US20020030047A1 - Heat treatment apparatus having a thin light-transmitting window - Google Patents
Heat treatment apparatus having a thin light-transmitting window Download PDFInfo
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- US20020030047A1 US20020030047A1 US09/930,495 US93049501A US2002030047A1 US 20020030047 A1 US20020030047 A1 US 20020030047A1 US 93049501 A US93049501 A US 93049501A US 2002030047 A1 US2002030047 A1 US 2002030047A1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B31/00—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor
- C30B31/06—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor by contacting with diffusion material in the gaseous state
- C30B31/12—Heating of the reaction chamber
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/48—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating by irradiation, e.g. photolysis, radiolysis, particle radiation
- C23C16/481—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating by irradiation, e.g. photolysis, radiolysis, particle radiation by radiant heating of the substrate
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/10—Heating of the reaction chamber or the substrate
- C30B25/105—Heating of the reaction chamber or the substrate by irradiation or electric discharge
Definitions
- the present invention generally relates to heat treatment apparatuses and more particularly to a heat treatment apparatus which performs an anneal process or a chemical vapor deposition (CVD) process by heating an object to be processed, such as a single crystalline substrate or a glass substrate, with a lamp and a quartz window used for such a heat treatment apparatus.
- the present invention is suitable for a rapid thermal processing (RTP: Rapid Thermal Processing) used for manufacturing semiconductor devices, such as a memory or an integrated circuit (IC).
- the rapid thermal processing (RTP) includes rapid thermal annealing (RTA), rapid thermal cleaning (RTC), rapid thermal chemical vapor deposition (RTCVD), rapid thermal oxidization (RTO) and rapid thermal nitriding (RTN).
- the heat radiation lamp 14 is arranged so as to opposite to the placement stage 12 with a light-transmitting window 13 formed of a quartz made flat plate.
- the placement stage 12 supports the peripheral edge of the wafer W from a lower part side.
- the wafer W is heated at a predetermined temperature while supplying a process gas from a side wall of one side of the process chamber 11 and exhausting from the side wall of another side.
- a rotation mechanism to rotate the placement stage 12 maintains airtightness of the process chamber 11 by using a magnetic coupling.
- the rotation mechanism is illustratively shown in FIG. 1.
- the lamp light is absorbed by quartz, which reduces the irradiation efficiency to the object to be processed.
- the quartz window may be damaged due to difference in the thermal stress between the front side and back side of the quartz window.
- the lamp is curved similar to the quartz window, a distance between the object to be processed and the lamp is increased, which deteriorates the directivity of the lamp.
- a heat treatment apparatus comprising: a process chamber which defines a process space for processing an object to be processes; a placement stage provided in the process chamber so as to place the object to be processed thereon; a gas supply part which supplies to the process chamber a process gas for processing the object to be processed; a light-transmitting window provided as a part of the process chamber so that the light-transmitting window is opposite to the object to be processed placed on the placement stage; and a heating unit which comprises a heat radiation lamp provided on an opposite side of the process chamber with respect to the light-transmitting window, wherein the light-transmitting window constitutes a convex lens part which is formed on a periphery of the light-transmitting window and protrudes into the process space.
- a heat treatment apparatus comprising: a process chamber in which a heat treatment is applied to an object to be processed; a heat source which heats the objects to be processed by irradiating a radiation light onto the object to be processed; and a quartz window provided between the object to be processed and the heat source, the quartz window comprising: a plate made of quartz; and a lens part fixed to the plate so as to improve a directivity of the radiation light emitted by the heat source and increase a mechanical strength of the plate.
- the heat source may have plurality of lamps, and the lens part may have a plurality of lens elements corresponding to the lamps. Each of the lens element improves the directivity of the radiation light emitted by a respective one of the lamps.
- the lens part may be provided on a surface of the plate facing the object to be processed. The lens part may be provided on both a surface of the plate facing the object to be processed and a surface opposite to the surface facing the object to be processed.
- the plate of the quartz window may have at least one reinforcing member which increases a strength of said plate. Accordingly, the thickness of quartz plate can be further reduced, thereby decreasing an amount radiation light absorbed by the quartz plate.
- the thickness of the plate of the quartz window is preferably equal to or less than 7 mm. More preferably, the thickness of the plate of the quartz window is equal to or less than 5 mm.
- the reinforcing member may made of aluminum.
- a plurality of reinforcing members may be provided on the plate, and at least one waveguiding part made of quartz may be provided between adjacent reinforcing members, the waveguiding part transmitting the radiation light passed through said lens part and said plate toward the object to be processed.
- a total reflection occurs within the waveguiding part.
- FIG. 2 is an illustration showing an arrangement of a single end lamp and a reflector
- FIG. 12 is a cross-sectional view of a curved light-transmitting window along which a plurality of heat radiation lamps are arranged;
- FIG. 13 is a cross-sectional view of a heat treatment apparatus according to a third embodiment of the present invention.
- FIG. 16 is a cross-sectional view of the quartz window taken along a line XVI-XVI of FIG. 14;
- FIG. 19 is an enlarged cross-sectional view of a part of a quartz window which is a variation of the quartz window shown in FIG. 13.
- FIG. 29 is a side view of the lamp shown in FIG. 27;
- FIG. 30 is a plan view of a heating unit which is a variation of the heating unit shown in FIG. 26;
- FIG. 44 is a graph for explaining a method of calculating an effective emissivity according to the present invention.
- FIG. 46 is a graph for explaining a method of calculating an effective emissivity according to the present invention.
- FIG. 47B is an illustration showing a view angle ⁇ of a rod
- FIG. 51 is a cross-sectional view of the heat treatment apparatus shown in FIG. 49 in a state in which the wafer is being cooled;
- FIG. 52 is a cross-sectional view of a helium gas supply part
- a part of a housing 23 which forms the annular groove 21 , extends on the downward side.
- An outer ring part is rotatably supported about the vertical axis on the outside of the housing 23 via a bearing parts having an upper part 42 and a lower part.
- a supply passage 44 of a purge gas such as nitrogen (N 2 ) is formed on an outer portion of the housing 23 which forms the annular groove 21 of the process chamber 2 .
- An end of the supply passage communicates with a position directly above the bearing part 41 in the annular groove 21 .
- a plurality of exhaust passages 45 of the purge gas is formed along a circumferential direction of an inner body part 23 forming the annular groove 21 .
- the purge gas enters the annular groove 21 from a gas supply pipe (not shown in the figure) via the supply passage 44 , and is exhausted from an exhaust pipe (not shown in the figure) via the exhaust passage 45 by passing through an interior of the bearing part 41 .
- a bottom plate 33 constitutes a bottom part of the process chamber 2 under the wafer W.
- a temperature detecting means 25 is inserted into the bottom plate 33 .
- the temperature detecting means 25 comprises, for example, a plurality of radiation thermometers for measuring a temperature of the wafer W from the backside.
- the radiation thermometers are arranged along a radial direction of the wafer W so that temperatures of a plurality of positions on the wafer W from the center to the peripheral edge can be measured.
- the bottom plate 33 is provided with lift pins (not shown in the figure) which lifts the wafer W when the wafer is transferred to or from a conveyance arm provided outside the process chamber 2 .
- the heating unit 5 is larger than the wafer W.
- the heating unit 5 comprises a plurality of heat radiation lamps 51 and a reflective plate 52 .
- the heat radiation lamps 51 constitute heating means for heating the wafer W by irradiating lights onto the wafer W.
- the reflective plate 52 has a circular cross section, and is provided so as to encircle a surface of each lamp 51 opposite to the wafer W.
- a power supply system of the heat radiation lamps 52 is accommodated in a housing 53 .
- halogen lamps are used as the heat radiation lamps 51 .
- the halogen lamps are concentrically arranged with the center being aligned with the center of the wafer W so that a plurality of generally annular light-emitting areas having different radii are formed.
- the process chamber 110 is formed of stainless steel or aluminum.
- the quartz window 120 is connected to a top of the process chamber 110 .
- the side wall of the process chamber 110 and the quartz window 12 define a process space in which an object W to be processed (semiconductor wafer: hereinafter referred to as a wafer W) is subjected to a heat treatment.
- the support ring 150 on which the wafer W is placed and a support part 152 connected to the support ring 150 are arranged in the process space.
- the process space is maintained to be a predetermined negative pressure by the exhaust part 190 .
- the wafer W is carried in or out from the process chamber through a gate valve (not shown in the figure) provided to the sidewall of the process chamber 110 .
- the quartz window 120 is attached to the process chamber in an airtight manner so as to maintain the negative pressure environment inside the process chamber 110 and transmit a heat radiation light emitted from lamps of the heating unit 140 .
- the lens assembly 122 serves to strengthen the quartz window 120 and increase the directivity of the radiation light form the lamps of the heating unit 140 .
- each of the lens assemblies 122 has a plurality of lens elements 123 ach having a light converging action.
- the lens assemblies 122 are arranged parallel to the direction X since the lamps of the heating unit 140 are arranged in the direction X. That is, the direction of arrangement of the lens assemblies 122 is dependent on the direction of arrangement of the lamps of the heating unit 140 .
- the window lens assemblies 122 are provided only on one side of the quartz plate 121 which side is opposite to the lamps 130 of the heating unit 140 , the window lens assemblies 122 may be provided on both sides or on the other side which is not opposite to the lamps 130 .
- the quartz plate 121 Since the strength with respect to thermal deformation of the quartz plate 121 is increased by the lens assemblies 122 , there is no need to form the quartz plate 121 in a domal shape which curves in a direction protruding from the process chamber 110 as in the conventional apparatus. Accordingly, the quartz plate 121 has a flat shape. Since the quartz window formed in a domal shape increases a distance between the wafer W and the lamps 130 of the heating unit 140 , there is a problem in that the directivity of the lamps is deteriorated. The present embodiment solves such a problem relating to the directivity of the lamps. Although the quartz plate 121 and the lens assemblies 122 are joined by welding in the present embodiment, the quartz plate 121 and the lens assemblies 122 may be joined by other methods or integrally formed with each other.
- the present embodiment solves the problem in that the lamp light is absorbed by the quartz window which results in deterioration of the irradiation efficiency.
- the quartz window is prevented from being damaged due to a difference in temperature between the front surface and the back surface of the quartz window 121 since the difference can be maintained smaller than that of the conventional quartz window. That is, the present embodiment solves the problem in that the conventional quartz window is easily destroyed due to a difference in the thermal stress between the front surface facing the lamps and the back surface opposite to the front surface when a rapid thermal process is performed as in a rapid thermal process (RTP) apparatus.
- RTP rapid thermal process
- the quartz window 120 solely constituted by the quartz plate, which does not have the lens assemblies 122 , may reduce an amount of light absorbed by the quartz plate 121 when the thickness of the quartz plate 121 is small as in the present embodiment, it is possible that the quartz window 120 is easily destroyed since the quartz plate 120 cannot withstand a pressure difference between the negative pressure in the process chamber and the atmospheric pressure. Accordingly, there is a problem in that the quartz window cannot be used with a process which must be performed under a negative pressure environment.
- the lens assemblies solve such a problem since the lens assemblies 122 reinforces the quartz plate 121 .
- FIG. 19 is an enlarged cross-sectional view of a part of the quartz window 120 A.
- the quartz window 120 A has reinforcing members (or columns) 124 , which are formed under the passage 128 and parallel to the passage 128 .
- Each of the reinforcing members 124 is made of aluminum or stainless steel, and has a square cross section.
- the reinforcing members 124 have cooling pipes 125 therein, and increase a strength of the quartz window 120 A.
- the radiation light from the lamps 130 is reflected by sidewalls of reinforcing members 124 , and reaches the wafer W placed under the quartz window.
- the cooling pipe 125 has a cooling function which cools both the reinforcing members 124 and the quartz plate 121 . If the reinforcing members 124 are made of aluminum, an appropriate temperature control (cooling) is needed since the aluminum may be deformed or melted at a temperature in the range of 200° C. to 700° C.
- the temperature control by the cooling pipe 125 may be the same as the cooling pipe 116 , or other known methods may be applied.
- the irradiance is maximum near the center of the wafer W, but the maximum value is not so large.
- the half value width forms a generally oblong shape, and the maximum of the half value with is about 100 mm.
- the directivity is improved as the maximum value is increased.
- the controllability of the half value width can be improved as it approaches a circle and its value is decreased.
- the controllability represents easiness of process when it is needed to heat a desired position of the wafer W (that is, irradiate the radiation light) and heat if not applied to a position where it is not desired to heat. Comparing FIGS. 21 and 22 with FIGS. 24 and 25, it can be appreciated that the quartz window 120 B is superior to the quartz window 120 C in both directivity and controllability.
- Each separation wall 144 has a width of about 12 mm, and is located above the passage 128 shown in FIG. 14 and the reinforcing member 124 shown in FIG. 19 and between the adjacent grooves 143 arranged in the direction X shown in FIG. 26.
- a pair of cooling pipes 145 arranged in parallel to the passage 128 (in the direction X shown in FIG. 26) are put in contact with the separation walls 144 .
- About 0.3 to 0.8 m 3 of air can flow through the groove 143 excluding the light emitting part 134 so as to cool the surface of the light-emitting part 134 .
- the lamps 130 of the present embodiment can be cooled by the air cooing arrangement and the cooling pipes 145 .
- FIG. 32 is a cross-sectional view for explaining the cooling arrangement of the lamps 130 arranged in the direction X in FIG. 26.
- FIG. 33 is a side view of the lamp 130 shown in FIG. 32.
- FIG. 34 is a plan view of the lamp 130 shown in FIG. 32.
- the plurality of lamps 130 arranged in the same row are subjected to heat exhaust (air cooling) by a blower.
- the exhaust efficiency by the blower is as good as 4 m 3 /min with respect to that achieved by a rectilinear arrangement of the lamps.
- the plated part 149 if formed of a metal film such as a gold film or silver film which reflects a radiation light at a high reflectance.
- the plated part 149 may be formed by electroplating such as hard gold plating or pure gold plating.
- the thickness of the plated part 149 can be about 10 ⁇ m so as to sufficiently prevent light leakage from the light-emitting part 134 . It should be noted that the plated part 149 is provided for improving the directivity, and there is no specific range of high-reflectivity of the plated part 149 .
- each lens arranged directly under the respective one of the lamps 130 A has a length corresponding to the light-emitting part 136 shown in FIG. 40 and a width which covers a pair of lamps 130 A shown in FIG. 41.
- the horizontal part 137 b is concentrically arranged with the dashed circles shown in FIG. 26.
- the dashed circle shown in FIG. 38 is concentric with the dashed circles shown in FIG. 26.
- the length of the horizontal part 137 b is determined by a length of a circle which is concentric with the dashed circles shown in FIG. 14 and a number of lamps 130 B arranged along the circle.
- the radii of the horizontal parts 137 b of the lams 130 B arranged along different concentric circles differ from each other.
- the plurality of lamps 130 can be mounted at a high density.
