US20030003700A1 - Methods providing oxide layers having reduced thicknesses at central portions thereof and related devices - Google Patents
Methods providing oxide layers having reduced thicknesses at central portions thereof and related devices Download PDFInfo
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- US20030003700A1 US20030003700A1 US10/173,373 US17337302A US2003003700A1 US 20030003700 A1 US20030003700 A1 US 20030003700A1 US 17337302 A US17337302 A US 17337302A US 2003003700 A1 US2003003700 A1 US 2003003700A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B99/00—Subject matter not provided for in other groups of this subclass
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
- H01L21/28167—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation
- H01L21/28176—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation with a treatment, e.g. annealing, after the formation of the definitive gate conductor
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
- H01L21/28167—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/20—Electrodes characterised by their shapes, relative sizes or dispositions
- H10D64/27—Electrodes not carrying the current to be rectified, amplified, oscillated or switched, e.g. gates
- H10D64/311—Gate electrodes for field-effect devices
- H10D64/411—Gate electrodes for field-effect devices for FETs
- H10D64/511—Gate electrodes for field-effect devices for FETs for IGFETs
- H10D64/514—Gate electrodes for field-effect devices for FETs for IGFETs characterised by the insulating layers
- H10D64/516—Gate electrodes for field-effect devices for FETs for IGFETs characterised by the insulating layers the thicknesses being non-uniform
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0144—Manufacturing their gate insulating layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0151—Manufacturing their isolation regions
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
Definitions
- the present invention relates to semiconductor devices, and more particularly, to methods of fabricating a integrated circuit devices including gate insulating layers and related devices.
- a gate insulating layer such as a gate oxide layer
- the thickness of a gate insulating layer may be reduced to increase the operational speed of a semiconductor device.
- a decrease in the thickness of the gate insulating layer may also increase a frequency of breakdowns because decreasing the thickness of the gate insulating layer generally results in a lower breakdown voltage.
- different areas of a memory device may have varying performance requirements. Therefore, a desired thickness of a gate insulating layer may vary from point to point on a semiconductor device based on desired performance characteristics.
- gate insulating layers in a cell array region and a peripheral circuit region have different thicknesses, it may be possible to improve operational features and reliability of the device.
- performance and reliability can be improved if the cell array region has a gate insulating layer with a greater thickness than the peripheral circuit region.
- the area of the cell array region of such devices has increased in size compared to the peripheral circuit region. If all of the gate insulating layers formed on a chip have the same thickness, a breakdown may occur first in a gate insulating layer positioned on the cell array region and the semiconductor device may lose reliability or fail to operate at all. This problem may be reduced by increasing thicknesses of the gate insulating layers formed on the cell array region in comparison to gate insulating layers formed on the peripheral circuit region.
- FIGS. 1A through 1D are cross-sectional views illustrating a semiconductor device having gate oxide layers of different thicknesses fabricated according to a conventional method.
- the gate oxide layer formed on a left region TK is thicker compared to the gate oxide layer formed on a right region TI.
- a semiconductor substrate 10 e.g. a silicon substrate, having a trench 11 is first oxidized to obtain a first gate oxide layer 13 .
- the first gate oxide layer 13 may be about 10 nm thick.
- a photoresist pattern 15 is formed on a portion of the first gate oxide layer 13 in the TK region.
- a portion of the first gate oxide layer 13 is then etched from the TI region.
- the thickness of the first gate oxide layer 13 remaining on the TI region is thinner compared to that on the TK region.
- the photoresist pattern 15 is removed from the TK region as shown in FIG. 1C.
- the first gate oxide layer 13 is etched such that the first gate oxide layer 13 is removed from the TI region. Because the photoresist pattern has been removed, the portion of the first gate oxide layer 13 on the TK region is also etched and the thickness of the gate oxide layer 13 in the TK region is reduced.
- the semiconductor substrate 10 is oxidized again to form a second gate oxide layer 17 on the TI. During this oxidation step, the thickness of the first gate oxide layer 13 on the TK region is increased.
- the first gate oxide layer 13 on the TK region can have a thickness greater than that of the second gate oxide layer 17 on the TI region.
- the resulting semiconductor device can thus have gate oxide layers with different thicknesses.
- the first gate oxide layer 13 remaining on the TK region may, however, be contaminated when the first gate oxide layer 13 is selectively removed from the TI region (see FIGS. 1B and 1C). This contamination may degrade the operational characteristics of the semiconductor device.
- Methods for forming an integrated circuit device can include forming a gate insulating layer on the semiconductor substrate extending between first and second spaced apart source/drain regions.
- the gate insulating layer may have a reduced thickness at a central portion thereof between the first and second spaced apart source/drain regions.
- Methods may also include forming a gate electrode on the gate insulating layer such that the gate insulating layer is between the semiconductor substrate and the gate electrode.
- Methods according to additional embodiments may include forming a gate insulating layer having a relatively uniform thickness extending between the first and second spaced apart source/drain regions, and, after forming the gate electrode, increasing a thickness of portions of the gate insulating layer.
