US20020160592A1 - Method for forming ultra-shallow junctions using laser annealing - Google Patents
Method for forming ultra-shallow junctions using laser annealing Download PDFInfo
- Publication number
- US20020160592A1 US20020160592A1 US10/016,534 US1653401A US2002160592A1 US 20020160592 A1 US20020160592 A1 US 20020160592A1 US 1653401 A US1653401 A US 1653401A US 2002160592 A1 US2002160592 A1 US 2002160592A1
- Authority
- US
- United States
- Prior art keywords
- layer
- forming
- gate
- laser annealing
- silicon substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 84
- 238000005224 laser annealing Methods 0.000 title claims abstract description 64
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 76
- 239000010703 silicon Substances 0.000 claims abstract description 76
- 239000000758 substrate Substances 0.000 claims abstract description 75
- 125000006850 spacer group Chemical group 0.000 claims abstract description 48
- 229910003481 amorphous carbon Inorganic materials 0.000 claims abstract description 38
- 239000006096 absorbing agent Substances 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000012535 impurity Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 19
- 229920005591 polysilicon Polymers 0.000 claims abstract description 19
- 238000000151 deposition Methods 0.000 claims abstract description 15
- 238000002955 isolation Methods 0.000 claims abstract description 14
- 239000011261 inert gas Substances 0.000 claims abstract 5
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 27
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 26
- 238000005530 etching Methods 0.000 claims description 22
- 230000015572 biosynthetic process Effects 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 13
- 238000009792 diffusion process Methods 0.000 claims description 9
- 238000001020 plasma etching Methods 0.000 claims description 8
- 238000007669 thermal treatment Methods 0.000 claims description 8
- 239000002019 doping agent Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000005468 ion implantation Methods 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 161
- 150000002500 ions Chemical class 0.000 description 9
- 239000010408 film Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000000206 photolithography Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/0223—Manufacture or treatment of FETs having insulated gates [IGFET] having source and drain regions or source and drain extensions self-aligned to sides of the gate
- H10D30/0227—Manufacture or treatment of FETs having insulated gates [IGFET] having source and drain regions or source and drain extensions self-aligned to sides of the gate having both lightly-doped source and drain extensions and source and drain regions self-aligned to the sides of the gate, e.g. lightly-doped drain [LDD] MOSFET or double-diffused drain [DDD] MOSFET
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/268—Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/021—Manufacture or treatment using multiple gate spacer layers, e.g. bilayered sidewall spacers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/661—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation
- H10D64/662—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation the conductor further comprising additional layers, e.g. multiple silicon layers having different crystal structures
Definitions
- the present invention relates generally to a method for fabricating semiconductor devices and, more particularly, to a method for forming ultra-shallow junctions using laser annealing with an amorphous carbon layer as an energy absorber layer.
- SDE Source/drain extension
- RTP rapid thermal process
- the above-described method is advantageous in forming a transistor having gate lengths of more than 130 nm. However, it has several drawbacks when applied to high performance transistors having gate lengths of less than 100 nm.
- FIG. 1 is a graph plotting sheet resistance versus junction depth in each method for forming ultra-shallow junctions, where reference code A indicates sheet resistance according to junction depths in which RTP is performed to activate doped impurities and reference code B indicates those in which laser annealing is performed. Reference code C indicates scaling rule requirements of junction depth and sheet resistance.
- a fabrication method for making 70 nm MOSFET using laser annealing will be described with reference to FIGS. 2A to 2 C. (IEDM 1999, “70 nm MOSFET with Ultra-Shallow, Abrupt, and Super-Doped S/D Extension Implemented by Laser Thermal Process”).
- a gate 23 having a gate oxide film 22 is formed on an active region of silicon substrate 20 defined by a trench type isolation layer 21 through well-known processes. Then, a first spacer 24 , made of silicon nitride layer (Si 3 N 4 ), is formed on the sidewalls of the gate 23 . An ion implantation process and a rapid thermal process are sequentially performed to form source/drain regions 25 a and 25 b on the silicon substrate 20 at both sides of gate 23 , including the first spacer 24 .
- the first spacer 24 is removed and ions are implanted on the resulting structure to form a SDE doping layer. Then, laser annealing is performed to selectively melt and solidify the amorphous surfaces of source/drain regions 25 a and 25 b , thereby forming a SDE doping layer 26 , activated in high concentration on silicon substrate 20 at both sides of gate 23 .
- a second spacer 27 is formed on sidewalls of gate 23 by oxide film deposition and blanket etching and then a metal layer, for example, a cobalt layer is deposited to a predetermined thickness on the resulting structure. Then, annealing is performed so that cobalt of the cobalt layer may respond to substrate silicon, thereby forming a cobalt silicide layer 28 on the surface of source/drain regions 25 a and 25 b and on the upper surface of the gate 23 .
- a metal layer for example, a cobalt layer is deposited to a predetermined thickness on the resulting structure.
- annealing is performed so that cobalt of the cobalt layer may respond to substrate silicon, thereby forming a cobalt silicide layer 28 on the surface of source/drain regions 25 a and 25 b and on the upper surface of the gate 23 .
- Ken-ichi Goto proposed a method that the activated dopant concentration of a contact formation region can be maintained at greater than 10 21 /cm 3 by using laser annealing after implanting the source/drain ions to improve contact resistance.
- the ultra-low resistance contact formation method by laser annealing will be described with reference to FIGS. 3A to 3 C. (IEDM 1999, “Ultra-Low Contact Resistance for Deca-nm MOSFETs by Laser Annealing”).
- a gate 33 having a gate oxide film 32 is formed on an active region of silicon substrate 30 defined by isolation layer 31 . And, ions are implanted to form source/drain extension doping layer and rapid thermal treatment is performed thereby, forming a SDE doping layer 34 electrically activated on the surface of substrate 30 at both sides of the gate 33 .
- a spacer 35 is formed on sidewalls of gate 33 and ions are implanted, thereby forming inactivated doping layer 36 to form source/drain regions on a silicon substrate 30 at both sides of gate including the spacer 35 .
- source/drain regions 36 a and 36 b are formed using laser annealing and, at the same time, the surface of the source/drain regions 36 a and 36 b and the upper surface of gate 33 are transformed into an activated doping layer 37 in a high concentration.
- reference numeral 40 indicates a silicon substrate
- reference numeral 41 is a isolation layer
- reference numeral 42 a is a gate insulating layer
- reference numeral 42 b is a silicon gate
- reference numeral 42 c is a diffusion preventing layer
- reference numeral 43 a is a source region
- reference numeral 43 b is a drain region
- reference numeral 44 is a SDE doping layer.
- a method has been developed that includes a step prior to laser annealing, in that a metal laser absorber layer, for example, a refractory metal thin film such as a Ti/TiN layer, is deposited on the surface of the substrate, thereby preventing an excessive rise in temperature of the metal gate.
- a metal laser absorber layer for example, a refractory metal thin film such as a Ti/TiN layer
- the melting point of Ti is 1,667° C., very similar to that of Si, 1,412° C. Therefore, the Ti components remain in the oxide film after the Ti/TiN layer is removed.
- an object of the present invention is to provide a method for forming an ultra-shallow junction capable of preventing transformation of a metal gate using laser annealing.
