US20020039608A1 - Food bar - Google Patents
Food bar Download PDFInfo
- Publication number
- US20020039608A1 US20020039608A1 US09/838,510 US83851001A US2002039608A1 US 20020039608 A1 US20020039608 A1 US 20020039608A1 US 83851001 A US83851001 A US 83851001A US 2002039608 A1 US2002039608 A1 US 2002039608A1
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- United States
- Prior art keywords
- parts
- milk
- binder
- fat
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 235000013305 food Nutrition 0.000 title claims description 16
- 235000013336 milk Nutrition 0.000 claims abstract description 44
- 239000008267 milk Substances 0.000 claims abstract description 44
- 210000004080 milk Anatomy 0.000 claims abstract description 44
- 235000000346 sugar Nutrition 0.000 claims abstract description 38
- 235000013339 cereals Nutrition 0.000 claims abstract description 36
- 239000011230 binding agent Substances 0.000 claims abstract description 34
- 239000007787 solid Substances 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 15
- 150000008163 sugars Chemical class 0.000 claims abstract description 15
- 235000021487 ready-to-eat food Nutrition 0.000 claims abstract description 14
- 239000003925 fat Substances 0.000 claims abstract description 12
- 239000003906 humectant Substances 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 235000019545 cooked cereal Nutrition 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 235000019197 fats Nutrition 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 10
- 239000004416 thermosoftening plastic Substances 0.000 claims description 10
- 235000019871 vegetable fat Nutrition 0.000 claims description 10
- 235000013861 fat-free Nutrition 0.000 claims description 9
- 238000005520 cutting process Methods 0.000 claims description 8
- 235000021243 milk fat Nutrition 0.000 claims description 8
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 235000020186 condensed milk Nutrition 0.000 claims description 5
- 239000008121 dextrose Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 235000009470 Theobroma cacao Nutrition 0.000 claims description 3
- 150000001720 carbohydrates Chemical class 0.000 claims description 2
- 235000014633 carbohydrates Nutrition 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 235000018102 proteins Nutrition 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- 244000240602 cacao Species 0.000 claims 1
- 241000209140 Triticum Species 0.000 description 8
- 235000021307 Triticum Nutrition 0.000 description 8
- 235000013312 flour Nutrition 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 244000299461 Theobroma cacao Species 0.000 description 3
- 238000010411 cooking Methods 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 239000006188 syrup Substances 0.000 description 3
- 235000020357 syrup Nutrition 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- 235000007319 Avena orientalis Nutrition 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 235000013325 dietary fiber Nutrition 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229960004903 invert sugar Drugs 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 235000020183 skimmed milk Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 229920001685 Amylomaize Polymers 0.000 description 1
- 241000209763 Avena sativa Species 0.000 description 1
- 235000007558 Avena sp Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- 239000005913 Maltodextrin Substances 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 102000014171 Milk Proteins Human genes 0.000 description 1
- 108010011756 Milk Proteins Proteins 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229940035034 maltodextrin Drugs 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 235000021404 traditional food Nutrition 0.000 description 1
- 235000015099 wheat brans Nutrition 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 235000019222 white chocolate Nutrition 0.000 description 1
- 235000020985 whole grains Nutrition 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/161—Puffed cereals, e.g. popcorn or puffed rice
- A23L7/165—Preparation of puffed cereals involving preparation of meal or dough as an intermediate step
- A23L7/17—Preparation of puffed cereals involving preparation of meal or dough as an intermediate step by extrusion
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/117—Flakes or other shapes of ready-to-eat type; Semi-finished or partly-finished products therefor
- A23L7/126—Snacks or the like obtained by binding, shaping or compacting together cereal grains or cereal pieces, e.g. cereal bars
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/20—Agglomerating; Granulating; Tabletting
- A23P10/28—Tabletting; Making food bars by compression of a dry powdered mixture
Definitions
- U.S. Pat. No. 4,650,685 to Persson et al. discloses a biscuit comprising agglomerated granules of a cooked-extruded base coated with a binder, the base comprising from 40 to 80 parts by weight of cereal flour, up to 20 parts sucrose and from 0.5 to 3 parts of oil or fat, and the binder comprising from 8 to 30 parts by weight of sucrose and/or mixtures of glucose and its polymers.
- PCT Application WO89/04121 assigned to HEINZ SCHAAF OHG discloses a process for manufacturing cereals by cooking-extruding a mixture of cereal material, vegetable and/or fruits with a partial amount of sugar and milk, cutting the expanded rope of cooked-extruded mixture into pieces having a large surface, spraying an aqueous suspension of sugar and milk onto the just cut, hot and moist pieces, coating the moistened pieces with a remaining part of components in powder form and drying the coated pieces.
- the present invention is a ready-to-eat food bar which includes agglomerated particles of amylaceous material, sugars and optionally milk solids.
