US20020180309A1 - Novel piezoelectric transducer assemblies and method for their use - Google Patents
Novel piezoelectric transducer assemblies and method for their use Download PDFInfo
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- US20020180309A1 US20020180309A1 US09/870,189 US87018901A US2002180309A1 US 20020180309 A1 US20020180309 A1 US 20020180309A1 US 87018901 A US87018901 A US 87018901A US 2002180309 A1 US2002180309 A1 US 2002180309A1
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- piezoelectric transducer
- assembly
- opening
- transducer
- retainer assembly
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
- H10N30/88—Mounts; Supports; Enclosures; Casings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04B—POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
- F04B43/00—Machines, pumps, or pumping installations having flexible working members
- F04B43/02—Machines, pumps, or pumping installations having flexible working members having plate-like flexible members, e.g. diaphragms
- F04B43/06—Pumps having fluid drive
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M15/00—Testing of engines
- G01M15/04—Testing internal-combustion engines
- G01M15/10—Testing internal-combustion engines by monitoring exhaust gases or combustion flame
- G01M15/102—Testing internal-combustion engines by monitoring exhaust gases or combustion flame by monitoring exhaust gases
- G01M15/106—Testing internal-combustion engines by monitoring exhaust gases or combustion flame by monitoring exhaust gases using pressure sensors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/30—Piezoelectric or electrostrictive devices with mechanical input and electrical output, e.g. functioning as generators or sensors
- H10N30/302—Sensors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04B—POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
- F04B2205/00—Fluid parameters
- F04B2205/05—Pressure after the pump outlet
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04B—POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
- F04B2205/00—Fluid parameters
- F04B2205/06—Pressure in a (hydraulic) circuit
Definitions
- the invention disclosed and claimed herein deals with a piezoelectric transducer assemblies that are useful for the monitoring of the gas output from a diaphragm or bellows pump using air, nitrogen, or carbon dioxide as a working medium, wherein the transducer is not an integral part of the input or output flow stream of the material being pumped, but is used to sense the exhaust gas flow of the gas driven pump whereby the gas pump can be controlled.
- gas pumps herein is pulsed gas output pumps of the diaphragm or bellows type.
- the transducers of the invention disclosed herein are intended to replace those transducers currently used in monitoring the input flow of material being pumped by a gas driven pump, the output flow of materials being pumped by a gas driven pump, and/or the pressure of the input or output flow of material being pumped by a gas driven pump.
- Such transducers are, for example, magnetic Hall effect transducers, Light Emitting Diodes or photo optic transducers, and the like.
- Some pressure sensing applications in which piezoelectric transducers have been used are: the actual measurement of pressure; measuring impact forces through the use of accelerometers; use of microphones for recording or detection of sound; the generation of sounds and/or ultrasonic waves; and, the detection of passing automobiles or trains over strings of transducers.
- the gas driven pump industry has used electronic feedback from operating pumps in some critical applications for a number of years.
- the feedback has been carried out in a number of ways.
- Traditionally in gas operated pumps, at least one part typically reciprocates.
- Some pump manufacturers use electronically shifting shuttle valves within or attached to these pumps. Such shifting has been accomplished by a reciprocating portion of the pump being detected with a proximity transducer, or by a color-contrasting portion of a reciprocating part in the pump passing an electronic eye, which in turn sends an electronic signal to a shuttle valve. This movement in turn shifts the shuttle valve.
- piezoelectric transducers that provide non-invasive means for monitoring the exhaust ports of gas driven pumps to eliminate the above-mentioned problems.
- the methods disclosed and claimed herein use the transducers described just above in conjunction with digital output electronics, in which a great number of digital output electronic configuration are known in the prior art today, to provide a means for monitoring gas driven pumps. Such methods enhance the performance of the pumps and the control of the pumps without the concomitant problems associated with transducers that are required to be inserted in the pumps per se.
- the transducers of this invention can be mounted as part of a gas diffuser, or can be remotely located, even at relatively long distances from the pump, such as, for example, when that pump is handling an explosive material.
- the transducer assemblies of this invention, and the methods of this invention provide a plurality of benefits not obtainable by the transducers and methods of the prior art, such as the ability to keep all parts out of the gas pump, and especially metal parts from the diaphragm and/or bellows of the pump; ability to handle high end acid materials or caustic materials without destruction of the transducers; ability to start and stop gas pumps very quickly owing to the instantaneous response by the transducer to air flow events; allow precise monitoring and control of flow rates and metering applications; have the ability to verify priming of the gas pump and initiation of a restart of any operation, or any sequence of operation; they provide quick and easy retrofit to older or existing equipment; they can verify that the gas pump is actually operating; they have the capability of constant flow rate monitoring; they have the ability to shut down pumps on certain specified deviations from standards; they can control precise metering of fluids such as gallons, quarts, liters, ounces, or larger or smaller quantities, and, their use generally
- a piezoelectric transducer assembly comprising in combination, an insertable transducer retainer assembly and a receiving transducer retainer assembly
- the insertable transducer retainer assembly comprises a housing having an outside surface, a front and a back.
- the back has centered in it, a hub.
- the centered hub has a centered opening through it and the centered hub is integrally connected to the insertable transducer retainer assembly.
- the outside surface has a fastening means on it and a tapered front outside circumferential edge.
- the insertable transducer retainer assembly has a first circular opening in the front, wherein the first circular opening has a circular piezoelectric transducer disposed in it.
- the piezoelectric transducer has a bottom surface and a top surface.
- the centered opening in the centered hub continues on through the transducer retainer assembly housing and opens into the second opening to provide a continuous channel through the transducer retainer assembly, which exits at the back of the hub.
- the piezoelectric transducer has electrical leads connected to its bottom surface.
- the receiving transducer retainer assembly also has a housing.
- the receiving transducer retainer assembly housing has a front and a back, wherein the back has centered in it a hub integrally mounted on it.
- the receiving transducer retainer hub has a back and a front and is lesser in diameter than the diameter of the receiving transducer retainer assembly housing.
- the front of the receiving transducer retainer assembly has located therein an opening.
- the receiving transducer retainer assembly opening has an interior surface and a bottom, wherein the interior surface has disposed on it, a fastening means compatible with the fastening means of the insertable transducer retainer assembly.
- the opening has a tapered circumferential edge at the bottom.
- the saucer-like depression has a bottom.
- the surface area of the top of the saucer-like depression is relative to the surface area of the top of the piezoelectric transducer, the surface area relationship having a ratio in the range of from zero to 1:1.
- the pump in this case is a gas pump, either of the bellows type air pump, or the diaphragm type air pump.
- a system comprising an gas pump, a piezoelectric transducer assembly operably associated with the gas pump, and a control system for monitoring and controlling the gas pump.
- FIG. 1 is a full side view of one embodiment of a piezoelectric transducer assembly of this invention.
- FIG. 2 is a cross sectional view of the piezoelectric transducer assembly of this invention taken through line A-A of FIG. 1, and exploded, the internal parts of the transducer being excluded in this Figure to provide clarity to the Figure.
- FIG. 3 is a front end view of the insertable transducer retainer assembly of this invention showing the various openings therein.
- FIG. 4 is a cross sectional full side view of the insertable transducer retainer assembly of this invention taken through line B-B of FIG. 1, showing a piezoelectric transducer suspended above the openings in the insertable transducer retainer assembly.
- FIG. 5 is a cross sectional full side view of the insertable transducer retainer assembly of this invention taken through line B-B of FIG. 1, showing the piezoelectric transducer in place in the first opening and resting on a shelf.
- FIG. 6 is a cross sectional full side view of the insertable transducer retainer assembly of this invention taken through line B-B of FIG. 1, showing the piezoelectric transducer in place in the first opening and covered with a protective covering.
- FIG. 7 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a stiffener disk surmounting the piezoelectric transducer.
- FIG. 8 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a stiffener disk surmounting the piezoelectric transducer and a protective covering surmounting the stiffener disk.
- FIG. 9 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a first stiffener disk surmounting the piezoelectric transducer, a second stiffener disk surmounting the first stiffener disk, and a protective covering surmounting the second stiffener disk.
- FIG. 10 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a protective covering over the piezoelectric transducer, and a compressible material disposed in the second opening
- FIG. 11 is an exploded cross sectional full side view of the piezoelectric transducer assembly of this invention taken through line A-A showing an electronic configuration surmounted by a piezoelectric transducer, which is surmounted by a stiffener disk, which is surmounted by a protective disk.
- FIG. 12 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing an electronic configuration encapsulated in the compressible material disposed in the second opening.
- FIG. 13A is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing the use of an adhesive tape layer to cover the piezoelectric transducer.
- FIG. 13B is a cross sectional full side view of the insertable transducer retainer of this invention from FIG. 13A in which there has been added a stiffener disk 33 , shown as exploded from the surface of the adhesive tape layer.
- FIG. 14 is a graph showing the measurement of the time elapsed between the exhaust strokes of a gas pump using the piezoelectric transducer of this invention.
- FIG. 15 is a full side view of one piezoelectric transducer assembly gas diffuser.
