CN109537074A - Coagulation forming device for cellulose spinning - Google Patents
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- 230000015271 coagulation Effects 0.000 title claims abstract description 88
- 238000005345 coagulation Methods 0.000 title claims abstract description 88
- 238000009987 spinning Methods 0.000 title claims abstract description 76
- 229920002678 cellulose Polymers 0.000 title claims abstract description 51
- 239000001913 cellulose Substances 0.000 title claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 123
- 230000001133 acceleration Effects 0.000 claims abstract description 25
- 238000000465 moulding Methods 0.000 claims description 21
- 238000007711 solidification Methods 0.000 claims description 6
- 230000008023 solidification Effects 0.000 claims description 6
- 230000000153 supplemental effect Effects 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 239000004753 textile Substances 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 8
- 229920003043 Cellulose fiber Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
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- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
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Abstract
公开了用于纤维素纺丝的凝固成型装置,属于纺织机械技术领域。包括凝固浴盘、补充水入口管、第一种多级多孔格栅、加速水管、加速水入口管、浴盘架、出水管和导流锥环。凝固浴盘设置于盘架的内腔中,凝固浴盘的中心设有第一通孔,盘架的中心设有第二通孔,其中,第一通孔与第二通孔对中。补充水入口管穿过盘架的侧壁后,与凝固浴盘的内腔连通。第一种多级多孔格栅设置于补充水入口管的径向。导流锥环的边缘固定连接于第一通孔的内侧,加速水管固定连接于第二通孔的内侧,使得导流锥环的芯孔与加速水管的芯孔顶端对中。加速水入口管与加速水管连通。加速水管的底端与出水管连通并对中。其能够实现纤维素的高速纺丝,并减少纺丝过程中的毛丝、并丝。
Disclosed is a coagulation forming device for cellulose spinning, which belongs to the technical field of textile machinery. It includes a coagulation bath tray, a supplementary water inlet pipe, the first multi-stage porous grid, an acceleration water pipe, an acceleration water inlet pipe, a bath tray holder, a water outlet pipe and a guide cone ring. The coagulation bath tray is arranged in the inner cavity of the tray rack, the center of the coagulation bath tray is provided with a first through hole, and the center of the tray rack is provided with a second through hole, wherein the first through hole and the second through hole are centered. After the supplementary water inlet pipe passes through the side wall of the tray frame, it communicates with the inner cavity of the coagulation bath tray. The first multi-stage porous grid is arranged in the radial direction of the supplementary water inlet pipe. The edge of the guide cone ring is fixedly connected to the inner side of the first through hole, and the accelerating water pipe is fixedly connected to the inner side of the second through hole, so that the core hole of the guide cone ring and the top of the core hole of the acceleration water pipe are centered. The acceleration water inlet pipe is communicated with the acceleration water pipe. The bottom end of the acceleration water pipe is communicated with the water outlet pipe and centered. It can realize high-speed spinning of cellulose, and reduce filaments and filaments in the spinning process.
Description
技术领域technical field
本发明涉及纺织机械技术领域,特别是涉及一种用于纤维素纺丝的凝固成型装置。The invention relates to the technical field of textile machinery, in particular to a coagulation forming device for cellulose spinning.
背景技术Background technique
众所周知,纤维素纤维具有绿色环保、生产流程简短、性能优异等特点,特别用于织物等用途,在高强度形式中,也用于技术用途,如轮胎帘子线。纤维素纤维通过干喷-湿法制备,在纺丝过程中,纤维素丝束经过气隙,液晶区的分子链在剪切力的作用下被拉伸取向,进而进入凝固浴固化成型。因此在通过气隙时,实现纤维素丝束的稳定高速拉伸取向,决定了纤维素纤维的强度与质量。Cellulose fibers are known to be environmentally friendly, have a short production process, and have excellent properties, especially for applications such as fabrics, and in high-strength forms, also for technical applications such as tire cords. Cellulose fibers are prepared by a dry spray-wet method. During the spinning process, the cellulose tow passes through the air gap, and the molecular chains in the liquid crystal region are stretched and oriented under the action of shearing force, and then enter the coagulation bath to solidify and form. Therefore, when passing through the air gap, the stable high-speed stretching orientation of the cellulose tow is achieved, which determines the strength and quality of the cellulose fiber.