- Methods according to embodiments of the invention can include forming third and fourth spaced apart source/drain regions on the surface of the semiconductor substrate.
- a second gate insulating layer can be formed on the semiconductor substrate extending between the third and fourth spaced apart source/drain regions.
- a second gate electrode can be formed on the second gate insulating layer such that the second gate electrode is between the semiconductor substrate and the second gate electrode.
- a thickness of portions of the gate insulating layer can then be increased while maintaining a uniform thickness for the second gate insulating layer.
- Methods for forming an integrated circuit device can include forming first and second spaced apart source/drain region on a surface of a semiconductor substrate, forming a gate insulating layer on the semiconductor substrate extending between the first and second spaced apart source drain regions, and forming a gate electrode on the gate insulating layer such that the gate insulating layer is between the semiconductor substrate and the gate electrode.
- Methods according to additional embodiments can include increasing a thickness of portions of the gate insulating layer after forming the gate insulating layer and forming the gate electrode on the gate insulating layer.
- Certain embodiments can include forming third and fourth spaced apart source/drain regions on the surface of the semiconductor substrate.
- a second gate insulating layer may be formed on the semiconductor substrate extending between the third and fourth spaced apart source/drain regions.
- a second gate electrode can be formed on the second gate insulating layer such that the second gate insulating layer is between the semiconductor substrate and the second gate electrode. Methods may include increasing a thickness of portions of the gate insulating layer while maintaining a uniform thickness of the second gate insulating layer.
- Integrated circuit devices may include a semiconductor substrate having first and second spaced apart source/drain regions at a surface thereof.
- a gate insulating layer on the semiconductor substrate can extend between the first and second spaced apart source/drain regions.
- the gate insulating layer can have a reduced thickness at a central portion thereof between the first and second spaced apart source/drain regions.
- a thickness of the gate insulating layer can increase as it extends toward each of the source/drain regions.
- a gate electrode can be on the gate insulating layer such that the gate insulating layer is between the semiconductor substrate and the gate electrode.
- methods for forming an integrated circuit can include forming a gate oxide layer and a gate pattern on a semiconductor substrate having a cell array region and a peripheral circuit region.
- a source/drain region between separated portions of the gate patterns can be formed near on the surface of the semiconductor substrate.
- An interlayer insulating film pattern which fills a gap between separated portions of the gate pattern, can be formed.
- the interlayer insulating film having a contact hole for exposing the semiconductor substrate may be formed in the cell array region.
- a gate oxide layer in the exposed cell array region whose thickness is greater than that of the gate oxide layer formed in the peripheral circuit region may be formed through oxygen diffusion by oxidizing the semiconductor substrate on the exposed cell array region.
- the thickness of the gate oxide layer in the cell array region changes depending on the extent of oxidation when the semiconductor substrate is oxidized.
- the semiconductor substrate in the exposed cell array region may be oxidized through a wet oxidation or dry oxidation method.
- a contact pad for filling the contact hole may be formed.
- FIGS. 1A through 1D are cross-sectional views illustrating a conventional method of fabricating a semiconductor device having gate oxide layers with different thicknesses
- FIGS. 2 through 12 are cross-sectional views illustrating methods of fabricating integrated circuit devices having according to embodiments of the present invention.
- FIG. 13 is a plan view of a structure shown in FIG. 7;
- FIGS. 14A and 14B are cross-sectional views illustrating changes in thickness of a gate oxide layer on a cell array region shown.
- FIGS. 2 through 12 are cross-sectional views illustrating steps of fabricating integrated circuit devices according to embodiments of the present invention.
- the gate insulating layer is described as a silicon oxide layer.
- Other gate insulating materials known to those of ordinary skill in the art may be used.
- a trench oxide layer 53 is formed in a semiconductor substrate 51 , e.g., p-type silicon substrate, to define two isolated regions.
- the isolated regions defined by the trench oxide layer 53 shown in FIG. 2 are a cell array (CA) region and a peripheral circuit (PA) region.
- a shallow trench isolation (STI) method may be used to form the isolated regions in the present embodiment.
- Other methods known to those of ordinary skill in the art can be used to isolate the cell array region and the peripheral circuit region.
- the portion of the semiconductor substrate 51 that includes the trench oxide layer 53 may be an inactive region while remaining portions of the semiconductor substrate 51 may be active regions.
- a gate insulating layer such as a gate oxide layer is formed.
- a first silicon oxide layer 55 for a gate oxide film can be formed on the entire semiconductor substrate 51 .
- the first silicon oxide layer 55 may be formed after well-ion implantation for forming a well and field-ion implantation and channel-ion implantation for forming a channel.
- the first silicon oxide layer 55 can be formed of a thermal oxide film.
- the first silicon oxide layer 55 can be formed such that its thickness is a thickness desired for a gate oxide layer in the PA region.
- the first silicon oxide layer 55 may have a thickness in a range of about 20 to about 60 ⁇ .
