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US20030033904A1 - Forged article with prealloyed powder - Google Patents

Forged article with prealloyed powder Download PDF

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Publication number
US20030033904A1
US20030033904A1 US09/919,426 US91942601A US2003033904A1 US 20030033904 A1 US20030033904 A1 US 20030033904A1 US 91942601 A US91942601 A US 91942601A US 2003033904 A1 US2003033904 A1 US 2003033904A1
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Prior art keywords
powder
prealloyed
copper
forged
weight percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US09/919,426
Inventor
Edmond Ilia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Masco Corp
Metaldyne Sintered Components Inc
Original Assignee
Masco Corp
Metaldyne Sintered Components Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Masco Corp, Metaldyne Sintered Components Inc filed Critical Masco Corp
Priority to US09/919,426 priority Critical patent/US20030033904A1/en
Assigned to MASCO CORPORATION reassignment MASCO CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ILIA, EDMOND
Assigned to METALDYNE SINTERED COMPONENTS, INC. reassignment METALDYNE SINTERED COMPONENTS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ILIA, EDMOND
Priority to PCT/US2002/023732 priority patent/WO2003011498A1/en
Publication of US20030033904A1 publication Critical patent/US20030033904A1/en
Priority to US10/417,834 priority patent/US20030196511A1/en
Assigned to JPMORGAN CHASE BANK, AS COLLATERAL AGENT reassignment JPMORGAN CHASE BANK, AS COLLATERAL AGENT SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: METALDYNE CORPORATION
Assigned to METALDYNE CORPORATION reassignment METALDYNE CORPORATION TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Assignors: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Abandoned legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C7/00Connecting-rods or like links pivoted at both ends; Construction of connecting-rod heads
    • F16C7/02Constructions of connecting-rods with constant length
    • F16C7/023Constructions of connecting-rods with constant length for piston engines, pumps or the like
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0207Using a mixture of prealloyed powders or a master alloy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy

Definitions

  • This invention relates to forged articles made from ferrous powder prealloyed with manganese and sulfur. More specifically, the forged articles are forged engine connecting rods.
  • the connecting rod manufacturing process involves pressure molding metal particles in a closed mold under significant pressure to produce a green compact form of the rod.
  • the green compact is heated in a furnace sufficiently to form a sintered preform in which metal particles are bonded.
  • the sintered preform is hot forged to final rod shape which increases the rod's density and strength.
  • the automobile industry continues to challenge connecting rod manufacturers to increase the fatigue strength of these articles. As a result, higher performance materials are needed for forged connecting rods.
  • the goal is to engineer a powder metal blend to manufacture connecting rods with the following characteristics: high strength; good machinability; reasonable cost, good weight and dimensional control. Our research included materials considerations; metallurgical and microstructure evaluation; dimensional change measurements; tensile strength; fatigue strength and machinability tests.
  • the forged articles or connecting rods of this invention are made from ferrous based powder prealloyed with manganese and sulfur.
  • the prealloyed powder then is admixed with copper at higher than normal copper contents.
  • Materials considered were as follows. In a first approach, I thought that increasing Cu content from 2% to 3% or even 4% would improve the strength of connecting rods for the following reasons: Cu strengthens the ferrite, Cu hardens the ferrite, and Cu hinders grain growth after forging.
  • the resulting forged connecting rods had an improvement in tensile strength and an improvement in fatigue strength.
  • FIG. 1 is a perspective view of a forged connecting rod.
  • the methods for preparing the prealloyed powder may vary widely.
  • the powder is prepared by atomization of a molten metal stream of iron, manganese and sulfur.
  • the resulting particles usually have an irregular spherical shape.
  • the atomized particles can be collected after solidification and subjected to annealing at 1700° F. for about 11 ⁇ 2 hours, followed by grinding to break up particle cakes, and then passed through an 80 mesh sieve.
  • the prealloyed ferrous powder then is mixed with copper and graphite at room temperature.
  • the copper powder generally has a purity of 99%.
  • the copper powder and carbon (graphite flake powder), however, are commercial grade materials.
  • the copper powder is mixed in a range of 2.0 to 5.0% by weight of the mixture.
  • the graphite powder is added to yield a final carbon content in the product ranging from 0.2 to 1.0 weight percent.
  • FIG. 1 illustrates forged connecting rod 10 .
  • Rod 10 has an elongated configuration extending along longitudinal axis A-A.
  • Rod 10 includes midportion 12 ; small end portion 14 ; and large end portion 16 .
  • Bore 18 is formed through small end portion 14 adapted to receive a wrist or piston pin (not shown) as is well known in the engine art.
  • Aperture 20 is formed through large diameter end 16 and is adapted to receive a journal of a crankshaft (not shown) as is well known in the engine art.
  • Large end portion 16 has a side thrust face 22 .
  • Rod 10 includes large end portion 16 having a pair of oppositely facing edges or end surfaces 24 . In the particular design of the connecting rod shown in FIG.
  • side thrust face 22 is in a raised plane with respect to the remaining side surface 26 .
  • Side thrust face 22 also includes a pair of radially outwardly extending portions 28 , 30 located to either side of aperture 20 . Portions 28 , 30 extend radially outward from aperture 20 and terminate at end of edges 24 .
  • FIG. 1 also shows a pair of slits or creases 32 , 34 formed in the side thrust face including extensions 28 , 30 .
  • Each crease 32 , 34 is arranged to one side of aperture 20 and they are substantially aligned across aperture 20 .
  • Creases 32 , 34 extend inwardly from surfaces 28 , to a considerable depth as is evident by examination of leftward end 24 and the cylindrical surface which forms the bore 20 .
  • the manufacturing processes for making the connecting rod may vary widely.
  • a green compact is made in the form of the rod by molding powder metal particles in a closed mold under great pressure, typically about 80,000 psi. This pressure molding causes the particles to mechanically interlock and form a stable, relatively weak part but strong enough for handling.
  • the green compact is heated in a furnace at temperatures higher than 2000 degrees F. for a period of time sufficient to cause the metal particles to bond. After sintering, the preform has the same configuration as the green compact but is much stronger.
  • the preform then is hot forged to achieve the shape and increase density and strength as required for a connecting rod. Typically, it is hot forged in a press at a pressure of about 60,000 psi and at a temperature of about 1800 degrees F.
  • Component Weight Percent Preferably, the mixture of this invention comprises: Cu 2.5 to 4.5 C 0.2 to 0.7 prealloyed MnS powder balance More preferably, the mixture is: Cu 3.0 to 4.0 C 0.4 to 0.7
  • the mixed powder of this invention may be used to forge articles other than connecting rods.
  • Other automotive uses include piston rings and valve seats for internal combustion engines.
  • Other parts include clutch races, differential gears and similar parts.
  • Fatigue results for the prealloyed Mn S ferrous based powders of this invention with 3% Cu show an improvement of 19% in fatigue strength compared to standard production.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

These connecting rods are made from prealloyed manganese, sulfur, ferrous based powder. The prealloyed powder then is mixed with copper and carbon. The copper content is at higher than normal copper contents. The resulting forged connecting rods had an improvement in tensile strength and an improvement in fatigue strength.