- Another object of the present invention is to provide a method for forming an ultra-shallow junction using laser annealing to be applied to fabrication of a high performance device without transformation of the gate.
- an embodiment of the present invention comprises the steps of: preparing a silicon substrate having isolation layers thereon; forming a gate which has a stacked structure of a gate insulating layer, a polysilicon layer and a metal layer on the silicon substrate; forming a sacrificial spacer on sidewalls of the gate; forming source/drain regions on the silicon substrate region at both sides of the gate including over the sacrificial spacer; removing the sacrificial spacer; doping impurities to form a source/drain extension doping layer on the silicon substrate at both sides of the gate; depositing a reaction preventing layer and an amorphous carbon layer as a laser absorber layer on the resulting structure; forming source/drain extension doping layers on inner sides of the source/drain regions by laser annealing; and removing the amorphous carbon layer.
- Another embodiment of the present invention comprises the steps of: preparing a silicon substrate having trench type isolation layers to define an active region; forming a gate having a stacked structure of a gate insulating layer, a polysilicon layer, a diffusion preventing layer, a metal layer and a hard mask layer on an active region of the silicon substrate; forming a thin oxide layer on the surface of the silicon substrate and the side of the polysilicon layer by performing oxidation processes; depositing a thin silicon nitride layer as an etching preventing layer on the resulting structure; forming a sacrificial spacer on the sidewalls of the gate on which the silicon nitride layer is deposited; forming source/drain regions on the silicon substrate region at both sides of gate including the sacrificial spacer; removing the sacrificial spacer, the silicon nitride layer and the oxide layer formed on the surface of the silicon substrate; doping impurities in low energy to form source/drain extension doping layers on the silicon substrate
- Still another embodiment of the present invention comprises the steps of: preparing a silicon substrate having isolation layers thereon; forming a gate having a stacked structure of a gate insulating layer, a polysilicon layer and a metal layer on the silicon substrate; forming source/drain extension doping layers on silicon substrates at both sides of the gate; forming a spacer on the sidewalls of the gate; doping impurities on the silicon substrate at both sides of the gate including the spacer to form source/drain regions; depositing a reaction preventing layer and an amorphous carbon layer as an energy absorber layer on the resulting structure; forming source and drain regions on the silicon substrate regions at both sides of gate including the spacer by using laser annealing; and removing the amorphous carbon layer.
- Still another embodiment of the present invention comprises the steps of: preparing a silicon substrate having trench type isolation layers thereon to define an active region; forming a gate having a stacked structure of a gate insulating layer, a polysilicon layer, a diffusion preventing layer, a metal layer and a hard mask layer; forming source/drain extension doping layers by doping impurities and rapid thermal treatment on the silicon substrate region at both sides of the gate; depositing a thin silicon nitride layer as an etching preventing layer on the resulting structure; forming a spacer on sidewalls of the gate having the silicon nitride layer thereon; doping impurities to form source and drain regions on the silicon substrate at both sides of gate including the spacer; depositing a silicon oxide layer as a reaction preventing layer and an amorphous carbon layer as an energy absorber layer on the resulting structure; forming source and drain regions on the silicon substrate at both sides of the gate including the spacer using laser annealing; and removing the a
- FIG. 1 is a graph for showing sheet resistance according to junction depth in each method for forming an ultra-shallow junction.
- FIGS. 2A to 2 C are cross-sectional views for showing a conventional method for forming an ultra-shallow junction.
- FIGS. 3A to 3 C are cross-sectional views for showing another conventional method for forming an ultra-shallow junction.
- FIG. 4 is a cross-sectional view for showing problems of conventional method for forming an ultra-shallow junction.
- FIGS. 5A to 5 E are cross-sectional views for showing a method for forming an ultra-shallow junction according to an embodiment of the present invention.
- FIGS. 6A to 6 E are cross-sectional views for showing a method for forming ultra-shallow junction according to another embodiment of the present invention.
- FIGS. 5A to 5 E are cross-sectional views for showing a method for forming an ultra-shallow junction using laser annealing according to an embodiment of the present invention.
- a trench type isolation layer 51 is formed on a silicon substrate 50 to define a field region and an active region, and an N-well and a P-well (not shown) are formed by well-known processes.
- a gate insulating layer 52 a , a polysilicon layer 52 b , a diffusion preventing layer 52 c , a gate metal layer 52 d and a hard mask layer 52 e are sequentially formed on the silicon substrate 50 .
- the layers are patterned through well-known photolithography processes, thereby forming a gate 52 having a stacked structure of the polysilicon layer 52 b , the diffusion preventing layer 52 c and the metal layer 52 d on the active region of the silicon substrate 50 .
- oxide layers 53 are formed on the surface of silicon substrate 50 and on the side of polysilicon layer 52 a .
- a thin silicon nitride layer 54 is deposited on the resulting structure to be used as an etching preventing layer in the succeeding process for removing spacer.
- an oxide layer is deposited on the silicon nitride layer 54 and the oxide layer is subjected to an anisotropy etching process, thereby forming a spacer 55 on the sidewalls of gate 52 having the silicon nitride layer 54 thereon. Then, N type or P type impurity ions are implanted or doped by plasma doping on silicon substrate 50 at both sides of gate 52 including the spacer 55 and rapid thermal treatment is performed to form source and drain regions 56 a and 56 b.
- the spacer is removed by selective etching process using HF solution and the silicon nitride layer 54 as an etching preventing layer. Then, the silicon nitride layer 54 and oxide layer 53 formed on the silicon substrate 50 are removed by an anisotropy etching process. Subsequently, N type or P type impurity ions are implanted in low energy or doped by plasma doping to form SDE doping layers on the silicon substrate 50 at both sides of gate 52 .
- reference code 57 indicates an inactivated doping layer.
- a reaction preventing layer 58 made of a silicon oxide layer is deposited on the resulting structure.
- An amorphous carbon layer 59 (Graphite) is deposited to a thickness of 200 to 400 ⁇ as a laser absorber layer on the reaction preventing layer 58 .
- laser annealing is performed in an atmosphere of inactive gas and under vacuum, thereby the inactivated doping layer is activated in a high concentration.
- SDE doping layer 57 a is formed on inner sides of source and drain regions 56 a and 56 b .
- Arrows D indicates a path by which energy absorbed in the amorphous carbon 59 is transferred to the lower structure and to the silicon substrate 50 .
- the amorphous carbon layer 59 absorbs laser energy and the absorbed energy is transferred to the lower structure, thereby activating dopants. Therefore, the metal layer 52 d is not transformed at the gate 52 .
- the amorphous carbon layer used as a laser absorber layer is removed by an O 2 plasma etching process.
- a MOSFET device having an ultra-shallow junction is obtained with a gate length of less than 100 nm.
- the amorphous carbon layer is desirable for a laser absorber layer because it has a very high melting point, approximately 3,800° C. and in laser annealing, has a diffusion length of 0.02 ⁇ in silicon.
- the laser absorber layer should meet several requirements. First, it should have a high laser absorption rate. Second, the melting point and the sublimation point thereof should be higher than the maximum temperature in laser annealing, for example, 1,300° C. Third, it should have no reaction with a reaction preventing layer, that is, the silicon oxide layer during laser annealing and it should be prevented from diffusing into the silicon oxide layer. Finally, when it is removed, it should have a high selective ratio to a lower structure and be capable of easy removal.