- a first conductive layer 57 for a gate electrode is formed on the first silicon oxide layer 55 .
- the first conductive layer 57 include an impurity-doped polysilicon film having a thickness of between about 500 and about 1000 ⁇ and a metal silicide film having a thickness of between about 500 and about 1000 ⁇ .
- a first insulating film 59 can be formed on the first conductive layer 57 .
- the first insulating film 59 may have a thickness of between about 1000 and about 2000 ⁇ .
- the first insulating film 59 is preferably formed of a material with etching selectivity with respect to the first silicon oxide layer 55 , e.g., a silicon nitride film.
- the first insulating layer 59 , the first conductive layer 57 and the first silicon oxide layer 55 are patterned, for example, through a photolithography process, to form a gate pattern 61 and a gate oxide layer 55 a .
- Gate oxide layer 55 a has a substantially uniform thickness.
- the gate pattern 61 can include a first insulating film pattern 59 a and a gate electrode 57 a . Thereafter, N-type impurities can be ion-implanted into the entire surface of the semiconductor substrate 51 to form a lightly doped drain (LDD).
- LDD lightly doped drain
- a first impurity region 63 can be formed on the surface of the semiconductor substrate 51 while being aligned with respect to the sidewalls of the gate pattern 61 .
- the first impurity region 63 includes first and second spaced apart source/drain regions 62 on the CA region and third and fourth spaced apart source/drain regions 64 on the PA region.
- a spacer 65 is formed along both sidewalls of the gate pattern 61 and the gate oxide layer 55 a .
- the spacer 65 may be obtained by forming an insulating film of thickness of about 300 ⁇ to about 1000 ⁇ on the entire surface of the semiconductor substrate 51 having the gate pattern 61 and anisotropically etching the insulating film.
- the insulating film for the spacer 65 may be formed of a material having high etching selectivity with respect to the silicon oxide layer 55 a , e.g., a silicon nitride film.
- a thermal oxide layer (not shown) may be formed to a thickness of about 50 ⁇ to about 100 ⁇ by thermally oxidizing the semiconductor substrate 51 so that silicon damaged during the anisotropic etching of the insulating film is removed from the semiconductor substrate 51 .
- N-type impurities can be implanted into the entire surface of the semiconductor substrate 51 on which the gate pattern 61 and the spacer 65 are formed.
- a second impurity region 67 is formed on the surface of the semiconductor substrate 51 while being aligned with reference to the spacer 65 .
- an LDD-type source/drain region 68 composed of the first and second impurity regions 63 and 67 can be obtained.
- a masking film depicted as second insulating film 69
- second insulating film 69 can be formed on the surface of the semiconductor substrate 51 .
- Any masking material may be used for second insulating film 69 .
- the second insulating film 69 may be formed to a thickness of about 100 ⁇ on the entire surface of the semiconductor substrate 51 having the gate pattern 61 and the gate spacer 65 .
- the second insulating film 69 is preferably formed of a material having high etching selectivity with respect to the silicon oxide layer 55 a , e.g., a silicon nitride film.
- another masking film such as third insulating layer 71
- third insulating layer 71 can be formed on the entire surface of the semiconductor substrate 51 over the second insulating film 69 .
- the third insulating layer 71 may be formed of a silicon oxide film, which preferably has excellent gap fill features for filling narrow and elongated gaps between gate patterns.
- an interlayer insulating layer 71 a can be obtained by planarizing the third insulating film 71 , for example, through a chemical mechanical polishing (CMP) method. At this time, the thickness of the interlayer insulating layer 71 a may be adjusted within about 0 ⁇ to about 1000 ⁇ from the upper surface of the gate pattern 61 .
- CMP chemical mechanical polishing
- portions of the interlayer insulating layer 71 a and the second insulating layer 69 (shown in FIG. 7) formed on the CA region are removed, for example, by selective etching using a photolithography process.
- the resulting interlayer insulating layer pattern 71 b and second insulating layer pattern 69 a provide a masking film pattern to expose the CA region while the interlayer insulating layer pattern 71 b and second insulating layer pattern 69 a are maintained on the PA region.
- the area exposed by interlayer insulating layer pattern 71 b and second insulating layer pattern 69 a in the CA region defines a contact hole 73 to expose the semiconductor substrate 51 .
- a contact pad may be formed in contact hole 73 in order that a bit line (or storage node) can easily electrically contact the impurity region on the semiconductor substrate 51 (see FIG. 13).
- the reference numerals 73 , 75 and 77 denote a contact hole, a gate line and an active region, respectively.
- the contact hole 73 may preferably be formed to be larger than the active region 77 by between about 20 to about 40 nm.
- a thickness of portions of the silicon oxide layer 55 a may be increased, as described in greater detail herein, to form gate oxide layer 55 b shown in FIG. 10 while a relatively uniform thickness of the gate oxide layer 55 a is maintained.
