+

US20020030047A1 - Heat treatment apparatus having a thin light-transmitting window - Google Patents

Heat treatment apparatus having a thin light-transmitting window Download PDF

Info

Publication number
US20020030047A1
US20020030047A1 US09/930,495 US93049501A US2002030047A1 US 20020030047 A1 US20020030047 A1 US 20020030047A1 US 93049501 A US93049501 A US 93049501A US 2002030047 A1 US2002030047 A1 US 2002030047A1
Authority
US
United States
Prior art keywords
heat treatment
treatment apparatus
processed
light
wafer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US09/930,495
Other versions
US6437290B1 (en
Inventor
Shouqian Shao
Yicheng Li
Takashi Shigeoka
Takeshi Sakuma
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Electron Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2000247591A external-priority patent/JP2002064069A/en
Priority claimed from JP2000343209A external-priority patent/JP4666427B2/en
Application filed by Individual filed Critical Individual
Assigned to TOKYO ELECTRON LIMITED reassignment TOKYO ELECTRON LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LI, YICHENG, SAKUMA, TAKESHI, SHAO, SHOUGIAN, SHIGEOKA, TAKASHI
Publication of US20020030047A1 publication Critical patent/US20020030047A1/en
Application granted granted Critical
Publication of US6437290B1 publication Critical patent/US6437290B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B31/00Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor
    • C30B31/06Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor by contacting with diffusion material in the gaseous state
    • C30B31/12Heating of the reaction chamber
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/48Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating by irradiation, e.g. photolysis, radiolysis, particle radiation
    • C23C16/481Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating by irradiation, e.g. photolysis, radiolysis, particle radiation by radiant heating of the substrate
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • C30B25/10Heating of the reaction chamber or the substrate
    • C30B25/105Heating of the reaction chamber or the substrate by irradiation or electric discharge

Definitions

  • the present invention generally relates to heat treatment apparatuses and more particularly to a heat treatment apparatus which performs an anneal process or a chemical vapor deposition (CVD) process by heating an object to be processed, such as a single crystalline substrate or a glass substrate, with a lamp and a quartz window used for such a heat treatment apparatus.
  • the present invention is suitable for a rapid thermal processing (RTP: Rapid Thermal Processing) used for manufacturing semiconductor devices, such as a memory or an integrated circuit (IC).
  • the rapid thermal processing (RTP) includes rapid thermal annealing (RTA), rapid thermal cleaning (RTC), rapid thermal chemical vapor deposition (RTCVD), rapid thermal oxidization (RTO) and rapid thermal nitriding (RTN).
  • the heat radiation lamp 14 is arranged so as to opposite to the placement stage 12 with a light-transmitting window 13 formed of a quartz made flat plate.
  • the placement stage 12 supports the peripheral edge of the wafer W from a lower part side.
  • the wafer W is heated at a predetermined temperature while supplying a process gas from a side wall of one side of the process chamber 11 and exhausting from the side wall of another side.
  • a rotation mechanism to rotate the placement stage 12 maintains airtightness of the process chamber 11 by using a magnetic coupling.
  • the rotation mechanism is illustratively shown in FIG. 1.
  • the lamp light is absorbed by quartz, which reduces the irradiation efficiency to the object to be processed.
  • the quartz window may be damaged due to difference in the thermal stress between the front side and back side of the quartz window.
  • the lamp is curved similar to the quartz window, a distance between the object to be processed and the lamp is increased, which deteriorates the directivity of the lamp.
  • a heat treatment apparatus comprising: a process chamber which defines a process space for processing an object to be processes; a placement stage provided in the process chamber so as to place the object to be processed thereon; a gas supply part which supplies to the process chamber a process gas for processing the object to be processed; a light-transmitting window provided as a part of the process chamber so that the light-transmitting window is opposite to the object to be processed placed on the placement stage; and a heating unit which comprises a heat radiation lamp provided on an opposite side of the process chamber with respect to the light-transmitting window, wherein the light-transmitting window constitutes a convex lens part which is formed on a periphery of the light-transmitting window and protrudes into the process space.
  • a heat treatment apparatus comprising: a process chamber in which a heat treatment is applied to an object to be processed; a heat source which heats the objects to be processed by irradiating a radiation light onto the object to be processed; and a quartz window provided between the object to be processed and the heat source, the quartz window comprising: a plate made of quartz; and a lens part fixed to the plate so as to improve a directivity of the radiation light emitted by the heat source and increase a mechanical strength of the plate.
  • the heat source may have plurality of lamps, and the lens part may have a plurality of lens elements corresponding to the lamps. Each of the lens element improves the directivity of the radiation light emitted by a respective one of the lamps.
  • the lens part may be provided on a surface of the plate facing the object to be processed. The lens part may be provided on both a surface of the plate facing the object to be processed and a surface opposite to the surface facing the object to be processed.
  • the plate of the quartz window may have at least one reinforcing member which increases a strength of said plate. Accordingly, the thickness of quartz plate can be further reduced, thereby decreasing an amount radiation light absorbed by the quartz plate.
  • the thickness of the plate of the quartz window is preferably equal to or less than 7 mm. More preferably, the thickness of the plate of the quartz window is equal to or less than 5 mm.
  • the reinforcing member may made of aluminum.
  • a plurality of reinforcing members may be provided on the plate, and at least one waveguiding part made of quartz may be provided between adjacent reinforcing members, the waveguiding part transmitting the radiation light passed through said lens part and said plate toward the object to be processed.
  • a total reflection occurs within the waveguiding part.
  • FIG. 2 is an illustration showing an arrangement of a single end lamp and a reflector
  • FIG. 12 is a cross-sectional view of a curved light-transmitting window along which a plurality of heat radiation lamps are arranged;
  • FIG. 13 is a cross-sectional view of a heat treatment apparatus according to a third embodiment of the present invention.
  • FIG. 16 is a cross-sectional view of the quartz window taken along a line XVI-XVI of FIG. 14;
  • FIG. 19 is an enlarged cross-sectional view of a part of a quartz window which is a variation of the quartz window shown in FIG. 13.
  • FIG. 29 is a side view of the lamp shown in FIG. 27;
  • FIG. 30 is a plan view of a heating unit which is a variation of the heating unit shown in FIG. 26;
  • FIG. 44 is a graph for explaining a method of calculating an effective emissivity according to the present invention.
  • FIG. 46 is a graph for explaining a method of calculating an effective emissivity according to the present invention.
  • FIG. 47B is an illustration showing a view angle ⁇ of a rod
  • FIG. 51 is a cross-sectional view of the heat treatment apparatus shown in FIG. 49 in a state in which the wafer is being cooled;
  • FIG. 52 is a cross-sectional view of a helium gas supply part
  • a part of a housing 23 which forms the annular groove 21 , extends on the downward side.
  • An outer ring part is rotatably supported about the vertical axis on the outside of the housing 23 via a bearing parts having an upper part 42 and a lower part.
  • a supply passage 44 of a purge gas such as nitrogen (N 2 ) is formed on an outer portion of the housing 23 which forms the annular groove 21 of the process chamber 2 .
  • An end of the supply passage communicates with a position directly above the bearing part 41 in the annular groove 21 .
  • a plurality of exhaust passages 45 of the purge gas is formed along a circumferential direction of an inner body part 23 forming the annular groove 21 .
  • the purge gas enters the annular groove 21 from a gas supply pipe (not shown in the figure) via the supply passage 44 , and is exhausted from an exhaust pipe (not shown in the figure) via the exhaust passage 45 by passing through an interior of the bearing part 41 .
  • a bottom plate 33 constitutes a bottom part of the process chamber 2 under the wafer W.
  • a temperature detecting means 25 is inserted into the bottom plate 33 .
  • the temperature detecting means 25 comprises, for example, a plurality of radiation thermometers for measuring a temperature of the wafer W from the backside.
  • the radiation thermometers are arranged along a radial direction of the wafer W so that temperatures of a plurality of positions on the wafer W from the center to the peripheral edge can be measured.
  • the bottom plate 33 is provided with lift pins (not shown in the figure) which lifts the wafer W when the wafer is transferred to or from a conveyance arm provided outside the process chamber 2 .
  • the heating unit 5 is larger than the wafer W.
  • the heating unit 5 comprises a plurality of heat radiation lamps 51 and a reflective plate 52 .
  • the heat radiation lamps 51 constitute heating means for heating the wafer W by irradiating lights onto the wafer W.
  • the reflective plate 52 has a circular cross section, and is provided so as to encircle a surface of each lamp 51 opposite to the wafer W.
  • a power supply system of the heat radiation lamps 52 is accommodated in a housing 53 .
  • halogen lamps are used as the heat radiation lamps 51 .
  • the halogen lamps are concentrically arranged with the center being aligned with the center of the wafer W so that a plurality of generally annular light-emitting areas having different radii are formed.
  • the process chamber 110 is formed of stainless steel or aluminum.
  • the quartz window 120 is connected to a top of the process chamber 110 .
  • the side wall of the process chamber 110 and the quartz window 12 define a process space in which an object W to be processed (semiconductor wafer: hereinafter referred to as a wafer W) is subjected to a heat treatment.
  • the support ring 150 on which the wafer W is placed and a support part 152 connected to the support ring 150 are arranged in the process space.
  • the process space is maintained to be a predetermined negative pressure by the exhaust part 190 .
  • the wafer W is carried in or out from the process chamber through a gate valve (not shown in the figure) provided to the sidewall of the process chamber 110 .
  • the quartz window 120 is attached to the process chamber in an airtight manner so as to maintain the negative pressure environment inside the process chamber 110 and transmit a heat radiation light emitted from lamps of the heating unit 140 .
  • the lens assembly 122 serves to strengthen the quartz window 120 and increase the directivity of the radiation light form the lamps of the heating unit 140 .
  • each of the lens assemblies 122 has a plurality of lens elements 123 ach having a light converging action.
  • the lens assemblies 122 are arranged parallel to the direction X since the lamps of the heating unit 140 are arranged in the direction X. That is, the direction of arrangement of the lens assemblies 122 is dependent on the direction of arrangement of the lamps of the heating unit 140 .
  • the window lens assemblies 122 are provided only on one side of the quartz plate 121 which side is opposite to the lamps 130 of the heating unit 140 , the window lens assemblies 122 may be provided on both sides or on the other side which is not opposite to the lamps 130 .
  • the quartz plate 121 Since the strength with respect to thermal deformation of the quartz plate 121 is increased by the lens assemblies 122 , there is no need to form the quartz plate 121 in a domal shape which curves in a direction protruding from the process chamber 110 as in the conventional apparatus. Accordingly, the quartz plate 121 has a flat shape. Since the quartz window formed in a domal shape increases a distance between the wafer W and the lamps 130 of the heating unit 140 , there is a problem in that the directivity of the lamps is deteriorated. The present embodiment solves such a problem relating to the directivity of the lamps. Although the quartz plate 121 and the lens assemblies 122 are joined by welding in the present embodiment, the quartz plate 121 and the lens assemblies 122 may be joined by other methods or integrally formed with each other.
  • the present embodiment solves the problem in that the lamp light is absorbed by the quartz window which results in deterioration of the irradiation efficiency.
  • the quartz window is prevented from being damaged due to a difference in temperature between the front surface and the back surface of the quartz window 121 since the difference can be maintained smaller than that of the conventional quartz window. That is, the present embodiment solves the problem in that the conventional quartz window is easily destroyed due to a difference in the thermal stress between the front surface facing the lamps and the back surface opposite to the front surface when a rapid thermal process is performed as in a rapid thermal process (RTP) apparatus.
  • RTP rapid thermal process
  • the quartz window 120 solely constituted by the quartz plate, which does not have the lens assemblies 122 , may reduce an amount of light absorbed by the quartz plate 121 when the thickness of the quartz plate 121 is small as in the present embodiment, it is possible that the quartz window 120 is easily destroyed since the quartz plate 120 cannot withstand a pressure difference between the negative pressure in the process chamber and the atmospheric pressure. Accordingly, there is a problem in that the quartz window cannot be used with a process which must be performed under a negative pressure environment.
  • the lens assemblies solve such a problem since the lens assemblies 122 reinforces the quartz plate 121 .
  • FIG. 19 is an enlarged cross-sectional view of a part of the quartz window 120 A.
  • the quartz window 120 A has reinforcing members (or columns) 124 , which are formed under the passage 128 and parallel to the passage 128 .
  • Each of the reinforcing members 124 is made of aluminum or stainless steel, and has a square cross section.
  • the reinforcing members 124 have cooling pipes 125 therein, and increase a strength of the quartz window 120 A.
  • the radiation light from the lamps 130 is reflected by sidewalls of reinforcing members 124 , and reaches the wafer W placed under the quartz window.
  • the cooling pipe 125 has a cooling function which cools both the reinforcing members 124 and the quartz plate 121 . If the reinforcing members 124 are made of aluminum, an appropriate temperature control (cooling) is needed since the aluminum may be deformed or melted at a temperature in the range of 200° C. to 700° C.
  • the temperature control by the cooling pipe 125 may be the same as the cooling pipe 116 , or other known methods may be applied.
  • the irradiance is maximum near the center of the wafer W, but the maximum value is not so large.
  • the half value width forms a generally oblong shape, and the maximum of the half value with is about 100 mm.
  • the directivity is improved as the maximum value is increased.
  • the controllability of the half value width can be improved as it approaches a circle and its value is decreased.
  • the controllability represents easiness of process when it is needed to heat a desired position of the wafer W (that is, irradiate the radiation light) and heat if not applied to a position where it is not desired to heat. Comparing FIGS. 21 and 22 with FIGS. 24 and 25, it can be appreciated that the quartz window 120 B is superior to the quartz window 120 C in both directivity and controllability.
  • Each separation wall 144 has a width of about 12 mm, and is located above the passage 128 shown in FIG. 14 and the reinforcing member 124 shown in FIG. 19 and between the adjacent grooves 143 arranged in the direction X shown in FIG. 26.
  • a pair of cooling pipes 145 arranged in parallel to the passage 128 (in the direction X shown in FIG. 26) are put in contact with the separation walls 144 .
  • About 0.3 to 0.8 m 3 of air can flow through the groove 143 excluding the light emitting part 134 so as to cool the surface of the light-emitting part 134 .
  • the lamps 130 of the present embodiment can be cooled by the air cooing arrangement and the cooling pipes 145 .
  • FIG. 32 is a cross-sectional view for explaining the cooling arrangement of the lamps 130 arranged in the direction X in FIG. 26.
  • FIG. 33 is a side view of the lamp 130 shown in FIG. 32.
  • FIG. 34 is a plan view of the lamp 130 shown in FIG. 32.
  • the plurality of lamps 130 arranged in the same row are subjected to heat exhaust (air cooling) by a blower.
  • the exhaust efficiency by the blower is as good as 4 m 3 /min with respect to that achieved by a rectilinear arrangement of the lamps.
  • the plated part 149 if formed of a metal film such as a gold film or silver film which reflects a radiation light at a high reflectance.
  • the plated part 149 may be formed by electroplating such as hard gold plating or pure gold plating.
  • the thickness of the plated part 149 can be about 10 ⁇ m so as to sufficiently prevent light leakage from the light-emitting part 134 . It should be noted that the plated part 149 is provided for improving the directivity, and there is no specific range of high-reflectivity of the plated part 149 .
  • each lens arranged directly under the respective one of the lamps 130 A has a length corresponding to the light-emitting part 136 shown in FIG. 40 and a width which covers a pair of lamps 130 A shown in FIG. 41.
  • the horizontal part 137 b is concentrically arranged with the dashed circles shown in FIG. 26.
  • the dashed circle shown in FIG. 38 is concentric with the dashed circles shown in FIG. 26.
  • the length of the horizontal part 137 b is determined by a length of a circle which is concentric with the dashed circles shown in FIG. 14 and a number of lamps 130 B arranged along the circle.
  • the radii of the horizontal parts 137 b of the lams 130 B arranged along different concentric circles differ from each other.
  • the plurality of lamps 130 can be mounted at a high density.
  • the lamps can be arranged can be mounted at a lamp density which is four times the lamp density of the arrangement having a reflector inclined by 45 degrees. Accordingly, the power density can be increased and, therefore, the heat treatment apparatus is suitable for RTP.
  • the radiation thermometers 200 A, 200 B and 200 C are provided on the opposite side of the lamps 130 with respect to the wafer W. Although the present invention does not exclude the structure in which the radiation thermometers 200 A, 200 B and 200 C is provided on the same side with the lamps 130 , it is preferable that the radiation light of the lamps 130 is prevented from being incident on the radiation thermometers 200 A, 200 B and 200 C.
  • the radiation thermometers 200 A and 200 B are mounted on a bottom part 114 of the process chamber 110 . More specifically, the radiation thermometers 200 A and 200 B are inserted into respective cylindrical through holes 115 a and 115 b of the bottom part 114 .
  • a surface 114 a of the bottom part 114 facing the interior of the process chamber 110 serves as a reflective plate (high-reflectance surface) by being subjected to a sufficient polishing. This is because if the surface 114 a is a low reflectance surface such as a black surface, the surface 114 a absorbs heat of the wafer W, which results in an undesired increase in the output of the lamps 130 .
  • Each of the optical fibers 220 A and 220 B comprises a core which transmits a light and a concentric clad which covers the core.
  • the core and the clad are made of a transparent dielectric material such as glass or plastic.
  • the refractive index of the clad is slightly smaller than that of the core, thereby achieving a total reflection.
  • the core can propagate a light without leaking outside.
  • the radiation thermometers 200 A and 200 B use a core and clad of different materials.
  • the photodiode (PD) 230 has an image forming lens, a silicon (Si) photocell and an amplification circuit so as to convert the radiation light incident on the image forming lens into a voltage, which is an electric signal representing radiation intensities E 1 (T) and E 2 (T), and send the electric signal to the control part 300 .
  • the control part 300 comprises a CPU, an MPU, other processors, and memories such as a RAM and a ROM so as to calculate an emissivity ⁇ and a substrate temperature T of the wafer W based on the radiation intensities E 1 (T) and E 2 (T).
  • a prediction equation which can establish the above-mentioned four conditions can be defined as the following equation (8).
  • the radiation thermometer 200 performs the conversion of temperature based on radiation light flux (W).
  • W radiation light flux
  • equation (17) can be changed into the following equation (18).
  • ⁇ eff 02 (1 ⁇ 0.2 ) ⁇ + ⁇ 0.2 ⁇ /[1 ⁇ F ⁇ r ⁇ (1 ⁇ )] (26)
  • the above-mentioned calculation method obtains an emissivity of the wafer W by the two radiation thermometers 200 A and 200 B having different NAs, the emissivity can be obtained based on the above-mentioned equation (9) by changing a ratio of D 1 /D 2 .
  • FIG. 43 is an illustration for explaining such a method.
  • the process gas includes N 2 , Ar, etc.; if the process is an oxidation process, the process gas includes O 2 , H 2 , H 2 O, NO 2 , etc.; if the process is a nitriding process, the process gas includes N 2 , NH 3 , etc.; if the process is a film deposition process, the process gas includes NH 3 , SiH2, Cl 2 , SiH 4 , etc. It should be noted that the process gas is not limited the above-mentioned gasses.
  • the inner surface of the supply pipe may be coated by an insulating material such as PTFE (Teflon), PPA, polyimide, PBI, etc. Additionally, the inner surface of the supply pipe may be subjected to an electropolishing. Further, a dust particle filter may be provided to the gas supply passage.
  • the present invention is applicable to a relative movement of the wafer W and the lamps 130 .
  • the rotating mechanism of the wafer W comprises the support ring 150 , the permanent magnet 170 , a ring-like magnetic member 172 , a motor driver 320 and a motor 330 .
  • the support ring 150 has a ring shape and is made of a heat resistant ceramic such as SiC.
  • the support ring 150 serves as a placement stage on which the wafer W is placed.
  • the support ring 150 supports a periphery of the backside of the wafer W. If necessary, the support ring 150 may be provided with an electrostatic chuck or a clamp mechanism so as to fix the wafer to the support ring 150 .
  • the support ring 150 is configured and arranged to prevent heat form being released from an outer edge of the wafer W so that the uniform heating of the wafer W is not deteriorated.
  • the controller controls the lamp driver 310 so as to send an instruction to drive the lamps 130 .
  • the lamp driver 310 drives the lamps 130 so that the lamps 130 heat the wafer W at a temperature of about 800° C.
  • the heat treatment apparatus 100 improves the directivity of the lamps 130 by the action of the lens assemblies 122 and the plated part 149 while removing the reflector, and, thereby, increasing the lamp density and consequently the power density.
  • a desired high rate temperature rise of the wafer W can be achieved.
  • a heat ray (radiation light) emitted by the lamps 130 is irradiated onto the surface of the wafer W by passing through the quartz window 120 so as to heat the wafer W at 800° C. with a heating rate of about 200° C./sec.
  • the present embodiment can provide a high directivity and temperature control capability since the lamps 130 according to the present invention are concentrically so as to enable a power control for each area.
  • the apparatus 100 uses the structure shown in FIG. 43, the bottom part 114 A is located at the home position as shown in FIG. 50.
  • the structure shown in FIG. 50 can provide an efficient rapid temperature rise since the wafer W hardly receives influence from the bottom part 114 a due to a large distance between the wafer W and the bottom part 114 A as a cooling plate.
  • the exhaust part 190 forms a negative pressure environment in the process chamber 110 at or around the time of heating the wafer W.
  • the quartz window 120 has a relatively small thickness due to the action of the lens assemblies 122 , the reinforcing members 124 and the waveguiding members 126 , which provides the following advantages with respect to the heating process of the wafer W.
  • the radiation thermometer 200 has a simple structure in which a chopper and an LED is not used, the radiation thermometer is inexpensive, which contributes to miniaturization and economization of the heat treatment apparatus 100 . Additionally, the temperature measured by the method of calculating effective emissivity is accurate. An electric characteristic of an integrated circuit formed in the wafer W is deteriorated due to diffusion of impurities when the wafer W is placed under a high-temperature environment for a long time. Accordingly, a rapid heating and a rapid cooling are required, which also requires a temperature control of the wafer W. The method of calculating effective emissivity according to the preset invention satisfies such requirements. Thus, the RTP apparatus 100 can provide a high-quality heat treatment.
  • a process gas is introduced into the process chamber 110 through the gas introducing part (not shown in the figure).
  • the controller 300 controls the lamp driver 310 so as to stop the heating by the lamps 130 . Then, the lamp driver stops to supply a power to the lamps 130 .
  • the controller 300 controls the vertical moving mechanism 117 so move the bottom part 114 A to a cooling position. Additionally, helium gas having a high heat conductivity is supplied between the wafer W and the bottom part 114 A as shown in FIG. 46. Thereby, the cooling efficiency to the wafer W is increased, and a rapid cooling can be achieved with a relatively small power consumption.
  • the cooling rate achieved by the apparatus 100 is about 200° C./sec.
  • the wafer W is carried out of the process chamber 110 by the conveyance arm of the cluster tool through the gate valve in the reverse sequence. Thereafter, if necessary, the conveyance arm conveys the wafer W to a next stage apparatus such as a film deposition apparatus.
  • a next stage apparatus such as a film deposition apparatus.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)

