US20020004294A1 - Dopant diffusion-retarding barrier region formed within polysilicon gate layer - Google Patents
Dopant diffusion-retarding barrier region formed within polysilicon gate layer Download PDFInfo
- Publication number
- US20020004294A1 US20020004294A1 US09/177,043 US17704398A US2002004294A1 US 20020004294 A1 US20020004294 A1 US 20020004294A1 US 17704398 A US17704398 A US 17704398A US 2002004294 A1 US2002004294 A1 US 2002004294A1
- Authority
- US
- United States
- Prior art keywords
- nitrogen
- barrier region
- polysilicon
- layer
- dopant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910021420 polycrystalline silicon Inorganic materials 0.000 title claims abstract description 101
- 229920005591 polysilicon Polymers 0.000 title claims abstract description 99
- 230000004888 barrier function Effects 0.000 title claims abstract description 69
- 239000002019 doping agent Substances 0.000 title claims abstract description 55
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 35
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052796 boron Inorganic materials 0.000 claims abstract description 31
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 17
- 238000009792 diffusion process Methods 0.000 claims abstract description 15
- 238000000137 annealing Methods 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 42
- 239000000463 material Substances 0.000 claims description 18
- 239000004065 semiconductor Substances 0.000 claims description 15
- 230000005669 field effect Effects 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000007772 electrode material Substances 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 238000000151 deposition Methods 0.000 abstract description 8
- 239000003989 dielectric material Substances 0.000 abstract description 6
- 229910052581 Si3N4 Inorganic materials 0.000 abstract description 4
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 abstract description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000979 retarding effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 59
- 239000000758 substrate Substances 0.000 description 19
- 239000007943 implant Substances 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 125000004429 atom Chemical group 0.000 description 10
- 230000008569 process Effects 0.000 description 9
- 229920002120 photoresistant polymer Polymers 0.000 description 8
- 125000006850 spacer group Chemical group 0.000 description 7
- 238000012545 processing Methods 0.000 description 6
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000005468 ion implantation Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/661—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation
- H10D64/662—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation the conductor further comprising additional layers, e.g. multiple silicon layers having different crystal structures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3215—Doping the layers
- H01L21/32155—Doping polycristalline - or amorphous silicon layers
Definitions
- the present invention is related to the manufacture of insulated gate field effect transistors, and more particularly to the structure and doping of gate electrode structures therein.
- An insulated-gate field-effect transistor such as a metal-oxide semiconductor field-effect transistor (MOSFET) uses a gate electrode to control an underlying surface channel joining a source and a drain.
- the channel, drain and source are located in a semiconductor substrate, with the channel being doped oppositely to the drain and source.
- the gate electrode is separated from the semiconductor substrate by a thin insulating layer (i.e., a gate dielectric layer) such as an oxide.
- the operation of the IGFET involves application of an input voltage to the gate electrode, which sets up a transverse electric field in the channel in order to modulate the longitudinal conductance of the channel.
- the source and drain are formed by introducing dopants of a second conductivity type (P or N) into the semiconductor substrate of a first conductivity type (N or P) using a patterned gate electrode as a mask.
- This self-aligning procedure tends to improve packing density and reduce parasitic overlap capacitances between the gate electrode and the source/drain regions.
- Polysilicon also called polycrystalline silicon, poly-Si, or just “poly” thin films are typically used as the gate electrode. Since polysilicon has the same high melting point as a silicon substrate, it can be deposited prior to source and drain formation.
- the polysilicon is anisotropically etched through openings in a photoresist mask to provide a gate electrode which forms a mask during formation of the source and drain by ion implantation.
- Photolithography is used to create patterns in the photoresist mask that define the gate electrode.
- the gate electrode is typically doped by the same type of ion implantation as are the source and drain.
- boron is frequently implanted to form the source and drain in a P-channel IGFET, and the boron is also implanted into the gate electrode of the IGFET to create a P-type polysilicon gate electrode.
- boron is such a “light” atom (i.e., low atomic mass)
- boron implanted into the polysilicon gate electrode can easily diffuse along the grain boundaries of the polysilicon and into the gate oxide, and may diffuse ultimately into the underlying channel region.
- the presence of boron in the channel affects the device parameters of the IGFET, especially the threshold voltage, and the presence of boron in the gate oxide can affect the reliability of the IGFET. Both effects are tremendously undesirable.
- the present invention improves upon the previous techniques for retarding dopant diffusion into the gate dielectric by incorporating a diffusion barrier region within a layer of polysilicon.
- the barrier region is a nitrogen-containing, diffusion-retarding barrier region.
- the portion of the polysilicon layer above the barrier region is doped more heavily than the portion below, and the barrier region serves to keep most of the dopant within the upper portion.
- the barrier region nevertheless allows some of the dopant to diffuse into the lower portion, which ensures that the polysilicon layer forms a gate electrode which is a single contiguous electrical node rather than an insulating portion due to polysilicon depletion effects.
- the barrier region is formed by implanting a nitrogen-containing material, such as elemental nitrogen or molecular nitrogen, so that a region is formed within the polysilicon layer.
- a nitrogen-containing material such as elemental nitrogen or molecular nitrogen
- the thickness of the nitrogen-containing region may be chosen for its ability to conduct current therethrough while retaining its ability to retard dopant diffusion, and may be chosen to be approximately 5-15 ⁇ thick.
- any nitrogen residing at the top of the gate dielectric may be kept to a concentration less than approximately 2%.
- the dopant concentration at the first polysilicon layer bottom surface may exceed approximately 1 ⁇ 10 21 atoms/cm 3 .
- the present invention is particularly well suited to thin gate dielectrics, such as a those having a thickness less than approximately 60 ⁇ when using a p-type dopant, such as B, BF 2 , and other similar compounds of boron and flourine (e.g., BF x ).
- a method of fabricating a gate electrode structure for an insulated gate field effect transistor includes the steps of: (1) forming a polysilicon layer on an underlying gate dielectric layer, the polysilicon layer having top and bottom surfaces, the bottom surface forming an interface with said gate dielectric layer; (2) implanting a nitrogen-containing material to form a nitrogen-containing diffusion-retarding barrier region within the polysilicon layer; (3) introducing a dopant into at least a portion of the polysilicon layer disposed between the barrier region and the top surface, resulting in a greater dopant concentration immediately above the barrier region than immediately below; and (4) removing regions of the polysilicon layer to form a gate electrode for the IGFET.
- the method includes the additional step of implanting a nitrogen-containing material to form a second nitrogen-containing diffusion-retarding barrier region above and spaced apart from the first nitrogen-containing diffusion-retarding barrier region.
- a semiconductor gate electrode structure for an insulated gate field effect transistor includes: (1) a polysilicon layer formed on an underlying gate dielectric layer, the polysilicon layer having respective top and bottom surfaces, the bottom surface forming an interface with said gate dielectric layer; (2) a first nitrogen-containing diffusion-retarding barrier region formed within the polysilicon layer; and (3) a dopant within the polysilicon layer having a greater dopant concentration immediately above the diffusion barrier region than immediately below.
- FIGS. 1 A- 1 D are cross-sectional views illustrating a semiconductor process flow in accordance with the present invention.
- FIG. 2 is a cross-sectional view illustrating a doping profile associated with the process flow depicted in FIGS. 1 A- 1 D.
