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JP2011159518A - Battery and method of manufacturing battery - Google Patents

Battery and method of manufacturing battery Download PDF

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JP2011159518A
JP2011159518A JP2010020847A JP2010020847A JP2011159518A JP 2011159518 A JP2011159518 A JP 2011159518A JP 2010020847 A JP2010020847 A JP 2010020847A JP 2010020847 A JP2010020847 A JP 2010020847A JP 2011159518 A JP2011159518 A JP 2011159518A
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positive electrode
negative electrode
metal foil
current collector
strip
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Toshiyuki Itabashi
利幸 板橋
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Connection Of Batteries Or Terminals (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

【課題】 集電端子部に抵抗バラツキが生じ難く、また、活物質層が剥がれ難く、製造が容易な電池等を提供することを目的とする。
【解決手段】 リチウム二次電池100は、捲回型電極体120を備える。この捲回型電極体120を構成する正電極板121の正極金属箔集電体122の帯状端部122mは、その長手方向に断続的に延び、捲回された状態で径方向に互いに隣在する複数のスリット122hを有し、帯状端部122mのうち、スリット122hよりも幅方向外側に位置し、捲回された状態で径方向に互いに隣在する複数のスリット外側部122sを、寄せ集め互いに重ねて正極集電端子部122yを構成している。
【選択図】 図1
PROBLEM TO BE SOLVED: To provide a battery and the like that are less likely to cause resistance variation in a current collecting terminal part and that an active material layer is difficult to peel off and that can be easily manufactured.
A lithium secondary battery includes a wound electrode body. The strip-shaped end portions 122m of the positive electrode metal foil current collector 122 of the positive electrode plate 121 constituting the wound electrode body 120 extend intermittently in the longitudinal direction and are adjacent to each other in the radial direction in the wound state. And a plurality of slit outer portions 122s that are positioned outside the slit 122h in the width direction and are adjacent to each other in the radial direction in a wound state. The positive electrode current collecting terminal portion 122y is formed so as to overlap each other.
[Selection] Figure 1

Description

本発明は、長尺状の正電極板と長尺状の負電極板とを長尺状のセパレータを介して互いに重ねて軸線周りに捲回してなる捲回型電極体を備える電池、及び、この電池の製造方法に関する。   The present invention is a battery comprising a wound electrode body formed by laminating a long positive electrode plate and a long negative electrode plate with each other through a long separator and wound around an axis, and The present invention relates to a method for manufacturing this battery.

従来より、長尺状の正電極板と長尺状の負電極板とを長尺状のセパレータを介して互いに重ねて軸線周りに捲回してなる捲回型電極体を備える電池が知られている。正電極板は、正極金属箔集電体とこの上に形成された正極活物質層とからなり、負電極板は、負極金属箔集電体とこの上に形成された負極活物質層とからなる。このような電池では、捲回型電極体の軸線方向の一端側に、正極金属箔集電体のうち幅方向の端に位置して帯状をなす正極帯状端部を、セパレータから突出させて、この正極帯状端部と電池の正極外部電極部材とを電気的に接続している。また、この電池では、捲回型電極体の軸線方向の他端側に、負極金属箔集電体のうち幅方向の端に位置して帯状をなす負極帯状端部を、セパレータから突出させて、この負極帯状端部と電池の負極外部電極部材とを電気的に接続している。   Conventionally, a battery having a wound electrode body in which a long positive electrode plate and a long negative electrode plate are overlapped with each other via a long separator and wound around an axis is known. Yes. The positive electrode plate is composed of a positive electrode metal foil current collector and a positive electrode active material layer formed thereon, and the negative electrode plate is composed of a negative electrode metal foil current collector and a negative electrode active material layer formed thereon. Become. In such a battery, on one end side in the axial direction of the wound electrode body, a positive electrode band-shaped end portion that forms a band shape at the end in the width direction of the positive electrode metal foil current collector is protruded from the separator, The positive electrode belt-shaped end portion and the positive electrode external electrode member of the battery are electrically connected. Further, in this battery, the negative electrode band-shaped end portion which is located at the end in the width direction of the negative electrode metal foil current collector and is formed in a band shape on the other end side in the axial direction of the wound electrode body is protruded from the separator. The negative electrode belt-like end and the negative electrode external electrode member of the battery are electrically connected.

正極帯状端部(または負極帯状端部)と正極外部電極部材(または負極外部電極部材)との接続形態としては、次のようなものが知られている。
第1の従来技術として、図21にその要部を示す電池910が挙げられる。即ち、この電池910は、軸線BX周りに捲回された前述の形態の捲回型電極体911を有する。この捲回型電極体911の帯状端部913には、短冊状をなす多数の集電タブ915,915,…が接合されている。また、この電池910は、図示外の外部電極部材と電気的に接続する棒状のリード端子917を有する。
As a connection form between the positive electrode strip end portion (or negative electrode strip end portion) and the positive electrode external electrode member (or negative electrode external electrode member), the following is known.
As a first conventional technique, there is a battery 910 whose main part is shown in FIG. That is, the battery 910 includes the wound electrode body 911 having the above-described configuration wound around the axis BX. A large number of strip-like current collecting tabs 915, 915,... Are joined to the strip-shaped end portion 913 of the wound electrode body 911. The battery 910 has a rod-like lead terminal 917 that is electrically connected to an external electrode member (not shown).

集電タブ915,915,…とリード端子917とは、レーザ溶接や抵抗溶接により接続されている。具体的には、レーザ溶接により、図21に示すように、径方向に隣在する集電タブ915,915,…同士を、例えば3つずつ溶接部919で互いに接合すると共に、径方向の最内側に位置する集電タブ915及びその径方向外側に位置する集電タブ915を、リード端子917にレーザ溶接する。これにより、全ての集電タブ915,915,…同士が互いに接続されると共に、集電タブ915,915,…とリード端子917とが接続される。   The current collecting tabs 915, 915,... And the lead terminals 917 are connected by laser welding or resistance welding. Specifically, as shown in FIG. 21, the current collecting tabs 915, 915,... Adjacent to each other in the radial direction are joined to each other by, for example, three welds 919, as shown in FIG. The current collecting tab 915 located on the inner side and the current collecting tab 915 located on the outer side in the radial direction are laser-welded to the lead terminal 917. As a result, all the current collecting tabs 915, 915,... Are connected to each other, and the current collecting tabs 915, 915,.

また、第2の従来技術として、図22にその要部を示す電池920が挙げられる。即ち、この電池920は、前述の従来技術1と同様に、捲回型電極体911に多数の集電タブ915,915,…が接合されている。また、この電池920は、前述のリード端子917を有する。この電池920では、集電タブ915,915,…とリード端子917とは、金属ベルト921を用いたタガ締めにより接続されている。具体的には、図22に示すように、金属ベルト921で全ての集電タブ915,915,…及びリード端子917をまとめて束ねることにより、全ての集電タブ915,915,…同士を互いに接続すると共に、集電タブ915,915,…とリード端子917とを接続している。
なお、図21及び図22に示した電池910,920の他に、捲回型電極体に集電タブを接続する形態の電池に関連する従来技術として、下記の特許文献1,2が挙げられる。
Further, as a second conventional technique, there is a battery 920 whose main part is shown in FIG. That is, in the battery 920, a number of current collecting tabs 915, 915,... Are joined to the wound electrode body 911, as in the prior art 1 described above. The battery 920 has the lead terminal 917 described above. In the battery 920, the current collecting tabs 915, 915,... And the lead terminal 917 are connected by tagging using a metal belt 921. Specifically, as shown in FIG. 22, all the current collecting tabs 915, 915,... Are connected to each other by bundling all the current collecting tabs 915, 915,. .. And the current collecting tabs 915, 915,... And the lead terminals 917 are connected.
In addition to the batteries 910 and 920 shown in FIG. 21 and FIG. 22, the following Patent Documents 1 and 2 are given as conventional techniques related to a battery in which a current collecting tab is connected to a wound electrode body. .

特開平11−162521号公報JP-A-11-162521 特開2009−181812号公報JP 2009-181812 A

しかしながら、従来技術1(図21参照)では、レーザの出力を上げて、一度に溶接できる集電タブ915,915,…の個数を増やそうとすると、径方向に隣在する集電タブ915,915,…の個数が少ない部分では、集電タブ915,915,…に穴があくなどの不具合が生じ易くなる。この問題は、抵抗溶接を行う場合でも同様に生じる。このため、レーザの出力を抑えて、一度に溶接する集電タブ915,915,…の個数を少なくし(本例では前述のように3つずつ)、その分、溶接部919,919,…を増やすことで、前述のように、全ての集電タブ915,915,…とリード端子917を接合している。従って、溶接部919,919,…が非常に多くなり、コスト高となる。また、溶接部91,919,…を減らすために、集電タブ915,915,…の個数を減らすと、集電効率が低下するおそれがある。   However, in the prior art 1 (see FIG. 21), if the number of current collecting tabs 915, 915,... That can be welded at once is increased by increasing the laser output, the current collecting tabs 915, 915 adjacent in the radial direction are used. In a portion where the number of... Is small, problems such as holes in the current collecting tabs 915, 915,. This problem similarly occurs even when resistance welding is performed. Therefore, the number of current collecting tabs 915, 915,... To be welded at a time is reduced by suppressing the laser output (three in this example as described above), and the welds 919, 919,. As described above, all the current collecting tabs 915, 915,... Are joined to the lead terminals 917. Therefore, the number of welds 919, 919,. In addition, if the number of current collecting tabs 915, 915,... Is reduced in order to reduce the welded portions 91, 919,.

また、従来技術2(図22参照)では、集電タブ915の長さが短いと、最外周に位置する集電タブ915の軸線BXに平行な長さHkが小さくなり、金属ベルト921が帯状端部913から抜け易くなるため、最外周に位置する集電タブ915の軸線BXに平行な長さHkをある程度大きくする必要がある。このため、集電タブ915,915,…とリード端子917との接続部分の軸線BX方向の寸法が大きくなり、電池920も大型化するなどの問題がある。   In the prior art 2 (see FIG. 22), when the length of the current collecting tab 915 is short, the length Hk parallel to the axis BX of the current collecting tab 915 located on the outermost periphery is reduced, and the metal belt 921 is strip-shaped. In order to easily come off from the end portion 913, it is necessary to increase the length Hk parallel to the axis BX of the current collecting tab 915 located on the outermost periphery to some extent. For this reason, there is a problem in that the dimension of the connecting portion between the current collecting tabs 915, 915,...

そこで、従来技術1,2とは異なる形態の電池として、図23及び図24に要部を示す電池940を考案した。即ち、この参考形態に係る電池940は、前述の捲回型電極体911を有するが、この捲回型電極体911では、図23に示す帯状端部913を、寄せ集め互いに重ねることにより、図24に示す集電端子部941を構成している。この集電端子部941は、図示しないリード線を介して、外部電極部材としての蓋部材に電気的に接続している。   Therefore, a battery 940 whose main part is shown in FIGS. 23 and 24 has been devised as a battery having a different form from the prior arts 1 and 2. That is, the battery 940 according to this reference embodiment has the above-described wound electrode body 911. In the wound electrode body 911, the band-shaped end portions 913 shown in FIG. The current collecting terminal portion 941 shown in FIG. The current collecting terminal portion 941 is electrically connected to a lid member as an external electrode member through a lead wire (not shown).

このような形態の電池940は、従来形態1,2のような集電タブ915,915,…を有しないので、集電タブ915,915,…同士を接続する際に生じる前述の不具合や、集電タブ905,905,…を設けることによる前述のコスト高を無くすことができる。 しかしながら、この電池940では、集電端子部941内で帯状端部913同士の接触が一定ではなく、集電端子部941に抵抗バラツキが生じ易い。また、帯状端部913を寄せ集めて集電端子部941を形成する際に、捲回型電極体911にシワが生じ易く、活物質層が部分的に剥がれるおそれがある。   Since the battery 940 in such a form does not have the current collecting tabs 915, 915,... Like the conventional forms 1 and 2, the above-described problems that occur when the current collecting tabs 915, 915,. By providing the current collecting tabs 905, 905,..., The above-described high cost can be eliminated. However, in the battery 940, the contact between the strip-shaped end portions 913 is not constant in the current collecting terminal portion 941, and resistance variation tends to occur in the current collecting terminal portion 941. Further, when the current collecting terminal portion 941 is formed by gathering the band-shaped end portions 913 together, the wound electrode body 911 is likely to be wrinkled, and the active material layer may be partially peeled off.

本発明は、かかる現状に鑑みてなされたものであって、集電端子部に抵抗バラツキが生じ難く、また、活物質層が剥がれ難く、製造が容易な電池、及び、この電池の製造方法を提供することを目的とする。   The present invention has been made in view of such a current situation, and it is difficult to produce resistance variation in the current collecting terminal part, and the active material layer is not easily peeled off, and a battery that is easy to manufacture and a method for manufacturing the battery. The purpose is to provide.

