US1346190A - Firearm and alloy for making same - Google Patents
Firearm and alloy for making same Download PDFInfo
- Publication number
- US1346190A US1346190A US345081A US34508119A US1346190A US 1346190 A US1346190 A US 1346190A US 345081 A US345081 A US 345081A US 34508119 A US34508119 A US 34508119A US 1346190 A US1346190 A US 1346190A
- Authority
- US
- United States
- Prior art keywords
- nickel
- alloy
- firearm
- iron
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title description 13
- 239000000956 alloy Substances 0.000 title description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 36
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 229910052759 nickel Inorganic materials 0.000 description 18
- 229910052742 iron Inorganic materials 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- VNTLIPZTSJSULJ-UHFFFAOYSA-N chromium molybdenum Chemical compound [Cr].[Mo] VNTLIPZTSJSULJ-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41A—FUNCTIONAL FEATURES OR DETAILS COMMON TO BOTH SMALLARMS AND ORDNANCE, e.g. CANNONS; MOUNTINGS FOR SMALLARMS OR ORDNANCE
- F41A21/00—Barrels; Gun tubes; Muzzle attachments; Barrel mounting means
- F41A21/20—Barrels or gun tubes characterised by the material
Definitions
- This invention relates to firearms and ordnance and has for its particular object the provision of a metallic alloy for use in the construction of the same which shall be more resistant to corrosion by the combustion products of the explosive as well as less corroded by atmospheric conditions and salt solutions (such as sea-water or perspiration) than any of the materials now in use for this purpose, as well as having sufficient mechanical strength to endure the strains to which such devices are subjected and at the same time being sufliciently soft and workable for manufacturing purposes.
- nickel can properly be considered the basic element, since with a small nickel content not enough chromium molybdenum or other chemically resistant element can be caused to alloy with copper to result in a substance of sufiieient non-corrodibility.
- the amount of hardening'metal permissible depends upon the amount of nickel present, since of the above hardening metals only aluminum, zinc and cadmium are scilgu- 6- sides the copper itself exerts a hardening effect on the nickel and when used in the with any necessity for theiruse.
- the nickel content permits the addition of up to about 5% of chromolybdenum
- mium mium, molybdenum, tungsten, cobalt, vanadium, tantalum, zirconium, titanium, or
- iron; or manganese can be added up to about 10% and owing to the copper content about 5%.
- aluminum could be added or some what larger amounts of zinc or cadmium; any of which additions serves to increase the hardness and tensile strength to a degree sufficient for practically any firearm requirement.
- nickel-soluble hardening ingredients in like proportion although the solubility of the copper-soluble constituents is correspondingly reduced;
- nickelsoluble hardness up to a maximum of about 20% of the nickel content, which maximum is rather high in the case of zirconium, titanium, vanadium, or tentalum, and can be considerably exceeded in the case of iron, chromium, or manganese.
- the desired hardness is most economically attained by the use of iron or manganese.
- chromium would of course offer the additional advantage of increased chemical resistivity, but as this is already sufiiciently high I prefer the cheaper ingredient.
- dioxidizer or scavenger such as manganese, titanium, aluminum, magnesium, vanadium, or chromium
- a firearm barrel made of an alloy containing copper alloyed with not less than about twenty-five per cent. of nickel.
- a firearm barrel made 0t an alloy containing copper alloyed with not less than about twenty five per cent. of nickel together with smaller amounts of one or more additional metals in or adjacent to the iron group in the periodic table.
- a firearm barrel consistin of an alloy containing from about twenty ve per cent. to about ninety-nine per cent. of nickel and the balance principally of copper.
- a firearm barrel made of an alloy consisting essentially of from about twenty-five per cent. to about ninety-nine per cent. of nickel, the balance being principally copper together with smaller amounts of one or more of metals, iron, manganese, chromium, molybdenum or tungsten.
- a firearm barrel made of an alloy containing from about forty per cent. to about sixty per cent. of nickel together with about one per cent. to fifteen per cent. of iron, manganese, or chromium and the balance principally copper.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Soft Magnetic Materials (AREA)
Description
1919, and
STATES PATENT OFFHE,
FIREARM AND ALLOY FOR MAKING SAME.
No Drawing.
To all whom it may concern:
Be it known that I, FRANK A. FAHREN- WALD, a citizen of the United States, residing at Cleveland Heights, in the county of Cuyahoga 'and State of Ohio, have invented a certain new and useful Improvement in Firearms and Alloys for Making Same, of which the following is a full, clear, and exact description.
This invention relates to firearms and ordnance and has for its particular object the provision of a metallic alloy for use in the construction of the same which shall be more resistant to corrosion by the combustion products of the explosive as well as less corroded by atmospheric conditions and salt solutions (such as sea-water or perspiration) than any of the materials now in use for this purpose, as well as having sufficient mechanical strength to endure the strains to which such devices are subjected and at the same time being sufliciently soft and workable for manufacturing purposes.
Hitherto the universal substance for use in the manufacture of the barrels and working parts of firearms (including both hand-arms and fixed or heavy ordnance) has been a steel of some nature, consisting essentially of carbid of iron dissolved in an excess of iron, sometimes also including up to one or two per cent. of other metals such as nickel, tungsten, vanadium, etc. These materials offer the disadvantage of rapid corrosion by powder gases and residues, particularly those of smokeless powder, and rapid rusting as a result of atmospheric and salt'condi-t' tions besides being subject to warping both during the course of manufacture and during the vicissitudes of operation. I have discovered that these disadvantages can be avoided by the employment of certain alloys containing a decreased amount of iron alloyed with a considerable amount of various protective metals of which the chief are nickel {and chromium. In the case of chromium, nickel and iron are the only logical carriers, and the use of these metals for the purpose is full tion s Serial No. 319,822, filed August 25, 1919, Serial No; 330,943, filed October 15, Serial No. 345,083, filed December 15, 1919. In the case of the nickel, however, I have found that while iron is the best carrier (see applications Nos, 330,943 and 319,822, above mentionedlcopper also may be'used' successfully. Alloys having be- Specifieation of Letters Patent.