- FIG. 3 is a cross-sectional view of a structure incorporating two barrier regions in accordance with another embodiment of the present invention.
- FIGS. 1 A- 1 D show cross-sectional views of successive process steps for forming a gate electrode in accordance with a first embodiment of the present invention.
- a layer of polysilicon 104 is shown disposed upon a gate dielectric 102 , which in turn is disposed on a semiconductor substrate 100 suitable for integrated circuit manufacture.
- substrate 100 includes a phosphorus-doped N-well formed in a P-type planar epitaxial surface layer (not shown) with a ⁇ 100> orientation and a resistivity of 12 ohm-cm.
- the epitaxial surface layer is disposed on a P+ base layer (not shown).
- a blanket layer of gate dielectric 102 (e.g., silicon dioxide, silicon oxynitride, nitrided silicon dioxide, etc.) is formed on the top surface of substrate 100 preferably using tube growth at a temperature of 700-1,000° C. in an O 2 containing ambient.
- Gate dielectric 102 has a preferred thickness in the range of 25 to 200 A.
- a first layer of polysilicon 104 preferably is deposited by low pressure chemical vapor deposition (LPCVD) on the top surface of the gate dielectric 102 .
- Polysilicon 104 is deposited undoped and has a preferred thickness in the range of 100-300 A.
- a nitrogen implant 105 is performed to create a nitrogen barrier region 106 within the polysilicon 104 .
- elemental nitrogen (N) may be implanted using an energy of 5-30 keV and at a dose of 5 ⁇ 10 14 -5 ⁇ 10 15 atoms/cm 2 .
- molecular nitrogen (N 2 ) may also be implanted using an energy of 10-60 keV and at a dose of 5 ⁇ 10 14 -5 ⁇ 10 15 atoms/cm 2 .
- An anneal may optionally follow the nitrogen implant. Such an anneal may be performed using a rapid thermal processing (RTP) step, using a tube anneal, or other similar methods.
- RTP rapid thermal processing
- an RTP anneal may be performed for a time in the range of 10-60 seconds at a temperature in the range of 900-1050° C.
- the resulting structure is shown in FIG. 1B.
- An upper portion 108 of polysilicon layer 104 is shown disposed between the barrier region 106 and the top surface of the polysilicon 104 .
- a lower portion 107 of polysilicon layer 104 is shown disposed between the barrier region 106 and the bottom surface of the polysilicon 104 (at the interface with the gate dielectric 102 ).
- the polysilicon 104 is formed with a thickness in the range of 300-2500 A.
- a photoresist layer (not shown) is next applied and a gate mask used to image the gate electrode features into the photoresist.
- the polysilicon region 108 , barrier region 106 , and polysilicon region 107 are then anisotropically etched to define a gate electrode 120 .
- a light dose of a first dopant e.g., boron
- the first dopant is also implanted into the gate electrode 120 wherein the polysilicon 108 is lightly doped.
- the structure is subjected to ion implantation of boron at a dose in the range of 5 ⁇ 10 13 to 1 ⁇ 10 14 atoms/cm 2 and an energy in the range of 2 to 80 kiloelectron-volts.
- the lightly doped source region 110 and the lightly doped drain region 112 are formed at and below the surface of substrate 100 .
- Lightly doped source and drain regions 110 , 112 are doped P- with a dopant concentration in the range of about 5 ⁇ 10 17 to 5 ⁇ 10 18 atoms/cm 3 , and a junction depth in the range of 0.01 to 0.15 ⁇
- Spacers 114 , 116 are then formed at the edges of the gate electrode 120 .
- the resulting structure is shown in FIG. 1C, which shows spacers 114 , 116 formed adjacent to the gate electrode 120 , and shows lightly-doped source region 110 and lightly-doped drain region 112 formed within the substrate 100 .
- a boron implant 118 is next performed to form P+ regions in both source and drain regions.
- the resulting structure is shown in FIG. 1D, which shows P+ source region 122 and P+ drain region 124 formed within the substrate 100 and outward of the spacers 114 , 116 , as is well known in the art.
- the boron implant 118 may be performed at a dose in the range of 2.0 ⁇ 10 15 to 8.0 ⁇ 10 15 atoms/cm 2 and an energy in the range of 2 to 20 kiloelectron-volts.
- the heavily doped source region 122 and the heavily doped drain region 124 are formed at and below the surface of substrate 100 .
- Heavily doped source and drain regions 122 , 124 are doped P+ with a dopant concentration in the range of about 5 ⁇ 10 19 to 5 ⁇ 10 20 atoms/cm 3 , and a junction depth in the range of 0.01 to 0.1 ⁇ .
- the presence of spacers 114 , 116 and the gate electrode 120 serve to prevent the boron implant from reaching the channel 101 underlying the gate electrode 120 and from reaching the lightly doped source and drain regions 110 , 112 .
- Further processing steps in the fabrication of IGFETs typically include forming a thick oxide layer over the active regions, forming contact windows in the oxide layer above the drain, source and gate electrode, forming appropriate interconnect metallization in the contact windows, and forming a passivation layer. These further processing steps are conventional and need not be repeated herein. Likewise the principal processing steps disclosed herein may be combined with other steps readily apparent to those skilled in the art.
- the preferred doping profile within the gate electrode 120 as a result of the boron implant 118 is shown in FIG. 2.
- the bulk of the dopant is implanted into the polysilicon region 108 , which is above the barrier region 106 . Only a small amount of the dopant is preferably implanted into the region of the barrier region 106 or into the polysilicon region 107 layer below the barrier region 106 .
- the barrier region 106 retards the downward diffusion of the boron and helps prevent boron from reaching the gate dielectric 102 /polysilicon 104 interface.
- the dopant profile may exist entirely within the upper layer of polysilicon 108 . In either case, the barrier region 106 retards the downward diffusion of dopant toward the gate dielectric 102 and toward the channel region 101 .
- the barrier region 106 may be formed by depositing a nitrogen-containing layer, such as silicon nitride or titanium nitride, onto the top surface of polysilicon 104 .
- a nitrogen-containing layer such as silicon nitride or titanium nitride
- Suitable conditions for depositing a layer of silicon nitride are low pressure chemical vapor deposition (LPCVD), plasma deposition and deposition by sputtering.
- Suitable conditions for depositing a layer of titanium nitride are low pressure chemical vapor deposition, plasma deposition and deposition by sputtering.
- Such a layer of titanium nitride is electrically conductive and thus helps ensure a good electrical connection between polysilicon region 107 and polysilicon region 108 .
- FIG. 3 is a cross-sectional view of a multi-layer structure incorporating three polysilicon layers, with a separate barrier region between each adjacent pair of polysilicon layers.
- a blanket layer of gate dielectric 102 e.g., silicon dioxide, silicon oxynitride, nitrided silicon dioxide, etc.
- gate dielectric 102 e.g., silicon dioxide, silicon oxynitride, nitrided silicon dioxide, etc.
- a first layer of polysilicon region 107 is deposited on the top surface of the gate dielectric 102 .
- Polysilicon region 107 is deposited undoped and has a preferred thickness in the range of 100-300 ⁇ .
- a first nitrogen anneal is performed to create a nitrogen barrier region 106 on the top surface of the polysilicon region 107 .
- a second layer of polysilicon 108 is then deposited on the top surface of the barrier region 106 , preferably to a thickness of 100-300 ⁇ .