- the food bar of the invention is nutritionally valuable and has a soft texture while retaining the crunchiness of cereal.
- the amylaceous material of the ready-to-eat food bar of the invention includes one or more cooked cereal bases which are coated with a binder.
- the binder includes sugars, milk solids, humectants and fat.
- the present invention is also a process for manufacturing the ready-to-eat food bar.
- This process includes the steps of preparing a dry mixture of particles of one or more cooked cereal bases which includes mainly amylaceous materials and optionally milk solids, mixing the dry mixture with a binder having sugars, milk solids, humectants and fat and forming the mass thus obtained into a bar shape.
- the expression “being nutritionally valuable” means a food bar which is rich in milk protein and calcium and which is based on amylaceous materials and sugar comprising, in percent by weight, from about 5.5% to about 27.5% of milk solids nonfat and from about 2.5% to about 25% of milk fat and/or vegetable fat.
- the present food bar can generally comprise, in percent by weight, from about 4% to about 12% of protein, from about 50% to about 80% of available carbohydrate and from about 2.5 to about 25% of fat.
- the expression “has a soft texture while retaining the crunchiness of cereal” means that the cereal particles are crunchy within the bar while the binder, namely the continuous phase of the bar is soft.
- the expression “particles of cooked cereal bases” covers, for example, any possible kind of cereal in piece form such as rolled cereals, gun puffed grains, cereal flakes and/or cooked-extruded cereals.
- the term “food bar” means a food product having a massive shape which can be eaten by hand, no limit being set as to the choice of the shape which can be for example, a bar as well as a stick, a ball, a heart, a star, a bear or a banana.
- the present food bar can include from about 5.5% to about 27.5% of milk solids nonfat, from about 2.5% to about 25% of milk fat and/or vegetable fat, from about 30% to about 60% of amylaceous material, from about 5% to about 30% of sugars, from about 2.5% to about 15% of humectants and from about 1.0% to about 7.0% of residual water.
- the present food bar can further comprise up to about 3% of additional calcium, preferably in form of calcium carbonate or milk calcium, in addition to the calcium already present in the milk solids nonfat.
- the milk solids can be incorporated into the food bar in two parts, a first part being incorporated into the cooked cereal basis and a second part being incorporated into the binder, or in one part, all incorporated into the binder.
- the milk solids nonfat in the cooked-extruded bases can be powdered skimmed milk.
- the milk solids in the binder can be milk solids from fresh milk, milk solids from condensed milk and/or milk powder.
- the milk fat and/or vegetable fat can be, for example, butter oil and/or vegetable fat such as partially hydrogenated sunflower or rape seed fat having a melting point of from about 33° C. to about 39° C.
- amylaceous material useful in the present invention includes, without limitation, a cereal flour, a starch and/or maltodextrin.
- the cereal flour can be, for example, wheat, barley, oat, rice and/or corn flour.
- the starch can be a native starch obtained from wheat, barley, rice and/or corn, preferably, high amylose starch.
- Useful sugars for the present invention include, without limitation, sucrose, dextrose, fructose, glucose syrup, invert sugar and/or maltose syrup in dry or liquid form.
- the possible source of fiber material can be without limitation a cereal bran.
- the binder comprises humectants and it can further comprise emulsifiers.
- the humectants can be glycerol and/or sorbitol.
- the emulsifier can be one or more mono- or di-glycerides of edible fatty acids, preferably of vegetable origin, or lecithin.
- Natural and/or artificial antioxydants can also be added in order to prolong the shelflife of the bar, such as tocopherols, BHA, BHT and mixtures thereof, for example.
- the present process for manufacturing a ready-to-eat food bar includes preparing a dry mixture of particles of one or more cooked cereal bases, which bases include primarily amylaceous materials and optionally milk solids; mixing the dry mixture with a binder which comprises primarily sugars, milk solids, humectants and fat and forming the mass thus obtained into a bar shape.
- Particles of cooked cereal bases can be any of those known to the man skilled in the art, including, without limitation, rolled cereals, gun puffed grains, cereal flakes and/or cooked-extruded cereals.
- Puffed grains can be prepared for example, by puffing whole grains of wheat or rice in a gun or in an oven.
- Cereal flakes are prepared by methods, including, without limitation, cooking cereal grits or grains with a liquor, forming pellets out of the cooked mass thus obtained, rolling, toasting and optionally them with sugar.
- Cooked-extruded cereals are prepared by cooking-extruding-expanding a mixture mainly comprising amylaceous materials and optionally milk solids, thus obtaining a rope of a thermoplastic mass having a porous texture, cutting the rope into pieces and optionally coating the pieces with sugar.