- the lamps can be arranged can be mounted at a lamp density which is four times the lamp density of the arrangement having a reflector inclined by 45 degrees. Accordingly, the power density can be increased and, therefore, the heat treatment apparatus is suitable for RTP.
- the radiation thermometers 200 A, 200 B and 200 C are provided on the opposite side of the lamps 130 with respect to the wafer W. Although the present invention does not exclude the structure in which the radiation thermometers 200 A, 200 B and 200 C is provided on the same side with the lamps 130 , it is preferable that the radiation light of the lamps 130 is prevented from being incident on the radiation thermometers 200 A, 200 B and 200 C.
- the radiation thermometers 200 A and 200 B are mounted on a bottom part 114 of the process chamber 110 . More specifically, the radiation thermometers 200 A and 200 B are inserted into respective cylindrical through holes 115 a and 115 b of the bottom part 114 .
- a surface 114 a of the bottom part 114 facing the interior of the process chamber 110 serves as a reflective plate (high-reflectance surface) by being subjected to a sufficient polishing. This is because if the surface 114 a is a low reflectance surface such as a black surface, the surface 114 a absorbs heat of the wafer W, which results in an undesired increase in the output of the lamps 130 .
- Each of the optical fibers 220 A and 220 B comprises a core which transmits a light and a concentric clad which covers the core.
- the core and the clad are made of a transparent dielectric material such as glass or plastic.
- the refractive index of the clad is slightly smaller than that of the core, thereby achieving a total reflection.
- the core can propagate a light without leaking outside.
- the radiation thermometers 200 A and 200 B use a core and clad of different materials.
- the photodiode (PD) 230 has an image forming lens, a silicon (Si) photocell and an amplification circuit so as to convert the radiation light incident on the image forming lens into a voltage, which is an electric signal representing radiation intensities E 1 (T) and E 2 (T), and send the electric signal to the control part 300 .
- the control part 300 comprises a CPU, an MPU, other processors, and memories such as a RAM and a ROM so as to calculate an emissivity ⁇ and a substrate temperature T of the wafer W based on the radiation intensities E 1 (T) and E 2 (T).
- a prediction equation which can establish the above-mentioned four conditions can be defined as the following equation (8).
- the radiation thermometer 200 performs the conversion of temperature based on radiation light flux (W).
- W radiation light flux
- equation (17) can be changed into the following equation (18).
- ⁇ eff 02 (1 ⁇ 0.2 ) ⁇ + ⁇ 0.2 ⁇ /[1 ⁇ F ⁇ r ⁇ (1 ⁇ )] (26)
- the above-mentioned calculation method obtains an emissivity of the wafer W by the two radiation thermometers 200 A and 200 B having different NAs, the emissivity can be obtained based on the above-mentioned equation (9) by changing a ratio of D 1 /D 2 .
- FIG. 43 is an illustration for explaining such a method.
- the process gas includes N 2 , Ar, etc.; if the process is an oxidation process, the process gas includes O 2 , H 2 , H 2 O, NO 2 , etc.; if the process is a nitriding process, the process gas includes N 2 , NH 3 , etc.; if the process is a film deposition process, the process gas includes NH 3 , SiH2, Cl 2 , SiH 4 , etc. It should be noted that the process gas is not limited the above-mentioned gasses.
- the inner surface of the supply pipe may be coated by an insulating material such as PTFE (Teflon), PPA, polyimide, PBI, etc. Additionally, the inner surface of the supply pipe may be subjected to an electropolishing. Further, a dust particle filter may be provided to the gas supply passage.
- the present invention is applicable to a relative movement of the wafer W and the lamps 130 .
- the rotating mechanism of the wafer W comprises the support ring 150 , the permanent magnet 170 , a ring-like magnetic member 172 , a motor driver 320 and a motor 330 .
- the support ring 150 has a ring shape and is made of a heat resistant ceramic such as SiC.
- the support ring 150 serves as a placement stage on which the wafer W is placed.
- the support ring 150 supports a periphery of the backside of the wafer W. If necessary, the support ring 150 may be provided with an electrostatic chuck or a clamp mechanism so as to fix the wafer to the support ring 150 .
- the support ring 150 is configured and arranged to prevent heat form being released from an outer edge of the wafer W so that the uniform heating of the wafer W is not deteriorated.
- the controller controls the lamp driver 310 so as to send an instruction to drive the lamps 130 .
- the lamp driver 310 drives the lamps 130 so that the lamps 130 heat the wafer W at a temperature of about 800° C.
- the heat treatment apparatus 100 improves the directivity of the lamps 130 by the action of the lens assemblies 122 and the plated part 149 while removing the reflector, and, thereby, increasing the lamp density and consequently the power density.
- a desired high rate temperature rise of the wafer W can be achieved.
- a heat ray (radiation light) emitted by the lamps 130 is irradiated onto the surface of the wafer W by passing through the quartz window 120 so as to heat the wafer W at 800° C. with a heating rate of about 200° C./sec.
- the present embodiment can provide a high directivity and temperature control capability since the lamps 130 according to the present invention are concentrically so as to enable a power control for each area.
- the apparatus 100 uses the structure shown in FIG. 43, the bottom part 114 A is located at the home position as shown in FIG. 50.
- the structure shown in FIG. 50 can provide an efficient rapid temperature rise since the wafer W hardly receives influence from the bottom part 114 a due to a large distance between the wafer W and the bottom part 114 A as a cooling plate.
- the exhaust part 190 forms a negative pressure environment in the process chamber 110 at or around the time of heating the wafer W.
- the quartz window 120 has a relatively small thickness due to the action of the lens assemblies 122 , the reinforcing members 124 and the waveguiding members 126 , which provides the following advantages with respect to the heating process of the wafer W.
- the radiation thermometer 200 has a simple structure in which a chopper and an LED is not used, the radiation thermometer is inexpensive, which contributes to miniaturization and economization of the heat treatment apparatus 100 . Additionally, the temperature measured by the method of calculating effective emissivity is accurate. An electric characteristic of an integrated circuit formed in the wafer W is deteriorated due to diffusion of impurities when the wafer W is placed under a high-temperature environment for a long time. Accordingly, a rapid heating and a rapid cooling are required, which also requires a temperature control of the wafer W. The method of calculating effective emissivity according to the preset invention satisfies such requirements. Thus, the RTP apparatus 100 can provide a high-quality heat treatment.
- a process gas is introduced into the process chamber 110 through the gas introducing part (not shown in the figure).
- the controller 300 controls the lamp driver 310 so as to stop the heating by the lamps 130 . Then, the lamp driver stops to supply a power to the lamps 130 .
- the controller 300 controls the vertical moving mechanism 117 so move the bottom part 114 A to a cooling position. Additionally, helium gas having a high heat conductivity is supplied between the wafer W and the bottom part 114 A as shown in FIG. 46. Thereby, the cooling efficiency to the wafer W is increased, and a rapid cooling can be achieved with a relatively small power consumption.
- the cooling rate achieved by the apparatus 100 is about 200° C./sec.
- the wafer W is carried out of the process chamber 110 by the conveyance arm of the cluster tool through the gate valve in the reverse sequence. Thereafter, if necessary, the conveyance arm conveys the wafer W to a next stage apparatus such as a film deposition apparatus.
- a next stage apparatus such as a film deposition apparatus.
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Abstract
Description
- 1. Field of the Invention
- The present invention generally relates to heat treatment apparatuses and more particularly to a heat treatment apparatus which performs an anneal process or a chemical vapor deposition (CVD) process by heating an object to be processed, such as a single crystalline substrate or a glass substrate, with a lamp and a quartz window used for such a heat treatment apparatus. The present invention is suitable for a rapid thermal processing (RTP: Rapid Thermal Processing) used for manufacturing semiconductor devices, such as a memory or an integrated circuit (IC). The rapid thermal processing (RTP) includes rapid thermal annealing (RTA), rapid thermal cleaning (RTC), rapid thermal chemical vapor deposition (RTCVD), rapid thermal oxidization (RTO) and rapid thermal nitriding (RTN).
- 2. Description of Related Art
- There is a single wafer heat treatment apparatus as one of semiconductor manufacturing apparatuses, which performs an annealing process or a CVD process by heating a semiconductor wafer (hereinafter simply referred to as a wafer) with a heat radiation lamp.
- FIG. 1 shows an example of a conventional heat treatment apparatus. The heat treatment apparatus shown in FIG. 1 comprises a
process chamber 11, aplacement stage 12 on which a wafer W is placed and aheat radiation lamp 14. Theplacement stage 12 having a ring-like shape is provided in theprocess chamber 11, and is rotatable about the vertical axis thereof. - The
heat radiation lamp 14 is arranged so as to opposite to theplacement stage 12 with a light-transmittingwindow 13 formed of a quartz made flat plate. Theplacement stage 12 supports the peripheral edge of the wafer W from a lower part side. The wafer W is heated at a predetermined temperature while supplying a process gas from a side wall of one side of theprocess chamber 11 and exhausting from the side wall of another side. It should be noted that a rotation mechanism to rotate theplacement stage 12 maintains airtightness of theprocess chamber 11 by using a magnetic coupling. The rotation mechanism is illustratively shown in FIG. 1. - The
placement stage 12 is formed of a material having a superior heat-resistance so that theplacement stage 12 is not transformed at a processing temperature of about 1000° C. SiC (silicon carbide) is used as such a material. - In the above-mentioned heat treatment apparatus, both the
placement stage 12 and the wafer W are heated with theheat radiation lamp 14 from an upper part side. When theplacement stage 12 is formed by SiC, the temperature rise of theplacement stage 12 is slower than that of the wafer W since the heat capacity of SiC is larger than Si (silicone) which forms the wafer W. - For this reason, at the time of heating the wafer W, the temperature of the
placement stage 12 is lower than the temperature of the wafer W. Therefore, heat of the circumferential edge of the wafer W transmits to theplacement stage 12, and, thus, the temperature of the circumferential edge of the wafer W becomes lower than the temperature of the central part thereof. Consequently, a temperature distribution is generated in the surface of the wafer W. - On the other hand, heating of the wafer W at a temperature higher than about 800° C. generates a crystal defect referred to as a slip in the wafer W. The slip is easily generated as a temperature difference within the surface of the wafer W increases.
- Therefore, in the conventional equipment, the wafer W cannot be heated at a high rate so that a delay in raising the temperature of the
placement stage 12 does not become large, that is, the temperature difference within the surface of the wafer W is maintained small. This is one of causes that prevents improvement in a throughput. As for measures to solve the problem, it can be considered to increase an amount of heat radiation on the side of the periphery of the wafer W, such a method is difficult to realize since it is difficult to increase directivity of theheat radiation lamp 14 due to its construction. - Irradiation areas corresponding to a plurality of
heat radiation lamps 14 are formed on the wafer W. A distance between theheat radiation lamp 14 and the wafer W cannot be made small from the point such as reservation of a conveyance area. For this reason, the directivity of eachheat radiation lamp 14 is bad. Specifically, the directivity of a unit which is formed by combining a single heat radiation lamp and a reflector is bad. That is, a plurality of irradiation areas overlap with each other and the overlapping area between the irradiation areas is large since each above-mentioned irradiation domain spreads. - A plurality of probes of the radiation thermometer (not shown) is arranged at a plurality of positions, respectively, underneath the wafer W. The magnitude of heat dissipation from the wafer W differ from the position at which the probe of the radiation thermometer is arranged to position at which the probe is not arranged. Therefore, in order to heat the wafer W uniformly over the whole surface, it is necessary to adjust the illumination distribution by the light (radiation heat) from the
lamp 14 on the wafer W. However, if the above-mentioned overlapping area between the irradiation areas is large, adjustment of an illumination distribution is difficult. - Additionally, in order to manufacture a semiconductor integrated circuit, various kinds of heat treatment, such as a film deposition process, an anneal process, an oxidization diffusion process, a sputtering process, an etching process and a nitriding processing may be repeatedly performed on a silicon wafer a plurality of times to silicone boards. Since yield rate and quality of semiconductor manufacturing processes can be improved, the RTP technology to rise and drop the temperature of the wafer (object to he processed) has attracted attention. A conventional RTP apparatus generally comprises: a single-wafer chamber (process chamber) for accommodating an object to be processed (for example, a semiconductor wafer, a glass substrate for photograph masks, a glass substrate for a liquid-crystal display or a substrate for optical discs); a reflector (reflective board) arranged at the opposite side of the object to be processed with respect to a quartz window arranged in the interior of the process chamber; and a heating lamp (for example, halogen lamp) arranged at an upper part or above the quartz window, and the lamp.
- The reflector is made of aluminum, and gold plating is given to a reflective part thereof. A cooling mechanism such as a cooling pipe is provided so as to prevent temperature breakage of the reflector (for example, exfoliation of gold plating due to a high temperature). The cooling mechanism is provided so as to prevent the reflector from being an obstacle of cooling the object to be processed at the time of cooling. The rapid temperature rising demanded for the RTP technology is dependent on the directivity of the optical irradiation to the object to be processed and the power density of the lamp.
- FIG. 2 is an illustration showing an arrangement of a single end lamp and a reflector. As shown in FIG. 2, the directivity with respect to the object to be processed arranged underneath the
single end lamp 15 having only oneelectrode part 16 and the energy efficiency of thelamp 15 is maximum when a degree of an angle a of inclination of thereflector 17 relative to thelamp 15 is set to 45 degrees. - The quartz window may be in the shape of a board, or can be in the form of tube which can accommodate the object to be processed. When maintaining a negative pressure environment in the process chamber by evacuating gasses in the process chamber by a vacuum pump, a thickness of the quartz window is set to, for example, about 30 to 40 mm so as to maintain the pressure difference between the internal pressure and the atmospheric pressure. The quartz window may be formed in a curved shape having a reduced thickness so as to prevent generation of a thermal stress due to temperature difference generated by a temperature rise.
- A plurality of halogen lamps are arranged so as to uniformly heat the object to be processed. The reflector reflects the infrared rays irradiated from the halogen lamps toward the object to be processed. The process chamber is typically provided with a gate valve on a sidewall thereof so as to carry in and out the object to be processed. Moreover, a gas supply nozzle, which introduces a process gas used for heat treatment, is connected to the sidewall of the process chamber.
- The temperature of the object to be processed affects the quality of process such as, for example, a thickness of a film in a film deposition process, etc. For this reason, it is necessary to know the correct temperature of the object to be processed. In order to attain high-speed heating and high-speed cooling, a temperature measuring device which measures the temperature of the object to be processed is provided in the process chamber. The temperature measuring device may be constituted by a thermocouple. However, since it is necessary to bring the thermocouple into contact with the object to be processed, there is a possibility that the processed body is polluted with the metal which constitutes the thermocouple. Therefore, there is proposed a payro meter as a temperature measuring device which detects an infrared intensity emitted and computes a temperature of an object to be processed from the back side thereof based on the detected infrared intensity. The payro meter computes the temperature of the object to be processed by carrying out a temperature conversion by an emissivity of the object to be processed according to the following expression:
- Em(T)=εEBB(T) (1)
- where, EBB(T) expresses a radiation intensity from a black body having the temperature T; Em(T) expresses a radiation intensity measured from the object to be processed having the temperature T; ε epsilon expresses a rate of radiation of the object to be processed.