- the amorphous carbon layer is desirable for a laser absorber layer in that it has a high laser absorption rate and a high melting point, approximately 3,800° C. Moreover, it has minimal reaction with the silicon oxide layer during short duration laser annealing of several nanoseconds (ns) and can be easily removed by O 2 plasma etching.
- the temperature of the amorphous carbon layer is about 1,200° C. for several ns and then is decreased to a lower temperature below 200° C. for 300 ns, resulting in minimal reaction between the carbon and the oxygen.
- the surface of the silicon oxide layer can be nitrified.
- FIGS. 6A to 6 E are cross-sectional views for showing a method for forming an ultra-shallow junction using laser annealing according to another embodiment of the present invention.
- a trench type isolation layer 61 is formed on a silicon substrate 60 to define a field region and an active region, and an N-well and a P-well (not shown) are formed through well-known processes.
- a gate insulating layer 62 a , a polysilicon layer 62 b , a diffusion preventing layer 62 c , a metal layer for gate 62 d and a hard mask layer 62 e are sequentially formed on the silicon substrate 60 .
- the layers are patterned by well-known photolithography processes, thereby forming a gate 62 having a stacked structure on the active region of the silicon substrate 60 .
- a selective oxidation process is performed to recover etching damage generated in forming the gate 62 , therefore an oxide film 63 is formed on the surface of silicon substrate 60 and on the side of polysilicon layer 62 a.
- N type or P type impurity ions are implanted or doped by plasma doping, and then a rapid thermal treatment is performed to form SDE doping layers 64 on the surface of the silicon substrate 60 at both sides of the gate 62 .
- a silicon nitride layer 65 is deposited at a thin thickness as an etching preventing layer on the resulting structure and a spacer 66 is formed by oxide layer deposition and anisotropy etching on sidewall of gate 62 having the silicon nitride layer 65 thereon.
- the silicon nitride layer 65 deposited on the silicon substrate 60 and the gate 62 are removed.
- N type or P type impurity ions are implanted or doped by plasma doping in order to form source and drain regions on the silicon substrate 60 at both sides of gate 62 including the spacer 66 .
- Reference numeral 67 indicates an inactivated doping layer.
- a reaction preventing layer 68 made of a silicon oxide layer is deposited on the resulting structure and an amorphous carbon layer 69 is deposited as a laser absorber layer on the reaction preventing layer 68 .
- source/drain regions 67 a and 67 b activated in a high concentration are formed on silicon substrate 60 at both sides of gate 62 including the spacer 66 by performing laser annealing in an atmosphere of inactive gas and under vacuum.
- the amorphous carbon layer used as a laser absorber layer is removed by O 2 plasma etching.
- an amorphous carbon layer is used as a laser absorber layer, thereby preventing transformation of the metal layer of the gate during laser annealing. Additionally, the problem of remaining metal ions has been solved, and as a result, it is possible to fabricate a high performance device.
- yield has increased since a laser absorber layer is easily removed by O 2 plasma etching.
- the present invention can be advantageously applied to the fabrication of high performance devices.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Electromagnetism (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
- 1. Field of the Invention
- The present invention relates generally to a method for fabricating semiconductor devices and, more particularly, to a method for forming ultra-shallow junctions using laser annealing with an amorphous carbon layer as an energy absorber layer.
- 2. Description of the Background Art
- As a design rule for high performance semiconductor device is reduced, recent research and development efforts are focused on formation of ultra-shallow junction. Therefore, research and development are being in progress.
- For example, in semiconductor devices having a gate length of less than 250 nm, that is, in MIS (Metal-Insulator-Semiconductor) transistors, source/drain extension (hereinafter, referred to as SDE) doping layers having ultra-shallow junctions are formed on inner sides of source/drain regions. In a conventional method, this SDE layer is formed by implanting impurity ions and performing a rapid thermal process (hereinafter referred to as RTP) and thereby, activating dopants in the SDE doping layer and source/drain regions.
- The above-described method is advantageous in forming a transistor having gate lengths of more than 130 nm. However, it has several drawbacks when applied to high performance transistors having gate lengths of less than 100 nm.
- First, when the high performance transistor is formed, it is required to maintain a junction depth of the SDE doping layer less than 35 nm. However, when junction depth of the SDE doping layer is less than 35 nm, a desired doping degree of the SDE doping layer is not maintained due to the solid solubility limit, thereby causing abrupt increase of sheet resistance. As a result, it is difficult to obtain a high performance transistor.
- Therefore, laser thermal processes have been developed to solve the above problems.
- FIG. 1 is a graph plotting sheet resistance versus junction depth in each method for forming ultra-shallow junctions, where reference code A indicates sheet resistance according to junction depths in which RTP is performed to activate doped impurities and reference code B indicates those in which laser annealing is performed. Reference code C indicates scaling rule requirements of junction depth and sheet resistance.
- As shown in FIG. 1, when RTP is performed to activate impurities (A), scaling rule requirements of junction depth and sheet resistance are not fulfilled. However, when laser annealing is performed (B), they are fulfilled.
- A fabrication method for making 70 nm MOSFET using laser annealing, as proposed by Bin Yu et al., will be described with reference to FIGS. 2A to2C. (IEDM 1999, “70 nm MOSFET with Ultra-Shallow, Abrupt, and Super-Doped S/D Extension Implemented by Laser Thermal Process”).
- Referring to FIG. 2A, a
gate 23 having agate oxide film 22 is formed on an active region ofsilicon substrate 20 defined by a trenchtype isolation layer 21 through well-known processes. Then, afirst spacer 24, made of silicon nitride layer (Si3N4), is formed on the sidewalls of thegate 23. An ion implantation process and a rapid thermal process are sequentially performed to form source/drain regions silicon substrate 20 at both sides ofgate 23, including thefirst spacer 24. - Referring to FIG. 2B, the
first spacer 24 is removed and ions are implanted on the resulting structure to form a SDE doping layer. Then, laser annealing is performed to selectively melt and solidify the amorphous surfaces of source/drain regions SDE doping layer 26, activated in high concentration onsilicon substrate 20 at both sides ofgate 23. - Referring to FIG. 2C, a
second spacer 27 is formed on sidewalls ofgate 23 by oxide film deposition and blanket etching and then a metal layer, for example, a cobalt layer is deposited to a predetermined thickness on the resulting structure. Then, annealing is performed so that cobalt of the cobalt layer may respond to substrate silicon, thereby forming acobalt silicide layer 28 on the surface of source/drain regions gate 23. - Ken-ichi Goto proposed a method that the activated dopant concentration of a contact formation region can be maintained at greater than 1021/cm3 by using laser annealing after implanting the source/drain ions to improve contact resistance. The ultra-low resistance contact formation method by laser annealing will be described with reference to FIGS. 3A to 3C. (IEDM 1999, “Ultra-Low Contact Resistance for Deca-nm MOSFETs by Laser Annealing”).