Description

    TECHNICAL FIELD
  • This invention relates to forged articles made from ferrous powder prealloyed with manganese and sulfur. More specifically, the forged articles are forged engine connecting rods. [0001]
  • BACKGROUND OF THE INVENTION
  • The connecting rod manufacturing process involves pressure molding metal particles in a closed mold under significant pressure to produce a green compact form of the rod. Next, the green compact is heated in a furnace sufficiently to form a sintered preform in which metal particles are bonded. Next, the sintered preform is hot forged to final rod shape which increases the rod's density and strength. The automobile industry continues to challenge connecting rod manufacturers to increase the fatigue strength of these articles. As a result, higher performance materials are needed for forged connecting rods. The goal is to engineer a powder metal blend to manufacture connecting rods with the following characteristics: high strength; good machinability; reasonable cost, good weight and dimensional control. Our research included materials considerations; metallurgical and microstructure evaluation; dimensional change measurements; tensile strength; fatigue strength and machinability tests. [0002]
  • BRIEF SUMMARY OF THE INVENTION
  • The forged articles or connecting rods of this invention are made from ferrous based powder prealloyed with manganese and sulfur. The prealloyed powder then is admixed with copper at higher than normal copper contents. Materials considered were as follows. In a first approach, I thought that increasing Cu content from 2% to 3% or even 4% would improve the strength of connecting rods for the following reasons: Cu strengthens the ferrite, Cu hardens the ferrite, and Cu hinders grain growth after forging. In a second approach I thought that using prealloyed MnS base powder, instead of admixed MnS base powder, would improve the strength of connecting rods for the following reasons: smaller inclusion (MnS) size, uniform inclusion (MnS) distribution, and higher Mn content. [0003]
  • As a result, I used a commercially available prealloyed manganese, sulfur, ferrous based powder for producing the forged article. The prealloyed powder then is mixed with copper and carbon to produce a mix comprising by weight percent: [0004]
    Component Weight Percent
    copper (Cu) < 2.0 to 5.0
    carbon (C)    0.2 to 1.0
    prealloyed MnS powder balance
  • The resulting forged connecting rods had an improvement in tensile strength and an improvement in fatigue strength.[0005]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a perspective view of a forged connecting rod.[0006]
  • DETAILED DESCRIPTION OF THE INVENTION
  • The methods for preparing the prealloyed powder may vary widely. Typically, the powder is prepared by atomization of a molten metal stream of iron, manganese and sulfur. The resulting particles usually have an irregular spherical shape. To facilitate compaction, the atomized particles can be collected after solidification and subjected to annealing at 1700° F. for about 1½ hours, followed by grinding to break up particle cakes, and then passed through an 80 mesh sieve. [0007]
  • The prealloyed ferrous powder then is mixed with copper and graphite at room temperature. The copper powder generally has a purity of 99%. The copper powder and carbon (graphite flake powder), however, are commercial grade materials. The copper powder is mixed in a range of 2.0 to 5.0% by weight of the mixture. The graphite powder is added to yield a final carbon content in the product ranging from 0.2 to 1.0 weight percent. [0008]
  • FIG. 1 illustrates forged connecting [0009] rod 10. Rod 10 has an elongated configuration extending along longitudinal axis A-A. Rod 10 includes midportion 12; small end portion 14; and large end portion 16. Bore 18 is formed through small end portion 14 adapted to receive a wrist or piston pin (not shown) as is well known in the engine art. Aperture 20 is formed through large diameter end 16 and is adapted to receive a journal of a crankshaft (not shown) as is well known in the engine art. Large end portion 16 has a side thrust face 22. Rod 10 includes large end portion 16 having a pair of oppositely facing edges or end surfaces 24. In the particular design of the connecting rod shown in FIG. 1, side thrust face 22 is in a raised plane with respect to the remaining side surface 26. Side thrust face 22 also includes a pair of radially outwardly extending portions 28, 30 located to either side of aperture 20. Portions 28, 30 extend radially outward from aperture 20 and terminate at end of edges 24.
  • FIG. 1 also shows a pair of slits or [0010] creases 32, 34 formed in the side thrust face including extensions 28, 30. Each crease 32,34 is arranged to one side of aperture 20 and they are substantially aligned across aperture 20. Creases 32, 34 extend inwardly from surfaces 28, to a considerable depth as is evident by examination of leftward end 24 and the cylindrical surface which forms the bore 20.
  • The manufacturing processes for making the connecting rod may vary widely. For example, a green compact is made in the form of the rod by molding powder metal particles in a closed mold under great pressure, typically about 80,000 psi. This pressure molding causes the particles to mechanically interlock and form a stable, relatively weak part but strong enough for handling. Next, the green compact is heated in a furnace at temperatures higher than 2000 degrees F. for a period of time sufficient to cause the metal particles to bond. After sintering, the preform has the same configuration as the green compact but is much stronger. [0011]
  • The preform then is hot forged to achieve the shape and increase density and strength as required for a connecting rod. Typically, it is hot forged in a press at a pressure of about 60,000 psi and at a temperature of about 1800 degrees F. [0012]
    Component Weight Percent
    Preferably, the mixture of this invention comprises:
    Cu 2.5 to 4.5
    C 0.2 to 0.7
    prealloyed MnS powder balance
    More preferably, the mixture is:
    Cu 3.0 to 4.0
    C 0.4 to 0.7
  • prealloyed MnS powder balance [0013]
  • The mixed powder of this invention may be used to forge articles other than connecting rods. Other automotive uses include piston rings and valve seats for internal combustion engines. Other parts include clutch races, differential gears and similar parts. [0014]
  • The following Examples further illustrates the composition of this invention. [0015]
  • EXAMPLE I Prior Art
  • The following shows average tensile results for standard production powders with varying amounts of copper. Results for a standard manganese sulfur admixture (rather than the prealloyed powder of this invention) also are shown. The average is based on 6 runs. [0016]
    TENSILE RESULTS
    Commercial Grade
    Prealloyed Mn S
    Standard Production Powder Powder
    2% Cu 3% Cu 4% Cu 2% Cu
    (psi) (psi) (psi) (psi)
    Avg. 124,534 144,788 145,046 120,268
    StDev 3,641 2,771 3,805 1,755
  • EXAMPLE II Prior Art
  • The following shows fatigue results for standard production powders with varying amounts of copper. Results for a standard prealloyed manganese sulfur powder also are shown. [0017]
    FATIGUE RESULTS
    Commercial Grade
    Standard Prealloyed
    production powder Mn S Powder
    2% Cu 3% Cu 4% Cu 2% Cu
    (ksi) (ksi) (ksi) (ksi)
    Endurance Limit @ 50% 45.21 52.63 52.64 50.77
    Scatter 1.07 2.18 2.10 1.88
    Standard deviation (s) 0.28 0.49 0.49 0.43
  • EXAMPLE III
  • Tensile Results for the prealloyed Mn S ferrous powder of this invention with 3% Cu show an improvement of approximately 5% in tensile strength compared to standard production. [0018]
  • EXAMPLE IV
  • Fatigue results for the prealloyed Mn S ferrous based powders of this invention with 3% Cu show an improvement of 19% in fatigue strength compared to standard production. [0019]
  • In addition to these embodiments, persons skilled in the art can see that numerous modifications and changes may be made to the above invention without departing from the intended spirit and scope thereof. [0020]