- FIG. 16 is a cross sectional side view of the piezoelectric transducer assembly gas diffuser of FIG. 15, showing the interior details of the gas exhaust ports.
- FIG. 17 is a schematic view of a combination of a gas pump and the piezoelectric transducer assembly gas diffuser of FIG. 15, in which the piezoelectric transducer assembly gas diffuser is attached directly to the exhaust gas stream of the gas pump.
- FIG. 18 is a schematic view of a combination of a gas pump and a piezoelectric transducer assembly of this invention that is attached indirectly to the exhaust gas stream of the gas pump.
- the piezoelectric transducer assembly 1 is comprised of two segments, a receivable transducer retainer assembly 11 and an insertable transducer retainer assembly 2 , said insertable transducer retainer assembly 2 being comprised of a housing 3 , having an outside surface 4 , a front 5 , and a back 6 .
- the back 6 has centered in it, a hub 7 , the centered hub 7 having a centered opening 8 through the hub back 9 to accommodate wire leads 31 from a piezoelectric transducer 10 , (shown in FIGS. 1 and 4), or an electronic configuration 15 , shown in FIG. 11.
- the essence of the electronic configuration 15 will be discussed infra.
- the piezoelectric transducer 10 has a top surface 35 , and a bottom surface 36 .
- the piezoelectric transducer 10 usually ranges in diameter from about 0.25 inches to about 2.5 inches, the preferred size being less than about 2 inches, and the most preferred being in the range of about 3 ⁇ 4 of an inch to about 11 ⁇ 8 inches.
- the preferred thickness of the piezoelectric transducers 10 is in the range of about 0.008 millimeters to 0.20 millimeters, and the most preferred range is about 0.01 to 0.05 millimeters, and especially preferred for this invention is a range of about 0.01 to about 0.03 millimeters.
- the piezoelectric transducers 10 useful in this invention are commercially available, and are manufactured typically from stainless steel, ceramic, brass, and polymeric films, the preferred piezoelectric transducers 10 being stainless steel, and polymeric films, and especially preferred for overall performance is stainless steel.
- Thin 2-layer transducers are the most versatile configuration of all. They may be used like single sheets (made up of 2 layers), they can be used to bend, or they can be used to extend. A 2-layer transducer produces curvature when one layer expands while the other layer contracts. These transducers are often referred to as benders, bimorphs, or flexural elements. “Benders” achieve large deflections relative to other piezo transducers.
- FIG. 2 is a cross sectional view of the piezoelectric transducer assembly 1 of FIG. 1, through the line A-A, exclusive of the wire leads and the piezoelectric transducer 10 , which is shown at least in FIG. 4, and FIG. 4 shows the interior of the piezoelectric transducer assembly 1 .
- the insertable transducer retainer assembly 2 is described as insertable, because the transducer retainer assembly 2 is capable of being inserted into the opening 21 of the receiving transducer retainer assembly 11 .
- the insertable transducer retainer assembly 2 is comprised of fastening means 12 , which as shown is a set of threads, but the fastening of the insertable transducer retainer assembly 2 and the receiving transducer retainer assembly 11 can be achieved by any means in which the two segments are securely coupled together during use, but which can be separable for examination, replacement, or repair.
- a tacky gel or adhesive can be applied to the outside surface 4 of the insertable transducer retainer assembly 2 , which would hold the two segments together, but would allow the two segments to be separated easily by hand, or the two segments could be bolted, pinned, or screwed together.
- the manner and means of fastening the two segments is not critical as long as the two segments stay together during operation, and are separable by a simple means.
- FIG. 3 there is shown in the interior of the insertable transducer retainer assembly 2 a first circular opening 13 , which is located in the front 5 of the insertable transducer retainer assembly 2 .
- a second opening 16 in the middle of the insertable transducer retainer assembly 2 , just under the first circular opening 13 .
- the second opening 16 has a lesser diameter than the diameter of the first circular opening 13 in order to provide a shelf 14 for supporting the piezoelectric transducer 10 in the insertable transducer retainer assembly 2 .
- the second opening 16 is deeper than the first circular opening 13 in order to accommodate a compressible material when desired, which will be described in detail infra, and also, when desired, to provide a housing for any electronic configuration that is desired for the operation of the piezoelectric transducer 10 .
- opening or channel 8 which opens from the second opening 16 , through its bottom 17 , through the hub 7 , and exits from the back 9 of the hub 7 .
- Any wire leads used in the transducer assembly are passed through this opening 17 to be attached to a computer controlled transducer used for receiving the information from the piezoelectric transducer 10 , or the electronic configuration 15 .
- FIG. 3 is a full front end view of the insertable transducer retainer assembly 2 of this invention. There is shown the housing 3 , the first circular opening 13 , the second opening 16 , the opening 8 and the shelf 14 provided by the differences in the respective diameters of the openings 13 and 16 .
- the front outside surface 18 , of the housing 3 is beveled. It should be noted that the receiving transducer retainer assembly 11 has a complimentary beveled surface 20 at the bottom 19 of the opening 21 , which mates with the beveled surface 18 of the insertable transducer retainer assembly 2 . This arrangement allows for the two segments, i.e. the insertable transducer retainer assembly 2 and the receiving transducer retainer assembly 11 to provide a sealed interior when they are coupled together.
- the integrity of the sealed interior is dependent to some extent on the type of materials being used to manufacture the piezoelectric transducer assembly 1 , wherein some materials, because of their inherent compressibility or flexibility provide a good seal at this location, but some materials do not provide these attributes, and therefore, it is contemplated within the scope of this invention in the alternative or in combination, to utilize a gasket at this juncture to provide the sealing needed.
- gaskets are known by those skilled in the art and can consist of O-rings, for example, and other such types of gasketing which can have circular, rectangular, or other such cross sectional configurations, or, they can be flat.
- the beveled surface 20 in the bottom 19 of the opening 29 and on the interior of the opening 29 of the receiving transducer retainer assembly 11 are the mating threads 22 for the fastening means 12 of the insertable transducer retainer assembly 2 . Also shown is a centered opening 23 through the bottom 19 into a hub 24 .
- the hub 24 is centered on the back 25 of the receiving transducer retainer assembly 11 and as shown, is configured with a hexagonal outer surface 26 , such that the piezoelectric transducer assembly 1 can be fitted to an exhaust port of a gas pump (gas pump not shown) and conveniently turned much like a threaded nut.
- the centered opening 23 allows for the exhaust stream from a gas pump to move into the opening 29 , and impact the piezoelectric transducer 10 , or any of certain disks that surmount the piezoelectric transducer 10 to provide the pulse that is needed to monitor the exhaust gas stream from the gas pump.
- the saucer-shaped depression 30 has a surface area at the top of the saucer-shaped depression 30 which is relative to the surface area of the top of the piezoelectric transducer 10 , said surface area relationship having a ratio in the range of from zero to 1:1, the ratio actually used being dependent on the type of piezoelectric transducer 10 being used, the number and/or the thickness of the stiffening disks 33 being used, the type of stiffening disks 33 used, the use of an adhesive tape, and the size of the piezoelectric transducer 10 being used, all of which will be discussed in detail infra.
- the saucer-shaped depression 30 is a gas expansion chamber, which essentially allows the diffusion of the incoming exhaust gas stream across the top surface 35 of the piezoelectric transducer 10 , or any disk or disks, or adhesive tape, surmounting the piezoelectric transducer 10 .
- the proper surface area ratio between the top of the saucer-like depression and the top of the piezoelectric transducer 10 because if the pulse provided by the exhaust gas from the gas pump is not properly distributed, the response characteristics of the piezoelectric transducer 10 are diminished.
- the first embodiment of this invention is a piezoelectric transducer assembly 1 wherein FIG. 4 shows only the insertable transducer retainer assembly 2 in a cross sectional full side view from FIG. 2.
- the insertable transducer retainer assembly 2 is shown with a disk-like piezoelectric transducer 10 , with electrical leads 31 and second opening 16 .
- FIG. 4 is illustrated such that the piezoelectric transducer 10 is not setting on the shelf 14 , but is suspended above it. This illustration is for clarity sake only, and it is intended that when the transducer is fully assembled, the piezoelectric transducer 10 is fully seated in the first opening 13 and fully supported by the shelf 14 as is shown in FIG. 5.
- This embodiment of the transducer can be used when the piezoelectric transducer 10 does not need to be protected, that is, this transducer can be used in those cases where the transducer 10 does not need to be protected from harsh materials and where low pressure gas is being used to drive the gas pump.
- the opening 16 is devoid of any backing material for the piezoelectric transducer 10 , and there is only gas beneath the transducer 10 .
- FIG. 5 shows a cross sectional full side view of the insertable transducer retainer assembly 2 of FIG. 2, there is shown the insertable transducer retainer assembly 2 with the piezoelectric transducer 10 in place in the first opening 13 , along with the electrical lead wires 31 .
- the opening 16 does not have any backing in it except gas, such as air, nitrogen, or carbon dioxide.
- FIG. 6 there is shown a cross sectional full side view of the insertable transducer retainer assembly 2 of FIG. 2, wherein there is shown the embodiment of FIG. 5, but there is in place, in addition, a protective covering 32 , which protective covering 32 lies over the piezoelectric transducer 10 and protects the piezoelectric transducer 10 from harsh chemicals and the like that may be carried by the exhaust gas stream coming in from the receiving transducer retainer assembly 11 openings.