- a second nitrogen anneal is performed to create a second nitrogen barrier region 130 on the top surface of the polysilicon 108 .
- a third layer of polysilicon 132 is then deposited on the top surface of the barrier region 130 , preferably to a thickness of 300-2500 ⁇ .
- a photoresist layer (not shown) is next applied and a gate mask used to image the gate electrode features into the photoresist.
- the polysilicon region 132 , barrier region 130 , polysilicon region 108 , barrier region 106 , and polysilicon region 107 are then anisotropically etched to define a gate electrode (not shown).
- LDD regions, spacers, and source/drain regions are formed in a manner similar to that described before. Specifically, a light dose of a first dopant (e.g., boron) is then implanted into the semiconductor substrate 100 to provide a lightly doped source and drain regions (i.e., LDD regions, not shown).
- a first dopant e.g., boron
- This first dopant is also implanted into the undoped polysilicon region 132 , possibly also into the undoped polysilicon 108 , and possibly into the undoped polysilicon region 107 , wherein each is lightly doped.
- the structure is subjected to ion implantation of boron at a dose in the range of 5 ⁇ 10 13 to 1 ⁇ 10 14 atoms/cm 2 and an energy in the range of 2 to 80 kiloelectron-volts. Spacers are then formed at the edges of the gate electrode as before, followed by a boron implant (not shown) to form P+ regions in both source and drain regions, as before.
- Such a multi-layer structure has several additional potential advantages. If, for example, the heavy boron implant is targeted to achieve an implant depth residing within the polysilicon 132 , then the barrier region 130 retards some amount of dopant diffusion into the middle polysilicon 108 , while the lower barrier region 106 additionally retards the diffusion of dopant already within the polysilicon 108 from reaching the lower layer of polysilicon region 107 . In other words, the presence of two barrier regions 130 , 106 allows a heavy dopant density within the upper layer of polysilicon 132 but yet reduces the amount of dopant reaching the lower layer of polysilicon 107 , and especially reduces the amount of dopant which reaches the polysilicon 107 /gate dielectric 102 interface.
- each barrier region thin enough to allow some amount of dopant diffusion sufficient to “dope” the polysilicon 108 and polysilicon 107 enough to prevent undesirable polysilicon depletion effects which otherwise result when the polysilicon near the gate dielectric interface remains undoped.
- the barrier regions may be produced at a sufficient thickness to substantially prevent implanted dopant from diffusing through the barrier regions.
- a dopant may be implanted into a particular polysilicon layer (e.g., polysilicon 108 ) and remain substantially “trapped” within that same layer.
- Other polysilicon layers may be implanted to different dopant densities, or even with a dopant of opposite conductivity type than a dopant already implanted into a different polysilicon layer.
- the gate dielectric may be reduced down to approximately 25 ⁇ , without serious concentration of boron reaching the gate dielectric. Moreover, a sharp doping profile is achieved at the nitrogen barrier region. The doping profile within the polysilicon retains a much sharper profile than is otherwise achievable without using the barrier region techniques disclosed herein.
- the N-channel transistors are processed in like manner as the P-channel transistor discussed above, except that an n-type dopant atom (e.g., arsenic) is implanted to form the N-channel source/drain regions.
- an n-type dopant atom e.g., arsenic
- the P-channel transistors may be masked with photoresist during the n-type source/drain implant step, which photoresist serves to prevent the n-type dopant from reaching the N-channel gate, channel, and source/drain regions.
- the p-type implanting step for the P-channel source/drain regions is performed while the N-channel IGFETs are protected. Consequently, barrier regions may be advantageously formed, if desired, only within the gate electrode of P-channel IGFETs which have greater dopant diffusion than N-channel IGFETs.
- An IGFET transistor may be conceptualized as having a control terminal which controls the flow of current between a first current handling terminal and a second current handling terminal.
- IGFET transistors are frequently discussed as having a drain, a gate, and a source, in most such devices the drain is interchangeable with the source. This is because the layout and semiconductor processing of the transistor is symmetrical.
- the current handling terminal normally residing at the higher voltage is customarily called the drain.
- the current handling terminal normally residing at the lower voltage is customarily called the source.
- a sufficient voltage on the gate causes a current to therefore flow from the drain to the source.
- the source voltage referred to in N-channel IGFET device equations merely refers to whichever drain or source terminal has the lower voltage at any given point in time.
- the “source” of the N-channel device of a bi-directional CMOS transfer gate depends on which side of the transfer gate is at the lower voltage.
- the control terminal may be deemed the gate
- the first current handling terminal may be termed the “drain/source”
- the second current handling terminal may be termed the “source/drain”.
- Such a description is equally valid for a P-channel IGFET transistor, since the polarity between drain and source voltages, and the direction of current flow between drain and source, is not implied by such terminology.
- one current-handling terminal may arbitrarily deemed the “drain” and the other deemed the “source”, with an implicit understanding that the two are not distinct, but interchangeable.
- IGFET transistors are commonly referred to as MOSFET transistors (which literally is an acronym for “Metal-Oxide-Semiconductor Field Effect Transistor”), even though the gate material may be polysilicon or some material other than metal, and the dielectric may be oxynitride, nitride, or some material other than oxide.
- MOSFET transistors which literally is an acronym for “Metal-Oxide-Semiconductor Field Effect Transistor”
- MOSFET transistors which literally is an acronym for “Metal-Oxide-Semiconductor Field Effect Transistor”
- MOSFET transistors which literally is an acronym for “Metal-Oxide-Semiconductor Field Effect Transistor”
- the gate material may be polysilicon or some material other than metal
- the dielectric may be oxy
- the boron implant steps described may utilize B, BF, BF 2 , or any other source containing boron atoms such as BF X
- any nitrogen implant step described may utilize atomic nitrogen (N), molecular nitrogen (N 2 ), or any other source containing nitrogen atoms.
- a given implant may be restricted to forming a corresponding layer within a certain region (for example, such as a P-channel gate electrode) and excluding other regions (for example, such as an N-channel gate electrode).
- a given implant step described above may be performed using two different implant operations, each at a different energy, to achieve a wider doping profile than achievable using a single implant. Accordingly, other embodiments, variations, and improvements not described herein are not necessarily excluded from the scope of the invention, which is defined by the following appended claims.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
- This patent document is related to the following commonly-assigned, copending U.S. patent applications, which are each incorporated herein by reference in its entirety:
- U.S. patent application Ser. No. 09/086,296, entitled “COMPOSITE GATE DIELECTRIC LAYER INCORPORATING DOPANT DIFFUSION-RETARDING BARRIER LAYER,” naming as inventors Mark I. Gardner, Robert Dawson, H. Jim Fulford, Jr., Frederick N. Hause, Mark W. Michael, Bradley T. Moore, and Derick J. Wristers;
- U.S. patent application Ser. No. 08/837,581, entitled “COMPOSITE GATE ELECTRODE INCORPORATING DOPANT DIFFUSION-RETARDING BARRIER LAYER ADJACENT TO UNDERLYING GATE DIELECTRIC,” naming as inventors Mark I. Gardner, Robert Dawson, H. Jim Fulford, Jr., Frederick N. Hause, Mark W. Michael, Bradley T. Moore, and Derick J. Wristers; and
- U.S. patent application Ser. No. 09/086,050, entitled “MULTI-LAYER GATE ELECTRODE INCORPORATING DOPANT DIFFUSION-RETARDING BARRIER LAYER,” naming as inventors Mark I. Gardner, Jon Cheek, Robert Dawson, H. Jim Fulford, Jr., Frederick N. Hause, Mark W. Michael, Bradley T. Moore, Thomas E. Spikes, Jr. and Derick J. Wristers.
