TWI480372B - Adhering agent for the application on a sanitary ebject - Google Patents

Description

An adhesive carrier for a carrier material comprising at least one adhesion promoter or consisting of at least one adhesion promoter

The present invention relates to an adhesive carrier for use in the sanitary field, in particular for application to a sanitary article, such as for application to a toilet.

Such adhesive carrier agents are viscous, usually in the form of a paste, which is applied directly to the surface of the bathroom from a suitable container and is attached thereto to be removed from the surface after relatively multiple flushes.

WO 99/66017 discloses a bathroom adhesive carrier for cleansing and aroma comprising a surfactant, water, a fragrance and an adhesion promoter. After the sanitary adhesive carrier is directly applied to the toiletries, it must be washed out after relatively many flushes.

EP 1 325 103 B1 discloses a modification of such a sanitary adhesive carrier which has a smoother surface due to the addition of a polyol.

EP 1 318 191 B1 discloses other bathroom-adhering carrier agents based on block copolymers containing oligomeric alkylene oxide or polyalkylene oxide or based on aryl ethoxylates or alkyl groups Aryl ethoxylates, DE 10 2004 056 554 A1, disclose a bath-attachment carrier containing a bleaching agent.

The conventional sanitary adhesive carrier can be applied in a simple and hygienic manner by suitable equipment, which adheres to the surface of the bathroom, keeps its shape unchanged, water cannot completely wash it, and must be washed a plurality of times. Will gradually decompose.

The advantages of these sanitary adhesive carrier agents are mainly that they can be avoided. For example, the so-called "WC-Körbchen" additional containers are considered to be unsanitary, in particular when replacing bathroom-adhering carrier or toilet bowls.

In recent years, a variety of multi-phase products have been developed which use traditional block toilet cleaners and fragrances in toilet baskets for toilets: for example, bathroom adhesive carrier containing additional bleach disclosed in WO 00/23558, EP 1 418 A sanitary adhesive carrier containing a detergent type body phase and a gel phase disclosed in 225 A1, and a detergent dosage form disclosed in WO 00/58434, which comprises a phase containing a water-soluble salt and a water-insoluble salt.

The multi-phase adhesive carrier can be divided into a plurality of phases for performing various functions by dividing a toilet detergent and a fragrance. For example, a special phase is used for a strong fragrance, and a special phase is used for cleaning. This will better meet user requirements.

It is an object of the present invention to provide a sanitary adhesive carrier which can be applied in a simple and hygienic manner, which can be applied in many aspects and which can meet the needs of users in terms of strong aroma and effective cleaning.

This object is achieved by the features of claim 1.

The present inventors have surprisingly found that a viscosity of at least 30 Pa s (measured using a Haake viscometer, a plate/plate system at a shear rate of 2.62 s ^-1 and 20 ° C, a plate diameter of 10 mm) and containing active substances And an adhesive adhesion agent for the bathroom adhesive agent can be directly applied not only to the sanitary article, but also to be washed away after relatively repeated washing, and the adhesive agent can also be used as a block bathroom adhesive carrier. Attached to the toilet, wherein the adhesion promoter is selected from the group consisting of a polyalkylene derivative, a polyoxymethylene system, a copolymer selected from the group consisting of poly(methyl-vinyl-diethyl ether/carboxylic anhydride monoalkyl ester group, olefin) a group of homopolymers and a copolymer of two or more olefins, wherein the olefin homopolymer and the olefin copolymer are partially oxidized or further functionalized by a grafting molecule (Pfropfmolek), and a group of or containing an alkylenimine (also alkoxylated), a polyetheramine (alkoxylated amine), and a polyglycerol polyether alkyl carboxylic acid (an ester of alkoxylated polyglycerol) a polymer of the group or a derivative of such compounds.

A special adhesion promoter is used to adhere the sanitary adhesive carrier to the surface of the sanitary article, and to adhere other materials (such as a block-like sanitary adhesive carrier containing an active ingredient having a clean and aromatic effect) to the surface of the adhesive carrier. . Another feature of such adhesion promoters is that the sanitary adhesive carrier containing the adhesion promoter can be washed away without leaving traces, and the adhesion promoter and the active substance in the sanitary adhesive carrier containing the adhesion promoter The change in the mixing ratio has no significant effect on the sanitary adhesive carrier.

The viscosity and/or scouring property of the sanitary adhesive carrier can be adjusted by adding an appropriate action substance, and the bathroom adhesive carrier can achieve the desired aroma and dyeing effect.

The sanitary adhesive carrier of the present invention has a wide range of uses: in the case of using a water-soluble adhesion promoter, the sanitary adhesive carrier can be used as a water-soluble adhesive for temporary adhesion, and a block detergent (for example) The continuous extruded body type cleaner) is attached to the toilet, and such cleaners thus eliminate the need for special attachment means.

When the sanitary adhesive carrier is used in a "pure adhesive", the sanitary adhesive carrier becomes a substitute for a small basket of toilets that the user considers to be unsanitary. The adhesive carrier applied to the surface of the toilet may be adhered to a bulk-attached carrier agent containing an active ingredient and having its own function, such as a conventional cleaning block having one or more phases, a cleaning block having an aromatic phase, and an aromatic tablet. A cleaning block containing a bleaching agent, etc., wherein the adhesive carrier agent replaces the small basket of the toilet hygienically, and is washed away and washed away together with the bulk adhesive carrier agent adhered thereto. It is of course also possible to attach a tablet or a water-soluble or water-insoluble plastic containing an active ingredient to an adhesive carrier.

In such an application, the sanitary adhesive carrier comprises at least one adhesion promoter of the invention and a thickener. Since the adhesion promoter of the present invention is usually a viscous liquid, it is necessary to add a thickener as a substance to enable the adhesion of the sanitary adhesive carrier to an expected value of at least 30 Pa s. Since the adhesion promoter of the present invention is water-soluble, it is not necessary to add a surfactant for improving the rinsing property in this specific example.

It is of course also possible to add other ingredients such as dyes, fragrances, (as appropriate) surfactants and foaming agents to the base formulation consisting of adhesion promoters and thickeners.

According to a modification of the first embodiment, the sanitary adhesive carrier agent contains a fragrance in addition to the adhesion promoter and the thickener, so that the sanitary adhesive carrier agent can simultaneously serve both adhesion and aroma.

In the second application mode, the adhesive carrier contains the adhesion promoter of the present invention and a surfactant as an active substance, and thus can be appropriately selected by selecting the type and concentration of the surfactant and possibly other additives. The adhesive carrier itself has a cleaning function. Other desirable effective adhesive carrier agents can be applied to the toilet by adhesion, such as fragrances, bleached tablets, descaling tablets, and advertising vehicles.