上記課題を解決するための本発明の一態様は、正極金属箔集電体及びこの正極金属箔集電体上に形成された正極活物質層を有する長尺状の正電極板と、負極金属箔集電体及びこの負極金属箔集電体上に形成された負極活物質層を有する長尺状の負電極板とを長尺状のセパレータを介して互いに重ねて軸線周りに捲回してなる捲回型電極体であって、前記軸線方向の一端側に、前記正極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出すると共に、前記軸線方向の他端側に、前記負極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出してなる捲回型電極体、を備える電池であって、前記正極金属箔集電体の帯状端部及び前記負極金属箔集電体の帯状端部のうち、少なくとも一方の帯状端部は、その長手方向に断続的に延びると共に、捲回された状態で径方向に互いに隣在する複数のスリットを有し、この帯状端部のうち、前記スリットよりも前記幅方向の外側に位置すると共に、捲回された状態で径方向に互いに隣在する複数のスリット外側部を、寄せ集め互いに重ねて集電端子部を構成してなる電池である。   One embodiment of the present invention for solving the above problems is a positive metal foil current collector, a long positive electrode plate having a positive electrode active material layer formed on the positive metal foil current collector, and a negative metal A foil current collector and a long negative electrode plate having a negative electrode active material layer formed on the negative metal foil current collector are overlapped with each other via a long separator and wound around an axis. In the wound electrode body, on one end side in the axial direction, the strip-shaped end portion that is exposed and located at the end in the width direction of the positive electrode metal foil current collector has a spiral shape, From the separator, the strip-shaped end portion that is exposed and located at the end in the width direction of the negative electrode metal foil current collector forms a spiral shape on the other end side in the axial direction and protrudes from the separator. A battery comprising a wound-type electrode body that protrudes, the strip of the positive electrode metal foil current collector And at least one of the strip-shaped end portions of the negative electrode metal foil current collector, the strip-shaped end portions extend intermittently in the longitudinal direction and are adjacent to each other in the radial direction in a wound state. Among the strip-shaped end portions, a plurality of slit outer portions that are located on the outer side in the width direction than the slits and that are adjacent to each other in the radial direction in a wound state are gathered and overlapped with each other. It is a battery which comprises a current collection terminal part.

この電池では、上述のように、電極板を構成する金属箔集電体の帯状端部のうちスリット外側部を、寄せ集め互いに重ねて集電端子部を構成している。このため、従来技術1,2(図21,図22参照)のように、帯状端部に多数の集電タブを接続し、これらの集電タブ同士を溶接したり、タガ締めする場合に比して、捲回型電極体及び電池の小型化が可能である。また、集電タブを少なくした場合に生じる前述の集電効率が低下するおそれもない。更に、集電タブを接続する必要がなく、また、集電端子部の形成が容易であるので、電池を安価にすることができる。   In this battery, as described above, among the strip-shaped end portions of the metal foil current collector constituting the electrode plate, the slit outer portions are gathered together and overlap each other to constitute a current collecting terminal portion. Therefore, as in the prior arts 1 and 2 (see FIGS. 21 and 22), a large number of current collecting tabs are connected to the belt-shaped end portions, and these current collecting tabs are welded together or are tightened. Thus, the wound electrode body and the battery can be reduced in size. Further, there is no possibility that the above-described current collection efficiency that occurs when the number of current collection tabs is reduced is lowered. Furthermore, it is not necessary to connect a current collecting tab, and since the current collecting terminal portion can be easily formed, the battery can be made inexpensive.

また、参考形態(図23及び図24参照)のように、帯状端部にスリットを設けることなく、帯状端部を寄せ集めて集電端子部を形成する場合には、前述のように、集電端子部に抵抗バラツキが生じ易い。しかるに、この電池では、帯状端部に上述のスリットを設けているので、帯状端部(スリット外側部)を寄せ集めて互いに重ねた集電端子部に、抵抗バラツキが生じ難い。また、上述のスリットを形成してあることから、集電端子部を形成する際に、捲回型電極体のうち、スリットよりも幅方向(軸線方向)内側の部分に影響が生じ難いので、正電極板や負電極板において活物質層が剥がれる不具合を防止できる。
なお、「スリット」は、前述のように、長手方向に延びる形態を有するものであるが、直線状に限られない。例えば、スリットの端が幅方向の延びるコ字状や、波線状などとしてもよい。
Further, as in the reference embodiment (see FIGS. 23 and 24), when the current collecting terminal portion is formed by gathering the belt-like end portions without providing the slits at the belt-like end portions, as described above, Resistance variation tends to occur in the electric terminal portion. However, in this battery, since the above-described slit is provided at the belt-like end portion, resistance variation hardly occurs in the current collecting terminal portions that are gathered together and overlapped with each other. In addition, since the above-described slit is formed, when forming the current collecting terminal portion, it is difficult to affect the inner part in the width direction (axial direction) than the slit in the wound electrode body. The problem that the active material layer peels off in the positive electrode plate and the negative electrode plate can be prevented.
As described above, the “slit” has a form extending in the longitudinal direction, but is not limited to a straight line. For example, the end of the slit may be a U shape extending in the width direction or a wavy shape.

更に、上記の電池であって、前記正極金属箔集電体及び前記負極金属箔集電体の各々に、前記集電端子部を有する電池とすると良い。   Furthermore, it is preferable that the battery has the current collecting terminal portion in each of the positive electrode metal foil current collector and the negative electrode metal foil current collector.

この電池では、正電極板の正極金属箔集電体及び負電極板の負極金属箔集電体の各々に、前述した集電端子部を有するので、正電極板と負電極板の各々で、前述した作用効果を得ることができ、より信頼性が高く、製造が容易な電池となる。   In this battery, since each of the positive electrode metal foil current collector of the positive electrode plate and the negative electrode metal foil current collector of the negative electrode plate has the above-described current collecting terminal portion, in each of the positive electrode plate and the negative electrode plate, The above-described effects can be obtained, and the battery is more reliable and easy to manufacture.

更に、上記のいずれかに記載の電池であって、前記帯状端部は、前記スリットよりも前記軸線方向の内側に位置し、前記スリット外側部を寄せ集めて前記集電端子部を構成したことにより、前記軸線方向の外側に露出する露出部を有し、前記帯状端部に電気的に接続する導電性の導電部材であって、前記集電端子部に前記軸線に直交する方向から当接して、この集電端子部に電気的に接続する第1接続部と、前記第1接続部と導通し、前記露出部に前記軸線方向の外側から当接して、この露出部に電気的に接続する第2接続部と、を有する導電部材、を更に備える電池とすると良い。   Furthermore, in the battery according to any one of the above, the band-shaped end portion is positioned on the inner side in the axial direction with respect to the slit, and the current collecting terminal portion is configured by gathering the outer portion of the slit. And a conductive conductive member having an exposed portion exposed outside in the axial direction and electrically connected to the strip-shaped end portion, and is in contact with the current collecting terminal portion from a direction orthogonal to the axial line. A first connecting portion electrically connected to the current collecting terminal portion, and electrically connected to the first connecting portion, contacting the exposed portion from the outside in the axial direction, and electrically connected to the exposed portion. The battery may further include a conductive member having a second connection portion.

この電池では、第1接続部と第2接続部とを有する導電部材を用い、金属箔集電体の帯状端部のうち、集電端子部だけでなく、露出部においても、導電部材と電気的に接続している。このため、金属箔集電体の帯状端部と導電部材とを更に低抵抗で接続できるから、この導電部材を介して、低抵抗で外部に正電位や負電位を取り出し得る。   In this battery, a conductive member having a first connection portion and a second connection portion is used, and the conductive member and the electric member are not only in the current collector terminal portion but also in the exposed portion of the strip-shaped end portion of the metal foil current collector. Connected. For this reason, since the strip | belt-shaped edge part of metal foil electrical power collector and a conductive member can be connected by low resistance, a positive potential and a negative potential can be taken out with low resistance through this conductive member.

なお、導電部材の第1接続部と集電端子部との接続手法としては、例えば、溶接により両者を互いに接合する手法や、ハンダや導電性接着剤を用いて両者を互いに接合する手法、リベットやボルト及びナットを用いて両者を互いに接続する手法、金属ベルトを用いて両者を互いに接続する手法などが挙げられる。
また、導電部材の第2接続部と露出部との接続手法としては、例えば、溶接により両者を互いに接合する手法や、ハンダや導電性接着剤を用いて両者を互いに接合する手法、前述の軸線方向外側からの当接のみにより両者を接続する手法などが挙げられる。
In addition, as a connection method between the first connection portion and the current collecting terminal portion of the conductive member, for example, a method of bonding the two together by welding, a method of bonding the two together using solder or a conductive adhesive, rivet And a method of connecting them to each other using bolts and nuts, a method of connecting them to each other using a metal belt, and the like.
In addition, as a method of connecting the second connecting portion and the exposed portion of the conductive member, for example, a method of bonding the two together by welding, a method of bonding the two together using solder or a conductive adhesive, the above-described axis For example, a method of connecting the two only by contact from the outside in the direction can be given.

更に、上記の電池であって、開口を有し、前記捲回型電極体を収容する電池ケース本体と、前記電池ケース本体の前記開口を閉塞すると共に、この電池の外部電極をなす外部電極部材と、を有する電池ケースを備え、前記導電部材は、前記第1接続部から延び、前記外部電極部材に当接して、この外部電極部材に電気的に接続する第3接続部を有する電池とすると良い。   And a battery case body having an opening and accommodating the wound electrode body; and an external electrode member for closing the opening of the battery case body and forming an external electrode of the battery And the conductive member extends from the first connection portion, contacts the external electrode member, and has a third connection portion that is electrically connected to the external electrode member. good.

この電池では、導電部材が上述の第3接続部を更に有するので、電極板の帯状端部(集電端子部あるいは集電端子部及び露出部)と外部電極部材とを、この導電部材のみで電気的に接続することができる。このため、導電部材と外部電極部材との接続にリード線等を用いる必要がなく、電池を安価にすることができる。   In this battery, since the conductive member further includes the above-described third connection portion, the strip-shaped end portion (the current collecting terminal portion or the current collecting terminal portion and the exposed portion) of the electrode plate and the external electrode member are connected only by this conductive member. Can be electrically connected. For this reason, it is not necessary to use a lead wire or the like for connection between the conductive member and the external electrode member, and the battery can be made inexpensive.

また、他の態様は、正極金属箔集電体及びこの正極金属箔集電体上に形成された正極活物質層を有する長尺状の正電極板と、負極金属箔集電体及びこの負極金属箔集電体上に形成された負極活物質層を有する長尺状の負電極板とを長尺状のセパレータを介して互いに重ねて軸線周りに捲回してなる捲回型電極体であって、前記軸線方向の一端側に、前記正極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出すると共に、前記軸線方向の他端側に、前記負極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出してなる捲回型電極体、を備え、前記正極金属箔集電体の帯状端部及び前記負極金属箔集電体の帯状端部のうち、少なくとも一方の帯状端部は、その長手方向に断続的に延びると共に、捲回された状態で径方向に互いに隣在する複数のスリットを有し、この帯状端部のうち、前記スリットよりも前記幅方向の外側に位置すると共に、捲回された状態で径方向に互いに隣在する複数のスリット外側部を、寄せ集め互いに重ねて集電端子部を構成してなる電池の製造方法であって、前記正電極板と前記負電極板とを前記セパレータを介して互いに重ねて前記軸線周りに捲回する捲回工程であって、前記一端側に前記正極金属箔集電体の前記帯状端部が突出し、前記他端側に前記負極金属箔集電体の帯状端部が突出すると共に、各々の前記スリットが径方向に互いに隣在する形態に捲回する捲回工程と、前記捲回工程に先だって、前記帯状端部に前記スリットを形成するスリット形成工程と、前記捲回工程後、前記帯状端部のうち、前記スリット外側部を、寄せ集め互いに重ねて前記集電端子部を形成する集電端子部形成工程と、を備える電池の製造方法である。   In another aspect, a positive metal foil current collector, a long positive electrode plate having a positive electrode active material layer formed on the positive metal foil current collector, a negative metal foil current collector, and the negative electrode This is a wound electrode body in which a long negative electrode plate having a negative electrode active material layer formed on a metal foil current collector is overlapped with each other through a long separator and wound around an axis. The strip-shaped end portion of the positive electrode metal foil current collector that is located at the end in the width direction and is exposed and forms a strip shape spirally and protrudes from the separator on one end side in the axial direction. On the other end side in the axial direction, a wound-type electrode in which the strip-shaped end portion of the negative electrode metal foil current collector located at the end in the width direction and exposed to form a strip shape spirals and protrudes from the separator A strip-shaped end portion of the positive electrode metal foil current collector and a strip-shaped end portion of the negative electrode metal foil current collector Among them, at least one strip-shaped end portion intermittently extends in the longitudinal direction thereof and has a plurality of slits adjacent to each other in the radial direction in a wound state. And a battery manufacturing method in which a plurality of slit outer portions adjacent to each other in the radial direction in a wound state are gathered together and overlap each other to constitute a current collecting terminal portion. A winding step in which the positive electrode plate and the negative electrode plate are wound around the axis while being overlapped with each other via the separator, and the belt-like shape of the positive electrode metal foil current collector on the one end side A winding step in which an end protrudes, a band-like end of the negative electrode metal foil current collector protrudes on the other end side, and the slits are wound adjacent to each other in the radial direction; Prior to the turning process, the strip ends are A slit forming step for forming a power strip, and, after the winding step, a current collecting terminal portion forming step for forming the current collecting terminal portion by stacking the slit outer portions together and overlapping each other, A method for producing a battery comprising:

前述した電池の製造にあたり、前述のスリットを形成するのに、まず、正電極板と負電極板とをセパレータを介して互いに重ねて軸線周りに捲回し、その後に、この捲回型電極体の帯状端部にスリットを形成する手法が考えられる。しかしながら、この方法では、スリットを形成する際に生じる切粉が捲回型電極体内に残り、この切粉により正電極板と負電極板との間で短絡を生じる可能性がある。   In manufacturing the above-described battery, in order to form the above-described slit, first, the positive electrode plate and the negative electrode plate are overlapped with each other via a separator and wound around the axis, and then the wound electrode body is formed. A method of forming a slit at the belt-shaped end can be considered. However, in this method, chips generated when forming the slit remain in the wound electrode body, and the chips may cause a short circuit between the positive electrode plate and the negative electrode plate.