Abstract

A quartz window decreases an amount of absorption of heat from a heat source while maintaining a pressure difference between the pressure inside a process chamber and an atmospheric pressure. The process chamber defines a process space for processing an object to be processes. A placement stage is provided in the process chamber so as to place the object to be processed thereon. A gas supply part which supplies to the process chamber a process gas for processing the object to be processed. The quartz window is provided as a part of the process chamber so that the quartz window is opposite to the object to be processed placed on the placement stage. A heating unit has a heat radiation lamp provided on an opposite side of the process chamber with respect to the light-transmitting window. The quartz window constitutes a convex lens part which is formed on a periphery of the quartz window and protrudes into the process space.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The present invention generally relates to heat treatment apparatuses and more particularly to a heat treatment apparatus which performs an anneal process or a chemical vapor deposition (CVD) process by heating an object to be processed, such as a single crystalline substrate or a glass substrate, with a lamp and a quartz window used for such a heat treatment apparatus. The present invention is suitable for a rapid thermal processing (RTP: Rapid Thermal Processing) used for manufacturing semiconductor devices, such as a memory or an integrated circuit (IC). The rapid thermal processing (RTP) includes rapid thermal annealing (RTA), rapid thermal cleaning (RTC), rapid thermal chemical vapor deposition (RTCVD), rapid thermal oxidization (RTO) and rapid thermal nitriding (RTN). [0002]
  • 2. Description of Related Art [0003]
  • There is a single wafer heat treatment apparatus as one of semiconductor manufacturing apparatuses, which performs an annealing process or a CVD process by heating a semiconductor wafer (hereinafter simply referred to as a wafer) with a heat radiation lamp. [0004]
  • FIG. 1 shows an example of a conventional heat treatment apparatus. The heat treatment apparatus shown in FIG. 1 comprises a [0005] process chamber 11, a placement stage 12 on which a wafer W is placed and a heat radiation lamp 14. The placement stage 12 having a ring-like shape is provided in the process chamber 11, and is rotatable about the vertical axis thereof.
  • The [0006] heat radiation lamp 14 is arranged so as to opposite to the placement stage 12 with a light-transmitting window 13 formed of a quartz made flat plate. The placement stage 12 supports the peripheral edge of the wafer W from a lower part side. The wafer W is heated at a predetermined temperature while supplying a process gas from a side wall of one side of the process chamber 11 and exhausting from the side wall of another side. It should be noted that a rotation mechanism to rotate the placement stage 12 maintains airtightness of the process chamber 11 by using a magnetic coupling. The rotation mechanism is illustratively shown in FIG. 1.
  • The [0007] placement stage 12 is formed of a material having a superior heat-resistance so that the placement stage 12 is not transformed at a processing temperature of about 1000° C. SiC (silicon carbide) is used as such a material.
  • In the above-mentioned heat treatment apparatus, both the [0008] placement stage 12 and the wafer W are heated with the heat radiation lamp 14 from an upper part side. When the placement stage 12 is formed by SiC, the temperature rise of the placement stage 12 is slower than that of the wafer W since the heat capacity of SiC is larger than Si (silicone) which forms the wafer W.
  • For this reason, at the time of heating the wafer W, the temperature of the [0009] placement stage 12 is lower than the temperature of the wafer W. Therefore, heat of the circumferential edge of the wafer W transmits to the placement stage 12, and, thus, the temperature of the circumferential edge of the wafer W becomes lower than the temperature of the central part thereof. Consequently, a temperature distribution is generated in the surface of the wafer W.
  • On the other hand, heating of the wafer W at a temperature higher than about 800° C. generates a crystal defect referred to as a slip in the wafer W. The slip is easily generated as a temperature difference within the surface of the wafer W increases. [0010]
  • Therefore, in the conventional equipment, the wafer W cannot be heated at a high rate so that a delay in raising the temperature of the [0011] placement stage 12 does not become large, that is, the temperature difference within the surface of the wafer W is maintained small. This is one of causes that prevents improvement in a throughput. As for measures to solve the problem, it can be considered to increase an amount of heat radiation on the side of the periphery of the wafer W, such a method is difficult to realize since it is difficult to increase directivity of the heat radiation lamp 14 due to its construction.
  • Irradiation areas corresponding to a plurality of [0012] heat radiation lamps 14 are formed on the wafer W. A distance between the heat radiation lamp 14 and the wafer W cannot be made small from the point such as reservation of a conveyance area. For this reason, the directivity of each heat radiation lamp 14 is bad. Specifically, the directivity of a unit which is formed by combining a single heat radiation lamp and a reflector is bad. That is, a plurality of irradiation areas overlap with each other and the overlapping area between the irradiation areas is large since each above-mentioned irradiation domain spreads.
  • A plurality of probes of the radiation thermometer (not shown) is arranged at a plurality of positions, respectively, underneath the wafer W. The magnitude of heat dissipation from the wafer W differ from the position at which the probe of the radiation thermometer is arranged to position at which the probe is not arranged. Therefore, in order to heat the wafer W uniformly over the whole surface, it is necessary to adjust the illumination distribution by the light (radiation heat) from the [0013] lamp 14 on the wafer W. However, if the above-mentioned overlapping area between the irradiation areas is large, adjustment of an illumination distribution is difficult.
  • Additionally, in order to manufacture a semiconductor integrated circuit, various kinds of heat treatment, such as a film deposition process, an anneal process, an oxidization diffusion process, a sputtering process, an etching process and a nitriding processing may be repeatedly performed on a silicon wafer a plurality of times to silicone boards. Since yield rate and quality of semiconductor manufacturing processes can be improved, the RTP technology to rise and drop the temperature of the wafer (object to he processed) has attracted attention. A conventional RTP apparatus generally comprises: a single-wafer chamber (process chamber) for accommodating an object to be processed (for example, a semiconductor wafer, a glass substrate for photograph masks, a glass substrate for a liquid-crystal display or a substrate for optical discs); a reflector (reflective board) arranged at the opposite side of the object to be processed with respect to a quartz window arranged in the interior of the process chamber; and a heating lamp (for example, halogen lamp) arranged at an upper part or above the quartz window, and the lamp. [0014]
  • The reflector is made of aluminum, and gold plating is given to a reflective part thereof. A cooling mechanism such as a cooling pipe is provided so as to prevent temperature breakage of the reflector (for example, exfoliation of gold plating due to a high temperature). The cooling mechanism is provided so as to prevent the reflector from being an obstacle of cooling the object to be processed at the time of cooling. The rapid temperature rising demanded for the RTP technology is dependent on the directivity of the optical irradiation to the object to be processed and the power density of the lamp. [0015]
  • FIG. 2 is an illustration showing an arrangement of a single end lamp and a reflector. As shown in FIG. 2, the directivity with respect to the object to be processed arranged underneath the [0016] single end lamp 15 having only one electrode part 16 and the energy efficiency of the lamp 15 is maximum when a degree of an angle a of inclination of the reflector 17 relative to the lamp 15 is set to 45 degrees.
  • The quartz window may be in the shape of a board, or can be in the form of tube which can accommodate the object to be processed. When maintaining a negative pressure environment in the process chamber by evacuating gasses in the process chamber by a vacuum pump, a thickness of the quartz window is set to, for example, about 30 to 40 mm so as to maintain the pressure difference between the internal pressure and the atmospheric pressure. The quartz window may be formed in a curved shape having a reduced thickness so as to prevent generation of a thermal stress due to temperature difference generated by a temperature rise. [0017]
  • A plurality of halogen lamps are arranged so as to uniformly heat the object to be processed. The reflector reflects the infrared rays irradiated from the halogen lamps toward the object to be processed. The process chamber is typically provided with a gate valve on a sidewall thereof so as to carry in and out the object to be processed. Moreover, a gas supply nozzle, which introduces a process gas used for heat treatment, is connected to the sidewall of the process chamber. [0018]
  • The temperature of the object to be processed affects the quality of process such as, for example, a thickness of a film in a film deposition process, etc. For this reason, it is necessary to know the correct temperature of the object to be processed. In order to attain high-speed heating and high-speed cooling, a temperature measuring device which measures the temperature of the object to be processed is provided in the process chamber. The temperature measuring device may be constituted by a thermocouple. However, since it is necessary to bring the thermocouple into contact with the object to be processed, there is a possibility that the processed body is polluted with the metal which constitutes the thermocouple. Therefore, there is proposed a payro meter as a temperature measuring device which detects an infrared intensity emitted and computes a temperature of an object to be processed from the back side thereof based on the detected infrared intensity. The payro meter computes the temperature of the object to be processed by carrying out a temperature conversion by an emissivity of the object to be processed according to the following expression: [0019]
  • Em(T)=εEBB(T)  (1)
  • where, E[0020] BB(T) expresses a radiation intensity from a black body having the temperature T; Em(T) expresses a radiation intensity measured from the object to be processed having the temperature T; ε epsilon expresses a rate of radiation of the object to be processed.
  • In operation, the object to be processed is introduced into the process chamber through the gate valve. The peripheral portion of the object to be processed is supported by a holder. At the time of heat treatment, process gases such as nitrogen gas and oxygen gas, are introduced into the process chamber through the gas supply nozzle. On the other hand, the infrared ray irradiated from the halogen lamps is absorbed by the object to be processed, thereby, rising the temperature of the object to be processed. However, the thickness of the conventional quartz window is as thick as several 10 mm. For this reason, there are the following problems. [0021]
  • First, the lamp light is absorbed by quartz, which reduces the irradiation efficiency to the object to be processed. Second, since a difference in temperature arises between a lamp side and its opposite side at the time of rapid temperature rising such as in RTP, the quartz window may be damaged due to difference in the thermal stress between the front side and back side of the quartz window. Third, if the lamp is curved similar to the quartz window, a distance between the object to be processed and the lamp is increased, which deteriorates the directivity of the lamp. Fourth, when the temperature of the quartz window rises, a deposition film or a byproduct may be formed on the surface of the quartz window especially when a film deposition process is performed, and, thus, a temperature repeatability cannot be maintained and the number of cleaning operations applied to a process chamber is increased. [0022]
  • On the other hand, absorption of the lamp light by the quartz window can be decreased by decreasing its thickness. However, if the thickness of the quartz window decreases, the quartz window cannot withstand the pressure difference between the negative pressure inside the process chamber and an atmospheric pressure and the quartz window may easily be destroyed. Thus, there is a problem in that the quartz window having a reduced thickness cannot be used for a process chamber which forms a negative pressure therein. Further, since the radiation light form a heat source is introduced into the object to be processed while being diffused, the directivity of the radiation light is not sufficient, and there is a demand for improving the directivity. [0023]
  • SUMMARY OF THE INVENTION
  • It is a general object of the present invention to provide an improved and useful quartz window and heat treatment apparatus in which the above-mentioned problems are solved. [0024]
  • A more specific object of the present invention is to provide a quartz window which can decrease an amount of absorption of heat from a heat source while maintaining a pressure difference between the pressure inside a process chamber and an atmospheric pressure. [0025]
  • Another object of the present invention is to heat an object to be processed with heat radiation lamps with less temperature difference within an entire surface of an object to be processed. [0026]
  • A further object of the present invention is to improve a directivity of a heat radiation lamp so as to achieve easy adjustment of the illumination distribution on the object to be processed. [0027]
  • In order to achieve the above-mentioned objects, there is provided according to one aspect of the present invention a heat treatment apparatus comprising: a process chamber which defines a process space for processing an object to be processes; a placement stage provided in the process chamber so as to place the object to be processed thereon; a gas supply part which supplies to the process chamber a process gas for processing the object to be processed; a light-transmitting window provided as a part of the process chamber so that the light-transmitting window is opposite to the object to be processed placed on the placement stage; and a heating unit which comprises a heat radiation lamp provided on an opposite side of the process chamber with respect to the light-transmitting window, wherein the light-transmitting window constitutes a convex lens part which is formed on a periphery of the light-transmitting window and protrudes into the process space. [0028]
  • According to the present invention, a light traveling from the heat radiation lamp toward outside of the object to be processed is deflected toward inside by the convex lens part. Thus, heat radiation energy emitted by the heat radiation lamp can be efficiently used. Additionally, if a temperature rising rate is increased when heating the object to be processed, uniformity within the surface of the object to be processed can be maintained high. In a case in which the object to be processed is a silicon wafer, generation of a slip, which is a crystal defect, can be prevented. [0029]
  • In the heat treatment apparatus according to the present invention, the placement stage may support a periphery of the object to be processed. Additionally, the placement stage may have a heat capacity greater than that of the object to be processed. In one embodiment, the object to be processed may be a silicon wafer and said placement stage is made of silicon carbide. The heat radiation lamp may be located at a focal point of the convex lens part. Further, the placement stage may be rotatable relative to the heat radiation lamp about a vertical axis thereof. [0030]
  • Additionally, there is provided according to another aspect of the present invention a heat treatment apparatus comprising: a process chamber which defines a process space for processing an object to be processes; a placement stage provided in the process chamber so as to place the object to be processed thereon; a gas supply part which supplies to the process chamber a process gas for processing the object to be processed; a light-transmitting window provided as a part of said process chamber so that the light-transmitting window is opposite to the object to be processed placed on the placement stage; and a heating unit which comprises a plurality of heat radiation lamps provided on an opposite side of the process chamber with respect to the light-transmitting window, wherein the light-transmitting window constitutes a plurality of convex lens parts each of which corresponds to a respective one of the heat radiation lamps and protrudes into the process space. [0031]
  • According to this invention, since the irradiation area of each of the heat radiation lamps is narrowed by the convex lens part, the directivity of the heat radiation lamps is improved, and easy adjustment of the luminescence distribution on the object to be processed is achieved. [0032]
  • In the above mentioned heat treatment apparatus according to the present invention, each of the heat radiation lamps may be located at a focal point of a respective one of the convex lens parts. Additionally, the placement stage may be rotatable relative to the heat radiation lamps about a vertical axis thereof. In one embodiment of the present invention, each of the heat radiation lamps may has an arc shape, and the heat radiation lamps may be concentrically arranged in the heating unit. In another embodiment, each of the heat radiation lamps may be a single end type, and the heat radiation lamps may be provided in the heating unit in an island arrangement. In still another embodiment, each of the heat radiation lamps may have a rectilinear shape, and the heat radiation lamps may be arranged parallel to each other in the heating unit. [0033]
  • Additionally, there is provided according to another aspect of the present invention a heat treatment apparatus comprising: a process chamber in which a heat treatment is applied to an object to be processed; a heat source which heats the objects to be processed by irradiating a radiation light onto the object to be processed; and a quartz window provided between the object to be processed and the heat source, the quartz window comprising: a plate made of quartz; and a lens part fixed to the plate so as to improve a directivity of the radiation light emitted by the heat source and increase a mechanical strength of the plate. [0034]
  • According to the above-mentioned invention, the quartz window has a reduced thickness with a sufficient strength since the lens part reinforces the plate. Accordingly, an amount of heat from the heat source absorbed by quartz window can be reduced. Additionally, since the lens part converges the radiation light emitted from the heat source, the directivity of the radiation light irradiated onto the object to be processed is improved. The heat treatment apparatus having the quarts window according to the present invention is suitable for a heat treatment performed under a negative pressure environment in which a load due to a pressure difference is applied to the quartz window. [0035]
  • In the heat treatment apparatus according to the present invention, the heat source may have plurality of lamps, and the lens part may have a plurality of lens elements corresponding to the lamps. Each of the lens element improves the directivity of the radiation light emitted by a respective one of the lamps. Additionally, the lens part may be provided on a surface of the plate facing the object to be processed. The lens part may be provided on both a surface of the plate facing the object to be processed and a surface opposite to the surface facing the object to be processed. [0036]
  • Additionally, the plate of the quartz window may have at least one reinforcing member which increases a strength of said plate. Accordingly, the thickness of quartz plate can be further reduced, thereby decreasing an amount radiation light absorbed by the quartz plate. The thickness of the plate of the quartz window is preferably equal to or less than 7 mm. More preferably, the thickness of the plate of the quartz window is equal to or less than 5 mm. The reinforcing member may made of aluminum. [0037]
  • Additionally, the heat treatment apparatus according to the present invention may further comprise a cooling arrangement which cools said reinforcing member so as to prevent the reinforcing member and the plate from being thermally deformed. The lens part may be provided on a first surface of the plate, and at least one reinforcing member may be provided on a second surface of said plate opposite to the first surface so as to increase a strength of the plate. [0038]
  • Further, a plurality of reinforcing members may be provided on the plate, and at least one waveguiding part made of quartz may be provided between adjacent reinforcing members, the waveguiding part transmitting the radiation light passed through said lens part and said plate toward the object to be processed. According to the difference in refraction index between quartz and air or vacuum, a total reflection occurs within the waveguiding part. Thus, the radiation light can be efficiently directed toward the object to be processed by being passed through the waveguiding part. [0039]
  • Additionally, the heat treatment apparatus according to the present invention may further comprise an exhaust device connected to the process chamber so as to maintain a negative pressure inside said process chamber. [0040]
  • Additionally, there is provided according to another aspect of the present invention a quartz window configured to be incorporated into a heat treatment apparatus which applies a heat treatment to an object to be processed by a radiation light emitted by a heat source, the quartz window being arranged between the object to be processed and the heat source, the quartz window comprising: a plate made of quartz; and a lens part fixed to said plate so as to converge the radiation light emitted by the heat source toward the object to be processed and increase a mechanical strength of the plate. [0041]
  • Other objects, features and advantages of the present invention will become more apparent from the following detailed description when read in conjunction with the accompanying drawings.[0042]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a cross-sectional view of a conventional heat treatment apparatus; [0043]
  • FIG. 2 is an illustration showing an arrangement of a single end lamp and a reflector; [0044]
  • FIG. 3 is a cross-sectional view of a heat treatment apparatus according to a first embodiment of the present invention; [0045]
  • FIG. 4 is a plan view of a reflective plate viewed from a side of a wafer; [0046]
  • FIG. 5 is an cross-sectional view of a part of a heating unit shown in FIG. 3 for explaining an action of a convex lens part provided in a light-emitting window; [0047]
  • FIG. 6 is a cross-sectional view of a heat treatment apparatus according to a second embodiment of the present invention; [0048]
  • FIG. 7 is a cross-sectional view of a part of a heating unit and a light-transmitting window shown in FIG. 6 for explaining an optical path of a light emitted from a lamp;. [0049]
  • FIG. 8 is a cross-sectional view of a variation of the light-transmitting window shown in FIG. 3; [0050]
  • FIG. 9 is a cross-sectional view of a variation of the light-transmitting window shown in FIG. 6; [0051]
  • FIG. 10 is a perspective view of a light-transmitting window corresponding to a plurality of straight double end lamps; [0052]
  • FIG. 11A is a plan view of a heating unit having a plurality of single end lamps; FIG. 11B is a cross-sectional view of a part of the heating unit shown in FIG. 11A in which the single end lamps are accommodated in circular concave portions formed in a reflective plate; FIG. 11C is a perspective view of a light-transmitting plate having a plurality of convex lens parts which are formed in positions corresponding to the single end lamps shown in FIG. 11A; [0053]
  • FIG. 12 is a cross-sectional view of a curved light-transmitting window along which a plurality of heat radiation lamps are arranged; [0054]
  • FIG. 13 is a cross-sectional view of a heat treatment apparatus according to a third embodiment of the present invention; [0055]
  • FIG. 14 is a plan view of the quartz window shown in FIG. 13; [0056]
  • FIG. 15 is a cross-sectional view of the quartz window taken along a line XV-XV of FIG. 14; [0057]
  • FIG. 16 is a cross-sectional view of the quartz window taken along a line XVI-XVI of FIG. 14; [0058]
  • FIG. 17 is an enlarged cross-sectional view of a part of the quartz window shown in FIG. 16; [0059]
  • FIG. 18 is an enlarged perspective view of a part of a lens assembly used in the quartz window; [0060]
  • FIG. 19 is an enlarged cross-sectional view of a part of a quartz window which is a variation of the quartz window shown in FIG. 13. [0061]
  • FIG. 20 is an enlarged cross-sectional view of a quartz window which is another variation of the quartz window shown in FIG. 13; [0062]
  • FIG. 21 is a graphic illustration showing a directivity achieved by the quartz window shown in FIG. 20; [0063]
  • FIG. 22 is a graphic illustration of the directivity shown in FIG. 21 viewed from above; [0064]
  • FIG. 23 is a side view of a part of a quartz window having reinforcing members; [0065]
  • FIG. 24 is a graphic illustration showing a directivity achieved by the quartz window shown in FIG. 23; [0066]
  • FIG. 25 is a graphic illustration of the directivity shown in FIG. 24 viewed from above; [0067]
  • FIG. 26 is a bottom view of a heating unit shown in FIG. 13; [0068]
  • FIG. 27 is a partial cross-sectional view of the heating unit shown in FIG. 13; [0069]
  • FIG. 28 is a front view of a lamp shown in FIG. 27; [0070]
  • FIG. 29 is a side view of the lamp shown in FIG. 27; [0071]
  • FIG. 30 is a plan view of a heating unit which is a variation of the heating unit shown in FIG. 26; [0072]
  • FIG. 31 is a partially cross-sectional view of the heating unit shown in FIG. 30; [0073]
  • FIG. 32 is a cross-sectional view for explaining a cooling arrangement of the lamps. [0074]
  • FIG. 33 is a side view of the lamp shown in FIG. 32; [0075]
  • FIG. 34 is a plan view of the lamp shown in FIG. 32; [0076]
  • FIG. 35 is a graphic illustrations showing the directivity achieved by a lamp having a plated [0077] part 149 formed of a gold plate film;
  • FIG. 36 is a graphic illustration of the directivity shown in FIG. 35 viewed from above; [0078]
  • FIG. 37 is a perspective view of a double end type lamp from which a plated part is removed; [0079]
  • FIG. 38 is a perspective view of another double end type lamp from which a plated part is removed; [0080]
  • FIG. 39 is a cross-sectional view for explaining the plated parts applied to the lamps shown in FIGS. 37 and 38; [0081]
  • FIG. 40 is a cross-sectional view of a heating unit having the lamps taken along the direction X in FIG. [0082] 26;
  • FIG. 41 is a cross-sectional view of the heating unit shown in FIG. 40 taken along the direction Y in FIG. 26; [0083]
  • FIG. 42 is a cross-sectional view showing two kinds of radiation thermometers; [0084]
  • FIG. 43 is a cross-sectional view showing two radiation thermometers of the same kind; [0085]
  • FIG. 44 is a graph for explaining a method of calculating an effective emissivity according to the present invention; [0086]
  • FIG. 45 is a graph for explaining a method of calculating an effective emissivity according to the present invention; [0087]
  • FIG. 46 is a graph for explaining a method of calculating an effective emissivity according to the present invention; [0088]
  • FIG. 47A is an illustration showing an incident angle θ of a radiation light to an optical fiber; [0089]
  • FIG. 47B is an illustration showing a view angle γ of a rod; [0090]
  • FIG. 48 is a graph showing a result of simulation with respect to a cooling rate of the wafer. [0091]
  • FIG. 49 is a cross-sectional view of the heat treatment apparatus shown in FIG. 13, which is provided with a variation of a bottom part; [0092]
  • FIG. 50 is a cross-sectional view of the heat treatment apparatus shown in FIG. 49 in a state in which the wafer is being heated; [0093]
  • FIG. 51 is a cross-sectional view of the heat treatment apparatus shown in FIG. 49 in a state in which the wafer is being cooled; [0094]
  • FIG. 52 is a cross-sectional view of a helium gas supply part; [0095]
  • FIG. 53 is a cross-sectional view of a circular quartz window for explaining the directivity of the light passing through the circular quartz window. [0096]
  • FIG. 54 is an graphic illustration showing the directivity achieved by a conventional single end lamps which does not have a gold plate film; and [0097]
  • FIG. 55 is a graphic illustration of the directivity shown in FIG. 54 viewed from above.[0098]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • (First Embodiment) [0099]
  • FIG. 3 is a cross-sectional view of a heat treatment apparatus according to a first embodiment of the present invention. The heat treatment apparatus shown in FIG. 3 generally comprises: a [0100] process chamber 2 which defines a process space for a semiconductor wafer W, which is an object to be processed; a light-transmitting window 6 provided on an upper portion of the process chamber 2; and a heating unit 5 provided above the light-transmitting window 6.
  • The [0101] process chamber 2 has a process chamber body 20 having a sidewall having a flat, circular horizontal cross section. The light-transmitting window 6 is provided so as to close a top opening of the process chamber body 20. An annular groove 21 is formed in the periphery of the process chamber 2. A inner ring part 31 is provided in the annular groove 21. The inner ring part 31 is rotatably supported about the vertical axis by an inner wall of the annular groove 21 via a bearing part 41. The inner ring part 31 is constituted by an upper member (support ring) 31 a and a lower member 31 b connected to the upper member 31. The inner ring part 31 is a support ring which supports a placement stage 22. The upper member 31 a is formed of opaque quartz (SiO2). The placement stage 22 is provided on an upper end of the upper member 31 a. The placement stage 22 is formed of silicon carbide (SiC) and has a ring shape so as to support the wafer W, which is an object to be processed. The placement stage 22 is arranged to rotate together with the inner ring part 31.
  • A part of a [0102] housing 23, which forms the annular groove 21, extends on the downward side. An outer ring part is rotatably supported about the vertical axis on the outside of the housing 23 via a bearing parts having an upper part 42 and a lower part.
  • The [0103] lower member 31 b (inner ring part 31) and the outer ring part 32 are provided with magnetic pole parts 33 and 34, respectively. The magnetic pole parts 33 and 34 are arranged on the inside and outside of the separation wall 24 of the housing 23, respectively, so as to constitute a magnetic coupling. A gear part 35 is formed on an outer surface of the outer ring part 32. The gear part 35 engages with a gear part 37 of a stepping motor 36, which is a drive part, so that the outer ring part 32 is rotated by the drive force of the stepping motor 36.
  • A [0104] supply passage 44 of a purge gas such as nitrogen (N2) is formed on an outer portion of the housing 23 which forms the annular groove 21 of the process chamber 2. An end of the supply passage communicates with a position directly above the bearing part 41 in the annular groove 21. Additionally, a plurality of exhaust passages 45 of the purge gas is formed along a circumferential direction of an inner body part 23 forming the annular groove 21. The purge gas enters the annular groove 21 from a gas supply pipe (not shown in the figure) via the supply passage 44, and is exhausted from an exhaust pipe (not shown in the figure) via the exhaust passage 45 by passing through an interior of the bearing part 41.
  • A [0105] bottom plate 33 constitutes a bottom part of the process chamber 2 under the wafer W. A temperature detecting means 25 is inserted into the bottom plate 33. the temperature detecting means 25 comprises, for example, a plurality of radiation thermometers for measuring a temperature of the wafer W from the backside. The radiation thermometers are arranged along a radial direction of the wafer W so that temperatures of a plurality of positions on the wafer W from the center to the peripheral edge can be measured. Additionally, the bottom plate 33 is provided with lift pins (not shown in the figure) which lifts the wafer W when the wafer is transferred to or from a conveyance arm provided outside the process chamber 2.
  • A [0106] gas supply passage 26 and an exhaust passage 27 are formed on a sidewall of the process chamber 2 in a position slightly above the wafer W. The gas supply passage 26 is an elongated silt-like gas supply part, which is provided for supplying a process gas from a gas supply source (not shown in the figure). The exhaust passage 27 is provided for exhausting the process gas by being connected to an exhaust pipe 29 via an exhaust chamber 28 protruding outside from the sidewall of the process chamber 2.
  • A description will now be given of the upper portion of the [0107] process chamber 2. As mentioned above, the heating unit 5 is provided on the top of the process chamber 2 so that the heating unit 5 is opposite to the front surface of the wafer W placed on the placement stage 22. The light-transmitting window 6 is provided in a space between the heating unit 5 and the wafer W.
  • The [0108] heating unit 5 is larger than the wafer W. The heating unit 5 comprises a plurality of heat radiation lamps 51 and a reflective plate 52. The heat radiation lamps 51 constitute heating means for heating the wafer W by irradiating lights onto the wafer W. The reflective plate 52 has a circular cross section, and is provided so as to encircle a surface of each lamp 51 opposite to the wafer W. A power supply system of the heat radiation lamps 52 is accommodated in a housing 53.
  • In the present embodiment, halogen lamps are used as the [0109] heat radiation lamps 51. The halogen lamps are concentrically arranged with the center being aligned with the center of the wafer W so that a plurality of generally annular light-emitting areas having different radii are formed.
  • FIG. 4 is a plan view of the [0110] reflective plate 52 viewed from the side of the wafer W. Each heat radiation lamp 51 has a shape corresponding to an arc which is formed by dividing one of concentric circles so that a plurality of lamps are formed in the concentric arrangement with a predetermined interval. In FIG. 4, a power supply part 54 extends in a vertical direction from opposite ends of each halogen lamps 51. The other side of the power supply part 54 is accommodated in the power supply system inside the housing 53 (refer to FIG. 3).
  • Each of the [0111] halogen lamps 51 is provided in a concave part 55 formed in the reflective plate 52. That is, a plurality of concave parts 55 having a semicircular cross section are formed in the reflective plate 52 in a concentric arrangement, and the halogen lamps 51 are accommodated in the respective concave parts 55. The heating unit 5 is constituted as mentioned above. An inner surface of each concave part 55 is gold-plated so as to reflect a light emitted by the halogen lamp 51. The shape of the concave portion 55 is determined so that the light from the halogen lamp 51 is reflected by the inner surface thereof and forwarded toward the wafer W on the placement stage 22. Accordingly, both the light emitted by the halogen lamp 51 and the light reflected by the reflective plate 52 are irradiated downwardly.
  • A description will now be given of the light-transmitting [0112] window 6. The light-transmitting window is a plate-like member formed of quartz, and is provided so as to opposite to the wafer W placed on the placement stage 22. The light-emitting plate has a generally flat top surface. A bottom surface of the light-emitting window 6 is provided with a convex lens part 61 which extends in a circumferential direction on the periphery of the light-emitting part 61 and protrudes toward the process space between the light-emitting window 6 and the wafer W. The convex lens part 61 is provided for deflecting the light irradiated from above the placement stage 22 so as to deflect the light traveling outward of the wafer W to inner side of the wafer W. Accordingly, the convex lens part 61 is positioned right above the placement stage 22.
  • A description will now be given of an operation of the heat treatment apparatus according to the above-mentioned embodiment. First, the wafer is transferred onto the [0113] placement stage 22 by a conveyance arm (not shown in the figure) which enters the process chamber 2 through a conveyance port (not shown in the figure) provided to the process chamber 2. Then, the outer ring part 32 is rotated by driving the stepping motor 36. At this time, since a magnetic force is applied between the magnetic pole part 34 of the outer ring part 34 and the magnetic pole part 33 of inner ring part 31 (lower member 31 b), the magnetic pole part 33 is attracted by the magnetic pole part 34 which results in rotation of the inner ring part 31, thereby rotating the wafer W.
  • A power is supplied to each [0114] halogen lamp 51 so as to heat the wafer W while supplying a process gas such as N2 gas which is an inert gas from the gas supply passage 26. The temperature of the wafer W is raised to, for example, 1000° C. at a rate of 150° C./min. while rotating the wafer W at a speed of 90 r.p.m. for example. The temperature is maintained for a predetermined time period so as to apply an anneal process to the wafer W. After the predetermined time period has elapsed, the power to each halogen lamp 51 is stopped and the temperature of the wafer is lowered, and stepping motor 36 is stopped. The processed wafer W is carried out of the process chamber 2 by the conveyance arm (not shown in the figure).
  • In the flat area other than the peripheral part of the light-emitting [0115] window 6, although the light emitted by the halogen lamp 51 and the light reflected by the reflective plate 52 have different optical axes, both lights substantially travels in the vertical direction so that a generally uniform irradiation distribution is achieved on the wafer W in accordance with the arrangement pattern of the halogen lamps 51. On the other hand, the light incident on the convex lens part 61 formed on the periphery of the light-emitting window 6 is refracted and the light traveling outward is deflected toward the inner side.
  • A description will now be give, with reference to FIG. 5, of the above-mentioned action of the [0116] convex lens part 61. The optical paths shown in FIG. 5 are calculated on the basis of a refractive index of quartz with respect to infrared ray being 1.45 and a critical angle being 42 degrees. The optical paths indicated by dashed lines are in the case in which the convex lens part 61 is not formed in the light-transmitting part 6. The optical paths indicated by solid lines are in the case in which the convex lens part 61 is formed in the light-transmitting part 6. Attention is given to a point P on a line extending outward from the periphery of the placement stage 22. The lines connecting each center of the first to fifth halogen lamps 51 and the point P correspond to the optical paths extending from each center to the pint P when the convex lens part 61 is not provided. It should be noted that the optical paths reaches a position slightly inner side since refraction in the flat part of the light-emitting window 6 is ignored for the sake of simplification of the model.