- In operation, the object to be processed is introduced into the process chamber through the gate valve. The peripheral portion of the object to be processed is supported by a holder. At the time of heat treatment, process gases such as nitrogen gas and oxygen gas, are introduced into the process chamber through the gas supply nozzle. On the other hand, the infrared ray irradiated from the halogen lamps is absorbed by the object to be processed, thereby, rising the temperature of the object to be processed. However, the thickness of the conventional quartz window is as thick as several 10 mm. For this reason, there are the following problems.
- First, the lamp light is absorbed by quartz, which reduces the irradiation efficiency to the object to be processed. Second, since a difference in temperature arises between a lamp side and its opposite side at the time of rapid temperature rising such as in RTP, the quartz window may be damaged due to difference in the thermal stress between the front side and back side of the quartz window. Third, if the lamp is curved similar to the quartz window, a distance between the object to be processed and the lamp is increased, which deteriorates the directivity of the lamp. Fourth, when the temperature of the quartz window rises, a deposition film or a byproduct may be formed on the surface of the quartz window especially when a film deposition process is performed, and, thus, a temperature repeatability cannot be maintained and the number of cleaning operations applied to a process chamber is increased.
- On the other hand, absorption of the lamp light by the quartz window can be decreased by decreasing its thickness. However, if the thickness of the quartz window decreases, the quartz window cannot withstand the pressure difference between the negative pressure inside the process chamber and an atmospheric pressure and the quartz window may easily be destroyed. Thus, there is a problem in that the quartz window having a reduced thickness cannot be used for a process chamber which forms a negative pressure therein. Further, since the radiation light form a heat source is introduced into the object to be processed while being diffused, the directivity of the radiation light is not sufficient, and there is a demand for improving the directivity.
- It is a general object of the present invention to provide an improved and useful quartz window and heat treatment apparatus in which the above-mentioned problems are solved.
- A more specific object of the present invention is to provide a quartz window which can decrease an amount of absorption of heat from a heat source while maintaining a pressure difference between the pressure inside a process chamber and an atmospheric pressure.
- Another object of the present invention is to heat an object to be processed with heat radiation lamps with less temperature difference within an entire surface of an object to be processed.
- A further object of the present invention is to improve a directivity of a heat radiation lamp so as to achieve easy adjustment of the illumination distribution on the object to be processed.
- In order to achieve the above-mentioned objects, there is provided according to one aspect of the present invention a heat treatment apparatus comprising: a process chamber which defines a process space for processing an object to be processes; a placement stage provided in the process chamber so as to place the object to be processed thereon; a gas supply part which supplies to the process chamber a process gas for processing the object to be processed; a light-transmitting window provided as a part of the process chamber so that the light-transmitting window is opposite to the object to be processed placed on the placement stage; and a heating unit which comprises a heat radiation lamp provided on an opposite side of the process chamber with respect to the light-transmitting window, wherein the light-transmitting window constitutes a convex lens part which is formed on a periphery of the light-transmitting window and protrudes into the process space.
- According to the present invention, a light traveling from the heat radiation lamp toward outside of the object to be processed is deflected toward inside by the convex lens part. Thus, heat radiation energy emitted by the heat radiation lamp can be efficiently used. Additionally, if a temperature rising rate is increased when heating the object to be processed, uniformity within the surface of the object to be processed can be maintained high. In a case in which the object to be processed is a silicon wafer, generation of a slip, which is a crystal defect, can be prevented.
- In the heat treatment apparatus according to the present invention, the placement stage may support a periphery of the object to be processed. Additionally, the placement stage may have a heat capacity greater than that of the object to be processed. In one embodiment, the object to be processed may be a silicon wafer and said placement stage is made of silicon carbide. The heat radiation lamp may be located at a focal point of the convex lens part. Further, the placement stage may be rotatable relative to the heat radiation lamp about a vertical axis thereof.
- Additionally, there is provided according to another aspect of the present invention a heat treatment apparatus comprising: a process chamber which defines a process space for processing an object to be processes; a placement stage provided in the process chamber so as to place the object to be processed thereon; a gas supply part which supplies to the process chamber a process gas for processing the object to be processed; a light-transmitting window provided as a part of said process chamber so that the light-transmitting window is opposite to the object to be processed placed on the placement stage; and a heating unit which comprises a plurality of heat radiation lamps provided on an opposite side of the process chamber with respect to the light-transmitting window, wherein the light-transmitting window constitutes a plurality of convex lens parts each of which corresponds to a respective one of the heat radiation lamps and protrudes into the process space.
- According to this invention, since the irradiation area of each of the heat radiation lamps is narrowed by the convex lens part, the directivity of the heat radiation lamps is improved, and easy adjustment of the luminescence distribution on the object to be processed is achieved.
- In the above mentioned heat treatment apparatus according to the present invention, each of the heat radiation lamps may be located at a focal point of a respective one of the convex lens parts. Additionally, the placement stage may be rotatable relative to the heat radiation lamps about a vertical axis thereof. In one embodiment of the present invention, each of the heat radiation lamps may has an arc shape, and the heat radiation lamps may be concentrically arranged in the heating unit. In another embodiment, each of the heat radiation lamps may be a single end type, and the heat radiation lamps may be provided in the heating unit in an island arrangement. In still another embodiment, each of the heat radiation lamps may have a rectilinear shape, and the heat radiation lamps may be arranged parallel to each other in the heating unit.
- Additionally, there is provided according to another aspect of the present invention a heat treatment apparatus comprising: a process chamber in which a heat treatment is applied to an object to be processed; a heat source which heats the objects to be processed by irradiating a radiation light onto the object to be processed; and a quartz window provided between the object to be processed and the heat source, the quartz window comprising: a plate made of quartz; and a lens part fixed to the plate so as to improve a directivity of the radiation light emitted by the heat source and increase a mechanical strength of the plate.
- According to the above-mentioned invention, the quartz window has a reduced thickness with a sufficient strength since the lens part reinforces the plate. Accordingly, an amount of heat from the heat source absorbed by quartz window can be reduced. Additionally, since the lens part converges the radiation light emitted from the heat source, the directivity of the radiation light irradiated onto the object to be processed is improved. The heat treatment apparatus having the quarts window according to the present invention is suitable for a heat treatment performed under a negative pressure environment in which a load due to a pressure difference is applied to the quartz window.
- In the heat treatment apparatus according to the present invention, the heat source may have plurality of lamps, and the lens part may have a plurality of lens elements corresponding to the lamps. Each of the lens element improves the directivity of the radiation light emitted by a respective one of the lamps. Additionally, the lens part may be provided on a surface of the plate facing the object to be processed. The lens part may be provided on both a surface of the plate facing the object to be processed and a surface opposite to the surface facing the object to be processed.
- Additionally, the plate of the quartz window may have at least one reinforcing member which increases a strength of said plate. Accordingly, the thickness of quartz plate can be further reduced, thereby decreasing an amount radiation light absorbed by the quartz plate. The thickness of the plate of the quartz window is preferably equal to or less than 7 mm. More preferably, the thickness of the plate of the quartz window is equal to or less than 5 mm. The reinforcing member may made of aluminum.
- Additionally, the heat treatment apparatus according to the present invention may further comprise a cooling arrangement which cools said reinforcing member so as to prevent the reinforcing member and the plate from being thermally deformed. The lens part may be provided on a first surface of the plate, and at least one reinforcing member may be provided on a second surface of said plate opposite to the first surface so as to increase a strength of the plate.
- Further, a plurality of reinforcing members may be provided on the plate, and at least one waveguiding part made of quartz may be provided between adjacent reinforcing members, the waveguiding part transmitting the radiation light passed through said lens part and said plate toward the object to be processed. According to the difference in refraction index between quartz and air or vacuum, a total reflection occurs within the waveguiding part. Thus, the radiation light can be efficiently directed toward the object to be processed by being passed through the waveguiding part.
- Additionally, the heat treatment apparatus according to the present invention may further comprise an exhaust device connected to the process chamber so as to maintain a negative pressure inside said process chamber.
- Additionally, there is provided according to another aspect of the present invention a quartz window configured to be incorporated into a heat treatment apparatus which applies a heat treatment to an object to be processed by a radiation light emitted by a heat source, the quartz window being arranged between the object to be processed and the heat source, the quartz window comprising: a plate made of quartz; and a lens part fixed to said plate so as to converge the radiation light emitted by the heat source toward the object to be processed and increase a mechanical strength of the plate.
- Other objects, features and advantages of the present invention will become more apparent from the following detailed description when read in conjunction with the accompanying drawings.
- FIG. 1 is a cross-sectional view of a conventional heat treatment apparatus;
- FIG. 2 is an illustration showing an arrangement of a single end lamp and a reflector;
- FIG. 3 is a cross-sectional view of a heat treatment apparatus according to a first embodiment of the present invention;
- FIG. 4 is a plan view of a reflective plate viewed from a side of a wafer;
- FIG. 5 is an cross-sectional view of a part of a heating unit shown in FIG. 3 for explaining an action of a convex lens part provided in a light-emitting window;
- FIG. 6 is a cross-sectional view of a heat treatment apparatus according to a second embodiment of the present invention;
- FIG. 7 is a cross-sectional view of a part of a heating unit and a light-transmitting window shown in FIG. 6 for explaining an optical path of a light emitted from a lamp;.
- FIG. 8 is a cross-sectional view of a variation of the light-transmitting window shown in FIG. 3;
- FIG. 9 is a cross-sectional view of a variation of the light-transmitting window shown in FIG. 6;
- FIG. 10 is a perspective view of a light-transmitting window corresponding to a plurality of straight double end lamps;
- FIG. 11A is a plan view of a heating unit having a plurality of single end lamps; FIG. 11B is a cross-sectional view of a part of the heating unit shown in FIG. 11A in which the single end lamps are accommodated in circular concave portions formed in a reflective plate; FIG. 11C is a perspective view of a light-transmitting plate having a plurality of convex lens parts which are formed in positions corresponding to the single end lamps shown in FIG. 11A;
- FIG. 12 is a cross-sectional view of a curved light-transmitting window along which a plurality of heat radiation lamps are arranged;
- FIG. 13 is a cross-sectional view of a heat treatment apparatus according to a third embodiment of the present invention;
- FIG. 14 is a plan view of the quartz window shown in FIG. 13;
- FIG. 15 is a cross-sectional view of the quartz window taken along a line XV-XV of FIG. 14;
- FIG. 16 is a cross-sectional view of the quartz window taken along a line XVI-XVI of FIG. 14;
- FIG. 17 is an enlarged cross-sectional view of a part of the quartz window shown in FIG. 16;
- FIG. 18 is an enlarged perspective view of a part of a lens assembly used in the quartz window;
- FIG. 19 is an enlarged cross-sectional view of a part of a quartz window which is a variation of the quartz window shown in FIG. 13.
- FIG. 20 is an enlarged cross-sectional view of a quartz window which is another variation of the quartz window shown in FIG. 13;
- FIG. 21 is a graphic illustration showing a directivity achieved by the quartz window shown in FIG. 20;
- FIG. 22 is a graphic illustration of the directivity shown in FIG. 21 viewed from above;
- FIG. 23 is a side view of a part of a quartz window having reinforcing members;
- FIG. 24 is a graphic illustration showing a directivity achieved by the quartz window shown in FIG. 23;
- FIG. 25 is a graphic illustration of the directivity shown in FIG. 24 viewed from above;
- FIG. 26 is a bottom view of a heating unit shown in FIG. 13;
- FIG. 27 is a partial cross-sectional view of the heating unit shown in FIG. 13;
- FIG. 28 is a front view of a lamp shown in FIG. 27;
- FIG. 29 is a side view of the lamp shown in FIG. 27;
- FIG. 30 is a plan view of a heating unit which is a variation of the heating unit shown in FIG. 26;
- FIG. 31 is a partially cross-sectional view of the heating unit shown in FIG. 30;
- FIG. 32 is a cross-sectional view for explaining a cooling arrangement of the lamps.
- FIG. 33 is a side view of the lamp shown in FIG. 32;
- FIG. 34 is a plan view of the lamp shown in FIG. 32;
- FIG. 35 is a graphic illustrations showing the directivity achieved by a lamp having a plated
part 149 formed of a gold plate film; - FIG. 36 is a graphic illustration of the directivity shown in FIG. 35 viewed from above;
- FIG. 37 is a perspective view of a double end type lamp from which a plated part is removed;
- FIG. 38 is a perspective view of another double end type lamp from which a plated part is removed;
- FIG. 39 is a cross-sectional view for explaining the plated parts applied to the lamps shown in FIGS. 37 and 38;
- FIG. 40 is a cross-sectional view of a heating unit having the lamps taken along the direction X in FIG.26;
- FIG. 41 is a cross-sectional view of the heating unit shown in FIG. 40 taken along the direction Y in FIG. 26;
- FIG. 42 is a cross-sectional view showing two kinds of radiation thermometers;
- FIG. 43 is a cross-sectional view showing two radiation thermometers of the same kind;
- FIG. 44 is a graph for explaining a method of calculating an effective emissivity according to the present invention;
- FIG. 45 is a graph for explaining a method of calculating an effective emissivity according to the present invention;
- FIG. 46 is a graph for explaining a method of calculating an effective emissivity according to the present invention;
- FIG. 47A is an illustration showing an incident angle θ of a radiation light to an optical fiber;
- FIG. 47B is an illustration showing a view angle γ of a rod;
- FIG. 48 is a graph showing a result of simulation with respect to a cooling rate of the wafer.
- FIG. 49 is a cross-sectional view of the heat treatment apparatus shown in FIG. 13, which is provided with a variation of a bottom part;
- FIG. 50 is a cross-sectional view of the heat treatment apparatus shown in FIG. 49 in a state in which the wafer is being heated;
- FIG. 51 is a cross-sectional view of the heat treatment apparatus shown in FIG. 49 in a state in which the wafer is being cooled;
- FIG. 52 is a cross-sectional view of a helium gas supply part;
- FIG. 53 is a cross-sectional view of a circular quartz window for explaining the directivity of the light passing through the circular quartz window.
- FIG. 54 is an graphic illustration showing the directivity achieved by a conventional single end lamps which does not have a gold plate film; and
- FIG. 55 is a graphic illustration of the directivity shown in FIG. 54 viewed from above.