これに対し、前述の電池の製造方法では、正電極板と負電極板とをセパレータを介して重ねて捲回する捲回工程に先だって、スリット形成工程において、帯状端部にスリットを形成する。このようにすることで、スリットを形成する際に生じた切粉を容易に除去できるので、その後に捲回型電極体を形成したときに、捲回型電極体内に切粉が混入することを防止できる。従って、信頼性の高い電池を製造できる。   On the other hand, in the battery manufacturing method described above, slits are formed at the belt-shaped end portions in the slit forming step prior to the winding step in which the positive electrode plate and the negative electrode plate are wound with a separator interposed therebetween. In this way, the chips generated when forming the slit can be easily removed, so that when the wound electrode body is formed thereafter, the chips are mixed into the wound electrode body. Can be prevented. Therefore, a highly reliable battery can be manufactured.

実施形態に係るリチウム二次電池の縦断面図である。It is a longitudinal cross-sectional view of the lithium secondary battery which concerns on embodiment. 実施形態に係り、捲回型電極体及びこれに接続した第1,第2導電プレート等を示す斜視図である。FIG. 4 is a perspective view showing a wound electrode body and first and second conductive plates connected thereto according to the embodiment. 実施形態に係り、捲回型電極体を示す斜視図である。1 is a perspective view showing a wound electrode body according to an embodiment. 実施形態に係り、正電極板を示す平面図である。It is a top view which concerns on embodiment and shows a positive electrode plate. 実施形態に係り、負電極板を示す平面図である。It is a top view which concerns on embodiment and shows a negative electrode plate. 実施形態に係り、セパレータを示す平面図である。It is a top view which concerns on embodiment and shows a separator. 実施形態に係るリチウム二次電池の製造方法に関し、正電極板を形成する様子を示す説明図である。It is explanatory drawing which shows a mode that a positive electrode plate is formed regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、正電極板と負電極板とをセパレータを介して軸線周りに捲回した状態を示す斜視図である。It is a perspective view which shows the state which wound the positive electrode board and the negative electrode board around the axis line via the separator regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、図8の捲回型電極体を図8の上方から見た平面図である。FIG. 9 is a plan view of the wound electrode body of FIG. 8 as viewed from above in FIG. 8 with respect to the method for manufacturing a lithium secondary battery according to the embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、捲回型電極体に正極集電端子部及び負極集電端子部を形成した状態を示す斜視図である。It is a perspective view which shows the state which formed the positive electrode current collection terminal part and the negative electrode current collection terminal part in the winding type electrode body regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、図10の捲回型電極体を図10の上方から見た平面図である。It is the top view which looked at the winding type electrode body of FIG. 10 from the upper direction of FIG. 10 regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、第1導電プレートとリード部材の形態を示す斜視図である。It is a perspective view which shows the form of a 1st electroconductive plate and a lead member regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、第1導電プレートとリード部材とを溶接した状態を示す斜視図である。It is a perspective view which shows the state which welded the 1st electroconductive plate and the lead member regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、捲回型電極体に第1導電プレート、リード部材、及び、第2導電プレートを接続した状態を示す斜視図である。It is a perspective view which shows the state which connected the 1st electroconductive plate, the lead member, and the 2nd electroconductive plate to the winding type electrode body regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、図14の捲回型電極体等に第2蓋部材を接続した状態を示す斜視図である。It is a perspective view which shows the state which connected the 2nd cover member to the winding type electrode body etc. of FIG. 14 regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、図15の捲回型電極体等を電池ケース本体内に挿入し、第2蓋部材を電池ケース本体に加締め固定した状態を示す斜視図である。FIG. 16 is a perspective view showing a state in which the wound electrode body of FIG. 15 is inserted into the battery case body and the second lid member is crimped and fixed to the battery case body with respect to the method for manufacturing the lithium secondary battery according to the embodiment. is there. 実施形態に係るリチウム二次電池の製造方法に関し、リード部材に第1蓋部材を接続した状態を示す斜視図である。It is a perspective view which shows the state which connected the 1st cover member to the lead member regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、スペーサの形態を示す斜視図である。It is a perspective view which shows the form of a spacer regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、スペーサを電池ケース本体内に配置した状態を示す横断面図である。It is a cross-sectional view which shows the state which has arrange | positioned the spacer in the battery case main body regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 実施形態に係るリチウム二次電池の製造方法に関し、第1蓋部材を電池ケース本体に加締め固定した状態を示す斜視図である。It is a perspective view which shows the state which crimped and fixed the 1st cover member to the battery case main body regarding the manufacturing method of the lithium secondary battery which concerns on embodiment. 従来技術1に係る電池の要部を示す説明図である。FIG. 6 is an explanatory diagram showing a main part of a battery according to prior art 1. 従来技術2に係る電池の要部を示す説明図である。FIG. 10 is an explanatory diagram showing a main part of a battery according to prior art 2. 参考技術に係る電池に関し、正電極板と負電極板とをセパレータを介して捲回した捲回型電極体を示す説明図である。It is explanatory drawing which shows the winding type electrode body which wound the positive electrode board and the negative electrode board through the separator regarding the battery which concerns on a reference technique. 参考技術に係る電池に関し、捲回型電極体に集電端子部を形成した状態を示す説明図である。It is explanatory drawing which shows the state which formed the current collection terminal part in the wound type electrode body regarding the battery which concerns on a reference technique.

以下、本発明の実施の形態を、図面を参照しつつ説明する。図1に、本実施形態に係るリチウム二次電池(電池)100を示す。また、図2に、このリチウム二次電池100を構成する捲回型電極体120及びこれに接続した第1,第2導電プレート(導電部材)151,161等を示し、また、図3に、捲回型電極体120を示す。更に、捲回型電極体120を構成する正電極板121を図4に示し、負電極板131を図5に示し、セパレータ141を図6に示す。   Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 1 shows a lithium secondary battery (battery) 100 according to this embodiment. 2 shows a wound electrode body 120 constituting the lithium secondary battery 100, and first and second conductive plates (conductive members) 151, 161 connected thereto, and FIG. A wound electrode body 120 is shown. Further, the positive electrode plate 121 constituting the wound electrode body 120 is shown in FIG. 4, the negative electrode plate 131 is shown in FIG. 5, and the separator 141 is shown in FIG.

このリチウム二次電池100は、円筒型電池であり、ハイブリットカーや電気自動車などの動力源として利用される。リチウム二次電池100は、電池ケース110、この電池ケース110内に収容された捲回型電極体120、この捲回型電極体120に接続された第1,第2導電プレート151,161及びリード部材155等から構成されている。また、電池ケース110内には、図示しない電解液が注入されて封止されている。   The lithium secondary battery 100 is a cylindrical battery and is used as a power source for a hybrid car, an electric vehicle, and the like. The lithium secondary battery 100 includes a battery case 110, a wound electrode body 120 accommodated in the battery case 110, first and second conductive plates 151, 161 connected to the wound electrode body 120, and leads. It is comprised from the member 155 grade | etc.,. In addition, an electrolyte solution (not shown) is injected into the battery case 110 and sealed.

電池ケース110は、軸線AX方向に延びる筒状(具体的には円筒状)をなし、捲回型電極体120を内側に配置する電池ケース本体111と、この電池ケース本体111の両端の開口111h1,111h2をそれぞれ閉塞する平面視円形状の第1蓋部材113及び第2蓋部材115とを有する(図1,図20等を参照)。電池ケース本体111、第1蓋部材113及び第2蓋部材115は、ぞれぞれ金属により形成されている。   The battery case 110 has a cylindrical shape (specifically, a cylindrical shape) extending in the direction of the axis AX, and a battery case main body 111 in which the wound electrode body 120 is disposed inside, and openings 111h1 at both ends of the battery case main body 111. , 111h2 each having a first lid member 113 and a second lid member 115 having a circular shape in plan view (see FIGS. 1, 20, etc.). Battery case body 111, first lid member 113, and second lid member 115 are each formed of metal.

第1蓋部材113は、電池の正極外部電極をなす正極外部電極部材でもあり、後述する正電極板121と電気的に接続されている。また、第2蓋部材115は、電池の負極外部電極をなす負極外部電極部材でもあり、後述する負電極板131と電気的に接続されている。
第1蓋部材113は、円板状の蓋本体部113eと、この蓋本体部113eの中央に立設されて軸線AX方向外側(図1中、上方)に延びる円柱状の端子部113fとからなる。蓋本体部113eには、電池ケース110内に電解液を注入するための電解液注入口113ehが設けられている。この電解液注入口113ehは、栓118により閉塞されている。
また、第2蓋部材115は、円板状の蓋本体部115eと、この蓋本体部115eの中央に立設されて軸線AX方向外側(図1中、下方)に延びる円柱状の端子部115fとからなる。
The first lid member 113 is also a positive external electrode member that forms a positive external electrode of the battery, and is electrically connected to a positive electrode plate 121 described later. The second lid member 115 is also a negative external electrode member that forms a negative external electrode of the battery, and is electrically connected to a negative electrode plate 131 described later.
The first lid member 113 includes a disc-shaped lid main body portion 113e and a columnar terminal portion 113f that stands up at the center of the lid main body portion 113e and extends outward in the axis AX direction (upward in FIG. 1). Become. The lid main body 113e is provided with an electrolyte inlet 113eh for injecting an electrolyte into the battery case 110. The electrolytic solution inlet 113eh is closed by a plug 118.
The second lid member 115 includes a disc-shaped lid body portion 115e and a columnar terminal portion 115f that stands upright at the center of the lid body portion 115e and extends outward in the axis AX direction (downward in FIG. 1). It consists of.

第1蓋部材113と電池ケース本体111の軸線AX方向の一方の端部111c1(図1中、上方)との間には、リング状の第1ガスケット117が配置され、第1蓋部材113と電池ケース本体111とを電気的に絶縁しつつ、電池ケース110内を封止している。また、第2蓋部材115と電池ケース本体111の軸線AX方向の他方の端部111c2(図1中、下方)との間にも、リング状の第2ガスケット119が配置され、第2蓋部材115と電池ケース本体111とを電気的に絶縁しつつ、電池ケース110内を封止している。   A ring-shaped first gasket 117 is disposed between the first lid member 113 and one end 111c1 (upward in FIG. 1) of the battery case body 111 in the axis AX direction. The battery case 110 is sealed while being electrically insulated from the battery case body 111. A ring-shaped second gasket 119 is also disposed between the second lid member 115 and the other end portion 111c2 (downward in FIG. 1) of the battery case body 111 in the axis AX direction. The battery case 110 is sealed while electrically insulating the battery case 115 and the battery case body 111.

電池ケース110と後述する捲回型電極体120との間には、捲回型電極体120を電池ケース110内の所定位置に保持するために、2つのガタつき防止用のスペーサ171,171が、周方向に等間隔に配置されている(図1,図18,図19等を参照)。具体的には、このスペーサ171は、板状の第1スペーサ部171aと、これに繋がる第2スペーサ部171bとからなる(図18参照)。このうち第1スペーサ部171aは、捲回型電極体120に接続された第1導電プレート151の第2接続部151bに軸線AX方向外側(図1中、上方)から当接している。また、第2スペーサ部171bは、ケース本体部材111と捲回型電極体120との間に介在し、捲回型電極体120が軸線AXと直交する方向に移動するのを防止している。   Between the battery case 110 and a wound electrode body 120, which will be described later, in order to hold the wound electrode body 120 at a predetermined position in the battery case 110, two backlash preventing spacers 171 and 171 are provided. Are arranged at equal intervals in the circumferential direction (see FIGS. 1, 18, 19 and the like). Specifically, the spacer 171 includes a plate-like first spacer portion 171a and a second spacer portion 171b connected thereto (see FIG. 18). Among these, the first spacer portion 171a is in contact with the second connection portion 151b of the first conductive plate 151 connected to the wound electrode body 120 from the outside in the axis AX direction (upward in FIG. 1). The second spacer portion 171b is interposed between the case body member 111 and the wound electrode body 120, and prevents the wound electrode body 120 from moving in a direction orthogonal to the axis AX.