- the semiconductor substrate 51 including the contact hole 73 , which exposes the CA region may be thermally oxidized, for example, through a wet-oxidation or dry-oxidation method as shown in FIG. 9.
- the PA region is covered by a masking film, which is shown in FIGS. 8 and 9 as the interlayer insulating layer pattern 71 b and second insulating layer pattern 69 a .
- a second silicon oxide layer 79 can be formed having a thickness of between about 30 ⁇ and about 100 ⁇ on the CA region of the semiconductor substrate 51 .
- the gate oxide layer 55 a shown in FIG. 14A is oxygen-diffused and changed into the second silicon oxide layer 79 .
- the second silicon oxide layer 79 shown in FIG. 14B has a “bird's beak” shape. That is, the second silicon oxide layer 79 has a reduced thickness at a central portion thereof such that a thickness of the second silicon oxide layer 79 increases as it extends toward each of the first and second source drain regions 62 as shown in FIG. 9. Then, as shown in FIG. 10, the second silicon oxide layer 79 on the CA region is anisotropically etched to form a gate oxide layer 55 b of which thickness is different from that of the gate oxide layer 55 a formed on the PA region.
- the thickness of the gate oxide layer 55 b on the CA region varies depending on the extent of oxidation of the exposed CA region. As shown in FIG. 10, the edges of the gate oxide layer 55 b are thicker than the central portion of the gate oxide layer 55 b.
- impurities may be implanted into the impurity region of the CA region, i.e. the source/drain region 68 , so that contact resistance between the source/drain region 68 and a contact pad formed in contact hole 73 is lowered.
- a second conductive layer 81 for a contact pad may be formed to a thickness of between about 3000 ⁇ and about 5000 ⁇ on the entire surface of the semiconductor substrate 51 such that the contact hole 73 (FIG. 8) on the CA region is completely filled.
- the second conductive layer 81 may be formed using an impurity-doped polysilicon film.
- the second conductive layer 81 for a contact pad is planarized, for example, through a CMP method thereby forming contact pads 81 a and 81 b .
- the upper surface of the gate pattern 61 serves as an etching stopper.
- Contact pad 81 a and contact pads 81 b are respectively connected with a bit line and storage nodes of a capacitor in a subsequent process.
- the resulting integrated circuit device includes a semiconductor substrate 51 having first and second spaced apart source/drain regions 62 on the surface thereof.
- a gate oxide layer 55 b extends between the first and second spaced apart source/drain regions 62 .
- the gate oxide layer 55 b has a reduced thickness at a central portion thereof between the first and second spaced apart source/drain regions 62 and a thickness of the gate oxide layer 55 b increases as it extends toward each of the source/drain regions 62 .
- the integrated circuit device also includes a gate electrode 57 on the gate oxide layer 55 b such that the gate oxide layer 55 b is between the semiconductor substrate 51 and the gate electrode.
- the integrated circuit device may also include a second gate oxide layer 55 a on the semiconductor substrate 51 extending between third and fourth spaced apart source/drain regions 64 .
- the second gate oxide layer 55 a may have a thickness that is relatively uniform across the second gate oxide layer 55 a between the third and fourth spaced apart source/drain regions.
- a second gate electrode 57 a may be situated on the substrate 51 such that the second gate oxide layer 55 a is between the semiconductor substrate 51 and the second gate electrode 57 a.
- Methods according to embodiments of the present invention can provide integrated circuit devices having gate insulting layers with a central portion having a reduced thickness.
- Integrated circuit devices according to embodiments of the present invention may be obtained by oxidizing the exposed semiconductor substrate, for example, in the CA region so that the thickness of gate oxide layer on the CA region is increased relative to that of a gate oxide layer formed on the PA region through oxygen diffusion.
- a gate oxide layer on the CA region may be formed with reduced contamination that may otherwise occur during etching processes, thus enhancing operational characteristics and reliability of the semiconductor device.
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Abstract
Description
- This application claims the benefit of Korean Patent Application No. 2001-0037634, filed Mar. 13, 2001, the disclosure of which is hereby incorporated herein by reference in its entirety as if set forth fully herein.
- 1. Field of the Invention
- The present invention relates to semiconductor devices, and more particularly, to methods of fabricating a integrated circuit devices including gate insulating layers and related devices.
- 2. Description of the Related Art
- High integration of semiconductor memory devices such as DRAM devices has resulted in a reduction in the size of transistors. As the length of a gate decreases, the thickness of a gate insulating layer (such as a gate oxide layer) may be reduced to increase the operational speed of a semiconductor device. However, a decrease in the thickness of the gate insulating layer may also increase a frequency of breakdowns because decreasing the thickness of the gate insulating layer generally results in a lower breakdown voltage. In addition, different areas of a memory device may have varying performance requirements. Therefore, a desired thickness of a gate insulating layer may vary from point to point on a semiconductor device based on desired performance characteristics.