- 1. Field of the Invention
- The present invention is related to the manufacture of insulated gate field effect transistors, and more particularly to the structure and doping of gate electrode structures therein.
- 2. Description of the Related Art
- An insulated-gate field-effect transistor (IGFET), such as a metal-oxide semiconductor field-effect transistor (MOSFET), uses a gate electrode to control an underlying surface channel joining a source and a drain. The channel, drain and source are located in a semiconductor substrate, with the channel being doped oppositely to the drain and source. The gate electrode is separated from the semiconductor substrate by a thin insulating layer (i.e., a gate dielectric layer) such as an oxide. The operation of the IGFET involves application of an input voltage to the gate electrode, which sets up a transverse electric field in the channel in order to modulate the longitudinal conductance of the channel.
- In typical IGFET processing, the source and drain are formed by introducing dopants of a second conductivity type (P or N) into the semiconductor substrate of a first conductivity type (N or P) using a patterned gate electrode as a mask. This self-aligning procedure tends to improve packing density and reduce parasitic overlap capacitances between the gate electrode and the source/drain regions. Polysilicon (also called polycrystalline silicon, poly-Si, or just “poly”) thin films are typically used as the gate electrode. Since polysilicon has the same high melting point as a silicon substrate, it can be deposited prior to source and drain formation. The polysilicon is anisotropically etched through openings in a photoresist mask to provide a gate electrode which forms a mask during formation of the source and drain by ion implantation. Photolithography is used to create patterns in the photoresist mask that define the gate electrode.
- The gate electrode is typically doped by the same type of ion implantation as are the source and drain. For example, boron is frequently implanted to form the source and drain in a P-channel IGFET, and the boron is also implanted into the gate electrode of the IGFET to create a P-type polysilicon gate electrode. However, because boron is such a “light” atom (i.e., low atomic mass), boron implanted into the polysilicon gate electrode can easily diffuse along the grain boundaries of the polysilicon and into the gate oxide, and may diffuse ultimately into the underlying channel region. The presence of boron in the channel affects the device parameters of the IGFET, especially the threshold voltage, and the presence of boron in the gate oxide can affect the reliability of the IGFET. Both effects are tremendously undesirable.
- A number of techniques have been utilized to reduce diffusion of dopants, especially boron, into the gate dielectric and into the underlying channel. One such method is disclosed by Fang, et al, in a paper entitled “Low-Temperature Furnace-Grown Reoxidized Nitrided Oxide Gate Dielectrics as a Barrier to Boron Penetration,”IEEE Electron Device Letters, Vol. 13, No. 4, April, 1992, which includes a nitridation of a partially grown gate oxide, followed by an additional oxidation step. Polysilicon is then deposited on the reoxidized nitrided oxide and etched to form gate electrodes.
- Other similar methods are disclosed by Joshi, et al in a paper entitled “Oxynitride Gate Dielectrics for P+ polysilicon Gate MOS Devices, ”IEEE Electron Device Letters, Vol. 14, No. 12, December, 1993, which compares several similar methods of forming oxynitride gate dielectrics.
- While such methods are helpful in reducing boron penetration into the channel, the desired gate oxide thickness continues to decrease. The effectiveness of earlier techniques may diminish with decreasing gate oxide thickness. Accordingly, there is a need for improved techniques for reducing dopant penetration (especially boron) into the gate oxide and into the channel region.
- The present invention improves upon the previous techniques for retarding dopant diffusion into the gate dielectric by incorporating a diffusion barrier region within a layer of polysilicon. The barrier region is a nitrogen-containing, diffusion-retarding barrier region. The portion of the polysilicon layer above the barrier region is doped more heavily than the portion below, and the barrier region serves to keep most of the dopant within the upper portion. The barrier region nevertheless allows some of the dopant to diffuse into the lower portion, which ensures that the polysilicon layer forms a gate electrode which is a single contiguous electrical node rather than an insulating portion due to polysilicon depletion effects.
- The barrier region is formed by implanting a nitrogen-containing material, such as elemental nitrogen or molecular nitrogen, so that a region is formed within the polysilicon layer. The thickness of the nitrogen-containing region may be chosen for its ability to conduct current therethrough while retaining its ability to retard dopant diffusion, and may be chosen to be approximately 5-15 Å thick.
- By use of this invention, any nitrogen residing at the top of the gate dielectric may be kept to a concentration less than approximately 2%. The dopant concentration at the first polysilicon layer bottom surface may exceed approximately 1×1021 atoms/cm3. The present invention is particularly well suited to thin gate dielectrics, such as a those having a thickness less than approximately 60 Å when using a p-type dopant, such as B, BF2, and other similar compounds of boron and flourine (e.g., BFx).
- In one embodiment for a semiconductor manufacturing process, a method of fabricating a gate electrode structure for an insulated gate field effect transistor includes the steps of: (1) forming a polysilicon layer on an underlying gate dielectric layer, the polysilicon layer having top and bottom surfaces, the bottom surface forming an interface with said gate dielectric layer; (2) implanting a nitrogen-containing material to form a nitrogen-containing diffusion-retarding barrier region within the polysilicon layer; (3) introducing a dopant into at least a portion of the polysilicon layer disposed between the barrier region and the top surface, resulting in a greater dopant concentration immediately above the barrier region than immediately below; and (4) removing regions of the polysilicon layer to form a gate electrode for the IGFET.
- In another embodiment, the method includes the additional step of implanting a nitrogen-containing material to form a second nitrogen-containing diffusion-retarding barrier region above and spaced apart from the first nitrogen-containing diffusion-retarding barrier region.
- In yet another embodiment of the present invention, a semiconductor gate electrode structure for an insulated gate field effect transistor includes: (1) a polysilicon layer formed on an underlying gate dielectric layer, the polysilicon layer having respective top and bottom surfaces, the bottom surface forming an interface with said gate dielectric layer; (2) a first nitrogen-containing diffusion-retarding barrier region formed within the polysilicon layer; and (3) a dopant within the polysilicon layer having a greater dopant concentration immediately above the diffusion barrier region than immediately below.
- The present invention may be better understood, and its numerous objects, features, and advantages made apparent to those skilled in the art by referencing the accompanying drawings.
- FIGS.1A-1D are cross-sectional views illustrating a semiconductor process flow in accordance with the present invention.
- FIG. 2 is a cross-sectional view illustrating a doping profile associated with the process flow depicted in FIGS.1A-1D.
- FIG. 3 is a cross-sectional view of a structure incorporating two barrier regions in accordance with another embodiment of the present invention.
- In the drawings, depicted elements are not necessarily drawn to scale, and like or similar elements may be designated by the same reference numeral throughout the several views.