- These protective coverings 32 are manufactured from chemical resistant materials, such as Teflon® or similar materials (Teflon® is a registered trademark of the DuPont Chemical Co., Wilmington, Del., USA for products manufactured from polytetrafluoroethylene).
- similar materials that could also be used are polyethylene, polypropylene or the like, depending on the environment that the piezoelectric transducer assembly 1 is being used in.
- the protective covering 32 has a larger diameter than the piezoelectric transducer 10 , and the reason for that is that it is required that the protective covering 32 cover the transducer 10 completely, and it is also a requirement of this invention that the protective cover 32 is retained by, and sealed at, the beveled surfaces 18 and 20 when the piezoelectric transducer assembly 1 comes together.
- a protective cover 32 is used in the piezoelectric transducer assembly 1 , it is believed that there is no requirement for gasketing at the interface of the beveled surfaces 18 and 20 .
- This embodiment is used when there is a need to protect the piezoelectric transducer 10 in applications where low exhaust gas pressures are being used.
- FIG. 7 is a cross sectional full side view of the insertable transducer retainer assembly 2 of FIG. 2, a piezoelectric transducer 10 , lying on the shelf 14 , and the piezoelectric transducer 10 is surmounted by a stiffening disk 33 .
- the stiffening disk 33 has a diameter approximating or nearly approximating the diameter of the piezoelectric transducer 10 such that the piezoelectric transducer 10 is sealed from the exhaust gas stream.
- the disk is required to have limited movement at the center of the piezoelectric transducer 10 after the piezoelectric transducer assembly 1 is assembled.
- the disk serves as a “stiffener” for the piezoelectric transducer 10 so that it will not permanently bend out of its flat configuration, but moreover, the stiffener disk 33 serves to diminish the return response of the piezoelectric transducer 10 after it flexes in response to positive force placed on it from the exhaust gas stream. In other words, the stiffening disk 33 creates a buffer to diminish the force acting on the piezoelectric transducer 10 , from any force that deflects it into the opening 16 . It is contemplated within the scope of this invention to use only one disk 33 , wherein the disk 33 can also be manufactured from a protective material such as Teflon, and also serve as a stiffener disk 33 .
- stiffening disks 33 having thicknesses in the range of about 0.01 millimeters (0.005 inches) to about 1.2 millimeters (0.050 inches), and it is preferred that the thickness be in the range of about 0.127 millimeters (0.010 inches) to about 1.016 millimeters (0.040 inches), and it is especially preferred that the thickness be in the range of about 0.254 millimeters (0.10 inches) to 0.508 millimeters (0.020 inches), all of the above depending on the type of material used to manufacture the disk 33 , and the number of such disks 33 used in the piezoelectric transducer assembly 1 , and the end use application of the gas pump that the piezoelectric transducer assembly 1 is associated with.
- stiffening disk 33 It is also contemplated within the scope of this invention to use more than one stiffening disk 33 and that stiffening disks 33 of various types of materials in a variable stacking configurations can be used herein to accommodate operating conditions or other characteristics of the piezoelectric transducer 10 for different applications.
- the disks are preferably manufactured from polymeric materials, for example, polyethylene, polypropylene, polytetraflurocarbons, such as polytetrafluroethylene, and the like.
- These materials typically have Tensile Modulus according to ASTM D638 in the range of 130,000 to 250,000 psi for the polypropylene, 25,000 to 130,000 psi for polyethylene, and in the range of 38,000 to about 110,000 psi for the fluorinated polymers.
- Fluorinated polymers can be selected from materials such as polytetrafluoroethylene, fluorinated-ethylenepropylene, perfluoroalkoxys, polychlorotrifluoroethylene, ethylene tetrafluoroethylene, and polyvinylidene fluoride, as long as the material is a solid.
- polyethylene, polypropylene, and polytetrafluoroethylene are especially preferred. It is contemplated within the scope of this invention to use silicone polymers having similar Tensile Modulii in the range of 50,000 to 80,000, as well.
- the number of, the type of, and the total thickness of the stiffening disk or disks 33 to be used can be determined from a simple test in which the stiffening disks 33 are placed in a piezoelectric transducer assembly 1 , operably attaching the piezoelectric transducer assembly 1 to the exhaust of the particular pump being tested, and running a test in which the pump activity as indicated by the exhaust gas versus the action of the transducer is charted.
- This embodiment is used when it is not necessary to have protection for the piezoelectric transducer 10 , but it is desired to use medium to high exhaust gas pressures.
- FIG. 8 shows a cross sectional full side view of the insertable transducer retainer assembly 2 of FIG. 2, in which there is additionally shown the piezoelectric transducer 10 in place in the first opening 13 and resting on the shelf 14 , the piezoelectric transducer 10 being surmounted by a stiffener disk 33 , and then a protective cover 32 covering the stiffener disk 33 .
- This embodiment is desired when the application requires that medium to high exhaust gas pressures are being used, and the environment requires that the piezoelectric transducer 10 be protected.
- FIG. 9 shows the embodiment of FIG. 8, except there is shown multiple layers of stiffener disks 33 , the reason being that these are used in exhaust gas high pressure applications.
- the configuration shown in FIG. 9 also shows a protective covering 32 , which would be necessary in an environment where the exhaust gas pressures are high and the piezoelectric transducer 10 needs to be protected.
- the piezoelectric transducer 10 may need support other than that provided by resting on the shelf 14 and in FIG. 10, there is shown a cross sectional full side view of the insertable transducer retainer assembly 2 of FIG. 2 in which there is shown a compressible material 34 located in the second opening 16 .
- This compressible material 34 is capable of compressing to the extent that the piezoelectric transducer 10 deflects into the opening 16 , but does not compress to the extent that the piezoelectric transducer 10 bursts from its position or is pushed from the shelf 14 and into the opening 16 .
- the compressible material allows for a rebound or flex from sustained high pressure applications up to about 100 psi.
- this material is an elastomeric or gelled silicone polymer but can be selected from other polymers such as fluoropolymers, urethanes, epoxies, acrylics, polyvinyl alcohols, and polyvinyl acetates, just to name a few.
- This manner of supporting the piezoelectric transducer 10 prevents destruction of the piezoelectric transducer 10 and helps prevent the piezoelectric transducer assembly 1 from malfunctioning.
- FIG. 11 there is shown an exploded cross sectional full side view of the piezoelectric transducer assembly 1 of FIG. 1, which has been modified to include an electronic configuration 15 in the opening 16 .
- the electronic configuration 15 has leads 37 that are attached to a control unit (not shown) for the application in which the piezoelectric transducer assembly 1 is being used.
- the electronic configuration 15 can be placed anywhere in the opening 16 , for example, resting on the bottom 17 of the insertable transducer retainer assembly 2 , or it could be suspended by the compressible material 34 , as shown in FIG. 12
- the term “compressible” means any elastomeric, gelled, or similar material that will allow the piezoelectric transducer 10 to move into it in direct response to the pulses from the exhaust gas of the gas pump, while preventing the piezoelectric transducer 10 from permanently bending, or bursting, or leaving the support provided by the shelf 14 .
- the compressible material 34 is typically used when the gas pressure on the pump exceeds about 20 psi and up to about 100 psi. Gas pressures below about 20 psi do not normally require the use of the compressible material 34 .
- FIG. 13A There is yet another embodiment of this invention which is shown in FIG. 13A in which an adhesive tape 45 surmounts the piezoelectric transducer 10 .
- an adhesive tape 45 surmounts the piezoelectric transducer 10 .
- One purpose for the use of the adhesive tape 45 is to hold the piezoelectric transducer 10 solidly on the shelf 14 and to help diffuse the pulse of the exhaust gas evenly over the piezoelectric transducer 10 .
- the type of adhesive tape 45 is not overly critical, and any adhesive tape 5 that fixes the piezoelectric transducer 10 in place and effectively distributes the effect of the pulse from the exhaust gas evenly over the piezoelectric transducer 10 can be used.
- One such adhesive tape is Teflon tape of about 3 to 8 mil thickness, with an acrylic adhesive on the back.
- the housing parts of the piezoelectric transducer assembly are constructed from any solid material that has sufficient strength to support the internal components. Such materials should be selected on the basis of the end use application that the piezoelectric transducer assembly and the associated pump will be used for, along with the cost of such materials, their handleability, durability, processability and machineability.
- Such materials can be, for example, polyethylene, polypropylene, polyfluorinated polymers selected from polytetrafluoroethylene, fluorinated ethylenepropylene, perfluoroalkoxys, polychlorotrifluoroethylene, ethylene tetrafluoroethylene and polyvinylidene fluoride, silicone polymers, nylon, synthetic resins, metals selected from aluminum, copper, and alloys of aluminum and copper.
- a method of monitoring a gas pump comprising two steps, the first step of providing a gas pump that has a piezoelectric transducer assembly operably attached to the exhaust outlet of a gas pump such that the exhaust pulses of the gas pump impact directly or indirectly, the piezoelectric transducer of the piezoelectric transducer assembly and step two, measuring the time elapsed between the exhaust strokes such that the number of strokes per unit of time can be determined.