- the preferred cooked-extruded-expanded cereals can be prepared by cooking-extruding-expanding at about 120° C. to about 170° C. under about 40 bar to 160 bar for about 5 to about 50 seconds a mixture comprising, in parts by weight, up to about 27.5 parts of milk solids nonfat, up to about 12.5 parts of milk fat and/or vegetable fat, from about 50 to about 90 parts of amylaceous material, up to 12 parts of sugars, and added water up to a water content of from about 11% to about 19% by weight of the mixture, thus obtaining a rope of a thermoplastic mass having a porous texture, cutting the rope into pieces and optionally drying them.
- This mixing step is carried out in a first mixing section of a traditional food extruder, preferably a twin screw extruder.
- Cooking the mixture is then be carried out in subsequent sections of the extruder where the mixture is heated, compressed and sheared so that it forms a cooked thermoplastic mass.
- thermoplastic mass is extruded by having it pushed by the extruder screw or twin screw through the openings of a die provided for at an end of the extruder.
- the die may have one or more circular openings having from about 2 mm to about 5 mm in diameter.
- thermoplastic mass can be expanded by extruding it through the die into an open space at ambiant temperature and at atmospheric pressure.
- Water is lost in form of steam escaping the thermoplastic mass during expansion so that the rope thus obtained has a porous texture and may have a water content of from about 5% to less than about 11%, for example.
- Drying the food bar pieces can be carried out on a belt dryer with hot air.
- the dried pieces are then coated with a sugar solution and dried again.
- the coating step can be carried out in a tumbler where a sugar solution can be sprayed onto the tumbling pieces, for example.
- the sugar solution comprises from about 50% to about 60% sugar, from about 3% to about 10% dextrose, from about 0.5% to about 1.5% oil and from about 10% to about 40%, especially from about 25% to about 35% water.
- the sugar solution can also include without limitation, cocoa powder, sodium chloride and aroma.
- the amount of sugar solution to be used can be such that the weight proportion of coating on the coated pieces is from about 10% to about 40%, preferably from about 15% to about 25%.
- the coated pieces can then be finally dried down to a residual water content of about 3% or less, preferably about 2% or less.
- the binder can include, in parts by weight, from about 10 to about 70 parts of sugars, from about 5 parts to about 30 parts of humectants, from about 5.5 to about 27.5 parts of milk solids nonfat, from about 10 to about 35 parts of milk fat and/or vegetable fat, up to 10 parts of cocoa powder, up to about 5 parts of emulsifier and added water up to a water content of from about 5% to about 15%.
- the binder can be prepared by mixing together its dry components in powdered form with its fluid components in liquid form.
- Milk solids which can be optionally included into the binder can be incorporated in the form of fresh milk, condensed milk and/or of milk powder.
- Water can be added as such, as water contained in condensed milk or as water contained in fresh milk.
- Sugar can be added as such and/or as sugar contained, for example, in sweetened condensed milk.
- a preferred binder comprises condensed sweetened milk, in an amount of from about 20 to about 45 parts by weight, for example.
- the binder can be prepared by mixing the components in a double walled tank while heating to a temperature of from 105° C. to 117° C., thus concentrating the mixture up to a dry matter content of from 80% to 95%, preferably of from 90% to 92%, and then cooling down to a temperature in a range of from about 33° C. to about 80° C.
- a dry mix of particles can be prepared and mixed with the binder in a flowable state, namely at a temperature such that the fat components are in a liquid state, especially at a temperature of from about 33° C. to about 80° C.
- Mixing particles and binder can be carried out by means of any gentle, especially continuous mixer which does not damage the cereal particles, such as a screw mixer of the helical spring type with an axial sprinkling nozzle, a coating drum or a paddle mixer.
- the dry mix and the binder can be mixed at a rate of about 40 to about 70 parts by weight of dry mix and about 60 parts to about 30 parts by weight of binder, while optionally adding thereto additional cereals, fruits having an adequate water activity (Aw) or nuts, for example.
- the mass thus obtained preferably has an Aw of from 0.1 to 0.5 (water content of from 1 to 7%), and more preferably an Aw of from 0.1 to 0.3 (water content of from 1 to 3%).
- the flowable mass obtained above can be formed into a bar shape by sheet-cutting, sheet-moulding, moulding or pressing through an opening and cutting.
- the ready-to-eat food bar may then be coated with a sweet coating such as a chocolate coating or a coating reminiscent of white chocolate such as a mixture of a milk powder and fat, for example.
- a sweet coating such as a chocolate coating or a coating reminiscent of white chocolate such as a mixture of a milk powder and fat, for example.
- the bar thus coated can be finally provided with any decorating usual in the confectionary art.
- the ready-to-eat food bar can be conditioned in a packing providing for its protection against humidity, such as a packing made of a film with aluminum foil, or a metallised foil.
- a ready-to-eat food bar having particles of a cooked-extruded wheat base was manufactured by first preparing, a mixture which had the following composition, (in parts, except added water): wheat flour 41 wheat starch 18 oat flour 9 wheat bran 9 calcium carbonate 0.5 added water, up to a water content of 19%
- the powders were first mixed together to obtain a dry mix.