- FIGS.1A-1D show cross-sectional views of successive process steps for forming a gate electrode in accordance with a first embodiment of the present invention. In FIG. 1A, a layer of
polysilicon 104 is shown disposed upon a gate dielectric 102, which in turn is disposed on asemiconductor substrate 100 suitable for integrated circuit manufacture. For example,substrate 100 includes a phosphorus-doped N-well formed in a P-type planar epitaxial surface layer (not shown) with a <100> orientation and a resistivity of 12 ohm-cm. Preferably, the epitaxial surface layer is disposed on a P+ base layer (not shown). A blanket layer of gate dielectric 102 (e.g., silicon dioxide, silicon oxynitride, nitrided silicon dioxide, etc.) is formed on the top surface ofsubstrate 100 preferably using tube growth at a temperature of 700-1,000° C. in an O2 containing ambient.Gate dielectric 102 has a preferred thickness in the range of 25 to 200 A. Thereafter, a first layer ofpolysilicon 104 preferably is deposited by low pressure chemical vapor deposition (LPCVD) on the top surface of thegate dielectric 102.Polysilicon 104 is deposited undoped and has a preferred thickness in the range of 100-300 A. - Continuing with this exemplary process sequence, a
nitrogen implant 105 is performed to create anitrogen barrier region 106 within thepolysilicon 104. For example, elemental nitrogen (N) may be implanted using an energy of 5-30 keV and at a dose of 5×1014-5×1015 atoms/cm2. Alternatively, molecular nitrogen (N2) may also be implanted using an energy of 10-60 keV and at a dose of 5×1014-5×1015 atoms/cm2. An anneal may optionally follow the nitrogen implant. Such an anneal may be performed using a rapid thermal processing (RTP) step, using a tube anneal, or other similar methods. For example, an RTP anneal may be performed for a time in the range of 10-60 seconds at a temperature in the range of 900-1050° C. The resulting structure is shown in FIG. 1B. Anupper portion 108 ofpolysilicon layer 104 is shown disposed between thebarrier region 106 and the top surface of thepolysilicon 104. Alower portion 107 ofpolysilicon layer 104 is shown disposed between thebarrier region 106 and the bottom surface of the polysilicon 104 (at the interface with the gate dielectric 102). Thepolysilicon 104 is formed with a thickness in the range of 300-2500 A. - A photoresist layer (not shown) is next applied and a gate mask used to image the gate electrode features into the photoresist. The
polysilicon region 108,barrier region 106, andpolysilicon region 107 are then anisotropically etched to define agate electrode 120. A light dose of a first dopant (e.g., boron) is implanted into thesemiconductor substrate 100 to provide a lightly dopedsource region 110 and a lightly dopeddrain region 112. The first dopant is also implanted into thegate electrode 120 wherein thepolysilicon 108 is lightly doped. For instance, the structure is subjected to ion implantation of boron at a dose in the range of 5×1013 to 1×1014 atoms/cm2 and an energy in the range of 2 to 80 kiloelectron-volts. As a result, the lightly dopedsource region 110 and the lightly dopeddrain region 112, both substantially aligned with thegate electrode 120, are formed at and below the surface ofsubstrate 100. Lightly doped source and drainregions -
Spacers gate electrode 120. The resulting structure is shown in FIG. 1C, which showsspacers gate electrode 120, and shows lightly-dopedsource region 110 and lightly-dopeddrain region 112 formed within thesubstrate 100. - Continuing with the process sequence, a boron implant118 is next performed to form P+ regions in both source and drain regions. The resulting structure is shown in FIG. 1D, which shows
P+ source region 122 andP+ drain region 124 formed within thesubstrate 100 and outward of thespacers source region 122 and the heavily dopeddrain region 124, both substantially aligned with thespacers substrate 100. Heavily doped source and drainregions spacers gate electrode 120 serve to prevent the boron implant from reaching thechannel 101 underlying thegate electrode 120 and from reaching the lightly doped source and drainregions - Further processing steps in the fabrication of IGFETs typically include forming a thick oxide layer over the active regions, forming contact windows in the oxide layer above the drain, source and gate electrode, forming appropriate interconnect metallization in the contact windows, and forming a passivation layer. These further processing steps are conventional and need not be repeated herein. Likewise the principal processing steps disclosed herein may be combined with other steps readily apparent to those skilled in the art.
- The preferred doping profile within the
gate electrode 120 as a result of the boron implant 118 is shown in FIG. 2. The bulk of the dopant is implanted into thepolysilicon region 108, which is above thebarrier region 106. Only a small amount of the dopant is preferably implanted into the region of thebarrier region 106 or into thepolysilicon region 107 layer below thebarrier region 106. Through subsequent heat treatment operations (e.g., implant anneal steps) thebarrier region 106 retards the downward diffusion of the boron and helps prevent boron from reaching thegate dielectric 102/polysilicon 104 interface. Alternatively, the dopant profile may exist entirely within the upper layer ofpolysilicon 108. In either case, thebarrier region 106 retards the downward diffusion of dopant toward thegate dielectric 102 and toward thechannel region 101. - In another embodiment generally following the sequence depicted in FIGS.1A-1D, the
barrier region 106 may be formed by depositing a nitrogen-containing layer, such as silicon nitride or titanium nitride, onto the top surface ofpolysilicon 104. Suitable conditions for depositing a layer of silicon nitride are low pressure chemical vapor deposition (LPCVD), plasma deposition and deposition by sputtering. Suitable conditions for depositing a layer of titanium nitride are low pressure chemical vapor deposition, plasma deposition and deposition by sputtering. Such a layer of titanium nitride is electrically conductive and thus helps ensure a good electrical connection betweenpolysilicon region 107 andpolysilicon region 108. - FIG. 3 is a cross-sectional view of a multi-layer structure incorporating three polysilicon layers, with a separate barrier region between each adjacent pair of polysilicon layers. A blanket layer of gate dielectric102 (e.g., silicon dioxide, silicon oxynitride, nitrided silicon dioxide, etc.) is formed on the top surface of
substrate 100 as before, preferably to a thickness in the range of 25 to 200 Å. Thereafter, a first layer ofpolysilicon region 107 is deposited on the top surface of thegate dielectric 102.Polysilicon region 107 is deposited undoped and has a preferred thickness in the range of 100-300 Å. - Continuing with the exemplary process sequence, a first nitrogen anneal is performed to create a
nitrogen barrier region 106 on the top surface of thepolysilicon region 107. A second layer ofpolysilicon 108 is then deposited on the top surface of thebarrier region 106, preferably to a thickness of 100-300 Å. A second nitrogen anneal is performed to create a secondnitrogen barrier region 130 on the top surface of thepolysilicon 108. A third layer ofpolysilicon 132 is then deposited on the top surface of thebarrier region 130, preferably to a thickness of 300-2500 Å. - A photoresist layer (not shown) is next applied and a gate mask used to image the gate electrode features into the photoresist. The
polysilicon region 132,barrier region 130,polysilicon region 108,barrier region 106, andpolysilicon region 107 are then anisotropically etched to define a gate electrode (not shown). Next, LDD regions, spacers, and source/drain regions are formed in a manner similar to that described before. Specifically, a light dose of a first dopant (e.g., boron) is then implanted into thesemiconductor substrate 100 to provide a lightly doped source and drain regions (i.e., LDD regions, not shown). This first dopant is also implanted into theundoped polysilicon region 132, possibly also into theundoped polysilicon 108, and possibly into theundoped polysilicon region 107, wherein each is lightly doped. For instance, the structure is subjected to ion implantation of boron at a dose in the range of 5×1013 to 1×1014 atoms/cm2 and an energy in the range of 2 to 80 kiloelectron-volts. Spacers are then formed at the edges of the gate electrode as before, followed by a boron implant (not shown) to form P+ regions in both source and drain regions, as before. - Such a multi-layer structure has several additional potential advantages. If, for example, the heavy boron implant is targeted to achieve an implant depth residing within the
polysilicon 132, then thebarrier region 130 retards some amount of dopant diffusion into themiddle polysilicon 108, while thelower barrier region 106 additionally retards the diffusion of dopant already within thepolysilicon 108 from reaching the lower layer ofpolysilicon region 107. In other words, the presence of twobarrier regions polysilicon 132 but yet reduces the amount of dopant reaching the lower layer ofpolysilicon 107, and especially reduces the amount of dopant which reaches thepolysilicon 107/gate dielectric 102 interface. This is accomplished while keeping the thickness of each barrier region thin enough to allow some amount of dopant diffusion sufficient to “dope” thepolysilicon 108 andpolysilicon 107 enough to prevent undesirable polysilicon depletion effects which otherwise result when the polysilicon near the gate dielectric interface remains undoped. - Alternatively, the barrier regions may be produced at a sufficient thickness to substantially prevent implanted dopant from diffusing through the barrier regions. A dopant may be implanted into a particular polysilicon layer (e.g., polysilicon108) and remain substantially “trapped” within that same layer. Other polysilicon layers may be implanted to different dopant densities, or even with a dopant of opposite conductivity type than a dopant already implanted into a different polysilicon layer.