By means of an adhesive carrier with a cleaning action, the user can, for example, select the corresponding fragrance according to his or her own will and press the corresponding aromatic tablet onto the applied adhesive carrier which has been applied, and the aromatic tablet can be adhered. On adherent carriers, this practice allows the toilet to remain aromatic for one or two weeks.

The adhesive carrier of the present invention can be used even with a series of aromatic tablets or aromatic gels, bleaching tablets, descaling tablets and strong cleaning tablets, so that the user can carry out the adhesive carrier for the user. Personalized equipment.

If the user desires additional bleaching, a bleached tablet can be adhered to the surface of the adherent carrier.

If the user desires a strong cleaning of the toilet, a cleaning tablet can be adhered to the adhesive carrier which has been cleaned. It is also possible to construct a multilayer adhesive carrier composed of a plurality of layers such as an adhesive-functional adhesive carrier-adhesive-functional adhesive carrier.

Although the conventional adhesive carrier described in the opening paragraph can be adhered to the sanitary article well and persistently, the other adhesive carrier agent cannot be "adhered" on the sanitary adhesive carrier.

In addition to being used for toilet hygiene, the adhesive carrier can also be used as a cold adhesive which can be washed away by water due to the addition of a surfactant. The adhesive carrier can be used as a cold adhesive in the bathroom to attach objects to the urinal, to the sink or tile in the shower, or to use in kitchens, restaurants, slaughterhouses or other A place that can be washed with water.

If the cold adhesive is used in a place where water can be washed, the adhesive carrier can be washed away and the surfactant contained in the adhesive carrier can be cleaned.

The adhesive carrier of the present invention can also be used in a cleaning device of a motor vehicle or on/in a drain or a gutter to achieve temporary aroma.

The adhesive carrier of the present invention can also be supplied to the bait as a washable paste to control pests, or can be continuously used for attachment to rainy windows or house surfaces.

The components of the adhesive carrier of the present invention are as follows: A preferred class of water-insoluble adhesion promoters from the group of polyalkylene derivatives contains a polyalkylene chain having randomly distributed functional groups. The polyalkylene chains are preferably polybutadiene chains, polyisopropyl chains and polypropylene chains.

The functional groups which are randomly distributed on the polyalkylene chain are preferably reactive groups, in particular selected from the group of anhydrides, thiols, epoxides or primary amines.

More preferably, it is a polymer containing a maleic anhydride group randomly bonded to a polybutadiene chain. The preferred maleic anhydride adduct on 1,4-cis-polybutadiene is sold under the name "Polyvest" by the company Degussa.

In addition, the polyoxymethylene system can be used as a water-insoluble adhesion promoter, for example, a polyoxymethylene system selected from the group consisting of a building block of acetic acid (Basilikon) (acetic acid system).

These organopolyoxane mixtures, also referred to as "cold vulcanized one-component polyoxyxene rubbers", are typically crosslinked into a rubber elastic polymer at room temperature in the presence of water from the surrounding environment. Using a difunctional and preferably higher functional ethoxy decane compound as a chain extender and a crosslinking agent, such ethoxy decane compounds The formation of a macromolecular network is caused by reaction with polyoxyalkylene or by dissociation of acetic acid by hydrolysis.

In principle, a polyoxyl system based on an amine/amineoxy system, a hydrazine system, a benzamidine system and an alkoxy system can also be used as an adhesion promoter, and only these systems can be used as an additional system as described herein. The ingredients are stabilized into a homogeneous, stable mixture.

In addition, olefin homopolymers and copolymers of two or more olefins, which are partially oxidized or further functionalized with grafted molecules, can be used as adhesion promoters. For example, polybutadiene rubbers, styrene-butadiene-block polymers and copolymers, and polyisopropylenes are such compounds as long as they are partially oxidized or further functionalized by grafting molecules. It is also possible to use "arbitrary (block) polymer" (made by 1,3-addition of butadiene or isoprene on styrene or alpha methylstyrene), homopolymerization of ethylene and propylene Or copolymers (such as ethylene-propylene diene-terpolymer, ethylene-ethylene oxide-copolymer), natural rubber and norbornene polymers (such as polydicyclopentadiene), as long as they are partially oxidized Or further functionalized by the grafted molecule.

Copolymers selected from the group consisting of poly(methyl vinyl ether/carboxylic anhydride monoalkyl ester groups) can also be used as water-soluble adhesion promoters, which are sold, for example, by the ISP company under the trade name "Gantrez". .

Another preferred class of water-soluble adhesion promoters is a polyalkylenimine, a polymeric amine or a polyimine-containing polymer. The class of polyimine specifically contains the formula -(R-NH) _n - (R = alkyl or alkyl derivative, n = 10-10 ⁵ ) and two-dimensional or three-dimensional cross-linking by nitrogen functional group Homopolymerized polyalkyleneimine (depending on the degree of alkylation or degree of arylation on the nitrogen).

A preferred class of polyalkylenimines are polymeric spherical polyalkylenimines, the basis of which is the specific proportion of homopolyethylene present between the primary, secondary and tertiary amine functional groups. This polyethyleneimine can be quaternized with water or acid to produce a polycation.

Of course, the polyethyleneimine may also contain a methylene group, a propenyl group, a butenyl group or a higher alkylene group as an alkylene group in addition to a vinyl group.

Polyalkylenimine is supplied by BASF under the trademark "Lupasol" and different molar masses and cross-linking degrees.

The polyalkyleneimine can in principle also be present in the form of derivatives and/or cationic polymers.

Polyalkylenimine is soluble in water and other polar solvents.

The polyimine can also be used in alkoxylated, especially in ethoxylated or propoxylated form.

A water-soluble polyetheramine (alkoxylated amine) can also be used as an adhesion promoter.

Particular reference is made to ethoxylated or propoxylated primary and/or secondary and/or tertiary alkylamines or arylamines. The alkyl or aryl group can be branched to form (formally) a di-, tri-, oligo- or poly(EO/PO)-amine. Alkoxylated polyamines undergo typical amine reactions with other functional groups (ammonium, urea analog, carbonyl group imidization, etc.).

The alkoxylated polyamine is preferably selected from the group of polyetheramines. These polyetheramines may contain trifunctional, difunctional and/or monofunctional primary amines, and as polyether groups may contain polyethylene oxide groups, mixed poly(ethylene oxide/propylene oxide) groups or polyoxypropylene groups. a base in which the hydrophilicity of the polyetheramines is reduced in this order. The alkoxylated amine may of course also contain other polyether groups, such as polyoxybutylene groups.