- a third step which is the adjustment of the pump input gas flow to bring the pump into normal working order, based on the measurement of time that has elapsed between the exhaust strokes.
- the inventor herein has found one example of connecting a piezoelectric transducer to the exhaust of a pump.
- the pump is not a gas pump, and the transducer assembly 1 of the instant invention was not used therein.
- the prior art device as disclosed in U.S. Pat. No. 5,655,357, that issued Aug. 12, 1997, uses a signal to display the progress of a vacuum process and/or shut down the vacuum pump upon establishing a substantial vacuum within the package being evacuated.
- the transducer assembly 1 of the instant invention detects gas pulses to establish a digital output to a personal computer, for example.
- the output from the instant transducer assembly 1 is time specific, not pressure specific, as in the prior art device.
- the number of strokes per unit of time can be determined, and in this manner, it can be determined if the pump is malfunctioning, and if malfunctioning, it can be adjusted, or shut down to prevent damage to the manufacturing or other applications in which it is being used.
- the timing between exhaust strokes increases, flow decreases, which might be due to a plugged filter, or changes in gas pressure being fed to the gas pump, or the like.
- the timing between exhaust strokes decreases, this indicates an increase in flow and problems with pump transducers or line pressure changes to the pump, or the like.
- By monitoring the number of strokes per unit of time one can gauge the flow rate of the pump and thereby control the pump.
- FIG. 17 there is shown a schematic of a gas pump 38 , which has attached directly to the gas exhaust 39 of the pump, the piezoelectric transducer assembly 1 of this invention configured as a gas diffuser 40 .
- the gas diffuser 40 can be observed from FIG. 15, wherein there is shown a full side view of the piezoelectric transducer assembly 1 of this invention in a configuration of the gas diffuser 40 , showing the exhaust ports 41 for the exhaust gas from the gas pump 38 .
- FIG. 16 shows a cross sectional full side view of the piezoelectric transducer assembly gas diffuser 40 of FIG. 15 through line C-C in which the construction of the exhaust ports 41 in the interior is shown.
- the placement of the exhaust ports 41 is not critical, as long as the exhaust from the gas pump 38 is allowed to enter the saucer-shaped depression 30 , diffuse and impinge on the piezoelectric transducer 10 , either directly, or indirectly through stiffener disks 33 and/or protective coverings 32 , and/or adhesive tapes 45 , and then allowed to exit the receiving transducer retainer assembly 11 without exhausting through the insertable transducer retainer assembly 2 .
- FIG. 17 also shows a gas inlet 42 to the pump 38 .
- the piezoelectric transducer assemblies 1 of this invention can also be hooked operably to the pump indirectly, such as is shown in FIG. 18, wherein there is shown the pump 38 , in schematic, the gas inlet port 42 , the pump gas exhaust line 39 , and a gas diffuser 43 for the pump gas exhaust line 39 . There is also shown the placement of a piezoelectric transducer assembly 11 , without the capability of exhausting gas pump exhaust through it, which is attached to the pump gas exhaust line 39 .
- gas line 44 leading from the pump gas exhaust line to the piezoelectric transducer assembly 11 can be a long line, and thus the piezoelectric transducer 10 can be dislocated a long distance from the pump 38 and the operations of the manufacturing to which the pump 38 is an accessory.
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Abstract
Description
- The invention disclosed and claimed herein deals with a piezoelectric transducer assemblies that are useful for the monitoring of the gas output from a diaphragm or bellows pump using air, nitrogen, or carbon dioxide as a working medium, wherein the transducer is not an integral part of the input or output flow stream of the material being pumped, but is used to sense the exhaust gas flow of the gas driven pump whereby the gas pump can be controlled. For purposes of this invention, what is meant by “gas pumps” herein is pulsed gas output pumps of the diaphragm or bellows type.
- The transducers of the invention disclosed herein are intended to replace those transducers currently used in monitoring the input flow of material being pumped by a gas driven pump, the output flow of materials being pumped by a gas driven pump, and/or the pressure of the input or output flow of material being pumped by a gas driven pump. Such transducers are, for example, magnetic Hall effect transducers, Light Emitting Diodes or photo optic transducers, and the like.
- In understanding the invention disclosed herein, one must remember that there are essentially, at minimum, two flow streams in a situation wherein material is being pumped by a gas driven pump. The first is the flow stream provided by the gas that is being used to drive the pump, and the second, or other streams, are those provided by the material being handled by the pump, such as water, non-toxic fluids, aqueous acids, aqueous caustics and other hazardous, toxic, and other pump destructive materials.
- With the invention herein, when describing “flow”, it is meant that the discussion deals essentially with the flow of material being handled by the gas driven pump, and not the flow of gas being used to drive the gas driven pump, unless the gas flow stream is indicated otherwise.
- The use of piezoelectric transducers to measure, monitor and track various events is not new in the art. Currently, manufacturers are using magnetic Hall effect transducers, photo optic transducers, Light Emitting Diode transducers and the like to monitor gas pumps, or measure events taking place in manufacturing processes where gas pumps are utilized, wherein most pumps in use today are air driven pumps.
- Some pressure sensing applications in which piezoelectric transducers have been used are: the actual measurement of pressure; measuring impact forces through the use of accelerometers; use of microphones for recording or detection of sound; the generation of sounds and/or ultrasonic waves; and, the detection of passing automobiles or trains over strings of transducers.
- The gas driven pump industry has used electronic feedback from operating pumps in some critical applications for a number of years. The feedback has been carried out in a number of ways. Traditionally, in gas operated pumps, at least one part typically reciprocates. Some pump manufacturers use electronically shifting shuttle valves within or attached to these pumps. Such shifting has been accomplished by a reciprocating portion of the pump being detected with a proximity transducer, or by a color-contrasting portion of a reciprocating part in the pump passing an electronic eye, which in turn sends an electronic signal to a shuttle valve. This movement in turn shifts the shuttle valve.
- Other pump manufacturers have used both mechanical and solid-state pressure switches, which receive a blast of gas from valves inside the pump at the desired time of shuttle valve switching. The mechanical or solid-state pressure switch then translates the blast of gas into an electronic signal that is then sent on to the shuttle valve for operation of the shuttle valve. In addition, the electronic signals that are sent to the shuttle valve can and have been tapped by manufacturers to provide electronic signals to other apparatii that monitor the pumps. These apparatii include but are not limited to: cycle counting transducers, tachometers, overrun monitors, underrun monitors and personal computer systems which are embedded in tools which monitor pumps, among other things.
- In every case, the use of such current equipment requires invasive transducer placement in the pump itself. This creates a situation where the parts placed in the interior of the pump cause contamination, or the parts are affected by the caustic, acid, or other destructive chemicals being handled by the pump. Such parts include, for example, flow meters, mass transducers, and paddle wheel transducers, all of which are placed directly in the flow of the materials being handled by the pump. In the case of foods, such parts create situations wherein the food is contaminated by trace metals and other materials. Also, the placement of these parts in the interior of the pump creates a situation wherein the parts act as plugs or create plugs, or partial plugs, in the flow of the material being handled by the pump, and in addition, these parts are difficult to replace or repair.
- In other situations, owing to the above stated problems, pump systems are not monitored at all and this leads to malfunctions in component parts of the manufacturing process and thus also leads to expensive downtime, cleanup and myriad other problems. In these situations, the only time that the pump is monitored is when there is a major malfunction that happens to be noticed by those monitoring the manufacturing process. The ultimate is when these problems cause the pump to stop completely, which often leads to human injury and equipment destruction.
- Thus, it would be valuable to have a means of monitoring and/or controlling gas driven pumps by a non-invasive transducer that would essentially eliminate all of the above-mentioned problems.
- What are disclosed and claimed herein are piezoelectric transducers that provide non-invasive means for monitoring the exhaust ports of gas driven pumps to eliminate the above-mentioned problems.
- The methods disclosed and claimed herein use the transducers described just above in conjunction with digital output electronics, in which a great number of digital output electronic configuration are known in the prior art today, to provide a means for monitoring gas driven pumps. Such methods enhance the performance of the pumps and the control of the pumps without the concomitant problems associated with transducers that are required to be inserted in the pumps per se. The transducers of this invention can be mounted as part of a gas diffuser, or can be remotely located, even at relatively long distances from the pump, such as, for example, when that pump is handling an explosive material.
- The transducer assemblies of this invention, and the methods of this invention provide a plurality of benefits not obtainable by the transducers and methods of the prior art, such as the ability to keep all parts out of the gas pump, and especially metal parts from the diaphragm and/or bellows of the pump; ability to handle high end acid materials or caustic materials without destruction of the transducers; ability to start and stop gas pumps very quickly owing to the instantaneous response by the transducer to air flow events; allow precise monitoring and control of flow rates and metering applications; have the ability to verify priming of the gas pump and initiation of a restart of any operation, or any sequence of operation; they provide quick and easy retrofit to older or existing equipment; they can verify that the gas pump is actually operating; they have the capability of constant flow rate monitoring; they have the ability to shut down pumps on certain specified deviations from standards; they can control precise metering of fluids such as gallons, quarts, liters, ounces, or larger or smaller quantities, and, their use generally leads to more efficient and more reliable gas pump designs.