- the dry mix and added water were then mixed together in the extruder.
- the mixture obtained in this way was cooked-extruded-expanded with the aid of a BC-45H type CLEXTRAL twin screw extruder having a screw diameter of 55 mm and a total processing length of 800 mm.
- Cooking-extruding was carried out at 150° C. under 100 bar for 30 seconds, the two intenneshing screws rotating at 300 rpm.
- the cooked thermoplastic mass obtained in this way was extruded through a die having eight circular openings of 3 mm in diameter.
- thermoplastic mass was extruded into ambiant air and immediately cut with a two blade cutter rotating adjacent to the opening at 2000 rpm.
- the particles were then dried with hot air on a belt dryer to a residual water content of about 2.9%.
- the sugar solution comprised about 59% sugar, about 10% dextrose, about 1% oil and about 30% water.
- the amount of sugar solution used was such that the weight proportion of coating on the coated pieces was about 20%.
- the coated particles were then finally dried down to a residual water content of about 2%.
- a binder was prepared which had the following composition (parts): skim milk powder 12.5 glucose syrup 9.4 sorbitol syrup 7.2 invert sugar 11.5 condensed sweetened milk (29% 33.5 water, 43% sugar) sodium chloride 0.3 hydrogenated vegetable fat 13.4 (melting point 39° C.) mixture of vegetable mono and diglycerides 0.6 Glycerine 6.7 Water 5.0
- the components were mixed together in a double walled tank while being heated to 114° C. until the mixture was concentrated up to a dry matter content of 91%. The binder was then cooled down to a temperature of 75° C.
- the mass thus obtained was formed into a bar shape by sheeting down to a thickness of 1 cm and cutting individual bars 3 cm in width and 10 cm in length.
- the bars had a water content of 5.3% and an Aw value of 0.35.
- the bars had a soft texture while retaining the crunchiness of the cooked-extruded-expanded wheat base. They had an appetizing taste and could be eaten as they were. They were nutritionally valuable, each individual bar representing a complete meal just as it was.
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Nutrition Science (AREA)
- Health & Medical Sciences (AREA)
- Grain Derivatives (AREA)
- Confectionery (AREA)
- Cereal-Derived Products (AREA)
- General Preparation And Processing Of Foods (AREA)
- Noodles (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Jellies, Jams, And Syrups (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Fish Paste Products (AREA)
- Seeds, Soups, And Other Foods (AREA)
Abstract
A ready-to-eat food bar including of agglomerated particles of one or more cereal bases is provided. The cereal bases include primarily amalyceous materials and optionally milk solids. The agglomerated particles are coated with a binder which includes sugars, milk solids, humectants or fat and optionally milk solids. A process for manufacturing the ready-to-eat food bar is also provided.
Description
- 1. Field of Invention
- The present invention relates to a ready-to-eat food bar and to a process for manufacturing it.
- 2. Description of the Related Art
- U.S. Pat. No. 4,650,685 to Persson et al. discloses a biscuit comprising agglomerated granules of a cooked-extruded base coated with a binder, the base comprising from 40 to 80 parts by weight of cereal flour, up to 20 parts sucrose and from 0.5 to 3 parts of oil or fat, and the binder comprising from 8 to 30 parts by weight of sucrose and/or mixtures of glucose and its polymers.
- PCT Application WO89/04121 assigned to HEINZ SCHAAF OHG discloses a process for manufacturing cereals by cooking-extruding a mixture of cereal material, vegetable and/or fruits with a partial amount of sugar and milk, cutting the expanded rope of cooked-extruded mixture into pieces having a large surface, spraying an aqueous suspension of sugar and milk onto the just cut, hot and moist pieces, coating the moistened pieces with a remaining part of components in powder form and drying the coated pieces.
- The present invention is a ready-to-eat food bar which includes agglomerated particles of amylaceous material, sugars and optionally milk solids. The food bar of the invention is nutritionally valuable and has a soft texture while retaining the crunchiness of cereal.
- The amylaceous material of the ready-to-eat food bar of the invention includes one or more cooked cereal bases which are coated with a binder. Advantageously, the binder includes sugars, milk solids, humectants and fat.
- The present invention is also a process for manufacturing the ready-to-eat food bar. This process includes the steps of preparing a dry mixture of particles of one or more cooked cereal bases which includes mainly amylaceous materials and optionally milk solids, mixing the dry mixture with a binder having sugars, milk solids, humectants and fat and forming the mass thus obtained into a bar shape.
- It has surprisingly been found that it was possible in this way to provide a food bar which is ready-to-eat, namely, it can be eaten just by scrunching it, is nutritionally valuable and has a soft texture while retaining the crunchiness of cereal.
- Other improvements which the present invention provides over the prior art will be identified as a result of the following description which sets forth the preferred embodiments of the present invention. The description is not in any way intended to limit the scope of the present invention, but rather only to provide the working example of the present preferred embodiments. The scope of the present invention will be pointed out in the appended claims.