次に、捲回型電極体120について詳述する(図1〜図6等を参照)。この捲回型電極体120は、長尺状の正電極板121(図4参照)と、長尺状の負電極板131(図5参照)とを、通気性を有する長尺状のセパレータ141(図6参照)を介して互いに重ね、これを複数回、軸線AX周りに円筒状に捲回することにより構成されている。捲回型電極体120の軸線AX方向の一端側(図1〜図3中、上方)には、正電極板121の正極金属箔集電体122のうち幅方向の端に位置し露出して帯状をなす正極帯状端部122mが渦巻き状をなして、セパレータ141から突出している。一方、捲回型電極体120の軸線AX方向の他端側(図1〜図3中、下方)には、負電極板131の負極金属箔集電体132のうち幅方向の端に位置し露出して帯状をなす負極帯状端部132mが渦巻き状をなして、セパレータ141から突出している。   Next, the wound electrode body 120 will be described in detail (see FIGS. 1 to 6 and the like). The wound electrode body 120 includes a long positive electrode plate 121 (see FIG. 4) and a long negative electrode plate 131 (see FIG. 5), a long separator 141 having air permeability. (See FIG. 6), and they are overlapped with each other via a plurality of times and wound around the axis AX in a cylindrical shape. One end side of the wound electrode body 120 in the axis AX direction (upward in FIGS. 1 to 3) is located at the end in the width direction of the positive electrode metal foil current collector 122 of the positive electrode plate 121 and is exposed. A strip-shaped positive electrode strip-shaped end portion 122 m is spirally projected from the separator 141. On the other hand, the other end side (downward in FIGS. 1 to 3) of the wound electrode body 120 in the axis AX direction is located at the end in the width direction of the negative electrode metal foil current collector 132 of the negative electrode plate 131. The negative electrode strip-shaped end portion 132m that is exposed and forms a strip shape is spirally projected from the separator 141.

このうち、正電極板121は、図4に示すように、芯材として、アルミニウム箔からなる正極金属箔集電体122を有する。この正極金属箔集電体122の表面(両面)のうち、幅方向(図4中、上下方向)中央の正極塗工部122wには、リチウムコバルト複合酸化物などの正極活物質を含む正極活物質層123が、長手方向(図4中、左右方向)に帯状に形成されている。これに伴い、正極金属箔集電体122のうち、幅方向の一端側(図4中、上方)は、正極活物質層123が存在しないでこの正極金属箔集電体122が露出し、長手方向に帯状に延びる第1正極未塗工部122mとなっている。また、正極金属箔集電体122のうち、幅方向の他端側(図4中、下方)も、正極活物質層123が存在しないでこの正極金属箔集電体122が露出し、長手方向に帯状に延び、第1正極未塗工部122mよりも幅狭な第2正極未塗工部122nとなっている。このうち、第1正極未塗工部122mは、捲回型電極体120において、セパレータ141から軸線AX方向に突出する前述の正極帯状端部122mでもある。   Among these, the positive electrode plate 121 has a positive electrode metal foil current collector 122 made of an aluminum foil as a core material, as shown in FIG. Among the surfaces (both sides) of the positive electrode metal foil current collector 122, the positive electrode coating part 122w in the center in the width direction (vertical direction in FIG. 4) has a positive electrode active material containing a positive electrode active material such as lithium cobalt composite oxide. The material layer 123 is formed in a strip shape in the longitudinal direction (left-right direction in FIG. 4). Accordingly, one end side in the width direction (upper side in FIG. 4) of the positive electrode metal foil current collector 122 is exposed without the positive electrode active material layer 123 and the longitudinal length of the positive electrode metal foil current collector 122 is exposed. It becomes the 1st positive electrode uncoated part 122m extended in a strip | belt shape in the direction. Further, among the positive electrode metal foil current collector 122, the other end side in the width direction (lower side in FIG. 4) also exposes this positive electrode metal foil current collector 122 without the presence of the positive electrode active material layer 123, and the longitudinal direction. The second positive electrode uncoated part 122n is narrower than the first positive electrode uncoated part 122m. Among these, the first positive electrode uncoated portion 122m is the above-described positive electrode belt-shaped end portion 122m that protrudes from the separator 141 in the axis AX direction in the wound electrode body 120.

第1正極未塗工部(正極帯状端部)122mには、その長手方向に断続的に延びる多数の正極スリット122h,122h,…が形成されている。これらの正極スリット122h,122h,…は、正電極板121が捲回型電極体120として捲回された状態で、交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の正極スリット122h,122h,…は、それぞれ径方向に互いに隣在している(図1〜図3,図8,図9等を参照)。
また、正極帯状端部122mのうち、正極スリット122h,122h,…よりも幅方向の外側(図4中、上方)に位置する多数の正極スリット外側部122s,122s,…は、正電極板121が捲回型電極体120として捲回された状態で、交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の正極スリット外側部122s,122s,…は、それぞれ径方向に互いに隣在している(図1〜図3,図8,図9等を参照)。
A number of positive electrode slits 122h, 122h,... Extending intermittently in the longitudinal direction are formed in the first positive electrode uncoated portion (positive electrode strip end portion) 122m. These positive electrode slits 122h, 122h,... Are arranged in two lines alternately in a state where the positive electrode plate 121 is wound as a wound electrode body 120, and are arranged almost line-symmetrically when viewed from the axis AX direction. The positive electrode slits 122h, 122h,... Of each group are adjacent to each other in the radial direction (see FIGS. 1 to 3, 8, and 9).
In addition, among the positive electrode strip-shaped end portions 122m, a large number of positive electrode slit outer portions 122s, 122s,... Positioned on the outer side in the width direction (upward in FIG. 4) than the positive electrode slits 122h, 122h,. Are wound as the wound electrode body 120 and are alternately divided into two groups, arranged substantially symmetrically with respect to the axis AX, and the positive electrode slit outer portions 122s, 122s,. Are adjacent to each other in the radial direction (see FIGS. 1 to 3, 8, and 9).

また、正極帯状端部122mの正極スリット外側部122s,122s,…には、図4に示すように、2つずつ貫通孔122sc,122scが形成されている。これらの貫通孔122sc,122sc,…は、正電極板121が捲回型電極体120として捲回された状態で、2つずつ交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の貫通孔122sc,122scは、それぞれ径方向に互いに隣在している(図1〜図3,図8等を参照)。
そして、これらの正極スリット外側部122s,122s,…は、寄せ集めて互いに重ねることにより、軸線AXに直交する断面がH字状をなす正極集電端子部122yを構成している。
Moreover, as shown in FIG. 4, two through-holes 122sc and 122sc are formed in the positive electrode slit outer side portions 122s, 122s,. These through holes 122sc, 122sc,... Are divided into two groups two by two in a state where the positive electrode plate 121 is wound as the wound electrode body 120, and are substantially line-shaped when viewed from the direction of the axis AX. The through holes 122sc and 122sc of each group are arranged symmetrically and are adjacent to each other in the radial direction (see FIGS. 1 to 3, FIG. 8, etc.).
And these positive electrode slit outer side parts 122s, 122s, ... gather together and overlap each other, thereby constituting a positive electrode current collecting terminal part 122y whose section perpendicular to the axis AX is H-shaped.

負電極板131は、図5に示すように、芯材として、銅箔からなる負極金属箔集電体132を有する。この負極金属箔集電体132の表面(両面)のうち、幅方向(図5中、上下方向)中央の負極塗工部132wには、天然黒鉛などの負極活物質を含む負極活物質層133が、長手方向(図5中、左右方向)に帯状に形成されている。これに伴い、負極金属箔集電体132のうち、幅方向の一端側(図5中、下方)は、負極活物質層133が存在しないでこの負極金属箔集電体132が露出し、長手方向に帯状に延びる第1負極未塗工部132mとなっている。また、負極金属箔集電体132のうち、幅方向の他端側(図5中、上方)も、負極活物質層133が存在しないでこの負極金属箔集電体132が露出し、長手方向に延び、第1負極未塗工部132mよりも幅狭な第2負極未塗工部132nとなっている。このうち、第1負極未塗工部132mは、捲回型電極体120において、セパレータ141から軸線AX方向に突出する前述の負極帯状端部132mでもある。   As shown in FIG. 5, the negative electrode plate 131 includes a negative electrode metal foil current collector 132 made of a copper foil as a core material. Of the surface (both sides) of the negative electrode metal foil current collector 132, the negative electrode coating portion 132 w at the center in the width direction (vertical direction in FIG. 5) has a negative electrode active material layer 133 containing a negative electrode active material such as natural graphite. Is formed in a strip shape in the longitudinal direction (left-right direction in FIG. 5). Accordingly, one end side in the width direction (downward in FIG. 5) of the negative electrode metal foil current collector 132 is exposed without the negative electrode active material layer 133 being present, and is elongated. It becomes the 1st negative electrode uncoated part 132m extended in a strip | belt shape in the direction. Further, among the negative electrode metal foil current collector 132, the other end side in the width direction (upward in FIG. 5) is also exposed in the longitudinal direction without the negative electrode active material layer 133 being exposed. The second negative electrode uncoated portion 132n is narrower than the first negative electrode uncoated portion 132m. Among these, the 1st negative electrode uncoated part 132m is the above-mentioned negative electrode strip | belt-shaped edge part 132m which protrudes in the axis line AX direction from the separator 141 in the wound electrode body 120. FIG.

第1負極未塗工部(負極帯状端部)132mには、その長手方向に断続的に延びる多数の負極スリット132h,132h,…が形成されている。これらの負極スリット132h,132h,…は、負電極板131が捲回型電極体120として捲回された状態で、交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の負極スリット132h,132h,…は、それぞれ径方向に互いに互いに隣在している(図1〜図3,図8,図9等を参照)。
また、負極帯状端部132mのうち、負極スリット132h,132h,…よりも幅方向の外側(図5中、下方)に位置する多数の負極スリット外側部132s,132s,…は、負電極板131が捲回型電極体120として捲回された状態で、交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の負極スリット外側部132s,132s,…は、それぞれ径方向に互いに隣在している(図1〜図3,図8,図9等を参照)。
A number of negative electrode slits 132h, 132h,... Extending intermittently in the longitudinal direction are formed in the first negative electrode uncoated portion (negative electrode strip-shaped end portion) 132m. These negative slits 132h, 132h,... Are alternately divided into two groups in a state in which the negative electrode plate 131 is wound as the wound electrode body 120, and are arranged almost line-symmetrically when viewed from the axis AX direction. The negative electrode slits 132h, 132h,... Of each group are adjacent to each other in the radial direction (see FIGS. 1 to 3, 8, and 9).
In addition, among the negative electrode belt-shaped end portions 132m, a large number of negative electrode slit outer portions 132s, 132s,... Located on the outer side in the width direction (lower in FIG. 5) than the negative electrode slits 132h, 132h,. Are wound as the wound electrode body 120, and are alternately divided into two groups and arranged substantially symmetrically when viewed from the axis AX direction. The negative electrode slit outer portions 132s, 132s,. Are adjacent to each other in the radial direction (see FIGS. 1 to 3, 8, and 9).

また、負極帯状端部132mの負極スリット外側部132s,132s,…には、図5に示すように、2つずつ貫通孔132sc,132scが形成されている。これらの貫通孔132sc,132sc,…は、負電極板131が捲回型電極体120として捲回された状態で、2つずつ交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の貫通孔132sc,132scは、それぞれ径方向に互いに隣在している(図1〜図3,図8等を参照)。
そして、これらの負極スリット外側部132s,132s,…は、寄せ集めて互いに重ねることにより、軸線AXに直交する断面がH字状をなす負極集電端子部132yを構成している。
Moreover, as shown in FIG. 5, two through holes 132sc and 132sc are formed in the negative electrode slit outer side portions 132s, 132s,. These through holes 132sc, 132sc,... Are divided into two groups alternately two by two in a state in which the negative electrode plate 131 is wound as the wound electrode body 120, and are substantially lines as viewed from the direction of the axis AX. The through holes 132sc and 132sc of each group are arranged symmetrically and are adjacent to each other in the radial direction (see FIGS. 1 to 3, FIG. 8, etc.).
And these negative electrode slit outer side parts 132s, 132s, ... gather together and overlap each other, thereby constituting a negative electrode current collecting terminal part 132y having a H-shaped cross section perpendicular to the axis AX.