- Referring to FIG. 3A, a
gate 33 having agate oxide film 32 is formed on an active region ofsilicon substrate 30 defined byisolation layer 31. And, ions are implanted to form source/drain extension doping layer and rapid thermal treatment is performed thereby, forming aSDE doping layer 34 electrically activated on the surface ofsubstrate 30 at both sides of thegate 33. - Referring to FIG. 3B, a
spacer 35 is formed on sidewalls ofgate 33 and ions are implanted, thereby forming inactivateddoping layer 36 to form source/drain regions on asilicon substrate 30 at both sides of gate including thespacer 35. - Referring to FIG. 3C, in order to obtain ultra-low resistance contact, source/
drain regions drain regions gate 33 are transformed into an activateddoping layer 37 in a high concentration. - Thereafter, a rapid thermal treatment at a low temperature of 800° C. and interconnection process are performed to complete the formation of the transistor.
- The above-mentioned method using laser annealing is advantageous to fabrication of a transistor having a silicon gate. However, as shown in FIG. 4, it is difficult to apply to fabrication of a transistor having a
metal gate 42 d on the upper part of agate 42, since themetal gate 42 d is transformed during laser annealing due to the fact that themetal gate 42 d has high laser absorption rate. In FIG. 4,reference numeral 40 indicates a silicon substrate,reference numeral 41 is a isolation layer,reference numeral 42 a is a gate insulating layer,reference numeral 42 b is a silicon gate,reference numeral 42 c is a diffusion preventing layer,reference numeral 43 a is a source region,reference numeral 43 b is a drain region andreference numeral 44 is a SDE doping layer. - In order to solve the above-described problems, a method has been developed that includes a step prior to laser annealing, in that a metal laser absorber layer, for example, a refractory metal thin film such as a Ti/TiN layer, is deposited on the surface of the substrate, thereby preventing an excessive rise in temperature of the metal gate. However, problems exist in that the melting point of Ti is 1,667° C., very similar to that of Si, 1,412° C. Therefore, the Ti components remain in the oxide film after the Ti/TiN layer is removed.
- Therefore, an object of the present invention is to provide a method for forming an ultra-shallow junction capable of preventing transformation of a metal gate using laser annealing.
- Another object of the present invention is to provide a method for forming an ultra-shallow junction using laser annealing to be applied to fabrication of a high performance device without transformation of the gate.
- In order to achieve the above-described objects, an embodiment of the present invention comprises the steps of: preparing a silicon substrate having isolation layers thereon; forming a gate which has a stacked structure of a gate insulating layer, a polysilicon layer and a metal layer on the silicon substrate; forming a sacrificial spacer on sidewalls of the gate; forming source/drain regions on the silicon substrate region at both sides of the gate including over the sacrificial spacer; removing the sacrificial spacer; doping impurities to form a source/drain extension doping layer on the silicon substrate at both sides of the gate; depositing a reaction preventing layer and an amorphous carbon layer as a laser absorber layer on the resulting structure; forming source/drain extension doping layers on inner sides of the source/drain regions by laser annealing; and removing the amorphous carbon layer.
- Another embodiment of the present invention comprises the steps of: preparing a silicon substrate having trench type isolation layers to define an active region; forming a gate having a stacked structure of a gate insulating layer, a polysilicon layer, a diffusion preventing layer, a metal layer and a hard mask layer on an active region of the silicon substrate; forming a thin oxide layer on the surface of the silicon substrate and the side of the polysilicon layer by performing oxidation processes; depositing a thin silicon nitride layer as an etching preventing layer on the resulting structure; forming a sacrificial spacer on the sidewalls of the gate on which the silicon nitride layer is deposited; forming source/drain regions on the silicon substrate region at both sides of gate including the sacrificial spacer; removing the sacrificial spacer, the silicon nitride layer and the oxide layer formed on the surface of the silicon substrate; doping impurities in low energy to form source/drain extension doping layers on the silicon substrate at both sides of the gate; depositing a silicon oxide layer as a reaction preventing layer and an amorphous carbon layer as a laser absorber layer on the resulting structure; forming source/drain extension doping layers on inner sides of the source and drain regions by performing laser annealing; and removing the amorphous carbon layer using an O2 plasma etching process.
- Still another embodiment of the present invention comprises the steps of: preparing a silicon substrate having isolation layers thereon; forming a gate having a stacked structure of a gate insulating layer, a polysilicon layer and a metal layer on the silicon substrate; forming source/drain extension doping layers on silicon substrates at both sides of the gate; forming a spacer on the sidewalls of the gate; doping impurities on the silicon substrate at both sides of the gate including the spacer to form source/drain regions; depositing a reaction preventing layer and an amorphous carbon layer as an energy absorber layer on the resulting structure; forming source and drain regions on the silicon substrate regions at both sides of gate including the spacer by using laser annealing; and removing the amorphous carbon layer.
- Still another embodiment of the present invention comprises the steps of: preparing a silicon substrate having trench type isolation layers thereon to define an active region; forming a gate having a stacked structure of a gate insulating layer, a polysilicon layer, a diffusion preventing layer, a metal layer and a hard mask layer; forming source/drain extension doping layers by doping impurities and rapid thermal treatment on the silicon substrate region at both sides of the gate; depositing a thin silicon nitride layer as an etching preventing layer on the resulting structure; forming a spacer on sidewalls of the gate having the silicon nitride layer thereon; doping impurities to form source and drain regions on the silicon substrate at both sides of gate including the spacer; depositing a silicon oxide layer as a reaction preventing layer and an amorphous carbon layer as an energy absorber layer on the resulting structure; forming source and drain regions on the silicon substrate at both sides of the gate including the spacer using laser annealing; and removing the amorphous carbon layer by using an O2 plasma etching process.
- The objects and features of the invention may be understood with reference to the following detailed description of several illustrative embodiments of the invention, taken together with the illustrations in the accompanying drawings.
- FIG. 1 is a graph for showing sheet resistance according to junction depth in each method for forming an ultra-shallow junction.
- FIGS. 2A to2C are cross-sectional views for showing a conventional method for forming an ultra-shallow junction.
- FIGS. 3A to3C are cross-sectional views for showing another conventional method for forming an ultra-shallow junction.
- FIG. 4 is a cross-sectional view for showing problems of conventional method for forming an ultra-shallow junction.
- FIGS. 5A to5E are cross-sectional views for showing a method for forming an ultra-shallow junction according to an embodiment of the present invention.
- FIGS. 6A to6E are cross-sectional views for showing a method for forming ultra-shallow junction according to another embodiment of the present invention.
- FIGS. 5A to5E are cross-sectional views for showing a method for forming an ultra-shallow junction using laser annealing according to an embodiment of the present invention.