- In the present context, the expression “being nutritionally valuable” means a food bar which is rich in milk protein and calcium and which is based on amylaceous materials and sugar comprising, in percent by weight, from about 5.5% to about 27.5% of milk solids nonfat and from about 2.5% to about 25% of milk fat and/or vegetable fat.
- In addition to relatively small amounts of each of residual water, ash, dietary fibers, vitamins and minerals, the present food bar can generally comprise, in percent by weight, from about 4% to about 12% of protein, from about 50% to about 80% of available carbohydrate and from about 2.5 to about 25% of fat.
- The expression “has a soft texture while retaining the crunchiness of cereal” means that the cereal particles are crunchy within the bar while the binder, namely the continuous phase of the bar is soft.
- The expression “particles of cooked cereal bases” covers, for example, any possible kind of cereal in piece form such as rolled cereals, gun puffed grains, cereal flakes and/or cooked-extruded cereals.
- The term “food bar” means a food product having a massive shape which can be eaten by hand, no limit being set as to the choice of the shape which can be for example, a bar as well as a stick, a ball, a heart, a star, a bear or a banana.
- The present food bar can include from about 5.5% to about 27.5% of milk solids nonfat, from about 2.5% to about 25% of milk fat and/or vegetable fat, from about 30% to about 60% of amylaceous material, from about 5% to about 30% of sugars, from about 2.5% to about 15% of humectants and from about 1.0% to about 7.0% of residual water.
- The present food bar can further comprise up to about 3% of additional calcium, preferably in form of calcium carbonate or milk calcium, in addition to the calcium already present in the milk solids nonfat.
- The food bar can also further comprise added vitamins, minerals and/or a source of dietary fibers.
- The milk solids can be incorporated into the food bar in two parts, a first part being incorporated into the cooked cereal basis and a second part being incorporated into the binder, or in one part, all incorporated into the binder.
- The milk solids nonfat in the cooked-extruded bases can be powdered skimmed milk.
- The milk solids in the binder can be milk solids from fresh milk, milk solids from condensed milk and/or milk powder.
- The milk fat and/or vegetable fat can be, for example, butter oil and/or vegetable fat such as partially hydrogenated sunflower or rape seed fat having a melting point of from about 33° C. to about 39° C.
- The amylaceous material useful in the present invention includes, without limitation, a cereal flour, a starch and/or maltodextrin.
- The cereal flour can be, for example, wheat, barley, oat, rice and/or corn flour.
- The starch can be a native starch obtained from wheat, barley, rice and/or corn, preferably, high amylose starch.
- Useful sugars for the present invention include, without limitation, sucrose, dextrose, fructose, glucose syrup, invert sugar and/or maltose syrup in dry or liquid form.
- The possible source of fiber material can be without limitation a cereal bran.
- Beside sugars and milk solids, the binder comprises humectants and it can further comprise emulsifiers.
- The humectants can be glycerol and/or sorbitol.
- The emulsifier can be one or more mono- or di-glycerides of edible fatty acids, preferably of vegetable origin, or lecithin.
- Natural and/or artificial antioxydants can also be added in order to prolong the shelflife of the bar, such as tocopherols, BHA, BHT and mixtures thereof, for example.
- As stated above, the present process for manufacturing a ready-to-eat food bar includes preparing a dry mixture of particles of one or more cooked cereal bases, which bases include primarily amylaceous materials and optionally milk solids; mixing the dry mixture with a binder which comprises primarily sugars, milk solids, humectants and fat and forming the mass thus obtained into a bar shape.
- Particles of cooked cereal bases can be any of those known to the man skilled in the art, including, without limitation, rolled cereals, gun puffed grains, cereal flakes and/or cooked-extruded cereals.
- Rolled cereals can be prepared by cooking grains (whole or grits) with a liquor comprising sugar, malt, salt and vitamins, partially drying, rolling and flaking them.
- Puffed grains can be prepared for example, by puffing whole grains of wheat or rice in a gun or in an oven.
- Cereal flakes are prepared by methods, including, without limitation, cooking cereal grits or grains with a liquor, forming pellets out of the cooked mass thus obtained, rolling, toasting and optionally them with sugar.
- Cooked-extruded cereals are prepared by cooking-extruding-expanding a mixture mainly comprising amylaceous materials and optionally milk solids, thus obtaining a rope of a thermoplastic mass having a porous texture, cutting the rope into pieces and optionally coating the pieces with sugar.
- The preferred cooked-extruded-expanded cereals can be prepared by cooking-extruding-expanding at about 120° C. to about 170° C. under about 40 bar to 160 bar for about 5 to about 50 seconds a mixture comprising, in parts by weight, up to about 27.5 parts of milk solids nonfat, up to about 12.5 parts of milk fat and/or vegetable fat, from about 50 to about 90 parts of amylaceous material, up to 12 parts of sugars, and added water up to a water content of from about 11% to about 19% by weight of the mixture, thus obtaining a rope of a thermoplastic mass having a porous texture, cutting the rope into pieces and optionally drying them.