正極集電端子部122yには、アルミニウムからなる2つの第1導電プレート151,151と1つのリード部材155とが接続されている(図1,図2,図12,図13等を参照)。
第1導電プレート151は、板状の第1接続部151aと、この第1接続部151aに連なり、第1接続部151aに直交する板状の第2接続部151bとを有するL字状をなす。このうち第1接続部151aには、正極集電端子部122yの貫通孔122sc,122scに対応する貫通孔151ah,151ahが設けられている(図12参照)。
Two first conductive plates 151, 151 made of aluminum and one lead member 155 are connected to the positive electrode current collecting terminal portion 122y (see FIGS. 1, 2, 12, 13, etc.).
The first conductive plate 151 has an L shape having a plate-like first connection portion 151a and a plate-like second connection portion 151b that is continuous with the first connection portion 151a and orthogonal to the first connection portion 151a. . Among these, the 1st connection part 151a is provided with the through-holes 151ah and 151ah corresponding to the through-holes 122sc and 122sc of the positive electrode current collection terminal part 122y (refer FIG. 12).

リード部材155は、矩形板状の第1リード部155aと、矩形板状の第3リード部155cと、これらの間を結ぶ細長い第2リード部155bとからなる。このうち第1リード部155aには、正極集電端子部122yの貫通孔122sc,122sc及び第1導電プレート151の貫通孔151ah,151ahに対応する貫通孔155ah,155ahが設けられている(図12参照)。   The lead member 155 includes a rectangular plate-shaped first lead portion 155a, a rectangular plate-shaped third lead portion 155c, and a long and narrow second lead portion 155b connecting them. Among these, the first lead portion 155a is provided with through holes 155ah and 155ah corresponding to the through holes 122sc and 122sc of the positive electrode current collecting terminal portion 122y and the through holes 151ah and 151ah of the first conductive plate 151 (FIG. 12). reference).

第1導電プレート151とリード部材155とは、第1導電プレート151の第1接続部151aとリード部材155の第1リード部155aとを互いに重ね、第1接続部151aの貫通孔151ah,151ahと第1リード部155aの貫通孔155ah,155ahとを連通させた状態で、互いに溶接されている(図2,図13等を参照)。なお、図2,図13等では、溶接箇所を「×」印で示してある。   The first conductive plate 151 and the lead member 155 are configured such that the first connection portion 151a of the first conductive plate 151 and the first lead portion 155a of the lead member 155 overlap each other, and the through holes 151ah and 151ah of the first connection portion 151a The first lead portions 155a are welded to each other with the through holes 155ah and 155ah communicating with each other (see FIGS. 2, 13 and the like). In FIG. 2 and FIG. 13 and the like, the welding locations are indicated by “x” marks.

そして、この第1導電プレート151の第1接続部151a及びリード部材155の第1リード部155aが、軸線AXに直交する方向から正極集電端子部122yに当接してこれに電気的に接続している。また、他方の第1導電プレート151も、その第1接続部151aが、軸線AXに直交する方向から正極集電端子部122yに当接してこれに電気的に接続している。
具体的には、一方の第1導電プレート151の第1接続部151a及びリード部材155の第1リード部155aと、他方の第1導電プレート151の第1接続部151aとの間に、軸線AXに直交する方向から正極集電端子部122yを挟んでいる。この状態で、第1接続部151a,151aの貫通孔151ah,151ah,…と、第1リード部155aの貫通孔155ah,155ahと、正極集電端子122yの貫通孔122sc,122scとが連通している。
Then, the first connecting portion 151a of the first conductive plate 151 and the first lead portion 155a of the lead member 155 are brought into contact with and electrically connected to the positive electrode current collecting terminal portion 122y from the direction orthogonal to the axis AX. ing. Further, the other first conductive plate 151 also has a first connecting portion 151a that is in contact with and electrically connected to the positive electrode current collecting terminal portion 122y from a direction orthogonal to the axis AX.
Specifically, the axis line AX is between the first connection portion 151a of one first conductive plate 151 and the first lead portion 155a of the lead member 155 and the first connection portion 151a of the other first conductive plate 151. The positive electrode current collector terminal portion 122y is sandwiched from the direction orthogonal to the vertical axis. In this state, the through holes 151ah, 151ah,... Of the first connection parts 151a, 151a, the through holes 155ah, 155ah of the first lead part 155a, and the through holes 122sc, 122sc of the positive current collecting terminal 122y communicate with each other. Yes.

また、第1導電プレート151,151の第2接続部151b,151bは、正極帯状端部122mのうち、正極スリット122h,122h,…よりも軸線AX方向内側に位置し、正極スリット外側部122s,122s,…を寄せ集めて正極集電端子部122yを構成したことにより、軸線AX方向外側に露出する正極露出部122r,122rに、軸線AX方向外側からそれぞれ当接している。そして、この当接により、第2接続部151b,151bと正極露出部122r,122rとが電気的に接続している。(図1,図2等を参照)。なお、第2接続部151b,151bと正極露出部122r,122rとを、導電性接着剤やハンダなどにより接合してもよい。
また、リベット153,153により、第1接続部151a,151a同士、及び、これらと第1リード部155aと正極集電端子部122yとを互いに緊結している。
In addition, the second connection portions 151b and 151b of the first conductive plates 151 and 151 are located on the inner side in the axis AX direction than the positive electrode slits 122h, 122h,. 122s,... Are combined to form the positive electrode current collecting terminal portion 122y, so that the positive electrode exposed portions 122r and 122r exposed to the outside in the axis AX direction are in contact with each other from the outside in the axis AX direction. And by this contact, the second connecting portions 151b and 151b and the positive electrode exposed portions 122r and 122r are electrically connected. (See FIG. 1, FIG. 2, etc.). Note that the second connection portions 151b and 151b and the positive electrode exposed portions 122r and 122r may be joined by a conductive adhesive, solder, or the like.
Further, the first connecting portions 151a and 151a and the first lead portion 155a and the positive electrode current collecting terminal portion 122y are tightly coupled to each other by the rivets 153 and 153.

一方、リード部材155の第3リード部155cは、レーザ溶接により、第1蓋部材113の蓋本体部113eに接続されている(図1,図17等を参照)。なお、図17等では、溶接箇所を「×」印で示してある。このようにして、捲回型電極体120の正極集電端子部122yが、第1導電プレート151,151及びリード部材155を介して、第1蓋部材113に電気的に接続されている。   On the other hand, the third lead portion 155c of the lead member 155 is connected to the lid main body portion 113e of the first lid member 113 by laser welding (see FIGS. 1, 17 and the like). In addition, in FIG. 17 etc., the welding location is shown by the "x" mark. In this way, the positive electrode current collecting terminal portion 122y of the wound electrode body 120 is electrically connected to the first lid member 113 via the first conductive plates 151 and 151 and the lead member 155.

負極集電端子部132yには、2つの第2導電プレート161,161が接続されている(図1,図2等を参照)。
第2導電プレート161は、板状の第2接続部161bと、これに平行な板状の第3接続部161cと、これら第2接続部161b及び第3接続部161cに直交し、これらの間を結ぶ板状の第1接続部161aとを有するコ字状をなす。このうち第1接続部161aには、負極集電端子部132yの貫通孔132sc,132scに対応する貫通孔(図示しない)が設けられている。
Two second conductive plates 161 and 161 are connected to the negative electrode current collecting terminal portion 132y (see FIGS. 1 and 2).
The second conductive plate 161 is orthogonal to the plate-like second connection portion 161b, the plate-like third connection portion 161c parallel to the plate-like second connection portion 161b, and the second connection portion 161b and the third connection portion 161c. And a plate-like first connecting portion 161a that connects the two. Among these, the 1st connection part 161a is provided with the through-hole (not shown) corresponding to the through-holes 132sc and 132sc of the negative electrode current collection terminal part 132y.

2つの第2導電プレート161,161の第1接続部161a,161aは、軸線AXに直交する方向から負極集電端子部132yに当接してこれに電気的に接続している。具体的には、一方の第2導電プレート161の第1接続部161aと他方の第2導電プレート161の第1接続部161aとの間に、軸線AXに直交する方向から負極集電端子部132yを挟んでいる。この状態で、第1接続部161a,161aの貫通孔と負極集電端子132yの貫通孔132sc,132scとが連通している。   The first connecting portions 161a and 161a of the two second conductive plates 161 and 161 are in contact with and electrically connected to the negative electrode current collecting terminal portion 132y from a direction orthogonal to the axis AX. Specifically, the negative electrode current collector terminal portion 132y from the direction perpendicular to the axis AX between the first connection portion 161a of one second conductive plate 161 and the first connection portion 161a of the other second conductive plate 161. Is sandwiched. In this state, the through holes of the first connecting portions 161a and 161a communicate with the through holes 132sc and 132sc of the negative electrode current collector terminal 132y.

また、第2導電プレート161,161の第2接続部161b,161bは、負極帯状端部132mのうち、負極スリット132h,132h,…よりも軸線AX方向内側に位置し、負極スリット外側部132s,132s,…を寄せ集めて負極集電端子部132yを構成したことにより、軸線AX方向外側に露出する負極露出部132r,132rに、軸線AX方向外側からそれぞれ当接している。そして、この当接により、第2接続部161b,161bと負極露出部132r,132rとが電気的に接続している。(図1,図2等を参照)。なお、第2接続部161b,161bと負極露出部132r,132rとを、導電性接着剤やハンダなどにより接合してもよい。
また、リベット163,163により、第1接続部161a,161a同士、及び、これらと負極集電端子部132yとを互いに緊結している。
In addition, the second connection portions 161b and 161b of the second conductive plates 161 and 161 are located on the inner side in the axis AX direction than the negative electrode slits 132h, 132h,. The negative electrode current collector terminal portion 132y is configured by gathering 132s,..., And is in contact with the negative electrode exposed portions 132r and 132r exposed on the outer side in the axis AX direction from the outer side in the axis AX direction. And by this contact, the second connection parts 161b and 161b and the negative electrode exposed parts 132r and 132r are electrically connected. (See FIG. 1, FIG. 2, etc.). Note that the second connecting portions 161b and 161b and the negative electrode exposed portions 132r and 132r may be joined by a conductive adhesive or solder.
The first connecting portions 161a and 161a and the negative current collecting terminal portion 132y are tightly coupled to each other by the rivets 163 and 163.

一方、第2導電プレート161,161の第3接続部161c,161cは、第2蓋部材115の蓋本体部115eに軸線AX方向から当接した状態で、レーザ溶接されている(図1、図2等を参照)。なお、図2等では、溶接箇所を「×」印で示してある。このようにして、捲回型電極体120の負極集電端子部132yが、第2導電プレート161,161を介して、第2蓋部材115に電気的に接続されている。   On the other hand, the third connection portions 161c and 161c of the second conductive plates 161 and 161 are laser-welded in a state of being in contact with the lid main body portion 115e of the second lid member 115 from the axis AX direction (FIGS. (See 2 etc.). In addition, in FIG. 2 etc., the welding location is shown by the "x" mark. In this way, the negative electrode current collecting terminal portion 132y of the wound electrode body 120 is electrically connected to the second lid member 115 via the second conductive plates 161 and 161.

以上で説明したように、本実施形態のリチウム二次電池100は、正電極板121の正極帯状端部122mのうち、正極スリット外側部122s,122s,…を、寄せ集め互いに重ねて正極集電端子部122yを構成している。このため、従来技術1,2(図21及び図22参照)のように、帯状端部913に多数の集電タブ915,915,…を接続し、これらの集電タブ915,915,…同士を溶接したり、タガ締めする場合に比して、捲回型電極体120及びリチウム二次電池100の小型化できる。また、集電タブ915,915,…を少なくした場合に生じる集電効率の低下のおそれもない。更に、集電タブを接続する必要がなく、また、後述するように、正極集電端子部122yの形成が容易であるので、リチウム二次電池100を安価にすることができる。   As described above, in the lithium secondary battery 100 of the present embodiment, the positive electrode current collectors 122m, 122s,. A terminal portion 122y is configured. For this reason, like the prior art 1 and 2 (refer FIG.21 and FIG.22), many current collection tabs 915,915, ... are connected to the strip | belt-shaped edge part 913, These current collection tabs 915,915, ... The wound electrode body 120 and the lithium secondary battery 100 can be downsized as compared with the case of welding or tightening. In addition, there is no fear of a decrease in current collection efficiency that occurs when the current collecting tabs 915, 915,. Furthermore, there is no need to connect a current collecting tab, and as will be described later, the positive electrode current collecting terminal portion 122y can be easily formed, so that the lithium secondary battery 100 can be made inexpensive.