- Referring to FIG. 5A, a trench
type isolation layer 51 is formed on asilicon substrate 50 to define a field region and an active region, and an N-well and a P-well (not shown) are formed by well-known processes. Agate insulating layer 52 a, apolysilicon layer 52 b, adiffusion preventing layer 52 c, agate metal layer 52 d and ahard mask layer 52 e are sequentially formed on thesilicon substrate 50. Then, the layers are patterned through well-known photolithography processes, thereby forming agate 52 having a stacked structure of thepolysilicon layer 52 b, thediffusion preventing layer 52 c and themetal layer 52 d on the active region of thesilicon substrate 50. - Subsequently, selective oxidation processes are performed to recover etching damage generated in forming the
gate 52. As a result, oxide layers 53 are formed on the surface ofsilicon substrate 50 and on the side ofpolysilicon layer 52 a. A thinsilicon nitride layer 54 is deposited on the resulting structure to be used as an etching preventing layer in the succeeding process for removing spacer. - Referring to FIG. 5B, an oxide layer is deposited on the
silicon nitride layer 54 and the oxide layer is subjected to an anisotropy etching process, thereby forming aspacer 55 on the sidewalls ofgate 52 having thesilicon nitride layer 54 thereon. Then, N type or P type impurity ions are implanted or doped by plasma doping onsilicon substrate 50 at both sides ofgate 52 including thespacer 55 and rapid thermal treatment is performed to form source and drainregions - Referring to FIG. 5C, the spacer is removed by selective etching process using HF solution and the
silicon nitride layer 54 as an etching preventing layer. Then, thesilicon nitride layer 54 andoxide layer 53 formed on thesilicon substrate 50 are removed by an anisotropy etching process. Subsequently, N type or P type impurity ions are implanted in low energy or doped by plasma doping to form SDE doping layers on thesilicon substrate 50 at both sides ofgate 52. Here,reference code 57 indicates an inactivated doping layer. - Referring to FIG. 5D, a
reaction preventing layer 58 made of a silicon oxide layer is deposited on the resulting structure. An amorphous carbon layer 59 (Graphite) is deposited to a thickness of 200 to 400 Å as a laser absorber layer on thereaction preventing layer 58. Then, laser annealing is performed in an atmosphere of inactive gas and under vacuum, thereby the inactivated doping layer is activated in a high concentration. As a result,SDE doping layer 57 a is formed on inner sides of source and drainregions amorphous carbon 59 is transferred to the lower structure and to thesilicon substrate 50. During laser annealing, theamorphous carbon layer 59 absorbs laser energy and the absorbed energy is transferred to the lower structure, thereby activating dopants. Therefore, themetal layer 52 d is not transformed at thegate 52. - Referring to FIG. 5E, the amorphous carbon layer used as a laser absorber layer is removed by an O2 plasma etching process.
- Thereafter, by performing well-known processes, for example, a spacer formation process, an interlayer insulating layer formation process, a contact formation process and an interconnection process, a MOSFET device having an ultra-shallow junction is obtained with a gate length of less than 100 nm.
- In the method for forming an ultra-shallow junction using laser annealing according to the present invention, the amorphous carbon layer is desirable for a laser absorber layer because it has a very high melting point, approximately 3,800° C. and in laser annealing, has a diffusion length of 0.02 Å in silicon.
- In short, the laser absorber layer should meet several requirements. First, it should have a high laser absorption rate. Second, the melting point and the sublimation point thereof should be higher than the maximum temperature in laser annealing, for example, 1,300° C. Third, it should have no reaction with a reaction preventing layer, that is, the silicon oxide layer during laser annealing and it should be prevented from diffusing into the silicon oxide layer. Finally, when it is removed, it should have a high selective ratio to a lower structure and be capable of easy removal.
- As a result, the amorphous carbon layer is desirable for a laser absorber layer in that it has a high laser absorption rate and a high melting point, approximately 3,800° C. Moreover, it has minimal reaction with the silicon oxide layer during short duration laser annealing of several nanoseconds (ns) and can be easily removed by O2 plasma etching.
- It is expected that carbon may react with the oxygen in the silicon oxide layer during annealing. However, in laser annealing, the temperature of the amorphous carbon layer is about 1,200° C. for several ns and then is decreased to a lower temperature below 200° C. for 300 ns, resulting in minimal reaction between the carbon and the oxygen. In order to completely prevent a reaction between carbon and oxygen, the surface of the silicon oxide layer can be nitrified.
- FIGS. 6A to6E are cross-sectional views for showing a method for forming an ultra-shallow junction using laser annealing according to another embodiment of the present invention.
- Referring to FIG. 6A, a trench
type isolation layer 61 is formed on asilicon substrate 60 to define a field region and an active region, and an N-well and a P-well (not shown) are formed through well-known processes. Agate insulating layer 62 a, apolysilicon layer 62 b, adiffusion preventing layer 62 c, a metal layer forgate 62 d and ahard mask layer 62 e are sequentially formed on thesilicon substrate 60. Then, the layers are patterned by well-known photolithography processes, thereby forming agate 62 having a stacked structure on the active region of thesilicon substrate 60. Sequentially, a selective oxidation process is performed to recover etching damage generated in forming thegate 62, therefore anoxide film 63 is formed on the surface ofsilicon substrate 60 and on the side ofpolysilicon layer 62 a. - Referring to FIG. 6B, N type or P type impurity ions are implanted or doped by plasma doping, and then a rapid thermal treatment is performed to form SDE doping layers64 on the surface of the
silicon substrate 60 at both sides of thegate 62. - Referring to FIG. 6C, a
silicon nitride layer 65 is deposited at a thin thickness as an etching preventing layer on the resulting structure and aspacer 66 is formed by oxide layer deposition and anisotropy etching on sidewall ofgate 62 having thesilicon nitride layer 65 thereon. Here, thesilicon nitride layer 65 deposited on thesilicon substrate 60 and thegate 62 are removed. Then, N type or P type impurity ions are implanted or doped by plasma doping in order to form source and drain regions on thesilicon substrate 60 at both sides ofgate 62 including thespacer 66.Reference numeral 67 indicates an inactivated doping layer. - Referring to FIG. 6D, a
reaction preventing layer 68 made of a silicon oxide layer is deposited on the resulting structure and anamorphous carbon layer 69 is deposited as a laser absorber layer on thereaction preventing layer 68. Then, source/drain regions silicon substrate 60 at both sides ofgate 62 including thespacer 66 by performing laser annealing in an atmosphere of inactive gas and under vacuum. - Referring to FIG. 6E, the amorphous carbon layer used as a laser absorber layer is removed by O2 plasma etching.
- Thereafter, well-known succeeding processes are performed to form a MOSFET device having an ultra-shallow junction with a gate length of less than 100 nm.
- According to this embodiment, an amorphous carbon layer is used as a laser absorber layer, thereby preventing transformation of the metal layer of the gate during laser annealing. Additionally, the problem of remaining metal ions has been solved, and as a result, it is possible to fabricate a high performance device.
- As described above, according to the present invention, during laser annealing, transformation of the metal gate is prevented since an amorphous carbon layer is used as a laser absorber layer.
- Use of the present inventive method embodiments can solve the problems of remaining metal ions in removing the laser absorber layer since an amorphous carbon layer is used as a laser absorber layer.
- Moreover, according to the present invention, yield has increased since a laser absorber layer is easily removed by O2 plasma etching.
- As a result, the present invention can be advantageously applied to the fabrication of high performance devices.
- The invention may be embodied in other specific forms without departing from the spirit or essential characteristics described and illustrated herein. The present embodiment is therefore to be considered in all respects as illustrative and not restrictive,. Any changes or modifications which come within the meaning and range of the following claims and equivalents thereof are therefore intended to be embraced thereby.