现有技术中,在纤维素纺丝生产过程中,往往使用一种纺丝加速漏斗来实现对丝束的高速拉伸,这种漏斗的原理是利用凝固浴液的重力使其从高处流下形成加速液流,丝束随凝固浴液一起流出,即液体流出速度便是纺丝速度。但随着纺丝速度提高,漏斗距水平地面的安装高度也要不断提高,而且其水流速度由漏斗高度控制,调节水速操作复杂,不便于实际生产,同时也限制了纺丝速度的进一步提高。In the prior art, in the production process of cellulose spinning, a spinning acceleration funnel is often used to achieve high-speed drawing of the tow. The principle of this funnel is to use the gravity of the coagulation bath to make it flow down from a high place. The accelerated liquid flow is formed, and the tow flows out with the coagulation bath, that is, the liquid outflow speed is the spinning speed. However, as the spinning speed increases, the installation height of the funnel from the horizontal ground must also be continuously increased, and the water flow speed is controlled by the height of the funnel. The operation of adjusting the water speed is complicated, which is inconvenient for actual production, and also limits the further improvement of the spinning speed. .
发明内容SUMMARY OF THE INVENTION
有鉴于此,本发明提供了一种用于纤维素纺丝的凝固成型装置,其通过稳定的凝固浴加速装置和导流系统,能够实现纤维素的高速纺丝,从而更加适于实用。In view of this, the present invention provides a coagulation molding device for cellulose spinning, which can realize high-speed spinning of cellulose through a stable coagulation bath acceleration device and a flow guiding system, which is more suitable for practical use.
为了达到上述目的,本发明提供的用于纤维素纺丝的凝固成型装置的技术方案如下:In order to achieve the above purpose, the technical scheme of the coagulation molding device for cellulose spinning provided by the present invention is as follows:
本发明提供的用于纤维素纺丝的凝固成型装置包括凝固浴盘(10)、补充水入口管(11)、第一种多级多孔格栅、加速水管(15)、加速水入口管(14)、浴盘架(18)、出水管(16)和导流锥环(6),The coagulation forming device for cellulose spinning provided by the present invention comprises a coagulation bath tray (10), a supplemental water inlet pipe (11), a first multi-stage porous grid, an acceleration water pipe (15), an acceleration water inlet pipe (11). 14), the bath tray frame (18), the water outlet pipe (16) and the guide cone ring (6),
所述凝固浴盘(10)设置于所述盘架(18)的内腔中,于所述凝固浴盘(10)的中心处开设有第一通孔,于所述盘架(18)的中心处开设有第二通孔,其中,所述第一通孔与所述第二通孔对中;The coagulation bath tray (10) is arranged in the inner cavity of the tray frame (18), a first through hole is opened at the center of the coagulation bath tray (10), and a first through hole is opened in the center of the coagulation bath tray (18). A second through hole is opened at the center, wherein the first through hole and the second through hole are centered;
所述补充水入口管(11)穿过所述盘架(18)的侧壁后,与所述凝固浴盘(10)的内腔连通;After the supplementary water inlet pipe (11) passes through the side wall of the tray frame (18), it communicates with the inner cavity of the coagulation bath tray (10);
所述第一种多级多孔格栅设置于所述补充水入口管(11)的径向;The first multi-stage porous grid is arranged in the radial direction of the supplementary water inlet pipe (11);
所述导流锥环(6)的边缘固定连接于所述第一通孔的内侧,所述加速水管(15)固定连接于所述第二通孔的内侧,使得所述导流锥环(6)的芯孔与所述加速水管(15)的芯孔顶端对中;The edge of the guide cone ring (6) is fixedly connected to the inner side of the first through hole, and the accelerating water pipe (15) is fixedly connected to the inner side of the second through hole, so that the guide cone ring ( 6) The core hole is aligned with the top of the core hole of the accelerating water pipe (15);
所述加速水入口管(14)与所述加速水管(15)连通;The acceleration water inlet pipe (14) is communicated with the acceleration water pipe (15);
所述加速水管(15)的底端与所述出水管(16)连通并对中。The bottom end of the accelerating water pipe (15) is communicated with and centered on the water outlet pipe (16).