  • When the [0117] convex lens part 61 is provided, the light traveling from each center toward the point P is incident on the convex lens part 61 from the flat top surface of the light-emitting window 6, and is refracted at the point of incidence. Then, the refracted light travels to a boundary surface 62 between the convex lens part 61 and the process space 60. If the incident angle to the boundary surface 62 is greater than a critical angle, the light is totally reflected by the boundary surface 62. If the incident angle to the boundary surface 62 is smaller than the critical angle, the light is refracted again and exit to the process space 60 and reaches a point Q on an outer edge of the placement stage 22. That is, by providing the convex lens part 61, the light traveling toward the point P is deflected inwardly by a distance d1.
  • In the present embodiment, since the [0118] convex lens part 61 is provided on the peripheral edge of the light-emitting window 6, the light traveling toward outside the placement stage 22 is refracted and reaches the placement stage 22, a total amount of heat radiation to the placement stage 22 is increased. Accordingly, even if a temperature rising rate is increased in the heating process, there is less delay in the temperature rise of the placement stage 22 with respect to the temperature rise of the wafer W. As a result, generation of a slip in the wafer W can be prevented while maintaining a high throughput by increasing the temperature rising rate. Additionally, since the placement stage 22 is heated by the heat which has not reached the placement stage 22, there is an effect that energy is effectively used.
  • Moreover, since an amount of light passing outside the [0119] placement stage 22 is decreased, a problem that the stray light enters the temperature detecting means 25 can be solved. That is, if transparent quartz is used for the upper member 31 a (support ring) of the inner ring 31 as in the present embodiment, a light entering through a gap outside the placement stage 22 enters a space between the wafer W and the bottom plate 24 by transmitting through the upper member 31 a and the light is multi-reflected inside the space. If the light enters the temperature detecting means 25, the temperature detected becomes in accurate. However, in the present embodiment, since opaque quartz is used for the upper member 31 a, less light enters the space between the wafer W and the bottom plate 24, which results in achieving a high accuracy in the detection of temperature of the wafer W.
  • It should be noted that although there is an effect to shorten the temperature rise of the [0120] placement stage 22 in the present embodiment, the present invention can be applied to a structure in which the placement stage does not extend from the outer side of the wafer W. That is, in such a case, an amount of heat released from the periphery of the wafer W is larger than that of the center portion since the temperature of the wall of the process chamber is lower than the temperature of the wafer W. Thus, the temperature rise in the periphery of the wafer W is delayed from the temperature rise in the center portion of the wafer W. However, the amount of heat radiation to the periphery if increased by providing the convex lens part 61 in the periphery of the light-emitting window 6 as mentioned above, which provides the effect that the uniformity within the surface of the wafer W can be high even when the temperature rising rate is increased. Accordingly, the present invention is not limited to the structure in which the periphery of the wafer W is supported by the placement stage.
  • (Second Embodiment) [0121]
  • A description will now be given, with reference to FIG. 6, of a second embodiment of the present invention. FIG. 6 is a cross-sectional view of a heat treatment apparatus according to the second embodiment of the present invention. In FIG. 6, pats that are the same as the parts shown in FIG. 3 are given the same reference numerals, and descriptions thereof will be omitted. [0122]
  • The heat treatment apparatus shown in FIG. 6 has the same structure as that of the heat treatment apparatus shown in FIG. 3 except for the light-transmitting [0123] window 6 being replaced by a light-transmitting window 6A having a different shape. The light-transmitting window 6A according to the present embodiment has a plurality of convex lens parts 61A on a bottom surface thereof so that the convex lens parts 61A protrude into the space 60A between the light-transmitting window 6A and the wafer W. The convex lens parts are formed in positions corresponding to the respective halogen lamps 51 of the heating unit 5.
  • A description will now be given, with reference to FIG. 7, of an optical path from a [0124] halogen lamp 51 to the wafer W. In FIG. 7, the center of the halogen lamp 51 is located at the focal point of the convex lens part 61A. Accordingly, a light emitted from the halogen lamp 51 is changed into a generally parallel light as indicated by solid lines in FIG. 7. It should be noted that, although the optical path is more complicated since the outside surface of the halogen lamp 51 is light emitting pints, the halogen lamp 51 is considered to be a pint light source for the sake of simplification of the model.
  • In FIG. 7, dashed lines indicate an optical path in a case in which the light-transmitting [0125] window 6 is formed of a flat plate having no convex lens part. Apparent from FIG. 7, the irradiated area by the halogen lamp 51 is decreased by the convex leans part 61. Accordingly, the directivity of each halogen lamp 51 is improved. Thus, the irradiated areas are independent or slightly overlap with each other. This results in an easy adjusting operation to control the luminescence distribution on the wafer W since the luminescence distribution can be controlled by adjusting the shape of the reflective plate 52 or adjusting an amount of light emitted from each of the halogen lamps 51 when a control is performed so as to increase, for example, the luminescence of a portion provided with the temperature detecting means 25.
  • Although the light-transmitting [0126] windows 6 and 6A according to the first and second embodiments of the present invention have a flat top surface, the light-transmitting windows 6 and 6A may have a top surface which follows the bottom surface which forms the convex lens parts 61 and 61A as shown in FIGS. 8 and 9. Additionally, the light-transmitting window may comprise a plurality of light-transmitting members as shown in FIG. 10 so as to provide an optical function the same as that of the convex lens part 61 or 61A.
  • In the above-mentioned embodiments, the heat radiation lamp (halogen lamp) [0127] 51 is not limited to the curved double end lamp, and a plurality of straight tubular lamps may be arranged parallel to each other so as to heat the entire wafer W. In such a case, the shape of the light-transmitting window 6 can be that shown in FIG. 10 in which the convex lens parts 61A correspond to the shape of the heat radiation lamp 51. It should be noted that the light-transmitting window 6 shown in FIG. 10 is upside down for the sake of convenience of explanation.
  • Additionally, the present invention can be applied to an apparatus having a plurality of single end heat radiation lamps having a generally spherical shape or an eggplant shape. FIG. 11A is a plan view of a [0128] heating unit 5A having a plurality of single end lamps 71. FIG. 11B is a cross-sectional view of a part of the heating unit 5A shown in FIG. 11A in which the single end lamps 71 are accommodated in circular concave portions 73 formed in a reflective plate 72. FIG. 11C is a perspective view of a light-transmitting plate 6B having a plurality of convex lens parts 61 which are formed in positions corresponding to the single end lamps 71. It should be noted that the light-transmitting window 6B shown in FIG. 11C is upside down for the sake of convenience of explanation.
  • Additionally, when the process space in the process chamber is depressurized by evacuating gasses in the process chamber, the light-transmitting window may be formed in a curved shape so that the light-transmitting window can withstand a pressure generated by the pressure difference between the negative pressure inside the process chamber and the atmospheric pressure. The present invention can be applied to such a case. FIG. 12 is a cross-sectional view of a curved light-transmitting window [0129] 6C along which a plurality of heat radiation lamps 81 are arranged so as to equalize a distance between each of the lamps 81 and the light-transmitting window 6C.
  • It should be noted that although the heat radiation lamps are fixed and the wafer W is rotated in the above-mentioned embodiments, the heat radiation lamps may be rotated relative to the wafer W. Additionally, the heat treatment apparatus according to the present is not limited to an annealing apparatus and the present invention can be applied to other apparatuses such as a CVD apparatus. [0130]
  • (Third Embodiment) [0131]
  • A description will now be given of a third embodiment of the present invention. FIG. 13 is a cross-sectional view of a heat treatment apparatus according to the third embodiment of the present invention. [0132]
  • As shown in FIG. 13, the [0133] heat treatment apparatus 100 generally comprises a process chamber 110, a quartz window (light-transmitting window) 120, a heating unit 140, a support ring 150, a gearing 160, a permanent magnet 170 a gas introducing part 180, an exhausting part 190, a radiation thermometer 200 and a control part 300.
  • The [0134] process chamber 110 is formed of stainless steel or aluminum. The quartz window 120 is connected to a top of the process chamber 110. The side wall of the process chamber 110 and the quartz window 12 define a process space in which an object W to be processed (semiconductor wafer: hereinafter referred to as a wafer W) is subjected to a heat treatment. The support ring 150 on which the wafer W is placed and a support part 152 connected to the support ring 150 are arranged in the process space. The process space is maintained to be a predetermined negative pressure by the exhaust part 190. The wafer W is carried in or out from the process chamber through a gate valve (not shown in the figure) provided to the sidewall of the process chamber 110.
  • A [0135] bottom part 114 of the process chamber 110 is connected to a cooling pipes 116 a and 116 b (hereinafter simply referred to as cooling pipe 116) so that the bottom part 114 serves as a cooling plate. If necessary, the cooling plate 114 may be provided with a temperature control arrangement as shown in FIG. 13. The temperature control arrangement may comprise a control part 300, a temperature sensor and a heater. A cooling water is supplied to the temperature control arrangement from a water supply source such as a water line. A coolant such as alcohol, gurden or flon may be used instead of the cooling water. As for the temperature sensor, a known sensor such as a PTC thermister, an infrared sensor, a thermocouple, etc. may be used. The heater can be a line heater wound on the outer surface of cooling pipe 116. The temperature of the cooling water flowing through the cooling pipe 116 can be adjusted by controlling an electric current flowing through the line heater.
  • The [0136] quartz window 120 is attached to the process chamber in an airtight manner so as to maintain the negative pressure environment inside the process chamber 110 and transmit a heat radiation light emitted from lamps of the heating unit 140.
  • FIG. 14 is a plan view of the [0137] quartz window 120. FIG. 15 is a cross-sectional view of the quartz window taken along a line XV-XV of FIG. 14. FIG. 16 is a cross-sectional view of the quartz window taken along a line XVI-XVI of FIG. 14. FIG. 17 is an enlarged cross-sectional view of a part of the quartz window shown in FIG. 16. FIG. 18 is an enlarged perspective view of a part of a lens assembly used in the quartz window.
  • As shown in FIGS. 14 through 17, the [0138] quartz window 120 comprises a cylindrical quartz plate 121 having a radius of about 400 mm and a thickness of about 33 mm and a plurality of quartz lens assembly 122 comprising a plurality of lens elements 123.
  • The [0139] lens assembly 122 serves to strengthen the quartz window 120 and increase the directivity of the radiation light form the lamps of the heating unit 140. As shown in FIG. 14, each of the lens assemblies 122 has a plurality of lens elements 123 ach having a light converging action. The lens assemblies 122 are arranged parallel to the direction X since the lamps of the heating unit 140 are arranged in the direction X. That is, the direction of arrangement of the lens assemblies 122 is dependent on the direction of arrangement of the lamps of the heating unit 140.
  • In the present embodiment, although each of the [0140] lens elements 123 is curved in the direction X, the orientation of each of the lens elements 123 is not limited to that shown in the figure, and each of the lens elements 123 may be curved in the direction X, the direction Y or both the directions X and Y. In the present embodiment, the lens assemblies 122 are arranged so as to uniformly heat the entire wafer W having a circular shape.
  • The [0141] lens assemblies 122 serve to provide air passages AF (refer to FIGS. 32 and 34) for cooling the lens assemblies 122, the quartz window 120 and the lamps of the heating unit 140. Additionally, a gap between the adjacent lens assemblies 122 serves as a contact part 128 which contacts a separation wall 144 (described later) which cools the quartz plate 121 by heat conduction.
  • In the present embodiment, as described above, the thickness of the [0142] quartz plate 121 is set equal to or less than 30 mm to 40 mm, for example, about 30 mm. Although the present invention does not exclude the thickness being in the range of 30 mm to 40 mm so as to use only the light converging action of the lens assemblies 122, the use of the thin quartz plate 121 according to the present embodiment can provide an effect described later. Additionally, although the lens assemblies 122 according to the present embodiment has a height about 3 mm and a width equal to or less than 21 mm, the height and width are not limited to such dimensions. Further, although the lens elements 123 according to the present embodiment has a length about 18 mm and a radius about 10 mm, the length and radius are not limited to such dimensions.
  • In the present embodiment, although the [0143] window lens assemblies 122 are provided only on one side of the quartz plate 121 which side is opposite to the lamps 130 of the heating unit 140, the window lens assemblies 122 may be provided on both sides or on the other side which is not opposite to the lamps 130.
  • Since the strength with respect to thermal deformation of the [0144] quartz plate 121 is increased by the lens assemblies 122, there is no need to form the quartz plate 121 in a domal shape which curves in a direction protruding from the process chamber 110 as in the conventional apparatus. Accordingly, the quartz plate 121 has a flat shape. Since the quartz window formed in a domal shape increases a distance between the wafer W and the lamps 130 of the heating unit 140, there is a problem in that the directivity of the lamps is deteriorated. The present embodiment solves such a problem relating to the directivity of the lamps. Although the quartz plate 121 and the lens assemblies 122 are joined by welding in the present embodiment, the quartz plate 121 and the lens assemblies 122 may be joined by other methods or integrally formed with each other.
  • The thickness of the [0145] quartz plate 121 is about 30 mm, which is smaller than the thickness of the conventional quartz plate which ranges from 30 mm to 40 mm. Consequently, the quartz window 120 according to the present embodiment absorbs a smaller amount of the light emitted by the lamps 130 than the conventional quartz window. Thus, the quartz window 120 has the following advantages over the conventional quartz window.
  • First, a high rate temperature rise can be achieved with a low power consumption since the irradiation efficiency of the [0146] lamps 130 to the wafer W can be improved. That is, the present embodiment solves the problem in that the lamp light is absorbed by the quartz window which results in deterioration of the irradiation efficiency. Second, the quartz window is prevented from being damaged due to a difference in temperature between the front surface and the back surface of the quartz window 121 since the difference can be maintained smaller than that of the conventional quartz window. That is, the present embodiment solves the problem in that the conventional quartz window is easily destroyed due to a difference in the thermal stress between the front surface facing the lamps and the back surface opposite to the front surface when a rapid thermal process is performed as in a rapid thermal process (RTP) apparatus. Third, the quartz window is prevented from forming a deposition film or a byproduct on a surface thereof during a film deposition process since the temperature of the quartz window 120 is lower than the conventional quartz window. Thus, a good repeatability can be maintained and a frequency of cleaning operations applied to the process chamber 110 can be decreased. That is, the present embodiment solves the problem in that the temperature of the conventional window is high especially when a film deposition process is performed, which results in deposition of a deposition film or a byproduct on the surface of the quartz window and increase in the frequency of cleaning operations of the process chamber.
  • Additionally, although the [0147] quartz window 120 solely constituted by the quartz plate, which does not have the lens assemblies 122, may reduce an amount of light absorbed by the quartz plate 121 when the thickness of the quartz plate 121 is small as in the present embodiment, it is possible that the quartz window 120 is easily destroyed since the quartz plate 120 cannot withstand a pressure difference between the negative pressure in the process chamber and the atmospheric pressure. Accordingly, there is a problem in that the quartz window cannot be used with a process which must be performed under a negative pressure environment. The lens assemblies solve such a problem since the lens assemblies 122 reinforces the quartz plate 121.
  • A description will now be given, with reference to FIGS. 17, 18 and [0148] 52, of a light converging action of the lens assemblies 122 of the quartz window 120. FIG. 53 is a cross-sectional view of a conventional circular quartz window such as a light-transmitting window 13 shown in FIG. 1 for explaining the directivity of the light passing through the circular quartz window 13. Referring to FIG. 53, the light emitted from a single end lamp (not shown in the figure) positioned above the quartz window and transmitting the quartz window 13 is spread, and, thus, the directivity of the light passed through the quartz window 13 with respect to the wafer W, which is placed under the quartz window, is dull.
  • On the other hand, as shown in FIGS. 5 and 6, the [0149] quartz window 120 according to the present embodiment collimates the light emitted from the lamps 130 by the lens assemblies 122 having the convex lens elements 123 so that the light is irradiated on the wafer W with a good directivity. It should be noted that the structure of each lens element 123 is not limited to the specifically disclosed shape and curvature which collimate the light from the lamps 130, and the lens element may provide a directivity the same as the conventional quartz window. That is, even if the directivity is the same as that of the conventional quartz window, the lens assemblies 122 have the above-mentioned reinforcing function.
  • A description will now be given, with reference to FIG. 19, of a [0150] quartz window 120A which is a variation of the quartz window according to the present embodiment. FIG. 19 is an enlarged cross-sectional view of a part of the quartz window 120A. The quartz window 120A has reinforcing members (or columns) 124, which are formed under the passage 128 and parallel to the passage 128. Each of the reinforcing members 124 is made of aluminum or stainless steel, and has a square cross section. The reinforcing members 124 have cooling pipes 125 therein, and increase a strength of the quartz window 120A.
  • The reinforcing [0151] members 124 have a good heat conductivity. Additionally, the reinforcing members 124 cannot be a source of pollution with respect to the wafer W since the reinforcing members 124 are formed of the same material as the process chamber. Due to the provision of the reinforcing members 124, the thickness of the quartz plate 121 can be 10 mm, preferably equal to or smaller than 7 mm, and, more preferably, about 5 mm.
  • In the present embodiment, the dimensions of the cross section of each reinforcing [0152] member 124 is 18 mm in height and about 12 mm in width. The diameter of the cooling pipe 125 is not limited to but about 6 mm. Additionally, the cross-section of each reinforcing member 124 is no limited to a square, and an arbitrary shape such as a wave shape may be used. The present invention encompasses a quarts window 120C which is a combination of the quartz plate 121 and the reinforcing members 124 as shown in FIG. 23.
  • As shown by arrows in FIG. 19, the radiation light from the [0153] lamps 130 is reflected by sidewalls of reinforcing members 124, and reaches the wafer W placed under the quartz window. The cooling pipe 125 has a cooling function which cools both the reinforcing members 124 and the quartz plate 121. If the reinforcing members 124 are made of aluminum, an appropriate temperature control (cooling) is needed since the aluminum may be deformed or melted at a temperature in the range of 200° C. to 700° C. The temperature control by the cooling pipe 125 may be the same as the cooling pipe 116, or other known methods may be applied.
  • A description will now be given, with reference to FIG. 20, of a [0154] quartz window 120B which is another variation of the quartz window 120 according to the present embodiment. FIG. 20 is an enlarged cross-sectional view of the quartz window 120B. The quartz window 120B has the same structure as the quartz window 120A shown in FIG. 19 except for waveguiding parts 126 having a square cross section being provided under the respective lens assemblies 122. The quartz window 120B can provide an improved irradiation efficiency than the quartz window 120A due to the waveguiding parts 126. Referring to FIG. 19, the radiation light emitted by the lamps 130 indicated by arrows generated energy loss about 10% when the radiation light is reflected by the reinforcing members 124. The rate of energy loss is dependent on the height of the reinforcing members 124 and other parameters. The energy loss can be decreased by forming a metal film having a high reflective index on the surface of the reinforcing members 124 by, for example, gold plating. However, such a metal film is not preferable since it may become a source of pollution with respect to the wafer W. Additionally, there in no material which is applicable to the reinforcing members 124 and has no reflective loss.
  • In order to reduce such an energy loss, the [0155] quartz window 120B is provided with the waveguiding parts 126 which has a square cross section and extending in parallel to the respective lens assemblies 122. The waveguiding parts 126 may be bonded to the quartz plate 121 by welding or may be integrally formed with each other. The waveguiding parts 126 are preferably made of quartz, and have a refractive index of about 1.4. Since the refractive index of vacuum and air is about 1.0, the radiation light is totally reflected within the quartz made waveguiding parts 126 according to the relationship between the refractive indexes of quartz and vacuum or air. Thus, the energy loss of the quartz window 120B is reduced to zero in theory.
  • FIGS. 21 and 22 are graphic illustrations showing the directivity achieved by the [0156] quartz window 120B shown in FIG. 20. In FIG. 21, the center of the wafer coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 14 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 22 shows the graphic illustration shown in FIG. 21 from above.
  • The above-mentioned relationship was obtained by using a 750W-lamp as the [0157] lamp 130 having a plated part 149 formed by a gold plate film. A distance between the lower end of the lamp 130 and the upper end of the lens assembly 122 was 2 mm. A distance between the wafer W and the aluminum made reinforcing part 124 was 20 mm. Additionally, in FIG. 20, the thickness of the quartz plate 121 was set to 5 mm, the radius was set to 10 mm, and the width was set to 19 mm. Additionally, the width of each waveguiding part 126 was set to 19 mm, and the height was set to 18 mm. Further, a distance between the adjacent reinforcing members 124 was set to 21 mm.
  • FIGS. 24 and 25 are graphic illustrations showing the directivity achieved by the [0158] quartz window 120C shown in FIG. 23. In FIG. 24, the center of the wafer coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 14 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 25 shows the graphic illustration shown in FIG. 24 from above.
  • The above-mentioned relationship was obtained by using a 750W-lamp as the [0159] lamp 130 having a plated part 149 formed by a gold plate film. A distance between the lower end of the lamp 130 and the upper end of the lens assembly 122 was 2 mm. A distance between the wafer W and the aluminum made reinforcing part 124 was 20 mm. Additionally, in FIG. 23, the thickness of the quartz plate 121 was set to 5 mm. A distance between the adjacent reinforcing members 124 was set to 21 mm.
  • It can be interpreted from FIGS. 21 and 22 that the irradiance is sharply maximized near the center of the wafer W, and the directivity is improved by the [0160] quartz window 120B. Additionally, a half spread (may be referred to as “half value width”) of the maximum height (a maximum irradiance) forms a generally circular shape and the maximum of the half value width is about 40 mm. The controllability is more improved as the half width becomes closer to a complete circle and the value of the half value width is reduces.
  • On the other hand, it can be appreciated from FIGS. 24 and 25 that the irradiance is maximum near the center of the wafer W, but the maximum value is not so large. Additionally, the half value width forms a generally oblong shape, and the maximum of the half value with is about 100 mm. The directivity is improved as the maximum value is increased. Additionally, the controllability of the half value width can be improved as it approaches a circle and its value is decreased. Here, the controllability represents easiness of process when it is needed to heat a desired position of the wafer W (that is, irradiate the radiation light) and heat if not applied to a position where it is not desired to heat. Comparing FIGS. 21 and 22 with FIGS. 24 and 25, it can be appreciated that the [0161] quartz window 120B is superior to the quartz window 120C in both directivity and controllability.
  • The above-mentioned quartz windows are not always needed to be used with the [0162] lamps 130 which do not need a reflector. In other words, the above-mentioned quartz windows can be applied to a heat treatment apparatus which has a reflector due to their strength and directivity. In such a case, the reinforcing members 124 having a waveform cross section are suitable for a wave-shaped reflector.
  • A description will now be given, with reference to FIGS. 26 through 29, of the [0163] heating unit 140 according to the present embodiment. FIG. 26 is a bottom view of the heating unit 140. FIG. 27 is a partial cross-sectional view of the heating unit 140. FIG. 28 is a front view of the lamp 130 shown in FIG. 27. FIG. 29 is a side view of the lamp 130 shown in FIG. 27. As shown in FIG. 26, the arrangement of the lamps 130 correspond to the arrangement of the lens elements 123 shown in FIG. FIG. 14. The heating unit 140 comprises the lamps 130 and a lamp support part 142.
  • Although each [0164] lamp 130 in the present embodiment is a single end type as shown in FIG. 27, the lamp 130 can be a double end type as explained later, or other heat sources such as an electric wire heater may be used. The single end type refers to a kind of lamp having a single electrode part 132 as shown in FIG. 27. The double end type refers to a kind of lamp having two ends like a fluorescent lamp. The lamp 130 serves as a heat source to heat the wafer W. In the present embodiment, the lamps 130 are not limited to but halogen lamps. The output of the lamps 130 is determined by a lamp driver 310. That is, the lamp driver is controlled by the control part 300 so as to supply a power to the lamps 130.
  • As shown in FIG. 28, each [0165] lamp 130 comprises the single electrode part 132 and a light-emitting part 134. The light-emitting part 134 includes a filament 135 which is connected to the electrode part 132. As indicated by dashed lines in FIG. 26, the plurality of lamps 130 are arranged along a plurality of lines in response to the lens elements 123 of the lens assemblies 122 so as to evenly heat the wafer W having a circular shape. Additionally, as mentioned above, since the reflector is not present between adjacent lamps 130 in the direction X as shown in FIG. 26, a distance between the adjacent lamps 130 in the direction X can be maintained as small as 3 mm, which contributes to an increase in the density of lamps and an increase in a power density. Additionally, as mentioned later, such a rectilinear arrangement of the lamps 130 contributes to the suitable heat exhaust (for example, 4 m3/min).
  • As shown in FIG. 29, a [0166] neck part 133 is formed as a part of the light-emitting part 134 under the electrode part 132. A plated part 149 is formed around the neck part 133. Referring to FIG. 13, a power supplied to the electrode part 132 is determined by the lamp driver 310, and the lamp driver 310 is controlled by the control part 300. Referring to FIG. 28, in the present embodiment, the height of the electrode part 132 is about 25 mm; the height of the light-emitting part 124 is about 65 mm, the thickness is about 1 mm; and the length of the filament 135 is about 25 mm. Additionally, referring to FIG. 29, in the present embodiment, the width of the electrode part 132 is about 5 mm and the width of the light-emitting part 134 (not the neck part 133) is about 15 mm. Nitrogen or argon gas and halogen gas are charged in the light-emitting part 134. The filament 135 is made tungsten. A distance between a lower part of the filament 135 and a bottom surface 134 a of the light-emitting part 134 shown in FIG. 28 is set within a predetermined range, thereby maintaining the directivity and the service life of the lamps. If the distance is too small, the directivity of the lamps 130 is deteriorated, and if the distance is too large, the halogen cycle is in sufficient which results in reducing the service life of the lamps.
  • Referring to FIGS. 26 and 27, the [0167] lamp support part 142 has a generally rectangular parallelepiped shape. The lamp support part 142 has a plurality of separation walls 144 and a plurality of cylindrical grooves which accommodate the lamps 130. Each of the cylindrical grooves comprises a part 143 a which accommodates the electrode part 132 of the lamp 130 and a part 143 b which accommodates the light-emitting part 134 of the lamp 130. The electrode part 132 of each lamp 130 is connected to the lamp driver 130 shown in FIG. 13. The part 143 a serves as a sealing part. The diameter of the part 143 b is larger than the diameter of the light-emitting part 134.
  • Each [0168] separation wall 144 has a width of about 12 mm, and is located above the passage 128 shown in FIG. 14 and the reinforcing member 124 shown in FIG. 19 and between the adjacent grooves 143 arranged in the direction X shown in FIG. 26. A pair of cooling pipes 145 arranged in parallel to the passage 128 (in the direction X shown in FIG. 26) are put in contact with the separation walls 144. About 0.3 to 0.8 m3 of air can flow through the groove 143 excluding the light emitting part 134 so as to cool the surface of the light-emitting part 134. Thus, the lamps 130 of the present embodiment can be cooled by the air cooing arrangement and the cooling pipes 145.
  • The lamps can be cooled the air cooling arrangement alone by removing the separation walls and the cooling [0169] pipes 145. As mentioned later, the plated part 149 is formed by gold plating, the temperature of the plated part 149 is maintained below 500° C. so as to prevent a temperature destruction such as exfoliation of gold plate. The temperature control by the cooling pipe 145 can be the same as the cooling pipes 116, and other known methods may be applied. Even when the plated part 149 has a heat resistance exceeding 500° C., the temperature of the lamps 130 is preferably controlled to be below 900° C. by the cooling pipes 145 or other cooling arrangements since transmittance is deteriorated (a phenomenon in which the light-emitting part 134 becomes white) if the temperature of the lamps 130 exceeds 900° C.
  • In the present embodiment, the [0170] separation walls 144 and the cooling pipes 145 are arranged along the direction X in FIG. 26, and a two-dimensional arrangement in the X and Y directions is not used as in a conventional reflector. Accordingly, the structure of the lamp support part 142 according to the present embodiment contributes to an increase in the lamp density and the power density of the lamps 130. For example, when the lamps are arranged with a conventional reflector (for example, a diameter of 50 mm), the lamp density is 0.04 unit/cm2. On the other hand, the lamp density achieved by the present embodiment is 0.16 unit/cm2. In a case in which the lamps 130 and the lamp support part 142 are cooled by air cooling alone instead of providing the separation walls 144 and the cooling pipes 145, the lamp density is increased to about 0.40 unit/cm2 at maximum. Generally, the power density required for an RTP is determined by a lamp power per one lamp and a lamp density. The lamp density can be decreased as the lamp power is increased. The arrangement of the lamps in the present embodiment can be applied to RTP which requires a further rapid temperature rising in the feature.
  • A description will now be given, with reference to FIGS. 30 and 31, of a [0171] heating unit 140A which is a variation of the heating unit shown in FIG. 26. The heating unit 140A improves the lamp density by removing the separation walls 144 and the cooling pipes 145 from the heating unit 140A. Since the cooing pipes 145 are not provided in to the lamp support part 142, the lamps 130 are sorely cooled by air cooling. The lamp density of the heating unit 140A is twice that of the heating unit 140. Since the reflector which conventionally requires the plated part 149 is removed, such a high-density lamp mount can be achieved.
  • A description will now be given, with reference to FIGS. [0172] 32 to 34, of the cooling arrangement of the lamps 130. FIG. 32 is a cross-sectional view for explaining the cooling arrangement of the lamps 130 arranged in the direction X in FIG. 26. FIG. 33 is a side view of the lamp 130 shown in FIG. 32. FIG. 34 is a plan view of the lamp 130 shown in FIG. 32. As shown in the figures, the plurality of lamps 130 arranged in the same row are subjected to heat exhaust (air cooling) by a blower. The exhaust efficiency by the blower is as good as 4 m3/min with respect to that achieved by a rectilinear arrangement of the lamps. In a case such heat exhaust is performed, heated are can be exhausted out of the heat treatment apparatus 100, or alternatively circulated. If the heated air is circulation, a radiator is provided so as to cool the heated air. In such a case, a load to an exhaust system is small due to the good exhaust efficiency being achieved.
  • The plated [0173] part 149 has a function to reflect the heat radiation light of the lamps 130 at a high reflectance within the light-emitting part 134. By providing the light-emitting part 134 having a high reflectance, the directivity of the light-emitting part 134 (radiation light emitted by the filament 135) to the wafer W is improved. As a result, the plated part 149 excludes the reflector (reflective plate), which is conventionally provided outside the light-emitting part. Since the reflector is not used, the plurality of lamps 130 can be mounted at a high density. For example, the lamps 130 can be arranged at an interval of 3 mm in the direction X as shown in FIG. 26, and can be mounted at a lamp density of 0.16 unit/cm2 which is four times the lamp density (0.04 unit/cm2) of the arrangement having a reflector inclined by 45 degrees. Accordingly, the power density can be increased and, therefore, the heat treatment apparatus 100 according to the present embodiment is suitable for RTP.
  • The plated [0174] part 149 is formed by various plating methods or other methods on the light emitting-part 134 including the neck part 133 except for the bottom surface 134 a of the light-emitting part 134. Accordingly, the directivity of the lamps 130 can be improved by the light directly irradiated on the wafer W and the light reflected by the plated part 149.
  • The plated [0175] part 149 if formed of a metal film such as a gold film or silver film which reflects a radiation light at a high reflectance. The plated part 149 may be formed by electroplating such as hard gold plating or pure gold plating. The thickness of the plated part 149 can be about 10 μm so as to sufficiently prevent light leakage from the light-emitting part 134. It should be noted that the plated part 149 is provided for improving the directivity, and there is no specific range of high-reflectivity of the plated part 149.
  • FIGS. 35 and 36 are graphic illustrations showing the directivity achieved by the [0176] lamp 130 having the plated part 149 formed of a gold plate film. In FIG. 35, the center of the wafer W coincides with the origin (0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 26 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 36 shows a graphic illustration of the directivity shown in FIG. 35 viewed from above.
  • The above-mentioned relationship was obtained by using a 750W-lamp having the plated [0177] part 149 formed of a gold plate film as the lamp 130. The process chamber 110 was maintained at a normal pressure. A distance between the lower end of the lamp 130 and the upper end of a circular quartz window, which is consisted of the quartz plate 121 alone, was 2 mm. A distance between the wafer W and the lower end of the quartz window was 20 mm.
  • FIGS. 53 and 54 are graphic illustrations showing the directivity achieved by a conventional single end lamp which does not have a gold plate film. In FIG. 54, the center of the wafer coincides with the origin ([0178] 0, 0) of coordinates, and a relationship between distances in the X and Y direction shown in FIG. 26 and irradiance of the radiation light irradiated onto the wafer W is indicated in a three-dimensional manner. FIG. 55 shows a graphic illustration of the directivity shown in FIG. 54 viewed from above.