Claims (6)

I claim:
1. A powder useful for producing forged articles comprising a mixture of the prealloyed manganese, sulfur, ferrous based powder, copper and carbon wherein the mixture has a copper content higher than standard copper contents.
2. A powder according to claim 1 comprising by weight percent:
Component Weight Percent copper (Cu) 2.0 to 5.0 carbon (C) 0.2 to 1.0 prealloyed Mn S ferrous based powder balance
3. A powder according to claim 1 comprising:
Component Weight Percent Cu 2.5 to 4.5 C 0.2 to 0.7 prealloyed Mn S ferrous based powder balance
4. A powder according to claim 1 comprising:
Component Weight Percent Cu 3.0 to 4.0 C 0.4 to 0.7 prealloyed Mn S ferrous based powder balance
5. A forged article produced from the prealloyed powder of claim 1.
6. A forged connecting rod produced from the prealloyed powder of claim 1.
US09/919,426 2001-07-31 2001-07-31 Forged article with prealloyed powder Abandoned US20030033904A1 (en)

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US09/919,426 US20030033904A1 (en) 2001-07-31 2001-07-31 Forged article with prealloyed powder
PCT/US2002/023732 WO2003011498A1 (en) 2001-07-31 2002-07-26 Forged article with prealloyed powder
US10/417,834 US20030196511A1 (en) 2001-07-31 2003-04-17 Forged article with prealloyed powder