本发明提供的用于纤维素纺丝的凝固成型装置还可采用以下技术措施进一步实现。The coagulation forming device for cellulose spinning provided by the present invention can be further realized by adopting the following technical measures.
其中,所述补充水入口管(11)包括竖直部和水平部,所述竖直部和水平部之间连通。Wherein, the supplementary water inlet pipe (11) includes a vertical part and a horizontal part, and the vertical part and the horizontal part communicate with each other.
其中,所述第一种多级多孔格栅至少包括第一级多孔格栅(1)和第二级多孔格栅(3),Wherein, the first multi-level porous grid includes at least a first-level porous grid (1) and a second-level porous grid (3),
所述第一级多孔格栅(1)设置于所述竖直部,所述第二级多孔格栅(3)设置于所述水平部。The first-level porous grid (1) is arranged on the vertical part, and the second-level porous grid (3) is arranged on the horizontal part.
其中,所述用于纤维素纺丝的凝固成型装置还包括环形凸台(4),Wherein, the coagulation forming device for cellulose spinning further comprises an annular boss (4),
所述环形凸台(4)与所述凝固浴盘(10)的底面对中,The annular boss (4) is centered with the bottom surface of the coagulation bath tray (10),
所述环形凸台(4)从所述凝固浴盘(10)内侧底部外周开始先凸起后下降,使得所述环形凸台(4)最高点所在的圆与所述环形凸台(4)、所述凝固盘(10)均对中。The annular boss (4) first protrudes and then descends from the outer circumference of the inner bottom of the coagulation bath tray (10), so that the circle where the highest point of the annular boss (4) is located is the same as the annular boss (4) , the solidification discs (10) are all centered.
其中,所述用于纤维素纺丝的凝固成型装置还包括第二种多孔格栅(5),Wherein, the coagulation forming device for cellulose spinning further comprises a second kind of porous grid (5),
所述第二种多孔格栅(5)设置于所述环形凸台(4)的内侧,所述第二种多孔格栅(5)所在圆与所述环形凸台(4)、所述凝固盘(10)均对中。The second type of porous grid (5) is arranged on the inner side of the annular boss (4), and the circle where the second type of porous grid (5) is located is connected to the annular boss (4), the solidification The discs (10) are all centered.
其中,in,
所述导流锥环(6)的中心外侧呈外锥面,所述导流锥环(6)的中心内侧呈锥孔,The outer side of the center of the guide cone ring (6) is an outer cone surface, and the inner side of the center of the guide cone ring (6) is a tapered hole,
所述加速水管(15)的顶端呈内锥面;The top end of the accelerating water pipe (15) is an inner conical surface;
所述外锥面与所述内锥面之间具有V型间隙(7),所述V型间隙(7)的取值范围为0~1.5mm。There is a V-shaped gap (7) between the outer tapered surface and the inner tapered surface, and the value of the V-shaped gap (7) ranges from 0 to 1.5 mm.
其中,所述用于纤维素纺丝的凝固成型装置还包括导流弯头(9)和牵伸出口管(17),Wherein, the coagulation forming device for cellulose spinning further comprises a guide elbow (9) and a drawing outlet pipe (17),
所述导流弯头(9)与所述出水管(16)连通并对中,所述牵伸出口管(17)与所述导流弯头(9)连通并对中,使得所述牵伸出口管(17)的方向与水平方向的夹角ɑ的取值范围满足-15°<ɑ<15°。The diversion elbow (9) is communicated with the water outlet pipe (16) and is centered, and the drawing outlet pipe (17) is communicated and centered with the diversion elbow (9), so that the pulling The value range of the included angle ɑ between the direction of the protruding orifice tube (17) and the horizontal direction satisfies -15°<ɑ<15°.