- By use of this invention, the gate dielectric may be reduced down to approximately 25 Å, without serious concentration of boron reaching the gate dielectric. Moreover, a sharp doping profile is achieved at the nitrogen barrier region. The doping profile within the polysilicon retains a much sharper profile than is otherwise achievable without using the barrier region techniques disclosed herein.
- Additional techniques for dopant implantation into polysilicon gate electrodes are disclosed in copending commonly-assigned application entitled “Displacement of Implanted Profile for Thin Polysilicon Transistors”, naming inventors Mark I. Gardner, Robert Dawson, H. Jim Fulford, Jr., Frederick N. Hause, Mark W. Michael, Bradley T. Moore, and Derick J. Wristers, filed on even date herewith, and having Ser. Number (unassigned, Attorney Docket No. M-4000 US), which application is incorporated by reference herein in its entirety.
- Although only a single FET has been shown for purposes of illustration, it is understood that in actual practice, many devices are fabricated on a single semiconductor wafer as widely practiced in the art. Accordingly, the invention is well-suited for use in an integrated circuit chip, as well as an electronic system including a microprocessor, a memory, and a system bus.
- Those skilled in the art will readily implement the steps necessary to provide the structures and methods disclosed herein, and will understand that the process parameters, materials, and dimensions are given by way of example only and can be varied to achieve the desired structure as well as modifications which are within the scope of the invention.
- In a typical embodiment for a CMOS process the N-channel transistors are processed in like manner as the P-channel transistor discussed above, except that an n-type dopant atom (e.g., arsenic) is implanted to form the N-channel source/drain regions. As is well known in the art, the P-channel transistors may be masked with photoresist during the n-type source/drain implant step, which photoresist serves to prevent the n-type dopant from reaching the N-channel gate, channel, and source/drain regions. Likewise, the p-type implanting step for the P-channel source/drain regions is performed while the N-channel IGFETs are protected. Consequently, barrier regions may be advantageously formed, if desired, only within the gate electrode of P-channel IGFETs which have greater dopant diffusion than N-channel IGFETs.
- An IGFET transistor may be conceptualized as having a control terminal which controls the flow of current between a first current handling terminal and a second current handling terminal. Although IGFET transistors are frequently discussed as having a drain, a gate, and a source, in most such devices the drain is interchangeable with the source. This is because the layout and semiconductor processing of the transistor is symmetrical. For an N-channel IGFET transistor, the current handling terminal normally residing at the higher voltage is customarily called the drain. The current handling terminal normally residing at the lower voltage is customarily called the source. A sufficient voltage on the gate (relative to the source voltage) causes a current to therefore flow from the drain to the source. The source voltage referred to in N-channel IGFET device equations merely refers to whichever drain or source terminal has the lower voltage at any given point in time. For example, the “source” of the N-channel device of a bi-directional CMOS transfer gate depends on which side of the transfer gate is at the lower voltage. To reflect this symmetry of most N-channel IGFET transistors, the control terminal may be deemed the gate, the first current handling terminal may be termed the “drain/source”, and the second current handling terminal may be termed the “source/drain”. Such a description is equally valid for a P-channel IGFET transistor, since the polarity between drain and source voltages, and the direction of current flow between drain and source, is not implied by such terminology. Alternatively, one current-handling terminal may arbitrarily deemed the “drain” and the other deemed the “source”, with an implicit understanding that the two are not distinct, but interchangeable. It should be noted that IGFET transistors are commonly referred to as MOSFET transistors (which literally is an acronym for “Metal-Oxide-Semiconductor Field Effect Transistor”), even though the gate material may be polysilicon or some material other than metal, and the dielectric may be oxynitride, nitride, or some material other than oxide. The casual use of such historical legacy terms as MOSFET should not be interpreted to literally specify a metal gate FET having an oxide dielectric.
- While the invention has been largely described with respect to the embodiments set forth above, the invention is not necessarily limited to these embodiments. Variations and modifications of the embodiments disclosed herein may be made based on the description set forth herein, without departing from the scope and spirit of the invention as set forth in the following claims. For example, the invention is not necessarily limited to any particular transistor process technology, or to any particular layer thickness or composition. Moreover, while gate dielectrics are commonly formed of silicon dioxide, such a
gate dielectric 102 in the above embodiments may be formed of a silicon oxynitride, a silicon nitride, or any other suitable insulating material which may be formed in an appropriate thickness. Moreover, while the embodiments have been described in the context of a P-channel IGFET formed within an N-well disposed within a P− epitaxial layer atop a P+ substrate, it should be appreciated that such detailed process descriptions are equally applicable for N-channel IGFET fabrication, and for various other types of semiconductor substrates including a P− substrate with an N-well, an N− substrate with a P-well, and an N− epitaxial layer on an N+ substrate. - The boron implant steps described may utilize B, BF, BF2, or any other source containing boron atoms such as BFX, and any nitrogen implant step described may utilize atomic nitrogen (N), molecular nitrogen (N2), or any other source containing nitrogen atoms. A given implant may be restricted to forming a corresponding layer within a certain region (for example, such as a P-channel gate electrode) and excluding other regions (for example, such as an N-channel gate electrode). A given implant step described above may be performed using two different implant operations, each at a different energy, to achieve a wider doping profile than achievable using a single implant. Accordingly, other embodiments, variations, and improvements not described herein are not necessarily excluded from the scope of the invention, which is defined by the following appended claims.
Claims (22)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/177,043 US6380055B2 (en) | 1998-10-22 | 1998-10-22 | Dopant diffusion-retarding barrier region formed within polysilicon gate layer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/177,043 US6380055B2 (en) | 1998-10-22 | 1998-10-22 | Dopant diffusion-retarding barrier region formed within polysilicon gate layer |
Publications (2)
Publication Number | Publication Date |
---|---|
US20020004294A1 true US20020004294A1 (en) | 2002-01-10 |
US6380055B2 US6380055B2 (en) | 2002-04-30 |
Family
ID=22646951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/177,043 Expired - Lifetime US6380055B2 (en) | 1998-10-22 | 1998-10-22 | Dopant diffusion-retarding barrier region formed within polysilicon gate layer |
Country Status (1)
Country | Link |
---|---|
US (1) | US6380055B2 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6534388B1 (en) * | 2000-09-27 | 2003-03-18 | Chartered Semiconductor Manufacturing Ltd. | Method to reduce variation in LDD series resistance |
US20040021161A1 (en) * | 2001-10-04 | 2004-02-05 | Agarwal Kishnu K. | Self-aligned poly-metal structures |
US20050181578A1 (en) * | 2003-08-01 | 2005-08-18 | Agarwal Kishnu K. | Self-aligned poly-metal structures |
US20080194087A1 (en) * | 2007-02-12 | 2008-08-14 | Chen-Hua Yu | Polysilicon gate formation by in-situ doping |
CN103972275A (en) * | 2013-01-30 | 2014-08-06 | 旺宏电子股份有限公司 | Semiconductor device and method for manufacturing the same |
CN110047947A (en) * | 2014-03-28 | 2019-07-23 | 太阳能公司 | Solar battery with tunnel dielectric |
US10553476B2 (en) * | 2017-05-26 | 2020-02-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device including polysilicon structures having differing grain sizes and including a barrier layer therebetween |
US20220165886A1 (en) * | 2020-11-23 | 2022-05-26 | Changxin Memory Technologies, Inc. | Semiconductor structure and a manufacturing method thereof |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6373114B1 (en) * | 1998-10-23 | 2002-04-16 | Micron Technology, Inc. | Barrier in gate stack for improved gate dielectric integrity |
JP2001332630A (en) * | 2000-05-19 | 2001-11-30 | Sharp Corp | Method for manufacturing semiconductor device |
JP2002208695A (en) * | 2001-01-11 | 2002-07-26 | Mitsubishi Electric Corp | Semiconductor device and method of manufacturing the same |
DE10234488B4 (en) * | 2002-07-29 | 2007-03-29 | Advanced Micro Devices, Inc., Sunnyvale | A method of making a localized implantation barrier in a polysilicon line |
US6686637B1 (en) * | 2002-11-21 | 2004-02-03 | International Business Machines Corporation | Gate structure with independently tailored vertical doping profile |
KR100530420B1 (en) * | 2003-07-11 | 2005-11-22 | 주식회사 하이닉스반도체 | Method of manufacturing in flash memory device |
SE526207C2 (en) * | 2003-07-18 | 2005-07-26 | Infineon Technologies Ag | Ldmos transistor device, integrated circuit and manufacturing method thereof |
US7473614B2 (en) * | 2004-11-12 | 2009-01-06 | Intel Corporation | Method for manufacturing a silicon-on-insulator (SOI) wafer with an etch stop layer |
US7271079B2 (en) * | 2005-04-06 | 2007-09-18 | International Business Machines Corporation | Method of doping a gate electrode of a field effect transistor |
US20080194072A1 (en) * | 2007-02-12 | 2008-08-14 | Chen-Hua Yu | Polysilicon gate formation by in-situ doping |
US7790535B2 (en) * | 2008-09-16 | 2010-09-07 | Taiwan Semiconductor Manufacturing Company, Ltd. | Depletion-free MOS using atomic-layer doping |
KR101594031B1 (en) * | 2009-08-28 | 2016-02-15 | 삼성전자주식회사 | Semiconductor device having impurity doped polycrystalline layer including impurity diffusion prevention layer therein and dynamic random memory device using the same |
JP2013074189A (en) * | 2011-09-28 | 2013-04-22 | Elpida Memory Inc | Semiconductor device and manufacturing method of the same |
JP6081816B2 (en) * | 2013-02-26 | 2017-02-15 | ルネサスエレクトロニクス株式会社 | Semiconductor device and manufacturing method thereof |
CN109494224B (en) * | 2017-09-08 | 2020-12-01 | 华邦电子股份有限公司 | Nonvolatile memory device and method of making the same |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL187328C (en) | 1980-12-23 | 1991-08-16 | Philips Nv | METHOD FOR MANUFACTURING A SEMICONDUCTOR DEVICE |
US4369072A (en) | 1981-01-22 | 1983-01-18 | International Business Machines Corp. | Method for forming IGFET devices having improved drain voltage characteristics |
US4481527A (en) | 1981-05-21 | 1984-11-06 | Mcdonnell Douglas Corporation | High density MNOS transistor with ion implant into nitride layer adjacent gate electrode |
US4575921A (en) * | 1983-11-04 | 1986-03-18 | General Motors Corporation | Silicon nitride formation and use in self-aligned semiconductor device manufacturing method |
JPS60189971A (en) * | 1984-03-09 | 1985-09-27 | Toshiba Corp | Manufacture of semiconductor device |
US4623912A (en) | 1984-12-05 | 1986-11-18 | At&T Bell Laboratories | Nitrided silicon dioxide layers for semiconductor integrated circuits |
US4774197A (en) | 1986-06-17 | 1988-09-27 | Advanced Micro Devices, Inc. | Method of improving silicon dioxide |
KR920002350B1 (en) | 1987-05-21 | 1992-03-21 | 마쯔시다덴기산교 가부시기가이샤 | Method of manufacturing semiconductor |
EP0313683A1 (en) | 1987-10-30 | 1989-05-03 | International Business Machines Corporation | Method for fabricating a semiconductor integrated circuit structure having a submicrometer length device element |
US5219773A (en) | 1990-06-26 | 1993-06-15 | Massachusetts Institute Of Technology | Method of making reoxidized nitrided oxide MOSFETs |
GB9103715D0 (en) | 1991-02-22 | 1991-04-10 | Ici Plc | Process for preparing foams |
US5436481A (en) | 1993-01-21 | 1995-07-25 | Nippon Steel Corporation | MOS-type semiconductor device and method of making the same |
US5514902A (en) | 1993-09-16 | 1996-05-07 | Mitsubishi Denki Kabushiki Kaisha | Semiconductor device having MOS transistor |
US6780718B2 (en) | 1993-11-30 | 2004-08-24 | Stmicroelectronics, Inc. | Transistor structure and method for making same |
US5518958A (en) | 1994-07-29 | 1996-05-21 | International Business Machines Corporation | Prevention of agglomeration and inversion in a semiconductor polycide process |
US5567638A (en) * | 1995-06-14 | 1996-10-22 | National Science Council | Method for suppressing boron penetration in PMOS with nitridized polysilicon gate |
DE19526184A1 (en) | 1995-07-18 | 1997-04-03 | Siemens Ag | Method of manufacturing a MOS transistor |
JPH0992728A (en) | 1995-09-21 | 1997-04-04 | Mitsubishi Electric Corp | Complementary MOS field effect transistor and manufacturing method thereof |
US5605848A (en) | 1995-12-27 | 1997-02-25 | Chartered Semiconductor Manufacturing Pte Ltd. | Dual ion implantation process for gate oxide improvement |
US5945904A (en) | 1996-09-06 | 1999-08-31 | Ford Motor Company | Giant magnetoresistors with high sensitivity and reduced hysteresis and thin layers |
US5872376A (en) * | 1997-03-06 | 1999-02-16 | Advanced Micro Devices, Inc. | Oxide formation technique using thin film silicon deposition |