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060086204A1 (en) * 2004-10-18 2006-04-27 Edmond Ilia Impact of copper and carbon on mechanical properties of iron-carbon-copper alloys for powder metal forging applications
US7160351B2 (en) * 2002-10-01 2007-01-09 Pmg Ohio Corp. Powder metal clutch races for one-way clutches and method of manufacture
US20100278681A1 (en) * 2007-12-27 2010-11-04 Hoganas Ab Low alloyed steel powder
US20100316521A1 (en) * 2007-12-27 2010-12-16 Hoganas Ab (Publ) Low alloyed steel powder
US20110000457A1 (en) * 2008-01-04 2011-01-06 Donaldson Ian W Prealloyed copper powder forged connecting rod
US20140170018A1 (en) * 2011-07-28 2014-06-19 Korea Automotive Technology Institute Aluminum alloy including iron-manganese complete solid solution and method of manufacturing the same
US9469890B2 (en) 2009-03-20 2016-10-18 Hoganas Ab (Publ) Iron vanadium powder alloy

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RU2588979C1 (en) * 2015-03-16 2016-07-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кубанский государственный технологический университет" (ФГБОУ ВПО "КубГТУ") Method of producing high-density powder chromium containing material based on iron
CN105251981A (en) * 2015-10-21 2016-01-20 马聪 Anti-corrosion ferrum-based powder metallurgy forging automobile connecting rod and preparation method thereof
CN105328194A (en) * 2015-10-21 2016-02-17 马聪 High-tensile-strength ferrum-based powder metallurgy forging automobile connecting rod and manufacturing method thereof
CN105251982A (en) * 2015-10-21 2016-01-20 马聪 Anti-corrosion ferrum-based powder metallurgy forging automobile connecting rod and preparation method thereof
CN105251980A (en) * 2015-10-21 2016-01-20 李学峰 High-hardness automotive connection rod forged through ferrum-based powder in metallurgical manner and manufacturing method thereof
CN105328198A (en) * 2015-10-21 2016-02-17 李学峰 High-compactness ferrum-based powder metallurgy forging automobile connecting rod and manufacturing method thereof
CN105251983A (en) * 2015-10-21 2016-01-20 李学峰 High-compactness high-strength ferrum-based powder metallurgy forging automobile connecting rod and preparation method thereof
CN106626501B (en) * 2016-12-23 2018-03-27 重庆龙悦食品有限公司 Dried bean curd extrusion device

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7160351B2 (en) * 2002-10-01 2007-01-09 Pmg Ohio Corp. Powder metal clutch races for one-way clutches and method of manufacture
US20070081915A1 (en) * 2002-10-01 2007-04-12 Trasorras Juan R Powder metal clutch races for one-way clutches and method of manufacture
US7534391B2 (en) 2002-10-01 2009-05-19 Pmg Indiana Corp. Powder metal clutch races for one-way clutches and method of manufacture
US20060086204A1 (en) * 2004-10-18 2006-04-27 Edmond Ilia Impact of copper and carbon on mechanical properties of iron-carbon-copper alloys for powder metal forging applications
US20100278681A1 (en) * 2007-12-27 2010-11-04 Hoganas Ab Low alloyed steel powder
US20100316521A1 (en) * 2007-12-27 2010-12-16 Hoganas Ab (Publ) Low alloyed steel powder
US8398739B2 (en) 2007-12-27 2013-03-19 Hoganas Ab (Publ) Iron-based steel powder composition, method for producing a sintered component and component
US20110000457A1 (en) * 2008-01-04 2011-01-06 Donaldson Ian W Prealloyed copper powder forged connecting rod
US8935852B2 (en) 2008-01-04 2015-01-20 Gkn Sinter Metals, Llc Prealloyed copper powder forged connecting rod
US9469890B2 (en) 2009-03-20 2016-10-18 Hoganas Ab (Publ) Iron vanadium powder alloy
US20140170018A1 (en) * 2011-07-28 2014-06-19 Korea Automotive Technology Institute Aluminum alloy including iron-manganese complete solid solution and method of manufacturing the same
US9617623B2 (en) * 2011-07-28 2017-04-11 Korea Automotive Technology Institute Aluminum alloy including iron-manganese complete solid solution and method of manufacturing the same

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WO2003011498A1 (en) 2003-02-13

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