- For example, if gate insulating layers in a cell array region and a peripheral circuit region have different thicknesses, it may be possible to improve operational features and reliability of the device. Typically, performance and reliability can be improved if the cell array region has a gate insulating layer with a greater thickness than the peripheral circuit region. More specifically, because of advances in highly integrated semiconductor devices such as DRAM devices, the area of the cell array region of such devices has increased in size compared to the peripheral circuit region. If all of the gate insulating layers formed on a chip have the same thickness, a breakdown may occur first in a gate insulating layer positioned on the cell array region and the semiconductor device may lose reliability or fail to operate at all. This problem may be reduced by increasing thicknesses of the gate insulating layers formed on the cell array region in comparison to gate insulating layers formed on the peripheral circuit region.
- FIGS. 1A through 1D are cross-sectional views illustrating a semiconductor device having gate oxide layers of different thicknesses fabricated according to a conventional method. In the structure shown in FIGS. 1A through 1D, the gate oxide layer formed on a left region TK is thicker compared to the gate oxide layer formed on a right region TI. As shown in FIG. 1A, a
semiconductor substrate 10, e.g. a silicon substrate, having atrench 11 is first oxidized to obtain a firstgate oxide layer 13. The firstgate oxide layer 13 may be about 10 nm thick. Next, as shown in FIG. 1B, aphotoresist pattern 15 is formed on a portion of the firstgate oxide layer 13 in the TK region. A portion of the firstgate oxide layer 13 is then etched from the TI region. As a result, the thickness of the firstgate oxide layer 13 remaining on the TI region is thinner compared to that on the TK region. - The
photoresist pattern 15 is removed from the TK region as shown in FIG. 1C. The firstgate oxide layer 13 is etched such that the firstgate oxide layer 13 is removed from the TI region. Because the photoresist pattern has been removed, the portion of the firstgate oxide layer 13 on the TK region is also etched and the thickness of thegate oxide layer 13 in the TK region is reduced. Next, referring to FIG. 1D, thesemiconductor substrate 10 is oxidized again to form a secondgate oxide layer 17 on the TI. During this oxidation step, the thickness of the firstgate oxide layer 13 on the TK region is increased. Through the above method, the firstgate oxide layer 13 on the TK region can have a thickness greater than that of the secondgate oxide layer 17 on the TI region. The resulting semiconductor device can thus have gate oxide layers with different thicknesses. - The first
gate oxide layer 13 remaining on the TK region may, however, be contaminated when the firstgate oxide layer 13 is selectively removed from the TI region (see FIGS. 1B and 1C). This contamination may degrade the operational characteristics of the semiconductor device. - Methods for forming an integrated circuit device according to embodiments of the invention can include forming a gate insulating layer on the semiconductor substrate extending between first and second spaced apart source/drain regions. The gate insulating layer may have a reduced thickness at a central portion thereof between the first and second spaced apart source/drain regions. Methods may also include forming a gate electrode on the gate insulating layer such that the gate insulating layer is between the semiconductor substrate and the gate electrode. Methods according to additional embodiments may include forming a gate insulating layer having a relatively uniform thickness extending between the first and second spaced apart source/drain regions, and, after forming the gate electrode, increasing a thickness of portions of the gate insulating layer.
- Methods according to embodiments of the invention can include forming third and fourth spaced apart source/drain regions on the surface of the semiconductor substrate. A second gate insulating layer can be formed on the semiconductor substrate extending between the third and fourth spaced apart source/drain regions. A second gate electrode can be formed on the second gate insulating layer such that the second gate electrode is between the semiconductor substrate and the second gate electrode. A thickness of portions of the gate insulating layer can then be increased while maintaining a uniform thickness for the second gate insulating layer.
- Methods for forming an integrated circuit device according to yet additional embodiments of the invention can include forming first and second spaced apart source/drain region on a surface of a semiconductor substrate, forming a gate insulating layer on the semiconductor substrate extending between the first and second spaced apart source drain regions, and forming a gate electrode on the gate insulating layer such that the gate insulating layer is between the semiconductor substrate and the gate electrode. Methods according to additional embodiments can include increasing a thickness of portions of the gate insulating layer after forming the gate insulating layer and forming the gate electrode on the gate insulating layer. Certain embodiments can include forming third and fourth spaced apart source/drain regions on the surface of the semiconductor substrate. A second gate insulating layer may be formed on the semiconductor substrate extending between the third and fourth spaced apart source/drain regions. A second gate electrode can be formed on the second gate insulating layer such that the second gate insulating layer is between the semiconductor substrate and the second gate electrode. Methods may include increasing a thickness of portions of the gate insulating layer while maintaining a uniform thickness of the second gate insulating layer.
- Integrated circuit devices according to embodiments of the present invention may include a semiconductor substrate having first and second spaced apart source/drain regions at a surface thereof. A gate insulating layer on the semiconductor substrate can extend between the first and second spaced apart source/drain regions. The gate insulating layer can have a reduced thickness at a central portion thereof between the first and second spaced apart source/drain regions. A thickness of the gate insulating layer can increase as it extends toward each of the source/drain regions. A gate electrode can be on the gate insulating layer such that the gate insulating layer is between the semiconductor substrate and the gate electrode.