- (First Embodiment)
- FIG. 3 is a cross-sectional view of a heat treatment apparatus according to a first embodiment of the present invention. The heat treatment apparatus shown in FIG. 3 generally comprises: a
process chamber 2 which defines a process space for a semiconductor wafer W, which is an object to be processed; a light-transmittingwindow 6 provided on an upper portion of theprocess chamber 2; and aheating unit 5 provided above the light-transmittingwindow 6. - The
process chamber 2 has aprocess chamber body 20 having a sidewall having a flat, circular horizontal cross section. The light-transmittingwindow 6 is provided so as to close a top opening of theprocess chamber body 20. Anannular groove 21 is formed in the periphery of theprocess chamber 2. Ainner ring part 31 is provided in theannular groove 21. Theinner ring part 31 is rotatably supported about the vertical axis by an inner wall of theannular groove 21 via a bearingpart 41. Theinner ring part 31 is constituted by an upper member (support ring) 31 a and alower member 31 b connected to theupper member 31. Theinner ring part 31 is a support ring which supports aplacement stage 22. Theupper member 31 a is formed of opaque quartz (SiO2). Theplacement stage 22 is provided on an upper end of theupper member 31 a. Theplacement stage 22 is formed of silicon carbide (SiC) and has a ring shape so as to support the wafer W, which is an object to be processed. Theplacement stage 22 is arranged to rotate together with theinner ring part 31. - A part of a
housing 23, which forms theannular groove 21, extends on the downward side. An outer ring part is rotatably supported about the vertical axis on the outside of thehousing 23 via a bearing parts having anupper part 42 and a lower part. - The
lower member 31 b (inner ring part 31) and theouter ring part 32 are provided withmagnetic pole parts magnetic pole parts separation wall 24 of thehousing 23, respectively, so as to constitute a magnetic coupling. Agear part 35 is formed on an outer surface of theouter ring part 32. Thegear part 35 engages with agear part 37 of a steppingmotor 36, which is a drive part, so that theouter ring part 32 is rotated by the drive force of the steppingmotor 36. - A
supply passage 44 of a purge gas such as nitrogen (N2) is formed on an outer portion of thehousing 23 which forms theannular groove 21 of theprocess chamber 2. An end of the supply passage communicates with a position directly above the bearingpart 41 in theannular groove 21. Additionally, a plurality ofexhaust passages 45 of the purge gas is formed along a circumferential direction of aninner body part 23 forming theannular groove 21. The purge gas enters theannular groove 21 from a gas supply pipe (not shown in the figure) via thesupply passage 44, and is exhausted from an exhaust pipe (not shown in the figure) via theexhaust passage 45 by passing through an interior of the bearingpart 41. - A
bottom plate 33 constitutes a bottom part of theprocess chamber 2 under the wafer W. Atemperature detecting means 25 is inserted into thebottom plate 33. thetemperature detecting means 25 comprises, for example, a plurality of radiation thermometers for measuring a temperature of the wafer W from the backside. The radiation thermometers are arranged along a radial direction of the wafer W so that temperatures of a plurality of positions on the wafer W from the center to the peripheral edge can be measured. Additionally, thebottom plate 33 is provided with lift pins (not shown in the figure) which lifts the wafer W when the wafer is transferred to or from a conveyance arm provided outside theprocess chamber 2. - A
gas supply passage 26 and anexhaust passage 27 are formed on a sidewall of theprocess chamber 2 in a position slightly above the wafer W. Thegas supply passage 26 is an elongated silt-like gas supply part, which is provided for supplying a process gas from a gas supply source (not shown in the figure). Theexhaust passage 27 is provided for exhausting the process gas by being connected to anexhaust pipe 29 via anexhaust chamber 28 protruding outside from the sidewall of theprocess chamber 2. - A description will now be given of the upper portion of the
process chamber 2. As mentioned above, theheating unit 5 is provided on the top of theprocess chamber 2 so that theheating unit 5 is opposite to the front surface of the wafer W placed on theplacement stage 22. The light-transmittingwindow 6 is provided in a space between theheating unit 5 and the wafer W. - The
heating unit 5 is larger than the wafer W. Theheating unit 5 comprises a plurality ofheat radiation lamps 51 and areflective plate 52. Theheat radiation lamps 51 constitute heating means for heating the wafer W by irradiating lights onto the wafer W. Thereflective plate 52 has a circular cross section, and is provided so as to encircle a surface of eachlamp 51 opposite to the wafer W. A power supply system of theheat radiation lamps 52 is accommodated in ahousing 53. - In the present embodiment, halogen lamps are used as the
heat radiation lamps 51. The halogen lamps are concentrically arranged with the center being aligned with the center of the wafer W so that a plurality of generally annular light-emitting areas having different radii are formed. - FIG. 4 is a plan view of the
reflective plate 52 viewed from the side of the wafer W. Eachheat radiation lamp 51 has a shape corresponding to an arc which is formed by dividing one of concentric circles so that a plurality of lamps are formed in the concentric arrangement with a predetermined interval. In FIG. 4, apower supply part 54 extends in a vertical direction from opposite ends of eachhalogen lamps 51. The other side of thepower supply part 54 is accommodated in the power supply system inside the housing 53 (refer to FIG. 3). - Each of the
halogen lamps 51 is provided in aconcave part 55 formed in thereflective plate 52. That is, a plurality ofconcave parts 55 having a semicircular cross section are formed in thereflective plate 52 in a concentric arrangement, and thehalogen lamps 51 are accommodated in the respectiveconcave parts 55. Theheating unit 5 is constituted as mentioned above. An inner surface of eachconcave part 55 is gold-plated so as to reflect a light emitted by thehalogen lamp 51. The shape of theconcave portion 55 is determined so that the light from thehalogen lamp 51 is reflected by the inner surface thereof and forwarded toward the wafer W on theplacement stage 22. Accordingly, both the light emitted by thehalogen lamp 51 and the light reflected by thereflective plate 52 are irradiated downwardly. - A description will now be given of the light-transmitting
window 6. The light-transmitting window is a plate-like member formed of quartz, and is provided so as to opposite to the wafer W placed on theplacement stage 22. The light-emitting plate has a generally flat top surface. A bottom surface of the light-emittingwindow 6 is provided with aconvex lens part 61 which extends in a circumferential direction on the periphery of the light-emittingpart 61 and protrudes toward the process space between the light-emittingwindow 6 and the wafer W. Theconvex lens part 61 is provided for deflecting the light irradiated from above theplacement stage 22 so as to deflect the light traveling outward of the wafer W to inner side of the wafer W. Accordingly, theconvex lens part 61 is positioned right above theplacement stage 22. - A description will now be given of an operation of the heat treatment apparatus according to the above-mentioned embodiment. First, the wafer is transferred onto the
placement stage 22 by a conveyance arm (not shown in the figure) which enters theprocess chamber 2 through a conveyance port (not shown in the figure) provided to theprocess chamber 2. Then, theouter ring part 32 is rotated by driving the steppingmotor 36. At this time, since a magnetic force is applied between themagnetic pole part 34 of theouter ring part 34 and themagnetic pole part 33 of inner ring part 31 (lower member 31 b), themagnetic pole part 33 is attracted by themagnetic pole part 34 which results in rotation of theinner ring part 31, thereby rotating the wafer W. - A power is supplied to each
halogen lamp 51 so as to heat the wafer W while supplying a process gas such as N2 gas which is an inert gas from thegas supply passage 26. The temperature of the wafer W is raised to, for example, 1000° C. at a rate of 150° C./min. while rotating the wafer W at a speed of 90 r.p.m. for example. The temperature is maintained for a predetermined time period so as to apply an anneal process to the wafer W. After the predetermined time period has elapsed, the power to eachhalogen lamp 51 is stopped and the temperature of the wafer is lowered, and steppingmotor 36 is stopped. The processed wafer W is carried out of theprocess chamber 2 by the conveyance arm (not shown in the figure). - In the flat area other than the peripheral part of the light-emitting
window 6, although the light emitted by thehalogen lamp 51 and the light reflected by thereflective plate 52 have different optical axes, both lights substantially travels in the vertical direction so that a generally uniform irradiation distribution is achieved on the wafer W in accordance with the arrangement pattern of thehalogen lamps 51. On the other hand, the light incident on theconvex lens part 61 formed on the periphery of the light-emittingwindow 6 is refracted and the light traveling outward is deflected toward the inner side. - A description will now be give, with reference to FIG. 5, of the above-mentioned action of the
convex lens part 61. The optical paths shown in FIG. 5 are calculated on the basis of a refractive index of quartz with respect to infrared ray being 1.45 and a critical angle being 42 degrees. The optical paths indicated by dashed lines are in the case in which theconvex lens part 61 is not formed in the light-transmittingpart 6. The optical paths indicated by solid lines are in the case in which theconvex lens part 61 is formed in the light-transmittingpart 6. Attention is given to a point P on a line extending outward from the periphery of theplacement stage 22. The lines connecting each center of the first tofifth halogen lamps 51 and the point P correspond to the optical paths extending from each center to the pint P when theconvex lens part 61 is not provided. It should be noted that the optical paths reaches a position slightly inner side since refraction in the flat part of the light-emittingwindow 6 is ignored for the sake of simplification of the model. - When the
convex lens part 61 is provided, the light traveling from each center toward the point P is incident on theconvex lens part 61 from the flat top surface of the light-emittingwindow 6, and is refracted at the point of incidence. Then, the refracted light travels to aboundary surface 62 between theconvex lens part 61 and theprocess space 60. If the incident angle to theboundary surface 62 is greater than a critical angle, the light is totally reflected by theboundary surface 62. If the incident angle to theboundary surface 62 is smaller than the critical angle, the light is refracted again and exit to theprocess space 60 and reaches a point Q on an outer edge of theplacement stage 22. That is, by providing theconvex lens part 61, the light traveling toward the point P is deflected inwardly by a distance d1. - In the present embodiment, since the
convex lens part 61 is provided on the peripheral edge of the light-emittingwindow 6, the light traveling toward outside theplacement stage 22 is refracted and reaches theplacement stage 22, a total amount of heat radiation to theplacement stage 22 is increased. Accordingly, even if a temperature rising rate is increased in the heating process, there is less delay in the temperature rise of theplacement stage 22 with respect to the temperature rise of the wafer W. As a result, generation of a slip in the wafer W can be prevented while maintaining a high throughput by increasing the temperature rising rate. Additionally, since theplacement stage 22 is heated by the heat which has not reached theplacement stage 22, there is an effect that energy is effectively used. - Moreover, since an amount of light passing outside the
placement stage 22 is decreased, a problem that the stray light enters the temperature detecting means 25 can be solved. That is, if transparent quartz is used for theupper member 31 a (support ring) of theinner ring 31 as in the present embodiment, a light entering through a gap outside theplacement stage 22 enters a space between the wafer W and thebottom plate 24 by transmitting through theupper member 31 a and the light is multi-reflected inside the space. If the light enters thetemperature detecting means 25, the temperature detected becomes in accurate. However, in the present embodiment, since opaque quartz is used for theupper member 31 a, less light enters the space between the wafer W and thebottom plate 24, which results in achieving a high accuracy in the detection of temperature of the wafer W. - It should be noted that although there is an effect to shorten the temperature rise of the
placement stage 22 in the present embodiment, the present invention can be applied to a structure in which the placement stage does not extend from the outer side of the wafer W. That is, in such a case, an amount of heat released from the periphery of the wafer W is larger than that of the center portion since the temperature of the wall of the process chamber is lower than the temperature of the wafer W. Thus, the temperature rise in the periphery of the wafer W is delayed from the temperature rise in the center portion of the wafer W. However, the amount of heat radiation to the periphery if increased by providing theconvex lens part 61 in the periphery of the light-emittingwindow 6 as mentioned above, which provides the effect that the uniformity within the surface of the wafer W can be high even when the temperature rising rate is increased. Accordingly, the present invention is not limited to the structure in which the periphery of the wafer W is supported by the placement stage. - (Second Embodiment)
- A description will now be given, with reference to FIG. 6, of a second embodiment of the present invention. FIG. 6 is a cross-sectional view of a heat treatment apparatus according to the second embodiment of the present invention. In FIG. 6, pats that are the same as the parts shown in FIG. 3 are given the same reference numerals, and descriptions thereof will be omitted.
- The heat treatment apparatus shown in FIG. 6 has the same structure as that of the heat treatment apparatus shown in FIG. 3 except for the light-transmitting
window 6 being replaced by a light-transmittingwindow 6A having a different shape. The light-transmittingwindow 6A according to the present embodiment has a plurality ofconvex lens parts 61A on a bottom surface thereof so that theconvex lens parts 61A protrude into the space 60A between the light-transmittingwindow 6A and the wafer W. The convex lens parts are formed in positions corresponding to therespective halogen lamps 51 of theheating unit 5. - A description will now be given, with reference to FIG. 7, of an optical path from a
halogen lamp 51 to the wafer W. In FIG. 7, the center of thehalogen lamp 51 is located at the focal point of theconvex lens part 61A. Accordingly, a light emitted from thehalogen lamp 51 is changed into a generally parallel light as indicated by solid lines in FIG. 7. It should be noted that, although the optical path is more complicated since the outside surface of thehalogen lamp 51 is light emitting pints, thehalogen lamp 51 is considered to be a pint light source for the sake of simplification of the model. - In FIG. 7, dashed lines indicate an optical path in a case in which the light-transmitting
window 6 is formed of a flat plate having no convex lens part. Apparent from FIG. 7, the irradiated area by thehalogen lamp 51 is decreased by the convex leanspart 61. Accordingly, the directivity of eachhalogen lamp 51 is improved. Thus, the irradiated areas are independent or slightly overlap with each other. This results in an easy adjusting operation to control the luminescence distribution on the wafer W since the luminescence distribution can be controlled by adjusting the shape of thereflective plate 52 or adjusting an amount of light emitted from each of thehalogen lamps 51 when a control is performed so as to increase, for example, the luminescence of a portion provided with thetemperature detecting means 25. - Although the light-transmitting
windows windows convex lens parts convex lens part - In the above-mentioned embodiments, the heat radiation lamp (halogen lamp)51 is not limited to the curved double end lamp, and a plurality of straight tubular lamps may be arranged parallel to each other so as to heat the entire wafer W. In such a case, the shape of the light-transmitting
window 6 can be that shown in FIG. 10 in which theconvex lens parts 61A correspond to the shape of theheat radiation lamp 51. It should be noted that the light-transmittingwindow 6 shown in FIG. 10 is upside down for the sake of convenience of explanation. - Additionally, the present invention can be applied to an apparatus having a plurality of single end heat radiation lamps having a generally spherical shape or an eggplant shape. FIG. 11A is a plan view of a
heating unit 5A having a plurality ofsingle end lamps 71. FIG. 11B is a cross-sectional view of a part of theheating unit 5A shown in FIG. 11A in which thesingle end lamps 71 are accommodated in circularconcave portions 73 formed in areflective plate 72. FIG. 11C is a perspective view of a light-transmittingplate 6B having a plurality ofconvex lens parts 61 which are formed in positions corresponding to thesingle end lamps 71. It should be noted that the light-transmittingwindow 6B shown in FIG. 11C is upside down for the sake of convenience of explanation. - Additionally, when the process space in the process chamber is depressurized by evacuating gasses in the process chamber, the light-transmitting window may be formed in a curved shape so that the light-transmitting window can withstand a pressure generated by the pressure difference between the negative pressure inside the process chamber and the atmospheric pressure. The present invention can be applied to such a case. FIG. 12 is a cross-sectional view of a curved light-transmitting window6C along which a plurality of
heat radiation lamps 81 are arranged so as to equalize a distance between each of thelamps 81 and the light-transmitting window 6C. - It should be noted that although the heat radiation lamps are fixed and the wafer W is rotated in the above-mentioned embodiments, the heat radiation lamps may be rotated relative to the wafer W. Additionally, the heat treatment apparatus according to the present is not limited to an annealing apparatus and the present invention can be applied to other apparatuses such as a CVD apparatus.
