RU2018142763A - Двухкомпонентная не содержащая растворитель клеевая композиция, включающая инициируемый амином полиол - Google Patents
Двухкомпонентная не содержащая растворитель клеевая композиция, включающая инициируемый амином полиол Download PDFInfo
- Publication number
- RU2018142763A RU2018142763A RU2018142763A RU2018142763A RU2018142763A RU 2018142763 A RU2018142763 A RU 2018142763A RU 2018142763 A RU2018142763 A RU 2018142763A RU 2018142763 A RU2018142763 A RU 2018142763A RU 2018142763 A RU2018142763 A RU 2018142763A
- Authority
- RU
- Russia
- Prior art keywords
- polyol
- component
- adhesive composition
- amine
- isocyanate
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title claims 19
- 150000003077 polyols Chemical class 0.000 title claims 19
- 239000000853 adhesive Substances 0.000 title claims 10
- 230000001070 adhesive effect Effects 0.000 title claims 10
- 239000002904 solvent Substances 0.000 title 1
- 239000012948 isocyanate Substances 0.000 claims 8
- 150000002513 isocyanates Chemical class 0.000 claims 8
- 239000000758 substrate Substances 0.000 claims 8
- 150000001412 amines Chemical class 0.000 claims 6
- 238000000034 method Methods 0.000 claims 3
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 239000003292 glue Substances 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 claims 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 claims 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 claims 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 239000005058 Isophorone diisocyanate Substances 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- JGCWKVKYRNXTMD-UHFFFAOYSA-N bicyclo[2.2.1]heptane;isocyanic acid Chemical compound N=C=O.N=C=O.C1CC2CCC1C2 JGCWKVKYRNXTMD-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 125000005442 diisocyanate group Chemical group 0.000 claims 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 1
- HLJDOURGTRAFHE-UHFFFAOYSA-N isocyanic acid;3,5,5-trimethylcyclohex-2-en-1-one Chemical compound N=C=O.N=C=O.CC1=CC(=O)CC(C)(C)C1 HLJDOURGTRAFHE-UHFFFAOYSA-N 0.000 claims 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229920001610 polycaprolactone Polymers 0.000 claims 1
- 239000004632 polycaprolactone Substances 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920005906 polyester polyol Polymers 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims 1
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- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
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- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Claims (17)
1. Двухкомпонентная не содержащая растворитель клеевая композиция, включающая
изоцианатный компонент, сформированный для нанесения на первый субстрат, и содержащий по меньшей мере один изоцианат; и
полиольный компонент, сформированный для нанесения на второй субстрат, и содержащий по меньшей мере один инициируемый амином полиол, имеющий функциональность от 3 до 8 и гидроксильное число от 20 до 1000.
2. Двухкомпонентная не содержащая растворитель клеевая композиция по п. 1, отличающаяся тем, что по меньшей мере один изоцианат выбирают из группы, состоящей из гексаметилендиизоцианата («HDI») и его изомеров, изофорондиизоцианата («IPDI») и его изомеров, норборнандиизоцианата («NBDI») и его изомеров, тетраметилксилилендиизоцианата («TMXDI») и его изомеров, ксилилендиизоцианата («XDI») и его изомеров, толуилендиизоцианата («TDI») и его изомеров, дифенилметандиизоцианата («MDI») и их изомеров, их изоцианатных преполимеров и комбинаций двух или более из них.
3. Двухкомпонентная не содержащая растворитель клеевая композиция по п. 1, отличающаяся тем, что инициируемый амином полиол представляет собой продукт реакции C1-C6 алкиленоксида и амина.
4. Двухкомпонентная не содержащая растворитель клеевая композиция по п. 1, отличающаяся тем, что инициируемый амином полиол составляет от 0,5 мас.% до 20 мас.% клеевой композиции, в пересчете на общую массу клеевой композиции.
5. Двухкомпонентная не содержащая растворитель клеевая композиция по п. 1, отличающаяся тем, что полиольный компонент дополнительно содержит, по меньшей мере, один неинициируемый амином полиол, выбранный из группы, состоящей из сложного полиэфирполиола, простого полиэфирполиола, поликарбонатного полиола, полиакрилатного полиола, поликапролактонполиола, полиолефинового полиола, природного масляного полиола и комбинаций двух или более из них.
6. Двухкомпонентная не содержащая растворитель клеевая композиция по п. 1, отличающаяся тем, что стехиометрическое соотношение изоцианатного компонента к полиольному компоненту составляет от 3:1 до 1:1.
7. Способ получения ламината, включающий
равномерное нанесение изоцианатного компонента на первый субстрат, где изоцианатный компонент содержит, по меньшей мере, один изоцианат; и
равномерное нанесение полиольного компонента на второй субстрат, где полиольный компонент содержит по меньшей мере один инициируемый амином полиол, имеющий функциональность от 3 до 8 и гидроксильное число от 20 до 1000;
соединение первого и второго субстратов вместе, что приводит к смешиванию и реакции изоцианатного компонента и полиольного компонента с образованием клея между первым и вторым субстратами; и
отверждение клея для склеивания первого и второго субстратов,
где клей имеет вязкость, превышающую 10000 мПа-с (при 40°С), в течение 10 минут после соединения первого и второго субстратов вместе.
8. Способ получения ламината по п. 7, отличающийся тем, что инициируемый амином полиол представляет собой продукт реакции C1-С6 алкиленоксида и амина.
9. Способ получения ламината по п. 8, отличающийся тем, что алкиленоксид выбирают из группы, состоящей из этиленоксида, пропиленоксида, 1,2-бутиленоксида и комбинаций двух или более из них.
10. Ламинат, полученный согласно способу по п. 7.
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PCT/US2017/029296 WO2017196531A1 (en) | 2016-05-10 | 2017-04-25 | Two-component solventless adhesive compositions comprising an amine-initiated polyol |
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CN109415478A (zh) | 2019-03-01 |
JP6989527B2 (ja) | 2022-01-05 |
US20190177575A1 (en) | 2019-06-13 |
AR108329A1 (es) | 2018-08-08 |
BR112018072979A2 (pt) | 2019-02-26 |
EP3455273A1 (en) | 2019-03-20 |
RU2018142763A3 (ru) | 2020-06-04 |
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