其中,所述用于纤维素纺丝的凝固成型装置还包括若干导流环(8),Wherein, the coagulation forming device for cellulose spinning further comprises several guide rings (8),
所述导流环(8)设置于所述出水管(16)和/或导流弯头(9)和/或牵伸出口管(17)的内部,并且,所述导流环(8)的外径与容置其的内腔的直径相等。The guide ring (8) is arranged inside the water outlet pipe (16) and/or the guide elbow (9) and/or the drawing outlet pipe (17), and the guide ring (8) The outer diameter is equal to the diameter of the lumen in which it is accommodated.
其中,所述若干导流环(8)包括第一导流环(8a)、第二导流环(8b)和第三导流环(8c),Wherein, the several guide rings (8) include a first guide ring (8a), a second guide ring (8b) and a third guide ring (8c),
所述第一导流环(8a)设置于所述出水管(16)的入口处,The first guide ring (8a) is arranged at the inlet of the water outlet pipe (16),
所述第二导流环(8b)设置于所述导流弯头(9)的转弯处,The second diversion ring (8b) is arranged at the turning of the diversion elbow (9),
所述第三导流环(8c)设置于所述牵伸出口管(17)的出口处。The third guide ring (8c) is arranged at the outlet of the drawn outlet pipe (17).
其中,所述第一种多孔格栅、第二种多孔格栅(5)、导流锥环(6)和若干导流环(8)均由陶瓷制成。Wherein, the first type of porous grid, the second type of porous grid (5), the guide cone ring (6) and the plurality of guide rings (8) are all made of ceramics.
本发明提供的用于纤维素纺丝的凝固成型装置中,基于文丘里原理,在补充水入口管11的径向设置有第一种多级多孔格栅,能够加快补充水进入凝固浴盘10的流速,通过加速后,能够使得纺丝速度达到1200m/min,此外,在导流锥环6到出水管16之间还设有加速水管15,加速水通过加速水入口管14进入加速水管15,因此,本发明提供的用于纤维素纺丝的凝固成型装置能够实现高速纺丝。In the coagulation molding device for cellulose spinning provided by the present invention, based on the Venturi principle, a first multi-stage porous grid is arranged radially of the supplementary water inlet pipe 11, which can accelerate the supplementary water entering the coagulation bath tray 10. After the acceleration, the spinning speed can reach 1200m/min. In addition, there is an acceleration water pipe 15 between the guide cone ring 6 and the water outlet pipe 16, and the acceleration water enters the acceleration water pipe 15 through the acceleration water inlet pipe 14. , therefore, the coagulation molding device for cellulose spinning provided by the present invention can realize high-speed spinning.
附图说明Description of drawings
通过阅读下文优选实施方式的详细描述,各种其他的优点和益处对于本领域普通技术人员将变得清楚明了。附图仅用于示出优选实施方式的目的,而并不认为是对本发明的限制。而且在整个附图中,用相同的参考符号表示相同的部件。在附图中:Various other advantages and benefits will become apparent to those of ordinary skill in the art upon reading the following detailed description of the preferred embodiment. The drawings are for the purpose of illustrating preferred embodiments only and are not to be considered limiting of the invention. Also throughout the drawings, the same reference numerals are used to designate the same parts. In the attached image:
图1为本发明实施例提供的用于纤维素纺丝的凝固成型装置的结构原理示意图;1 is a schematic diagram of the structural principle of a coagulation and molding device for cellulose spinning provided by an embodiment of the present invention;
图2为本发明实施例提供的用于纤维素纺丝的凝固成型装置一个方向的立体结构示意图。FIG. 2 is a schematic three-dimensional structure diagram of one direction of the coagulation molding device for cellulose spinning provided by the embodiment of the present invention.
具体实施方式Detailed ways
本发明为解决现有技术存在的问题,提供一种用于纤维素纺丝的凝固成型装置,其通过稳定的凝固浴加速装置和导流系统,能够实现纤维素的高速纺丝,经由该装置制备得到的纤维素纤维性能优良,并且能够减少纤维素纺丝过程中产生的毛丝、并丝,从而更加适于实用。In order to solve the problems existing in the prior art, the present invention provides a coagulation molding device for cellulose spinning, which can realize high-speed spinning of cellulose through a stable coagulation bath acceleration device and a flow guiding system. The prepared cellulose fibers have excellent properties, and can reduce the filaments and filaments produced in the cellulose spinning process, so that they are more suitable for practical use.