- (Third Embodiment)
- A description will now be given of a third embodiment of the present invention. FIG. 13 is a cross-sectional view of a heat treatment apparatus according to the third embodiment of the present invention.
- As shown in FIG. 13, the
heat treatment apparatus 100 generally comprises aprocess chamber 110, a quartz window (light-transmitting window) 120, aheating unit 140, asupport ring 150, agearing 160, a permanent magnet 170 agas introducing part 180, anexhausting part 190, aradiation thermometer 200 and acontrol part 300. - The
process chamber 110 is formed of stainless steel or aluminum. Thequartz window 120 is connected to a top of theprocess chamber 110. The side wall of theprocess chamber 110 and thequartz window 12 define a process space in which an object W to be processed (semiconductor wafer: hereinafter referred to as a wafer W) is subjected to a heat treatment. Thesupport ring 150 on which the wafer W is placed and asupport part 152 connected to thesupport ring 150 are arranged in the process space. The process space is maintained to be a predetermined negative pressure by theexhaust part 190. The wafer W is carried in or out from the process chamber through a gate valve (not shown in the figure) provided to the sidewall of theprocess chamber 110. - A
bottom part 114 of theprocess chamber 110 is connected to a coolingpipes bottom part 114 serves as a cooling plate. If necessary, thecooling plate 114 may be provided with a temperature control arrangement as shown in FIG. 13. The temperature control arrangement may comprise acontrol part 300, a temperature sensor and a heater. A cooling water is supplied to the temperature control arrangement from a water supply source such as a water line. A coolant such as alcohol, gurden or flon may be used instead of the cooling water. As for the temperature sensor, a known sensor such as a PTC thermister, an infrared sensor, a thermocouple, etc. may be used. The heater can be a line heater wound on the outer surface of cooling pipe 116. The temperature of the cooling water flowing through the cooling pipe 116 can be adjusted by controlling an electric current flowing through the line heater. - The
quartz window 120 is attached to the process chamber in an airtight manner so as to maintain the negative pressure environment inside theprocess chamber 110 and transmit a heat radiation light emitted from lamps of theheating unit 140. - FIG. 14 is a plan view of the
quartz window 120. FIG. 15 is a cross-sectional view of the quartz window taken along a line XV-XV of FIG. 14. FIG. 16 is a cross-sectional view of the quartz window taken along a line XVI-XVI of FIG. 14. FIG. 17 is an enlarged cross-sectional view of a part of the quartz window shown in FIG. 16. FIG. 18 is an enlarged perspective view of a part of a lens assembly used in the quartz window. - As shown in FIGS. 14 through 17, the
quartz window 120 comprises acylindrical quartz plate 121 having a radius of about 400 mm and a thickness of about 33 mm and a plurality ofquartz lens assembly 122 comprising a plurality oflens elements 123. - The
lens assembly 122 serves to strengthen thequartz window 120 and increase the directivity of the radiation light form the lamps of theheating unit 140. As shown in FIG. 14, each of thelens assemblies 122 has a plurality oflens elements 123 ach having a light converging action. Thelens assemblies 122 are arranged parallel to the direction X since the lamps of theheating unit 140 are arranged in the direction X. That is, the direction of arrangement of thelens assemblies 122 is dependent on the direction of arrangement of the lamps of theheating unit 140. - In the present embodiment, although each of the
lens elements 123 is curved in the direction X, the orientation of each of thelens elements 123 is not limited to that shown in the figure, and each of thelens elements 123 may be curved in the direction X, the direction Y or both the directions X and Y. In the present embodiment, thelens assemblies 122 are arranged so as to uniformly heat the entire wafer W having a circular shape. - The
lens assemblies 122 serve to provide air passages AF (refer to FIGS. 32 and 34) for cooling thelens assemblies 122, thequartz window 120 and the lamps of theheating unit 140. Additionally, a gap between theadjacent lens assemblies 122 serves as acontact part 128 which contacts a separation wall 144 (described later) which cools thequartz plate 121 by heat conduction. - In the present embodiment, as described above, the thickness of the
quartz plate 121 is set equal to or less than 30 mm to 40 mm, for example, about 30 mm. Although the present invention does not exclude the thickness being in the range of 30 mm to 40 mm so as to use only the light converging action of thelens assemblies 122, the use of thethin quartz plate 121 according to the present embodiment can provide an effect described later. Additionally, although thelens assemblies 122 according to the present embodiment has a height about 3 mm and a width equal to or less than 21 mm, the height and width are not limited to such dimensions. Further, although thelens elements 123 according to the present embodiment has a length about 18 mm and a radius about 10 mm, the length and radius are not limited to such dimensions. - In the present embodiment, although the
window lens assemblies 122 are provided only on one side of thequartz plate 121 which side is opposite to thelamps 130 of theheating unit 140, thewindow lens assemblies 122 may be provided on both sides or on the other side which is not opposite to thelamps 130. - Since the strength with respect to thermal deformation of the
quartz plate 121 is increased by thelens assemblies 122, there is no need to form thequartz plate 121 in a domal shape which curves in a direction protruding from theprocess chamber 110 as in the conventional apparatus. Accordingly, thequartz plate 121 has a flat shape. Since the quartz window formed in a domal shape increases a distance between the wafer W and thelamps 130 of theheating unit 140, there is a problem in that the directivity of the lamps is deteriorated. The present embodiment solves such a problem relating to the directivity of the lamps. Although thequartz plate 121 and thelens assemblies 122 are joined by welding in the present embodiment, thequartz plate 121 and thelens assemblies 122 may be joined by other methods or integrally formed with each other. - The thickness of the
quartz plate 121 is about 30 mm, which is smaller than the thickness of the conventional quartz plate which ranges from 30 mm to 40 mm. Consequently, thequartz window 120 according to the present embodiment absorbs a smaller amount of the light emitted by thelamps 130 than the conventional quartz window. Thus, thequartz window 120 has the following advantages over the conventional quartz window. - First, a high rate temperature rise can be achieved with a low power consumption since the irradiation efficiency of the
lamps 130 to the wafer W can be improved. That is, the present embodiment solves the problem in that the lamp light is absorbed by the quartz window which results in deterioration of the irradiation efficiency. Second, the quartz window is prevented from being damaged due to a difference in temperature between the front surface and the back surface of thequartz window 121 since the difference can be maintained smaller than that of the conventional quartz window. That is, the present embodiment solves the problem in that the conventional quartz window is easily destroyed due to a difference in the thermal stress between the front surface facing the lamps and the back surface opposite to the front surface when a rapid thermal process is performed as in a rapid thermal process (RTP) apparatus. Third, the quartz window is prevented from forming a deposition film or a byproduct on a surface thereof during a film deposition process since the temperature of thequartz window 120 is lower than the conventional quartz window. Thus, a good repeatability can be maintained and a frequency of cleaning operations applied to theprocess chamber 110 can be decreased. That is, the present embodiment solves the problem in that the temperature of the conventional window is high especially when a film deposition process is performed, which results in deposition of a deposition film or a byproduct on the surface of the quartz window and increase in the frequency of cleaning operations of the process chamber. - Additionally, although the
quartz window 120 solely constituted by the quartz plate, which does not have thelens assemblies 122, may reduce an amount of light absorbed by thequartz plate 121 when the thickness of thequartz plate 121 is small as in the present embodiment, it is possible that thequartz window 120 is easily destroyed since thequartz plate 120 cannot withstand a pressure difference between the negative pressure in the process chamber and the atmospheric pressure. Accordingly, there is a problem in that the quartz window cannot be used with a process which must be performed under a negative pressure environment. The lens assemblies solve such a problem since thelens assemblies 122 reinforces thequartz plate 121. - A description will now be given, with reference to FIGS. 17, 18 and52, of a light converging action of the
lens assemblies 122 of thequartz window 120. FIG. 53 is a cross-sectional view of a conventional circular quartz window such as a light-transmittingwindow 13 shown in FIG. 1 for explaining the directivity of the light passing through thecircular quartz window 13. Referring to FIG. 53, the light emitted from a single end lamp (not shown in the figure) positioned above the quartz window and transmitting thequartz window 13 is spread, and, thus, the directivity of the light passed through thequartz window 13 with respect to the wafer W, which is placed under the quartz window, is dull. - On the other hand, as shown in FIGS. 5 and 6, the
quartz window 120 according to the present embodiment collimates the light emitted from thelamps 130 by thelens assemblies 122 having theconvex lens elements 123 so that the light is irradiated on the wafer W with a good directivity. It should be noted that the structure of eachlens element 123 is not limited to the specifically disclosed shape and curvature which collimate the light from thelamps 130, and the lens element may provide a directivity the same as the conventional quartz window. That is, even if the directivity is the same as that of the conventional quartz window, thelens assemblies 122 have the above-mentioned reinforcing function. - A description will now be given, with reference to FIG. 19, of a
quartz window 120A which is a variation of the quartz window according to the present embodiment. FIG. 19 is an enlarged cross-sectional view of a part of thequartz window 120A. Thequartz window 120A has reinforcing members (or columns) 124, which are formed under thepassage 128 and parallel to thepassage 128. Each of the reinforcingmembers 124 is made of aluminum or stainless steel, and has a square cross section. The reinforcingmembers 124 have coolingpipes 125 therein, and increase a strength of thequartz window 120A. - The reinforcing
members 124 have a good heat conductivity. Additionally, the reinforcingmembers 124 cannot be a source of pollution with respect to the wafer W since the reinforcingmembers 124 are formed of the same material as the process chamber. Due to the provision of the reinforcingmembers 124, the thickness of thequartz plate 121 can be 10 mm, preferably equal to or smaller than 7 mm, and, more preferably, about 5 mm. - In the present embodiment, the dimensions of the cross section of each reinforcing
member 124 is 18 mm in height and about 12 mm in width. The diameter of thecooling pipe 125 is not limited to but about 6 mm. Additionally, the cross-section of each reinforcingmember 124 is no limited to a square, and an arbitrary shape such as a wave shape may be used. The present invention encompasses aquarts window 120C which is a combination of thequartz plate 121 and the reinforcingmembers 124 as shown in FIG. 23. - As shown by arrows in FIG. 19, the radiation light from the
lamps 130 is reflected by sidewalls of reinforcingmembers 124, and reaches the wafer W placed under the quartz window. Thecooling pipe 125 has a cooling function which cools both the reinforcingmembers 124 and thequartz plate 121. If the reinforcingmembers 124 are made of aluminum, an appropriate temperature control (cooling) is needed since the aluminum may be deformed or melted at a temperature in the range of 200° C. to 700° C. The temperature control by the coolingpipe 125 may be the same as the cooling pipe 116, or other known methods may be applied. - A description will now be given, with reference to FIG. 20, of a
quartz window 120B which is another variation of thequartz window 120 according to the present embodiment. FIG. 20 is an enlarged cross-sectional view of thequartz window 120B. Thequartz window 120B has the same structure as thequartz window 120A shown in FIG. 19 except for waveguidingparts 126 having a square cross section being provided under therespective lens assemblies 122. Thequartz window 120B can provide an improved irradiation efficiency than thequartz window 120A due to thewaveguiding parts 126. Referring to FIG. 19, the radiation light emitted by thelamps 130 indicated by arrows generated energy loss about 10% when the radiation light is reflected by the reinforcingmembers 124. The rate of energy loss is dependent on the height of the reinforcingmembers 124 and other parameters. The energy loss can be decreased by forming a metal film having a high reflective index on the surface of the reinforcingmembers 124 by, for example, gold plating. However, such a metal film is not preferable since it may become a source of pollution with respect to the wafer W. Additionally, there in no material which is applicable to the reinforcingmembers 124 and has no reflective loss. - In order to reduce such an energy loss, the
quartz window 120B is provided with thewaveguiding parts 126 which has a square cross section and extending in parallel to therespective lens assemblies 122. Thewaveguiding parts 126 may be bonded to thequartz plate 121 by welding or may be integrally formed with each other. Thewaveguiding parts 126 are preferably made of quartz, and have a refractive index of about 1.4. Since the refractive index of vacuum and air is about 1.0, the radiation light is totally reflected within the quartz madewaveguiding parts 126 according to the relationship between the refractive indexes of quartz and vacuum or air. Thus, the energy loss of thequartz window 120B is reduced to zero in theory. - FIGS. 21 and 22 are graphic illustrations showing the directivity achieved by the