また、参考形態(図23及び図24参照)のように、帯状端部913にスリットを設けることなく、帯状端部913を寄せ集めて集電端子部941を形成する場合には、前述のように、集電端子部941に抵抗バラツキが生じ易い。しかるに、本実施形態のリチウム二次電池100では、正極帯状端部122mに正極スリット122h,122h,…を設けているので、正極帯状端部122m(正極スリット外側部122s,122s,…)を寄せ集め互いに重ねた正極集電端子部122yに、抵抗バラツキが生じ難い。
また、正極スリット122h,122h,…を形成してあることから、正極集電端子部122yを形成する際に、捲回型電極体120のうち、正極スリット122h,122h,…よりも幅方向(軸線AX方向)内側の部分に影響が生じ難いので、正電極板121や負電極板132において活物質層123,133が剥がれる不具合を防止できる。
Further, as in the reference embodiment (see FIGS. 23 and 24), when the current collecting terminal portion 941 is formed by gathering the belt-shaped end portions 913 without providing the slits in the belt-shaped end portions 913, as described above. In addition, resistance variation tends to occur in the current collecting terminal portion 941. However, in the lithium secondary battery 100 of the present embodiment, since the positive electrode strip-shaped end portion 122m is provided with the positive electrode slit 122h, 122h,..., The positive electrode band-shaped end portion 122m (positive electrode slit outer portion 122s, 122s,. Resistance variations hardly occur in the positive electrode current collecting terminal portions 122y collected and overlapped with each other.
In addition, since the positive electrode slits 122h, 122h,... Are formed, when forming the positive electrode current collecting terminal portion 122y, the width direction of the positive electrode slits 122h, 122h,. Since it is difficult to affect the inner portion (in the direction of the axis AX), it is possible to prevent the active material layers 123 and 133 from being peeled off at the positive electrode plate 121 and the negative electrode plate 132.

また、本実施形態では、負電極板131の負極帯状端部132mのうち、負極スリット外側部132s,132s,…を、寄せ集め互いに重ねて負極集電端子部132yを構成している。このため、従来技術1,2(図21及び図22参照)のように、帯状端部913に多数の集電タブ915,915,…を接続し、これらの集電タブ915,915,…同士を溶接したり、タガ締めする場合に比して、捲回型電極体120及びリチウム二次電池100の小型化できる。また、集電タブ915,915,…を少なくした場合に生じる集電効率の低下のおそれもない。更に、集電タブを接続する必要がなく、また、後述するように、負極集電端子部132yの形成が容易であるので、リチウム二次電池100を安価にすることができる。   In the present embodiment, the negative electrode slit outer end portions 132s, 132s,... Of the negative electrode strip-like end portion 132m of the negative electrode plate 131 are gathered together and overlap each other to constitute the negative electrode current collecting terminal portion 132y. For this reason, like the prior art 1 and 2 (refer FIG.21 and FIG.22), many current collection tabs 915,915, ... are connected to the strip | belt-shaped edge part 913, These current collection tabs 915,915, ... The wound electrode body 120 and the lithium secondary battery 100 can be downsized as compared with the case of welding or tightening. In addition, there is no fear of a decrease in current collection efficiency that occurs when the current collecting tabs 915, 915,. Furthermore, there is no need to connect a current collecting tab, and as will be described later, since the negative electrode current collecting terminal portion 132y can be easily formed, the lithium secondary battery 100 can be made inexpensive.

また、参考形態(図23及び図24参照)のように、帯状端部913にスリットを設けることなく、帯状端部913を寄せ集めて集電端子部941を形成する場合には、前述のように、集電端子部941に抵抗バラツキが生じ易い。しかるに、本実施形態のリチウム二次電池100では、負極帯状端部132m (負極スリット外側部132s,132s,…)を寄せ集め互いに重ねた負極集電端子部132yに、抵抗バラツキが生じ難い。
また、負極スリット132h,132h,…を形成してあることから、負極集電端子部132yを形成する際に、捲回型電極体120のうち、負極スリット132h,132h,…よりも幅方向(軸線AX方向)内側の部分に影響が生じ難いので、正電極板121や負電極板131において活物質層123,133が剥がれる不具合を防止できる。
Further, as in the reference embodiment (see FIGS. 23 and 24), when the current collecting terminal portion 941 is formed by gathering the belt-shaped end portions 913 without providing the slits in the belt-shaped end portions 913, as described above. In addition, resistance variation tends to occur in the current collecting terminal portion 941. However, in the lithium secondary battery 100 of the present embodiment, resistance variations are unlikely to occur in the negative electrode current collecting terminal portion 132y that has the negative electrode band-shaped end portions 132m (negative electrode slit outer portions 132s, 132s,.
Further, since the negative electrode slits 132h, 132h,... Are formed, when forming the negative electrode current collector terminal portion 132y, the width direction of the negative electrode slits 132h, 132h,. Since the inner portion (in the direction of the axis AX) is hardly affected, it is possible to prevent the active material layers 123 and 133 from being peeled off at the positive electrode plate 121 and the negative electrode plate 131.

また、本実施形態では、前述の第1導電プレート151,151を用い、正電極板121の正極金属箔集電体122の正極帯状端部122mのうち、正極集電端子部122yだけでなく、正極露出部122r,122rにおいても、第1導電プレート151,151とそれぞれ電気的に接続している。このため、正極帯状端部122mと第1導電プレート151,151とをさらに低抵抗で接続できるから、この第1導電プレート151,151を介して、より低抵抗で電池外部に正電位を取り出し得る。   In the present embodiment, not only the positive electrode current collector terminal portion 122y but also the positive electrode band-shaped end portion 122m of the positive electrode metal foil current collector 122 of the positive electrode plate 121 using the first conductive plates 151 and 151 described above, The positive electrode exposed portions 122r and 122r are also electrically connected to the first conductive plates 151 and 151, respectively. For this reason, since the positive electrode belt-shaped end portion 122m and the first conductive plates 151 and 151 can be connected with lower resistance, a positive potential can be taken out of the battery with lower resistance through the first conductive plates 151 and 151. .

また、本実施形態では、前述の第2導電プレート161,161を用い、負電極板131の負極金属箔集電体132の負極帯状端部132mのうち、負極集電端子部132yだけでなく、負極露出部132r,132rにおいても、第2導電プレート161,161とそれぞれ電気的に接続している。このため、負極帯状端部132mと第2導電プレート161,161とをさらに低抵抗で接続できるから、この第2導電プレート161,161を介して、より低抵抗で電池外部に負電位を取り出し得る。   Further, in the present embodiment, not only the negative electrode current collector terminal portion 132y but also the negative electrode strip end portion 132m of the negative electrode metal foil current collector 132 of the negative electrode plate 131 using the second conductive plates 161 and 161 described above, The negative electrode exposed portions 132r and 132r are also electrically connected to the second conductive plates 161 and 161, respectively. For this reason, since the negative electrode belt-shaped end portion 132m and the second conductive plates 161 and 161 can be connected with a lower resistance, a negative potential can be extracted outside the battery with a lower resistance via the second conductive plates 161 and 161. .

更に、この第2導電プレート161は、前述の第3接続部161cを有するので、負極帯状端部132m(負極集電端子部132y及び負極露出部132r,132r)と第2蓋部材115とを、この第2導電プレート161,161のみで電気的に接続できる。このため、第2導電プレート161と第2蓋部材115との接続に、リード線等を用いる必要がなく、リチウム二次電池100を安価にすることができる。   Further, since the second conductive plate 161 has the above-described third connection portion 161c, the negative electrode band-shaped end portion 132m (the negative electrode current collecting terminal portion 132y and the negative electrode exposed portions 132r and 132r) and the second lid member 115 are connected. Only the second conductive plates 161 and 161 can be electrically connected. For this reason, it is not necessary to use a lead wire or the like for the connection between the second conductive plate 161 and the second lid member 115, and the lithium secondary battery 100 can be made inexpensive.

次いで、上記リチウム二次電池100の製造方法について説明する。
まず、正電極板121を製造する(図7参照)。長尺状のアルミニウム箔からなる正極金属箔集電体122を用意する。そして、ペースト塗布工程において、ペースト塗布機210により、この正極金属箔集電体122の幅方向の両端部に長手方向の沿う帯状の第1正極未塗工部122m及び第2正極未塗工部122nを形成しつつ、中央部(正極塗工部122w)に正極活物質を含む正極活物質ペーストを塗布する。
その後、乾燥工程において、乾燥機220により熱風を吹きかけて、正極金属箔集電体122に塗布された正極活物質ペーストを乾燥させ、正極活物質123を形成する。
Next, a method for manufacturing the lithium secondary battery 100 will be described.
First, the positive electrode plate 121 is manufactured (see FIG. 7). A positive electrode metal foil current collector 122 made of a long aluminum foil is prepared. In the paste application step, the first positive electrode uncoated portion 122m and the second positive electrode uncoated portion in the longitudinal direction along both ends in the width direction of the positive electrode metal foil current collector 122 are pasted by the paste applicator 210. While forming 122n, the positive electrode active material paste containing a positive electrode active material is apply | coated to the center part (positive electrode coating part 122w).
Thereafter, in the drying step, hot air is blown by the dryer 220 to dry the positive electrode active material paste applied to the positive electrode metal foil current collector 122, thereby forming the positive electrode active material 123.

その後、プレス工程において、電極密度を向上させるために、プレス機(加圧ロール)230により、正極活物質層123を圧縮する。
その後、スリット形成工程において、円形回転刃241を有するスリット形成機240により、第1正極未塗工部(正極帯状端部)122mの所定位置に、長手方向に断続的に延びる多数の正極スリット122h,122h,…を形成する。
その後、パンチング工程において、パンチ刃251を有するパンチング機250により、第1正極未塗工部(正極帯状端部)122mのうち正極スリット外側部122s,122s,…の所定位置に、2つずつ貫通孔122sc,122scを形成する。かくして、正電極板121が形成される。
Thereafter, in the pressing step, the positive electrode active material layer 123 is compressed by a press machine (pressure roll) 230 in order to improve the electrode density.
Thereafter, in the slit forming step, a number of positive electrode slits 122h extending intermittently in the longitudinal direction at a predetermined position of the first positive electrode uncoated portion (positive electrode strip end portion) 122m by a slit forming machine 240 having a circular rotary blade 241. , 122h,.
Then, in the punching process, two punches are passed through the punching machine 250 having the punching blade 251 at predetermined positions of the positive electrode slit outer portions 122s, 122s,... In the first positive electrode uncoated portion (positive electrode strip end portion) 122m. Holes 122sc and 122sc are formed. Thus, the positive electrode plate 121 is formed.

なお、スリット形成やパンチング工程は、ペースト塗布工程に先だって行うこともできる。即ち、まず、スリット形成及びパンチング工程において、長尺状の正極金属箔集電体122に、正極スリット122h,122h,…や貫通孔122sc,122sc,…を形成してから、ペースト塗布工程、乾燥工程、プレス工程を行って、正電極板121を形成することもできる。   The slit formation and punching process can be performed prior to the paste application process. That is, first, in the slit formation and punching process, positive slits 122h, 122h,... And through holes 122sc, 122sc,. The positive electrode plate 121 can also be formed by performing a process and a pressing process.

次に、負電極板131を製造する。長尺状の銅箔からなる負極金属箔集電体132を用意する。そして、ペースト塗布工程において、ペースト塗布機210により、この負極金属箔集電体132の幅方向の両端部に長手方向の沿う帯状の第1負極未塗工部132m及び第2負極未塗工部132nを形成しつつ、中央部(負極塗工部132w)に負極活物質を含む負極活物質ペーストを塗布する。
その後、乾燥工程において、乾燥機220により熱風を吹きかけて、負極金属箔集電体132に塗布された負極活物質ペーストを乾燥させ、負極活物質133を形成する。
Next, the negative electrode plate 131 is manufactured. A negative electrode metal foil current collector 132 made of a long copper foil is prepared. In the paste application step, the first negative electrode uncoated portion 132m and the second negative electrode uncoated portion in the longitudinal direction along both ends in the width direction of the negative electrode metal foil current collector 132 are pasted by the paste applicator 210. While forming 132n, the negative electrode active material paste containing a negative electrode active material is apply | coated to the center part (negative electrode coating part 132w).
Thereafter, in the drying step, hot air is blown by the dryer 220 to dry the negative electrode active material paste applied to the negative electrode metal foil current collector 132, thereby forming the negative electrode active material 133.

その後、プレス工程において、電極密度を向上させるために、プレス機(加圧ロール)230により、負極活物質層133を圧縮する。
その後、スリット形成工程において、円形回転刃241を有するスリット形成機240により、第1負極未塗工部(負極帯状端部)132mの所定位置に、長手方向に断続的に延びる多数の負極スリット132h,132h,…を形成する。
その後、パンチング工程において、パンチ刃251を有するパンチング機250により、第1負極未塗工部(負極帯状端部)132mの負極スリット外側部132s,132s,…の所定位置に、2つずつ貫通孔132sc,132scを形成する。かくして、負電極板131が形成される。
Thereafter, in the pressing step, the negative electrode active material layer 133 is compressed by a press machine (pressure roll) 230 in order to improve the electrode density.
Thereafter, in the slit forming step, a number of negative electrode slits 132h extending intermittently in the longitudinal direction at predetermined positions of the first negative electrode uncoated portion (negative electrode strip end portion) 132m by a slit forming machine 240 having a circular rotary blade 241. , 132h,.
Thereafter, in the punching process, two punching holes are formed at predetermined positions on the negative electrode slit outer side portions 132s, 132s,... Of the first negative electrode uncoated portion (negative electrode strip end portion) 132m by a punching machine 250 having a punch blade 251. 132sc and 132sc are formed. Thus, the negative electrode plate 131 is formed.