为更进一步阐述本发明为达成预定发明目的所采取的技术手段及功效,以下结合附图及较佳实施例,对依据本发明提出的用于纤维素纺丝的凝固成型装置,其具体实施方式、结构、特征及其功效,详细说明如后。在下述说明中,不同的“一实施例”或“实施例”指的不一定是同一实施例。此外,一或多个实施例中的特征、结构、或特点可由任何合适形式组合。In order to further illustrate the technical means and effects adopted by the present invention to achieve the predetermined purpose of the invention, the following describes the specific implementation of the coagulation and molding device for cellulose spinning according to the present invention with reference to the accompanying drawings and preferred embodiments. , structure, characteristics and efficacy, as detailed below. In the following description, different "an embodiment" or "embodiments" do not necessarily refer to the same embodiment. Furthermore, the features, structures, or characteristics of one or more embodiments may be combined in any suitable form.
本文中术语“和/或”,仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,例如,A和/或B,具体的理解为:可以同时包含有A与B,可以单独存在A,也可以单独存在B,能够具备上述三种任一种情况。The term "and/or" in this document is only an association relationship to describe the associated objects, indicating that there can be three kinds of relationships, for example, A and/or B, which is specifically understood as: A and B may be included at the same time, and a separate relationship may exist. If A exists, B may exist alone, and any of the above three situations can be provided.
发明人经过长期不懈地观察发现,在纤维素纤维通过干喷-湿法制备时,在纺丝过程中,纤维素丝束经过气隙,液晶区的分子链在剪切力的作用下被拉伸取向,进而进入凝固浴固化成型。因此在通过气隙时,实现纤维素丝束的稳定高速拉伸取向,决定了纤维素纤维的强度与质量。传统黏胶长丝纺速一般为100~150m/min,其生产过程中,往往使用一种纺丝加速漏斗来实现对丝束的高速拉伸,这种漏斗的原理是利用凝固浴液的重力使其从高处流下形成加速液流,丝束随凝固浴液一起流出,即液体流出速度便是纺丝速度。但随着纺丝速度提高,漏斗距水平地面的安装高度也要不断提高,而且其水流速度由漏斗高度控制,调节水速操作复杂,不便于实际生产,同时也限制了纺丝速度的进一步提高。After long-term unremitting observation, the inventor found that when cellulose fibers are prepared by the dry spray-wet method, during the spinning process, the cellulose tow passes through the air gap, and the molecular chains in the liquid crystal region are pulled under the action of shearing force. stretch orientation, and then enter the coagulation bath to solidify and form. Therefore, when passing through the air gap, the stable high-speed stretching orientation of the cellulose tow is achieved, which determines the strength and quality of the cellulose fiber. The spinning speed of traditional viscose filaments is generally 100-150m/min. In the production process, a spinning acceleration funnel is often used to achieve high-speed stretching of the tow. The principle of this funnel is to use the gravity of the coagulation bath. It flows down from a height to form an accelerated liquid flow, and the tow flows out with the coagulation bath liquid, that is, the liquid outflow speed is the spinning speed. However, as the spinning speed increases, the installation height of the funnel from the horizontal ground must also be continuously increased, and the water flow speed is controlled by the height of the funnel. The operation of adjusting the water speed is complicated, which is inconvenient for actual production, and also limits the further improvement of the spinning speed. .