quartz window 120B shown in FIG. 20. In FIG. 21, the center of the wafer coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 14 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 22 shows the graphic illustration shown in FIG. 21 from above. - The above-mentioned relationship was obtained by using a 750W-lamp as the
lamp 130 having a platedpart 149 formed by a gold plate film. A distance between the lower end of thelamp 130 and the upper end of thelens assembly 122 was 2 mm. A distance between the wafer W and the aluminum made reinforcingpart 124 was 20 mm. Additionally, in FIG. 20, the thickness of thequartz plate 121 was set to 5 mm, the radius was set to 10 mm, and the width was set to 19 mm. Additionally, the width of eachwaveguiding part 126 was set to 19 mm, and the height was set to 18 mm. Further, a distance between the adjacent reinforcingmembers 124 was set to 21 mm. - FIGS. 24 and 25 are graphic illustrations showing the directivity achieved by the
quartz window 120C shown in FIG. 23. In FIG. 24, the center of the wafer coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 14 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 25 shows the graphic illustration shown in FIG. 24 from above. - The above-mentioned relationship was obtained by using a 750W-lamp as the
lamp 130 having a platedpart 149 formed by a gold plate film. A distance between the lower end of thelamp 130 and the upper end of thelens assembly 122 was 2 mm. A distance between the wafer W and the aluminum made reinforcingpart 124 was 20 mm. Additionally, in FIG. 23, the thickness of thequartz plate 121 was set to 5 mm. A distance between the adjacent reinforcingmembers 124 was set to 21 mm. - It can be interpreted from FIGS. 21 and 22 that the irradiance is sharply maximized near the center of the wafer W, and the directivity is improved by the
quartz window 120B. Additionally, a half spread (may be referred to as “half value width”) of the maximum height (a maximum irradiance) forms a generally circular shape and the maximum of the half value width is about 40 mm. The controllability is more improved as the half width becomes closer to a complete circle and the value of the half value width is reduces. - On the other hand, it can be appreciated from FIGS. 24 and 25 that the irradiance is maximum near the center of the wafer W, but the maximum value is not so large. Additionally, the half value width forms a generally oblong shape, and the maximum of the half value with is about 100 mm. The directivity is improved as the maximum value is increased. Additionally, the controllability of the half value width can be improved as it approaches a circle and its value is decreased. Here, the controllability represents easiness of process when it is needed to heat a desired position of the wafer W (that is, irradiate the radiation light) and heat if not applied to a position where it is not desired to heat. Comparing FIGS. 21 and 22 with FIGS. 24 and 25, it can be appreciated that the
quartz window 120B is superior to thequartz window 120C in both directivity and controllability. - The above-mentioned quartz windows are not always needed to be used with the
lamps 130 which do not need a reflector. In other words, the above-mentioned quartz windows can be applied to a heat treatment apparatus which has a reflector due to their strength and directivity. In such a case, the reinforcingmembers 124 having a waveform cross section are suitable for a wave-shaped reflector. - A description will now be given, with reference to FIGS. 26 through 29, of the
heating unit 140 according to the present embodiment. FIG. 26 is a bottom view of theheating unit 140. FIG. 27 is a partial cross-sectional view of theheating unit 140. FIG. 28 is a front view of thelamp 130 shown in FIG. 27. FIG. 29 is a side view of thelamp 130 shown in FIG. 27. As shown in FIG. 26, the arrangement of thelamps 130 correspond to the arrangement of thelens elements 123 shown in FIG. FIG. 14. Theheating unit 140 comprises thelamps 130 and alamp support part 142. - Although each
lamp 130 in the present embodiment is a single end type as shown in FIG. 27, thelamp 130 can be a double end type as explained later, or other heat sources such as an electric wire heater may be used. The single end type refers to a kind of lamp having asingle electrode part 132 as shown in FIG. 27. The double end type refers to a kind of lamp having two ends like a fluorescent lamp. Thelamp 130 serves as a heat source to heat the wafer W. In the present embodiment, thelamps 130 are not limited to but halogen lamps. The output of thelamps 130 is determined by alamp driver 310. That is, the lamp driver is controlled by thecontrol part 300 so as to supply a power to thelamps 130. - As shown in FIG. 28, each
lamp 130 comprises thesingle electrode part 132 and a light-emittingpart 134. The light-emittingpart 134 includes afilament 135 which is connected to theelectrode part 132. As indicated by dashed lines in FIG. 26, the plurality oflamps 130 are arranged along a plurality of lines in response to thelens elements 123 of thelens assemblies 122 so as to evenly heat the wafer W having a circular shape. Additionally, as mentioned above, since the reflector is not present betweenadjacent lamps 130 in the direction X as shown in FIG. 26, a distance between theadjacent lamps 130 in the direction X can be maintained as small as 3 mm, which contributes to an increase in the density of lamps and an increase in a power density. Additionally, as mentioned later, such a rectilinear arrangement of thelamps 130 contributes to the suitable heat exhaust (for example, 4 m3/min). - As shown in FIG. 29, a
neck part 133 is formed as a part of the light-emittingpart 134 under theelectrode part 132. A platedpart 149 is formed around theneck part 133. Referring to FIG. 13, a power supplied to theelectrode part 132 is determined by thelamp driver 310, and thelamp driver 310 is controlled by thecontrol part 300. Referring to FIG. 28, in the present embodiment, the height of theelectrode part 132 is about 25 mm; the height of the light-emittingpart 124 is about 65 mm, the thickness is about 1 mm; and the length of thefilament 135 is about 25 mm. Additionally, referring to FIG. 29, in the present embodiment, the width of theelectrode part 132 is about 5 mm and the width of the light-emitting part 134 (not the neck part 133) is about 15 mm. Nitrogen or argon gas and halogen gas are charged in the light-emittingpart 134. Thefilament 135 is made tungsten. A distance between a lower part of thefilament 135 and abottom surface 134 a of the light-emittingpart 134 shown in FIG. 28 is set within a predetermined range, thereby maintaining the directivity and the service life of the lamps. If the distance is too small, the directivity of thelamps 130 is deteriorated, and if the distance is too large, the halogen cycle is in sufficient which results in reducing the service life of the lamps. - Referring to FIGS. 26 and 27, the
lamp support part 142 has a generally rectangular parallelepiped shape. Thelamp support part 142 has a plurality ofseparation walls 144 and a plurality of cylindrical grooves which accommodate thelamps 130. Each of the cylindrical grooves comprises apart 143 a which accommodates theelectrode part 132 of thelamp 130 and apart 143 b which accommodates the light-emittingpart 134 of thelamp 130. Theelectrode part 132 of eachlamp 130 is connected to thelamp driver 130 shown in FIG. 13. Thepart 143 a serves as a sealing part. The diameter of thepart 143 b is larger than the diameter of the light-emittingpart 134. - Each
separation wall 144 has a width of about 12 mm, and is located above thepassage 128 shown in FIG. 14 and the reinforcingmember 124 shown in FIG. 19 and between theadjacent grooves 143 arranged in the direction X shown in FIG. 26. A pair of coolingpipes 145 arranged in parallel to the passage 128 (in the direction X shown in FIG. 26) are put in contact with theseparation walls 144. About 0.3 to 0.8 m3 of air can flow through thegroove 143 excluding thelight emitting part 134 so as to cool the surface of the light-emittingpart 134. Thus, thelamps 130 of the present embodiment can be cooled by the air cooing arrangement and the coolingpipes 145. - The lamps can be cooled the air cooling arrangement alone by removing the separation walls and the cooling
pipes 145. As mentioned later, the platedpart 149 is formed by gold plating, the temperature of the platedpart 149 is maintained below 500° C. so as to prevent a temperature destruction such as exfoliation of gold plate. The temperature control by the coolingpipe 145 can be the same as the cooling pipes 116, and other known methods may be applied. Even when the platedpart 149 has a heat resistance exceeding 500° C., the temperature of thelamps 130 is preferably controlled to be below 900° C. by the coolingpipes 145 or other cooling arrangements since transmittance is deteriorated (a phenomenon in which the light-emittingpart 134 becomes white) if the temperature of thelamps 130 exceeds 900° C. - In the present embodiment, the
separation walls 144 and the coolingpipes 145 are arranged along the direction X in FIG. 26, and a two-dimensional arrangement in the X and Y directions is not used as in a conventional reflector. Accordingly, the structure of thelamp support part 142 according to the present embodiment contributes to an increase in the lamp density and the power density of thelamps 130. For example, when the lamps are arranged with a conventional reflector (for example, a diameter of 50 mm), the lamp density is 0.04 unit/cm2. On the other hand, the lamp density achieved by the present embodiment is 0.16 unit/cm2. In a case in which thelamps 130 and thelamp support part 142 are cooled by air cooling alone instead of providing theseparation walls 144 and the coolingpipes 145, the lamp density is increased to about 0.40 unit/cm2 at maximum. Generally, the power density required for an RTP is determined by a lamp power per one lamp and a lamp density. The lamp density can be decreased as the lamp power is increased. The arrangement of the lamps in the present embodiment can be applied to RTP which requires a further rapid temperature rising in the feature. - A description will now be given, with reference to FIGS. 30 and 31, of a
heating unit 140A which is a variation of the heating unit shown in FIG. 26. Theheating unit 140A improves the lamp density by removing theseparation walls 144 and the coolingpipes 145 from theheating unit 140A. Since the cooingpipes 145 are not provided in to thelamp support part 142, thelamps 130 are sorely cooled by air cooling. The lamp density of theheating unit 140A is twice that of theheating unit 140. Since the reflector which conventionally requires the platedpart 149 is removed, such a high-density lamp mount can be achieved. - A description will now be given, with reference to FIGS.32 to 34, of the cooling arrangement of the
lamps 130. FIG. 32 is a cross-sectional view for explaining the cooling arrangement of thelamps 130 arranged in the direction X in FIG. 26. FIG. 33 is a side view of thelamp 130 shown in FIG. 32. FIG. 34 is a plan view of thelamp 130 shown in FIG. 32. As shown in the figures, the plurality oflamps 130 arranged in the same row are subjected to heat exhaust (air cooling) by a blower. The exhaust efficiency by the blower is as good as 4 m3/min with respect to that achieved by a rectilinear arrangement of the lamps. In a case such heat exhaust is performed, heated are can be exhausted out of theheat treatment apparatus 100, or alternatively circulated. If the heated air is circulation, a radiator is provided so as to cool the heated air. In such a case, a load to an exhaust system is small due to the good exhaust efficiency being achieved. - The plated
part 149 has a function to reflect the heat radiation light of thelamps 130 at a high reflectance within the light-emittingpart 134. By providing the light-emittingpart 134 having a high reflectance, the directivity of the light-emitting part 134 (radiation light emitted by the filament 135) to the wafer W is improved. As a result, the platedpart 149 excludes the reflector (reflective plate), which is conventionally provided outside the light-emitting part. Since the reflector is not used, the plurality oflamps 130 can be mounted at a high density. For example, thelamps 130 can be arranged at an interval of 3 mm in the direction X as shown in FIG. 26, and can be mounted at a lamp density of 0.16 unit/cm2 which is four times the lamp density (0.04 unit/cm2) of the arrangement having a reflector inclined by 45 degrees. Accordingly, the power density can be increased and, therefore, theheat treatment apparatus 100 according to the present embodiment is suitable for RTP. - The plated
part 149 is formed by various plating methods or other methods on the light emitting-part 134 including theneck part 133 except for thebottom surface 134 a of the light-emittingpart 134. Accordingly, the directivity of thelamps 130 can be improved by the light directly irradiated on the wafer W and the light reflected by the platedpart 149. - The plated
part 149 if formed of a metal film such as a gold film or silver film which reflects a radiation light at a high reflectance. The platedpart 149 may be formed by electroplating such as hard gold plating or pure gold plating. The thickness of the platedpart 149 can be about 10 μm so as to sufficiently prevent light leakage from the light-emittingpart 134. It should be noted that the platedpart 149 is provided for improving the directivity, and there is no specific range of high-reflectivity of the platedpart 149. - FIGS. 35 and 36 are graphic illustrations showing the directivity achieved by the
lamp 130 having the platedpart 149 formed of a gold plate film. In FIG. 35, the center of the wafer W coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 26 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 36 shows a graphic illustration of the directivity shown in FIG. 35 viewed from above. - The above-mentioned relationship was obtained by using a 750W-lamp having the plated
part 149 formed of a gold plate film as thelamp 130. Theprocess chamber 110 was maintained at a normal pressure. A distance between the lower end of thelamp 130 and the upper end of a circular quartz window, which is consisted of thequartz plate 121 alone, was 2 mm. A distance between the wafer W and the lower end of the quartz window was 20 mm. - FIGS. 53 and 54 are graphic illustrations showing the directivity achieved by a conventional single end lamp which does not have a gold plate film. In FIG. 54, the center of the wafer coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 26 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 55 shows a graphic illustration of the directivity shown in FIG. 54 viewed from above.