  • The above-mentioned relationship was obtained by using a 750W-lamp which does not have the plated [0179] part 149 formed of a gold plate film as the lamp 130. The process chamber 110 was maintained at a normal pressure. A distance between the lower end the lamp 130 and the upper end of a circular quartz window, which is consisted of the quartz plate 121 alone, was 2 mm. A distance between the wafer W and the lower end of the quartz window was 20 mm.
  • It can be interpreted from FIGS. 35 and 36 that the irradiance is sharply maximized near the center of the wafer W, and the directivity is improved by the plated [0180] part 149. Additionally, a half spread is about 40 mm. On the other hand, it can be appreciated from FIGS. 53 and 54 that the irradiance is maximum near the center of the wafer W, but the maximum value is not so large. Additionally, the half value width forms a generally oblong shape, and the maximum of the half value with is about 80 mm. Comparing FIGS. 35 and 36 with FIGS. 52 and 53, it can be appreciated that the lamp 130 having the plated part 149 is superior to the conventional lamp having no plated part in both directivity and controllability.
  • The light-emitting [0181] part 134 preferably has unevenness in a portion covered by the plated part 149 as indicated by a circled portion shown in FIG. 29. According to the unevenness, the light reflected by the plated part 149 can be directed to the wafer W without repeating reflection within the cylindrical side surface of the light-emitting part 134. The unevenness can be formed by surface treatment such as sand-blasting or corrosion by a chemical solution.
  • As mentioned above, the [0182] lamp 130 can be of a double end type. A description will now be given, with reference to FIGS. 37 through 41, of a case in which the lamps 130 are replaced by the double end type lamps. FIG. 37 is a perspective view of a double end type lamp 130A from which a plated part 149A is removed. FIG. 38 is a perspective view of another double end type lamps from which a plated part 149B is removed. FIG. 39 is a cross-sectional view for explaining the plated parts 149A and 149B applied to the lamps 130A and 130B, respectively. FIG. 40 is a cross-sectional view of a heating unit 140B having the lamps 130A taken along the direction X in FIG. 26. FIG. 41 is a cross-sectional view of the heating unit 140B shown in FIG. 40 taken along the direction Y in FIG. 26.
  • FIG. 37 shows one of the [0183] double end lamps 130A having a rectilinear shape and arranged in the direction in FIG. 26. FIG. 38 shows one of the arc-like double end lamps 130B which are concentrically arranged as indicated by dashed circles in FIG. 13. It should be noted that the lamp support part must be changed so as to receive the lamps 130A or 130B when the lamps 130 are replaced by the lamps 130A or 130B. For example, the lamp support part 142 may be changed so as to have a plurality of vertical through holes, which accommodate electrode parts 132A and 132B and vertical parts 136 a and 137 a, and a plurality of rectilinear or concentric horizontal grooves, which accommodate horizontal parts 136 b or 137 b. Referring to FIGS. 40 and 41, each lens arranged directly under the respective one of the lamps 130A has a length corresponding to the light-emitting part 136 shown in FIG. 40 and a width which covers a pair of lamps 130A shown in FIG. 41.
  • As shown in FIG. 37, each [0184] lamp 130A comprises two electrode parts 132A and the light-emitting part 136. The light-emitting part 136 includes a filament 135A which connects the two electrode parts 132A. Similarly, as shown in FIG. 26, the lamp 130B includes two electrode parts 132B and the light-emitting part 137. The light-emitting part 137 includes a filament 135B which connects the two electrode parts 132B. A power supplied to the electrode parts 132A and 132B is determined by the lamp driver 310 shown in FIG. 13. The lamp driver 310 is controlled by the control part 300.
  • As shown in FIG. 37, the light-emitting [0185] part 136 includes the vertical parts 136 a and the rectilinear horizontal part 136 b which is bent by 90 degrees with respect to the vertical parts 136 a. Additionally, as shown in FIG. 38, the light-emitting part 136 includes the vertical parts 137 a and the arc-like horizontal part 137 b which is bent by 90 degrees with respect to the vertical parts 137 a. It should be noted that the double end lamp applicable to the present invention is not limited to the lamps 130A and 130B, and lamps including vertical and horizontal part having arbitrary shapes may be used. Additionally, the angle between the vertical part and the horizontal part is not limited to 90 degrees.
  • The [0186] horizontal part 136 b is mounted along the direction X arranged in a portion in which the lamps 130 are arranged as shown in FIG. 26. The length of the horizontal part 136 b may be equal to or less than a distance (for example, interval E) between the lamps 130 at opposite ends which distance is determined by an outermost circle P and arbitrary positions (for example, indicated by D) of the lamps in the direction Y as shown in FIG. 26. If the length is equal to the above-mentioned distance, a single lamp 130A is mounted in the lamp mounting position. If the length is less than the above-mentioned distance, a plurality of lamps 130A are mounted in the lamp mounting position. The horizontal parts 136 b of the lamps 130A mounted in different lamp positions may be the same or different from each other.
  • The [0187] horizontal part 137 b is concentrically arranged with the dashed circles shown in FIG. 26. The dashed circle shown in FIG. 38 is concentric with the dashed circles shown in FIG. 26. The length of the horizontal part 137 b is determined by a length of a circle which is concentric with the dashed circles shown in FIG. 14 and a number of lamps 130B arranged along the circle. The radii of the horizontal parts 137 b of the lams 130B arranged along different concentric circles differ from each other.
  • In FIGS. 37 and 38, the plated [0188] parts 149A and 149B are removed from the respective lamps 130A and 130B for the sake of convenience. However, in practice, as shown in FIG. 39, portions of the light-emitting parts 136 and 137, which portions face the wafer W, are covered by the plated parts 149A and 149B. The plated part 149A is provided on entire side surfaces of the vertical parts 136 a and an upper half portion of the horizontal part 136 b. The plated part 149B is provided on entire side surfaces of the vertical parts 137 a and an upper half portion of the horizontal part 137 b.
  • Similar to the plated [0189] part 149, the plated parts 149A and 149B have a function to reflect the heat radiation light of the respective lamps 130A and 130B at a high reflectance within the respective light-emitting parts 136 and 137. By providing the light-emitting parts 136 and 137 having a high reflectance, the directivity of the light-emitting parts 136 and 137 (radiation light emitted by the filaments 135A and 135B) to the wafer W is improved. As a result, the plated parts 149A and 149B exclude the reflector (reflective plate), which is conventionally provided outside the light-emitting part. Since the reflector is not used, the plurality of lamps 130 can be mounted at a high density. For example, the lamps can be arranged can be mounted at a lamp density which is four times the lamp density of the arrangement having a reflector inclined by 45 degrees. Accordingly, the power density can be increased and, therefore, the heat treatment apparatus is suitable for RTP.
  • A description will now be given, with reference to FIGS. 42 through 46, of a method of calculating an effective emissivity which is another aspect of the present invention. FIG. 42 is a cross-sectional view showing two kinds of [0190] radiation thermometers 200A and 200B. FIG. 43 is a cross-sectional view showing two radiation thermometers 200C of the same kind. FIGS. 44 through 46 are graphs for explaining the method of calculating an effective emissivity according to the present invention. Hereinafter, the radiation thermometers 200A, 200B and 200C may be simply referred to as radiation thermometer 200.
  • The [0191] radiation thermometers 200A, 200B and 200C are provided on the opposite side of the lamps 130 with respect to the wafer W. Although the present invention does not exclude the structure in which the radiation thermometers 200A, 200B and 200C is provided on the same side with the lamps 130, it is preferable that the radiation light of the lamps 130 is prevented from being incident on the radiation thermometers 200A, 200B and 200C.
  • Each of the [0192] radiation thermometers 200A, 200B and 200C shown in FIGS. 42 and 43 comprises a quartz or sapphire rod 210, respective optical fibers 220A, 220B and 220C, and a photodetector (PD) 230. Since the radiation thermometers 200A, 200B and 200C according to the present invention do not use a chopper, a motor for rotating the chopper, an LED and a temperature adjusting arrangement for achieving a stable light emission of the LED, the radiation thermometers 200A, 200B and 200C have a relatively inexpensive structure.
  • Referring to FIG. 30, the [0193] radiation thermometers 200A and 200B are mounted on a bottom part 114 of the process chamber 110. More specifically, the radiation thermometers 200A and 200B are inserted into respective cylindrical through holes 115 a and 115 b of the bottom part 114. A surface 114 a of the bottom part 114 facing the interior of the process chamber 110 serves as a reflective plate (high-reflectance surface) by being subjected to a sufficient polishing. This is because if the surface 114 a is a low reflectance surface such as a black surface, the surface 114 a absorbs heat of the wafer W, which results in an undesired increase in the output of the lamps 130.
  • Each of the [0194] radiation thermometers 200A and 200B comprises the same rod 210 (210A and 210B), respective optical fibers 220A and 220B having different aperture numbers (N/A) and a photodetector (PD) 230. The rod 210 is formed of a quartz rod having a diameter off 4 mm. Although quartz and sapphire can be used since they have a food heat resistance and a good optical characteristic, the material of the rod 210 is not limited to quarts or sapphire. If necessary, the rod 210 can protrude inside the process chamber 110 by a predetermined length. The rod 210 of each of the radiation thermometers 200A and 200B is inserted into respective through holes 115A and 115B provided in the bottom part 114 of the process chamber 110, and is sealed by an O-ring (not shown in the figure). Accordingly, a negative pressure environment can be maintained in the process chamber irrespective of the through holes 115A and 115B. The rod 210 has an excellent light collecting efficiency since the rod 210 can guide a radiation light, which is incident on the rod 210, to the respective optical fibers 210A and 210B with less attenuation and less leakage. The rod 210 receives a radiation light from the wafer W, and guides received radiation light to the PD 230 via the respective optical fibers 220A and 220B.
  • Each of the [0195] optical fibers 220A and 220B comprises a core which transmits a light and a concentric clad which covers the core. The core and the clad are made of a transparent dielectric material such as glass or plastic. The refractive index of the clad is slightly smaller than that of the core, thereby achieving a total reflection. Thus, the core can propagate a light without leaking outside. In order to achieve different NA, the radiation thermometers 200A and 200B use a core and clad of different materials.
  • The photodiode (PD) [0196] 230 has an image forming lens, a silicon (Si) photocell and an amplification circuit so as to convert the radiation light incident on the image forming lens into a voltage, which is an electric signal representing radiation intensities E1(T) and E2(T), and send the electric signal to the control part 300. The control part 300 comprises a CPU, an MPU, other processors, and memories such as a RAM and a ROM so as to calculate an emissivity ε and a substrate temperature T of the wafer W based on the radiation intensities E1(T) and E2(T). It should be noted that the calculation may be performed by an arithmetic part (not shown in the figure) provided in the radiation thermometers 200A, 200B and 200C. The radiation light received by the rod 210 is introduced into the photodetector (PD) 230 via the optical fibers 220A and 220B.
  • A description will now be given of a method of calculating an effective emissivity according to the present invention which uses different NA. Considering multiple reflection between the wafer W and the [0197] rod 210 and a direct light form the lamps 130, the effective emissivity εeff of the wafer W can be given by the following equation (2).
  • εeff=(1−α)×ε+αxε/[1−F×r×(1−ε)]  (2)
  • where, ε[0198] eff represents an effective emissivity of the wafer W; ε represents an emissivity of the wafer W; r represents a reflectance of the surface 114 a of the bottom part 114 of the process chamber 110; F is a view factor given by the following equation (3); α is a coefficient of multiple reflection.
  • F=(1+cos2γ)/2  (3)
  • The coefficient of multiple reflection α is supposed to take the following values depending on three values which are 1) a diameter D[0199] 1 of the rod 210, 2) a distance D2 between the wafer W and the surface 114 a and 3) number of aperture NA of the radiation thermometers 200A and 200B. It should be noted that y represents a view angle determined by a positional relationship between the rod 210, the surface 114 a and the wafer W as shown in FIG. 47B.
  • NA=0→(1−α)=1  (4)
  • NA=1→(1−α)≈1  (5)
  • D1/D2=∞→(1−α)=1  (6)
  • D1/D2=0→(1−α)=1  (7)
  • A prediction equation which can establish the above-mentioned four conditions can be defined as the following equation (8). [0200]
  • (1−α)=(1[0201]    −NA×N1)N2/(D1/D)  (8)
  • where N[0202] 1 and N2 are the parameters in the equation (8). Accordingly, the coefficient of multiple reflection a is represented by the following equation (9).
  • α=1−(1−NA×N1)N2/(D1/D2)  (9)
  • It can be appreciated that the coefficient of multiple reflection a represented by the equation (9) possibly satisfies the equations (4) through (7). Thus, the adequacy of equation (9) is considered by determining N[0203] 1 and N2 based on equation (9).
  • First, a calculation is made by fixing the diameter (4 mm) of the [0204] rod 210 and varying NA. It is assumed that the wafer W has ε=0.2 for the sake of saving time. At this time, NA ranges from 0 to 1. Values of N1 and N2/(D1/D2) are tentatively determined by comparing data obtained by the calculation and the assumption of equation (9). In a similar manner, values of N1 and N2/(D1/D2) are determined for the diameters of 2 mm and 20 mm. As for a method of determining N1 and N2, N2 and N2/(D1/D2)-D1/D2 curve are used. N1 is selected so that N2 is common to the three conditions in N2/(D1/D2).
  • According to the tentative values of N[0205] 1 and N2/(D1/D2) determined by the above-mentioned method, relationships between (1−α) and NA are shown in FIGS. 44 through 46. As a result, N1=0.01 and N2=500 are obtained, and equation (9) can be represented by the following equation (10).
  • α=1−(1−0.01×NA)500/(D1/D2)  (10)
  • Accordingly, if the diameter of the [0206] rod 210 is changed, or if the distance between the wafer W and the surface 114 a is changed, the effective emissivity can be easily calculated irrespective of the value of NA.
  • In a case in which the [0207] optical fiber 220A has NA=0.2 and the optical fiber 220B has NA=0.34, the coefficients of multiple reflection α0.2 and α0.34 can be represented by the following equations (11) and (12).
  • α0.2=1−(1−0.01×0.2)500/D1/D2)  (11)
  • α0.34=1−(1−0.01×0.34)500/D1/D2)  (12)
  • Accordingly, the effective emissivity of the wafer W can be given by the following equations (13) and (14). [0208]
  • εeff 0.2=(1−α0.2)×ε+α0.2×ε/[1−F×r×(1−ε)]  (13)
  • εeff 0.34=(1−α 0.34)×ε+α0.34×ε/[1−ε×r×(1−ε)]  (14)
  • The [0209] radiation thermometer 200 performs the conversion of temperature based on radiation light flux (W). Thus, a difference in the incident light fluxes at the two radiation thermometers are given by the following equations (15) and (16), where θ1 is an incident angle at NA=0.2 and θ2 is an incident angle at NA=0.34. The incident angle θ represents a maximum light-receiving angle of an optical fiber as shown in FIG. 47A, and the incident angle θ can be represented as θ=sin−1(NA).
  • E 0.2 =A ROD×(tanθ1)2 ×π×L/r 2  (15)
  • E 0.34 A ROD×(tanθ2)2 ×π×L/r 2  (16)
  • Accordingly, the ratio of the incident light fluxes of the two [0210] radiation thermometers 200A and 200B can be represented by the following equation (17)
  • [0211]    eff 0.34 ×E 0.34)/(εeff 0.2 ×E 0.2)=(εeff 0.34×tan2θ2)/(εeff 0.2×tan2θ1)  (17)
  • According to the above-mentioned equations (13) and (14), equation (17) can be changed into the following equation (18). [0212]
  • [0213]    eff 0.34 ×E 0.34)/(εeff 0.2 ×E 0.2)={(1−α0.34)×ε+α0.34×ε/[1−F×r×(1−ε)]}×tan2θ2/{(1−vα0.2)×ε+α0.2×ε/[1−F×r×(1−ε)]}  (18)
  • Then, if β is defined as in the following equation (19), the above-mentioned equation (18) can be changed into the following equations (20) through (24). [0214]
  • β=[(εeff 0.34 ×E 0.34)/(εeff 0.2 ×E 0.2)]×[(εeff 0.34×tan2θ2)/(εeff 0.2×tan2θ1)]  (19)
  • β×{(1−α0.2)×ε+α0.2×ε/[1−F×r×(1−ε)]}={(1−α0.34)×ε+α0.34×ε/[1−F×r×(1−ε)]}  (20)
  • β×{(1−α0.2)×[1−F×r×(1−ε)]+α0.2}={(1−α0.34)×[1−F×r×(1−ε)]+α0.34}  (21)
  • β×(1−α0.2)−β×(1−α0.2)×[F×r×(1−ε)]+β×α0.2=(1−α0.34)−(1−9α0.34)×[F×r×(1−ε]+α0.34  (22)
  • ε×(1−α0.2)−β×(1−0.2F×r+β×α 0.2−(1−α0.34)+(1−α0.34F×r×−α 0.34=(1−α0.34F×r+F×r×(1−α1.34F×r×ε−β×(1−α0.2F×r×ε  (23)
  • Accordingly, the emissivity ε of the wafer W can be calculated by the following equation (25). [0215]
  • ε={β×(1−α0.2)−β×(1−α0.2F×r+β×α 0.2−(1−α0.34)+(1−α0.34F×r−α 0.34}/{(1−α0.2F×r}  (25)
  • Then, the effective emissivity is calculated again by the equations (11) and (12). At this time, the calculation is performed based on the small value of NA, that is, NA=2. The following equation (26) can be obtained by entering the emissivity E, which was calculated by equation (23), in equation (11). [0216]
  • εeff 02=(1−α0.2)×ε+α0.2×ε/[1−F×r×(1−ε)]  (26)
  • Since radiation energy of E[0217] 0.2 is incident on the radiation thermometer 200A of NA=0.2, the following equation (27) is established, where Eb is radiation energy according to black body radiation.
  • E 0.2 =εeff 0.2 ×E b  (27)
  • Then, the above-mentioned equation (25) is changed as follows. [0218]
  • E b =E 0.2 /εeff 0.2  (28)
  • Regarding incident energy, the following relationship is defined by Japanese Industrial Standard (JIS 1612), where T represents a temperature of the wafer W; c[0219] 2 represents a second constant of radiation (0.014388 m/k); A, B and C are constants peculiar to the radiation thermometer 200 (determined by calibration); Eb is radiation energy from a black body (normally an output V of a radiation thermometer).
  • T=c2/A/(lnC−lnE b)−B/A  (29)
  • The above-mentioned calculation method obtains an emissivity of the wafer W by the two [0220] radiation thermometers 200A and 200B having different NAs, the emissivity can be obtained based on the above-mentioned equation (9) by changing a ratio of D1/D2. FIG. 43 is an illustration for explaining such a method.
  • In FIG. 43, a [0221] bottom surface 114 b corresponding to the bottom surface 114 a and an upper surface 114 d of a protruding part 114 c protruding form the bottom surface 114 b are provided in the bottom part 114 of the process chamber 110. Accordingly, identical radiation thermometers 200C are used, but distances between the wafer W and the quartz rod 210 of each of the radiation thermometers 200C are different. Thus, in the example shown in FIG. 43, an emissivity of the wafer W can be obtained similar to the example shown in FIG. 40.
  • For example, in FIG. 43, the two [0222] radiation thermometers 200C have NA=0.2, and the distance between the wafer W and the rod 210 of one of the radiation thermometers 200C is set to 3.5 mm (left side of FIG. 43) and the distance between the wafer W and the rod 210 of the other radiation thermometer 200C is set to 5 mm (right side of FIG. 43). Additionally, the diameter of the rod 210 is set to 4 mm. According to equation (9), each coefficient of multiple reflection can be represented by the following equations (30) and (31).
  • α3.5=1−(1−0.001×0.2)500/(D1/3.5)  (30)
  • α5.0=131 (1−0.001×0.2)500(D1/5.0)  (31)
  • Using the above equations (30) and (31), the effective emissivities α[0223] 3.5 and α5.0 are obtained in the similar manner as equations (13) and (14). The subsequent calculation of obtaining the temperature of the wafer W is performed in the same manner as that explained with reference to equations (15) through (28) by replacing the suffix 0.2 by 3.5 and 0.34 by 5.0.
  • The detector [0224] 270 and the control part 300 can calculate the temperature T of the wafer W based on equations (25) through (29). In any case, the control part 300 can obtain the temperature T of the wafer W. Additionally, a temperature measurement calculation program including the above-mentioned equations is stored in a computer readable medium such as a floppy disk, or the program is distributed through a communication network such as the Internet or the like.
  • The [0225] control part 300 has a CPU and a memory incorporated therein. The control part 300 feedback-controls the output of the lamps 130 by recognizing the temperature T of the wafer W and controlling the lamp driver 310. Additionally, the control part 300 controls a rotational speed of the wafer W by sending a drive signal to the motor driver 320 at a predetermined timing.
  • The [0226] gags introducing part 180 includes a gas source, a flow adjust valve, a mass-flow controller, a gas supply nozzle and a gas supply passage interconnecting the aforementioned (not shown in the figure) so as to introduce a gas used for heat treatment into the process chamber 110. It should be noted that although the gas introducing part 180 is provided to the sidewall 112 of the process chamber 110 so as to introduce the gas into the process chamber from the side, the position of the as introducing part 180 is not limited to the side of the process chamber. For example, the gas introducing part 180 may be constituted as a showerhead which introduces the process gas from an upper portion of the process chamber 110.
  • If the process to be performed in the [0227] process chamber 110 is an annealing process, the process gas includes N2, Ar, etc.; if the process is an oxidation process, the process gas includes O2, H2, H2O, NO2, etc.; if the process is a nitriding process, the process gas includes N2, NH3, etc.; if the process is a film deposition process, the process gas includes NH3, SiH2, Cl2, SiH4, etc. It should be noted that the process gas is not limited the above-mentioned gasses.
  • The mass-flow controller is provided for controlling a flow of the process gas. The mass-flow controller comprises a bridge circuit, an amplification circuit, a comparator control circuit, a follow adjust valve, etc. so as to control the flow adjust valve by measuring a gas flow by detecting an amount of heat transmitted from the upstream side to the downstream side in association with the gas flow. The gas supply passage uses a seamless pipe and a bite-type coupling or a metal gasket coupling so as to prevent impurities from entering the gas to be supplied. Additionally, the supply pipe is made of a corrosion resistant material so as to generation of dust particles due to dirt or corrosion on an inner surface of the supply pipe. The inner surface of the supply pipe may be coated by an insulating material such as PTFE (Teflon), PPA, polyimide, PBI, etc. Additionally, the inner surface of the supply pipe may be subjected to an electropolishing. Further, a dust particle filter may be provided to the gas supply passage. [0228]
  • In the present embodiment, although the [0229] exhaust part 190 is provided parallel to the gas introducing part 180, the position and the number are not limited to that shown in the figure. The exhaust part 190 is connected to a desired exhaust pump, such as a turbomolecular pump, a sputter ion pump, a getter pump, a sorption pump, a cryostat pump, together with a pressure adjust valve. It should be noted that although process chamber is maintained at a negative pressure environment in the present embodiment, such a structure is not an essential feature of the present invention. That is, for example, the process chamber may be maintained at a pressure ranging from 133 Pa to an atmospheric pressure. The exhaust part 190 has a function to exhaust helium gas before starting a subsequent heat treatment.
  • FIG. 48 is a graph showing a result of simulation with respect to a cooling rate of the wafer W. In FIG. 48, a gap represents a distance between the wafer W and the [0230] bottom part 114. It can be appreciated from FIG. 48 that 1) a cooling rate increases as the gap decreases, and 2) the cooling rate remarkably increases by flowing helium gas, which has a high heat conductivity, between the wafer W and the bottom part 114.
  • In the structure of the [0231] RTP apparatus 100 shown in FIG. 13, the upper surface of the wafer W is heated by the lamps 130, and the bottom part 114 is provided as a cooling plate on the back side of the wafer W. Accordingly, the structure shown in FIG. 13 gives a high cooling rate, but needs a relatively large power so as to perform a rapid temperature rise since an amount of heat released from the wafer W is increased. In order to solve such a problem, supply of cooling water to the cooling pipe 116 may be stopped when heating the wafer. However, such a method is not preferable since a yield rate is decreased.
  • Accordingly, as shown in FIGS. 49 through 51, the [0232] bottom part 114 as a cooling plate may be replaced by a bottom part 114A which is arranged movable relative to the wafer W. More preferably, helium gas, which has a high heat conductivity, is supplied between the wafer W and the bottom part 114A when cooling the wafer W so as to increase a radiation efficiency. FIG. 49 is a cross-sectional view of the heat treatment apparatus 100 having the bottom plate 114A. FIG. 50 is a cross-sectional view of the heat treatment apparatus 100 in a state in which the wafer W is being heated. FIG. 51 is a cross-sectional view of the heat treatment apparatus 100 in a state in which the wafer W is being cooled. It should be noted that, in FIGS. 49 through 51, the cooling pipe 116 and the control part 300 connected to the radiation thermometer 200 are omitted for the sake of simplification of the figure.
  • As shown in FIG. 49, the [0233] bottom part 114A is movable up and down with respect to the wafer W (object to processed) by a vertical moving mechanism 117 which is controlled by the control part 300. The vertical moving mechanism 117 includes a bellows so as to maintain the negative pressure environment in the process chamber 110. The vertical moving mechanism 117 can be constituted by a known mechanism in the art, and a detailed description thereof will be omitted. It should be noted that the wafer W or the support ring 150 may be arranged to be movable relative to the bottom part 114A. When heating the wafer W, the bottom part 114A is moved downward so as to separate the bottom plate 114A from the wafer W as shown in FIG. 50, and supply of helium gas is stopped. At this time, a distance between the wafer W and the bottom part 114A is 10 mm, for example. Since the distance between the bottom part 114A and the wafer W is large, the wafer is not influenced by eth bottom part 114A, thereby achieving a rapid temperature rise of the wafer W. The position of the bottom part 114A shown in FIG. 50 may be set as a home position.
  • When cooing the wafer W, the [0234] bottom part 114A is moved upward so as to approach the bottom part 114A to the wafer W, and the supply of helium gas is started. Since the distance between the wafer W and the bottom part 114A is small, the wafer W is influenced by the bottom plate 114A, thereby achieving a high-rate cooling. At this time, the distance between the wafer W and the bottom part 114A is 1 mm, for example. FIG. 52 is an enlarged cross-sectional view of a helium gas supply part provided in an area V shown in FIG. 51. As shown in FIG. 52, the bottom part 114A is provided with a lot of small holes 115 a through which helium gas is introduced into the process chamber 110. A case 410 is connected to the bottom part 114A, and a helium gas supply pipe is connected to the case 410 via a valve 400, which operates to start or stop the supply of helium gas.
  • In the present embodiment, although a relative movement is performed between the bottom part (cooling plate) [0235] 114A and the wafer W, the present invention is applicable to a relative movement of the wafer W and the lamps 130.
  • A description will now be given, with reference to FIG. 13, of a rotating mechanism of the wafer W. In order to maintain a good electric characteristic of each element in an integrated circuit and a high yield rate of products, a uniform heat treatment is required over the entirety of the surface of the wafer W. If a temperature distribution on the surface of the wafer W is uneven, the [0236] RTP apparatus 100 cannot provide a high-quality heat treatment since a thickness of a film produced by a film deposition process may vary and a slip may be generated in the wafer W due to a thermal stress.
  • The uneven temperature distribution on the surface of the wafer W may be caused by an uneven irradiance distribution or may be caused by a process gas, which is supplied near the [0237] gas introducing part 180, absorbing heat from the surface of the wafer W. The rotating mechanism rotates the wafer W, which enables a uniform heating by the lamps 130 over the entire surface of the wafer W.
  • The rotating mechanism of the wafer W comprises the [0238] support ring 150, the permanent magnet 170, a ring-like magnetic member 172, a motor driver 320 and a motor 330.
  • The [0239] support ring 150 has a ring shape and is made of a heat resistant ceramic such as SiC. The support ring 150 serves as a placement stage on which the wafer W is placed. The support ring 150 supports a periphery of the backside of the wafer W. If necessary, the support ring 150 may be provided with an electrostatic chuck or a clamp mechanism so as to fix the wafer to the support ring 150. The support ring 150 is configured and arranged to prevent heat form being released from an outer edge of the wafer W so that the uniform heating of the wafer W is not deteriorated.
  • The [0240] support ring 150 is connected to the support part 152 at outer end thereof. If necessary, a heat insulating member formed on quartz glass is interposed between the support ring 150 and the support part 152 so as to thermally protect the magnetic member 172. In the present embodiment, the support part 152 is formed as an opaque quartz member having a hollow cylindrical shape. The bearing 160 is fixed to the support part 152 and the inner wall of process chamber 110 so as to allow a rotation of the support part 152 while maintaining the negative pressure environment of the process chamber 110. The magnetic member 172 is attached to the lower end of the support part 152.
  • The ring-like [0241] permanent magnet 170 and magnetic member 172, which are concentrically arranged, are magnetically coupled with each other, and the permanent magnet 170 is rotated by the motor 330. The motor 330 is driven by the motor driver 320, which is controlled by the control part 300.
  • Consequently, when the [0242] permanent magnet 170 rotates, the magnetically coupled magnetic member 172 is rotated together with the support part 152, which results in rotation of the support ring and the wafer W. Although the rotation speed in the present embodiment is 90 r.p.m., the rotation speed may be determined based on a material and size of the wafer W (object to be processed) and a type and temperature of the process gas so that there is less effect of turbulence of gas within the process chamber 110 and stream of gas due to the rotation of the wafer W. The permanent magnet 170 and the magnetic member 172 may be reversed as long as they are magnetically coupled, or the magnetic member 172 may also be formed of a permanent magnet.
  • A description will now be given of an operation of the [0243] RTP apparatus 100. First, the wafer W is carried in the process chamber 110 through a gate valve (not shown in the figure) by a conveyance arm of a cluster tool (not shown in the figure). When the conveyance arm supporting the wafer W reaches above the support ring 150, a lifter pin vertically moving system moves lifter pins (for example, three lifter pins) upward so as to protrude the lifter pins from the support ring 150 to support the wafer W. As a result, the wafer is transferred from the conveyance arm to the lifter pins, and, then, the conveyance arm returns out of the process chamber 110 through the gate valve. Thereafter, the gate valve is closed. The conveyance arm may return to a home position (not shown in the figure).
  • The lifter vertically moving mechanism retract the lifter pins below the surface of the [0244] support ring 150, thereby placing the wafer W on the support ring 150. The lifter pin vertically moving mechanism may use a bellows so as to maintain the a negative pressure environment in the process chamber and prevent the atmosphere inside the process chamber from flowing out of the process chamber 110 during the vertically moving operation.
  • Thereafter, the controller controls the [0245] lamp driver 310 so as to send an instruction to drive the lamps 130. In response to the instruction, the lamp driver 310 drives the lamps 130 so that the lamps 130 heat the wafer W at a temperature of about 800° C. The heat treatment apparatus 100 according to the present embodiment improves the directivity of the lamps 130 by the action of the lens assemblies 122 and the plated part 149 while removing the reflector, and, thereby, increasing the lamp density and consequently the power density. Thus, a desired high rate temperature rise of the wafer W can be achieved. A heat ray (radiation light) emitted by the lamps 130 is irradiated onto the surface of the wafer W by passing through the quartz window 120 so as to heat the wafer W at 800° C. with a heating rate of about 200° C./sec.
  • Generally, a periphery of the wafer W tends to release a greater amount of heat than the center portion thereof. However, the present embodiment can provide a high directivity and temperature control capability since the [0246] lamps 130 according to the present invention are concentrically so as to enable a power control for each area. If the apparatus 100 uses the structure shown in FIG. 43, the bottom part 114A is located at the home position as shown in FIG. 50. Especially, the structure shown in FIG. 50 can provide an efficient rapid temperature rise since the wafer W hardly receives influence from the bottom part 114 a due to a large distance between the wafer W and the bottom part 114A as a cooling plate. The exhaust part 190 forms a negative pressure environment in the process chamber 110 at or around the time of heating the wafer W.
  • At the same time the [0247] control part 300 controls the motor driver 320 to send an instruction to drive the motor 330. In response to the instruction, the motor driver 320 drives the motor 330 so as to rotate the ring-like magnet 170. As a result, the support part 152 (or 152A) rotates, and the wafer W rates together with the support ring 150. Since the wafer W rotates, the temperature within the surface of the wafer W is maintained uniform during the heat treatment process.
  • The [0248] quartz window 120 has a relatively small thickness due to the action of the lens assemblies 122, the reinforcing members 124 and the waveguiding members 126, which provides the following advantages with respect to the heating process of the wafer W.
  • 1) The irradiation efficiency to the wafer W is not deteriorated since the [0249] quartz window 120 having the reduced thickness absorbs less heat.
  • 2) A thermal stress fracture hardly occurs since the temperature difference between the front and back surfaces of the [0250] quartz plate 121 of the quartz window 120 is small.
  • 3) In a case of a film deposition process, a deposition film an byproduct is hardly formed on the surface of the [0251] quarts window 120 since a temperature rise in the surface of the quartz window 120 is small.
  • 4) A pressure difference between the negative pressure in the [0252] process chamber 110 and the atmospheric pressure can be maintained even if the thickness of the quartz plate 121 is small since the mechanical strength of the quartz plate 121 is increased by the lens assemblies 122.
  • The temperature of the wafer W is measured by the [0253] radiation thermometer 200, and the control part 300 feedback-controls the lamp driver 310 based on the result of measurement. Since the wafer W is rotated, the temperature distribution on the surface of the wafer W is supposed to be uniform. However, if necessary, the radiation thermometer 200 may measure a temperature at a plurality of points on the surface of the wafer W so that the control part 300 sends an instruction to change the output of the lamps with respect to a specific area of the wafer W when the result of measurement of the radiation thermometer 200 indicates that the temperature distribution on the surface of the wafer W is not uniform. Since the controllability of irradiation of heat is improved by the plated part 149 and the lens assemblies 122, a desired part of the wafer W can be accurately heated with a desired degree.
  • The [0254] radiation thermometer 200 has a simple structure in which a chopper and an LED is not used, the radiation thermometer is inexpensive, which contributes to miniaturization and economization of the heat treatment apparatus 100. Additionally, the temperature measured by the method of calculating effective emissivity is accurate. An electric characteristic of an integrated circuit formed in the wafer W is deteriorated due to diffusion of impurities when the wafer W is placed under a high-temperature environment for a long time. Accordingly, a rapid heating and a rapid cooling are required, which also requires a temperature control of the wafer W. The method of calculating effective emissivity according to the preset invention satisfies such requirements. Thus, the RTP apparatus 100 can provide a high-quality heat treatment.
  • After the wafer W is heated at the desired temperature, a process gas is introduced into the [0255] process chamber 110 through the gas introducing part (not shown in the figure). After the heat treatment is completed, the controller 300 controls the lamp driver 310 so as to stop the heating by the lamps 130. Then, the lamp driver stops to supply a power to the lamps 130. If the apparatus 100 uses the structure shown in FIG. 43, the controller 300 controls the vertical moving mechanism 117 so move the bottom part 114A to a cooling position. Additionally, helium gas having a high heat conductivity is supplied between the wafer W and the bottom part 114A as shown in FIG. 46. Thereby, the cooling efficiency to the wafer W is increased, and a rapid cooling can be achieved with a relatively small power consumption. The cooling rate achieved by the apparatus 100 is about 200° C./sec.
  • After the heat treatment, the wafer W is carried out of the [0256] process chamber 110 by the conveyance arm of the cluster tool through the gate valve in the reverse sequence. Thereafter, if necessary, the conveyance arm conveys the wafer W to a next stage apparatus such as a film deposition apparatus.
  • The present invention is not limited to the specifically disclosed embodiments, and variations and modifications may be made without departing from the scope of the present invention. [0257]
  • The present application is based on Japanese priority applications No. 2000-247591 filed on Aug. 17, 2000 and No. 2000-343209 filed on Nov. 10, 2000, the entire contents of which are herein incorporated by reference. [0258]