Claims (26)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020010023403A KR100365414B1 (en) | 2001-04-30 | 2001-04-30 | Method for forming ultra-shallow junction using laser annealing process |
KR2001-23403 | 2001-04-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
US20020160592A1 true US20020160592A1 (en) | 2002-10-31 |
US6475888B1 US6475888B1 (en) | 2002-11-05 |
Family
ID=19708905
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/016,534 Expired - Fee Related US6475888B1 (en) | 2001-04-30 | 2001-12-10 | Method for forming ultra-shallow junctions using laser annealing |
Country Status (3)
Country | Link |
---|---|
US (1) | US6475888B1 (en) |
JP (1) | JP4128771B2 (en) |
KR (1) | KR100365414B1 (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050074956A1 (en) * | 2003-10-03 | 2005-04-07 | Applied Materials, Inc. | Absorber layer for DSA processing |
WO2005036627A1 (en) | 2003-10-03 | 2005-04-21 | Applied Materials, Inc. | Absorber layer for dynamic surface annealing processing |
US20060057828A1 (en) * | 2004-09-10 | 2006-03-16 | Mitsuhiro Omura | Method of manufacturing semiconductor device |
EP1753019A1 (en) * | 2004-05-21 | 2007-02-14 | Matsushita Electric Industrial Co., Ltd. | Impurity introducing method and electronic element using it |
EP1780776A1 (en) * | 2005-10-28 | 2007-05-02 | STMicroelectronics S.r.l. | Process for manufacturing a high-scale-integration mos device |
US20070249131A1 (en) * | 2006-04-21 | 2007-10-25 | International Business Machines Corporation | Opto-thermal annealing methods for forming metal gate and fully silicided gate field effect transistors |
US20080160769A1 (en) * | 2006-12-27 | 2008-07-03 | Hynix Semiconductor Inc. | Method for fabricating semiconductor device with recess gate |
US20080254579A1 (en) * | 2007-04-13 | 2008-10-16 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and fabrication thereof |
US20080293192A1 (en) * | 2007-05-22 | 2008-11-27 | Stefan Zollner | Semiconductor device with stressors and methods thereof |
US20080299750A1 (en) * | 2007-05-31 | 2008-12-04 | Spencer Gregory S | Multiple millisecond anneals for semiconductor device fabrication |
US7494885B1 (en) * | 2004-04-05 | 2009-02-24 | Advanced Micro Devices, Inc. | Disposable spacer process for field effect transistor fabrication |
US20100029073A1 (en) * | 2008-06-04 | 2010-02-04 | Park Jae-Hwa | Methods of Forming Integrated Circuit Devices Having Anisotropically-Oxidized Nitride Layers |
US20110001197A1 (en) * | 2006-10-19 | 2011-01-06 | Tokyo Electron Limited | Method for manufacturing semiconductor device and semiconductor device |
EP1965419A3 (en) * | 2007-03-02 | 2011-03-23 | Applied Materials, Inc. | Absorber layer candidates and techniques for application |
WO2011090571A2 (en) | 2009-12-30 | 2011-07-28 | Intel Corporation | Self-aligned contacts |
CN102637581A (en) * | 2012-04-06 | 2012-08-15 | 上海华力微电子有限公司 | Method for preventing outgassing of boron doped layer |
WO2013095347A1 (en) * | 2011-12-19 | 2013-06-27 | Intel Corporation | Selective laser annealing process for buried regions in a mos device |
CN103325826A (en) * | 2012-03-20 | 2013-09-25 | 中国科学院微电子研究所 | Semiconductor structure and manufacturing method thereof |
US8896030B2 (en) | 2012-09-07 | 2014-11-25 | Intel Corporation | Integrated circuits with selective gate electrode recess |
US20170373149A1 (en) * | 2016-06-28 | 2017-12-28 | International Business Machines Corporation | Iii-v extension by high temperature plasma doping |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7223676B2 (en) | 2002-06-05 | 2007-05-29 | Applied Materials, Inc. | Very low temperature CVD process with independently variable conformality, stress and composition of the CVD layer |
US20030160233A1 (en) * | 2002-02-28 | 2003-08-28 | Rendon Michael J. | Method of forming a semiconductor device having an energy absorbing layer and structure thereof |
KR100416628B1 (en) * | 2002-06-22 | 2004-01-31 | 삼성전자주식회사 | Manufacturing method for semiconductor device including gate spacer |
KR100464935B1 (en) * | 2002-09-17 | 2005-01-05 | 주식회사 하이닉스반도체 | Method of fabricating semiconductor device with ultra-shallow super-steep-retrograde epi-channel by Boron-fluoride compound doping |
US6764947B1 (en) * | 2003-02-14 | 2004-07-20 | Advanced Micro Devices, Inc. | Method for reducing gate line deformation and reducing gate line widths in semiconductor devices |
JP4589606B2 (en) | 2003-06-02 | 2010-12-01 | 住友重機械工業株式会社 | Manufacturing method of semiconductor device |
KR100568858B1 (en) * | 2003-07-24 | 2006-04-10 | 삼성전자주식회사 | Method for manufacturing SOI transistor having vertical double channel and structure thereof |
JP2005101196A (en) * | 2003-09-24 | 2005-04-14 | Hitachi Ltd | Manufacturing method of semiconductor integrated circuit device |
US6974730B2 (en) * | 2003-12-17 | 2005-12-13 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method for fabricating a recessed channel field effect transistor (FET) device |
JP4691939B2 (en) * | 2004-09-27 | 2011-06-01 | ソニー株式会社 | Manufacturing method of back-illuminated solid-state imaging device |
US7422775B2 (en) * | 2005-05-17 | 2008-09-09 | Applied Materials, Inc. | Process for low temperature plasma deposition of an optical absorption layer and high speed optical annealing |
US7312162B2 (en) | 2005-05-17 | 2007-12-25 | Applied Materials, Inc. | Low temperature plasma deposition process for carbon layer deposition |
US7109098B1 (en) * | 2005-05-17 | 2006-09-19 | Applied Materials, Inc. | Semiconductor junction formation process including low temperature plasma deposition of an optical absorption layer and high speed optical annealing |
US7335611B2 (en) | 2005-08-08 | 2008-02-26 | Applied Materials, Inc. | Copper conductor annealing process employing high speed optical annealing with a low temperature-deposited optical absorber layer |
US7429532B2 (en) | 2005-08-08 | 2008-09-30 | Applied Materials, Inc. | Semiconductor substrate process using an optically writable carbon-containing mask |
US7312148B2 (en) | 2005-08-08 | 2007-12-25 | Applied Materials, Inc. | Copper barrier reflow process employing high speed optical annealing |
US7323401B2 (en) | 2005-08-08 | 2008-01-29 | Applied Materials, Inc. | Semiconductor substrate process using a low temperature deposited carbon-containing hard mask |
JP2007115927A (en) * | 2005-10-20 | 2007-05-10 | Tokyo Univ Of Agriculture & Technology | Heat treatment method |
US7541234B2 (en) * | 2005-11-03 | 2009-06-02 | Samsung Electronics Co., Ltd. | Methods of fabricating integrated circuit transistors by simultaneously removing a photoresist layer and a carbon-containing layer on different active areas |