- The above-mentioned relationship was obtained by using a 750W-lamp which does not have the plated
part 149 formed of a gold plate film as thelamp 130. Theprocess chamber 110 was maintained at a normal pressure. A distance between the lower end thelamp 130 and the upper end of a circular quartz window, which is consisted of thequartz plate 121 alone, was 2 mm. A distance between the wafer W and the lower end of the quartz window was 20 mm. - It can be interpreted from FIGS. 35 and 36 that the irradiance is sharply maximized near the center of the wafer W, and the directivity is improved by the plated
part 149. Additionally, a half spread is about 40 mm. On the other hand, it can be appreciated from FIGS. 53 and 54 that the irradiance is maximum near the center of the wafer W, but the maximum value is not so large. Additionally, the half value width forms a generally oblong shape, and the maximum of the half value with is about 80 mm. Comparing FIGS. 35 and 36 with FIGS. 52 and 53, it can be appreciated that thelamp 130 having the platedpart 149 is superior to the conventional lamp having no plated part in both directivity and controllability. - The light-emitting
part 134 preferably has unevenness in a portion covered by the platedpart 149 as indicated by a circled portion shown in FIG. 29. According to the unevenness, the light reflected by the platedpart 149 can be directed to the wafer W without repeating reflection within the cylindrical side surface of the light-emittingpart 134. The unevenness can be formed by surface treatment such as sand-blasting or corrosion by a chemical solution. - As mentioned above, the
lamp 130 can be of a double end type. A description will now be given, with reference to FIGS. 37 through 41, of a case in which thelamps 130 are replaced by the double end type lamps. FIG. 37 is a perspective view of a doubleend type lamp 130A from which a platedpart 149A is removed. FIG. 38 is a perspective view of another double end type lamps from which a platedpart 149B is removed. FIG. 39 is a cross-sectional view for explaining the platedparts lamps heating unit 140B having thelamps 130A taken along the direction X in FIG. 26. FIG. 41 is a cross-sectional view of theheating unit 140B shown in FIG. 40 taken along the direction Y in FIG. 26. - FIG. 37 shows one of the
double end lamps 130A having a rectilinear shape and arranged in the direction in FIG. 26. FIG. 38 shows one of the arc-likedouble end lamps 130B which are concentrically arranged as indicated by dashed circles in FIG. 13. It should be noted that the lamp support part must be changed so as to receive thelamps lamps 130 are replaced by thelamps lamp support part 142 may be changed so as to have a plurality of vertical through holes, which accommodateelectrode parts vertical parts horizontal parts lamps 130A has a length corresponding to the light-emittingpart 136 shown in FIG. 40 and a width which covers a pair oflamps 130A shown in FIG. 41. - As shown in FIG. 37, each
lamp 130A comprises twoelectrode parts 132A and the light-emittingpart 136. The light-emittingpart 136 includes afilament 135A which connects the twoelectrode parts 132A. Similarly, as shown in FIG. 26, thelamp 130B includes twoelectrode parts 132B and the light-emittingpart 137. The light-emittingpart 137 includes afilament 135B which connects the twoelectrode parts 132B. A power supplied to theelectrode parts lamp driver 310 shown in FIG. 13. Thelamp driver 310 is controlled by thecontrol part 300. - As shown in FIG. 37, the light-emitting
part 136 includes thevertical parts 136 a and the rectilinearhorizontal part 136 b which is bent by 90 degrees with respect to thevertical parts 136 a. Additionally, as shown in FIG. 38, the light-emittingpart 136 includes thevertical parts 137 a and the arc-likehorizontal part 137 b which is bent by 90 degrees with respect to thevertical parts 137 a. It should be noted that the double end lamp applicable to the present invention is not limited to thelamps - The
horizontal part 136 b is mounted along the direction X arranged in a portion in which thelamps 130 are arranged as shown in FIG. 26. The length of thehorizontal part 136 b may be equal to or less than a distance (for example, interval E) between thelamps 130 at opposite ends which distance is determined by an outermost circle P and arbitrary positions (for example, indicated by D) of the lamps in the direction Y as shown in FIG. 26. If the length is equal to the above-mentioned distance, asingle lamp 130A is mounted in the lamp mounting position. If the length is less than the above-mentioned distance, a plurality oflamps 130A are mounted in the lamp mounting position. Thehorizontal parts 136 b of thelamps 130A mounted in different lamp positions may be the same or different from each other. - The
horizontal part 137 b is concentrically arranged with the dashed circles shown in FIG. 26. The dashed circle shown in FIG. 38 is concentric with the dashed circles shown in FIG. 26. The length of thehorizontal part 137 b is determined by a length of a circle which is concentric with the dashed circles shown in FIG. 14 and a number oflamps 130B arranged along the circle. The radii of thehorizontal parts 137 b of thelams 130B arranged along different concentric circles differ from each other. - In FIGS. 37 and 38, the plated
parts respective lamps parts parts part 149A is provided on entire side surfaces of thevertical parts 136 a and an upper half portion of thehorizontal part 136 b. The platedpart 149B is provided on entire side surfaces of thevertical parts 137 a and an upper half portion of thehorizontal part 137 b. - Similar to the plated
part 149, the platedparts respective lamps parts parts parts 136 and 137 (radiation light emitted by thefilaments parts lamps 130 can be mounted at a high density. For example, the lamps can be arranged can be mounted at a lamp density which is four times the lamp density of the arrangement having a reflector inclined by 45 degrees. Accordingly, the power density can be increased and, therefore, the heat treatment apparatus is suitable for RTP. - A description will now be given, with reference to FIGS. 42 through 46, of a method of calculating an effective emissivity which is another aspect of the present invention. FIG. 42 is a cross-sectional view showing two kinds of
radiation thermometers radiation thermometers 200C of the same kind. FIGS. 44 through 46 are graphs for explaining the method of calculating an effective emissivity according to the present invention. Hereinafter, theradiation thermometers radiation thermometer 200. - The
radiation thermometers lamps 130 with respect to the wafer W. Although the present invention does not exclude the structure in which theradiation thermometers lamps 130, it is preferable that the radiation light of thelamps 130 is prevented from being incident on theradiation thermometers - Each of the
radiation thermometers sapphire rod 210, respectiveoptical fibers radiation thermometers radiation thermometers - Referring to FIG. 30, the
radiation thermometers bottom part 114 of theprocess chamber 110. More specifically, theradiation thermometers holes 115 a and 115 b of thebottom part 114. Asurface 114 a of thebottom part 114 facing the interior of theprocess chamber 110 serves as a reflective plate (high-reflectance surface) by being subjected to a sufficient polishing. This is because if thesurface 114 a is a low reflectance surface such as a black surface, thesurface 114 a absorbs heat of the wafer W, which results in an undesired increase in the output of thelamps 130. - Each of the
radiation thermometers optical fibers rod 210 is formed of a quartz rod having a diameter off 4 mm. Although quartz and sapphire can be used since they have a food heat resistance and a good optical characteristic, the material of therod 210 is not limited to quarts or sapphire. If necessary, therod 210 can protrude inside theprocess chamber 110 by a predetermined length. Therod 210 of each of theradiation thermometers bottom part 114 of theprocess chamber 110, and is sealed by an O-ring (not shown in the figure). Accordingly, a negative pressure environment can be maintained in the process chamber irrespective of the through holes 115A and 115B. Therod 210 has an excellent light collecting efficiency since therod 210 can guide a radiation light, which is incident on therod 210, to the respective optical fibers 210A and 210B with less attenuation and less leakage. Therod 210 receives a radiation light from the wafer W, and guides received radiation light to thePD 230 via the respectiveoptical fibers - Each of the
optical fibers radiation thermometers - The photodiode (PD)230 has an image forming lens, a silicon (Si) photocell and an amplification circuit so as to convert the radiation light incident on the image forming lens into a voltage, which is an electric signal representing radiation intensities E1(T) and E2(T), and send the electric signal to the
control part 300. Thecontrol part 300 comprises a CPU, an MPU, other processors, and memories such as a RAM and a ROM so as to calculate an emissivity ε and a substrate temperature T of the wafer W based on the radiation intensities E1(T) and E2(T). It should be noted that the calculation may be performed by an arithmetic part (not shown in the figure) provided in theradiation thermometers rod 210 is introduced into the photodetector (PD) 230 via theoptical fibers - A description will now be given of a method of calculating an effective emissivity according to the present invention which uses different NA. Considering multiple reflection between the wafer W and the
rod 210 and a direct light form thelamps 130, the effective emissivity εeff of the wafer W can be given by the following equation (2). - εeff=(1−α)×ε+αxε/[1−F×r×(1−ε)] (2)
- where, εeff represents an effective emissivity of the wafer W; ε represents an emissivity of the wafer W; r represents a reflectance of the
surface 114 a of thebottom part 114 of theprocess chamber 110; F is a view factor given by the following equation (3); α is a coefficient of multiple reflection. - F=(1+cos2γ)/2 (3)
- The coefficient of multiple reflection α is supposed to take the following values depending on three values which are 1) a diameter D1 of the
rod 210, 2) a distance D2 between the wafer W and thesurface 114 a and 3) number of aperture NA of theradiation thermometers rod 210, thesurface 114 a and the wafer W as shown in FIG. 47B. - NA=0→(1−α)=1 (4)
- NA=1→(1−α)≈1 (5)
- D1/D2=∞→(1−α)=1 (6)
- D1/D2=0→(1−α)=1 (7)
- A prediction equation which can establish the above-mentioned four conditions can be defined as the following equation (8).
- (1−α)=(1−NA×N1)N2/(D1/D) (8)
- where N1 and N2 are the parameters in the equation (8). Accordingly, the coefficient of multiple reflection a is represented by the following equation (9).
- α=1−(1−NA×N1)N2/(D1/D2) (9)
- It can be appreciated that the coefficient of multiple reflection a represented by the equation (9) possibly satisfies the equations (4) through (7). Thus, the adequacy of equation (9) is considered by determining N1 and N2 based on equation (9).
- First, a calculation is made by fixing the diameter (4 mm) of the
rod 210 and varying NA. It is assumed that the wafer W has ε=0.2 for the sake of saving time. At this time, NA ranges from 0 to 1. Values of N1 and N2/(D1/D2) are tentatively determined by comparing data obtained by the calculation and the assumption of equation (9). In a similar manner, values of N1 and N2/(D1/D2) are determined for the diameters of 2 mm and 20 mm. As for a method of determining N1 and N2, N2 and N2/(D1/D2)-D1/D2 curve are used. N1 is selected so that N2 is common to the three conditions in N2/(D1/D2). - According to the tentative values of N1 and N2/(D1/D2) determined by the above-mentioned method, relationships between (1−α) and NA are shown in FIGS. 44 through 46. As a result, N1=0.01 and N2=500 are obtained, and equation (9) can be represented by the following equation (10).
- α=1−(1−0.01×NA)500/(D1/D2) (10)
- Accordingly, if the diameter of the
rod 210 is changed, or if the distance between the wafer W and thesurface 114 a is changed, the effective emissivity can be easily calculated irrespective of the value of NA. - In a case in which the
optical fiber 220A has NA=0.2 and theoptical fiber 220B has NA=0.34, the coefficients of multiple reflection α0.2 and α0.34 can be represented by the following equations (11) and (12). - α0.2=1−(1−0.01×0.2)500/D1/D2) (11)
- α0.34=1−(1−0.01×0.34)500/D1/D2) (12)
- Accordingly, the effective emissivity of the wafer W can be given by the following equations (13) and (14).
- εeff 0.2=(1−α0.2)×ε+α0.2×ε/[1−F×r×(1−ε)] (13)
- εeff 0.34=(1−α 0.34)×ε+α0.34×ε/[1−ε×r×(1−ε)] (14)
- The
radiation thermometer 200 performs the conversion of temperature based on radiation light flux (W). Thus, a difference in the incident light fluxes at the two radiation thermometers are given by the following equations (15) and (16), where θ1 is an incident angle at NA=0.2 and θ2 is an incident angle at NA=0.34. The incident angle θ represents a maximum light-receiving angle of an optical fiber as shown in FIG. 47A, and the incident angle θ can be represented as θ=sin−1(NA). - E 0.2 =A ROD×(r×tanθ1)2 ×π×L/r 2 (15)
- E 0.34 A ROD×(r×tanθ2)2 ×π×L/r 2 (16)
- Accordingly, the ratio of the incident light fluxes of the two
radiation thermometers - (εeff 0.34 ×E 0.34)/(εeff 0.2 ×E 0.2)=(εeff 0.34×tan2θ2)/(εeff 0.2×tan2θ1) (17)
- According to the above-mentioned equations (13) and (14), equation (17) can be changed into the following equation (18).
- (εeff 0.34 ×E 0.34)/(εeff 0.2 ×E 0.2)={(1−α0.34)×ε+α0.34×ε/[1−F×r×(1−ε)]}×tan2θ2/{(1−vα0.2)×ε+α0.2×ε/[1−F×r×(1−ε)]} (18)
- Then, if β is defined as in the following equation (19), the above-mentioned equation (18) can be changed into the following equations (20) through (24).
- β=[(εeff 0.34 ×E 0.34)/(εeff 0.2 ×E 0.2)]×[(εeff 0.34×tan2θ2)/(εeff 0.2×tan2θ1)] (19)
- β×{(1−α0.2)×ε+α0.2×ε/[1−F×r×(1−ε)]}={(1−α0.34)×ε+α0.34×ε/[1−F×r×(1−ε)]} (20)
- β×{(1−α0.2)×[1−F×r×(1−ε)]+α0.2}={(1−α0.34)×[1−F×r×(1−ε)]+α0.34} (21)
- β×(1−α0.2)−β×(1−α0.2)×[F×r×(1−ε)]+β×α0.2=(1−α0.34)−(1−9α0.34)×[F×r×(1−ε]+α0.34 (22)
- ε×(1−α0.2)−β×(1−0.2)×F×r+β×α 0.2−(1−α0.34)+(1−α0.34)×F×r×−α 0.34=(1−α0.34)×F×r+F×r×(1−α1.34)×F×r×ε−β×(1−α0.2)×F×r×ε (23)
- Accordingly, the emissivity ε of the wafer W can be calculated by the following equation (25).
- ε={β×(1−α0.2)−β×(1−α0.2)×F×r+β×α 0.2−(1−α0.34)+(1−α0.34)×F×r−α 0.34}/{(1−α0.2)×F×r} (25)
- Then, the effective emissivity is calculated again by the equations (11) and (12). At this time, the calculation is performed based on the small value of NA, that is, NA=2. The following equation (26) can be obtained by entering the emissivity E, which was calculated by equation (23), in equation (11).
- εeff 02=(1−α0.2)×ε+α0.2×ε/[1−F×r×(1−ε)] (26)
- Since radiation energy of E0.2 is incident on the
radiation thermometer 200A of NA=0.2, the following equation (27) is established, where Eb is radiation energy according to black body radiation. - E 0.2 =εeff 0.2 ×E b (27)
- Then, the above-mentioned equation (25) is changed as follows.
- E b =E 0.2 /εeff 0.2 (28)
- Regarding incident energy, the following relationship is defined by Japanese Industrial Standard (JIS 1612), where T represents a temperature of the wafer W; c2 represents a second constant of radiation (0.014388 m/k); A, B and C are constants peculiar to the radiation thermometer 200 (determined by calibration); Eb is radiation energy from a black body (normally an output V of a radiation thermometer).
- T=c2/A/(lnC−lnE b)−B/A (29)
- The above-mentioned calculation method obtains an emissivity of the wafer W by the two
radiation thermometers - In FIG. 43, a
bottom surface 114 b corresponding to thebottom surface 114 a and anupper surface 114 d of a protruding part 114 c protruding form thebottom surface 114 b are provided in thebottom part 114 of theprocess chamber 110. Accordingly,identical radiation thermometers 200C are used, but distances between the wafer W and thequartz rod 210 of each of theradiation thermometers 200C are different. Thus, in the example shown in FIG. 43, an emissivity of the wafer W can be obtained similar to the example shown in FIG. 40. - For example, in FIG. 43, the two
radiation thermometers 200C have NA=0.2, and the distance between the wafer W and therod 210 of one of theradiation thermometers 200C is set to 3.5 mm (left side of FIG. 43) and the distance between the wafer W and therod 210 of theother radiation thermometer 200C is set to 5 mm (right side of FIG. 43). Additionally, the diameter of therod 210 is set to 4 mm. According to equation (9), each coefficient of multiple reflection can be represented by the following equations (30) and (31). - α3.5=1−(1−0.001×0.2)500/(D1/3.5) (30)
- α5.0=131 (1−0.001×0.2)500(D1/5.0) (31)
- Using the above equations (30) and (31), the effective emissivities α3.5 and α5.0 are obtained in the similar manner as equations (13) and (14). The subsequent calculation of obtaining the temperature of the wafer W is performed in the same manner as that explained with reference to equations (15) through (28) by replacing the suffix 0.2 by 3.5 and 0.34 by 5.0.
- The detector270 and the
control part 300 can calculate the temperature T of the wafer W based on equations (25) through (29). In any case, thecontrol part 300 can obtain the temperature T of the wafer W. Additionally, a temperature measurement calculation program including the above-mentioned equations is stored in a computer readable medium such as a floppy disk, or the program is distributed through a communication network such as the Internet or the like. - The
control part 300 has a CPU and a memory incorporated therein. Thecontrol part 300 feedback-controls the output of thelamps 130 by recognizing the temperature T of the wafer W and controlling thelamp driver 310. Additionally, thecontrol part 300 controls a rotational speed of the wafer W by sending a drive signal to themotor driver 320 at a predetermined timing. - The
gags introducing part 180 includes a gas source, a flow adjust valve, a mass-flow controller, a gas supply nozzle and a gas supply passage interconnecting the aforementioned (not shown in the figure) so as to introduce a gas used for heat treatment into theprocess chamber 110. It should be noted that although thegas introducing part 180 is provided to thesidewall 112 of theprocess chamber 110 so as to introduce the gas into the process chamber from the side, the position of the as introducingpart 180 is not limited to the side of the process chamber. For example, thegas introducing part 180 may be constituted as a showerhead which introduces the process gas from an upper portion of theprocess chamber 110. - If the process to be performed in the
process chamber 110 is an annealing process, the process gas includes N2, Ar, etc.; if the process is an oxidation process, the process gas includes O2, H2, H2O, NO2, etc.; if the process is a nitriding process, the process gas includes N2, NH3, etc.; if the process is a film deposition process, the process gas includes NH3, SiH2, Cl2, SiH4, etc. It should be noted that the process gas is not limited the above-mentioned gasses. - The mass-flow controller is provided for controlling a flow of the process gas. The mass-flow controller comprises a bridge circuit, an amplification circuit, a comparator control circuit, a follow adjust valve, etc. so as to control the flow adjust valve by measuring a gas flow by detecting an amount of heat transmitted from the upstream side to the downstream side in association with the gas flow. The gas supply passage uses a seamless pipe and a bite-type coupling or a metal gasket coupling so as to prevent impurities from entering the gas to be supplied. Additionally, the supply pipe is made of a corrosion resistant material so as to generation of dust particles due to dirt or corrosion on an inner surface of the supply pipe. The inner surface of the supply pipe may be coated by an insulating material such as PTFE (Teflon), PPA, polyimide, PBI, etc. Additionally, the inner surface of the supply pipe may be subjected to an electropolishing. Further, a dust particle filter may be provided to the gas supply passage.