- In certain embodiments of the invention, methods for forming an integrated circuit can include forming a gate oxide layer and a gate pattern on a semiconductor substrate having a cell array region and a peripheral circuit region. A source/drain region between separated portions of the gate patterns can be formed near on the surface of the semiconductor substrate. An interlayer insulating film pattern, which fills a gap between separated portions of the gate pattern, can be formed. The interlayer insulating film having a contact hole for exposing the semiconductor substrate may be formed in the cell array region. Finally, a gate oxide layer in the exposed cell array region whose thickness is greater than that of the gate oxide layer formed in the peripheral circuit region may be formed through oxygen diffusion by oxidizing the semiconductor substrate on the exposed cell array region. At this time, the thickness of the gate oxide layer in the cell array region changes depending on the extent of oxidation when the semiconductor substrate is oxidized. Also, the semiconductor substrate in the exposed cell array region may be oxidized through a wet oxidation or dry oxidation method. A contact pad for filling the contact hole may be formed.
- FIGS. 1A through 1D are cross-sectional views illustrating a conventional method of fabricating a semiconductor device having gate oxide layers with different thicknesses;
- FIGS. 2 through 12 are cross-sectional views illustrating methods of fabricating integrated circuit devices having according to embodiments of the present invention;
- FIG. 13 is a plan view of a structure shown in FIG. 7; and
- FIGS. 14A and 14B are cross-sectional views illustrating changes in thickness of a gate oxide layer on a cell array region shown.
- The present invention now will be described more fully hereinafter with reference to the accompanying drawings, in which various embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the relative sizes of elements may be exaggerated for clarity. When a layer is described as being formed on another layer or a semiconductor substrate, the layer may be formed directly on the other layer or semiconductor substrate, or other layers may be interposed therebetween. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present. Like reference numerals in the drawings denote like members.
- FIGS. 2 through 12 are cross-sectional views illustrating steps of fabricating integrated circuit devices according to embodiments of the present invention. For ease of discussion, the gate insulating layer is described as a silicon oxide layer. Other gate insulating materials known to those of ordinary skill in the art may be used.
- Referring to FIG. 2, a
trench oxide layer 53 is formed in asemiconductor substrate 51, e.g., p-type silicon substrate, to define two isolated regions. The isolated regions defined by thetrench oxide layer 53 shown in FIG. 2 are a cell array (CA) region and a peripheral circuit (PA) region. A shallow trench isolation (STI) method may be used to form the isolated regions in the present embodiment. Other methods known to those of ordinary skill in the art can be used to isolate the cell array region and the peripheral circuit region. The portion of thesemiconductor substrate 51 that includes thetrench oxide layer 53 may be an inactive region while remaining portions of thesemiconductor substrate 51 may be active regions. - Thereafter, a gate insulating layer such as a gate oxide layer is formed. As shown, a first
silicon oxide layer 55 for a gate oxide film can be formed on theentire semiconductor substrate 51. The firstsilicon oxide layer 55 may be formed after well-ion implantation for forming a well and field-ion implantation and channel-ion implantation for forming a channel. The firstsilicon oxide layer 55 can be formed of a thermal oxide film. The firstsilicon oxide layer 55 can be formed such that its thickness is a thickness desired for a gate oxide layer in the PA region. For example, the firstsilicon oxide layer 55 may have a thickness in a range of about 20 to about 60 Å. - Next, a first
conductive layer 57 for a gate electrode is formed on the firstsilicon oxide layer 55. For example, the firstconductive layer 57 include an impurity-doped polysilicon film having a thickness of between about 500 and about 1000 Å and a metal silicide film having a thickness of between about 500 and about 1000 Å. Then, a first insulatingfilm 59 can be formed on the firstconductive layer 57. The first insulatingfilm 59 may have a thickness of between about 1000 and about 2000 Å. The first insulatingfilm 59 is preferably formed of a material with etching selectivity with respect to the firstsilicon oxide layer 55, e.g., a silicon nitride film. - Referring to FIG. 3, the first insulating
layer 59, the firstconductive layer 57 and the firstsilicon oxide layer 55 are patterned, for example, through a photolithography process, to form agate pattern 61 and agate oxide layer 55 a.Gate oxide layer 55 a has a substantially uniform thickness. Thegate pattern 61 can include a firstinsulating film pattern 59 a and agate electrode 57 a. Thereafter, N-type impurities can be ion-implanted into the entire surface of thesemiconductor substrate 51 to form a lightly doped drain (LDD). As a result, afirst impurity region 63 can be formed on the surface of thesemiconductor substrate 51 while being aligned with respect to the sidewalls of thegate pattern 61. Thefirst impurity region 63 includes first and second spaced apart source/drain regions 62 on the CA region and third and fourth spaced apart source/drain regions 64 on the PA region. - Referring to FIG. 4, a