参见附图1和附图2,本发明实施例提供的用于纤维素纺丝的凝固成型装置包括凝固浴盘10、补充水入口管11、第一种多级多孔格栅、加速水管15、加速水入口管14、浴盘架18、出水管16和导流锥环6。凝固浴盘10设置于盘架18的内腔中,于凝固浴盘10的中心处开设有第一通孔,于盘架18的中心处开设有第二通孔,其中,第一通孔与第二通孔对中。补充水入口管11穿过盘架18的侧壁后,与凝固浴盘10的内腔连通。第一种多级多孔格栅设置于补充水入口管11的径向。导流锥环6的边缘固定连接于第一通孔的内侧,加速水管15固定连接于第二通孔的内侧,使得导流锥环6的芯孔与加速水管15的芯孔顶端对中。加速水入口管14与加速水管15连通。加速水管15的底端与出水管16连通并对中。Referring to Fig. 1 and Fig. 2, the coagulation molding device for cellulose spinning provided by the embodiment of the present invention includes a coagulation bath tray 10, a supplementary water inlet pipe 11, a first multi-stage porous grid, an accelerating water pipe 15, Accelerate the water inlet pipe 14, the bath tray frame 18, the water outlet pipe 16 and the guide cone ring 6. The coagulation bath tray 10 is arranged in the inner cavity of the tray frame 18 , a first through hole is opened at the center of the coagulation bath tray 10 , and a second through hole is opened at the center of the tray frame 18 , wherein the first through hole and the The second through hole is centered. The supplementary water inlet pipe 11 communicates with the inner cavity of the coagulation bath tray 10 after passing through the side wall of the tray frame 18 . The first multi-stage porous grid is arranged in the radial direction of the supplementary water inlet pipe 11 . The edge of the guide cone 6 is fixedly connected to the inside of the first through hole, and the accelerating water pipe 15 is fixedly connected to the inside of the second through hole, so that the core hole of the guide cone 6 and the top of the core hole of the accelerating water pipe 15 are centered. The acceleration water inlet pipe 14 communicates with the acceleration water pipe 15 . The bottom end of the acceleration water pipe 15 is communicated with the water outlet pipe 16 and is centered.
本发明实施例提供的用于纤维素纺丝的凝固成型装置中,基于文丘里原理,在补充水入口管11的径向设置有第一种多级多孔格栅,能够加快补充水进入凝固浴盘10的流速,通过加速后,能够使得纺丝速度达到1200m/min,此外,在导流锥环6到出水管16之间还设有加速水管15,加速水通过加速水入口管14进入加速水管15,因此,本发明提供的用于纤维素纺丝的凝固成型装置能够实现高速纺丝。In the coagulation molding device for cellulose spinning provided by the embodiment of the present invention, based on the Venturi principle, a first multi-stage porous grid is arranged radially of the supplementary water inlet pipe 11, which can accelerate the supplementary water entering the coagulation bath. The flow rate of the disc 10, after being accelerated, can make the spinning speed reach 1200m/min. In addition, there is an accelerating water pipe 15 between the guide cone ring 6 and the water outlet pipe 16, and the accelerating water enters the accelerating water through the accelerating water inlet pipe 14. Therefore, the coagulation and forming device for cellulose spinning provided by the present invention can realize high-speed spinning.
其中,补充水入口管11包括竖直部和水平部,竖直部和水平部之间连通。本实施例中,第一种多级多孔格栅至少包括第一级多孔格栅1和第二级多孔格栅3。第一级多孔格栅1设置于竖直部,第二级多孔格栅3设置于水平部。本实施例中,第一种多级多孔格栅包括三级多孔格栅,其中,第一级多孔格栅1水平放置,处于补充水入口管11的竖直部,孔径为1500~2000μm,第二级多孔格栅2水平放置,处于补充水入口管11的竖直部,孔径为800~1500μm,第三级多孔格栅3竖直放置,处于补充水入口管11的水平部,孔径为400~800μm;更为优选地,第一级多孔格栅1孔径为1700~1900μm,第二级多孔格栅2孔径为1000~1300μm,第三级多孔格栅3孔径为500~750μm。在这种情况下通过多级多孔格栅(本实施例中,包括第一级多孔格栅1、第二级多孔格栅2和第三级多孔格栅3),可以使补充水入口管11腔体内的水流逐级分配,从而使补充水入口管11腔体内每两级多孔格栅之间(本实施例中,为第一级多空格栅1和第二级多孔格栅2之间,第二级多孔格栅2与第三级多孔格栅3之间)的水流更加均匀平稳,逐级缩小多孔格栅孔径(本实施例中,第三级多孔格栅3的孔径<第二级多孔格栅2的孔径<第一级多孔格栅1的孔径)是为了保证补充水入口管11腔体内每两级多孔格栅之间(本实施例中,为第一级多空格栅1和第二级多孔格栅2之间,第二级多孔格栅2与第三级多孔格栅3之间)充满补充水,最终水流以趋向于环面的形式溢出到凝固浴盘10内,从而使得凝固浴盘10内的液面各向同性,而不至于有的位置水流过急,而有的位置水流过缓而造成凝固浴盘10内部的涡流,从而使本发明实施例提供的用于纤维素纺丝的凝固成型装置更加稳定。