Claims (30)

What is claimed is:
1. A heat treatment apparatus comprising:
a process chamber which defines a process space for processing an object to be processes;
a placement stage provided in the process chamber so as to place the object to be processed thereon;
a gas supply part which supplies to the process chamber a process gas for processing the object to be processed;
a light-transmitting window provided as a part of said process chamber so that the light-transmitting window is opposite to the object to be processed placed on said placement stage; and
a heating unit which comprises a heat radiation lamp provided on an opposite side of said process chamber with respect to the light-transmitting window,
wherein the light-transmitting window constitutes a convex lens part which is formed on a periphery of the light-transmitting window and protrudes into the process space.
2. The heat treatment apparatus as claimed in claim 1, wherein said placement stage supports a periphery of the object to be processed
3. The heat treatment apparatus as claimed in claim 2, wherein said placement stage has a heat capacity greater than that of the object to be processed.
4. The heat treatment apparatus as claimed in claim 3, wherein the object to be processed is a silicon wafer and said placement stage is made of silicon carbide.
5. The heat treatment apparatus as claimed in claim 1, wherein said heat radiation lamp is located at a focal point of said convex lens part.
6. The heat treatment apparatus as claimed in claim 1, wherein said placement stage is rotatable relative to said heat radiation lamp about a vertical axis thereof.
7. A heat treatment apparatus comprising:
a process chamber which defines a process space for processing an object to be processes;
a placement stage provided in the process chamber so as-to place the object to be processed thereon;
a gas supply part which supplies to the process chamber a process gas for processing the object to be processed;
a light-transmitting window provided as a part of said process chamber so that the light-transmitting window is opposite to the object to be processed placed on said placement stage; and
a heating unit which comprises a plurality of heat radiation lamps provided on an opposite side of said process chamber with respect to the light-transmitting window,
wherein the light-transmitting window constitutes a plurality of convex lens parts each of which corresponds to a respective one of the heat radiation lamps and protrudes into the process space.
8. The heat treatment apparatus as claimed in claim 7, wherein each of the heat radiation lamps is located at a focal point of a respective one of the convex lens parts.
9. The heat treatment apparatus as claimed in claim 7, wherein said placement stage is rotatable relative to said heat radiation lamps about a vertical axis thereof.
10. The heat treatment apparatus as claimed in claim 7, wherein each of said heat radiation lamps has an arc shape, and said heat radiation lamps are concentrically arranged in said heating unit.
11. The heat treatment apparatus as claimed in claim 7, wherein each of said heat radiation lamps is a single end type, and said heat radiation lamps are provided in said heating unit in an island arrangement.
12. The heat treatment apparatus as claimed in claim 7, wherein each of said heat radiation lamps has a rectilinear shape, and said heat radiation lamps are arranged parallel to each other in said heating unit.
13. A heat treatment apparatus comprising:
a process chamber in which a heat treatment is applied to an object to be processed;
a heat source which heats the objects to be processed by irradiating a radiation light onto the object to be processed; and
a quartz window provided between the object to be processed and said heat source, said quartz window comprising:
a plate made of quartz; and
a lens part fixed to said plate so as to improve a directivity of the radiation light emitted by said heat source and increase a mechanical strength of said plate.
14. The heat treatment apparatus as claimed in claim 13, wherein said heat source has a plurality of lamps, and said lens part has a plurality of lens elements corresponding to said lamps.
15. The heat treatment apparatus as claimed in claim 13, wherein said lens part is provided on a surface of said plate facing the object to be processed.
16. The heat treatment apparatus as claimed in claim 13, wherein said lens part is provided on both a surface of said plate facing the object to be processed and a surface opposite to the surface facing the object to be processed.
17. The heat treatment apparatus as claimed in claim 13, wherein said plate has at least one reinforcing member which increases a strength of said plate.
18. The heat treatment apparatus as claimed in claim 17, wherein a thickness of said plate is equal to or less than 7 mm.
19. The heat treatment apparatus as claimed in claim 17, wherein a thickness of said plate is equal to or less than 5 mm.
20. The heat treatment apparatus as claimed in claim 17, wherein said reinforcing member is made of aluminum.
21. The heat treatment apparatus as claimed in claim 17, further comprising a cooling arrangement which cools said reinforcing member.
22. The heat treatment apparatus as claimed in claim 13, wherein said lens part is provided on a first surface of said plate, and at least one reinforcing member is provided on a second surface of said plate opposite to said first surface so as to increase a strength of said plate.
23. The heat treatment apparatus as claimed in claim 22, wherein a plurality of reinforcing members are provided on said plate, and at least one waveguiding part made of quartz is provided between adjacent reinforcing members, the waveguiding part transmitting the radiation light passed through said lens part and said plate toward the object to be processed.
24. The heat treatment apparatus as claimed in claim 13, further comprising an exhaust device connected to said process chamber so as to maintain a negative pressure inside said process chamber.
25. A quartz window configured to be incorporated into a heat treatment apparatus which applies a heat treatment to an object to be processed by a radiation light emitted by a heat source, said quartz window being arranged between the object to be processed and the heat source, said quartz window comprising:
a plate made of quartz; and
a lens part fixed to said plate so as to converge the radiation light emitted by said heat source toward the object to be processed and increase a mechanical strength of said plate.
26. The heat treatment apparatus as claimed in claim 25, wherein said heat source has a plurality of lamps, and said lens part has a plurality of lens elements corresponding to said lamps.
27. The heat treatment apparatus as claimed in claim 25, wherein said lens part is provided on a surface of said plate facing the object to be processed.
28. The heat treatment apparatus as claimed in claim 25, wherein said lens part is provided on both a surface of said plate facing the object to be processed and a surface opposite to the surface facing the object to be processed.
29. The heat treatment apparatus as claimed in claim 25, wherein a thickness of said plate is equal to or less than 7 mm.
30. The heat treatment apparatus as claimed in claim 25, wherein a thickness of said plate is equal to or less than 5 mm.
US09/930,495 2000-08-17 2001-08-16 Heat treatment apparatus having a thin light-transmitting window Expired - Fee Related US6437290B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2000247591A JP2002064069A (en) 2000-08-17 2000-08-17 Heat treatment equipment
JP2000-247591 2000-08-17
JP2000343209A JP4666427B2 (en) 2000-11-10 2000-11-10 Quartz window and heat treatment equipment
JP2000-343209 2000-11-10

Publications (2)

Publication Number Publication Date
US20020030047A1 true US20020030047A1 (en) 2002-03-14
US6437290B1 US6437290B1 (en) 2002-08-20

Family

ID=26598041

Family Applications (1)

Application Number Title Priority Date Filing Date
US09/930,495 Expired - Fee Related US6437290B1 (en) 2000-08-17 2001-08-16 Heat treatment apparatus having a thin light-transmitting window

Country Status (1)

Country Link
US (1) US6437290B1 (en)

