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CN102294869A - Epoxy powder insulating anticorrosive paint - Google Patents

Epoxy powder insulating anticorrosive paint Download PDF

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Publication number
CN102294869A
CN102294869A CN2011101608665A CN201110160866A CN102294869A CN 102294869 A CN102294869 A CN 102294869A CN 2011101608665 A CN2011101608665 A CN 2011101608665A CN 201110160866 A CN201110160866 A CN 201110160866A CN 102294869 A CN102294869 A CN 102294869A
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China
Prior art keywords
epoxy resin
agent
paint
subbing
curing agent
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Pending
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CN2011101608665A
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Chinese (zh)
Inventor
吴金岳
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KEXIN CORROSION CONTROL ENGINEERING Co Ltd NINGBO
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KEXIN CORROSION CONTROL ENGINEERING Co Ltd NINGBO
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Priority to CN2011101608665A priority Critical patent/CN102294869A/en
Publication of CN102294869A publication Critical patent/CN102294869A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to a thermosetting epoxy powder insulation anticorrosive paint, comprising a priming paint and a topping paint which together form a electrical isolating anticorrosive coating, the priming paint comprises epoxy resin, curing agent and auxiliary agent, the topping paint comprises epoxy resin, curing agent, filling material and other auxiliary agents, and the priming paint and the topping paint are prepared into powder products with melt extrusion mixing method. According to the invention, the priming paint contains no or little filling material, so that the adhesion force of the formed base coating is not influenced; and the topping paint performs main functions of electrical isolation, corrosion resistance and the like, so that the paint disclosed in the invention has strong adhesion force and good electrical isolation performance, has the functions of corrosion resistance, rust resistance, mildew resistance, heat resistance, wear resistance and the like, and has the advantages of low cost.

Description

A kind of epoxy powder insulating corrosion coating
Technical field
The invention belongs to the powdery paints technical field, be specifically related to heat curing-type epoxy powder insulating corrosion coating.
Technical background
Specific functions such as applying coating is at object surface, forms to adhere to firmly, have certain intensity, continuous coating, coated object played protection, decoration effect, or make it have insulation, antirust, mildew-resistant, heat-resisting, and is wear-resisting.The patent No. is 200410014489.4 patent of invention " electromagnetic wire insulating powder coating ", discloses a kind of insulating powder coating that is used for electromagnetic wire electrostatic spraying technology.This insulating powder coating film or the property of coating is an electrical insulation capability.This powdery paints is made up of resin, curing agent and auxiliary material, and wherein higher resin and the hardener dose of price accounts for 98%, and the lower amount of filler of price only accounts for 1~2%.If increase substantially amount of filler, bring up to such as amount of filler and to account for 20~40%, then can significantly reduce the consumption of resin and curing agent, reduce the manufacturing cost of coating.But, increase substantially the content of filler in the coating, may cause the reduction of paint adhesion.If the coating separated into two parts, a part is a subbing, does not contain or contains filler less, is used to be coated in object surface.Because of it does not contain or contain less filler, formed primer coating adhesive force is unaffected.Another part is an investment precoat, is coated in the primer coating surface, and the surface layer coating of formation is born main electric insulation, function such as anticorrosive.So both can reduce the coating cost, guarantee again that adhesive force did not reduce, also guarantee its excellent electric insulation, function such as anticorrosive.The present invention just relates to this heat curing-type epoxy powder insulating corrosion coating of being made up of subbing and investment precoat.
Summary of the invention
The invention provides that a kind of strong adhesion, electrical insulation capability are good, anticorrosion, heat curing-type epoxy powder insulating corrosion coating that cost is low.
This epoxy powder insulating corrosion coating comprises subbing and investment precoat, subbing is coated on needs electric insulation and etch-proof object to ask clean surface, investment precoat is coated on by the formed primer coating of subbing surface, forms the etch-proof coating of electric insulation jointly.
Subbing is made up of epoxy resin, curing agent and auxiliary agent, and its percentage by weight is 49~85: 5~49: 2~10.Epoxy resin can be bis-phenol, A type epoxy resin or phenol aldehyde modified epoxy resin.Curing agent can be phenolic hydroxyl group resin, dicyandiamide, replacement dicyandiamide or dicarboxyl acid dihydrazide.Auxiliary agent is made up of flexibilizer, levelling agent, defoamer and promoter, and its percentage by weight is 40~70: 10~20: 10~20: 10~20.Wherein, flexibilizer can be phthalate or epoxy ester series; Levelling agent can be polyethyl acrylate or butyl acrylate; Defoamer can be common defoamer ZS-601 or high effective antifoaming agent ZS-603; Promoter can be glyoxal ethyline quinoline, 2-benzylimidazoline, ring amidine, croak pyridine, guanidine or urea derivative.
Investment precoat is made up of epoxy resin, curing agent, filler and other auxiliary agents, and its percentage by weight is 25~44: 25~44: 10~40: 2~10.Epoxy resin can be bisphenol A type epoxy resin or phenol aldehyde modified epoxy resin.Curing agent can be phenolic hydroxyl group resin, dicyandiamide, replacement dicyandiamide or dicarboxyl acid dihydrazide.Filler can be a precipitation Two Silica, aerosil or mica powder.Other auxiliary agents are made up of flexibilizer, levelling agent and promoter, and its percentage by weight is 50~70: 15~25: 15~25.Flexibilizer can be phthalate or epoxy ester series; Levelling agent can be polyethyl acrylate or butyl acrylate; Promoter can be glyoxal ethyline quinoline, 2-benzylimidazoline, ring amidine, croak pyridine, guanidine or urea derivative.
Subbing and investment precoat all adopt and melt extrude mixing method and make powder product.Adopt the method that applies the heat curing-type epoxy powder electric insulation anticorrosive paint of forming by subbing and investment precoat that conducting copper is carried out electric insulation and preservative treatment.
Insulating corrosion coating coating of the present invention is because separated into two parts, subbing does not contain or contains less filler, formed primer coating adhesive force is unaffected, investment precoat is born main electric insulation, function such as anticorrosive, thereby paint adhesion of the present invention is strong, electrical insulation capability is good, have anticorrosion, antirust, mildew-resistant, heat-resisting, function such as wear-resisting, and have the low characteristics of cost.
Embodiment
Subbing of the present invention and investment precoat all adopt and melt extrude mixing method and make powder product, meet HG/T2006-2006 " thermosetting powder coating " standard-required.
Its subbing and investment precoat formulation Example are as follows:
The subbing prescription:
Figure BSA00000517977500021
The investment precoat prescription:

Claims (8)

1. an epoxy powder insulating corrosion coating is characterized in that: be made up of subbing and investment precoat, form the etch-proof coating of electric insulation jointly.
2. according to the described anticorrosive paint of claim 1, it is characterized in that: described subbing is made up of epoxy resin, curing agent and auxiliary agent; Epoxy resin can be bisphenol A type epoxy resin or phenol aldehyde modified epoxy resin; Curing agent can be phenolic hydroxyl group resin, dicyandiamide, replacement dicyandiamide or dicarboxyl acid dihydrazide; Auxiliary agent is made up of flexibilizer, levelling agent, defoamer and promoter, and wherein: flexibilizer can be phthalate or epoxy ester series; Levelling agent can be polyethyl acrylate or butyl acrylate; Defoamer can be common defoamer ZS-601 or high effective antifoaming agent ZS-603; Promoter can be glyoxal ethyline quinoline, 2-benzylimidazoline, ring amidine, croak pyridine, guanidine or urea derivative.
3. according to the described anticorrosive paint of claim 2, it is characterized in that: epoxy resin, curing agent and auxiliary agent weight ratio that described subbing is formed are 49~85: 5~49: 2~10; Flexibilizer, levelling agent, defoamer and promoter weight ratio that described auxiliary agent is formed are 40~70: 10~20: 10~20: 10~20.
4. according to claim 2,3 described anticorrosive paints, it is characterized in that:
The subbing prescription:
Figure FSA00000517977400011
5. according to the described anticorrosive paint of claim 1, it is characterized in that: described investment precoat is made up of epoxy resin, curing agent, filler and other auxiliary agents; Epoxy resin can be bisphenol A type epoxy resin or phenol aldehyde modified epoxy resin; Curing agent can be phenolic hydroxyl group resin, dicyandiamide, replacement dicyandiamide or dicarboxyl acid dihydrazide; Filler can be precipitated silica, aerosil or mica powder; Other auxiliary agents are made up of flexibilizer, levelling agent and promoter; Flexibilizer can be phthalate or epoxy ester series; Levelling agent can be polyethyl acrylate or butyl acrylate; Promoter can be glyoxal ethyline quinoline, 2-benzylimidazoline, ring amidine, croak pyridine, guanidine or urea derivative.
6. according to the described anticorrosive paint of claim 5, it is characterized in that: epoxy resin, curing agent, filler and other auxiliary agent percentage by weights that described investment precoat is formed are 25~44: 25~44: 10~40: 2~10; Flexibilizer, levelling agent and promoter percentage by weight that described other auxiliary agents are formed are 50~70: 15~25: 15~25.
7. according to claim 5,6 described investment precoats, it is characterized in that:
The investment precoat prescription:
Figure FSA00000517977400021
8. the using method of claim 2 and 5 described insulating corrosion coating, it is characterized in that: subbing is coated on needs electric insulation and etch-proof object to ask clean surface, investment precoat is coated on by the formed primer coating of subbing surface, forms the etch-proof coating of electric insulation jointly.
CN2011101608665A 2011-06-16 2011-06-16 Epoxy powder insulating anticorrosive paint Pending CN102294869A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011101608665A CN102294869A (en) 2011-06-16 2011-06-16 Epoxy powder insulating anticorrosive paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011101608665A CN102294869A (en) 2011-06-16 2011-06-16 Epoxy powder insulating anticorrosive paint