US5885877A (en) * | 1997-04-21 | 1999-03-23 | Advanced Micro Devices, Inc. | Composite gate electrode incorporating dopant diffusion-retarding barrier layer adjacent to underlying gate dielectric |
US5879975A (en) | 1997-09-05 | 1999-03-09 | Advanced Micro Devices, Inc. | Heat treating nitrogen implanted gate electrode layer for improved gate electrode etch profile |
US5977561A (en) | 1998-03-02 | 1999-11-02 | Texas Instruments - Acer Incorporated | Elevated source/drain MOSFET with solid phase diffused source/drain extension |
-
1998
- 1998-10-22 US US09/177,043 patent/US6380055B2/en not_active Expired - Lifetime
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6534388B1 (en) * | 2000-09-27 | 2003-03-18 | Chartered Semiconductor Manufacturing Ltd. | Method to reduce variation in LDD series resistance |
US20040021161A1 (en) * | 2001-10-04 | 2004-02-05 | Agarwal Kishnu K. | Self-aligned poly-metal structures |
US7078327B2 (en) * | 2001-10-04 | 2006-07-18 | Micron Technology, Inc. | Self-aligned poly-metal structures |
US7508075B2 (en) | 2003-08-01 | 2009-03-24 | Micron Technology, Inc. | Self-aligned poly-metal structures |
US20050181578A1 (en) * | 2003-08-01 | 2005-08-18 | Agarwal Kishnu K. | Self-aligned poly-metal structures |
US7892909B2 (en) | 2007-02-12 | 2011-02-22 | Taiwan Semiconductor Manufacturing Company, Ltd. | Polysilicon gate formation by in-situ doping |
US20080194087A1 (en) * | 2007-02-12 | 2008-08-14 | Chen-Hua Yu | Polysilicon gate formation by in-situ doping |
CN103972275A (en) * | 2013-01-30 | 2014-08-06 | 旺宏电子股份有限公司 | Semiconductor device and method for manufacturing the same |
CN110047947A (en) * | 2014-03-28 | 2019-07-23 | 太阳能公司 | Solar battery with tunnel dielectric |
US10553476B2 (en) * | 2017-05-26 | 2020-02-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device including polysilicon structures having differing grain sizes and including a barrier layer therebetween |
US11094584B2 (en) | 2017-05-26 | 2021-08-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of forming semiconductor device including polysilicon structures |
US11676856B2 (en) | 2017-05-26 | 2023-06-13 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device including polysilicon structures and method of making |
US20220165886A1 (en) * | 2020-11-23 | 2022-05-26 | Changxin Memory Technologies, Inc. | Semiconductor structure and a manufacturing method thereof |
US12166133B2 (en) * | 2020-11-23 | 2024-12-10 | Changxin Memory Technologies, Inc. | Semiconductor structure and a manufacturing method thereof |
Also Published As
Publication number | Publication date |
---|---|
US6380055B2 (en) | 2002-04-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5885877A (en) | Composite gate electrode incorporating dopant diffusion-retarding barrier layer adjacent to underlying gate dielectric | |
US6380055B2 (en) | Dopant diffusion-retarding barrier region formed within polysilicon gate layer | |
US5583067A (en) | Inverse T-gate semiconductor device with self-aligned punchthrough stops and method of fabrication | |
US5933721A (en) | Method for fabricating differential threshold voltage transistor pair | |
US5963803A (en) | Method of making N-channel and P-channel IGFETs with different gate thicknesses and spacer widths | |
US5648287A (en) | Method of salicidation for deep quarter micron LDD MOSFET devices | |
US6383879B1 (en) | Semiconductor device having a metal gate with a work function compatible with a semiconductor device | |
US5091763A (en) | Self-aligned overlap MOSFET and method of fabrication | |
US5508212A (en) | Salicide process for a MOS semiconductor device using nitrogen implant of titanium | |
US6020244A (en) | Channel dopant implantation with automatic compensation for variations in critical dimension | |
US6312995B1 (en) | MOS transistor with assisted-gates and ultra-shallow “Psuedo” source and drain extensions for ultra-large-scale integration | |
US5930642A (en) | Transistor with buried insulative layer beneath the channel region | |
US6030874A (en) | Doped polysilicon to retard boron diffusion into and through thin gate dielectrics | |
US6911384B2 (en) | Gate structure with independently tailored vertical doping profile | |
US20020003273A1 (en) | Igfet with silicide contact on ultra-thin gate | |
US5744845A (en) | Complementary MOS field effect transistor with tunnel effect means | |
US6232166B1 (en) | CMOS processing employing zero degree halo implant for P-channel transistor | |
US6004849A (en) | Method of making an asymmetrical IGFET with a silicide contact on the drain without a silicide contact on the source | |
US5705417A (en) | Method for forming self-aligned silicide structure | |
KR100591344B1 (en) | Manufacturing method of semiconductor device | |
US5973370A (en) | Preventing boron penetration through thin gate oxide of P-channel devices in advanced CMOS technology | |
KR20050107591A (en) | Cmos integration for multi-thickness silicide devices | |
US6576521B1 (en) | Method of forming semiconductor device with LDD structure | |
US6188114B1 (en) | Method of forming an insulated-gate field-effect transistor with metal spacers | |
US5877058A (en) | Method of forming an insulated-gate field-effect transistor with metal spacers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: ADVANCED MICRO DEVICES, INC., CALIFORNIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GARDNER, MARK I.;DAWSON, ROBERT;FULFORD, H. JIM, JR.;AND OTHERS;REEL/FRAME:009538/0410;SIGNING DATES FROM 19981006 TO 19981019 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
CC | Certificate of correction | ||
FPAY | Fee payment |
Year of fee payment: 4 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES INC., CAYMAN ISLANDS Free format text: AFFIRMATION OF PATENT ASSIGNMENT;ASSIGNOR:ADVANCED MICRO DEVICES, INC.;REEL/FRAME:023119/0083 Effective date: 20090630 Owner name: GLOBALFOUNDRIES INC., CAYMAN ISLANDS Free format text: AFFIRMATION OF PATENT ASSIGNMENT;ASSIGNOR:ADVANCED MICRO DEVICES, INC.;REEL/FRAME:023120/0426 Effective date: 20090630 Owner name: GLOBALFOUNDRIES INC.,CAYMAN ISLANDS Free format text: AFFIRMATION OF PATENT ASSIGNMENT;ASSIGNOR:ADVANCED MICRO DEVICES, INC.;REEL/FRAME:023120/0426 Effective date: 20090630 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
FPAY | Fee payment |
Year of fee payment: 12 |
|
AS | Assignment |
Owner name: WILMINGTON TRUST, NATIONAL ASSOCIATION, DELAWARE Free format text: SECURITY AGREEMENT;ASSIGNOR:GLOBALFOUNDRIES INC.;REEL/FRAME:049490/0001 Effective date: 20181127 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES INC., CAYMAN ISLANDS Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WILMINGTON TRUST, NATIONAL ASSOCIATION;REEL/FRAME:054636/0001 Effective date: 20201117 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES U.S. INC., NEW YORK Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WILMINGTON TRUST, NATIONAL ASSOCIATION;REEL/FRAME:056987/0001 Effective date: 20201117 |