EP1791173A1 (en) * | 2005-11-25 | 2007-05-30 | STMicroelectronics S.r.l. | Process for manufacturing a MOSFET and corresponding MOSFET |
WO2007148476A1 (en) * | 2006-06-21 | 2007-12-27 | Hightec Systems Corporation | Semiconductor heat treatment method |
US7588990B2 (en) * | 2006-08-31 | 2009-09-15 | Applied Materials, Inc. | Dynamic surface annealing of implanted dopants with low temperature HDPCVD process for depositing a high extinction coefficient optical absorber layer |
US7968473B2 (en) * | 2006-11-03 | 2011-06-28 | Applied Materials, Inc. | Low temperature process for depositing a high extinction coefficient non-peeling optical absorber for a scanning laser surface anneal of implanted dopants |
US7863193B2 (en) * | 2007-08-09 | 2011-01-04 | Applied Materials, Inc. | Integrated circuit fabrication process using a compression cap layer in forming a silicide with minimal post-laser annealing dopant deactivation |
US7737036B2 (en) * | 2007-08-09 | 2010-06-15 | Applied Materials, Inc. | Integrated circuit fabrication process with minimal post-laser annealing dopant deactivation |
US20090042353A1 (en) * | 2007-08-09 | 2009-02-12 | Yi Ma | Integrated circuit fabrication process for a high melting temperature silicide with minimal post-laser annealing dopant deactivation |
US7855110B2 (en) * | 2008-07-08 | 2010-12-21 | International Business Machines Corporation | Field effect transistor and method of fabricating same |
JP2014090045A (en) * | 2012-10-30 | 2014-05-15 | Sanken Electric Co Ltd | Method for activating ion introduction layer, and method for manufacturing semiconductor device |
US9679773B1 (en) * | 2016-03-14 | 2017-06-13 | Infineon Technologies Ag | Method for thermal annealing and a semiconductor device formed by the method |
KR102608340B1 (en) | 2021-07-26 | 2023-12-01 | 주식회사 지엔테크 | Formation method of silicide layer using the Excimer laser for the semiconductor devices |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61154073A (en) | 1984-12-26 | 1986-07-12 | Matsushita Electric Ind Co Ltd | Manufacturing method of semiconductor device |
US5079600A (en) * | 1987-03-06 | 1992-01-07 | Schnur Joel M | High resolution patterning on solid substrates |
JP2605287B2 (en) | 1987-07-07 | 1997-04-30 | キヤノン株式会社 | Playback method |
JP3431647B2 (en) | 1992-10-30 | 2003-07-28 | 株式会社半導体エネルギー研究所 | Semiconductor device, method for manufacturing same, method for manufacturing memory device, and method for laser doping |
JPH06204418A (en) | 1992-12-28 | 1994-07-22 | Mitsubishi Electric Corp | Semiconductor device and manufacture thereof |
TW299897U (en) * | 1993-11-05 | 1997-03-01 | Semiconductor Energy Lab | A semiconductor integrated circuit |
US5882991A (en) | 1996-09-20 | 1999-03-16 | Texas Instruments Incorporated | Approaches for shallow junction formation |
JP2000031488A (en) * | 1997-08-26 | 2000-01-28 | Semiconductor Energy Lab Co Ltd | Semiconductor device and manufacturing method thereof |
JP2000077680A (en) | 1998-08-31 | 2000-03-14 | Yazaki Corp | Method of forming mesa structure, mesa structure using the same, mesa diaphragm and pressure sensor using the same |
-
2001
- 2001-04-30 KR KR1020010023403A patent/KR100365414B1/en not_active Expired - Fee Related
- 2001-11-30 JP JP2001367836A patent/JP4128771B2/en not_active Expired - Fee Related
- 2001-12-10 US US10/016,534 patent/US6475888B1/en not_active Expired - Fee Related
Cited By (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005036627A1 (en) | 2003-10-03 | 2005-04-21 | Applied Materials, Inc. | Absorber layer for dynamic surface annealing processing |
US20050074956A1 (en) * | 2003-10-03 | 2005-04-07 | Applied Materials, Inc. | Absorber layer for DSA processing |
US20060292808A1 (en) * | 2003-10-03 | 2006-12-28 | Applied Materials, Inc. | Absorber layer for dsa processing |
US7262106B2 (en) | 2003-10-03 | 2007-08-28 | Applied Materials, Inc. | Absorber layer for DSA processing |
US20070243721A1 (en) * | 2003-10-03 | 2007-10-18 | Applied Materials, Inc. | Absorber layer for dsa processing |
CN100459050C (en) * | 2003-10-03 | 2009-02-04 | 应用材料股份有限公司 | Absorber layer for dynamic surface annealing processing |
US7494885B1 (en) * | 2004-04-05 | 2009-02-24 | Advanced Micro Devices, Inc. | Disposable spacer process for field effect transistor fabrication |
EP1753019A4 (en) * | 2004-05-21 | 2008-12-03 | Panasonic Corp | METHOD OF INTRODUCING IMPURITIES AND ELECTRONIC ELEMENT USING THE SAME |
EP1753019A1 (en) * | 2004-05-21 | 2007-02-14 | Matsushita Electric Industrial Co., Ltd. | Impurity introducing method and electronic element using it |
US7582492B2 (en) | 2004-05-21 | 2009-09-01 | Panasonic Corporation | Method of doping impurities, and electronic element using the same |
US20100112801A1 (en) * | 2004-09-10 | 2010-05-06 | Kabushiki Kaisha Toshiba | Method of manufacturing semiconductor device |
US8158509B2 (en) | 2004-09-10 | 2012-04-17 | Kabushiki Kaisha Toshiba | Method of manufacturing semiconductor device |
US20060057828A1 (en) * | 2004-09-10 | 2006-03-16 | Mitsuhiro Omura | Method of manufacturing semiconductor device |
US7670891B2 (en) * | 2004-09-10 | 2010-03-02 | Kabushiki Kaisha Toshiba | Method of manufacturing semiconductor device |
EP1780776A1 (en) * | 2005-10-28 | 2007-05-02 | STMicroelectronics S.r.l. | Process for manufacturing a high-scale-integration mos device |
US7410852B2 (en) * | 2006-04-21 | 2008-08-12 | International Business Machines Corporation | Opto-thermal annealing methods for forming metal gate and fully silicided gate field effect transistors |
US20070249131A1 (en) * | 2006-04-21 | 2007-10-25 | International Business Machines Corporation | Opto-thermal annealing methods for forming metal gate and fully silicided gate field effect transistors |
US20110001197A1 (en) * | 2006-10-19 | 2011-01-06 | Tokyo Electron Limited | Method for manufacturing semiconductor device and semiconductor device |
US7989350B2 (en) * | 2006-12-27 | 2011-08-02 | Hynix Semiconductor Inc. | Method for fabricating semiconductor device with recess gate |
US20080160769A1 (en) * | 2006-12-27 | 2008-07-03 | Hynix Semiconductor Inc. | Method for fabricating semiconductor device with recess gate |
EP1965419A3 (en) * | 2007-03-02 | 2011-03-23 | Applied Materials, Inc. | Absorber layer candidates and techniques for application |
US8421166B2 (en) | 2007-04-13 | 2013-04-16 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and fabrication thereof |
US7994040B2 (en) * | 2007-04-13 | 2011-08-09 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and fabrication thereof |
US20080254579A1 (en) * | 2007-04-13 | 2008-10-16 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and fabrication thereof |