なお、負電極板131の製造においても、スリット形成やパンチング工程は、ペースト塗布工程に先だって行うことができる。即ち、まず、スリット形成及びパンチング工程において、長尺状の負極金属箔集電体132に、負極スリット132h,132h,…や貫通孔132sc,132sc,…を形成してから、ペースト塗布工程、乾燥工程、プレス工程を行って、負電極板131を形成することもできる。   In the manufacture of the negative electrode plate 131, the slit formation and punching process can be performed prior to the paste application process. That is, first, in the slit forming and punching process, negative electrode slits 132h, 132h,... And through holes 132sc, 132sc,. The negative electrode plate 131 can also be formed by performing a process and a pressing process.

次に、捲回工程において、図8及び図9に示すように、正電極板121と負電極板131とをセパレータ141を介して互いに重ねて軸線AX周りに捲回し、一端側に正極金属箔集電体122の正極帯状端部122mを渦巻き状に突出させ、他端側に負極金属箔集電体132の負極帯状端部132mを渦巻き状に突出させる。また、多数の正極スリット122h,122h,…を交互に2つの群に分けて、軸線AX方向から見てほぼ線対称な形態で、各群の正極スリット122h,122h,…を径方向に互いに隣在させる。また、多数の負極スリット132h,132h,…を交互に2つの群に分けて、軸線AX方向から見てほぼ線対称な形態で、各群の負極スリット132h,132h,…を径方向に互いに隣在させる。   Next, in the winding step, as shown in FIGS. 8 and 9, the positive electrode plate 121 and the negative electrode plate 131 are overlapped with each other via the separator 141 and wound around the axis AX, and the positive electrode metal foil is disposed on one end side. The positive electrode strip end 122m of the current collector 122 protrudes in a spiral shape, and the negative electrode strip end 132m of the negative electrode metal foil current collector 132 protrudes in a spiral shape on the other end side. In addition, the positive electrode slits 122h, 122h,... Are divided into two groups alternately, and the positive electrode slits 122h, 122h,. Let it be. Further, the negative electrode slits 132h, 132h,... Are alternately divided into two groups, and the negative electrode slits 132h, 132h,. Let it be.

また、この捲回工程により、多数の正極スリット外側部122s,122s,…が、交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の正極スリット外側部122s,122sが径方向に互いに隣在する。また、多数の負極スリット外側部132s,132s,…が、交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の負極スリット外側部132s,132sが径方向に互いに隣在する。   In addition, by this winding process, a large number of positive electrode slit outer portions 122s, 122s,... Are alternately divided into two groups and arranged substantially symmetrically when viewed from the direction of the axis AX. 122s and 122s are adjacent to each other in the radial direction. In addition, a large number of negative electrode slit outer portions 132s, 132s,... Are alternately divided into two groups and arranged substantially symmetrically with respect to the axis AX direction, and the negative electrode slit outer portions 132s, 132s of each group are in the radial direction. Next to each other.

また、正極スリット外側部122s,122s,…の貫通孔122sc,122sc,…が、2つずつ交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の貫通孔122sc,122sc,…が径方向に互いに隣在する。また、負極スリット外側部132s,132s,…の貫通孔132sc,132sc,…が、2つずつ交互に2つの群に分かれて、軸線AX方向から見てほぼ線対称に配置され、各群の貫通孔132sc,132sc,…が径方向に互いに隣在する。   Further, the through holes 122sc, 122sc,... Of the positive electrode slit outer portions 122s, 122s,... Are alternately divided into two groups, and are arranged substantially symmetrically with respect to the axis AX direction. The holes 122sc, 122sc,... Are adjacent to each other in the radial direction. Further, the through holes 132sc, 132sc,... Of the negative electrode slit outer portions 132s, 132s,... Are alternately divided into two groups, and are arranged substantially symmetrically with respect to the axis AX direction. The holes 132sc, 132sc,... Are adjacent to each other in the radial direction.

次に、集電端子部形成工程において、正極帯状端部122mのうち、多数の正極スリット外側部122s,122s,…を、プレスにより、寄せ集め互いに重ねて、軸線AXに直交する断面がH字状をなす正極集電端子部122yを形成する。また、負極帯状端部132mのうち、多数の負極スリット外側部132s,132s,…を、プレスにより、寄せ集め互いに重ねて、軸線AXに直交する断面がH字状をなす負極集電端子部132yを形成する。これにより、正極露出部122r及び負極露出部132rが、軸線AX方向の外側に露出する。かくして、図10及び図11に示す捲回型電極体120が形成される。   Next, in the current collecting terminal part forming step, among the positive electrode belt-shaped end parts 122m, a large number of positive electrode slit outer parts 122s, 122s,... A positive current collecting terminal portion 122y having a shape is formed. Further, among the negative electrode belt-shaped end portions 132m, a large number of negative electrode slit outer portions 132s, 132s,... Are gathered together by pressing to be overlapped with each other, and a negative electrode current collecting terminal portion 132y having a H-shaped cross section perpendicular to the axis AX. Form. Thereby, the positive electrode exposed part 122r and the negative electrode exposed part 132r are exposed to the outside in the direction of the axis AX. Thus, the wound electrode body 120 shown in FIGS. 10 and 11 is formed.

次に、図12に示すように、前述の第1導電プレート151とリード部材155を用意する。そして、図13に示すように、第1導電プレート151の第1接続部151aとリード部材155の第1リード部155aとを互いに重ね、第1接続部151aの貫通孔151ah,151ahと第1リード部155aの貫通孔155ah,155ahとを連通させた状態で、互いに溶接する。   Next, as shown in FIG. 12, the first conductive plate 151 and the lead member 155 are prepared. Then, as shown in FIG. 13, the first connection portion 151a of the first conductive plate 151 and the first lead portion 155a of the lead member 155 are overlapped with each other, and the through holes 151ah and 151ah of the first connection portion 151a and the first lead are overlapped. In a state where the through holes 155ah and 155ah of the portion 155a are communicated with each other, they are welded to each other.

次に、この第1導電プレート151の第1接続部151a及びリード部材155の第1リード部155aと、もう一方の第1導電プレート151の第1接続部151aとの間に、正極集電端子部122yを挟んで、第1接続部151a,151aの貫通孔151ah,151ah,…と、第1リード部155aの貫通孔155ah,155ahと、正極集電端子122yの貫通孔122sc,122scを連通させる(図14参照)。
また、第1導電プレート151,151の第2接続部151b,151bを、正極帯状端部122mの正極露出部122r,122rに、軸線AX方向外側からそれぞれ当接させて、この当接のみにより第2接続部151b,151bと正極露出部122r,122rとを電気的に接続する。
そして、リベット153,153により、第1接続部151a,151a及び第1リード部155aと正極集電端子部122yとを互いに緊結する。
Next, a positive current collecting terminal is provided between the first connecting portion 151a of the first conductive plate 151 and the first lead portion 155a of the lead member 155 and the first connecting portion 151a of the other first conductive plate 151. Through the portion 122y, the through holes 151ah, 151ah,... Of the first connection portions 151a, 151a, the through holes 155ah, 155ah of the first lead portion 155a, and the through holes 122sc, 122sc of the positive current collector terminal 122y are communicated. (See FIG. 14).
Further, the second connection portions 151b and 151b of the first conductive plates 151 and 151 are brought into contact with the positive electrode exposed portions 122r and 122r of the positive electrode strip-shaped end portion 122m from the outside in the axis AX direction, respectively, and the first connection plate 151 and 151b The two connecting portions 151b and 151b and the positive electrode exposed portions 122r and 122r are electrically connected.
Then, the first connecting portions 151a and 151a and the first lead portion 155a and the positive electrode current collecting terminal portion 122y are tightly coupled to each other by the rivets 153 and 153.

次に、前述の第2導電プレート161,161を用意する。そして、一方の第2導電プレート161の第1接続部161aと他方の第2導電プレート161の第1接続部161aとの間に、負極集電端子部132yを挟んで、第1接続部161a,161aの貫通孔と負極集電端子132yの貫通孔132sc,132scを連通させる(図14参照)。
また、第2導電プレート161,161の第2接続部161b,161bを、負極帯状端部132mの負極露出部132r,132rに、軸線AX方向外側からそれぞれ当接させて、この当接のみにより第2接続部161b,161bと負極露出部132r,132rとを電気的に接続する。
そして、リベット163,163により、第1接続部161a,161aと負極集電端子部132yとを互いに緊結する。
Next, the second conductive plates 161 and 161 described above are prepared. Then, the first connecting portion 161a, the negative current collecting terminal portion 132y is sandwiched between the first connecting portion 161a of one second conductive plate 161 and the first connecting portion 161a of the other second conductive plate 161. The through hole 161a and the through holes 132sc and 132sc of the negative electrode current collector terminal 132y are communicated (see FIG. 14).
Further, the second connection portions 161b and 161b of the second conductive plates 161 and 161 are brought into contact with the negative electrode exposed portions 132r and 132r of the negative electrode belt-shaped end portion 132m from the outside in the axis AX direction, respectively, and the first connection is performed only by this contact. The two connecting portions 161b and 161b and the negative electrode exposed portions 132r and 132r are electrically connected.
Then, the first connecting portions 161a and 161a and the negative electrode current collecting terminal portion 132y are coupled to each other by the rivets 163 and 163.

次に、図15に示すように、第2導電プレート161,161の第3接続部161c,161cに、第2蓋部材115の蓋本体部115eを当接させて、これらをレーザ溶接する。
次に、電池ケース本体111を用意し、これに捲回型電極体120等を挿入する。そして、第2蓋部材115と電池ケース本体111の一方の端部111c2との間に、第2ガスケット119(図1参照)を配置し、電池ケース本体111の端部111c2を加締める。これにより、図16に示すように、第2蓋部材115と電池ケース本体111とが電気的に絶縁されつつ、互いに固定される。
次に、図17に示すように、リード部材155の第3接続部155cに、第1蓋部材113の蓋本体部113eを重ねて、これらをレーザ溶接する。
Next, as shown in FIG. 15, the lid main body 115e of the second lid member 115 is brought into contact with the third connecting portions 161c and 161c of the second conductive plates 161 and 161, and these are laser-welded.
Next, the battery case body 111 is prepared, and the wound electrode body 120 and the like are inserted into the battery case body 111. And the 2nd gasket 119 (refer FIG. 1) is arrange | positioned between the 2nd cover member 115 and one edge part 111c2 of the battery case main body 111, and the edge part 111c2 of the battery case main body 111 is crimped. Thereby, as shown in FIG. 16, the second lid member 115 and the battery case body 111 are fixed to each other while being electrically insulated.
Next, as shown in FIG. 17, the lid main body portion 113e of the first lid member 113 is overlapped on the third connection portion 155c of the lead member 155, and these are laser-welded.

次に、図18に示すガタつき防止用のスペーサ171を2つ用意する。そして、これらのスペーサ171,171を、図1及び図19に示すように、電池ケース本体111と捲回型電極体120との間に配置する。
次に、第1蓋部材113と電池ケース本体111の他方の端部111c1との間に、第1ガスケット117(図1参照)を配置し、電池ケース本体111の端部111c1を加締める。これにより、図20に示すように、第1蓋部材113と電池ケース本体111とが電気的に絶縁されつつ、互いに固定される。
次に、第1蓋部材113に設けられた電解液注入口113ehから、電池ケース110内に電解液を注入し、その後、この電解液注入口113ehを栓118により閉塞する。かくして、リチウム二次電池100ができる。
Next, two spacers 171 for preventing rattling shown in FIG. 18 are prepared. These spacers 171 and 171 are arranged between the battery case main body 111 and the wound electrode body 120 as shown in FIGS.
Next, the first gasket 117 (see FIG. 1) is disposed between the first lid member 113 and the other end 111c1 of the battery case main body 111, and the end 111c1 of the battery case main body 111 is crimped. Accordingly, as shown in FIG. 20, the first lid member 113 and the battery case body 111 are fixed to each other while being electrically insulated.
Next, the electrolytic solution is injected into the battery case 110 from the electrolytic solution injection port 113eh provided in the first lid member 113, and then the electrolytic solution injection port 113eh is closed by the plug 118. Thus, the lithium secondary battery 100 is obtained.

以上で説明したように、本実施形態の製造方法では、正電極板121と負電極板131とをセパレータ141を介して重ねて捲回する捲回工程に先だって、スリット形成工程において、正極帯状端部122mに正極スリット122h,122h,…を形成する。また、負極帯状端部132mに負極スリット132h,132h,…を形成する。このようにすることで、正極スリット122h,122h,…を形成する際に生じた切粉や、負極スリット132h,132h,…を形成する際に生じた切粉を、容易に除去できるので、捲回型電極体120内に切粉が混入することを防止できる。従って、信頼性の高いリチウム二次電池100を製造できる。   As described above, in the manufacturing method according to the present embodiment, the positive electrode plate 121 and the negative electrode plate 131 are stacked with the separator 141 interposed therebetween and wound in the slit forming step before the positive electrode belt-shaped end. The positive slits 122h, 122h,... Are formed in the portion 122m. Further, negative electrode slits 132h, 132h,... Are formed in the negative electrode belt-shaped end portion 132m. By doing in this way, the chips generated when forming the positive electrode slits 122h, 122h,... And the chips generated when forming the negative electrode slits 132h, 132h,. It is possible to prevent chips from entering the rotary electrode body 120. Therefore, the lithium secondary battery 100 with high reliability can be manufactured.