spacer 65 is formed along both sidewalls of thegate pattern 61 and thegate oxide layer 55 a. Thespacer 65 may be obtained by forming an insulating film of thickness of about 300 Å to about 1000 Å on the entire surface of thesemiconductor substrate 51 having thegate pattern 61 and anisotropically etching the insulating film. At this time, the insulating film for thespacer 65 may be formed of a material having high etching selectivity with respect to thesilicon oxide layer 55 a, e.g., a silicon nitride film. - Next, if necessary, a thermal oxide layer (not shown) may be formed to a thickness of about 50 Å to about 100 Å by thermally oxidizing the
semiconductor substrate 51 so that silicon damaged during the anisotropic etching of the insulating film is removed from thesemiconductor substrate 51. Further, N-type impurities can be implanted into the entire surface of thesemiconductor substrate 51 on which thegate pattern 61 and thespacer 65 are formed. As a result, asecond impurity region 67 is formed on the surface of thesemiconductor substrate 51 while being aligned with reference to thespacer 65. Finally, an LDD-type source/drain region 68 composed of the first andsecond impurity regions - Referring to FIG. 5, a masking film, depicted as second insulating
film 69, can be formed on the surface of thesemiconductor substrate 51. Any masking material may be used for second insulatingfilm 69. The second insulatingfilm 69 may be formed to a thickness of about 100 Å on the entire surface of thesemiconductor substrate 51 having thegate pattern 61 and thegate spacer 65. The second insulatingfilm 69 is preferably formed of a material having high etching selectivity with respect to thesilicon oxide layer 55 a, e.g., a silicon nitride film. - Referring to FIG. 6, another masking film, such as third insulating
layer 71, can be formed on the entire surface of thesemiconductor substrate 51 over the second insulatingfilm 69. The third insulatinglayer 71 may be formed of a silicon oxide film, which preferably has excellent gap fill features for filling narrow and elongated gaps between gate patterns. - Referring to FIG. 7, an
interlayer insulating layer 71 a can be obtained by planarizing the third insulatingfilm 71, for example, through a chemical mechanical polishing (CMP) method. At this time, the thickness of the interlayer insulatinglayer 71 a may be adjusted within about 0 Å to about 1000 Å from the upper surface of thegate pattern 61. - Referring to FIGS. 8 and 13, portions of the interlayer insulating
layer 71 a and the second insulating layer 69 (shown in FIG. 7) formed on the CA region are removed, for example, by selective etching using a photolithography process. The resulting interlayer insulatinglayer pattern 71 b and second insulatinglayer pattern 69 a provide a masking film pattern to expose the CA region while the interlayer insulatinglayer pattern 71 b and second insulatinglayer pattern 69 a are maintained on the PA region. The area exposed by interlayer insulatinglayer pattern 71 b and second insulatinglayer pattern 69 a in the CA region defines acontact hole 73 to expose thesemiconductor substrate 51. - The CA region of the
semiconductor substrate 51 is exposed and the PA region is covered by the interlayer insulatinglayer pattern 71 b and second insulatinglayer pattern 69 a for two reasons. First, a contact pad may be formed incontact hole 73 in order that a bit line (or storage node) can easily electrically contact the impurity region on the semiconductor substrate 51 (see FIG. 13). In FIG. 13, thereference numerals contact hole 73 may preferably be formed to be larger than theactive region 77 by between about 20 to about 40 nm. Second, a thickness of portions of thesilicon oxide layer 55 a may be increased, as described in greater detail herein, to formgate oxide layer 55 b shown in FIG. 10 while a relatively uniform thickness of thegate oxide layer 55 a is maintained. - Referring to FIGS. 9, 10,14A and 14B, the
semiconductor substrate 51 including thecontact hole 73, which exposes the CA region may be thermally oxidized, for example, through a wet-oxidation or dry-oxidation method as shown in FIG. 9. The PA region is covered by a masking film, which is shown in FIGS. 8 and 9 as the interlayer insulatinglayer pattern 71 b and second insulatinglayer pattern 69 a. A secondsilicon oxide layer 79 can be formed having a thickness of between about 30 Å and about 100 Å on the CA region of thesemiconductor substrate 51. Thus, thegate oxide layer 55 a shown in FIG. 14A is oxygen-diffused and changed into the secondsilicon oxide layer 79. The secondsilicon oxide layer 79 shown in FIG. 14B has a “bird's beak” shape. That is, the secondsilicon oxide layer 79 has a reduced thickness at a central portion thereof such that a thickness of the secondsilicon oxide layer 79 increases as it extends toward each of the first and secondsource drain regions 62 as shown in FIG. 9. Then, as shown in FIG. 10, the secondsilicon oxide layer 79 on the CA region is anisotropically etched to form agate oxide layer 55 b of which thickness is different from that of thegate oxide layer 55 a formed on the PA region. The thickness of thegate oxide layer 55 b on the CA region varies depending on the extent of oxidation of the exposed CA region. As shown in FIG. 10, the edges of thegate oxide layer 55 b are thicker than the central portion of thegate oxide layer 55 b. - If desired, prior to the anisotropical etching of the second