- In the present embodiment, although the
exhaust part 190 is provided parallel to thegas introducing part 180, the position and the number are not limited to that shown in the figure. Theexhaust part 190 is connected to a desired exhaust pump, such as a turbomolecular pump, a sputter ion pump, a getter pump, a sorption pump, a cryostat pump, together with a pressure adjust valve. It should be noted that although process chamber is maintained at a negative pressure environment in the present embodiment, such a structure is not an essential feature of the present invention. That is, for example, the process chamber may be maintained at a pressure ranging from 133 Pa to an atmospheric pressure. Theexhaust part 190 has a function to exhaust helium gas before starting a subsequent heat treatment. - FIG. 48 is a graph showing a result of simulation with respect to a cooling rate of the wafer W. In FIG. 48, a gap represents a distance between the wafer W and the
bottom part 114. It can be appreciated from FIG. 48 that 1) a cooling rate increases as the gap decreases, and 2) the cooling rate remarkably increases by flowing helium gas, which has a high heat conductivity, between the wafer W and thebottom part 114. - In the structure of the
RTP apparatus 100 shown in FIG. 13, the upper surface of the wafer W is heated by thelamps 130, and thebottom part 114 is provided as a cooling plate on the back side of the wafer W. Accordingly, the structure shown in FIG. 13 gives a high cooling rate, but needs a relatively large power so as to perform a rapid temperature rise since an amount of heat released from the wafer W is increased. In order to solve such a problem, supply of cooling water to the cooling pipe 116 may be stopped when heating the wafer. However, such a method is not preferable since a yield rate is decreased. - Accordingly, as shown in FIGS. 49 through 51, the
bottom part 114 as a cooling plate may be replaced by abottom part 114A which is arranged movable relative to the wafer W. More preferably, helium gas, which has a high heat conductivity, is supplied between the wafer W and thebottom part 114A when cooling the wafer W so as to increase a radiation efficiency. FIG. 49 is a cross-sectional view of theheat treatment apparatus 100 having thebottom plate 114A. FIG. 50 is a cross-sectional view of theheat treatment apparatus 100 in a state in which the wafer W is being heated. FIG. 51 is a cross-sectional view of theheat treatment apparatus 100 in a state in which the wafer W is being cooled. It should be noted that, in FIGS. 49 through 51, the cooling pipe 116 and thecontrol part 300 connected to theradiation thermometer 200 are omitted for the sake of simplification of the figure. - As shown in FIG. 49, the
bottom part 114A is movable up and down with respect to the wafer W (object to processed) by a vertical movingmechanism 117 which is controlled by thecontrol part 300. Thevertical moving mechanism 117 includes a bellows so as to maintain the negative pressure environment in theprocess chamber 110. Thevertical moving mechanism 117 can be constituted by a known mechanism in the art, and a detailed description thereof will be omitted. It should be noted that the wafer W or thesupport ring 150 may be arranged to be movable relative to thebottom part 114A. When heating the wafer W, thebottom part 114A is moved downward so as to separate thebottom plate 114A from the wafer W as shown in FIG. 50, and supply of helium gas is stopped. At this time, a distance between the wafer W and thebottom part 114A is 10 mm, for example. Since the distance between thebottom part 114A and the wafer W is large, the wafer is not influenced by ethbottom part 114A, thereby achieving a rapid temperature rise of the wafer W. The position of thebottom part 114A shown in FIG. 50 may be set as a home position. - When cooing the wafer W, the
bottom part 114A is moved upward so as to approach thebottom part 114A to the wafer W, and the supply of helium gas is started. Since the distance between the wafer W and thebottom part 114A is small, the wafer W is influenced by thebottom plate 114A, thereby achieving a high-rate cooling. At this time, the distance between the wafer W and thebottom part 114A is 1 mm, for example. FIG. 52 is an enlarged cross-sectional view of a helium gas supply part provided in an area V shown in FIG. 51. As shown in FIG. 52, thebottom part 114A is provided with a lot ofsmall holes 115 a through which helium gas is introduced into theprocess chamber 110. Acase 410 is connected to thebottom part 114A, and a helium gas supply pipe is connected to thecase 410 via avalve 400, which operates to start or stop the supply of helium gas. - In the present embodiment, although a relative movement is performed between the bottom part (cooling plate)114A and the wafer W, the present invention is applicable to a relative movement of the wafer W and the
lamps 130. - A description will now be given, with reference to FIG. 13, of a rotating mechanism of the wafer W. In order to maintain a good electric characteristic of each element in an integrated circuit and a high yield rate of products, a uniform heat treatment is required over the entirety of the surface of the wafer W. If a temperature distribution on the surface of the wafer W is uneven, the
RTP apparatus 100 cannot provide a high-quality heat treatment since a thickness of a film produced by a film deposition process may vary and a slip may be generated in the wafer W due to a thermal stress. - The uneven temperature distribution on the surface of the wafer W may be caused by an uneven irradiance distribution or may be caused by a process gas, which is supplied near the
gas introducing part 180, absorbing heat from the surface of the wafer W. The rotating mechanism rotates the wafer W, which enables a uniform heating by thelamps 130 over the entire surface of the wafer W. - The rotating mechanism of the wafer W comprises the
support ring 150, thepermanent magnet 170, a ring-likemagnetic member 172, amotor driver 320 and amotor 330. - The
support ring 150 has a ring shape and is made of a heat resistant ceramic such as SiC. Thesupport ring 150 serves as a placement stage on which the wafer W is placed. Thesupport ring 150 supports a periphery of the backside of the wafer W. If necessary, thesupport ring 150 may be provided with an electrostatic chuck or a clamp mechanism so as to fix the wafer to thesupport ring 150. Thesupport ring 150 is configured and arranged to prevent heat form being released from an outer edge of the wafer W so that the uniform heating of the wafer W is not deteriorated. - The
support ring 150 is connected to thesupport part 152 at outer end thereof. If necessary, a heat insulating member formed on quartz glass is interposed between thesupport ring 150 and thesupport part 152 so as to thermally protect themagnetic member 172. In the present embodiment, thesupport part 152 is formed as an opaque quartz member having a hollow cylindrical shape. Thebearing 160 is fixed to thesupport part 152 and the inner wall ofprocess chamber 110 so as to allow a rotation of thesupport part 152 while maintaining the negative pressure environment of theprocess chamber 110. Themagnetic member 172 is attached to the lower end of thesupport part 152. - The ring-like
permanent magnet 170 andmagnetic member 172, which are concentrically arranged, are magnetically coupled with each other, and thepermanent magnet 170 is rotated by themotor 330. Themotor 330 is driven by themotor driver 320, which is controlled by thecontrol part 300. - Consequently, when the
permanent magnet 170 rotates, the magnetically coupledmagnetic member 172 is rotated together with thesupport part 152, which results in rotation of the support ring and the wafer W. Although the rotation speed in the present embodiment is 90 r.p.m., the rotation speed may be determined based on a material and size of the wafer W (object to be processed) and a type and temperature of the process gas so that there is less effect of turbulence of gas within theprocess chamber 110 and stream of gas due to the rotation of the wafer W. Thepermanent magnet 170 and themagnetic member 172 may be reversed as long as they are magnetically coupled, or themagnetic member 172 may also be formed of a permanent magnet. - A description will now be given of an operation of the
RTP apparatus 100. First, the wafer W is carried in theprocess chamber 110 through a gate valve (not shown in the figure) by a conveyance arm of a cluster tool (not shown in the figure). When the conveyance arm supporting the wafer W reaches above thesupport ring 150, a lifter pin vertically moving system moves lifter pins (for example, three lifter pins) upward so as to protrude the lifter pins from thesupport ring 150 to support the wafer W. As a result, the wafer is transferred from the conveyance arm to the lifter pins, and, then, the conveyance arm returns out of theprocess chamber 110 through the gate valve. Thereafter, the gate valve is closed. The conveyance arm may return to a home position (not shown in the figure). - The lifter vertically moving mechanism retract the lifter pins below the surface of the
support ring 150, thereby placing the wafer W on thesupport ring 150. The lifter pin vertically moving mechanism may use a bellows so as to maintain the a negative pressure environment in the process chamber and prevent the atmosphere inside the process chamber from flowing out of theprocess chamber 110 during the vertically moving operation. - Thereafter, the controller controls the
lamp driver 310 so as to send an instruction to drive thelamps 130. In response to the instruction, thelamp driver 310 drives thelamps 130 so that thelamps 130 heat the wafer W at a temperature of about 800° C. Theheat treatment apparatus 100 according to the present embodiment improves the directivity of thelamps 130 by the action of thelens assemblies 122 and the platedpart 149 while removing the reflector, and, thereby, increasing the lamp density and consequently the power density. Thus, a desired high rate temperature rise of the wafer W can be achieved. A heat ray (radiation light) emitted by thelamps 130 is irradiated onto the surface of the wafer W by passing through thequartz window 120 so as to heat the wafer W at 800° C. with a heating rate of about 200° C./sec. - Generally, a periphery of the wafer W tends to release a greater amount of heat than the center portion thereof. However, the present embodiment can provide a high directivity and temperature control capability since the
lamps 130 according to the present invention are concentrically so as to enable a power control for each area. If theapparatus 100 uses the structure shown in FIG. 43, thebottom part 114A is located at the home position as shown in FIG. 50. Especially, the structure shown in FIG. 50 can provide an efficient rapid temperature rise since the wafer W hardly receives influence from thebottom part 114 a due to a large distance between the wafer W and thebottom part 114A as a cooling plate. Theexhaust part 190 forms a negative pressure environment in theprocess chamber 110 at or around the time of heating the wafer W. - At the same time the
control part 300 controls themotor driver 320 to send an instruction to drive themotor 330. In response to the instruction, themotor driver 320 drives themotor 330 so as to rotate the ring-like magnet 170. As a result, the support part 152 (or 152A) rotates, and the wafer W rates together with thesupport ring 150. Since the wafer W rotates, the temperature within the surface of the wafer W is maintained uniform during the heat treatment process. - The
quartz window 120 has a relatively small thickness due to the action of thelens assemblies 122, the reinforcingmembers 124 and thewaveguiding members 126, which provides the following advantages with respect to the heating process of the wafer W. - 1) The irradiation efficiency to the wafer W is not deteriorated since the
quartz window 120 having the reduced thickness absorbs less heat. - 2) A thermal stress fracture hardly occurs since the temperature difference between the front and back surfaces of the
quartz plate 121 of thequartz window 120 is small. - 3) In a case of a film deposition process, a deposition film an byproduct is hardly formed on the surface of the
quarts window 120 since a temperature rise in the surface of thequartz window 120 is small. - 4) A pressure difference between the negative pressure in the
process chamber 110 and the atmospheric pressure can be maintained even if the thickness of thequartz plate 121 is small since the mechanical strength of thequartz plate 121 is increased by thelens assemblies 122. - The temperature of the wafer W is measured by the
radiation thermometer 200, and thecontrol part 300 feedback-controls thelamp driver 310 based on the result of measurement. Since the wafer W is rotated, the temperature distribution on the surface of the wafer W is supposed to be uniform. However, if necessary, theradiation thermometer 200 may measure a temperature at a plurality of points on the surface of the wafer W so that thecontrol part 300 sends an instruction to change the output of the lamps with respect to a specific area of the wafer W when the result of measurement of theradiation thermometer 200 indicates that the temperature distribution on the surface of the wafer W is not uniform. Since the controllability of irradiation of heat is improved by the platedpart 149 and thelens assemblies 122, a desired part of the wafer W can be accurately heated with a desired degree. - The
radiation thermometer 200 has a simple structure in which a chopper and an LED is not used, the radiation thermometer is inexpensive, which contributes to miniaturization and economization of theheat treatment apparatus 100. Additionally, the temperature measured by the method of calculating effective emissivity is accurate. An electric characteristic of an integrated circuit formed in the wafer W is deteriorated due to diffusion of impurities when the wafer W is placed under a high-temperature environment for a long time. Accordingly, a rapid heating and a rapid cooling are required, which also requires a temperature control of the wafer W. The method of calculating effective emissivity according to the preset invention satisfies such requirements. Thus, theRTP apparatus 100 can provide a high-quality heat treatment. - After the wafer W is heated at the desired temperature, a process gas is introduced into the
process chamber 110 through the gas introducing part (not shown in the figure). After the heat treatment is completed, thecontroller 300 controls thelamp driver 310 so as to stop the heating by thelamps 130. Then, the lamp driver stops to supply a power to thelamps 130. If theapparatus 100 uses the structure shown in FIG. 43, thecontroller 300 controls the vertical movingmechanism 117 so move thebottom part 114A to a cooling position. Additionally, helium gas having a high heat conductivity is supplied between the wafer W and thebottom part 114A as shown in FIG. 46. Thereby, the cooling efficiency to the wafer W is increased, and a rapid cooling can be achieved with a relatively small power consumption. The cooling rate achieved by theapparatus 100 is about 200° C./sec. - After the heat treatment, the wafer W is carried out of the
process chamber 110 by the conveyance arm of the cluster tool through the gate valve in the reverse sequence. Thereafter, if necessary, the conveyance arm conveys the wafer W to a next stage apparatus such as a film deposition apparatus. - The present invention is not limited to the specifically disclosed embodiments, and variations and modifications may be made without departing from the scope of the present invention.
- The present application is based on Japanese priority applications No. 2000-247591 filed on Aug. 17, 2000 and No. 2000-343209 filed on Nov. 10, 2000, the entire contents of which are herein incorporated by reference.
Claims (30)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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JP2000247591A JP2002064069A (en) | 2000-08-17 | 2000-08-17 | Heat treatment equipment |
JP2000-247591 | 2000-08-17 | ||
JP2000343209A JP4666427B2 (en) | 2000-11-10 | 2000-11-10 | Quartz window and heat treatment equipment |
JP2000-343209 | 2000-11-10 |
Publications (2)
Publication Number | Publication Date |
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US20020030047A1 true US20020030047A1 (en) | 2002-03-14 |
US6437290B1 US6437290B1 (en) | 2002-08-20 |
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US09/930,495 Expired - Fee Related US6437290B1 (en) | 2000-08-17 | 2001-08-16 | Heat treatment apparatus having a thin light-transmitting window |
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