- The mixture can be prepared by first mixing together the powdery components to obtain a dry mix and then mixing the dry mix and the liquid or fluid components.
- This mixing step is carried out in a first mixing section of a traditional food extruder, preferably a twin screw extruder.
- Cooking the mixture is then be carried out in subsequent sections of the extruder where the mixture is heated, compressed and sheared so that it forms a cooked thermoplastic mass.
- The thermoplastic mass is extruded by having it pushed by the extruder screw or twin screw through the openings of a die provided for at an end of the extruder.
- The die may have one or more circular openings having from about 2 mm to about 5 mm in diameter.
- The thermoplastic mass can be expanded by extruding it through the die into an open space at ambiant temperature and at atmospheric pressure.
- Water is lost in form of steam escaping the thermoplastic mass during expansion so that the rope thus obtained has a porous texture and may have a water content of from about 5% to less than about 11%, for example.
- The rope of expanded thermoplastic mass thus obtained can be cut into pieces by using a two or more blade cutter rotating adjacent to the die openings of the extruder.
- Drying the food bar pieces can be carried out on a belt dryer with hot air.
- Preferably, the dried pieces are then coated with a sugar solution and dried again. The coating step can be carried out in a tumbler where a sugar solution can be sprayed onto the tumbling pieces, for example.
- The sugar solution comprises from about 50% to about 60% sugar, from about 3% to about 10% dextrose, from about 0.5% to about 1.5% oil and from about 10% to about 40%, especially from about 25% to about 35% water. The sugar solution can also include without limitation, cocoa powder, sodium chloride and aroma.
- The amount of sugar solution to be used can be such that the weight proportion of coating on the coated pieces is from about 10% to about 40%, preferably from about 15% to about 25%.
- The coated pieces can then be finally dried down to a residual water content of about 3% or less, preferably about 2% or less.
- As a whole, the binder can include, in parts by weight, from about 10 to about 70 parts of sugars, from about 5 parts to about 30 parts of humectants, from about 5.5 to about 27.5 parts of milk solids nonfat, from about 10 to about 35 parts of milk fat and/or vegetable fat, up to 10 parts of cocoa powder, up to about 5 parts of emulsifier and added water up to a water content of from about 5% to about 15%.
- The binder can be prepared by mixing together its dry components in powdered form with its fluid components in liquid form.
- Milk solids which can be optionally included into the binder can be incorporated in the form of fresh milk, condensed milk and/or of milk powder.
- Water can be added as such, as water contained in condensed milk or as water contained in fresh milk.
- Sugar can be added as such and/or as sugar contained, for example, in sweetened condensed milk.
- A preferred binder comprises condensed sweetened milk, in an amount of from about 20 to about 45 parts by weight, for example. In this case, the binder can be prepared by mixing the components in a double walled tank while heating to a temperature of from 105° C. to 117° C., thus concentrating the mixture up to a dry matter content of from 80% to 95%, preferably of from 90% to 92%, and then cooling down to a temperature in a range of from about 33° C. to about 80° C.
- A dry mix of particles can be prepared and mixed with the binder in a flowable state, namely at a temperature such that the fat components are in a liquid state, especially at a temperature of from about 33° C. to about 80° C.
- Mixing particles and binder can be carried out by means of any gentle, especially continuous mixer which does not damage the cereal particles, such as a screw mixer of the helical spring type with an axial sprinkling nozzle, a coating drum or a paddle mixer.
- The dry mix and the binder can be mixed at a rate of about 40 to about 70 parts by weight of dry mix and about 60 parts to about 30 parts by weight of binder, while optionally adding thereto additional cereals, fruits having an adequate water activity (Aw) or nuts, for example.
- The mass thus obtained preferably has an Aw of from 0.1 to 0.5 (water content of from 1 to 7%), and more preferably an Aw of from 0.1 to 0.3 (water content of from 1 to 3%).
- The flowable mass obtained above can be formed into a bar shape by sheet-cutting, sheet-moulding, moulding or pressing through an opening and cutting.
- The ready-to-eat food bar may then be coated with a sweet coating such as a chocolate coating or a coating reminiscent of white chocolate such as a mixture of a milk powder and fat, for example. The bar thus coated can be finally provided with any decorating usual in the confectionary art.
- The ready-to-eat food bar can be conditioned in a packing providing for its protection against humidity, such as a packing made of a film with aluminum foil, or a metallised foil.
- The following example is given as illustration of a preferred embodiment of the ready-to-eat food bar and of the process for its manufacture according to the present invention. This example is not intended in any way to limit the scope of the invention which is defined in the appended claims. The parts and percentages are by weight.