Publications (1)

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CN102294869A true CN102294869A (en) 2011-12-28

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497600A (en) * 2013-09-03 2014-01-08 安徽普源分离机械制造有限公司 Insulating powdery paint for electromagnetic wire
CN103773176A (en) * 2014-01-20 2014-05-07 南通钰成光电科技有限公司 Environment-friendly coating for lamp ornament and preparation method of environment-friendly coating
CN103881536A (en) * 2014-02-25 2014-06-25 蚌埠凯盛工程技术有限公司 Halogen-free, flame-retardant and high-temperature-resistant insulating paint
CN103897555A (en) * 2013-11-19 2014-07-02 东南大学 Powder coating with high levelling property
CN104893494A (en) * 2015-05-13 2015-09-09 国润恒科(天津)防腐工程技术有限公司 Powder coating used for heavy-duty corrosion-resistant high-bounding stress double-coating thin layer steel bar, heavy-duty corrosion-resistant high-bounding stress double-coating thin layer steel bar, and manufacturing method and applications of heavy-duty corrosion-resistant high-bounding stress double-coating thin layer steel bar
CN105199535A (en) * 2015-09-18 2015-12-30 广州擎天材料科技有限公司 A kind of pure epoxy powder coating for electromagnetic wire coating and preparation method thereof
WO2016004609A1 (en) * 2014-07-10 2016-01-14 姚红丽 Wear-resistant coating agent for textile equipment
CN105602356A (en) * 2016-02-17 2016-05-25 合肥爱诺伟机械设备有限公司 Wear and corrosion resisting centrifugal pump impeller coating layer and preparation method and application thereof
CN105754454A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Electric insulation anti-corrosion powder coating
CN105754455A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Method for preparing electric insulation anticorrosion powder coating
CN106589319A (en) * 2016-11-22 2017-04-26 天津翔盛新材料有限公司 Four-functional-group super-flexible linear phenolic curing agent dedicated for heavy-duty anticorrosive powder coating, and synthetic method and application thereof
CN111876047A (en) * 2020-07-16 2020-11-03 溧阳市永新绝缘粉末有限公司 High-temperature-resistant rapid-curing insulating powder coating, preparation method and application method thereof
CN114854287A (en) * 2022-06-08 2022-08-05 宁波博士盾纳米新材料科技有限公司 Frosted high-performance composite epoxy steel bar coating and preparation method thereof
CN114990925A (en) * 2021-03-02 2022-09-02 中国制浆造纸研究院有限公司 Preparation method of heat-resistant auxiliary agent
WO2024114726A1 (en) * 2022-11-30 2024-06-06 Valspar Coatings (Shanghai) Co. Ltd. Thermal-insulating electro-insulating coating system and coated article