A polyamine amine containing a diamine or a polyether amine containing a secondary amine can also be used.

Polyetheramines are sold, for example, by the company Fa. Huntsman, Inc. under the trademark "Jeffamine ^® T-5000".

The molar mass of the polyetheramine can vary over a wide range. Polyetheramines having a molar mass between 500 and 5000 are used within the scope of the invention.

In view of the small viscosity of the alkoxylated amine, the adhesion carrier of the present invention must be added with a viscosity-increasing substance in the form of a substance, such as a powdered surfactant, a polysaccharide (wood flour, starch, wheat flour), lignin. Wait.

In addition, an ethoxylated polyamine (ie, a system obtained by ethoxylation of a polyamine) conforming to the following chemical formula can also be used as the polyamine derivative:

Wherein R ₁ = alkyl or alkyl derivative, R ₂ , R ₃ = (-CH ₂ -CH ₂ -O) _n -R ₄ or (-(CH ₂ ) ₃ -O) _n -R ₄ ,R ₄ = H, alkyl, aryl, n = 1 - 100.

A compound obtained by reacting on a nitrogen functional group can also be used as a polyamine derivative such as a polyurethane derivative or the like, that is, R ₂ , R ₃ =C(O)-NX, X=copolymer, For example, a polyurethane, that is, a pendant group (Seitenrest) is again hung on the polymeric chain of the above formula (1) (the imine can be regarded as a quasi-copolymer of a block polymer).

According to the invention, polyglycerol polyether alkyl carboxylic acids can also be used as water-soluble adhesion promoters. Polyglycerol polyether alkyl carboxylic acid is a polyalkyl ether carboxylic acid esterified by glycerol, such as polyethylene glycol-150-polyglyceryl-2-tristearate or PEG-150-diglycerol Base-tristearate or PEG-150-tetraglyceryl- The distearate wherein PEG-150-polyglyceryl-2-tristearate is preferred.

The polymer consists of a polyglyceryl-spiral (Rückgrad) with a fatty acid group attached to it via a flexible chain.

The thickening effect may be based on the combined interaction of the fatty acid groups of PEG-150-polyglyceryl-2-tristearate with the surfactant micelles within the formulation. By physical interaction, a three-dimensional network can be formed which has an increased viscosity in an aqueous surfactant system, such as a flushing process in a toilet. The structure of the polymer (ie, the polarity of the fatty acid group (C chain length)), the length of the flexible spacer chain (the degree of ethoxylation of the PEG), and the structure of the spine (the number of glycerol units) are increased Thick properties have an effect.

It is of course also possible to apply the combination of the above adhesion promoters to the adhesive carrier of the present invention.

The reactivity must also be considered when selecting an adhesion promoter. It is within the scope of the present invention that highly reactive polymeric host compounds (e.g., reactive polyoxynitrides) should not be used as adhesion promoters because such polymeric leading compounds will continue to polymerize and become increasingly viscous. The polyurethane-based system or the system comprising the epoxide-containing lead compound also reacts too quickly and becomes viscose when mixed. These systems have only minimal stickiness or no stickiness at all.

The adhesion promoter causes the adhesive carrier to adhere to the surface of the toiletries. The adhesive carrier of the present invention can be attached to a dry surface or to a wet surface.

In addition, the special adhesion promoter can also be used to apply the adhesive carrier The surface is viscous whereby other effective adhesive carrier agents can be adhered to the surface of the adhesive carrier.

The adhesion promoter also generally produces a network-like structure which allows the adhesive carrier to have the necessary shape stability even under the extreme force of the rinsing water.

The concentration of the adhesion promoter depends on the material type and network formation ability of the adhesion promoter, and is usually between 2 wt% and 60 wt%, preferably between 7 wt% and 50 wt%, and particularly preferably between 8 wt%. Between 40% by weight.

Further, the adhesive carrier of the present invention comprises an active substance which may be selected from the group consisting of surfactants, thickeners, fragrances, dyes, salts, foam stabilizers, foam stabilizers, foaming agents, and polymerization. Natural substance.

In principle, it is possible to use all customary anionic surfactants and/or cationic surfactants and/or nonionic surfactants and/or amphoteric surfactants, of which powdered to hard pasty surfactants are preferred. selected. The surfactant portion of the adhesive carrier should be between 0 wt% and 80 wt%, preferably 10 wt% to 60 wt%, and more preferably 25 wt% to 45 wt%.

Anionic surfactants have a variety of functions in the present invention; first, when the polymer matrix is water-insoluble, the anionic surfactant emulsifies the polymer matrix without destroying the viscosity. Secondly, an anionic surfactant as a tackifier (thickener) also has the effect of plasticizing the initial polymer (adhesion). Preferably, the anionic surfactant should also have a strong foaming effect to produce a visual cleansing effect in the toilet. Finally, such surfactants should also have good cleaning benefits supported by good wetting characteristics.

Preferably, one or more selected from the group consisting of a carboxylate, a sulfuric acid half ester, and a sulfonic acid, preferably selected from the group consisting of a fatty acid, an aliphatic alkyl sulfuric acid, and an alkyl aryl sulfonic acid, is used as an anionic surfactant. Agent. These anionic surfactants have a carbon chain distribution ranging from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms, specifically from 12 to 22 carbon atoms.

A metal salt (preferably an alkali metal salt) and a carboxylic acid (C6-C22) in the form of a natural or synthetic mixture, and an alkali metal salt of a sulfuric acid half ester and a long-chain alcohol can also be used as the anionic surfactant.

Another class of anionic surfactants useful in the present invention are the alkali metal salts of alkyl ether sulfates. The alkyl ether sulfuric acid is synthesized in the same manner as the alkyl sulfuric acid by a fatty alcohol, and the fatty alcohol is reacted with ethylene oxide to form the corresponding ethoxylated fatty alcohol. Instead of ethylene oxide, propylene oxide can also be used. Subsequent sulfonation produces alkyl ether sulfuric acid.

Alkali metal salts of alkane sulfonic acids and olefin sulfonic acids can also be used as anionic surfactants within the scope of the present invention. The alkanesulfonic acid may have a sulfonic acid group in a terminal bond (primary alkanesulfonic acid) or a C chain (secondary alkanesulfonic acid). A typical representative is an alkylbenzene sulfonate, more preferably a linear alkylbenzene sulfonate (LAS).

The above anionic surfactants may be used singly in their neutral form or in combination with each other.

Within the scope of the invention, the surfactant phase preferably comprises from 10% to 90% by weight of lauryl sulfate, more preferably from 40% to 85% by weight of lauryl sulfate, based on weight.

Adhesive carrier containing a low adhesion promoter based on butadiene derivatives Among the agents, the anionic surfactant also acts as a thickener.

Alkoxylated alcohols, preferably ethoxylated alcohols, in particular, primary alcohols having preferably from 8 to 18 carbon atoms and having an average of from 1 to 12 moles of ethylene oxide (EO) per mole of alcohol are used. a nonionic surfactant in which the alcohol group may be a linear or preferably a methyl group at the 2-position or a linear group and a methyl branch in a mixed state such as an oxy-ol group. base. But an alcoholic ethoxy group containing a linear group of natural alcohols having a carbon number of 12 to 18 (for example, cocool, palmitolol, tallow or oleyl alcohol) and an average of 2 to 8 moles of EO per mole of alcohol. The compound is preferred. In addition to these nonionic surfactants, fatty alcohols of 12 EO or more can also be used. For example, 14 EO, 25 EO, 30 EO or 40 EO of animal fatty alcohol.

Further, an alkyl glycoside of the formula alkyl-O(G) can also be used as the nonionic surfactant, wherein "alkyl" represents a primary one having 8 to 22, preferably 12 to 18 carbon atoms. A straight-chain aliphatic or methyl-branched (specifically, 2-methyl-branched) aliphatic group, and G represents a glycoside unit having 5 or 6 carbon atoms, preferably representing glucose.

Another preferred class of nonionic surfactants useful in the present invention are alkoxylated fatty acid alkyl esters preferably having from 1 to 4 carbon atoms in the alkyl chain, preferably ethoxylated fatty acid alkyl groups. Ester or ethoxylated and propoxylated fatty acid alkyl esters, in particular fatty acid methyl esters, these nonionic surfactants may be used alone or in combination with other nonionic surfactants. Amine oxides can also be used as nonionic surfactants, such as N-cocoalkyl-N,N-dimethylamino oxide and N-tallow alkyl-N,N-dihydroxyethylamine oxide Or an alkanolamine.

The or nonionic surfactant may be present in the total surfactant phase in an amount of up to 50%, preferably up to 30%, and especially up to 25%.

If desired, the surfactant phase may also be provided with a cationic surfactant or an amphoteric surfactant or a zwitterionic surfactant. For example, the amphoteric surfactant can be provided with a fatty acid guanamine propyl betaine having a C5-C12 fatty acid content, and of course an amphoteric diacetate.

Cationic surfactants are preferably used in combination with bactericidal materials in an acidic formulation. The zwitterionic surfactant can be exemplarily described as a quaternary ammonium component, a cerium component or a cerium component by an aliphatic bridge with an other anionic group (eg, a carboxyl group, a sulfonate, a sulfate, a phosphate or a phosphine). Acidate) connected.

An alkenyl sulfonate, an ether sulfate or an acid methyl taurine (Säuremethyltaurid) used as a foaming agent can be continuously added to the adhesive carrier. If a strong blowing agent is to be used, preferably from 1% to 50%, in particular 1-25%, of the surfactant may be replaced by one or more selected from, for example, a betaine group, alkoxylated. A foaming agent of the alkyl ether sulfate group or the lactobionic acid derivative group. Such a foaming agent may be an alkali metal salt or ammonium having a C5-C21 fatty acid content of a fatty acid guanamine propyl betaine (for example, cocoamidopropyl betaine), a lauryl ether sulfate having 1 to 5 EO. Salt, lactose cocoamine (Lactobionococoylamid), lactose decylamine, lactose tallowamine, and the like, and mixtures thereof. These foaming agents are well incorporated into the pair of pressure sensitive adhesive carrier agents. It is preferred to use a co-surfactant in the form of a solid, preferably powder or high viscosity.

In addition to the ingredients of the present invention, the adhesive carrier may contain other commonly used ingredients such as salts, bactericides (such as oxygen or chlorine gas release agents), preservatives (eg, Such as isothiazolinone derivatives), foam stabilizers (such as alkanolamines), hydrophobic agents (such as mineral oil or (partially methylated) decane and decane), calcium dispersants (such as polycarboxylic acids) Sodium salt) or dye.

The adhesive can also be used in aromatic indoor air by the addition of perfume oil or fragrance.

Various aromatic compounds such as synthetic products of aldehydes, alcohols, esters, ethers, ketones and hydrocarbons can be used as perfume oils or fragrances. The ester aromatic compound is, for example, benzyl acetate or benzyl formate. The ethers are benzyl ethyl ether, the aldehydes are citronellal, the ketones are α-isomethylionone, and the alcohols are citronellol, eugenol, geraniol and linalol. Hydrocarbons are mainly terpenoids such as limonene and terpenes. However, it is preferred to use a mixture of different fragrances to produce the desired aroma. These include perfume oils containing a mixture of herbal natural fragrances such as pine oil, citrus oil, lavender oil, peppermint oil or orange peel oil.

The fragrance is added directly to the formulation at a concentration of between 0.25 wt% and 20 wt%, preferably between 3 wt% and 15 wt%, and more preferably between 5 wt% and 10 wt%.

If necessary, a salt acting substance such as sodium sulfate may also be added to the formulation to increase the dissolution rate. A salt content of up to 90% by weight can greatly reduce the cost of the product. The salt content is usually as high as 10% by weight, preferably as high as 5% by weight. A strong acid alkali metal salt such as sodium sulfate, sodium chloride or sodium polyphosphate is a suitable salt. Alkali metal salts of monocarboxylic acids, dicarboxylic acids and polycarboxylic acids and alkaline earth metal salts of strong acids (such as calcium sulfate) or carbonates of carbonates can also be used.

The use of a calcium salt improves the durability of the adhesive carrier because the calcium salt is based on the polybutadiene derivative and the maleic anhydride of the adhesion promoter. Together with the formation of the poly soap, the poly soap has a hydrophobic effect and stabilizes the entire system on the surface in the case of forming a calcium soap network, thereby resisting the scouring property.

When the adhesive carrier is subjected to an excessively strong hydrophobic action due to the formation of calcium polyseifen, a calcium soap dispersant such as amphoteric dipropionate may be added to the adhesive carrier to improve the scouring property. (Lonza KL type) or maleic acid / acrylic acid - copolymer - sodium salt (BASF company Sokalan series, such as Sokalan CP5 or CP45).