- A ready-to-eat food bar having particles of a cooked-extruded wheat base was manufactured by first preparing, a mixture which had the following composition, (in parts, except added water):
wheat flour 41 wheat starch 18 oat flour 9 wheat bran 9 calcium carbonate 0.5 added water, up to a water content of 19% - In preparing the mixture, the powders were first mixed together to obtain a dry mix. The dry mix and added water were then mixed together in the extruder. The mixture obtained in this way was cooked-extruded-expanded with the aid of a BC-45H type CLEXTRAL twin screw extruder having a screw diameter of 55 mm and a total processing length of 800 mm. Cooking-extruding was carried out at 150° C. under 100 bar for 30 seconds, the two intenneshing screws rotating at 300 rpm. The cooked thermoplastic mass obtained in this way was extruded through a die having eight circular openings of 3 mm in diameter.
- The thermoplastic mass was extruded into ambiant air and immediately cut with a two blade cutter rotating adjacent to the opening at 2000 rpm.
- The particles of cooked-extruded-expanded wheat base obtained in this way expanded after cutting so that they were about 5 mm in diameter. They had a water content of about 10.6%.
- The particles were then dried with hot air on a belt dryer to a residual water content of about 2.9%.
- The dried pieces were coated with a sugar solution in a tumbler.
- The sugar solution comprised about 59% sugar, about 10% dextrose, about 1% oil and about 30% water.
- The amount of sugar solution used was such that the weight proportion of coating on the coated pieces was about 20%. The coated particles were then finally dried down to a residual water content of about 2%.
- A binder was prepared which had the following composition (parts):
skim milk powder 12.5 glucose syrup 9.4 sorbitol syrup 7.2 invert sugar 11.5 condensed sweetened milk (29% 33.5 water, 43% sugar) sodium chloride 0.3 hydrogenated vegetable fat 13.4 (melting point 39° C.) mixture of vegetable mono and diglycerides 0.6 Glycerine 6.7 Water 5.0 - In preparing the binder, the components were mixed together in a double walled tank while being heated to 114° C. until the mixture was concentrated up to a dry matter content of 91%. The binder was then cooled down to a temperature of 75° C.
- 50 parts of particles of a cooked-extruded wheat base and 50 parts of binder were gently mixed by means of a mixer of the helical spring type.
- The mass thus obtained was formed into a bar shape by sheeting down to a thickness of 1 cm and cutting individual bars 3 cm in width and 10 cm in length.
- The bars had a water content of 5.3% and an Aw value of 0.35.
- The bars had a soft texture while retaining the crunchiness of the cooked-extruded-expanded wheat base. They had an appetizing taste and could be eaten as they were. They were nutritionally valuable, each individual bar representing a complete meal just as it was.
- Thus, while we have described what are the preferred embodiments of the present invention, further changes and modifications can be made by those skilled in the art without departing from the true spirit of the invention, and it is intended to include all such changes and modifications as come within the scope of the claims set forth below.
Claims (15)
1. A ready-to-eat food bar comprising agglomerated particles of one or more cooked cereal bases and a binder, the cooked cereal bases comprising amylaceous material and the binder comprising sugars, milk solids, humecants and fat.
2. The ready-to-eat food bar according to claim 1 , wherein the cooked cereal bases further comprise milk solids.
3. The food bar according to claim 1 , comprising, in percent by weight, from about 4% to about 12% of protein, from about 50% to about 80% of available carbohydrate and from about 2.5% to about 25% of fat.
4. The food bar according to claim 1 , comprising, in percent by weight, from about 5.5% to about 27.5% of milk solids nonfat, from about 2.5% to about 25% of milk fat or vegetable fat, from about 30% to about 60% of amylaceous material, from about 5% to about 30% of sugars, from about 2.5% to about 15% of humectants and added water up to a water content from about 1.0% to about 7%.
5. The food bar according to claim 1 , which has an Aw value of from about 0.1 to about 0.5.
6. A process for manufacturing a ready-to-eat food bar, comprising:
preparing a dry mixture of particles of one or more cooked cereal bases, the bases comprising amylaceous materials;
mixing the dry mixture with a binder to form a mass, the binder comprising sugars, milk solids, humectants and fat; and
forming the mass thus obtained into a bar shape.
7. The process according to claim 6 , wherein the cooked cereal bases further comprise milk solids.
8. The process according to claim 6 , whereby the particles of cooked cereal bases are rolled cereals, gun puffed grains, cereal flakes or cooked-extruded cereals.