- ble in copper to an appreciable extent.
set forth and claimed in my applica Patented July 13, 1920.
Application filed December 15, 1919. Serial No. 345,081.
done by the addition of any one or more of v the following: chromium, tungsten, cobalt, vanadium, tantalum, zirconium, titanium, aluminum, iron, manganese, zinc, cadmium, all of which are soluble in one or the other of the prima ingredients, principally in the nickel. Til this series of alloys nickel can properly be considered the basic element, since with a small nickel content not enough chromium molybdenum or other chemically resistant element can be caused to alloy with copper to result in a substance of sufiieient non-corrodibility. The amount of hardening'metal permissible depends upon the amount of nickel present, since of the above hardening metals only aluminum, zinc and cadmium are scilgu- 6- sides the copper itself exerts a hardening effect on the nickel and when used in the with any necessity for theiruse. Thus ,while the alloy containing the minimum'of nickel above mentioned, namely 25%, 1s
sufiiciently strong for low power arms like.
.22 caliber rifles, the nickel content permits the addition of up to about 5% of chromolybdenum,
mium, molybdenum, tungsten, cobalt, vanadium, tantalum, zirconium, titanium, or
' iron; or manganese can be added up to about 10% and owing to the copper content about 5%. of aluminum could be added or some what larger amounts of zinc or cadmium; any of which additions serves to increase the hardness and tensile strength to a degree sufficient for practically any firearm requirement.
- Within the preferred range of between 40% and 60% of nickel it is possible to increase the amounts of the nickel-soluble hardening ingredients in like proportion although the solubility of the copper-soluble constituents is correspondingly reduced; For practical purposes I recommend the use of one or more of the above named nickelsoluble hardness up to a maximum of about 20% of the nickel content, which maximum is rather high in the case of zirconium, titanium, vanadium, or tentalum, and can be considerably exceeded in the case of iron, chromium, or manganese. The desired hardness is most economically attained by the use of iron or manganese. The use of chromium would of course offer the additional advantage of increased chemical resistivity, but as this is already sufiiciently high I prefer the cheaper ingredient.
11 any case it is necessary to use small amounts of dioxidizer or scavenger such as manganese, titanium, aluminum, magnesium, vanadium, or chromium, even though none of the same be desired in the resulting alloy, and of these I prefer manganese as being the cheapest.
. Having thus described my invention, what I claim is:
1. A firearm barrel made of an alloy containing copper alloyed with not less than about twenty-five per cent. of nickel.
2. A firearm barrel made 0t an alloy containing copper alloyed with not less than about twenty five per cent. of nickel together with smaller amounts of one or more additional metals in or adjacent to the iron group in the periodic table.
3. A firearm barrel consistin of an alloy containing from about twenty ve per cent. to about ninety-nine per cent. of nickel and the balance principally of copper.
4. A firearm barrel made of an alloy consisting essentially of from about twenty-five per cent. to about ninety-nine per cent. of nickel, the balance being principally copper together with smaller amounts of one or more of metals, iron, manganese, chromium, molybdenum or tungsten.
5. A firearm barrel made of an alloy containing from about forty per cent. to about sixty per cent. of nickel together with about one per cent. to fifteen per cent. of iron, manganese, or chromium and the balance principally copper.
In testimony whereof I hereunto afiix my signature.
FRANIC A. FAHRENWALD.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US345081A US1346190A (en) | 1919-12-15 | 1919-12-15 | Firearm and alloy for making same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US345081A US1346190A (en) | 1919-12-15 | 1919-12-15 | Firearm and alloy for making same |
Publications (1)
Publication Number | Publication Date |
---|---|
US1346190A true US1346190A (en) | 1920-07-13 |
Family
ID=23353419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US345081A Expired - Lifetime US1346190A (en) | 1919-12-15 | 1919-12-15 | Firearm and alloy for making same |
Country Status (1)
Country | Link |
---|---|
US (1) | US1346190A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2780019A (en) * | 1952-02-19 | 1957-02-05 | George C Sullivan | Gun barrel of aluminum alloy with metallic coatings |
US2850828A (en) * | 1953-03-24 | 1958-09-09 | George C Sullivan | Aluminum alloy gun barrel with a lubricating film |
US3628949A (en) * | 1969-12-16 | 1971-12-21 | Driver Co Wilbur B | Thermocouple extension wire |
US4450210A (en) * | 1981-10-23 | 1984-05-22 | Nippon Gakki Seizo Kabushiki Kaisha | Clad material |
-
1919
- 1919-12-15 US US345081A patent/US1346190A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2780019A (en) * | 1952-02-19 | 1957-02-05 | George C Sullivan | Gun barrel of aluminum alloy with metallic coatings |
US2850828A (en) * | 1953-03-24 | 1958-09-09 | George C Sullivan | Aluminum alloy gun barrel with a lubricating film |
US3628949A (en) * | 1969-12-16 | 1971-12-21 | Driver Co Wilbur B | Thermocouple extension wire |
US4450210A (en) * | 1981-10-23 | 1984-05-22 | Nippon Gakki Seizo Kabushiki Kaisha | Clad material |
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