また、本実施形態では、前述の捲回工程に先だって、パンチング工程において、正極帯状端部122mの正極スリット外側部122s,122s,…に貫通孔122sc,122sc,…を形成する。また、負極帯状端部132mの負極スリット外側部132s,132s,…に貫通孔132sc,132sc,…を形成する。このようにすることで、貫通孔122sc,122sc,…を形成する際に生じた切粉や、貫通孔132sc,132sc,…を形成する際に生じた切粉を、容易に除去できるので、捲回型電極体120内に切粉が混入することを防止できる。従って、信頼性の高いリチウム二次電池100を製造できる。   Further, in the present embodiment, prior to the winding process described above, through holes 122sc, 122sc,... Are formed in the positive electrode slit outer portions 122s, 122s,. Further, through holes 132sc, 132sc,... Are formed in the negative electrode slit outer portions 132s, 132s,. By doing in this way, the chips generated when forming the through holes 122sc, 122sc,... And the chips generated when forming the through holes 132sc, 132sc,. It is possible to prevent chips from entering the rotary electrode body 120. Therefore, the lithium secondary battery 100 with high reliability can be manufactured.

以上において、本発明を実施形態に即して説明したが、本発明は上述の実施形態に限定されるものではなく、その要旨を逸脱しない範囲で、適宜変更して適用できることは言うまでもない。
例えば、上記実施形態では、第1導電プレート151,151の第1接続部151a,151a及びリード部材155の第1リード部155aと捲回型電極体120の正極集電端子部122yとを、リベット153,153により接続しているが、これらを例えば溶接やハンダ、導電接着剤などにより接続することもできる。同様に、第2導電プレート161,161の第1接続部161a,161aと捲回型電極体120の負極集電端子部132yとを、リベット163,163により接続しているが、これらを例えば溶接やハンダ、導電性接着剤などにより接続することもできる。
In the above, the present invention has been described with reference to the embodiment. However, the present invention is not limited to the above-described embodiment, and it is needless to say that the present invention can be appropriately modified and applied without departing from the gist thereof.
For example, in the above embodiment, the first connecting portions 151a and 151a of the first conductive plates 151 and 151 and the first lead portion 155a of the lead member 155 and the positive electrode current collecting terminal portion 122y of the wound electrode body 120 are connected to the rivet. These are connected by 153 and 153, but they can also be connected by welding, solder, conductive adhesive or the like. Similarly, the first connecting portions 161a and 161a of the second conductive plates 161 and 161 and the negative electrode current collecting terminal portion 132y of the wound electrode body 120 are connected by rivets 163 and 163. It can also be connected with solder, conductive adhesive, or the like.

100 リチウム二次電池(電池)
110 電池ケース
111 電池ケース本体
111h1,111h2 開口
113 第1蓋部材(外部電極部材)
115 第2蓋部材(外部電極部材)
120 捲回型電極体
121 正電極板
122 正極金属箔集電体
122m 第1正極未塗工部(帯状端部)
122h 正極スリット
122s 正極スリット外側部
122y 正極集電端子部
122r 正極露出部
123 正極活物質層
131 負電極板
132 負極金属箔集電体
132m 第1負極未塗工部(帯状端部)
132h 負極スリット
132s 負極スリット外側部
132y 負極集電端子部
132r 負極露出部
133 負極活物質層
141 セパレータ
151 第1導電プレート(導電部材)
151a 第1接続部
151b 第2接続部
155 リード部材
161 第2導電プレート(導電部材)
161a 第1接続部
161b 第2接続部
161c 第3接続部
AX 軸線
100 Lithium secondary battery (battery)
110 Battery Case 111 Battery Case Body 111h1, 111h2 Opening 113 First Lid Member (External Electrode Member)
115 Second lid member (external electrode member)
120 wound electrode body 121 positive electrode plate 122 positive electrode metal foil current collector 122m first positive electrode uncoated portion (band-shaped end)
122h Positive electrode slit 122s Positive electrode slit outer part 122y Positive electrode current collector terminal part 122r Positive electrode exposed part 123 Positive electrode active material layer 131 Negative electrode plate 132 Negative electrode metal foil current collector 132m First negative electrode uncoated part (band-like end part)
132h Negative electrode slit 132s Negative electrode slit outer portion 132y Negative current collecting terminal portion 132r Negative electrode exposed portion 133 Negative electrode active material layer 141 Separator 151 First conductive plate (conductive member)
151a First connection portion 151b Second connection portion 155 Lead member 161 Second conductive plate (conductive member)
161a 1st connection part 161b 2nd connection part 161c 3rd connection part AX Axis line

Claims (5)

正極金属箔集電体及びこの正極金属箔集電体上に形成された正極活物質層を有する長尺状の正電極板と、負極金属箔集電体及びこの負極金属箔集電体上に形成された負極活物質層を有する長尺状の負電極板とを長尺状のセパレータを介して互いに重ねて軸線周りに捲回してなる捲回型電極体であって、
前記軸線方向の一端側に、前記正極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出すると共に、
前記軸線方向の他端側に、前記負極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出してなる捲回型電極体、を備える
電池であって、
前記正極金属箔集電体の帯状端部及び前記負極金属箔集電体の帯状端部のうち、少なくとも一方の帯状端部は、その長手方向に断続的に延びると共に、捲回された状態で径方向に互いに隣在する複数のスリットを有し、
この帯状端部のうち、前記スリットよりも前記幅方向の外側に位置すると共に、捲回された状態で径方向に互いに隣在する複数のスリット外側部を、寄せ集め互いに重ねて集電端子部を構成してなる
電池。
A positive electrode metal foil current collector and a long positive electrode plate having a positive electrode active material layer formed on the positive electrode metal foil current collector; a negative electrode metal foil current collector; and the negative electrode metal foil current collector A wound-type electrode body formed by winding a long negative electrode plate having a formed negative electrode active material layer and winding them around an axis line with a long separator interposed therebetween,
On one end side in the axial direction, the strip-shaped end portion that is exposed and located at the end in the width direction of the positive electrode metal foil current collector forms a spiral shape, and protrudes from the separator,
On the other end side in the axial direction, a wound type in which a strip-shaped end portion of the negative electrode metal foil current collector located at the end in the width direction and exposed to form a strip shape spirals and protrudes from the separator A battery comprising an electrode body,
Of the strip-shaped end portion of the positive electrode metal foil current collector and the strip-shaped end portion of the negative electrode metal foil current collector, at least one of the strip-shaped end portions extends intermittently in the longitudinal direction and is wound. Having a plurality of slits adjacent to each other in the radial direction;
Among the strip-shaped end portions, a plurality of slit outer portions that are located outside the slit in the width direction and are adjacent to each other in the radial direction in a wound state are gathered and overlapped with each other to collect current collecting terminal portions A battery comprising
請求項1に記載の電池であって、
前記正極金属箔集電体及び前記負極金属箔集電体の各々に、前記集電端子部を有する
電池。
The battery according to claim 1,
The battery which has the said current collection terminal part in each of the said positive electrode metal foil collector and the said negative electrode metal foil collector.
請求項1または請求項2に記載の電池であって、
前記帯状端部は、前記スリットよりも前記軸線方向の内側に位置し、前記スリット外側部を寄せ集めて前記集電端子部を構成したことにより、前記軸線方向の外側に露出する露出部を有し、
前記帯状端部に電気的に接続する導電性の導電部材であって、
前記集電端子部に前記軸線に直交する方向から当接して、この集電端子部に電気的に接続する第1接続部と、
前記第1接続部と導通し、前記露出部に前記軸線方向の外側から当接して、この露出部に電気的に接続する第2接続部と、を有する
導電部材、を更に備える
電池。
The battery according to claim 1 or 2,
The strip-shaped end portion is located on the inner side in the axial direction from the slit, and has an exposed portion exposed to the outer side in the axial direction by forming the current collecting terminal portion by gathering the outer portions of the slit. And
A conductive member electrically connected to the strip-shaped end,
A first connecting portion that contacts the current collecting terminal portion from a direction orthogonal to the axis and is electrically connected to the current collecting terminal portion;
A battery further comprising: a conductive member having a second connection portion that is electrically connected to the first connection portion, contacts the exposed portion from the outside in the axial direction, and is electrically connected to the exposed portion.
請求項3に記載の電池であって、
開口を有し、前記捲回型電極体を収容する電池ケース本体と、
前記電池ケース本体の前記開口を閉塞すると共に、この電池の外部電極をなす外部電極部材と、を有する
電池ケースを備え、
前記導電部材は、前記第1接続部から延び、前記外部電極部材に当接して、この外部電極部材に電気的に接続する第3接続部を有する
電池。
The battery according to claim 3,
A battery case body having an opening and accommodating the wound electrode body;
An external electrode member that closes the opening of the battery case body and forms an external electrode of the battery, and includes a battery case.
The battery includes a third connection portion that extends from the first connection portion, contacts the external electrode member, and is electrically connected to the external electrode member.
正極金属箔集電体及びこの正極金属箔集電体上に形成された正極活物質層を有する長尺状の正電極板と、負極金属箔集電体及びこの負極金属箔集電体上に形成された負極活物質層を有する長尺状の負電極板とを長尺状のセパレータを介して互いに重ねて軸線周りに捲回してなる捲回型電極体であって、
前記軸線方向の一端側に、前記正極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出すると共に、
前記軸線方向の他端側に、前記負極金属箔集電体のうち幅方向の端に位置し露出して帯状をなす帯状端部が渦巻き状をなして、前記セパレータから突出してなる捲回型電極体、を備え、
前記正極金属箔集電体の帯状端部及び前記負極金属箔集電体の帯状端部のうち、少なくとも一方の帯状端部は、その長手方向に断続的に延びると共に、捲回された状態で径方向に互いに隣在する複数のスリットを有し、
この帯状端部のうち、前記スリットよりも前記幅方向の外側に位置すると共に、捲回された状態で径方向に互いに隣在する複数のスリット外側部を、寄せ集め互いに重ねて集電端子部を構成してなる
電池の製造方法であって、
前記正電極板と前記負電極板とを前記セパレータを介して互いに重ねて前記軸線周りに捲回する捲回工程であって、前記一端側に前記正極金属箔集電体の前記帯状端部が突出し、前記他端側に前記負極金属箔集電体の帯状端部が突出すると共に、各々の前記スリットが径方向に互いに隣在する形態に捲回する捲回工程と、
前記捲回工程に先だって、前記帯状端部に前記スリットを形成するスリット形成工程と、
前記捲回工程後、前記帯状端部のうち、前記スリット外側部を、寄せ集め互いに重ねて前記集電端子部を形成する集電端子部形成工程と、を備える
電池の製造方法。
A positive electrode metal foil current collector and a long positive electrode plate having a positive electrode active material layer formed on the positive electrode metal foil current collector; a negative electrode metal foil current collector; and the negative electrode metal foil current collector A wound-type electrode body formed by winding a long negative electrode plate having a formed negative electrode active material layer and winding them around an axis line with a long separator interposed therebetween,
On one end side in the axial direction, the strip-shaped end portion that is exposed and located at the end in the width direction of the positive electrode metal foil current collector forms a spiral shape, and protrudes from the separator,
On the other end side in the axial direction, a wound type in which a strip-shaped end portion of the negative electrode metal foil current collector located at the end in the width direction and exposed to form a strip shape spirals and protrudes from the separator An electrode body,
Of the strip-shaped end portion of the positive electrode metal foil current collector and the strip-shaped end portion of the negative electrode metal foil current collector, at least one of the strip-shaped end portions extends intermittently in the longitudinal direction and is wound. Having a plurality of slits adjacent to each other in the radial direction;
Among the strip-shaped end portions, a plurality of slit outer portions that are located outside the slit in the width direction and are adjacent to each other in the radial direction in a wound state are gathered and overlapped with each other to collect current collecting terminal portions A battery manufacturing method comprising:
A winding step in which the positive electrode plate and the negative electrode plate are overlapped with each other via the separator and wound around the axis line, and the band-shaped end portion of the positive electrode metal foil current collector is disposed on the one end side. A winding step in which the strip-shaped end of the negative electrode metal foil current collector protrudes on the other end side, and the slits are wound in a form adjacent to each other in the radial direction;
Prior to the winding step, a slit forming step of forming the slit in the band-shaped end,
A battery manufacturing method comprising: a current collecting terminal part forming step of forming the current collecting terminal part by gathering the slit outer parts out of the belt-shaped end part and gathering each other after the winding process.
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