Cited By (325)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020105275A1 (en) * 2000-10-24 2002-08-08 Takashi Shigeoka Lamp having a high-reflectance film for improving directivity of light and heat treatment apparatus having such a lamp
US20050213950A1 (en) * 2004-03-23 2005-09-29 Canon Kabushiki Kaisha Cooling device, and apparatus and method for manufacturing image display panel using cooling device
EP1801861A1 (en) * 2004-07-09 2007-06-27 Sekisui Chemical Co., Ltd. Method and device for treating outer periphery of base material
US20080017613A1 (en) * 2004-07-09 2008-01-24 Sekisui Chemical Co., Ltd. Method for processing outer periphery of substrate and apparatus thereof
US20080092819A1 (en) * 2006-10-24 2008-04-24 Applied Materials, Inc. Substrate support structure with rapid temperature change
US20080199163A1 (en) * 2007-02-15 2008-08-21 Applied Materials, Inc. Lamp for Rapid Thermal Processing Chamber
US20110033175A1 (en) * 2008-01-28 2011-02-10 Tokyo Electron Limited Annealing apparatus
US20110044060A1 (en) * 2006-03-28 2011-02-24 Heraeus Noblelight Gmbh Infra-red radiation device
US20120181265A1 (en) * 2010-07-15 2012-07-19 Despatch Industries Limited Partnership Firing furnace configuration for thermal processing system
US20130284095A1 (en) * 2012-04-25 2013-10-31 Joseph M. Ranish Optics for controlling light transmitted through a conical quartz dome
US20140179053A1 (en) * 2012-12-21 2014-06-26 Industrial Technology Research Institute Method for fabricating absorbing layer of solar cell and thermal treatment device thereof
US20140341551A1 (en) * 2013-05-15 2014-11-20 Applied Materials, Inc. Diffuser for lamp heating assembly
US9186699B2 (en) * 2012-08-31 2015-11-17 Lg Display Co., Ltd. Curing apparatus
US20160370795A1 (en) * 2015-06-22 2016-12-22 Lam Research Corporation Systems and methods for calibrating scalar field contribution values for a limited number of sensors including a temperature value of an electrostatic chuck and estimating temperature distribution profiles based on calibrated values
CN106898567A (en) * 2015-12-17 2017-06-27 北京北方微电子基地设备工艺研究中心有限责任公司 A kind of transparent medium window, Substrate treatment chamber and substrate handling system
US20190019697A1 (en) * 2017-07-14 2019-01-17 SCREEN Holdings Co., Ltd. Light irradiation type heat treatment apparatus
US20190027384A1 (en) * 2017-07-20 2019-01-24 SCREEN Holdings Co., Ltd. Light irradiation type heat treatment apparatus
WO2019020387A1 (en) * 2017-07-26 2019-01-31 Siltronic Ag EPITACTICALLY COATED SEMICONDUCTOR SILICONE SEMICONDUCTOR DISC AND METHOD FOR THE PRODUCTION THEREOF
US10381248B2 (en) 2015-06-22 2019-08-13 Lam Research Corporation Auto-correction of electrostatic chuck temperature non-uniformity
US10655221B2 (en) 2017-02-09 2020-05-19 Asm Ip Holding B.V. Method for depositing oxide film by thermal ALD and PEALD
US10658205B2 (en) 2017-09-28 2020-05-19 Asm Ip Holdings B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US10665452B2 (en) 2016-05-02 2020-05-26 Asm Ip Holdings B.V. Source/drain performance through conformal solid state doping
US10672636B2 (en) 2017-08-09 2020-06-02 Asm Ip Holding B.V. Cassette holder assembly for a substrate cassette and holding member for use in such assembly
US10683571B2 (en) 2014-02-25 2020-06-16 Asm Ip Holding B.V. Gas supply manifold and method of supplying gases to chamber using same
US10685834B2 (en) 2017-07-05 2020-06-16 Asm Ip Holdings B.V. Methods for forming a silicon germanium tin layer and related semiconductor device structures
US10692741B2 (en) 2017-08-08 2020-06-23 Asm Ip Holdings B.V. Radiation shield
US10707106B2 (en) 2011-06-06 2020-07-07 Asm Ip Holding B.V. High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules
US10714315B2 (en) 2012-10-12 2020-07-14 Asm Ip Holdings B.V. Semiconductor reaction chamber showerhead
US10714385B2 (en) 2016-07-19 2020-07-14 Asm Ip Holding B.V. Selective deposition of tungsten
US10714350B2 (en) 2016-11-01 2020-07-14 ASM IP Holdings, B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10714335B2 (en) 2017-04-25 2020-07-14 Asm Ip Holding B.V. Method of depositing thin film and method of manufacturing semiconductor device
US10720331B2 (en) 2016-11-01 2020-07-21 ASM IP Holdings, B.V. Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10734244B2 (en) 2017-11-16 2020-08-04 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by the same
US10734223B2 (en) 2017-10-10 2020-08-04 Asm Ip Holding B.V. Method for depositing a metal chalcogenide on a substrate by cyclical deposition
US10731249B2 (en) 2018-02-15 2020-08-04 Asm Ip Holding B.V. Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus
US10734497B2 (en) 2017-07-18 2020-08-04 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US10741385B2 (en) 2016-07-28 2020-08-11 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10755923B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10755922B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10763142B2 (en) 2015-06-22 2020-09-01 Lam Research Corporation System and method for determining field non-uniformities of a wafer processing chamber using a wafer processing parameter
US10770336B2 (en) 2017-08-08 2020-09-08 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US10767789B2 (en) 2018-07-16 2020-09-08 Asm Ip Holding B.V. Diaphragm valves, valve components, and methods for forming valve components
US10784102B2 (en) 2016-12-22 2020-09-22 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10787741B2 (en) 2014-08-21 2020-09-29 Asm Ip Holding B.V. Method and system for in situ formation of gas-phase compounds
US10797133B2 (en) 2018-06-21 2020-10-06 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
US10804098B2 (en) 2009-08-14 2020-10-13 Asm Ip Holding B.V. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
US10811256B2 (en) 2018-10-16 2020-10-20 Asm Ip Holding B.V. Method for etching a carbon-containing feature
US10818758B2 (en) 2018-11-16 2020-10-27 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US10829852B2 (en) 2018-08-16 2020-11-10 Asm Ip Holding B.V. Gas distribution device for a wafer processing apparatus
US10832903B2 (en) 2011-10-28 2020-11-10 Asm Ip Holding B.V. Process feed management for semiconductor substrate processing
US10847371B2 (en) 2018-03-27 2020-11-24 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US10847365B2 (en) 2018-10-11 2020-11-24 Asm Ip Holding B.V. Method of forming conformal silicon carbide film by cyclic CVD
US10844484B2 (en) 2017-09-22 2020-11-24 Asm Ip Holding B.V. Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US10847366B2 (en) 2018-11-16 2020-11-24 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US10844486B2 (en) 2009-04-06 2020-11-24 Asm Ip Holding B.V. Semiconductor processing reactor and components thereof
US10851456B2 (en) 2016-04-21 2020-12-01 Asm Ip Holding B.V. Deposition of metal borides
USD903477S1 (en) 2018-01-24 2020-12-01 Asm Ip Holdings B.V. Metal clamp
US10858737B2 (en) 2014-07-28 2020-12-08 Asm Ip Holding B.V. Showerhead assembly and components thereof
US10867788B2 (en) 2016-12-28 2020-12-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10867786B2 (en) 2018-03-30 2020-12-15 Asm Ip Holding B.V. Substrate processing method
US10865475B2 (en) 2016-04-21 2020-12-15 Asm Ip Holding B.V. Deposition of metal borides and silicides
US10872771B2 (en) 2018-01-16 2020-12-22 Asm Ip Holding B. V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
US10883175B2 (en) 2018-08-09 2021-01-05 Asm Ip Holding B.V. Vertical furnace for processing substrates and a liner for use therein
US10892156B2 (en) 2017-05-08 2021-01-12 Asm Ip Holding B.V. Methods for forming a silicon nitride film on a substrate and related semiconductor device structures
US10896820B2 (en) 2018-02-14 2021-01-19 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US10910262B2 (en) 2017-11-16 2021-02-02 Asm Ip Holding B.V. Method of selectively depositing a capping layer structure on a semiconductor device structure
US10914004B2 (en) 2018-06-29 2021-02-09 Asm Ip Holding B.V. Thin-film deposition method and manufacturing method of semiconductor device
US10923344B2 (en) 2017-10-30 2021-02-16 Asm Ip Holding B.V. Methods for forming a semiconductor structure and related semiconductor structures
US10928731B2 (en) 2017-09-21 2021-02-23 Asm Ip Holding B.V. Method of sequential infiltration synthesis treatment of infiltrateable material and structures and devices formed using same
US10934619B2 (en) 2016-11-15 2021-03-02 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including the gas supply unit
US10941490B2 (en) 2014-10-07 2021-03-09 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US10943771B2 (en) 2016-10-26 2021-03-09 Asm Ip Holding B.V. Methods for thermally calibrating reaction chambers
USD913980S1 (en) 2018-02-01 2021-03-23 Asm Ip Holding B.V. Gas supply plate for semiconductor manufacturing apparatus
US10975470B2 (en) 2018-02-23 2021-04-13 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US11001925B2 (en) 2016-12-19 2021-05-11 Asm Ip Holding B.V. Substrate processing apparatus
US11004977B2 (en) 2017-07-19 2021-05-11 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11015245B2 (en) 2014-03-19 2021-05-25 Asm Ip Holding B.V. Gas-phase reactor and system having exhaust plenum and components thereof
US11018047B2 (en) 2018-01-25 2021-05-25 Asm Ip Holding B.V. Hybrid lift pin
US11018002B2 (en) 2017-07-19 2021-05-25 Asm Ip Holding B.V. Method for selectively depositing a Group IV semiconductor and related semiconductor device structures
US11024523B2 (en) 2018-09-11 2021-06-01 Asm Ip Holding B.V. Substrate processing apparatus and method
US11022879B2 (en) 2017-11-24 2021-06-01 Asm Ip Holding B.V. Method of forming an enhanced unexposed photoresist layer
US11031242B2 (en) 2018-11-07 2021-06-08 Asm Ip Holding B.V. Methods for depositing a boron doped silicon germanium film
USD922229S1 (en) 2019-06-05 2021-06-15 Asm Ip Holding B.V. Device for controlling a temperature of a gas supply unit
US11049751B2 (en) 2018-09-14 2021-06-29 Asm Ip Holding B.V. Cassette supply system to store and handle cassettes and processing apparatus equipped therewith
US11053591B2 (en) 2018-08-06 2021-07-06 Asm Ip Holding B.V. Multi-port gas injection system and reactor system including same
US11056567B2 (en) 2018-05-11 2021-07-06 Asm Ip Holding B.V. Method of forming a doped metal carbide film on a substrate and related semiconductor device structures
US11056344B2 (en) 2017-08-30 2021-07-06 Asm Ip Holding B.V. Layer forming method
US11069510B2 (en) 2017-08-30 2021-07-20 Asm Ip Holding B.V. Substrate processing apparatus
US11081345B2 (en) 2018-02-06 2021-08-03 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US11087997B2 (en) 2018-10-31 2021-08-10 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11088002B2 (en) 2018-03-29 2021-08-10 Asm Ip Holding B.V. Substrate rack and a substrate processing system and method
US11094582B2 (en) 2016-07-08 2021-08-17 Asm Ip Holding B.V. Selective deposition method to form air gaps
US11094546B2 (en) 2017-10-05 2021-08-17 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US11101370B2 (en) 2016-05-02 2021-08-24 Asm Ip Holding B.V. Method of forming a germanium oxynitride film
US11114294B2 (en) 2019-03-08 2021-09-07 Asm Ip Holding B.V. Structure including SiOC layer and method of forming same
US11114283B2 (en) 2018-03-16 2021-09-07 Asm Ip Holding B.V. Reactor, system including the reactor, and methods of manufacturing and using same
USD930782S1 (en) 2019-08-22 2021-09-14 Asm Ip Holding B.V. Gas distributor
US11127617B2 (en) 2017-11-27 2021-09-21 Asm Ip Holding B.V. Storage device for storing wafer cassettes for use with a batch furnace
US11127589B2 (en) 2019-02-01 2021-09-21 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
USD931978S1 (en) 2019-06-27 2021-09-28 Asm Ip Holding B.V. Showerhead vacuum transport
US11139191B2 (en) 2017-08-09 2021-10-05 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US11139308B2 (en) 2015-12-29 2021-10-05 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US11158513B2 (en) 2018-12-13 2021-10-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
USD935572S1 (en) 2019-05-24 2021-11-09 Asm Ip Holding B.V. Gas channel plate
US11168395B2 (en) 2018-06-29 2021-11-09 Asm Ip Holding B.V. Temperature-controlled flange and reactor system including same
US11171025B2 (en) 2019-01-22 2021-11-09 Asm Ip Holding B.V. Substrate processing device
US11205585B2 (en) 2016-07-28 2021-12-21 Asm Ip Holding B.V. Substrate processing apparatus and method of operating the same
US11217444B2 (en) 2018-11-30 2022-01-04 Asm Ip Holding B.V. Method for forming an ultraviolet radiation responsive metal oxide-containing film
USD940837S1 (en) 2019-08-22 2022-01-11 Asm Ip Holding B.V. Electrode
US11222772B2 (en) 2016-12-14 2022-01-11 Asm Ip Holding B.V. Substrate processing apparatus
US11227789B2 (en) 2019-02-20 2022-01-18 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US11227782B2 (en) 2019-07-31 2022-01-18 Asm Ip Holding B.V. Vertical batch furnace assembly
US11230766B2 (en) 2018-03-29 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11232963B2 (en) 2018-10-03 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11233133B2 (en) 2015-10-21 2022-01-25 Asm Ip Holding B.V. NbMC layers
US11242598B2 (en) 2015-06-26 2022-02-08 Asm Ip Holding B.V. Structures including metal carbide material, devices including the structures, and methods of forming same
US11251040B2 (en) 2019-02-20 2022-02-15 Asm Ip Holding B.V. Cyclical deposition method including treatment step and apparatus for same
US11251068B2 (en) 2018-10-19 2022-02-15 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
USD944946S1 (en) 2019-06-14 2022-03-01 Asm Ip Holding B.V. Shower plate
US11270899B2 (en) 2018-06-04 2022-03-08 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11274369B2 (en) 2018-09-11 2022-03-15 Asm Ip Holding B.V. Thin film deposition method
US11282698B2 (en) 2019-07-19 2022-03-22 Asm Ip Holding B.V. Method of forming topology-controlled amorphous carbon polymer film
CN114230390A (en) * 2021-12-13 2022-03-25 塔里木大学 A device for accelerating decomposing of orchard green manure and its overturning mechanism
US11289326B2 (en) 2019-05-07 2022-03-29 Asm Ip Holding B.V. Method for reforming amorphous carbon polymer film
US11286562B2 (en) 2018-06-08 2022-03-29 Asm Ip Holding B.V. Gas-phase chemical reactor and method of using same
US11286558B2 (en) 2019-08-23 2022-03-29 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
USD947913S1 (en) 2019-05-17 2022-04-05 Asm Ip Holding B.V. Susceptor shaft
US11295980B2 (en) 2017-08-30 2022-04-05 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
USD948463S1 (en) 2018-10-24 2022-04-12 Asm Ip Holding B.V. Susceptor for semiconductor substrate supporting apparatus
USD949319S1 (en) 2019-08-22 2022-04-19 Asm Ip Holding B.V. Exhaust duct
US11306395B2 (en) * 2017-06-28 2022-04-19 Asm Ip Holding B.V. Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus
US11315794B2 (en) 2019-10-21 2022-04-26 Asm Ip Holding B.V. Apparatus and methods for selectively etching films
US20220144684A1 (en) * 2018-10-19 2022-05-12 Heraeus Noblelight Gmbh Jet system for jetting laminated glass panels of differing widths
US11342216B2 (en) 2019-02-20 2022-05-24 Asm Ip Holding B.V. Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11339476B2 (en) 2019-10-08 2022-05-24 Asm Ip Holding B.V. Substrate processing device having connection plates, substrate processing method
US11345999B2 (en) 2019-06-06 2022-05-31 Asm Ip Holding B.V. Method of using a gas-phase reactor system including analyzing exhausted gas
US11355338B2 (en) 2019-05-10 2022-06-07 Asm Ip Holding B.V. Method of depositing material onto a surface and structure formed according to the method
US11361990B2 (en) 2018-05-28 2022-06-14 Asm Ip Holding B.V. Substrate processing method and device manufactured by using the same
US11374112B2 (en) 2017-07-19 2022-06-28 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11378337B2 (en) 2019-03-28 2022-07-05 Asm Ip Holding B.V. Door opener and substrate processing apparatus provided therewith
US11390946B2 (en) 2019-01-17 2022-07-19 Asm Ip Holding B.V. Methods of forming a transition metal containing film on a substrate by a cyclical deposition process
US11393690B2 (en) 2018-01-19 2022-07-19 Asm Ip Holding B.V. Deposition method
US11390950B2 (en) 2017-01-10 2022-07-19 Asm Ip Holding B.V. Reactor system and method to reduce residue buildup during a film deposition process
US11390945B2 (en) 2019-07-03 2022-07-19 Asm Ip Holding B.V. Temperature control assembly for substrate processing apparatus and method of using same
US11401605B2 (en) 2019-11-26 2022-08-02 Asm Ip Holding B.V. Substrate processing apparatus
US11410851B2 (en) 2017-02-15 2022-08-09 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures
US11414760B2 (en) 2018-10-08 2022-08-16 Asm Ip Holding B.V. Substrate support unit, thin film deposition apparatus including the same, and substrate processing apparatus including the same
US11424119B2 (en) 2019-03-08 2022-08-23 Asm Ip Holding B.V. Method for selective deposition of silicon nitride layer and structure including selectively-deposited silicon nitride layer
US11430674B2 (en) 2018-08-22 2022-08-30 Asm Ip Holding B.V. Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US11430640B2 (en) 2019-07-30 2022-08-30 Asm Ip Holding B.V. Substrate processing apparatus
US11437241B2 (en) 2020-04-08 2022-09-06 Asm Ip Holding B.V. Apparatus and methods for selectively etching silicon oxide films
US11443926B2 (en) 2019-07-30 2022-09-13 Asm Ip Holding B.V. Substrate processing apparatus
US11447864B2 (en) 2019-04-19 2022-09-20 Asm Ip Holding B.V. Layer forming method and apparatus
US11447861B2 (en) 2016-12-15 2022-09-20 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
USD965044S1 (en) 2019-08-19 2022-09-27 Asm Ip Holding B.V. Susceptor shaft
US11453943B2 (en) 2016-05-25 2022-09-27 Asm Ip Holding B.V. Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor
USD965524S1 (en) 2019-08-19 2022-10-04 Asm Ip Holding B.V. Susceptor support
US11469098B2 (en) 2018-05-08 2022-10-11 Asm Ip Holding B.V. Methods for depositing an oxide film on a substrate by a cyclical deposition process and related device structures
US11476109B2 (en) 2019-06-11 2022-10-18 Asm Ip Holding B.V. Method of forming an electronic structure using reforming gas, system for performing the method, and structure formed using the method
US11473195B2 (en) 2018-03-01 2022-10-18 Asm Ip Holding B.V. Semiconductor processing apparatus and a method for processing a substrate
US11482418B2 (en) 2018-02-20 2022-10-25 Asm Ip Holding B.V. Substrate processing method and apparatus
US11482412B2 (en) 2018-01-19 2022-10-25 Asm Ip Holding B.V. Method for depositing a gap-fill layer by plasma-assisted deposition
US11482533B2 (en) 2019-02-20 2022-10-25 Asm Ip Holding B.V. Apparatus and methods for plug fill deposition in 3-D NAND applications
US11488854B2 (en) 2020-03-11 2022-11-01 Asm Ip Holding B.V. Substrate handling device with adjustable joints
US11488819B2 (en) 2018-12-04 2022-11-01 Asm Ip Holding B.V. Method of cleaning substrate processing apparatus
US11495459B2 (en) 2019-09-04 2022-11-08 Asm Ip Holding B.V. Methods for selective deposition using a sacrificial capping layer
US11492703B2 (en) 2018-06-27 2022-11-08 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11499222B2 (en) 2018-06-27 2022-11-15 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11499226B2 (en) 2018-11-02 2022-11-15 Asm Ip Holding B.V. Substrate supporting unit and a substrate processing device including the same
US11501968B2 (en) 2019-11-15 2022-11-15 Asm Ip Holding B.V. Method for providing a semiconductor device with silicon filled gaps
US11515187B2 (en) 2020-05-01 2022-11-29 Asm Ip Holding B.V. Fast FOUP swapping with a FOUP handler
US11515188B2 (en) 2019-05-16 2022-11-29 Asm Ip Holding B.V. Wafer boat handling device, vertical batch furnace and method
US11521851B2 (en) 2020-02-03 2022-12-06 Asm Ip Holding B.V. Method of forming structures including a vanadium or indium layer
US11527400B2 (en) 2019-08-23 2022-12-13 Asm Ip Holding B.V. Method for depositing silicon oxide film having improved quality by peald using bis(diethylamino)silane
US11527403B2 (en) 2019-12-19 2022-12-13 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US11530483B2 (en) 2018-06-21 2022-12-20 Asm Ip Holding B.V. Substrate processing system
US11532757B2 (en) 2016-10-27 2022-12-20 Asm Ip Holding B.V. Deposition of charge trapping layers
US11530876B2 (en) 2020-04-24 2022-12-20 Asm Ip Holding B.V. Vertical batch furnace assembly comprising a cooling gas supply
US11551912B2 (en) 2020-01-20 2023-01-10 Asm Ip Holding B.V. Method of forming thin film and method of modifying surface of thin film
US11551925B2 (en) 2019-04-01 2023-01-10 Asm Ip Holding B.V. Method for manufacturing a semiconductor device
USD975665S1 (en) 2019-05-17 2023-01-17 Asm Ip Holding B.V. Susceptor shaft
US11557474B2 (en) 2019-07-29 2023-01-17 Asm Ip Holding B.V. Methods for selective deposition utilizing n-type dopants and/or alternative dopants to achieve high dopant incorporation
US11562901B2 (en) 2019-09-25 2023-01-24 Asm Ip Holding B.V. Substrate processing method
US11572620B2 (en) 2018-11-06 2023-02-07 Asm Ip Holding B.V. Methods for selectively depositing an amorphous silicon film on a substrate
US11581186B2 (en) 2016-12-15 2023-02-14 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus
US11587815B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587814B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11594450B2 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Method for forming a structure with a hole
US11594600B2 (en) 2019-11-05 2023-02-28 Asm Ip Holding B.V. Structures with doped semiconductor layers and methods and systems for forming same
USD979506S1 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Insulator
USD980814S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas distributor for substrate processing apparatus
USD980813S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas flow control plate for substrate processing apparatus
US11605528B2 (en) 2019-07-09 2023-03-14 Asm Ip Holding B.V. Plasma device using coaxial waveguide, and substrate treatment method
US11610775B2 (en) 2016-07-28 2023-03-21 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11610774B2 (en) 2019-10-02 2023-03-21 Asm Ip Holding B.V. Methods for forming a topographically selective silicon oxide film by a cyclical plasma-enhanced deposition process
USD981973S1 (en) 2021-05-11 2023-03-28 Asm Ip Holding B.V. Reactor wall for substrate processing apparatus
US11615970B2 (en) 2019-07-17 2023-03-28 Asm Ip Holding B.V. Radical assist ignition plasma system and method
US11626308B2 (en) 2020-05-13 2023-04-11 Asm Ip Holding B.V. Laser alignment fixture for a reactor system
US11626316B2 (en) 2019-11-20 2023-04-11 Asm Ip Holding B.V. Method of depositing carbon-containing material on a surface of a substrate, structure formed using the method, and system for forming the structure
US11629406B2 (en) 2018-03-09 2023-04-18 Asm Ip Holding B.V. Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate
US11629407B2 (en) 2019-02-22 2023-04-18 Asm Ip Holding B.V. Substrate processing apparatus and method for processing substrates
US11637011B2 (en) 2019-10-16 2023-04-25 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11637014B2 (en) 2019-10-17 2023-04-25 Asm Ip Holding B.V. Methods for selective deposition of doped semiconductor material
US20230132307A1 (en) * 2021-10-26 2023-04-27 Applied Materials, Inc. Chuck For Processing Semiconductor Workpieces At High Temperatures
US11639811B2 (en) 2017-11-27 2023-05-02 Asm Ip Holding B.V. Apparatus including a clean mini environment
US11639548B2 (en) 2019-08-21 2023-05-02 Asm Ip Holding B.V. Film-forming material mixed-gas forming device and film forming device
US11644758B2 (en) 2020-07-17 2023-05-09 Asm Ip Holding B.V. Structures and methods for use in photolithography
US11646184B2 (en) 2019-11-29 2023-05-09 Asm Ip Holding B.V. Substrate processing apparatus
US11646204B2 (en) 2020-06-24 2023-05-09 Asm Ip Holding B.V. Method for forming a layer provided with silicon
US11646205B2 (en) 2019-10-29 2023-05-09 Asm Ip Holding B.V. Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same
US11643724B2 (en) 2019-07-18 2023-05-09 Asm Ip Holding B.V. Method of forming structures using a neutral beam
US11649546B2 (en) 2016-07-08 2023-05-16 Asm Ip Holding B.V. Organic reactants for atomic layer deposition
US11658029B2 (en) 2018-12-14 2023-05-23 Asm Ip Holding B.V. Method of forming a device structure using selective deposition of gallium nitride and system for same
US11658035B2 (en) 2020-06-30 2023-05-23 Asm Ip Holding B.V. Substrate processing method
US11658030B2 (en) 2017-03-29 2023-05-23 Asm Ip Holding B.V. Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures
US11664267B2 (en) 2019-07-10 2023-05-30 Asm Ip Holding B.V. Substrate support assembly and substrate processing device including the same
US11664199B2 (en) 2018-10-19 2023-05-30 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
US11664245B2 (en) 2019-07-16 2023-05-30 Asm Ip Holding B.V. Substrate processing device
US11676812B2 (en) 2016-02-19 2023-06-13 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on top/bottom portions
US11674220B2 (en) 2020-07-20 2023-06-13 Asm Ip Holding B.V. Method for depositing molybdenum layers using an underlayer
US11680839B2 (en) 2019-08-05 2023-06-20 Asm Ip Holding B.V. Liquid level sensor for a chemical source vessel
USD990441S1 (en) 2021-09-07 2023-06-27 Asm Ip Holding B.V. Gas flow control plate
US11685991B2 (en) 2018-02-14 2023-06-27 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
USD990534S1 (en) 2020-09-11 2023-06-27 Asm Ip Holding B.V. Weighted lift pin
US11688603B2 (en) 2019-07-17 2023-06-27 Asm Ip Holding B.V. Methods of forming silicon germanium structures
US11705333B2 (en) 2020-05-21 2023-07-18 Asm Ip Holding B.V. Structures including multiple carbon layers and methods of forming and using same
US11718913B2 (en) 2018-06-04 2023-08-08 Asm Ip Holding B.V. Gas distribution system and reactor system including same
US11725277B2 (en) 2011-07-20 2023-08-15 Asm Ip Holding B.V. Pressure transmitter for a semiconductor processing environment
US11725280B2 (en) 2020-08-26 2023-08-15 Asm Ip Holding B.V. Method for forming metal silicon oxide and metal silicon oxynitride layers
US11735422B2 (en) 2019-10-10 2023-08-22 Asm Ip Holding B.V. Method of forming a photoresist underlayer and structure including same
US11742189B2 (en) 2015-03-12 2023-08-29 Asm Ip Holding B.V. Multi-zone reactor, system including the reactor, and method of using the same
US11742198B2 (en) 2019-03-08 2023-08-29 Asm Ip Holding B.V. Structure including SiOCN layer and method of forming same
US11767589B2 (en) 2020-05-29 2023-09-26 Asm Ip Holding B.V. Substrate processing device
US11769682B2 (en) 2017-08-09 2023-09-26 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US11776846B2 (en) 2020-02-07 2023-10-03 Asm Ip Holding B.V. Methods for depositing gap filling fluids and related systems and devices
US11781243B2 (en) 2020-02-17 2023-10-10 Asm Ip Holding B.V. Method for depositing low temperature phosphorous-doped silicon
US11781221B2 (en) 2019-05-07 2023-10-10 Asm Ip Holding B.V. Chemical source vessel with dip tube
US11804364B2 (en) 2020-05-19 2023-10-31 Asm Ip Holding B.V. Substrate processing apparatus
US11802338B2 (en) 2017-07-26 2023-10-31 Asm Ip Holding B.V. Chemical treatment, deposition and/or infiltration apparatus and method for using the same
US11814747B2 (en) 2019-04-24 2023-11-14 Asm Ip Holding B.V. Gas-phase reactor system-with a reaction chamber, a solid precursor source vessel, a gas distribution system, and a flange assembly
US11823876B2 (en) 2019-09-05 2023-11-21 Asm Ip Holding B.V. Substrate processing apparatus
US11823866B2 (en) 2020-04-02 2023-11-21 Asm Ip Holding B.V. Thin film forming method
US11821078B2 (en) 2020-04-15 2023-11-21 Asm Ip Holding B.V. Method for forming precoat film and method for forming silicon-containing film
US11830738B2 (en) 2020-04-03 2023-11-28 Asm Ip Holding B.V. Method for forming barrier layer and method for manufacturing semiconductor device
US11828707B2 (en) 2020-02-04 2023-11-28 Asm Ip Holding B.V. Method and apparatus for transmittance measurements of large articles
US11827981B2 (en) 2020-10-14 2023-11-28 Asm Ip Holding B.V. Method of depositing material on stepped structure
US11830730B2 (en) 2017-08-29 2023-11-28 Asm Ip Holding B.V. Layer forming method and apparatus
US11840761B2 (en) 2019-12-04 2023-12-12 Asm Ip Holding B.V. Substrate processing apparatus
US11848200B2 (en) 2017-05-08 2023-12-19 Asm Ip Holding B.V. Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures
US11873557B2 (en) 2020-10-22 2024-01-16 Asm Ip Holding B.V. Method of depositing vanadium metal
US11876356B2 (en) 2020-03-11 2024-01-16 Asm Ip Holding B.V. Lockout tagout assembly and system and method of using same
US11885020B2 (en) 2020-12-22 2024-01-30 Asm Ip Holding B.V. Transition metal deposition method
US11885023B2 (en) 2018-10-01 2024-01-30 Asm Ip Holding B.V. Substrate retaining apparatus, system including the apparatus, and method of using same
US11887857B2 (en) 2020-04-24 2024-01-30 Asm Ip Holding B.V. Methods and systems for depositing a layer comprising vanadium, nitrogen, and a further element
USD1012873S1 (en) 2020-09-24 2024-01-30 Asm Ip Holding B.V. Electrode for semiconductor processing apparatus
US11885013B2 (en) 2019-12-17 2024-01-30 Asm Ip Holding B.V. Method of forming vanadium nitride layer and structure including the vanadium nitride layer
US11891696B2 (en) 2020-11-30 2024-02-06 Asm Ip Holding B.V. Injector configured for arrangement within a reaction chamber of a substrate processing apparatus
TWI832555B (en) * 2021-12-29 2024-02-11 大陸商上海陛通半導體能源科技股份有限公司 Multifunctional wafer pretreatment chamber and chemical vapor deposition equipment
US11901179B2 (en) 2020-10-28 2024-02-13 Asm Ip Holding B.V. Method and device for depositing silicon onto substrates
US11898243B2 (en) 2020-04-24 2024-02-13 Asm Ip Holding B.V. Method of forming vanadium nitride-containing layer
US11915929B2 (en) 2019-11-26 2024-02-27 Asm Ip Holding B.V. Methods for selectively forming a target film on a substrate comprising a first dielectric surface and a second metallic surface
US11923181B2 (en) 2019-11-29 2024-03-05 Asm Ip Holding B.V. Substrate processing apparatus for minimizing the effect of a filling gas during substrate processing
US11929251B2 (en) 2019-12-02 2024-03-12 Asm Ip Holding B.V. Substrate processing apparatus having electrostatic chuck and substrate processing method
US11946137B2 (en) 2020-12-16 2024-04-02 Asm Ip Holding B.V. Runout and wobble measurement fixtures
US11961741B2 (en) 2020-03-12 2024-04-16 Asm Ip Holding B.V. Method for fabricating layer structure having target topological profile
US11959168B2 (en) 2020-04-29 2024-04-16 Asm Ip Holding B.V. Solid source precursor vessel
US11967488B2 (en) 2013-02-01 2024-04-23 Asm Ip Holding B.V. Method for treatment of deposition reactor
USD1023959S1 (en) 2021-05-11 2024-04-23 Asm Ip Holding B.V. Electrode for substrate processing apparatus
US11976359B2 (en) 2020-01-06 2024-05-07 Asm Ip Holding B.V. Gas supply assembly, components thereof, and reactor system including same
US11986868B2 (en) 2020-02-28 2024-05-21 Asm Ip Holding B.V. System dedicated for parts cleaning
US11987881B2 (en) 2020-05-22 2024-05-21 Asm Ip Holding B.V. Apparatus for depositing thin films using hydrogen peroxide
US11996292B2 (en) 2019-10-25 2024-05-28 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US11993843B2 (en) 2017-08-31 2024-05-28 Asm Ip Holding B.V. Substrate processing apparatus
US11996289B2 (en) 2020-04-16 2024-05-28 Asm Ip Holding B.V. Methods of forming structures including silicon germanium and silicon layers, devices formed using the methods, and systems for performing the methods
US11996309B2 (en) 2019-05-16 2024-05-28 Asm Ip Holding B.V. Wafer boat handling device, vertical batch furnace and method
US11993847B2 (en) 2020-01-08 2024-05-28 Asm Ip Holding B.V. Injector
US12009224B2 (en) 2020-09-29 2024-06-11 Asm Ip Holding B.V. Apparatus and method for etching metal nitrides
US12009241B2 (en) 2019-10-14 2024-06-11 Asm Ip Holding B.V. Vertical batch furnace assembly with detector to detect cassette
US12006572B2 (en) 2019-10-08 2024-06-11 Asm Ip Holding B.V. Reactor system including a gas distribution assembly for use with activated species and method of using same
US12020934B2 (en) 2020-07-08 2024-06-25 Asm Ip Holding B.V. Substrate processing method
US12025484B2 (en) 2018-05-08 2024-07-02 Asm Ip Holding B.V. Thin film forming method
US12027365B2 (en) 2020-11-24 2024-07-02 Asm Ip Holding B.V. Methods for filling a gap and related systems and devices
US12033885B2 (en) 2020-01-06 2024-07-09 Asm Ip Holding B.V. Channeled lift pin
US12040199B2 (en) 2018-11-28 2024-07-16 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US12040177B2 (en) 2020-08-18 2024-07-16 Asm Ip Holding B.V. Methods for forming a laminate film by cyclical plasma-enhanced deposition processes
US12040200B2 (en) 2017-06-20 2024-07-16 Asm Ip Holding B.V. Semiconductor processing apparatus and methods for calibrating a semiconductor processing apparatus
US12051602B2 (en) 2020-05-04 2024-07-30 Asm Ip Holding B.V. Substrate processing system for processing substrates with an electronics module located behind a door in a front wall of the substrate processing system
US12051567B2 (en) 2020-10-07 2024-07-30 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including gas supply unit
US12057314B2 (en) 2020-05-15 2024-08-06 Asm Ip Holding B.V. Methods for silicon germanium uniformity control using multiple precursors
US12074022B2 (en) 2020-08-27 2024-08-27 Asm Ip Holding B.V. Method and system for forming patterned structures using multiple patterning process
US12087586B2 (en) 2020-04-15 2024-09-10 Asm Ip Holding B.V. Method of forming chromium nitride layer and structure including the chromium nitride layer
US12107005B2 (en) 2020-10-06 2024-10-01 Asm Ip Holding B.V. Deposition method and an apparatus for depositing a silicon-containing material
US12106944B2 (en) 2020-06-02 2024-10-01 Asm Ip Holding B.V. Rotating substrate support
US12112940B2 (en) 2019-07-19 2024-10-08 Asm Ip Holding B.V. Method of forming topology-controlled amorphous carbon polymer film
US12125700B2 (en) 2020-01-16 2024-10-22 Asm Ip Holding B.V. Method of forming high aspect ratio features
US12131885B2 (en) 2020-12-22 2024-10-29 Asm Ip Holding B.V. Plasma treatment device having matching box
US12129545B2 (en) 2020-12-22 2024-10-29 Asm Ip Holding B.V. Precursor capsule, a vessel and a method
US12148609B2 (en) 2020-09-16 2024-11-19 Asm Ip Holding B.V. Silicon oxide deposition method
US12154824B2 (en) 2020-08-14 2024-11-26 Asm Ip Holding B.V. Substrate processing method
US12159788B2 (en) 2020-12-14 2024-12-03 Asm Ip Holding B.V. Method of forming structures for threshold voltage control
US12169361B2 (en) 2019-07-30 2024-12-17 Asm Ip Holding B.V. Substrate processing apparatus and method
US12173404B2 (en) 2020-03-17 2024-12-24 Asm Ip Holding B.V. Method of depositing epitaxial material, structure formed using the method, and system for performing the method
US12195852B2 (en) 2020-11-23 2025-01-14 Asm Ip Holding B.V. Substrate processing apparatus with an injector
US12209308B2 (en) 2020-11-12 2025-01-28 Asm Ip Holding B.V. Reactor and related methods
US12211742B2 (en) 2020-09-10 2025-01-28 Asm Ip Holding B.V. Methods for depositing gap filling fluid
USD1060598S1 (en) 2021-12-03 2025-02-04 Asm Ip Holding B.V. Split showerhead cover
US12218269B2 (en) 2020-02-13 2025-02-04 Asm Ip Holding B.V. Substrate processing apparatus including light receiving device and calibration method of light receiving device
US12217954B2 (en) 2020-08-25 2025-02-04 Asm Ip Holding B.V. Method of cleaning a surface
US12218000B2 (en) 2020-09-25 2025-02-04 Asm Ip Holding B.V. Semiconductor processing method
US12217946B2 (en) 2020-10-15 2025-02-04 Asm Ip Holding B.V. Method of manufacturing semiconductor device, and substrate treatment apparatus using ether-CAT
US12221357B2 (en) 2020-04-24 2025-02-11 Asm Ip Holding B.V. Methods and apparatus for stabilizing vanadium compounds
US12230531B2 (en) 2018-04-09 2025-02-18 Asm Ip Holding B.V. Substrate supporting apparatus, substrate processing apparatus including the same, and substrate processing method
US12243757B2 (en) 2020-05-21 2025-03-04 Asm Ip Holding B.V. Flange and apparatus for processing substrates
US12241158B2 (en) 2020-07-20 2025-03-04 Asm Ip Holding B.V. Method for forming structures including transition metal layers
US12243747B2 (en) 2020-04-24 2025-03-04 Asm Ip Holding B.V. Methods of forming structures including vanadium boride and vanadium phosphide layers
US12240760B2 (en) 2016-03-18 2025-03-04 Asm Ip Holding B.V. Aligned carbon nanotubes
US12243742B2 (en) 2020-04-21 2025-03-04 Asm Ip Holding B.V. Method for processing a substrate
US12247286B2 (en) 2019-08-09 2025-03-11 Asm Ip Holding B.V. Heater assembly including cooling apparatus and method of using same
US12255053B2 (en) 2020-12-10 2025-03-18 Asm Ip Holding B.V. Methods and systems for depositing a layer
US12252785B2 (en) 2019-06-10 2025-03-18 Asm Ip Holding B.V. Method for cleaning quartz epitaxial chambers
US12266524B2 (en) 2020-06-16 2025-04-01 Asm Ip Holding B.V. Method for depositing boron containing silicon germanium layers
US12272527B2 (en) 2018-05-09 2025-04-08 Asm Ip Holding B.V. Apparatus for use with hydrogen radicals and method of using same
US12278129B2 (en) 2020-03-04 2025-04-15 Asm Ip Holding B.V. Alignment fixture for a reactor system
US12276023B2 (en) 2017-08-04 2025-04-15 Asm Ip Holding B.V. Showerhead assembly for distributing a gas within a reaction chamber
US12288710B2 (en) 2020-12-18 2025-04-29 Asm Ip Holding B.V. Wafer processing apparatus with a rotatable table