US20080293192A1 (en) * | 2007-05-22 | 2008-11-27 | Stefan Zollner | Semiconductor device with stressors and methods thereof |
US7846803B2 (en) | 2007-05-31 | 2010-12-07 | Freescale Semiconductor, Inc. | Multiple millisecond anneals for semiconductor device fabrication |
WO2008150683A1 (en) * | 2007-05-31 | 2008-12-11 | Freescale Semiconductor Inc. | Multiple millisecond anneals for semiconductor device fabrication |
US20080299750A1 (en) * | 2007-05-31 | 2008-12-04 | Spencer Gregory S | Multiple millisecond anneals for semiconductor device fabrication |
US20120100708A1 (en) * | 2008-06-04 | 2012-04-26 | Park Jae-Hwa | Methods of Forming Integrated Circuit Devices Having Anisotropically-Oxidized Nitride Layers |
US20100029073A1 (en) * | 2008-06-04 | 2010-02-04 | Park Jae-Hwa | Methods of Forming Integrated Circuit Devices Having Anisotropically-Oxidized Nitride Layers |
US7989333B2 (en) * | 2008-06-04 | 2011-08-02 | Samsung Electronics Co., Ltd. | Methods of forming integrated circuit devices having anisotropically-oxidized nitride layers |
US10141226B2 (en) | 2009-12-30 | 2018-11-27 | Intel Corporation | Self-aligned contacts |
WO2011090571A2 (en) | 2009-12-30 | 2011-07-28 | Intel Corporation | Self-aligned contacts |
US12266571B2 (en) | 2009-12-30 | 2025-04-01 | Intel Corporation | Self-aligned contacts |
US11887891B2 (en) | 2009-12-30 | 2024-01-30 | Intel Corporation | Self-aligned contacts |
EP2519975A4 (en) * | 2009-12-30 | 2013-09-11 | Intel Corp | SELF-ORIENTING CONTACTS |
US11600524B2 (en) | 2009-12-30 | 2023-03-07 | Intel Corporation | Self-aligned contacts |
KR101459198B1 (en) * | 2009-12-30 | 2014-11-07 | 인텔 코포레이션 | Self-aligned contacts |
US10930557B2 (en) | 2009-12-30 | 2021-02-23 | Intel Corporation | Self-aligned contacts |
US9054178B2 (en) | 2009-12-30 | 2015-06-09 | Intel Corporation | Self-aligned contacts |
US9093513B2 (en) | 2009-12-30 | 2015-07-28 | Intel Corporation | Self-aligned contacts |
US10629483B2 (en) | 2009-12-30 | 2020-04-21 | Intel Corporation | Self-aligned contacts |
KR101987928B1 (en) * | 2009-12-30 | 2019-06-11 | 인텔 코포레이션 | Self-aligned contacts |
US9466565B2 (en) | 2009-12-30 | 2016-10-11 | Intel Corporation | Self-aligned contacts |
US9508821B2 (en) | 2009-12-30 | 2016-11-29 | Intel Corporation | Self-aligned contacts |
EP2519975A2 (en) * | 2009-12-30 | 2012-11-07 | Intel Corporation | Self-aligned contacts |
US9892967B2 (en) | 2009-12-30 | 2018-02-13 | Intel Corporation | Self-aligned contacts |
KR101778717B1 (en) * | 2009-12-30 | 2017-09-14 | 인텔 코포레이션 | Self-aligned contacts |
KR20180108872A (en) * | 2009-12-30 | 2018-10-04 | 인텔 코포레이션 | Self-aligned contacts |
US9196704B2 (en) | 2011-12-19 | 2015-11-24 | Intel Corporation | Selective laser annealing process for buried regions in a MOS device |
WO2013095347A1 (en) * | 2011-12-19 | 2013-06-27 | Intel Corporation | Selective laser annealing process for buried regions in a mos device |
CN103325826A (en) * | 2012-03-20 | 2013-09-25 | 中国科学院微电子研究所 | Semiconductor structure and manufacturing method thereof |
CN102637581A (en) * | 2012-04-06 | 2012-08-15 | 上海华力微电子有限公司 | Method for preventing outgassing of boron doped layer |
US10020232B2 (en) | 2012-09-07 | 2018-07-10 | Intel Corporation | Integrated circuits with recessed gate electrodes |
US9418898B2 (en) | 2012-09-07 | 2016-08-16 | Intel Corporation | Integrated circuits with selective gate electrode recess |
US10651093B2 (en) | 2012-09-07 | 2020-05-12 | Intel Corporation | Integrated circuits with recessed gate electrodes |
US8896030B2 (en) | 2012-09-07 | 2014-11-25 | Intel Corporation | Integrated circuits with selective gate electrode recess |
US11183432B2 (en) | 2012-09-07 | 2021-11-23 | Intel Corporation | Integrated circuits with recessed gate electrodes |
US20170373149A1 (en) * | 2016-06-28 | 2017-12-28 | International Business Machines Corporation | Iii-v extension by high temperature plasma doping |
US11018225B2 (en) * | 2016-06-28 | 2021-05-25 | International Business Machines Corporation | III-V extension by high temperature plasma doping |
Also Published As
Publication number | Publication date |
---|---|
US6475888B1 (en) | 2002-11-05 |
JP2002343734A (en) | 2002-11-29 |
JP4128771B2 (en) | 2008-07-30 |
KR100365414B1 (en) | 2002-12-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6475888B1 (en) | Method for forming ultra-shallow junctions using laser annealing | |
CN100495662C (en) | Semiconductor device and manufacturing method thereof | |
KR100440840B1 (en) | Method of manufacturing semiconductor device and semiconductor device | |
US7344948B2 (en) | Methods of forming transistors | |
US6372589B1 (en) | Method of forming ultra-shallow source/drain extension by impurity diffusion from doped dielectric spacer | |
US20040009644A1 (en) | Method for manufacturing channel gate type field effect transistor | |
US20050151203A1 (en) | Temporary self-aligned stop layer is applied on silicon sidewall | |
JP4514023B2 (en) | Silicon oxide liner ion implantation to prevent dopants from diffusing out of source / drain extensions | |
JPH05326552A (en) | Semiconductor element and its manufacture | |
JP3874716B2 (en) | Manufacturing method of semiconductor device | |
US6281085B1 (en) | Method of manufacturing a semiconductor device | |
JP3496723B2 (en) | Method for manufacturing semiconductor device | |
WO2004114413A1 (en) | Semiconductor device and its manufacturing method | |
US20040203210A1 (en) | Method of fabricating a semiconductor device having a shallow source/drain region | |
JP2733082B2 (en) | MOS device manufacturing method | |
KR100313089B1 (en) | Method for manufacturing semiconductor device | |
KR100586178B1 (en) | Schottky Barrier Through Transistors and Manufacturing Method Thereof | |
JP3371875B2 (en) | Method for manufacturing semiconductor device | |
JP3362722B2 (en) | Method for manufacturing semiconductor device | |
JP3186708B2 (en) | Method for manufacturing semiconductor device | |
US6194298B1 (en) | Method of fabricating semiconductor device | |
JP2004228351A (en) | Semiconductor device and its manufacturing method | |
JP3455742B2 (en) | Semiconductor device | |
KR100705233B1 (en) | Method of manufacturing semiconductor device | |
KR100401500B1 (en) | Method of fabricating semiconductor devices |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: HYNIX SEMICONDUCTOR INC., KOREA, REPUBLIC OF Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SOHN, YONG SUN;REEL/FRAME:012388/0200 Effective date: 20011115 |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
REMI | Maintenance fee reminder mailed | ||
LAPS | Lapse for failure to pay maintenance fees | ||
STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
|
FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20141105 |