- Thus, what is disclosed and claimed herein in one embodiment is a piezoelectric transducer assembly comprising in combination, an insertable transducer retainer assembly and a receiving transducer retainer assembly, the insertable transducer retainer assembly comprises a housing having an outside surface, a front and a back. The back has centered in it, a hub. The centered hub has a centered opening through it and the centered hub is integrally connected to the insertable transducer retainer assembly. The outside surface has a fastening means on it and a tapered front outside circumferential edge.
- The insertable transducer retainer assembly has a first circular opening in the front, wherein the first circular opening has a circular piezoelectric transducer disposed in it. The piezoelectric transducer has a bottom surface and a top surface.
- There is a second opening in the front of the insertable transducer retainer assembly, deeper than the first circular opening and having a lesser diameter than the diameter of the first circular opening.
- The centered opening in the centered hub continues on through the transducer retainer assembly housing and opens into the second opening to provide a continuous channel through the transducer retainer assembly, which exits at the back of the hub. The piezoelectric transducer has electrical leads connected to its bottom surface.
- The receiving transducer retainer assembly also has a housing. The receiving transducer retainer assembly housing has a front and a back, wherein the back has centered in it a hub integrally mounted on it. The receiving transducer retainer hub has a back and a front and is lesser in diameter than the diameter of the receiving transducer retainer assembly housing.
- The front of the receiving transducer retainer assembly has located therein an opening. The receiving transducer retainer assembly opening has an interior surface and a bottom, wherein the interior surface has disposed on it, a fastening means compatible with the fastening means of the insertable transducer retainer assembly. The opening has a tapered circumferential edge at the bottom. There is a saucer-like depression below the bottom of the opening in the receiving transducer retainer assembly. The saucer-like depression has a bottom. The surface area of the top of the saucer-like depression is relative to the surface area of the top of the piezoelectric transducer, the surface area relationship having a ratio in the range of from zero to 1:1.
- There is a channeled opening from the bottom of the saucer-like depression through the center of the receiving transducer retainer hub and the interior of the receiving transducer retainer hub has an adapting means for adapting the receiving transducer retainer assembly to a pump. The pump in this case is a gas pump, either of the bellows type air pump, or the diaphragm type air pump.
- In a further embodiment of this invention, in the piezoelectric transducer, there is disposed over the top of the piezoelectric transducer, an elastomeric protective covering, typically in the form of a disk, the details of which are set forth infra.
- In yet another embodiment of this invention, there is further disposed in the bottom of the second opening of the transducer retainer assembly, an electronic configuration, the details of which are provided infra.
- In still another embodiment of this invention, there is disposed in the second opening a compressible material, the details of which are provided infra.
- In addition, there is an embodiment of this invention in which there is provided at least one stiffening disk covering the piezoelectric transducer per se, the details of which are also provided intra.
- In still another embodiment of this invention, there is set forth a system comprising an gas pump, a piezoelectric transducer assembly operably associated with the gas pump, and a control system for monitoring and controlling the gas pump.
- FIG. 1 is a full side view of one embodiment of a piezoelectric transducer assembly of this invention.
- FIG. 2 is a cross sectional view of the piezoelectric transducer assembly of this invention taken through line A-A of FIG. 1, and exploded, the internal parts of the transducer being excluded in this Figure to provide clarity to the Figure.
- FIG. 3 is a front end view of the insertable transducer retainer assembly of this invention showing the various openings therein.
- FIG. 4 is a cross sectional full side view of the insertable transducer retainer assembly of this invention taken through line B-B of FIG. 1, showing a piezoelectric transducer suspended above the openings in the insertable transducer retainer assembly.
- FIG. 5 is a cross sectional full side view of the insertable transducer retainer assembly of this invention taken through line B-B of FIG. 1, showing the piezoelectric transducer in place in the first opening and resting on a shelf.
- FIG. 6 is a cross sectional full side view of the insertable transducer retainer assembly of this invention taken through line B-B of FIG. 1, showing the piezoelectric transducer in place in the first opening and covered with a protective covering.
- FIG. 7 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a stiffener disk surmounting the piezoelectric transducer.
- FIG. 8 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a stiffener disk surmounting the piezoelectric transducer and a protective covering surmounting the stiffener disk.
- FIG. 9 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a first stiffener disk surmounting the piezoelectric transducer, a second stiffener disk surmounting the first stiffener disk, and a protective covering surmounting the second stiffener disk.
- FIG. 10 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing a protective covering over the piezoelectric transducer, and a compressible material disposed in the second opening
- FIG. 11 is an exploded cross sectional full side view of the piezoelectric transducer assembly of this invention taken through line A-A showing an electronic configuration surmounted by a piezoelectric transducer, which is surmounted by a stiffener disk, which is surmounted by a protective disk.
- FIG. 12 is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing an electronic configuration encapsulated in the compressible material disposed in the second opening.
- FIG. 13A is a cross sectional full side view of the insertable transducer retainer of this invention taken through line B-B of FIG. 1, showing the use of an adhesive tape layer to cover the piezoelectric transducer.
- FIG. 13B is a cross sectional full side view of the insertable transducer retainer of this invention from FIG. 13A in which there has been added a
stiffener disk 33, shown as exploded from the surface of the adhesive tape layer. - FIG. 14 is a graph showing the measurement of the time elapsed between the exhaust strokes of a gas pump using the piezoelectric transducer of this invention.
- FIG. 15 is a full side view of one piezoelectric transducer assembly gas diffuser.
- FIG. 16 is a cross sectional side view of the piezoelectric transducer assembly gas diffuser of FIG. 15, showing the interior details of the gas exhaust ports.
- FIG. 17 is a schematic view of a combination of a gas pump and the piezoelectric transducer assembly gas diffuser of FIG. 15, in which the piezoelectric transducer assembly gas diffuser is attached directly to the exhaust gas stream of the gas pump.
- FIG. 18 is a schematic view of a combination of a gas pump and a piezoelectric transducer assembly of this invention that is attached indirectly to the exhaust gas stream of the gas pump.
- Turning now to the Figures, and with regard to FIGS. 1 and 2, there is shown a full side view of a piezoelectric transducer assembly1 of this invention. The piezoelectric transducer assembly 1 is comprised of two segments, a receivable
transducer retainer assembly 11 and an insertabletransducer retainer assembly 2, said insertabletransducer retainer assembly 2 being comprised of ahousing 3, having anoutside surface 4, afront 5, and a back 6. The back 6 has centered in it, a hub 7, the centered hub 7 having acentered opening 8 through the hub back 9 to accommodate wire leads 31 from apiezoelectric transducer 10, (shown in FIGS. 1 and 4), or anelectronic configuration 15, shown in FIG. 11. The essence of theelectronic configuration 15 will be discussed infra. Thepiezoelectric transducer 10 has atop surface 35, and abottom surface 36. - The
piezoelectric transducer 10 usually ranges in diameter from about 0.25 inches to about 2.5 inches, the preferred size being less than about 2 inches, and the most preferred being in the range of about ¾ of an inch to about 1⅛ inches. The preferred thickness of thepiezoelectric transducers 10 is in the range of about 0.008 millimeters to 0.20 millimeters, and the most preferred range is about 0.01 to 0.05 millimeters, and especially preferred for this invention is a range of about 0.01 to about 0.03 millimeters. Thepiezoelectric transducers 10 useful in this invention are commercially available, and are manufactured typically from stainless steel, ceramic, brass, and polymeric films, the preferredpiezoelectric transducers 10 being stainless steel, and polymeric films, and especially preferred for overall performance is stainless steel. Thin 2-layer transducers are the most versatile configuration of all. They may be used like single sheets (made up of 2 layers), they can be used to bend, or they can be used to extend. A 2-layer transducer produces curvature when one layer expands while the other layer contracts. These transducers are often referred to as benders, bimorphs, or flexural elements. “Benders” achieve large deflections relative to other piezo transducers. - FIG. 2 is a cross sectional view of the piezoelectric transducer assembly1 of FIG. 1, through the line A-A, exclusive of the wire leads and the
piezoelectric transducer 10, which is shown at least in FIG. 4, and FIG. 4 shows the interior of the piezoelectric transducer assembly 1. The insertabletransducer retainer assembly 2 is described as insertable, because thetransducer retainer assembly 2 is capable of being inserted into theopening 21 of the receivingtransducer retainer assembly 11. - The insertable