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3545672B2 (en) * 2000-04-21 2004-07-21 東京エレクトロン株式会社 Substrate processing method and substrate processing apparatus
DE20020148U1 (en) * 2000-09-18 2001-03-22 Advanced Photonics Technologies AG, 83052 Bruckmühl Radiation source and radiation arrangement
JP4842429B2 (en) * 2000-10-03 2011-12-21 東京エレクトロン株式会社 Heat treatment apparatus design method and computer-readable recording medium
JP2002118071A (en) * 2000-10-10 2002-04-19 Ushio Inc Apparatus and method for heat treatment by light irradiation
US6970644B2 (en) * 2000-12-21 2005-11-29 Mattson Technology, Inc. Heating configuration for use in thermal processing chambers
JP3857623B2 (en) * 2001-08-07 2006-12-13 株式会社日立国際電気 Temperature control method and semiconductor device manufacturing method
US7038173B2 (en) * 2002-02-07 2006-05-02 Dainippon Screen Mfg. Co., Ltd. Thermal processing apparatus and thermal processing method
US6576565B1 (en) * 2002-02-14 2003-06-10 Infineon Technologies, Ag RTCVD process and reactor for improved conformality and step-coverage
JP4437641B2 (en) * 2002-08-21 2010-03-24 大日本スクリーン製造株式会社 Heat treatment equipment
KR100429296B1 (en) * 2002-09-09 2004-04-29 한국전자통신연구원 Apparatus for manufacturing semiconductor device and method for manufacturing semiconductor device for using the same
US6879777B2 (en) * 2002-10-03 2005-04-12 Asm America, Inc. Localized heating of substrates using optics
KR100377011B1 (en) * 2002-11-01 2003-03-19 코닉 시스템 주식회사 Heater module of rapid thermal process apparatus
US6862404B1 (en) * 2003-09-08 2005-03-01 Wafermasters Focused photon energy heating chamber
JP4866020B2 (en) * 2005-05-02 2012-02-01 大日本スクリーン製造株式会社 Heat treatment equipment
JP4979472B2 (en) * 2007-06-05 2012-07-18 東京エレクトロン株式会社 Processing equipment
JP4971078B2 (en) * 2007-08-30 2012-07-11 東京応化工業株式会社 Surface treatment equipment
US8314368B2 (en) * 2008-02-22 2012-11-20 Applied Materials, Inc. Silver reflectors for semiconductor processing chambers
JP5533335B2 (en) * 2009-07-22 2014-06-25 東京エレクトロン株式会社 Processing apparatus and operation method thereof
WO2011031672A2 (en) * 2009-09-09 2011-03-17 Applied Materials, Inc. Parallel system for epitaxial chemical vapor deposition
JP5730521B2 (en) * 2010-09-08 2015-06-10 株式会社日立ハイテクノロジーズ Heat treatment equipment
US8772055B1 (en) 2013-01-16 2014-07-08 Applied Materials, Inc. Multizone control of lamps in a conical lamphead using pyrometers
CN105629590A (en) * 2016-01-04 2016-06-01 京东方科技集团股份有限公司 Seal glue coating device and coating method
US10727094B2 (en) 2016-01-29 2020-07-28 Taiwan Semiconductor Manufacturing Co., Ltd Thermal reflector device for semiconductor fabrication tool
US10446420B2 (en) * 2016-08-19 2019-10-15 Applied Materials, Inc. Upper cone for epitaxy chamber
KR102408720B1 (en) * 2017-06-07 2022-06-14 삼성전자주식회사 Semiconductor process chamber including upper dome
US20220143657A1 (en) * 2020-11-06 2022-05-12 Jelight Company, Inc. Ultraviolet specimen cleaning apparatus
US12165907B2 (en) * 2020-11-19 2024-12-10 Applied Materials, Inc. Apparatus for rotating substrates

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4755654A (en) * 1987-03-26 1988-07-05 Crowley John L Semiconductor wafer heating chamber
US5085887A (en) * 1990-09-07 1992-02-04 Applied Materials, Inc. Wafer reactor vessel window with pressure-thermal compensation
JPH0799162A (en) * 1993-06-21 1995-04-11 Hitachi Ltd CVD reactor device
KR0158780B1 (en) * 1994-12-22 1998-11-16 가네꼬 히사시 Method and apparatus for film formation by chemical vapor deposition
US6099648A (en) * 1997-08-06 2000-08-08 Applied Materials, Inc. Domed wafer reactor vessel window with reduced stress at atmospheric and above atmospheric pressures
US6156079A (en) * 1998-10-21 2000-12-05 Ho; Henry Window support member for a semiconductor processing system