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050037207A1 (en) * 2002-08-05 2005-02-17 Hirofumi Komiyama Epoxy resin powder coating material
CN1786093A (en) * 2005-11-30 2006-06-14 北京北航天汇科技孵化器有限公司 Expansion type fire retarding epoxide resin powder paint suitable for steel structure and its preparation method
US20070116963A1 (en) * 2003-12-09 2007-05-24 Chuo Hatsujo Kabushiki Kaisha Highly durable spring and method for coating same
CN101928503A (en) * 2009-06-19 2010-12-29 扬州市金晨化工有限公司 Anti-corrosion and super-weatherability powder coating and preparation process thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050037207A1 (en) * 2002-08-05 2005-02-17 Hirofumi Komiyama Epoxy resin powder coating material
US20070116963A1 (en) * 2003-12-09 2007-05-24 Chuo Hatsujo Kabushiki Kaisha Highly durable spring and method for coating same
CN1786093A (en) * 2005-11-30 2006-06-14 北京北航天汇科技孵化器有限公司 Expansion type fire retarding epoxide resin powder paint suitable for steel structure and its preparation method
CN101928503A (en) * 2009-06-19 2010-12-29 扬州市金晨化工有限公司 Anti-corrosion and super-weatherability powder coating and preparation process thereof

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497600B (en) * 2013-09-03 2016-05-04 安徽普源分离机械制造有限公司 A kind of coating material of insulating powder in use for electromagnetic wire
CN103497600A (en) * 2013-09-03 2014-01-08 安徽普源分离机械制造有限公司 Insulating powdery paint for electromagnetic wire
CN103897555A (en) * 2013-11-19 2014-07-02 东南大学 Powder coating with high levelling property
CN103773176A (en) * 2014-01-20 2014-05-07 南通钰成光电科技有限公司 Environment-friendly coating for lamp ornament and preparation method of environment-friendly coating
CN103881536A (en) * 2014-02-25 2014-06-25 蚌埠凯盛工程技术有限公司 Halogen-free, flame-retardant and high-temperature-resistant insulating paint
WO2016004609A1 (en) * 2014-07-10 2016-01-14 姚红丽 Wear-resistant coating agent for textile equipment
CN104893494A (en) * 2015-05-13 2015-09-09 国润恒科(天津)防腐工程技术有限公司 Powder coating used for heavy-duty corrosion-resistant high-bounding stress double-coating thin layer steel bar, heavy-duty corrosion-resistant high-bounding stress double-coating thin layer steel bar, and manufacturing method and applications of heavy-duty corrosion-resistant high-bounding stress double-coating thin layer steel bar
CN105199535B (en) * 2015-09-18 2018-05-29 广州擎天材料科技有限公司 A kind of electromagnetic wire application pure epoxy powdery paints and preparation method thereof
CN105199535A (en) * 2015-09-18 2015-12-30 广州擎天材料科技有限公司 A kind of pure epoxy powder coating for electromagnetic wire coating and preparation method thereof
CN105602356A (en) * 2016-02-17 2016-05-25 合肥爱诺伟机械设备有限公司 Wear and corrosion resisting centrifugal pump impeller coating layer and preparation method and application thereof
CN105602356B (en) * 2016-02-17 2018-06-26 合肥爱诺伟机械设备有限公司 Centrifugal pump impeller coating of wear resistant corrosion resistant and its preparation method and application
CN105754455A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Method for preparing electric insulation anticorrosion powder coating
CN105754454A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Electric insulation anti-corrosion powder coating
CN106589319A (en) * 2016-11-22 2017-04-26 天津翔盛新材料有限公司 Four-functional-group super-flexible linear phenolic curing agent dedicated for heavy-duty anticorrosive powder coating, and synthetic method and application thereof
CN111876047A (en) * 2020-07-16 2020-11-03 溧阳市永新绝缘粉末有限公司 High-temperature-resistant rapid-curing insulating powder coating, preparation method and application method thereof
CN114990925A (en) * 2021-03-02 2022-09-02 中国制浆造纸研究院有限公司 Preparation method of heat-resistant auxiliary agent
CN114990925B (en) * 2021-03-02 2023-06-16 中国制浆造纸研究院有限公司 Preparation method of heat-resistant auxiliary agent
CN114854287A (en) * 2022-06-08 2022-08-05 宁波博士盾纳米新材料科技有限公司 Frosted high-performance composite epoxy steel bar coating and preparation method thereof
CN114854287B (en) * 2022-06-08 2023-03-10 宁波博士盾纳米新材料科技有限公司 Preparation process of frosted high-performance composite epoxy steel bar coating
WO2024114726A1 (en) * 2022-11-30 2024-06-06 Valspar Coatings (Shanghai) Co. Ltd. Thermal-insulating electro-insulating coating system and coated article

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Application publication date: 20111228

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