transducer retainer assembly 2 is comprised of fastening means 12, which as shown is a set of threads, but the fastening of the insertabletransducer retainer assembly 2 and the receivingtransducer retainer assembly 11 can be achieved by any means in which the two segments are securely coupled together during use, but which can be separable for examination, replacement, or repair. For example, a tacky gel or adhesive can be applied to theoutside surface 4 of the insertabletransducer retainer assembly 2, which would hold the two segments together, but would allow the two segments to be separated easily by hand, or the two segments could be bolted, pinned, or screwed together. The manner and means of fastening the two segments is not critical as long as the two segments stay together during operation, and are separable by a simple means. - With regard to FIG. 3, there is shown in the interior of the insertable transducer retainer assembly2 a first
circular opening 13, which is located in thefront 5 of the insertabletransducer retainer assembly 2. There is asecond opening 16 in the middle of the insertabletransducer retainer assembly 2, just under the firstcircular opening 13. Thesecond opening 16 has a lesser diameter than the diameter of the firstcircular opening 13 in order to provide ashelf 14 for supporting thepiezoelectric transducer 10 in the insertabletransducer retainer assembly 2. Also, thesecond opening 16 is deeper than the firstcircular opening 13 in order to accommodate a compressible material when desired, which will be described in detail infra, and also, when desired, to provide a housing for any electronic configuration that is desired for the operation of thepiezoelectric transducer 10. - In addition to the
openings channel 8, which opens from thesecond opening 16, through its bottom 17, through the hub 7, and exits from theback 9 of the hub 7. Any wire leads used in the transducer assembly, are passed through thisopening 17 to be attached to a computer controlled transducer used for receiving the information from thepiezoelectric transducer 10, or theelectronic configuration 15. - The
openings shelf 14 can be further appreciated by viewing FIG. 3, which is a full front end view of the insertabletransducer retainer assembly 2 of this invention. There is shown thehousing 3, the firstcircular opening 13, thesecond opening 16, theopening 8 and theshelf 14 provided by the differences in the respective diameters of theopenings - The front outside
surface 18, of thehousing 3, is beveled. It should be noted that the receivingtransducer retainer assembly 11 has a complimentarybeveled surface 20 at the bottom 19 of theopening 21, which mates with thebeveled surface 18 of the insertabletransducer retainer assembly 2. This arrangement allows for the two segments, i.e. the insertabletransducer retainer assembly 2 and the receivingtransducer retainer assembly 11 to provide a sealed interior when they are coupled together. The integrity of the sealed interior is dependent to some extent on the type of materials being used to manufacture the piezoelectric transducer assembly 1, wherein some materials, because of their inherent compressibility or flexibility provide a good seal at this location, but some materials do not provide these attributes, and therefore, it is contemplated within the scope of this invention in the alternative or in combination, to utilize a gasket at this juncture to provide the sealing needed. Such gaskets are known by those skilled in the art and can consist of O-rings, for example, and other such types of gasketing which can have circular, rectangular, or other such cross sectional configurations, or, they can be flat. - Turning now to the receiving
transducer retainer assembly 11, as it can be observed from FIG. 2, there is shown such anassembly 11, wherein there is anopening 29 in thefront 28 of thehousing 27. - Shown in the
opening 29 is thebeveled surface 20 in the bottom 19 of theopening 29 and on the interior of theopening 29 of the receivingtransducer retainer assembly 11 are themating threads 22 for the fastening means 12 of the insertabletransducer retainer assembly 2. Also shown is acentered opening 23 through the bottom 19 into ahub 24. Thehub 24 is centered on theback 25 of the receivingtransducer retainer assembly 11 and as shown, is configured with a hexagonalouter surface 26, such that the piezoelectric transducer assembly 1 can be fitted to an exhaust port of a gas pump (gas pump not shown) and conveniently turned much like a threaded nut. The centeredopening 23 allows for the exhaust stream from a gas pump to move into theopening 29, and impact thepiezoelectric transducer 10, or any of certain disks that surmount thepiezoelectric transducer 10 to provide the pulse that is needed to monitor the exhaust gas stream from the gas pump. - Note should be taken of the saucer-shaped
depression 30 in the center of the bottom of theopening 29. The saucer-shapeddepression 30 has a surface area at the top of the saucer-shapeddepression 30 which is relative to the surface area of the top of thepiezoelectric transducer 10, said surface area relationship having a ratio in the range of from zero to 1:1, the ratio actually used being dependent on the type ofpiezoelectric transducer 10 being used, the number and/or the thickness of the stiffeningdisks 33 being used, the type of stiffeningdisks 33 used, the use of an adhesive tape, and the size of thepiezoelectric transducer 10 being used, all of which will be discussed in detail infra. The saucer-shapeddepression 30 is a gas expansion chamber, which essentially allows the diffusion of the incoming exhaust gas stream across thetop surface 35 of thepiezoelectric transducer 10, or any disk or disks, or adhesive tape, surmounting thepiezoelectric transducer 10. Thus, there is an importance to providing the proper surface area ratio between the top of the saucer-like depression and the top of thepiezoelectric transducer 10, because if the pulse provided by the exhaust gas from the gas pump is not properly distributed, the response characteristics of thepiezoelectric transducer 10 are diminished. - The first embodiment of this invention is a piezoelectric transducer assembly1 wherein FIG. 4 shows only the insertable
transducer retainer assembly 2 in a cross sectional full side view from FIG. 2. The insertabletransducer retainer assembly 2 is shown with a disk-likepiezoelectric transducer 10, withelectrical leads 31 andsecond opening 16. FIG. 4 is illustrated such that thepiezoelectric transducer 10 is not setting on theshelf 14, but is suspended above it. This illustration is for clarity sake only, and it is intended that when the transducer is fully assembled, thepiezoelectric transducer 10 is fully seated in thefirst opening 13 and fully supported by theshelf 14 as is shown in FIG. 5. This embodiment of the transducer can be used when thepiezoelectric transducer 10 does not need to be protected, that is, this transducer can be used in those cases where thetransducer 10 does not need to be protected from harsh materials and where low pressure gas is being used to drive the gas pump. - For purposes of this invention, “low pressure” means in the range of over zero to about 10 psi. Also for purposes of this invention, “medium pressure” means in the range in excess of 10 to about 20 psi and “high pressure” means in excess of about 20 to about 100 psi. It should be noted that in this embodiment, the
opening 16 is devoid of any backing material for thepiezoelectric transducer 10, and there is only gas beneath thetransducer 10. FIG. 5, shows a cross sectional full side view of the insertabletransducer retainer assembly 2 of FIG. 2, there is shown the insertabletransducer retainer assembly 2 with thepiezoelectric transducer 10 in place in thefirst opening 13, along with theelectrical lead wires 31. Again, in this embodiment, theopening 16 does not have any backing in it except gas, such as air, nitrogen, or carbon dioxide. - Turning to FIG. 6, there is shown a cross sectional full side view of the insertable
transducer retainer assembly 2 of FIG. 2, wherein there is shown the embodiment of FIG. 5, but there is in place, in addition, aprotective covering 32, whichprotective covering 32 lies over thepiezoelectric transducer 10 and protects thepiezoelectric transducer 10 from harsh chemicals and the like that may be carried by the exhaust gas stream coming in from the receivingtransducer retainer assembly 11 openings. Theseprotective coverings 32 are manufactured from chemical resistant materials, such as Teflon® or similar materials (Teflon® is a registered trademark of the DuPont Chemical Co., Wilmington, Del., USA for products manufactured from polytetrafluoroethylene). For example, similar materials that could also be used are polyethylene, polypropylene or the like, depending on the environment that the piezoelectric transducer assembly 1 is being used in. It should be noted that theprotective covering 32 has a larger diameter than thepiezoelectric transducer 10, and the reason for that is that it is required that theprotective covering 32 cover thetransducer 10 completely, and it is also a requirement of this invention that theprotective cover 32 is retained by, and sealed at, thebeveled surfaces protective cover 32 is used in the piezoelectric transducer assembly 1, it is believed that there is no requirement for gasketing at the interface of thebeveled surfaces piezoelectric transducer 10 in applications where low exhaust gas pressures are being used. - Turning now to another embodiment of this invention, which is a critical concept for this invention, there is shown in FIG. 7, which is a cross sectional full side view of the insertable
transducer retainer assembly 2 of FIG. 2, apiezoelectric transducer 10, lying on theshelf 14, and thepiezoelectric transducer 10 is surmounted by astiffening disk 33. Note that thestiffening disk 33 has a diameter approximating or nearly approximating the diameter of thepiezoelectric transducer 10 such that thepiezoelectric transducer 10 is sealed from the exhaust gas stream. The disk is required to have limited movement at the center of thepiezoelectric transducer 10 after the piezoelectric transducer assembly 1 is assembled. In addition to the sealing function, the disk serves as a “stiffener” for thepiezoelectric transducer 10 so that it will not permanently bend out of its flat configuration, but moreover, thestiffener disk 33 serves to diminish the return response of thepiezoelectric transducer 10 after it flexes in response to positive force placed on it from the exhaust gas stream. In other words, thestiffening disk 33 creates a buffer to diminish the force acting on thepiezoelectric transducer 10, from any force that deflects it into theopening 16. It is contemplated within the scope of this invention to use only onedisk 33, wherein thedisk 33 can also be manufactured from a protective material such as Teflon, and also serve as astiffener disk 33. - It is contemplated within the scope of this invention to use stiffening