Cited By (427)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6825615B2 (en) * 2000-10-24 2004-11-30 Tokyo Electron Limited Lamp having a high-reflectance film for improving directivity of light and heat treatment apparatus having such a lamp
US20020105275A1 (en) * 2000-10-24 2002-08-08 Takashi Shigeoka Lamp having a high-reflectance film for improving directivity of light and heat treatment apparatus having such a lamp
US7239804B2 (en) * 2004-03-23 2007-07-03 Canon Kabushiki Kaisha Cooling device, and apparatus and method for manufacturing image display panel using cooling device
US20050213950A1 (en) * 2004-03-23 2005-09-29 Canon Kabushiki Kaisha Cooling device, and apparatus and method for manufacturing image display panel using cooling device
EP1833078A3 (en) * 2004-07-09 2011-04-27 Sekisui Chemical Co., Ltd. Method for processing outer periphery of substrate and apparatus thereof
US20080017613A1 (en) * 2004-07-09 2008-01-24 Sekisui Chemical Co., Ltd. Method for processing outer periphery of substrate and apparatus thereof
US20080073324A1 (en) * 2004-07-09 2008-03-27 Sekisui Chemical Co., Ltd. Method For Processing Outer Periphery Of Substrate And Apparatus Thereof
EP1833078A2 (en) * 2004-07-09 2007-09-12 Sekisui Chemical Co., Ltd. Method for processing outer periphery of substrate and apparatus thereof
EP1801861A1 (en) * 2004-07-09 2007-06-27 Sekisui Chemical Co., Ltd. Method and device for treating outer periphery of base material
EP1801861A4 (en) * 2004-07-09 2011-04-27 Sekisui Chemical Co Ltd Method and device for treating outer periphery of base material
US20110044060A1 (en) * 2006-03-28 2011-02-24 Heraeus Noblelight Gmbh Infra-red radiation device
US20080092819A1 (en) * 2006-10-24 2008-04-24 Applied Materials, Inc. Substrate support structure with rapid temperature change
EP2115372A4 (en) * 2007-02-15 2011-04-27 Applied Materials Inc LAMP FOR FAST THERMAL TREATMENT CHAMBER
US9536728B2 (en) 2007-02-15 2017-01-03 Applied Material, Inc. Lamp for rapid thermal processing chamber
EP2115372A1 (en) * 2007-02-15 2009-11-11 Applied Materials, Inc. Lamp for rapid thermal processing chamber
US20080199163A1 (en) * 2007-02-15 2008-08-21 Applied Materials, Inc. Lamp for Rapid Thermal Processing Chamber
US20110033175A1 (en) * 2008-01-28 2011-02-10 Tokyo Electron Limited Annealing apparatus
US8897631B2 (en) * 2008-01-28 2014-11-25 Tokyo Electron Limited Annealing apparatus
US10844486B2 (en) 2009-04-06 2020-11-24 Asm Ip Holding B.V. Semiconductor processing reactor and components thereof
US10804098B2 (en) 2009-08-14 2020-10-13 Asm Ip Holding B.V. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
US20120181265A1 (en) * 2010-07-15 2012-07-19 Despatch Industries Limited Partnership Firing furnace configuration for thermal processing system
US10707106B2 (en) 2011-06-06 2020-07-07 Asm Ip Holding B.V. High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules
US11725277B2 (en) 2011-07-20 2023-08-15 Asm Ip Holding B.V. Pressure transmitter for a semiconductor processing environment
US10832903B2 (en) 2011-10-28 2020-11-10 Asm Ip Holding B.V. Process feed management for semiconductor substrate processing
CN104246981A (en) * 2012-04-25 2014-12-24 应用材料公司 Optics for controlling light transmitted through a conical quartz dome
US20130284095A1 (en) * 2012-04-25 2013-10-31 Joseph M. Ranish Optics for controlling light transmitted through a conical quartz dome
TWI623992B (en) * 2012-04-25 2018-05-11 應用材料股份有限公司 Optics for controlling light transmitted through a conical quartz dome
CN108051906A (en) * 2012-04-25 2018-05-18 应用材料公司 The optical system of the light of taper quartz dome structure is passed through for controlling transmission
US9905444B2 (en) * 2012-04-25 2018-02-27 Applied Materials, Inc. Optics for controlling light transmitted through a conical quartz dome
US9186699B2 (en) * 2012-08-31 2015-11-17 Lg Display Co., Ltd. Curing apparatus
US10714315B2 (en) 2012-10-12 2020-07-14 Asm Ip Holdings B.V. Semiconductor reaction chamber showerhead
US11501956B2 (en) 2012-10-12 2022-11-15 Asm Ip Holding B.V. Semiconductor reaction chamber showerhead
US20140179053A1 (en) * 2012-12-21 2014-06-26 Industrial Technology Research Institute Method for fabricating absorbing layer of solar cell and thermal treatment device thereof
US11967488B2 (en) 2013-02-01 2024-04-23 Asm Ip Holding B.V. Method for treatment of deposition reactor
CN105190850A (en) * 2013-05-15 2015-12-23 应用材料公司 Diffuser for lamp heating assembly
US10327284B2 (en) * 2013-05-15 2019-06-18 Applied Materials, Inc. Diffuser for lamp heating assembly
KR20160010505A (en) * 2013-05-15 2016-01-27 어플라이드 머티어리얼스, 인코포레이티드 Diffuser for lamp heating assembly
KR102357780B1 (en) 2013-05-15 2022-02-08 어플라이드 머티어리얼스, 인코포레이티드 Diffuser for lamp heating assembly
TWI622101B (en) * 2013-05-15 2018-04-21 應用材料股份有限公司 Diffuser for lamp heating assembly
US20140341551A1 (en) * 2013-05-15 2014-11-20 Applied Materials, Inc. Diffuser for lamp heating assembly
TWI691030B (en) * 2013-05-15 2020-04-11 美商應用材料股份有限公司 Diffuser for lamp heating assembly
KR20210080632A (en) * 2013-05-15 2021-06-30 어플라이드 머티어리얼스, 인코포레이티드 Diffuser for lamp heating assembly
KR102271250B1 (en) * 2013-05-15 2021-06-30 어플라이드 머티어리얼스, 인코포레이티드 Diffuser for lamp heating assembly
US10683571B2 (en) 2014-02-25 2020-06-16 Asm Ip Holding B.V. Gas supply manifold and method of supplying gases to chamber using same
US11015245B2 (en) 2014-03-19 2021-05-25 Asm Ip Holding B.V. Gas-phase reactor and system having exhaust plenum and components thereof
US10858737B2 (en) 2014-07-28 2020-12-08 Asm Ip Holding B.V. Showerhead assembly and components thereof
US10787741B2 (en) 2014-08-21 2020-09-29 Asm Ip Holding B.V. Method and system for in situ formation of gas-phase compounds
US10941490B2 (en) 2014-10-07 2021-03-09 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US11795545B2 (en) 2014-10-07 2023-10-24 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US11742189B2 (en) 2015-03-12 2023-08-29 Asm Ip Holding B.V. Multi-zone reactor, system including the reactor, and method of using the same
US10763142B2 (en) 2015-06-22 2020-09-01 Lam Research Corporation System and method for determining field non-uniformities of a wafer processing chamber using a wafer processing parameter
US20160370795A1 (en) * 2015-06-22 2016-12-22 Lam Research Corporation Systems and methods for calibrating scalar field contribution values for a limited number of sensors including a temperature value of an electrostatic chuck and estimating temperature distribution profiles based on calibrated values
US11029668B2 (en) 2015-06-22 2021-06-08 Lam Research Corporation Systems and methods for calibrating scalar field contribution values for a limited number of sensors including a temperature value of an electrostatic chuck and estimating temperature distribution profiles based on calibrated values
US10381248B2 (en) 2015-06-22 2019-08-13 Lam Research Corporation Auto-correction of electrostatic chuck temperature non-uniformity
US10386821B2 (en) * 2015-06-22 2019-08-20 Lam Research Corporation Systems and methods for calibrating scalar field contribution values for a limited number of sensors including a temperature value of an electrostatic chuck and estimating temperature distribution profiles based on calibrated values
US11242598B2 (en) 2015-06-26 2022-02-08 Asm Ip Holding B.V. Structures including metal carbide material, devices including the structures, and methods of forming same
US11233133B2 (en) 2015-10-21 2022-01-25 Asm Ip Holding B.V. NbMC layers
CN106898567A (en) * 2015-12-17 2017-06-27 北京北方微电子基地设备工艺研究中心有限责任公司 A kind of transparent medium window, Substrate treatment chamber and substrate handling system
US11956977B2 (en) 2015-12-29 2024-04-09 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US11139308B2 (en) 2015-12-29 2021-10-05 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US11676812B2 (en) 2016-02-19 2023-06-13 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on top/bottom portions
US12240760B2 (en) 2016-03-18 2025-03-04 Asm Ip Holding B.V. Aligned carbon nanotubes
US10865475B2 (en) 2016-04-21 2020-12-15 Asm Ip Holding B.V. Deposition of metal borides and silicides
US10851456B2 (en) 2016-04-21 2020-12-01 Asm Ip Holding B.V. Deposition of metal borides
US11101370B2 (en) 2016-05-02 2021-08-24 Asm Ip Holding B.V. Method of forming a germanium oxynitride film
US10665452B2 (en) 2016-05-02 2020-05-26 Asm Ip Holdings B.V. Source/drain performance through conformal solid state doping
US11453943B2 (en) 2016-05-25 2022-09-27 Asm Ip Holding B.V. Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor
US11749562B2 (en) 2016-07-08 2023-09-05 Asm Ip Holding B.V. Selective deposition method to form air gaps
US11649546B2 (en) 2016-07-08 2023-05-16 Asm Ip Holding B.V. Organic reactants for atomic layer deposition
US11094582B2 (en) 2016-07-08 2021-08-17 Asm Ip Holding B.V. Selective deposition method to form air gaps
US10714385B2 (en) 2016-07-19 2020-07-14 Asm Ip Holding B.V. Selective deposition of tungsten
US11205585B2 (en) 2016-07-28 2021-12-21 Asm Ip Holding B.V. Substrate processing apparatus and method of operating the same
US11107676B2 (en) 2016-07-28 2021-08-31 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10741385B2 (en) 2016-07-28 2020-08-11 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11610775B2 (en) 2016-07-28 2023-03-21 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11694892B2 (en) 2016-07-28 2023-07-04 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10943771B2 (en) 2016-10-26 2021-03-09 Asm Ip Holding B.V. Methods for thermally calibrating reaction chambers
US11532757B2 (en) 2016-10-27 2022-12-20 Asm Ip Holding B.V. Deposition of charge trapping layers
US10714350B2 (en) 2016-11-01 2020-07-14 ASM IP Holdings, B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10720331B2 (en) 2016-11-01 2020-07-21 ASM IP Holdings, B.V. Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US11810788B2 (en) 2016-11-01 2023-11-07 Asm Ip Holding B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10934619B2 (en) 2016-11-15 2021-03-02 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including the gas supply unit
US11396702B2 (en) 2016-11-15 2022-07-26 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including the gas supply unit
US11222772B2 (en) 2016-12-14 2022-01-11 Asm Ip Holding B.V. Substrate processing apparatus
US11581186B2 (en) 2016-12-15 2023-02-14 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus
US12000042B2 (en) 2016-12-15 2024-06-04 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11970766B2 (en) 2016-12-15 2024-04-30 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus
US11447861B2 (en) 2016-12-15 2022-09-20 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11851755B2 (en) 2016-12-15 2023-12-26 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11001925B2 (en) 2016-12-19 2021-05-11 Asm Ip Holding B.V. Substrate processing apparatus
US10784102B2 (en) 2016-12-22 2020-09-22 Asm Ip Holding B.V. Method of forming a structure on a substrate
US11251035B2 (en) 2016-12-22 2022-02-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10867788B2 (en) 2016-12-28 2020-12-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US12043899B2 (en) 2017-01-10 2024-07-23 Asm Ip Holding B.V. Reactor system and method to reduce residue buildup during a film deposition process
US11390950B2 (en) 2017-01-10 2022-07-19 Asm Ip Holding B.V. Reactor system and method to reduce residue buildup during a film deposition process
US10655221B2 (en) 2017-02-09 2020-05-19 Asm Ip Holding B.V. Method for depositing oxide film by thermal ALD and PEALD
US11410851B2 (en) 2017-02-15 2022-08-09 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures
US12106965B2 (en) 2017-02-15 2024-10-01 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures
US11658030B2 (en) 2017-03-29 2023-05-23 Asm Ip Holding B.V. Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures
US10714335B2 (en) 2017-04-25 2020-07-14 Asm Ip Holding B.V. Method of depositing thin film and method of manufacturing semiconductor device
US10950432B2 (en) 2017-04-25 2021-03-16 Asm Ip Holding B.V. Method of depositing thin film and method of manufacturing semiconductor device
US10892156B2 (en) 2017-05-08 2021-01-12 Asm Ip Holding B.V. Methods for forming a silicon nitride film on a substrate and related semiconductor device structures
US11848200B2 (en) 2017-05-08 2023-12-19 Asm Ip Holding B.V. Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures
US12040200B2 (en) 2017-06-20 2024-07-16 Asm Ip Holding B.V. Semiconductor processing apparatus and methods for calibrating a semiconductor processing apparatus
US11306395B2 (en) * 2017-06-28 2022-04-19 Asm Ip Holding B.V. Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus
CN115613008A (en) * 2017-06-28 2023-01-17 Asm Ip控股有限公司 Method and associated deposition apparatus for depositing transition metal nitride films on substrates by atomic layer deposition
US11976361B2 (en) 2017-06-28 2024-05-07 Asm Ip Holding B.V. Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus
US10685834B2 (en) 2017-07-05 2020-06-16 Asm Ip Holdings B.V. Methods for forming a silicon germanium tin layer and related semiconductor device structures
US20190019697A1 (en) * 2017-07-14 2019-01-17 SCREEN Holdings Co., Ltd. Light irradiation type heat treatment apparatus
US11328941B2 (en) * 2017-07-14 2022-05-10 SCREEN Holdings Co., Ltd. Light irradiation type heat treatment apparatus
TWI672747B (en) * 2017-07-14 2019-09-21 日商斯庫林集團股份有限公司 Heat treatment apparatus
US10734497B2 (en) 2017-07-18 2020-08-04 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US11164955B2 (en) 2017-07-18 2021-11-02 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US11695054B2 (en) 2017-07-18 2023-07-04 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US11018002B2 (en) 2017-07-19 2021-05-25 Asm Ip Holding B.V. Method for selectively depositing a Group IV semiconductor and related semiconductor device structures
US11004977B2 (en) 2017-07-19 2021-05-11 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11374112B2 (en) 2017-07-19 2022-06-28 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US20190027384A1 (en) * 2017-07-20 2019-01-24 SCREEN Holdings Co., Ltd. Light irradiation type heat treatment apparatus
CN110998787A (en) * 2017-07-26 2020-04-10 硅电子股份公司 Epitaxially coated semiconductor wafer made of monocrystalline silicon and method for the production thereof
WO2019020387A1 (en) * 2017-07-26 2019-01-31 Siltronic Ag EPITACTICALLY COATED SEMICONDUCTOR SILICONE SEMICONDUCTOR DISC AND METHOD FOR THE PRODUCTION THEREOF
US11578424B2 (en) 2017-07-26 2023-02-14 Siltronic Ag Epitaxially coated semiconductor wafer of monocrystalline silicon and method for production thereof
US11802338B2 (en) 2017-07-26 2023-10-31 Asm Ip Holding B.V. Chemical treatment, deposition and/or infiltration apparatus and method for using the same
US12276023B2 (en) 2017-08-04 2025-04-15 Asm Ip Holding B.V. Showerhead assembly for distributing a gas within a reaction chamber
US10770336B2 (en) 2017-08-08 2020-09-08 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US10692741B2 (en) 2017-08-08 2020-06-23 Asm Ip Holdings B.V. Radiation shield
US11587821B2 (en) 2017-08-08 2023-02-21 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US11417545B2 (en) 2017-08-08 2022-08-16 Asm Ip Holding B.V. Radiation shield
US11139191B2 (en) 2017-08-09 2021-10-05 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US10672636B2 (en) 2017-08-09 2020-06-02 Asm Ip Holding B.V. Cassette holder assembly for a substrate cassette and holding member for use in such assembly
US11769682B2 (en) 2017-08-09 2023-09-26 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US11830730B2 (en) 2017-08-29 2023-11-28 Asm Ip Holding B.V. Layer forming method and apparatus
US11295980B2 (en) 2017-08-30 2022-04-05 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
US11581220B2 (en) 2017-08-30 2023-02-14 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
US11056344B2 (en) 2017-08-30 2021-07-06 Asm Ip Holding B.V. Layer forming method
US11069510B2 (en) 2017-08-30 2021-07-20 Asm Ip Holding B.V. Substrate processing apparatus
US11993843B2 (en) 2017-08-31 2024-05-28 Asm Ip Holding B.V. Substrate processing apparatus
US10928731B2 (en) 2017-09-21 2021-02-23 Asm Ip Holding B.V. Method of sequential infiltration synthesis treatment of infiltrateable material and structures and devices formed using same
US10844484B2 (en) 2017-09-22 2020-11-24 Asm Ip Holding B.V. Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US10658205B2 (en) 2017-09-28 2020-05-19 Asm Ip Holdings B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US11387120B2 (en) 2017-09-28 2022-07-12 Asm Ip Holding B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US11094546B2 (en) 2017-10-05 2021-08-17 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US12033861B2 (en) 2017-10-05 2024-07-09 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US10734223B2 (en) 2017-10-10 2020-08-04 Asm Ip Holding B.V. Method for depositing a metal chalcogenide on a substrate by cyclical deposition
US10923344B2 (en) 2017-10-30 2021-02-16 Asm Ip Holding B.V. Methods for forming a semiconductor structure and related semiconductor structures
US12040184B2 (en) 2017-10-30 2024-07-16 Asm Ip Holding B.V. Methods for forming a semiconductor structure and related semiconductor structures
US10910262B2 (en) 2017-11-16 2021-02-02 Asm Ip Holding B.V. Method of selectively depositing a capping layer structure on a semiconductor device structure
US10734244B2 (en) 2017-11-16 2020-08-04 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by the same
US11022879B2 (en) 2017-11-24 2021-06-01 Asm Ip Holding B.V. Method of forming an enhanced unexposed photoresist layer
US11682572B2 (en) 2017-11-27 2023-06-20 Asm Ip Holdings B.V. Storage device for storing wafer cassettes for use with a batch furnace
US11639811B2 (en) 2017-11-27 2023-05-02 Asm Ip Holding B.V. Apparatus including a clean mini environment
US11127617B2 (en) 2017-11-27 2021-09-21 Asm Ip Holding B.V. Storage device for storing wafer cassettes for use with a batch furnace
US10872771B2 (en) 2018-01-16 2020-12-22 Asm Ip Holding B. V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
US11501973B2 (en) 2018-01-16 2022-11-15 Asm Ip Holding B.V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
US11972944B2 (en) 2018-01-19 2024-04-30 Asm Ip Holding B.V. Method for depositing a gap-fill layer by plasma-assisted deposition
US11393690B2 (en) 2018-01-19 2022-07-19 Asm Ip Holding B.V. Deposition method
US12119228B2 (en) 2018-01-19 2024-10-15 Asm Ip Holding B.V. Deposition method
US11482412B2 (en) 2018-01-19 2022-10-25 Asm Ip Holding B.V. Method for depositing a gap-fill layer by plasma-assisted deposition
USD903477S1 (en) 2018-01-24 2020-12-01 Asm Ip Holdings B.V. Metal clamp
US11018047B2 (en) 2018-01-25 2021-05-25 Asm Ip Holding B.V. Hybrid lift pin
USD913980S1 (en) 2018-02-01 2021-03-23 Asm Ip Holding B.V. Gas supply plate for semiconductor manufacturing apparatus
US11735414B2 (en) 2018-02-06 2023-08-22 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US11081345B2 (en) 2018-02-06 2021-08-03 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US11387106B2 (en) 2018-02-14 2022-07-12 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US11685991B2 (en) 2018-02-14 2023-06-27 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US10896820B2 (en) 2018-02-14 2021-01-19 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US12173402B2 (en) 2018-02-15 2024-12-24 Asm Ip Holding B.V. Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus
US10731249B2 (en) 2018-02-15 2020-08-04 Asm Ip Holding B.V. Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus
US11482418B2 (en) 2018-02-20 2022-10-25 Asm Ip Holding B.V. Substrate processing method and apparatus
US10975470B2 (en) 2018-02-23 2021-04-13 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US11939673B2 (en) 2018-02-23 2024-03-26 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US11473195B2 (en) 2018-03-01 2022-10-18 Asm Ip Holding B.V. Semiconductor processing apparatus and a method for processing a substrate
US11629406B2 (en) 2018-03-09 2023-04-18 Asm Ip Holding B.V. Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate
US11114283B2 (en) 2018-03-16 2021-09-07 Asm Ip Holding B.V. Reactor, system including the reactor, and methods of manufacturing and using same
US12020938B2 (en) 2018-03-27 2024-06-25 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US10847371B2 (en) 2018-03-27 2020-11-24 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US11398382B2 (en) 2018-03-27 2022-07-26 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US11230766B2 (en) 2018-03-29 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11088002B2 (en) 2018-03-29 2021-08-10 Asm Ip Holding B.V. Substrate rack and a substrate processing system and method
US10867786B2 (en) 2018-03-30 2020-12-15 Asm Ip Holding B.V. Substrate processing method
US12230531B2 (en) 2018-04-09 2025-02-18 Asm Ip Holding B.V. Substrate supporting apparatus, substrate processing apparatus including the same, and substrate processing method
US12025484B2 (en) 2018-05-08 2024-07-02 Asm Ip Holding B.V. Thin film forming method
US11469098B2 (en) 2018-05-08 2022-10-11 Asm Ip Holding B.V. Methods for depositing an oxide film on a substrate by a cyclical deposition process and related device structures
US12272527B2 (en) 2018-05-09 2025-04-08 Asm Ip Holding B.V. Apparatus for use with hydrogen radicals and method of using same
US11056567B2 (en) 2018-05-11 2021-07-06 Asm Ip Holding B.V. Method of forming a doped metal carbide film on a substrate and related semiconductor device structures
US11908733B2 (en) 2018-05-28 2024-02-20 Asm Ip Holding B.V. Substrate processing method and device manufactured by using the same
US11361990B2 (en) 2018-05-28 2022-06-14 Asm Ip Holding B.V. Substrate processing method and device manufactured by using the same
US11718913B2 (en) 2018-06-04 2023-08-08 Asm Ip Holding B.V. Gas distribution system and reactor system including same
US11837483B2 (en) 2018-06-04 2023-12-05 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11270899B2 (en) 2018-06-04 2022-03-08 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11286562B2 (en) 2018-06-08 2022-03-29 Asm Ip Holding B.V. Gas-phase chemical reactor and method of using same
US10797133B2 (en) 2018-06-21 2020-10-06 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
US11530483B2 (en) 2018-06-21 2022-12-20 Asm Ip Holding B.V. Substrate processing system
US11296189B2 (en) 2018-06-21 2022-04-05 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
US11499222B2 (en) 2018-06-27 2022-11-15 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11492703B2 (en) 2018-06-27 2022-11-08 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11814715B2 (en) 2018-06-27 2023-11-14 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11952658B2 (en) 2018-06-27 2024-04-09 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11168395B2 (en) 2018-06-29 2021-11-09 Asm Ip Holding B.V. Temperature-controlled flange and reactor system including same
US10914004B2 (en) 2018-06-29 2021-02-09 Asm Ip Holding B.V. Thin-film deposition method and manufacturing method of semiconductor device
US10755923B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US11646197B2 (en) 2018-07-03 2023-05-09 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US11923190B2 (en) 2018-07-03 2024-03-05 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10755922B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10767789B2 (en) 2018-07-16 2020-09-08 Asm Ip Holding B.V. Diaphragm valves, valve components, and methods for forming valve components
US11053591B2 (en) 2018-08-06 2021-07-06 Asm Ip Holding B.V. Multi-port gas injection system and reactor system including same
US10883175B2 (en) 2018-08-09 2021-01-05 Asm Ip Holding B.V. Vertical furnace for processing substrates and a liner for use therein
US10829852B2 (en) 2018-08-16 2020-11-10 Asm Ip Holding B.V. Gas distribution device for a wafer processing apparatus
US11430674B2 (en) 2018-08-22 2022-08-30 Asm Ip Holding B.V. Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US11804388B2 (en) 2018-09-11 2023-10-31 Asm Ip Holding B.V. Substrate processing apparatus and method
US11274369B2 (en) 2018-09-11 2022-03-15 Asm Ip Holding B.V. Thin film deposition method
US11024523B2 (en) 2018-09-11 2021-06-01 Asm Ip Holding B.V. Substrate processing apparatus and method
US11049751B2 (en) 2018-09-14 2021-06-29 Asm Ip Holding B.V. Cassette supply system to store and handle cassettes and processing apparatus equipped therewith
US11885023B2 (en) 2018-10-01 2024-01-30 Asm Ip Holding B.V. Substrate retaining apparatus, system including the apparatus, and method of using same
US11232963B2 (en) 2018-10-03 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11414760B2 (en) 2018-10-08 2022-08-16 Asm Ip Holding B.V. Substrate support unit, thin film deposition apparatus including the same, and substrate processing apparatus including the same
US10847365B2 (en) 2018-10-11 2020-11-24 Asm Ip Holding B.V. Method of forming conformal silicon carbide film by cyclic CVD
US10811256B2 (en) 2018-10-16 2020-10-20 Asm Ip Holding B.V. Method for etching a carbon-containing feature
US11664199B2 (en) 2018-10-19 2023-05-30 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
US11251068B2 (en) 2018-10-19 2022-02-15 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
US20220144684A1 (en) * 2018-10-19 2022-05-12 Heraeus Noblelight Gmbh Jet system for jetting laminated glass panels of differing widths
USD948463S1 (en) 2018-10-24 2022-04-12 Asm Ip Holding B.V. Susceptor for semiconductor substrate supporting apparatus
US11087997B2 (en) 2018-10-31 2021-08-10 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11735445B2 (en) 2018-10-31 2023-08-22 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11499226B2 (en) 2018-11-02 2022-11-15 Asm Ip Holding B.V. Substrate supporting unit and a substrate processing device including the same
US11866823B2 (en) 2018-11-02 2024-01-09 Asm Ip Holding B.V. Substrate supporting unit and a substrate processing device including the same
US11572620B2 (en) 2018-11-06 2023-02-07 Asm Ip Holding B.V. Methods for selectively depositing an amorphous silicon film on a substrate
US11031242B2 (en) 2018-11-07 2021-06-08 Asm Ip Holding B.V. Methods for depositing a boron doped silicon germanium film
US11798999B2 (en) 2018-11-16 2023-10-24 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US10847366B2 (en) 2018-11-16 2020-11-24 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US11411088B2 (en) 2018-11-16 2022-08-09 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US10818758B2 (en) 2018-11-16 2020-10-27 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US11244825B2 (en) 2018-11-16 2022-02-08 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US12040199B2 (en) 2018-11-28 2024-07-16 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11217444B2 (en) 2018-11-30 2022-01-04 Asm Ip Holding B.V. Method for forming an ultraviolet radiation responsive metal oxide-containing film
US11488819B2 (en) 2018-12-04 2022-11-01 Asm Ip Holding B.V. Method of cleaning substrate processing apparatus
US11769670B2 (en) 2018-12-13 2023-09-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
US11158513B2 (en) 2018-12-13 2021-10-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
US11658029B2 (en) 2018-12-14 2023-05-23 Asm Ip Holding B.V. Method of forming a device structure using selective deposition of gallium nitride and system for same
US11959171B2 (en) 2019-01-17 2024-04-16 Asm Ip Holding B.V. Methods of forming a transition metal containing film on a substrate by a cyclical deposition process
US11390946B2 (en) 2019-01-17 2022-07-19 Asm Ip Holding B.V. Methods of forming a transition metal containing film on a substrate by a cyclical deposition process
US11171025B2 (en) 2019-01-22 2021-11-09 Asm Ip Holding B.V. Substrate processing device
US11127589B2 (en) 2019-02-01 2021-09-21 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11227789B2 (en) 2019-02-20 2022-01-18 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US12176243B2 (en) 2019-02-20 2024-12-24 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US11342216B2 (en) 2019-02-20 2022-05-24 Asm Ip Holding B.V. Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11251040B2 (en) 2019-02-20 2022-02-15 Asm Ip Holding B.V. Cyclical deposition method including treatment step and apparatus for same
US11798834B2 (en) 2019-02-20 2023-10-24 Asm Ip Holding B.V. Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11615980B2 (en) 2019-02-20 2023-03-28 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US11482533B2 (en) 2019-02-20 2022-10-25 Asm Ip Holding B.V. Apparatus and methods for plug fill deposition in 3-D NAND applications
US11629407B2 (en) 2019-02-22 2023-04-18 Asm Ip Holding B.V. Substrate processing apparatus and method for processing substrates
US11901175B2 (en) 2019-03-08 2024-02-13 Asm Ip Holding B.V. Method for selective deposition of silicon nitride layer and structure including selectively-deposited silicon nitride layer
US11114294B2 (en) 2019-03-08 2021-09-07 Asm Ip Holding B.V. Structure including SiOC layer and method of forming same
US11424119B2 (en) 2019-03-08 2022-08-23 Asm Ip Holding B.V. Method for selective deposition of silicon nitride layer and structure including selectively-deposited silicon nitride layer
US11742198B2 (en) 2019-03-08 2023-08-29 Asm Ip Holding B.V. Structure including SiOCN layer and method of forming same
US11378337B2 (en) 2019-03-28 2022-07-05 Asm Ip Holding B.V. Door opener and substrate processing apparatus provided therewith
US11551925B2 (en) 2019-04-01 2023-01-10 Asm Ip Holding B.V. Method for manufacturing a semiconductor device
US11447864B2 (en) 2019-04-19 2022-09-20 Asm Ip Holding B.V. Layer forming method and apparatus
US11814747B2 (en) 2019-04-24 2023-11-14 Asm Ip Holding B.V. Gas-phase reactor system-with a reaction chamber, a solid precursor source vessel, a gas distribution system, and a flange assembly
US11781221B2 (en) 2019-05-07 2023-10-10 Asm Ip Holding B.V. Chemical source vessel with dip tube
US11289326B2 (en) 2019-05-07 2022-03-29 Asm Ip Holding B.V. Method for reforming amorphous carbon polymer film
US11355338B2 (en) 2019-05-10 2022-06-07 Asm Ip Holding B.V. Method of depositing material onto a surface and structure formed according to the method
US11515188B2 (en) 2019-05-16 2022-11-29 Asm Ip Holding B.V. Wafer boat handling device, vertical batch furnace and method
US11996309B2 (en) 2019-05-16 2024-05-28 Asm Ip Holding B.V. Wafer boat handling device, vertical batch furnace and method
USD947913S1 (en) 2019-05-17 2022-04-05 Asm Ip Holding B.V. Susceptor shaft
USD975665S1 (en) 2019-05-17 2023-01-17 Asm Ip Holding B.V. Susceptor shaft
USD935572S1 (en) 2019-05-24 2021-11-09 Asm Ip Holding B.V. Gas channel plate
USD922229S1 (en) 2019-06-05 2021-06-15 Asm Ip Holding B.V. Device for controlling a temperature of a gas supply unit
US11345999B2 (en) 2019-06-06 2022-05-31 Asm Ip Holding B.V. Method of using a gas-phase reactor system including analyzing exhausted gas
US12195855B2 (en) 2019-06-06 2025-01-14 Asm Ip Holding B.V. Gas-phase reactor system including a gas detector
US11453946B2 (en) 2019-06-06 2022-09-27 Asm Ip Holding B.V. Gas-phase reactor system including a gas detector
US12252785B2 (en) 2019-06-10 2025-03-18 Asm Ip Holding B.V. Method for cleaning quartz epitaxial chambers
US11476109B2 (en) 2019-06-11 2022-10-18 Asm Ip Holding B.V. Method of forming an electronic structure using reforming gas, system for performing the method, and structure formed using the method
US11908684B2 (en) 2019-06-11 2024-02-20 Asm Ip Holding B.V. Method of forming an electronic structure using reforming gas, system for performing the method, and structure formed using the method
USD944946S1 (en) 2019-06-14 2022-03-01 Asm Ip Holding B.V. Shower plate
USD931978S1 (en) 2019-06-27 2021-09-28 Asm Ip Holding B.V. Showerhead vacuum transport
US11390945B2 (en) 2019-07-03 2022-07-19 Asm Ip Holding B.V. Temperature control assembly for substrate processing apparatus and method of using same
US11746414B2 (en) 2019-07-03 2023-09-05 Asm Ip Holding B.V. Temperature control assembly for substrate processing apparatus and method of using same
US11605528B2 (en) 2019-07-09 2023-03-14 Asm Ip Holding B.V. Plasma device using coaxial waveguide, and substrate treatment method
US12107000B2 (en) 2019-07-10 2024-10-01 Asm Ip Holding B.V. Substrate support assembly and substrate processing device including the same
US11664267B2 (en) 2019-07-10 2023-05-30 Asm Ip Holding B.V. Substrate support assembly and substrate processing device including the same
US11664245B2 (en) 2019-07-16 2023-05-30 Asm Ip Holding B.V. Substrate processing device
US11996304B2 (en) 2019-07-16 2024-05-28 Asm Ip Holding B.V. Substrate processing device
US11688603B2 (en) 2019-07-17 2023-06-27 Asm Ip Holding B.V. Methods of forming silicon germanium structures
US11615970B2 (en) 2019-07-17 2023-03-28 Asm Ip Holding B.V. Radical assist ignition plasma system and method
US12129548B2 (en) 2019-07-18 2024-10-29 Asm Ip Holding B.V. Method of forming structures using a neutral beam
US11643724B2 (en) 2019-07-18 2023-05-09 Asm Ip Holding B.V. Method of forming structures using a neutral beam
US11282698B2 (en) 2019-07-19 2022-03-22 Asm Ip Holding B.V. Method of forming topology-controlled amorphous carbon polymer film
US12112940B2 (en) 2019-07-19 2024-10-08 Asm Ip Holding B.V. Method of forming topology-controlled amorphous carbon polymer film
US11557474B2 (en) 2019-07-29 2023-01-17 Asm Ip Holding B.V. Methods for selective deposition utilizing n-type dopants and/or alternative dopants to achieve high dopant incorporation
US12169361B2 (en) 2019-07-30 2024-12-17 Asm Ip Holding B.V. Substrate processing apparatus and method
US11430640B2 (en) 2019-07-30 2022-08-30 Asm Ip Holding B.V. Substrate processing apparatus
US11443926B2 (en) 2019-07-30 2022-09-13 Asm Ip Holding B.V. Substrate processing apparatus
US11227782B2 (en) 2019-07-31 2022-01-18 Asm Ip Holding B.V. Vertical batch furnace assembly
US11876008B2 (en) 2019-07-31 2024-01-16 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587815B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587814B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11680839B2 (en) 2019-08-05 2023-06-20 Asm Ip Holding B.V. Liquid level sensor for a chemical source vessel
US12247286B2 (en) 2019-08-09 2025-03-11 Asm Ip Holding B.V. Heater assembly including cooling apparatus and method of using same
USD965044S1 (en) 2019-08-19 2022-09-27 Asm Ip Holding B.V. Susceptor shaft
USD965524S1 (en) 2019-08-19 2022-10-04 Asm Ip Holding B.V. Susceptor support
US11639548B2 (en) 2019-08-21 2023-05-02 Asm Ip Holding B.V. Film-forming material mixed-gas forming device and film forming device
USD930782S1 (en) 2019-08-22 2021-09-14 Asm Ip Holding B.V. Gas distributor
US12040229B2 (en) 2019-08-22 2024-07-16 Asm Ip Holding B.V. Method for forming a structure with a hole
USD979506S1 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Insulator
USD940837S1 (en) 2019-08-22 2022-01-11 Asm Ip Holding B.V. Electrode
US11594450B2 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Method for forming a structure with a hole
USD949319S1 (en) 2019-08-22 2022-04-19 Asm Ip Holding B.V. Exhaust duct
US12033849B2 (en) 2019-08-23 2024-07-09 Asm Ip Holding B.V. Method for depositing silicon oxide film having improved quality by PEALD using bis(diethylamino)silane
US11827978B2 (en) 2019-08-23 2023-11-28 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
US11527400B2 (en) 2019-08-23 2022-12-13 Asm Ip Holding B.V. Method for depositing silicon oxide film having improved quality by peald using bis(diethylamino)silane
US11898242B2 (en) 2019-08-23 2024-02-13 Asm Ip Holding B.V. Methods for forming a polycrystalline molybdenum film over a surface of a substrate and related structures including a polycrystalline molybdenum film
US11286558B2 (en) 2019-08-23 2022-03-29 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
US11495459B2 (en) 2019-09-04 2022-11-08 Asm Ip Holding B.V. Methods for selective deposition using a sacrificial capping layer
US11823876B2 (en) 2019-09-05 2023-11-21 Asm Ip Holding B.V. Substrate processing apparatus
US11562901B2 (en) 2019-09-25 2023-01-24 Asm Ip Holding B.V. Substrate processing method
US12230497B2 (en) 2019-10-02 2025-02-18 Asm Ip Holding B.V. Methods for forming a topographically selective silicon oxide film by a cyclical plasma-enhanced deposition process
US11610774B2 (en) 2019-10-02 2023-03-21 Asm Ip Holding B.V. Methods for forming a topographically selective silicon oxide film by a cyclical plasma-enhanced deposition process
US11339476B2 (en) 2019-10-08 2022-05-24 Asm Ip Holding B.V. Substrate processing device having connection plates, substrate processing method
US12006572B2 (en) 2019-10-08 2024-06-11 Asm Ip Holding B.V. Reactor system including a gas distribution assembly for use with activated species and method of using same
US11735422B2 (en) 2019-10-10 2023-08-22 Asm Ip Holding B.V. Method of forming a photoresist underlayer and structure including same
US12009241B2 (en) 2019-10-14 2024-06-11 Asm Ip Holding B.V. Vertical batch furnace assembly with detector to detect cassette
US11637011B2 (en) 2019-10-16 2023-04-25 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11637014B2 (en) 2019-10-17 2023-04-25 Asm Ip Holding B.V. Methods for selective deposition of doped semiconductor material
US11315794B2 (en) 2019-10-21 2022-04-26 Asm Ip Holding B.V. Apparatus and methods for selectively etching films
US11996292B2 (en) 2019-10-25 2024-05-28 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US11646205B2 (en) 2019-10-29 2023-05-09 Asm Ip Holding B.V. Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same
US12266695B2 (en) 2019-11-05 2025-04-01 Asm Ip Holding B.V. Structures with doped semiconductor layers and methods and systems for forming same
US11594600B2 (en) 2019-11-05 2023-02-28 Asm Ip Holding B.V. Structures with doped semiconductor layers and methods and systems for forming same
US11501968B2 (en) 2019-11-15 2022-11-15 Asm Ip Holding B.V. Method for providing a semiconductor device with silicon filled gaps
US11626316B2 (en) 2019-11-20 2023-04-11 Asm Ip Holding B.V. Method of depositing carbon-containing material on a surface of a substrate, structure formed using the method, and system for forming the structure
US11401605B2 (en) 2019-11-26 2022-08-02 Asm Ip Holding B.V. Substrate processing apparatus
US11915929B2 (en) 2019-11-26 2024-02-27 Asm Ip Holding B.V. Methods for selectively forming a target film on a substrate comprising a first dielectric surface and a second metallic surface
US11646184B2 (en) 2019-11-29 2023-05-09 Asm Ip Holding B.V. Substrate processing apparatus
US11923181B2 (en) 2019-11-29 2024-03-05 Asm Ip Holding B.V. Substrate processing apparatus for minimizing the effect of a filling gas during substrate processing
US11929251B2 (en) 2019-12-02 2024-03-12 Asm Ip Holding B.V. Substrate processing apparatus having electrostatic chuck and substrate processing method
US11840761B2 (en) 2019-12-04 2023-12-12 Asm Ip Holding B.V. Substrate processing apparatus
US11885013B2 (en) 2019-12-17 2024-01-30 Asm Ip Holding B.V. Method of forming vanadium nitride layer and structure including the vanadium nitride layer
US12119220B2 (en) 2019-12-19 2024-10-15 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US11527403B2 (en) 2019-12-19 2022-12-13 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US12033885B2 (en) 2020-01-06 2024-07-09 Asm Ip Holding B.V. Channeled lift pin
US11976359B2 (en) 2020-01-06 2024-05-07 Asm Ip Holding B.V. Gas supply assembly, components thereof, and reactor system including same
US11993847B2 (en) 2020-01-08 2024-05-28 Asm Ip Holding B.V. Injector
US12125700B2 (en) 2020-01-16 2024-10-22 Asm Ip Holding B.V. Method of forming high aspect ratio features
US11551912B2 (en) 2020-01-20 2023-01-10 Asm Ip Holding B.V. Method of forming thin film and method of modifying surface of thin film
US11521851B2 (en) 2020-02-03 2022-12-06 Asm Ip Holding B.V. Method of forming structures including a vanadium or indium layer
US11828707B2 (en) 2020-02-04 2023-11-28 Asm Ip Holding B.V. Method and apparatus for transmittance measurements of large articles
US11776846B2 (en) 2020-02-07 2023-10-03 Asm Ip Holding B.V. Methods for depositing gap filling fluids and related systems and devices
US12218269B2 (en) 2020-02-13 2025-02-04 Asm Ip Holding B.V. Substrate processing apparatus including light receiving device and calibration method of light receiving device
US11781243B2 (en) 2020-02-17 2023-10-10 Asm Ip Holding B.V. Method for depositing low temperature phosphorous-doped silicon
US11986868B2 (en) 2020-02-28 2024-05-21 Asm Ip Holding B.V. System dedicated for parts cleaning
US12278129B2 (en) 2020-03-04 2025-04-15 Asm Ip Holding B.V. Alignment fixture for a reactor system
US11488854B2 (en) 2020-03-11 2022-11-01 Asm Ip Holding B.V. Substrate handling device with adjustable joints
US11837494B2 (en) 2020-03-11 2023-12-05 Asm Ip Holding B.V. Substrate handling device with adjustable joints
US11876356B2 (en) 2020-03-11 2024-01-16 Asm Ip Holding B.V. Lockout tagout assembly and system and method of using same
US11961741B2 (en) 2020-03-12 2024-04-16 Asm Ip Holding B.V. Method for fabricating layer structure having target topological profile
US12173404B2 (en) 2020-03-17 2024-12-24 Asm Ip Holding B.V. Method of depositing epitaxial material, structure formed using the method, and system for performing the method
US11823866B2 (en) 2020-04-02 2023-11-21 Asm Ip Holding B.V. Thin film forming method
US11830738B2 (en) 2020-04-03 2023-11-28 Asm Ip Holding B.V. Method for forming barrier layer and method for manufacturing semiconductor device
US11437241B2 (en) 2020-04-08 2022-09-06 Asm Ip Holding B.V. Apparatus and methods for selectively etching silicon oxide films
US12087586B2 (en) 2020-04-15 2024-09-10 Asm Ip Holding B.V. Method of forming chromium nitride layer and structure including the chromium nitride layer
US11821078B2 (en) 2020-04-15 2023-11-21 Asm Ip Holding B.V. Method for forming precoat film and method for forming silicon-containing film
US11996289B2 (en) 2020-04-16 2024-05-28 Asm Ip Holding B.V. Methods of forming structures including silicon germanium and silicon layers, devices formed using the methods, and systems for performing the methods
US12243742B2 (en) 2020-04-21 2025-03-04 Asm Ip Holding B.V. Method for processing a substrate
US12221357B2 (en) 2020-04-24 2025-02-11 Asm Ip Holding B.V. Methods and apparatus for stabilizing vanadium compounds
US12243747B2 (en) 2020-04-24 2025-03-04 Asm Ip Holding B.V. Methods of forming structures including vanadium boride and vanadium phosphide layers
US11530876B2 (en) 2020-04-24 2022-12-20 Asm Ip Holding B.V. Vertical batch furnace assembly comprising a cooling gas supply
US12130084B2 (en) 2020-04-24 2024-10-29 Asm Ip Holding B.V. Vertical batch furnace assembly comprising a cooling gas supply
US11887857B2 (en) 2020-04-24 2024-01-30 Asm Ip Holding B.V. Methods and systems for depositing a layer comprising vanadium, nitrogen, and a further element
US11898243B2 (en) 2020-04-24 2024-02-13 Asm Ip Holding B.V. Method of forming vanadium nitride-containing layer
US11959168B2 (en) 2020-04-29 2024-04-16 Asm Ip Holding B.V. Solid source precursor vessel
US11798830B2 (en) 2020-05-01 2023-10-24 Asm Ip Holding B.V. Fast FOUP swapping with a FOUP handler
US11515187B2 (en) 2020-05-01 2022-11-29 Asm Ip Holding B.V. Fast FOUP swapping with a FOUP handler
US12051602B2 (en) 2020-05-04 2024-07-30 Asm Ip Holding B.V. Substrate processing system for processing substrates with an electronics module located behind a door in a front wall of the substrate processing system
US11626308B2 (en) 2020-05-13 2023-04-11 Asm Ip Holding B.V. Laser alignment fixture for a reactor system
US12057314B2 (en) 2020-05-15 2024-08-06 Asm Ip Holding B.V. Methods for silicon germanium uniformity control using multiple precursors
US11804364B2 (en) 2020-05-19 2023-10-31 Asm Ip Holding B.V. Substrate processing apparatus
US11705333B2 (en) 2020-05-21 2023-07-18 Asm Ip Holding B.V. Structures including multiple carbon layers and methods of forming and using same
US12243757B2 (en) 2020-05-21 2025-03-04 Asm Ip Holding B.V. Flange and apparatus for processing substrates
US11987881B2 (en) 2020-05-22 2024-05-21 Asm Ip Holding B.V. Apparatus for depositing thin films using hydrogen peroxide
US11767589B2 (en) 2020-05-29 2023-09-26 Asm Ip Holding B.V. Substrate processing device
US12106944B2 (en) 2020-06-02 2024-10-01 Asm Ip Holding B.V. Rotating substrate support
US12266524B2 (en) 2020-06-16 2025-04-01 Asm Ip Holding B.V. Method for depositing boron containing silicon germanium layers
US11646204B2 (en) 2020-06-24 2023-05-09 Asm Ip Holding B.V. Method for forming a layer provided with silicon
US11658035B2 (en) 2020-06-30 2023-05-23 Asm Ip Holding B.V. Substrate processing method
US12020934B2 (en) 2020-07-08 2024-06-25 Asm Ip Holding B.V. Substrate processing method
US12055863B2 (en) 2020-07-17 2024-08-06 Asm Ip Holding B.V. Structures and methods for use in photolithography
US11644758B2 (en) 2020-07-17 2023-05-09 Asm Ip Holding B.V. Structures and methods for use in photolithography
US12241158B2 (en) 2020-07-20 2025-03-04 Asm Ip Holding B.V. Method for forming structures including transition metal layers
US11674220B2 (en) 2020-07-20 2023-06-13 Asm Ip Holding B.V. Method for depositing molybdenum layers using an underlayer
US12154824B2 (en) 2020-08-14 2024-11-26 Asm Ip Holding B.V. Substrate processing method
US12040177B2 (en) 2020-08-18 2024-07-16 Asm Ip Holding B.V. Methods for forming a laminate film by cyclical plasma-enhanced deposition processes
US12217954B2 (en) 2020-08-25 2025-02-04 Asm Ip Holding B.V. Method of cleaning a surface
US11725280B2 (en) 2020-08-26 2023-08-15 Asm Ip Holding B.V. Method for forming metal silicon oxide and metal silicon oxynitride layers
US12074022B2 (en) 2020-08-27 2024-08-27 Asm Ip Holding B.V. Method and system for forming patterned structures using multiple patterning process
US12211742B2 (en) 2020-09-10 2025-01-28 Asm Ip Holding B.V. Methods for depositing gap filling fluid
USD990534S1 (en) 2020-09-11 2023-06-27 Asm Ip Holding B.V. Weighted lift pin
US12148609B2 (en) 2020-09-16 2024-11-19 Asm Ip Holding B.V. Silicon oxide deposition method
USD1012873S1 (en) 2020-09-24 2024-01-30 Asm Ip Holding B.V. Electrode for semiconductor processing apparatus
US12218000B2 (en) 2020-09-25 2025-02-04 Asm Ip Holding B.V. Semiconductor processing method
US12009224B2 (en) 2020-09-29 2024-06-11 Asm Ip Holding B.V. Apparatus and method for etching metal nitrides
US12107005B2 (en) 2020-10-06 2024-10-01 Asm Ip Holding B.V. Deposition method and an apparatus for depositing a silicon-containing material
US12051567B2 (en) 2020-10-07 2024-07-30 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including gas supply unit
US11827981B2 (en) 2020-10-14 2023-11-28 Asm Ip Holding B.V. Method of depositing material on stepped structure
US12217946B2 (en) 2020-10-15 2025-02-04 Asm Ip Holding B.V. Method of manufacturing semiconductor device, and substrate treatment apparatus using ether-CAT
US11873557B2 (en) 2020-10-22 2024-01-16 Asm Ip Holding B.V. Method of depositing vanadium metal
US11901179B2 (en) 2020-10-28 2024-02-13 Asm Ip Holding B.V. Method and device for depositing silicon onto substrates
US12209308B2 (en) 2020-11-12 2025-01-28 Asm Ip Holding B.V. Reactor and related methods
US12195852B2 (en) 2020-11-23 2025-01-14 Asm Ip Holding B.V. Substrate processing apparatus with an injector
US12027365B2 (en) 2020-11-24 2024-07-02 Asm Ip Holding B.V. Methods for filling a gap and related systems and devices
US11891696B2 (en) 2020-11-30 2024-02-06 Asm Ip Holding B.V. Injector configured for arrangement within a reaction chamber of a substrate processing apparatus
US12255053B2 (en) 2020-12-10 2025-03-18 Asm Ip Holding B.V. Methods and systems for depositing a layer
US12159788B2 (en) 2020-12-14 2024-12-03 Asm Ip Holding B.V. Method of forming structures for threshold voltage control
US11946137B2 (en) 2020-12-16 2024-04-02 Asm Ip Holding B.V. Runout and wobble measurement fixtures
US12288710B2 (en) 2020-12-18 2025-04-29 Asm Ip Holding B.V. Wafer processing apparatus with a rotatable table
US11885020B2 (en) 2020-12-22 2024-01-30 Asm Ip Holding B.V. Transition metal deposition method
US12131885B2 (en) 2020-12-22 2024-10-29 Asm Ip Holding B.V. Plasma treatment device having matching box
US12129545B2 (en) 2020-12-22 2024-10-29 Asm Ip Holding B.V. Precursor capsule, a vessel and a method
USD1023959S1 (en) 2021-05-11 2024-04-23 Asm Ip Holding B.V. Electrode for substrate processing apparatus
USD981973S1 (en) 2021-05-11 2023-03-28 Asm Ip Holding B.V. Reactor wall for substrate processing apparatus
USD980813S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas flow control plate for substrate processing apparatus
USD980814S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas distributor for substrate processing apparatus
USD990441S1 (en) 2021-09-07 2023-06-27 Asm Ip Holding B.V. Gas flow control plate
US20230132307A1 (en) * 2021-10-26 2023-04-27 Applied Materials, Inc. Chuck For Processing Semiconductor Workpieces At High Temperatures
US12046503B2 (en) * 2021-10-26 2024-07-23 Applied Materials, Inc. Chuck for processing semiconductor workpieces at high temperatures
USD1060598S1 (en) 2021-12-03 2025-02-04 Asm Ip Holding B.V. Split showerhead cover
CN114230390A (en) * 2021-12-13 2022-03-25 塔里木大学 A device for accelerating decomposing of orchard green manure and its overturning mechanism
TWI832555B (en) * 2021-12-29 2024-02-11 大陸商上海陛通半導體能源科技股份有限公司 Multifunctional wafer pretreatment chamber and chemical vapor deposition equipment

Also Published As

Publication number Publication date
US6437290B1 (en) 2002-08-20

Similar Documents

Publication Publication Date Title
US6437290B1 (en) Heat treatment apparatus having a thin light-transmitting window
US6860634B2 (en) Temperature measuring method, heat treating device and method, computer program, and radiation thermometer
US6876816B2 (en) Heating device, heat treatment apparatus having the heating device and method for controlling heat treatment
US6825615B2 (en) Lamp having a high-reflectance film for improving directivity of light and heat treatment apparatus having such a lamp
US7323661B2 (en) Heat treatment apparatus using a lamp for rapidly and uniformly heating a wafer
US6435869B2 (en) Quartz window having reinforcing ribs
JP2001308023A (en) Heat treatment apparatus and method
TWI575635B (en) Apparatus and methods for rapid thermal processing
US6566630B2 (en) Thermal processing apparatus for introducing gas between a target object and a cooling unit for cooling the target object
KR20080058488A (en) Heating device, heat treatment device, computer program and storage medium
KR100970013B1 (en) Heat treatment device
JP4346208B2 (en) Temperature measuring method, heat treatment apparatus and method, and computer-readable medium
JP4828031B2 (en) Lamp, heat treatment equipment using lamp
JP4905907B2 (en) Lamp and heat treatment apparatus
JP4666427B2 (en) Quartz window and heat treatment equipment
JP2002261038A (en) Heat treatment device
JP2002198319A (en) Heat treatment apparatus
JP2002357481A (en) Temperature measuring method and apparatus, heat treatment apparatus and heat treatment method
JP4646354B2 (en) Heat treatment apparatus and method
JP2012032401A (en) Temperature measurement method and apparatus, and heat treatment apparatus and heat treatment method
TW202405982A (en) Radiative heat windows and wafer support pads in vapor etch reactors
WO1995028002A1 (en) Method and device for processing semiconductor wafer

Legal Events

Date Code Title Description
AS Assignment

Owner name: TOKYO ELECTRON LIMITED, JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SHAO, SHOUGIAN;LI, YICHENG;SHIGEOKA, TAKASHI;AND OTHERS;REEL/FRAME:012342/0755

Effective date: 20010917

FEPP Fee payment procedure

Free format text: PAYER NUMBER DE-ASSIGNED (ORIGINAL EVENT CODE: RMPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

REMI Maintenance fee reminder mailed
LAPS Lapse for failure to pay maintenance fees
STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20140820

点击 这是indexloc提供的php浏览器服务,不要输入任何密码和下载