9. The process according to claim 8 , wherein the cooked-extruded-expanded cereals are prepared by the following steps:
cooking-extruding-expanding at about 120° C. to about 170° C. under from about 40 bar to about 160 bar for about 5 seconds to 50 seconds a mixture comprising, in parts by weight, up to about 27.5 parts of milk solids nonfat, up to about 12.5 parts of milk fat or vegetable fat, from about 50 to about 90 parts of amylaceous material, up to about 12 parts of sugars, and added water up to a water content of from about 11% to about 19% by weight of the mixture;
forming the mixture into a rope of a thermoplastic mass having a porous texture, cutting the rope into pieces; and
optionally drying the pieces.
10. The process according to claim 9 , further comprising coating the dried pieces with a sugar solution and drying the sugar coated pieces.
11. The process according to claim 10 , wherein the sugar solution comprises from about 50% to about 60% sugar, from about 3% to about 10% dextrose, from about 0.5% to about 1.5% oil and from about 10% to 40% water.
12. The process according to claim 6 , wherein the binder comprises, in parts by weight, from about 10 parts to about 70 parts of sugars, from about 5 to 30 parts of humectants, from about 5.5 to about 27.5 parts of milk solids nonfat, from about 10 parts to about 35 parts of milk fat or vegetable fat, up to about 10 parts of cocoa powder, up to about 5 parts of emulsifier and added water up to a water content of from about 5% to about 15%.
13. The process according to claim 6 , wherein the milk solids are incorporated into the binder in form of fresh milk, condensed milk or milk powder.
14. The process according to claim 6 , wherein the binder comprises condensed sweetened milk in an amount of from about 20 to about 45 parts by weight.
15. The process according to claim 6 , wherein the binder is prepared by mixing the components in a double walled tank while heating to a temperature of from about 105° C. to about 117° C., thereby concentrating the mixture up to a dry matter content of from about 80% to 95% and then cooling down to a temperature in a range of from about 33° C. to about 80° C.
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- 2001-04-27 BR BRPI0101673-3B1A patent/BR0101673B1/en not_active IP Right Cessation
- 2001-04-30 PL PL347354A patent/PL199448B1/en unknown
- 2001-04-30 KR KR1020010023539A patent/KR20010100946A/en not_active Abandoned
-
2003
- 2003-03-11 US US10/386,224 patent/US6773734B2/en not_active Expired - Lifetime
-
2009
- 2009-01-21 CY CY20091100079T patent/CY1108723T1/en unknown
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040115313A1 (en) * | 2002-12-13 | 2004-06-17 | Racicot William F. | Food products of reduced density and increased perceived sweetness and process of production |
US7244457B2 (en) * | 2002-12-13 | 2007-07-17 | Quaker Oats Company | Food products of reduced density and increased perceived sweetness and process of production |
US20050153040A1 (en) * | 2004-01-08 | 2005-07-14 | Axelrod Glen S. | Apparatus and process for forming pet treats |
US7288275B2 (en) | 2004-01-08 | 2007-10-30 | T.F.H. Publications, Inc | Apparatus and process for forming pet treats |
US9320292B2 (en) | 2010-04-07 | 2016-04-26 | Kraft Foods Group Brands Llc | Intermediate moisture bar using a dairy-based binder |
US9326538B2 (en) | 2010-04-07 | 2016-05-03 | Kraft Foods Group Brands Llc | Intermediate moisture bar using a dairy-based binder |
US9232807B2 (en) | 2011-09-30 | 2016-01-12 | Kraft Foods Group Brands Llc | Dairy-based foods having high levels of lactose |
US11102998B1 (en) | 2017-08-25 | 2021-08-31 | The Hershey Company | Binders and methods of making and using the same |
Also Published As
Publication number | Publication date |
---|---|
EP1151676B1 (en) | 2008-11-19 |
CA2341125C (en) | 2010-03-09 |
CY1108723T1 (en) | 2014-04-09 |
IL141889A0 (en) | 2002-03-10 |
NZ510790A (en) | 2002-10-25 |
ID30002A (en) | 2001-11-01 |
IL141889A (en) | 2004-01-04 |
US20030157223A1 (en) | 2003-08-21 |
PL347354A1 (en) | 2001-11-05 |
BR0101673A (en) | 2002-01-02 |
JP3494629B2 (en) | 2004-02-09 |
CA2341125A1 (en) | 2001-11-01 |
KR20010100946A (en) | 2001-11-14 |
BR0101673B1 (en) | 2013-12-17 |
SI1151676T1 (en) | 2009-04-30 |
JP2001352927A (en) | 2001-12-25 |
AU783754B2 (en) | 2005-12-01 |
PL199448B1 (en) | 2008-09-30 |
EP1151676A1 (en) | 2001-11-07 |
PT1151676E (en) | 2008-12-12 |
DE60040843D1 (en) | 2009-01-02 |
AU3892701A (en) | 2001-11-08 |
ES2315220T3 (en) | 2009-04-01 |
ATE414427T1 (en) | 2008-12-15 |
MY127268A (en) | 2006-11-30 |
SG100660A1 (en) | 2003-12-26 |
US6773734B2 (en) | 2004-08-10 |
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