disks 33 having thicknesses in the range of about 0.01 millimeters (0.005 inches) to about 1.2 millimeters (0.050 inches), and it is preferred that the thickness be in the range of about 0.127 millimeters (0.010 inches) to about 1.016 millimeters (0.040 inches), and it is especially preferred that the thickness be in the range of about 0.254 millimeters (0.10 inches) to 0.508 millimeters (0.020 inches), all of the above depending on the type of material used to manufacture thedisk 33, and the number ofsuch disks 33 used in the piezoelectric transducer assembly 1, and the end use application of the gas pump that the piezoelectric transducer assembly 1 is associated with. - It is also contemplated within the scope of this invention to use more than one
stiffening disk 33 and that stiffeningdisks 33 of various types of materials in a variable stacking configurations can be used herein to accommodate operating conditions or other characteristics of thepiezoelectric transducer 10 for different applications. The disks are preferably manufactured from polymeric materials, for example, polyethylene, polypropylene, polytetraflurocarbons, such as polytetrafluroethylene, and the like. These materials typically have Tensile Modulus according to ASTM D638 in the range of 130,000 to 250,000 psi for the polypropylene, 25,000 to 130,000 psi for polyethylene, and in the range of 38,000 to about 110,000 psi for the fluorinated polymers. Fluorinated polymers can be selected from materials such as polytetrafluoroethylene, fluorinated-ethylenepropylene, perfluoroalkoxys, polychlorotrifluoroethylene, ethylene tetrafluoroethylene, and polyvinylidene fluoride, as long as the material is a solid. Especially preferred are polyethylene, polypropylene, and polytetrafluoroethylene. It is contemplated within the scope of this invention to use silicone polymers having similar Tensile Modulii in the range of 50,000 to 80,000, as well. - The number of, the type of, and the total thickness of the stiffening disk or
disks 33 to be used can be determined from a simple test in which thestiffening disks 33 are placed in a piezoelectric transducer assembly 1, operably attaching the piezoelectric transducer assembly 1 to the exhaust of the particular pump being tested, and running a test in which the pump activity as indicated by the exhaust gas versus the action of the transducer is charted. This embodiment is used when it is not necessary to have protection for thepiezoelectric transducer 10, but it is desired to use medium to high exhaust gas pressures. - In yet another embodiment of this invention, FIG. 8 shows a cross sectional full side view of the insertable
transducer retainer assembly 2 of FIG. 2, in which there is additionally shown thepiezoelectric transducer 10 in place in thefirst opening 13 and resting on theshelf 14, thepiezoelectric transducer 10 being surmounted by astiffener disk 33, and then aprotective cover 32 covering thestiffener disk 33. This embodiment is desired when the application requires that medium to high exhaust gas pressures are being used, and the environment requires that thepiezoelectric transducer 10 be protected. - FIG. 9 shows the embodiment of FIG. 8, except there is shown multiple layers of
stiffener disks 33, the reason being that these are used in exhaust gas high pressure applications. The configuration shown in FIG. 9 also shows aprotective covering 32, which would be necessary in an environment where the exhaust gas pressures are high and thepiezoelectric transducer 10 needs to be protected. - For some medium to high pressure applications, the
piezoelectric transducer 10 may need support other than that provided by resting on theshelf 14 and in FIG. 10, there is shown a cross sectional full side view of the insertabletransducer retainer assembly 2 of FIG. 2 in which there is shown acompressible material 34 located in thesecond opening 16. Thiscompressible material 34 is capable of compressing to the extent that thepiezoelectric transducer 10 deflects into theopening 16, but does not compress to the extent that thepiezoelectric transducer 10 bursts from its position or is pushed from theshelf 14 and into theopening 16. The compressible material allows for a rebound or flex from sustained high pressure applications up to about 100 psi. Typically, this material is an elastomeric or gelled silicone polymer but can be selected from other polymers such as fluoropolymers, urethanes, epoxies, acrylics, polyvinyl alcohols, and polyvinyl acetates, just to name a few. This manner of supporting thepiezoelectric transducer 10 prevents destruction of thepiezoelectric transducer 10 and helps prevent the piezoelectric transducer assembly 1 from malfunctioning. - Turning to still another embodiment of this invention, which is shown in FIG. 11, there is shown an exploded cross sectional full side view of the piezoelectric transducer assembly1 of FIG. 1, which has been modified to include an
electronic configuration 15 in theopening 16. As shown, theelectronic configuration 15 has leads 37 that are attached to a control unit (not shown) for the application in which the piezoelectric transducer assembly 1 is being used. Theelectronic configuration 15 can be placed anywhere in theopening 16, for example, resting on the bottom 17 of the insertabletransducer retainer assembly 2, or it could be suspended by thecompressible material 34, as shown in FIG. 12 - For purposes of this invention, the term “compressible” means any elastomeric, gelled, or similar material that will allow the
piezoelectric transducer 10 to move into it in direct response to the pulses from the exhaust gas of the gas pump, while preventing thepiezoelectric transducer 10 from permanently bending, or bursting, or leaving the support provided by theshelf 14. Thecompressible material 34 is typically used when the gas pressure on the pump exceeds about 20 psi and up to about 100 psi. Gas pressures below about 20 psi do not normally require the use of thecompressible material 34. - There is yet another embodiment of this invention which is shown in FIG. 13A in which an
adhesive tape 45 surmounts thepiezoelectric transducer 10. One purpose for the use of theadhesive tape 45 is to hold thepiezoelectric transducer 10 solidly on theshelf 14 and to help diffuse the pulse of the exhaust gas evenly over thepiezoelectric transducer 10. For purposes of this invention, the type ofadhesive tape 45 is not overly critical, and anyadhesive tape 5 that fixes thepiezoelectric transducer 10 in place and effectively distributes the effect of the pulse from the exhaust gas evenly over thepiezoelectric transducer 10 can be used. One such adhesive tape is Teflon tape of about 3 to 8 mil thickness, with an acrylic adhesive on the back. It should be noted that best results are achieved by making sure that theadhesive tape 45 uniformly rests on and is bonded to the top surface of thepiezoelectric transducer 10. As far as the inventor herein can ascertain, any adhesive tape will suffice for this application, as long as it will adhere to the piezoelectric transducer surface and transmit impulses evenly across the piezoelectric transducer surface. If the adhesive tape is not used, the assembly will still tolerate a small gap between the top surface of thepiezoelectric transducer 10, and whatever may be the material surmounting thepiezoelectric transducer 10. - In the event that in certain applications, protection is needed for the
piezoelectric transducer 10, then one can surmount theadhesive tape 45 with astiffener disk 33 manufactured from Teflon, or the like, as is shown in FIG. 13B. - The housing parts of the piezoelectric transducer assembly, along with any connectors, and the like, are constructed from any solid material that has sufficient strength to support the internal components. Such materials should be selected on the basis of the end use application that the piezoelectric transducer assembly and the associated pump will be used for, along with the cost of such materials, their handleability, durability, processability and machineability. Such materials can be, for example, polyethylene, polypropylene, polyfluorinated polymers selected from polytetrafluoroethylene, fluorinated ethylenepropylene, perfluoroalkoxys, polychlorotrifluoroethylene, ethylene tetrafluoroethylene and polyvinylidene fluoride, silicone polymers, nylon, synthetic resins, metals selected from aluminum, copper, and alloys of aluminum and copper.
- Turning now to another embodiment of this invention, there is a method of monitoring a gas pump, the method comprising two steps, the first step of providing a gas pump that has a piezoelectric transducer assembly operably attached to the exhaust outlet of a gas pump such that the exhaust pulses of the gas pump impact directly or indirectly, the piezoelectric transducer of the piezoelectric transducer assembly and step two, measuring the time elapsed between the exhaust strokes such that the number of strokes per unit of time can be determined. In an analogous method, there is a third step, which is the adjustment of the pump input gas flow to bring the pump into normal working order, based on the measurement of time that has elapsed between the exhaust strokes.
- The inventor herein has found one example of connecting a piezoelectric transducer to the exhaust of a pump. However, the pump is not a gas pump, and the transducer assembly1 of the instant invention was not used therein. The prior art device, as disclosed in U.S. Pat. No. 5,655,357, that issued Aug. 12, 1997, uses a signal to display the progress of a vacuum process and/or shut down the vacuum pump upon establishing a substantial vacuum within the package being evacuated. The transducer assembly 1 of the instant invention detects gas pulses to establish a digital output to a personal computer, for example. The output from the instant transducer assembly 1 is time specific, not pressure specific, as in the prior art device. In addition, by taking the time measurements, i.e., measuring the time elapsed between the exhaust strokes, the number of strokes per unit of time can be determined, and in this manner, it can be determined if the pump is malfunctioning, and if malfunctioning, it can be adjusted, or shut down to prevent damage to the manufacturing or other applications in which it is being used. In general, if the timing between exhaust strokes increases, flow decreases, which might be due to a plugged filter, or changes in gas pressure being fed to the gas pump, or the like. Likewise, if the timing between exhaust strokes decreases, this indicates an increase in flow and problems with pump transducers or line pressure changes to the pump, or the like. By monitoring the number of strokes per unit of time, one can gauge the flow rate of the pump and thereby control the pump.