Any dye-acting substance which has no direct directness to the surface to be treated with the dye may be added to the adhesive carrier. If a water-soluble dye is used in the formulation and the formulation is contacted with water as a finished product (e.g., flushing the toilet with water), a favorable color elevation can be obtained, which is also associated with marketing-argumenten. For example, a slow blue dyeing process (light blue to dark blue) can indicate that the active ingredient is slowly acting until it reaches its optimum activity.

Similarly, the adhesive carrier may be adjusted to be acidic to contain, for example, a substance capable of dissolving limestone scale or urinary scale (acid) as an active substance.

Further, a (co) thickener may be added to the adhesive carrier of the present invention in order to increase the plasticity of the adhesive carrier. For example, a bentonite, a powdered surfactant, a triterpene, a polybutadiene rubber, a polyisopropene, a block copolymer (containing oligo- or polyethylene oxide and/or oligo- or A crosslinked oligomer composed of propylene oxide and/or oligo- or polyoxybutylene) and an aryl ethoxylate or alkylaryl ethoxylate are used as the (co) thickener. Polymeric natural substances such as lignin or its alkali metal or alkaline earth metal salts can also be used as (co) thickeners.

Hydrophilic Sanxian gum is a preferred class of (co) thickeners. Use hydrophilic three The gum can produce a highly hydrophilic compound in the adhesive carrier, and when the adhesive carrier is adhered to a wet surface, the compound "absorbs" the surrounding moisture.

Furthermore, it is also possible to add to the adhesive carrier an active substance in the form of a hydrophobic agent, for example, aerosolized cerium oxide (Aerosil), in particular completely methylated smouldering cerium (Fa. Carbot Carbon).

If it is desired to accelerate the adhesion rate, an action substance in the form of a tackifier may be added to the adhesive carrier, in particular, a hydrocarbon resin, a natural resin (such as a taro oil rosin or a fragrant resin) or a polydecene resin. Adhesive.

In order to remove odor, the adhesive carrier may contain a deodorant, and such deodorants are preferably added to the fragrance. Such deodorants are disclosed, for example, in US 7,288,507 B2.

When the adhesive carrier of the present invention is applied and replaced, it does not come into contact with the unclean equipment connected to the toilet sink, so the application method is very hygienic.

A major advantage of the adhesive carrier of the present invention is that the adhesive carrier can be dispensed for use by the user and/or provided in a variety of different packaging. For example, administration of the adhesive carrier can be accomplished by a syringe or by a suitable amount of equipment in a pre-dispensed amount. Such applicator devices can be, for example, "clamp systems", clamps or film tear sheets, application systems with pull-on elements that can place a corresponding portion of the adhesive carrier on the ceramic surface.

The adhesive carrier of the present invention can also be applied to different locations of the toiletries simultaneously in a simple manner so that a plurality of effective adhesive carrier agents (e.g., aromatic tablets and bleached tablets) can be used in close proximity.

The adhesive carrier agent also achieves an excellent adhesion on the vertical surface of the toiletries, and the adhesive carrier does not fall off even with the additional force of the rinse water.

The adhesive carrier of the present invention is washed away after relatively multiple flushes. The number of rinses depends on the composition of the adhesive carrier used, the amount applied, and the geometry of the adhesive carrier used. In the case of applying a thickness of 2 mm to 5 mm, the number of rinses that can be washed away by the adhesive carrier is usually between Between 50 and 150 times, the specific statement is more than 120 times.

If the adhesive carrier is used as an adhesive in a toilet, the durability of the adhesive carrier depends mainly on the rinsing resistance time of the other adhesive carrier (block-like carrier) to which it is applied. In the case of a conventional toilet cleaning block, the durability can be achieved from 100 to 200 rinses, and in some cases up to 250 cycles, during which the adhesive carrier is gradually washed away with the attached material. . The application amount is from 3% by weight to 15% by weight, in particular, from 5% by weight to 10% by weight, based on the mass of the adhesive carrier agent.

The adhesive carrier of the present invention is preferably white, in the form of a paste, a paste and/or a milk, and has a stable shape, so that the adhesive carrier does not "fall" or "drop".

The adhesive carrier retains its attached state and shape even when subjected to a large force (friction, deformation, shearing effect) caused by the flushing process.

The adhesive carrier exhibits pseudoplasticity, that is, the viscosity becomes smaller as the shear force increases. However, if the shear rate is low, a very strong current limiting effect can be observed; in addition, the viscosity curve exhibits a local maximum at the shear rate deceleration stage between 2.5 s ^-1 and 30 s ^-1 . Obviously, the adhesive carrier has a different viscosity range, or the adhesive carrier will change its structure for a shorter measurement time (100 seconds of deceleration time).

The adhesive carrier should have a viscosity of at least 30 Pa s at a shear gradient of 2.62 s ^-1 and 20 ° C using a Haake viscometer, a plate/plate system of 10 mm, preferably at least 30 Pa s. 45Pa s, especially preferably at least 100Pa s. Preferably, the viscosity should be between 150 Pa s or between 300 Pa s and 6000 Pa s, and more preferably between 200 Pa s and 1000 Pa s or between 1000 Pa s and 4000 Pa s.

The surfactant-containing adhesive carrier of the present invention preferably produces a fine blister foam which can be adjusted by a suitable additive (foaming agent). The number of bubbles of the adhesive carrier of the present invention should exceed 40 ml. The preferred number of bubbles should be >60ml, and the preferred number of bubbles should be 140ml or more than 200ml.

The surface tension of the adhesive carrier may be between 50 mN/m and 65 mN/m. Preferably, the surface tension of the adhesive carrier is <= 60 mN/m. The surface tension of the preferred carrier agent should be less than or equal to 40 mN/m. Surface tension is a standard used to measure the wettability of a surface. The smaller the surface tension, the easier the surface will wet. A good wetting effect is a prerequisite for the good cleaning ability of the adhesive carrier.

The adhesive carrier of the present invention is prepared by agitating the ingredients together at room temperature.

The invention will now be illustrated by means of various specific examples and experiments.

Table 1 attached at the end of the description of the invention collectively shows various formulations of the adhesive carrier of the present invention.

The number of rinses in Table 1 was determined on an application rate of 2-5 g.

Table 2 attached at the end of the description of the invention gives the starting materials for the preparation of the adhesive carrier of the present invention as listed in Table 1.