silicon oxide layer 79, impurities may be implanted into the impurity region of the CA region, i.e. the source/drain region 68, so that contact resistance between the source/drain region 68 and a contact pad formed incontact hole 73 is lowered. - Referring now to FIG. 11, a second
conductive layer 81 for a contact pad may be formed to a thickness of between about 3000 Å and about 5000 Å on the entire surface of thesemiconductor substrate 51 such that the contact hole 73 (FIG. 8) on the CA region is completely filled. The secondconductive layer 81 may be formed using an impurity-doped polysilicon film. - Referring to FIG. 12, the second
conductive layer 81 for a contact pad is planarized, for example, through a CMP method thereby formingcontact pads conductive layer 81 is polished, the upper surface of thegate pattern 61 serves as an etching stopper.Contact pad 81 a andcontact pads 81 b are respectively connected with a bit line and storage nodes of a capacitor in a subsequent process. - The resulting integrated circuit device (FIG. 12) includes a
semiconductor substrate 51 having first and second spaced apart source/drain regions 62 on the surface thereof. Agate oxide layer 55 b extends between the first and second spaced apart source/drain regions 62. Thegate oxide layer 55 b has a reduced thickness at a central portion thereof between the first and second spaced apart source/drain regions 62 and a thickness of thegate oxide layer 55 b increases as it extends toward each of the source/drain regions 62. The integrated circuit device also includes agate electrode 57 on thegate oxide layer 55 b such that thegate oxide layer 55 b is between thesemiconductor substrate 51 and the gate electrode. The integrated circuit device may also include a secondgate oxide layer 55 a on thesemiconductor substrate 51 extending between third and fourth spaced apart source/drain regions 64. The secondgate oxide layer 55 a may have a thickness that is relatively uniform across the secondgate oxide layer 55 a between the third and fourth spaced apart source/drain regions. Asecond gate electrode 57 a may be situated on thesubstrate 51 such that the secondgate oxide layer 55 a is between thesemiconductor substrate 51 and thesecond gate electrode 57 a. - Methods according to embodiments of the present invention can provide integrated circuit devices having gate insulting layers with a central portion having a reduced thickness. Integrated circuit devices according to embodiments of the present invention may be obtained by oxidizing the exposed semiconductor substrate, for example, in the CA region so that the thickness of gate oxide layer on the CA region is increased relative to that of a gate oxide layer formed on the PA region through oxygen diffusion. A gate oxide layer on the CA region may be formed with reduced contamination that may otherwise occur during etching processes, thus enhancing operational characteristics and reliability of the semiconductor device.
- In the drawings and specification, there have been disclosed typical preferred embodiments of the invention and, although specific terms are employed, they are used in a generic and descriptive sense only and not for purposes of limitation, the scope of the invention being set forth in the following claims.
Claims (38)
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KR1020010037634A KR20030001827A (en) | 2001-06-28 | 2001-06-28 | Fabrication method of semiconductor device having dual gate oxide layer |
KR2001-0037634 | 2001-06-28 |
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US20030003700A1 true US20030003700A1 (en) | 2003-01-02 |
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Cited By (2)
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US20040067610A1 (en) * | 2002-07-26 | 2004-04-08 | Lee Yong Guen | RF semiconductor devices and methods for fabricating the same |
US20070077717A1 (en) * | 2005-09-30 | 2007-04-05 | Hynix Semiconductor Inc. | Method for forming transistor of semiconductor device |
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KR100906641B1 (en) * | 2002-12-27 | 2009-07-07 | 주식회사 하이닉스반도체 | Method for manufacturing a semiconductor device having a landing plug |
JP4529024B2 (en) * | 2003-04-22 | 2010-08-25 | ルネサスエレクトロニクス株式会社 | Semiconductor device and manufacturing method thereof |
KR100955929B1 (en) | 2003-07-25 | 2010-05-03 | 주식회사 하이닉스반도체 | Method for forming gate buffer spacer of semiconductor device |
KR100618908B1 (en) * | 2005-08-12 | 2006-09-05 | 삼성전자주식회사 | Semiconductor device and manufacturing method with improved gate resistance |
US7763517B2 (en) * | 2007-02-12 | 2010-07-27 | Macronix International Co., Ltd. | Method of forming non-volatile memory cell |
CN102122637B (en) * | 2010-01-08 | 2013-09-11 | 中芯国际集成电路制造(上海)有限公司 | Detection structure, detection method and method for forming detection structure |
KR101865566B1 (en) | 2011-09-08 | 2018-06-11 | 삼성전자주식회사 | Methods of manufacturing a vertical memory device |
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Also Published As
Publication number | Publication date |
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JP4122181B2 (en) | 2008-07-23 |
US20030199155A9 (en) | 2003-10-23 |
KR20030001827A (en) | 2003-01-08 |
US6969658B2 (en) | 2005-11-29 |
JP2003060069A (en) | 2003-02-28 |
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