- Turning now to FIG. 17, there is shown a schematic of a
gas pump 38, which has attached directly to thegas exhaust 39 of the pump, the piezoelectric transducer assembly 1 of this invention configured as agas diffuser 40. Thegas diffuser 40 can be observed from FIG. 15, wherein there is shown a full side view of the piezoelectric transducer assembly 1 of this invention in a configuration of thegas diffuser 40, showing theexhaust ports 41 for the exhaust gas from thegas pump 38. - FIG. 16 shows a cross sectional full side view of the piezoelectric transducer
assembly gas diffuser 40 of FIG. 15 through line C-C in which the construction of theexhaust ports 41 in the interior is shown. The placement of theexhaust ports 41 is not critical, as long as the exhaust from thegas pump 38 is allowed to enter the saucer-shapeddepression 30, diffuse and impinge on thepiezoelectric transducer 10, either directly, or indirectly throughstiffener disks 33 and/orprotective coverings 32, and/oradhesive tapes 45, and then allowed to exit the receivingtransducer retainer assembly 11 without exhausting through the insertabletransducer retainer assembly 2. In this manner, thegas diffuser 40 can exhaust the exhaust gas, while maintaining the integrity of thepiezoelectric transducer 10. This manner of exhausting the gas from thegas pump 38 does not severely impact the operation of the piezoelectric transducer assembly 1. FIG. 17 also shows agas inlet 42 to thepump 38. - The piezoelectric transducer assemblies1 of this invention can also be hooked operably to the pump indirectly, such as is shown in FIG. 18, wherein there is shown the
pump 38, in schematic, thegas inlet port 42, the pumpgas exhaust line 39, and agas diffuser 43 for the pumpgas exhaust line 39. There is also shown the placement of apiezoelectric transducer assembly 11, without the capability of exhausting gas pump exhaust through it, which is attached to the pumpgas exhaust line 39. - The indirect configuration shown in FIG. 18 is useful when it is desired to dislocate the piezoelectric transducer assembly1 from the direct hook up with the
pump 38. In this manner,gas line 44, leading from the pump gas exhaust line to thepiezoelectric transducer assembly 11 can be a long line, and thus thepiezoelectric transducer 10 can be dislocated a long distance from thepump 38 and the operations of the manufacturing to which thepump 38 is an accessory.
Claims (52)
Priority Applications (21)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/870,189 US6484589B1 (en) | 2001-05-30 | 2001-05-30 | Piezoelectric transducer assemblies and methods for their use |
CZ20033483A CZ20033483A3 (en) | 2001-05-30 | 2002-03-21 | Piezoelectric transducer assembly, method of monitoring a gas driven pump, combination of the gas driven pump and the piezoelectric transducer assembly, a system for monitoring the gas driven pump and production operations |
CNB02810837XA CN1311225C (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
DE60234035T DE60234035D1 (en) | 2001-05-30 | 2002-03-21 | NOVEL PIEZOELECTRIC CONVERTER MODULES AND METHOD FOR THEIR USE |
PL02373674A PL373674A1 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
AU2002254313A AU2002254313B2 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
PCT/US2002/008686 WO2002099852A2 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
IL15881602A IL158816A0 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
BR0209730-3A BR0209730A (en) | 2001-05-30 | 2002-03-21 | Piezoelectric transducer assemblies and processes for their use |
JP2003502867A JP4309249B2 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assembly and method of use thereof |
MXPA03010819A MXPA03010819A (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use. |
AT02723541T ATE445913T1 (en) | 2001-05-30 | 2002-03-21 | NOVEL PIEZOELECTRIC TRANSDUCER ASSEMBLY AND METHOD FOR USE THEREOF |
CA002446718A CA2446718A1 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
HU0400201A HUP0400201A2 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
EP02723541A EP1417461B1 (en) | 2001-05-30 | 2002-03-21 | Novel piezoelectric transducer assemblies and methods for their use |
KR1020037015648A KR100835025B1 (en) | 2001-05-30 | 2002-03-21 | Piezoelectric transducer assembly, combination of piezoelectric transducer assembly and gas pump, gas pump monitoring method, gas pump monitoring system and manufacturing process using the same |
TW091107155A TW513565B (en) | 2001-05-30 | 2002-04-10 | Novel piezoelectric transducer assemblies and methods for their use |
US10/163,705 US6823742B2 (en) | 2001-05-30 | 2002-06-06 | Piezoelectric transducer assemblies and methods for their use |
IL158816A IL158816A (en) | 2001-05-30 | 2003-11-11 | Piezoelectric transducer assemblies and methods for their use |
YU93803A YU93803A (en) | 2001-05-30 | 2003-11-26 | Novel piezoelectric transducer assemblies and methods for their use |
JP2007284140A JP2008075659A (en) | 2001-05-30 | 2007-10-31 | Novel piezoelectric transducer assembly and method for use thereof |
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US09/870,189 US6484589B1 (en) | 2001-05-30 | 2001-05-30 | Piezoelectric transducer assemblies and methods for their use |
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US10/163,705 Division US6823742B2 (en) | 2001-05-30 | 2002-06-06 | Piezoelectric transducer assemblies and methods for their use |
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US6484589B1 US6484589B1 (en) | 2002-11-26 |
US20020180309A1 true US20020180309A1 (en) | 2002-12-05 |
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US09/870,189 Expired - Lifetime US6484589B1 (en) | 2001-05-30 | 2001-05-30 | Piezoelectric transducer assemblies and methods for their use |
US10/163,705 Expired - Fee Related US6823742B2 (en) | 2001-05-30 | 2002-06-06 | Piezoelectric transducer assemblies and methods for their use |
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US10/163,705 Expired - Fee Related US6823742B2 (en) | 2001-05-30 | 2002-06-06 | Piezoelectric transducer assemblies and methods for their use |
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US (2) | US6484589B1 (en) |
EP (1) | EP1417461B1 (en) |
JP (2) | JP4309249B2 (en) |
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CN (1) | CN1311225C (en) |
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TW (1) | TW513565B (en) |
WO (1) | WO2002099852A2 (en) |
YU (1) | YU93803A (en) |
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2002
- 2002-03-21 AU AU2002254313A patent/AU2002254313B2/en not_active Ceased
- 2002-03-21 DE DE60234035T patent/DE60234035D1/en not_active Expired - Lifetime
- 2002-03-21 AT AT02723541T patent/ATE445913T1/en not_active IP Right Cessation
- 2002-03-21 CA CA002446718A patent/CA2446718A1/en not_active Abandoned
- 2002-03-21 PL PL02373674A patent/PL373674A1/en unknown
- 2002-03-21 MX MXPA03010819A patent/MXPA03010819A/en active IP Right Grant
- 2002-03-21 JP JP2003502867A patent/JP4309249B2/en not_active Expired - Fee Related
- 2002-03-21 CN CNB02810837XA patent/CN1311225C/en not_active Expired - Fee Related
- 2002-03-21 EP EP02723541A patent/EP1417461B1/en not_active Expired - Lifetime
- 2002-03-21 BR BR0209730-3A patent/BR0209730A/en not_active IP Right Cessation
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- 2002-03-21 WO PCT/US2002/008686 patent/WO2002099852A2/en active Search and Examination
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- 2002-03-21 CZ CZ20033483A patent/CZ20033483A3/en unknown
- 2002-03-21 HU HU0400201A patent/HUP0400201A2/en unknown
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- 2002-06-06 US US10/163,705 patent/US6823742B2/en not_active Expired - Fee Related
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2003
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- 2003-11-26 YU YU93803A patent/YU93803A/en unknown
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2007
- 2007-10-31 JP JP2007284140A patent/JP2008075659A/en active Pending
Cited By (1)
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US20050081638A1 (en) * | 2003-09-05 | 2005-04-21 | Couch Philip R. | Sensing diaphragm for a differential pressure sensor with over-pressure protection and methods |
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JP2008075659A (en) | 2008-04-03 |
YU93803A (en) | 2006-08-17 |
IL158816A (en) | 2008-11-26 |
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AU2002254313B2 (en) | 2006-11-30 |
CN1311225C (en) | 2007-04-18 |
US6823742B2 (en) | 2004-11-30 |
CN1633585A (en) | 2005-06-29 |
HUP0400201A2 (en) | 2006-03-28 |
PL373674A1 (en) | 2005-09-05 |
US20020178835A1 (en) | 2002-12-05 |
BR0209730A (en) | 2006-02-07 |
CA2446718A1 (en) | 2002-12-12 |
EP1417461A2 (en) | 2004-05-12 |
JP2005514584A (en) | 2005-05-19 |
KR100835025B1 (en) | 2008-06-03 |
JP4309249B2 (en) | 2009-08-05 |
WO2002099852A2 (en) | 2002-12-12 |
WO2002099852A3 (en) | 2004-02-19 |
ATE445913T1 (en) | 2009-10-15 |
KR20040004674A (en) | 2004-01-13 |
CZ20033483A3 (en) | 2004-05-12 |
EP1417461B1 (en) | 2009-10-14 |
US6484589B1 (en) | 2002-11-26 |
MXPA03010819A (en) | 2004-11-22 |
TW513565B (en) | 2002-12-11 |
IL158816A0 (en) | 2004-05-12 |
EP1417461A4 (en) | 2007-05-16 |
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