All of the adhesives of the formulations V13 to V38 of the present invention have excellent adhesion, and the adhesiveness of the outer surface thereof can be adhered to a conventional toilet cleaner having a quality of up to 50 g depending on the amount of the specific adhesive. Wherein, the ratio of the adhesion quality of the bulk adhesive carrier to the mass of the adhesive is at most 100:1, preferably at most 50:1, and most preferably at most 10:1. Of course, if the adhesion area is increased, the adhesion effect of the adhesive carrier can be improved. Commonly used adhesive areas are between 1000mm ² and 800mm ² (complete contact). If the adhesive is applied in a strip shape, the adhesion area may be less than 400 mm ² .

In all tests in which the adherent carrier agents were successfully washed away, the surfactants used were all anionic surfactants. The number of rinses that such adhesive carrier agents can withstand indicates that these adhesive carrier agents have a relatively high to high durability.

V20 is a formulation for preparing an acidic adhesive carrier. The adhesive carrier can be subjected to less rinsing times, possibly due to the small pH value and the inability to form a calcium soap which increases the number of rinsings.

V23a, V29 and V30 contain only (anionic) surfactants and adhesion promoters. The adhesive carrier consisting of only two components also has the desired adhesion, the necessary viscosity, and the number of rinses of more than 100 times.

Compared to this, the pure adhesion promoter Polyvest 800 S (1,4-cis-butadiene cis Butene anhydride adducts -- a low-viscosity product -- will flow down immediately after application on the toilet, with no adhesion. Traditional toilet cleaning blocks with a mass of 50g, 30g, 10g, and 5g cannot be adhered to this pure adhesion promoter Polyvest. The bulky adhesive carrier immediately fell off; no adhesion was observed.

Table 3 attached at the end of the description of the invention gives the results of various adhesion tests carried out using the adhesive carrier of the present invention as listed in Table 1.

When performing these adhesion tests, a given amount of an adhesive carrier (adhesive) is applied to the back side of the sample so that it can be firmly adhered by adhesion, or a thickness is applied to a surface area of the sample by a doctor blade. It is 2-4 mm of the adhesive.

The sample was then directly adhered to a ceramic toilet. The sample is typically adhered to the wet front surface of the toilet with less pressure. The adhesive and the sample are immediately in standby and can be rinsed directly.

The tests listed in Table 3 show that the adhesive carrier containing the adhesion promoter Polyvest (1,4-cis polybutadiene-maleic anhydride adduct) of the present invention can be attached not only to sanitary articles, but also The stickiness can also adhere to toilet cleaning blocks, descaling tablets, transparent soap systems, and the like.

If the adhesion properties of the system of the present application are compared to those disclosed in WO 99/66017, it will be found that the latter does not impart any stickiness to the samples listed in Table 3.

Immediately after attempting to attach a commonly used toilet cleaning block to the surface of the gel disclosed in WO 99/66017, the toilet cleaning block will immediately fall under the force of gravity. That is, the gel does not have a long-lasting adhesive effect.

According to the Applicant's hypothesis, the Polyvest-based adhesive carrier of the present invention has good adhesion characteristics, on the one hand, in that there is a random distribution of maleic anhydride groups, and these maleic anhydride groups can be used. The surface of the support chemically exerts a binding effect on the functional groups (reactive adhesive); on the other hand, this effect may also continue inward, and such maleic anhydride groups may be related to functional groups in the structure (eg, The nucleophilic group of the surfactant and the co-thickener reacts (cohesive effect) to form a structure of the gannon-like resin having a strong degree of swelling.

The starting material is already a pressure sensitive adhesive in pure form and remains viscous for a long time (until the reactive group hardens). However, without a surface active ingredient, it is impossible or difficult to remove such a pure adhesive from the ceramic surface.

The cohesive effect of the maleic anhydride functional group should be enhanced in the long chain fat pure or long chain PEG system (Polyox WSR 303) included in the formulation.

The test V22 conducted in combination with the V2 blocker first illustrates the above interaction (Table 3). In the case of a very small sample, the V2 block formulation can achieve more than 460 flushes.

In addition to the cross-linking process, the fact that calcium ions form poly soaps also plays an important role in this formulation, which enhances the hydrophobicity of the overall system, thereby increasing the difficulty of dissolving the system in water.

In addition, the Sanxian gum used also has an effect of increasing adhesion. The rapid formation of the hydrocolloid causes rapid dehydration of the surface upon contact with the aqueous surface within the toilet system. Thereby, the adhesive can quickly interact with other types of pseudo-dried ceramic surfaces (eg, adhesive interactions).

As a result of all of the above interactions, these adhesion compounds will adhere to the ceramic surface for a relatively long period of time even if they are washed by water flow. The surprising reason for this is that the rinsing water should be such that the surfactant-containing adhesive carrier (having a good wetting rate) is displaced during the rinsing process, causing it to fall off the ceramic.

In the present system, it may even occur that the adhesive or the second component adhered to the adhesive is corroded from the outside to the inside.

Table 4 attached to the end of the description of the invention exemplarily shows the number of bubbles and surface tension of the partially adherent carrier agent of the present invention as listed in Table 1.

Table 4 shows that the adhesive carrier of the present invention is significantly different from the conventional adhesive carrier disclosed in EP 1325103 B1. In other words, the present adhesive carrier is a significantly better foaming agent.

When the number of bubbles was measured, 100 ml of the mother liquid adjusted to 20 ° C was introduced into a 250 ml volumetric flask, and the volumetric flask was closed with a PTFE base. The volumetric flask was then turned back and forth twenty times (inverted 20 times). The resulting foam volume (ml) was read and recorded after 30 sec/5 min/30 min, respectively.

The surface tension was measured using a BP 2 bubble pressure gauge from Fa. Krüss.

The blank test value was examined as follows: A 0.1% solution was prepared using Ufaryl DL 90 C, and three measurement curves were recorded at 20 ° C by a capillary diameter measured in advance, and the average value was obtained. The allowable deviation from the mean is at most 1 mN/m.

The initial test was taken as the initial value, and all the successive tests were compared with the initial value (50/100/500 ms). When the deviation is greater than ±2mN/m, replace the capillary tube.

At the time of measurement, a 0.1% solution (20 ° C) was measured for the surface tension associated with its surface age. The surface tension was observed after 100 ms, 500 ms, and 1000 ms, respectively.

The listed in Table 5 are the various formulations of the adhesive carrier of the present invention using polyalkylenimine as an adhesion promoter, and those listed in Table 6 are the adhesive carrier agents of the present invention to alkoxylate amines and poly Glycerol polyether alkyl carboxylic acids are various formulations of adhesion promoters.

* Applying with an applicator having a rectangular narrow opening, it is applied to a strip having a width of about 2 cm and a thickness of about 3 mm.

