FR2338945A1 - Nouveaux composes organometalliques lithies et leur application comme catalyseurs de polymerisation et de copolymerisation - Google Patents
Nouveaux composes organometalliques lithies et leur application comme catalyseurs de polymerisation et de copolymerisationInfo
- Publication number
- FR2338945A1 FR2338945A1 FR7601915A FR7601915A FR2338945A1 FR 2338945 A1 FR2338945 A1 FR 2338945A1 FR 7601915 A FR7601915 A FR 7601915A FR 7601915 A FR7601915 A FR 7601915A FR 2338945 A1 FR2338945 A1 FR 2338945A1
- Authority
- FR
- France
- Prior art keywords
- lithium
- catalysts
- polymerisation
- atoms
- steps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052744 lithium Inorganic materials 0.000 title 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title 1
- 150000004984 aromatic diamines Chemical class 0.000 title 1
- 229920001400 block copolymer Polymers 0.000 title 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 125000002897 diene group Chemical group 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
- C08F4/486—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium at least two metal atoms in the same molecule
- C08F4/488—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium at least two metal atoms in the same molecule at least two lithium atoms in the same molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/02—Lithium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
- C08F4/484—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium an alkali metal bound to a cyclic carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7601915A FR2338945A1 (fr) | 1976-01-23 | 1976-01-23 | Nouveaux composes organometalliques lithies et leur application comme catalyseurs de polymerisation et de copolymerisation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7601915A FR2338945A1 (fr) | 1976-01-23 | 1976-01-23 | Nouveaux composes organometalliques lithies et leur application comme catalyseurs de polymerisation et de copolymerisation |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2338945A1 true FR2338945A1 (fr) | 1977-08-19 |
FR2338945B1 FR2338945B1 (fr) | 1979-10-05 |
Family
ID=9168323
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7601915A Granted FR2338945A1 (fr) | 1976-01-23 | 1976-01-23 | Nouveaux composes organometalliques lithies et leur application comme catalyseurs de polymerisation et de copolymerisation |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2338945A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0316857A3 (fr) * | 1987-11-16 | 1991-02-06 | The Dow Chemical Company | Initiateur contenant la fonction amine pour la polymérisation anionique |
-
1976
- 1976-01-23 FR FR7601915A patent/FR2338945A1/fr active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0316857A3 (fr) * | 1987-11-16 | 1991-02-06 | The Dow Chemical Company | Initiateur contenant la fonction amine pour la polymérisation anionique |
Also Published As
Publication number | Publication date |
---|---|
FR2338945B1 (fr) | 1979-10-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2192825A1 (fr) | Complexes dieniques metalliques du groupe 4, et catalyseurs de polymerisation par addition tires de ceux-ci | |
EP0227124A3 (en) | Olefinic benzocyclobutene polymers and processes for the preparation thereof | |
AU1887076A (en) | Controlling molecular weight distribution of latex polymers | |
DE3853810D1 (de) | Propylenpolymere und Herstellung derselben. | |
GB1454229A (en) | Block polymers of styrene-butadiene-2-vinylpyridine | |
GB1010060A (en) | Improvements in and relating to polymers | |
FR2338945A1 (fr) | Nouveaux composes organometalliques lithies et leur application comme catalyseurs de polymerisation et de copolymerisation | |
US4009150A (en) | Time-lapse free-radical polymerizable composition | |
GB1518206A (en) | Preparation of homopolymers and copolymers of conjugated dienes | |
IE44690L (en) | Compositions containing polyvinylbenzenesulphonic acids. | |
GB1311943A (en) | Preparation of organodilithium initiator and polymerizations utilizing same | |
GB2090157B (en) | Phosphated alumina or aluminum phosphate chromium-containing olefin polymerisation catalyst process for the preparation and use thereof | |
GB1488401A (en) | Process for producing polymers from ethylenically unsaturated monomers | |
Johansson et al. | Influence of allyl ethers on free radical polymerization of styrene | |
DE59602934D1 (de) | Verfahren zur Herstellung von verzweigten Polymerisaten | |
SU454811A1 (ru) | Способ получени органокремнийорганических полимеров | |
JPS5486587A (en) | Propylene polymer for injection molding | |
JPS51129475A (en) | A process for polymerizing monomers | |
ES8100664A1 (es) | Procedimiento para la preparacion de polimeros de cloruro devinilo y recipiente de polimerizacion para realizacion del procedimiento | |
JPS5284268A (en) | Preparation of super-high-molecular-weight polymers | |
Furukawa et al. | Alternating Copolymerization of Acetylenic Donor and Acceptor Monomers | |
JPS5284269A (en) | Preparation of super-high-molecular-weight polymers | |
ES445565A1 (es) | Procedimiento de preparacion de polimeros de dienos conjugados y de copolimeros de dienos conjugados | |
JPS5355388A (en) | Preparation of conjugated diolefinic polymer | |
Deshpande et al. | Polymerization of styrene with chromium acetylacetonate–triisobutylaluminum catalyst system |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |