fabrication process for the light-emitting device of the invention can omit the conventional activation step, and achieve the same effect in a subsequent fabrication step. The fabrication process of the light-emitting device in accordance with the invention is described below with reference being made to FIG. 10. - First, as shown in
step 101, abuffer layer 2, an n-type semiconductor layer 3, an n-type AlGaN layer 4, anactive layer 5, a p-type AlGaN layer 6, and a p-type semiconductor layer 7 are formed on thesubstrate 1 in this order. - Next, as shown in
step 102, the p-type semiconductor layer 7, p-type AlGaN layer 6,active layer 5, and n-type AlGaN layer 4 are partially etched away to expose a surface of the n-type semiconductor layer 3. Here, a part of the n-type semiconductor layer 3 is also etched away. - Next, as shown in
step 103, anelectrode 8A is formed on the n-type semiconductor layer 3. Theelectrodes 8A can be formed by known deposition methods such as evaporation or sputtering. Besides, as described in above-mentioned examples, before forming theelectrode 8A on the n-type semiconductor layer 3, a step of implanting silicon atoms into the n-type semiconductor layer and a recovery of the n-type semiconductor layer can be performed. - Then, as shown in
step 104, an annealing process is performed. The object of this step is to lower the ohmic contact resistance of theelectrode 8A. The annealing process is performed at a temperature ranging from 400 to 950° C. Under this annealing condition, activating effect of the p-type semiconductor layer 7 can be achieved at the same time. - Next, as shown in
step 105, theelectrode 8B is formed on the p-type semiconductor layer 7 by such as evaporation or sputtering. After forming theelectrode 8B, an annealing at a low-temperature of below 700° C. can be performed to lower the ohmic contact resistance of theelectrode 8B. - As above, since the annealing and activating effect can be achieved at the same time in
step 104, the method for manufacturing a compound semiconductor device provided by the invention is simpler than conventional fabrication processes, which can lower the costs and increase the yield. - While the present invention has been particularly described, in conjunction with specific examples, it is evident that many alternatives, modifications and variations will be apparent to those skilled in the art in light of the foregoing description. It is therefore contemplated that the appended claims will embrace any such alternatives, modifications and variations as falling within the true scope and spirit of the present invention.
Claims (6)
1. A gallium nitride-based III-V group compound semiconductor device, comprising:
an n-type gallium nitride-based III-V group compound semiconductor layer; and
an electrode on said n-type gallium nitride-based III-V group compound semiconductor layer, and said electrode having an ohmic contact layer, a barrier layer over said ohmic contact layer, and a pad layer over said barrier layer.
2. The device as in claim 1 , wherein said barrier layer comprises platinum, tungsten, or nickel.
3. The device as in claim 1 , wherein said electrode is composed of titanium/aluminum/platinum/gold.
4. A gallium nitride-based III-V group compound semiconductor device, comprising:
a substrate having a first and a second major surfaces;
a semiconductor stacked structure formed over the first major surface of said substrate, and said semiconductor stacked structure having an n-type gallium nitride-based III-V group compound semiconductor layer, an active layer, and a p-type gallium nitride-based III-V group compound semiconductor layer;
a first electrode on the n-type semiconductor layer, and said first electrode having an ohmic contact layer, a barrier layer over said ohmic contact layer, and a pad layer over said barrier layer; and
a second electrode on the p-type semiconductor layer.
5. The device as in claim 4 , wherein said barrier layer comprises platinum, tungsten, or nickel.
6. The device as in claim 4 , wherein said electrode is composed of titanium/aluminum/platinum/gold.
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JP (1) | JP2002057321A (en) |
DE (1) | DE10048196A1 (en) |
TW (1) | TW451504B (en) |
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EP1450415A3 (en) * | 1993-04-28 | 2005-05-04 | Nichia Corporation | Gallium nitride-based III-V group compound semiconductor device |
US5777350A (en) * | 1994-12-02 | 1998-07-07 | Nichia Chemical Industries, Ltd. | Nitride semiconductor light-emitting device |
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US6198116B1 (en) * | 1998-04-14 | 2001-03-06 | The United States Of America As Represented By The Secretary Of The Air Force | Complementary heterostructure integrated single metal transistor fabrication method |
JP3804335B2 (en) * | 1998-11-26 | 2006-08-02 | ソニー株式会社 | Semiconductor laser |
-
2000
- 2000-07-28 TW TW089115205A patent/TW451504B/en not_active IP Right Cessation
- 2000-09-27 US US09/671,946 patent/US6531383B1/en not_active Expired - Lifetime
- 2000-09-28 DE DE10048196A patent/DE10048196A1/en not_active Ceased
- 2000-10-25 JP JP2000325170A patent/JP2002057321A/en active Pending
-
2002
- 2002-11-15 US US10/295,407 patent/US20030073274A1/en not_active Abandoned
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20040084697A1 (en) * | 2002-10-18 | 2004-05-06 | Youn Doo Hyeb | Nitride semiconductor field effect transistor (FET) and method of fabricating the same |
US6864510B2 (en) * | 2002-10-18 | 2005-03-08 | Electronics And Telecommunications Research Institute | Nitride semiconductor field effect transistor (FET) and method of fabricating the same |
US20080017870A1 (en) * | 2006-04-04 | 2008-01-24 | Georg Diamantidis | Semiconductor light-emitting means and light-emitting panel comprising the same |
Also Published As
Publication number | Publication date |
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US6531383B1 (en) | 2003-03-11 |
DE10048196A1 (en) | 2002-02-14 |
JP2002057321A (en) | 2002-02-22 |
TW451504B (en) | 2001-08-21 |
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