** Apply the adhesive carrier to the toilet cleaning block in an amount of about 10% of the weight of the toilet cleaning block. Subsequent carrier agent Adhere the toilet cleaning block to the surface of the bathroom.

Tensopol USP 94 is a surfactant (C12-C16 lauryl sulfate) supplied by Manro.

Marlinat 242/90T consists of C12-C14-alcohol-polyethylene glycol and propylene ether-(2EO)-sulfate, ethylene glycol triisopropoxide ammonium salt (Fa. Sasol).

Orange Fun is a spice, supplied by Givaudan.

Kelzan AS is a Sanxian gum (thickener/co-thickener) supplied by Kelco.

Genapol DAT is PEG-150 polyglyceryl-2-tristearate and PEG-6-mercapto/capric glyceride.

Lupasol SK is a liquid polyethyleneimine supplied by BASF with a molar mass of approximately 2,000,000. Lupasol P is a liquid polyethyleneimine supplied by BASF with a molar mass of approximately 750,000.

Emanon XLF is a glycerol polyether-7 caprylate/caprate ester supplied by Kao Corporation, S.A.

Jeffamine T 5000 is a polyetheramine supplied by Fa. Huntsman, USA, with a molar mass of approximately 5000 (triamine, reacted with propylene oxide and a triol starter, followed by amination of terminal hydroxyl groups). ).

Jeffamine ST-404 is a polyetheramine derivative with a molar mass of approximately 565, supplied by the company Fa. Huntsman, USA (a secondary amine variant, a secondary triamine. The amine end group reacts with a ketone (eg acetone), And was restored).

Cab-Osil is fine-grained tannic acid.

Arboform (water-soluble) supplied by Tecnaro, Ilsfeld, Germany, as a pellet, consisting of lignin polymers or lignin derivatives, biodegradable polyester, lignocellulose or wood fiber And natural resin (ie, aliphatic or aromatic ketones, alcohols, carboxylic acids, lactones and monomers, oligomers and polymeric polycyclics).

Hydriol® PGR is a polyglycerol ricinoleate.

All of the adhesive carrier agents tested in the present invention are excellently adhered/adhered to the dry surface, and are also excellently attached/adhered to the wetted surface.

The adhesiveness of the surface of the adhesive carrier may be adhered to a conventional toilet cleaner having a quality of up to 50 g or more depending on the amount of the specific adhesive. In all tests in which the adherent carrier agents were successfully washed away, the surfactants used were all anionic surfactants. The number of rinses that such adhesive carrier agents can withstand indicates that these adhesive carrier agents have a relatively high to high durability.

() () The surface tension was measured using a BP 2 bubble pressure gauge from Fa. Krüss.

The blank test value was examined as follows: A 0.1% solution was prepared using Ufaryl DL 90 C, and three measurement curves were recorded at 20 ° C by a capillary diameter measured in advance, and the average value was obtained. The allowable deviation from the mean is at most 1 mN/m.

The initial test was taken as the initial value, and all the successive tests were compared with the initial value (50/100/500 ms). When the deviation is greater than ±2 mN/m, replace the capillary.

At the time of measurement, a 0.1% solution (20 ° C) was measured for the surface tension associated with its surface age. The surface tension was observed after 100 ms, 500 ms, and 1000 ms, respectively.

The number of flushes was measured according to a predetermined schedule with a flushing capacity of 8 l per flush and a flushing frequency of 19 flushes per day. During a short rinse interval (eg between the third and fifth rinses), the rinse water temperature is between 13 ° C and 14 ° C during the longer rest period (eg in the nineteenth and first Between the rinses, the rinse water temperature is between 15 ° C and 16 ° C. The temperature of the rinse water is checked and recorded every working day.

Claims (42)

An adhesive carrier for acting substances, the adhesive carrier comprising at least one adhesion promoter or itself consisting of at least one adhesion promoter for carrying the active substance on a surface of a sanitary device for a long period of time The active substance comprises a surfactant, which can be directly applied to the sanitary article, and is attached thereto, and is washed away after relatively repeated washing, wherein the adhesive carrier contains the surfactant. a group of acting substances and an adhesion promoter, characterized in that the adhesion promoter is selected from the group of polyalkylene derivatives containing a polyalkylene chain having a randomly distributed functional group, or selected from poly/methyl vinyl groups. a copolymer of a monoalkyl ester group of diethyl ether/carboxy anhydride, an olefin homopolymer, and a copolymer of two or more olefins, wherein the olefin homopolymer and the olefin copolymer are partially oxidized or borrowed Further functionalized by a grafting molecule, and selected from the group consisting of polyalkylenimine (also in the form of alkoxylated), polyetheramine (alkoxylated amine), and polyglycerol polyether alkyl carboxylic acid Group or group containing such polymer groups Or derivatives, the viscosity of the adhesion of the carrier agent is at least 30 Pas, at a shear gradient of 2.62s ^-1 and at 20 ℃, using a Haake viscometer, plate / plate measuring system, plate diameter of 10mm, attached to the carrier The viscosity of the agent can adhere the bulk adhesive carrier to the toilet, wherein when the adhesion promoter is from the group of polyalkylenimine, the concentration of the surfactant is between 7 and 60% by weight, Wherein the surfactant portion in the adhesive carrier is between 10% and 60% by weight. The adhesive carrier according to claim 1, wherein the polyalkylene chain from the adhesion promoter of the polyalkylene derivative group is preferably a polybutadiene chain or a polyisopropyl chain. And polypropylene chain. An adhesive carrier according to claim 2, wherein the functional groups are anhydrides, thiols, epoxides or primary amines. The adhesive carrier according to any one of the preceding claims, wherein the polyalkylene derivative is a maleic acid containing a random bond bonded to a polybutadiene chain. An acid anhydride based polymer. An adhesive carrier according to claim 4, wherein the polyalkylene derivative comprises a maleic anhydride adduct on 1,4 cis-polybutadiene. An adhesive carrier according to claim 1 of the invention, characterized in that the adhesion promoter is derived from a group of partially oxidized or further functionalized olefin homopolymers and copolymers of two or more olefins The agent is selected from the group consisting of polybutadiene rubber, styrene-butadiene-block polymers and copolymers, polyisopropylene, "arbitrary (block) polymers" (by styrene or alpha methyl styrene) a homopolymer or a copolymer of ethylene and propylene (for example, ethylene-propylene diene-terpolymer, ethylene-ethylene oxide-made by adding 1,3-addition of butadiene or isoprene) Copolymer), natural rubber and groups of norbornene polymers (such as polydicyclopentadiene). The adhesive carrier according to the first aspect of the invention is characterized in that the adhesion promoter derived from polyalkylenimine is a homopolyalkyleneimine. An adhesive carrier according to claim 1, wherein the adhesion promoter is of the formula -(R-NH) _n - wherein R = alkyl or alkyl derivative, n = 10-10 ⁵ , nitrogen function There are two-dimensional or three-dimensional crosslinks on the base. The adhesive carrier according to claim 7, wherein the polyalkylenimine contains an alkyl group, a vinyl group, a methyl group and a carbon group. Alkenyl, butenyl or higher alkylene. The adhesive carrier according to the first aspect of the invention is characterized in that the polyetheramines are alkoxylated primary and/or secondary and/or tertiary alkylamines or arylamines. The adhesive carrier according to claim 1, wherein the polyetheramine contains a trifunctional, difunctional and/or monofunctional primary amine, and the polyether group contains a polyethylene oxide group and a mixed poly (Ethylene oxide/propylene oxide) group or polyoxypropylene group. The adhesive carrier according to claim 1, wherein the polyglycerol polyether alkyl carboxylic acid is selected from the group consisting of polyethylene glycol-150-polyglyceryl-2-tristearate or PEG. -150-Diglyceryl-tristearate or PEG-150-tetraglyceryl-distearate group. The adhesive carrier according to any one of claims 1 to 6 to 10, wherein the adhesion promoter is present in the adhesive carrier at a concentration of between 2% by weight and 60% by weight. The adhesive carrier according to claim 13, wherein the concentration is between 7 wt% and 50 wt%. The adhesive carrier according to claim 14, wherein the concentration is between 8 wt% and 40 wt%. The adhesive carrier according to any one of claims 1 to 5, wherein the adhesion promoter has a concentration in the adhesive carrier of between 15% by weight and 80% by weight, preferably 20% by weight. Between 70% and 70% by weight, particularly preferably between 30% by weight and 50% by weight. Such as the adhesive carrier of claim 16 of the patent scope, wherein: The concentration is between 20% and 70% by weight. The adhesive carrier according to claim 17, wherein the concentration is between 30% by weight and 50% by weight. The adhesive carrier according to any one of claims 1 to 3, wherein the active substances are selected from the group consisting of thickeners, fragrances, dyes, salts, foam stabilizers, Foaming agents, foaming agents and polymeric natural substances. The adhesive carrier according to claim 13 is characterized in that the surfactant portion in the adhesive carrier is between 25 wt% and 45 wt%. The adhesive carrier according to claim 20, wherein the surfactant portion is between 10% by weight and 60% by weight. The adhesive carrier according to claim 21, wherein the surfactant portion is between 20% by weight and 45% by weight. The adhesive carrier according to any one of the preceding claims, wherein the surfactant is in the form of a powder or a hard paste. The adhesive carrier according to any one of claims 1 to 3, wherein the surfactant is an anionic surfactant selected from the group consisting of a carboxylate, a sulfuric acid half ester, and a sulfonic acid. A group of long chain alcohols and ethoxylated fatty alcohols. The adhesive carrier according to claim 19, wherein the surfactant is a nonionic surfactant and is selected from the group consisting of an alcohol ethoxylate, an alkyl glycoside, and an alkoxylated fatty acid alkane. Group of base esters, amine oxides, and octanamines. The adhesive carrier according to claim 19, wherein the adhesive carrier comprises a concentration of between 0.25 wt% and 20 wt%. An adhesive carrier according to claim 26, wherein the concentration is between 3 wt% and 15 wt%. An adhesive carrier according to claim 27, wherein the concentration is between 5 wt% and 10 wt%. The adhesive carrier according to claim 13, wherein the adhesive carrier contains up to 90% by weight of a salt, and the salts are preferably selected from the group consisting of strong acids or monocarboxylic acids and dicarboxylic acids. And a group of alkali metal salts and alkaline earth metal salts of polycarboxylic acids. For example, the adhesive carrier of claim 29, wherein: The salt can be as high as 10% by weight. If you apply for the scope of patents, item 30 An adhesive carrier wherein the salt can be as high as 5% by weight. The adhesive carrier according to claim 13, wherein the adhesive carrier comprises a (co) thickener from the group consisting of: benton, powdered surfactant, triterpene, polybutadiene Diene rubber, polyisopropylene, block copolymers, aryl ethoxylates or alkylaryl ethoxylates or polymeric natural materials. The adhesive carrier according to any one of claims 1 to 3, wherein the adhesive carrier is a water-soluble/water-dispersible adhesive having a temporary attachment effect. Use of an adhesive carrier according to any one of claims 1 to 3, characterized in that the blockable composition can be adhered It is a traditional cleaning block with one or more phases, a cleaning block with an aromatic phase, a cleaning block containing bleach, a compressed tablet, a water-soluble or water-insoluble plastic containing an active ingredient, an aromatic tablet, and a solid aromatic condensation. Glue, bleached tablets, descaling tablets or powerful cleaning tablets. The adhesive carrier according to any one of the preceding claims, wherein the adhesive carrier comprises a cleaning action and/or an aroma action and/or a bleaching action and/or a dyeing action. additive. The adhesive carrier according to any one of the preceding claims, wherein the adhesive carrier is in the form of a paste, a paste and/or a milk, and has a stable shape. The adhesive carrier according to any one of the preceding claims, wherein the adhesive carrier has a surface tension of between 50 mN/m and 65 mN/m. The adhesive carrier according to claim 37, wherein the adhesive carrier has a surface tension of less than 60 mN/m. A toilet cleaning kit comprising at least one adhesive carrier according to any one of the preceding claims and one or more bulk compositions from the group: a cleaning block having one or more phases, having a fragrance Phase cleaning block, bleach-containing cleaning block, compressed tablet, water-soluble or water-insoluble plastic containing active ingredients, aromatic tablets, solid aromatic gel, bleached tablets, descaling tablets or strong cleaning tablets Agent. Use of an adhesive carrier according to any one of the preceding claims, which is used as a cold adhesive in the sanitary field, in particular for attaching objects to urinals, sinks or tiles, kitchens, restaurants Butcher In the slaughterhouse, cleaning equipment, or applied to/in the drain pipe or ditch, or paste is supplied to the bait to control pests, or used to attach to windows or house surfaces. The use according to claim 27, characterized in that the mass of the adhesive carrier applied to the object is from 3% by weight to 15% by weight based on the mass of the object. A method of preparing an adhesive carrier according to any one of the preceding claims, characterized in that the ingredients are stirred together at room temperature.