Wherein, the supplementary water inlet pipe 11 includes a vertical part and a horizontal part, and the vertical part and the horizontal part communicate with each other. In this embodiment, the first multi-level porous grid includes at least a first-level porous grid 1 and a second-level porous grid 3 . The first-stage porous grid 1 is arranged on the vertical part, and the second-level porous grid 3 is arranged on the horizontal part. In this embodiment, the first multi-level porous grid includes a three-level porous grid, wherein the first-level porous grid 1 is placed horizontally, at the vertical part of the supplementary water inlet pipe 11, and the pore size is 1500-2000 μm. The secondary porous grid 2 is placed horizontally, at the vertical part of the supplemental water inlet pipe 11, and the pore size is 800-1500 μm; ˜800 μm; more preferably, the aperture of the first-stage porous grid 1 is 1700-1900 μm, the aperture of the second-stage porous grid 2 is 1000-1300 μm, and the aperture of the third-stage porous grid 3 is 500-750 μm. In this case, through the multi-stage porous grid (in this embodiment, including the first-stage porous grid 1, the second-stage porous grid 2 and the third-stage porous grid 3), the supplementary water inlet pipe 11 can be The water flow in the cavity is distributed step by step, so that the supplementary water inlet pipe 11 is between every two stages of porous grids in the cavity (in this embodiment, it is between the first-level porous grid 1 and the second-level porous grid 2 ). , the water flow between the second-level porous grid 2 and the third-level porous grid 3) is more uniform and stable, and the pore size of the porous grid is gradually reduced (in this embodiment, the pore size of the third-level porous grid 3 < the second The pore size of the first-stage porous grid 2 < the pore size of the first-stage porous grid 1) is to ensure that every two-stage porous grid in the cavity of the supplementary water inlet pipe 11 (in this embodiment, it is the first-stage porous grid 1 and the second-level porous grid 2, between the second-level porous grid 2 and the third-level porous grid 3) is filled with supplementary water, and finally the water flow overflows into the coagulation bath tray 10 in the form of a torus. , so that the liquid level in the coagulation bath tray 10 is isotropic, and the water flow in some positions is not too fast, while the water flow in some positions is too slow, causing eddy currents inside the coagulation bath tray 10, so that the embodiment of the present invention provides The coagulation forming device for cellulose spinning is more stable.
其中,用于纤维素纺丝的凝固成型装置还包括环形凸台4。环形凸台4与凝固浴盘10的底面对中。环形凸台4从凝固浴盘10内侧底部外周开始先凸起后下降,使得环形凸台4最高点所在的圆与环形凸台4、凝固盘10均对中。Wherein, the coagulation forming device for cellulose spinning also includes an annular boss 4 . The annular boss 4 is centered on the bottom surface of the coagulation bath tray 10 . The annular boss 4 first bulges and then descends from the outer periphery of the inner bottom of the coagulation bath tray 10 , so that the circle where the highest point of the annular boss 4 is located is aligned with the annular boss 4 and the coagulation tray 10 .
其中,用于纤维素纺丝的凝固成型装置还包括第二种多孔格栅5。第二种多孔格栅5设置于环形凸台4的内侧,第二种多孔格栅5所在圆与环形凸台4、凝固盘10均对中。第二种多孔格栅5竖直放置,第二种多孔格栅5孔径为1000~1500μm。该环形凸台4内侧设的多孔格栅5为可拆卸的多孔格栅,在这种情况下,参见附图2,经过环形凸台4后,补充水分别从多空格栅5的孔19a、19b、19c和19d四个方向进入导流锥环6,能够消除或者减少凝固浴水流的湍流,实现凝固浴液面平稳,减少纺丝过程中丝束波动造成的并丝,从而保证经过本发明实施例提供的用于纤维素纺丝的凝固成型装置进行纺丝后所得的纤维的质量。Wherein, the coagulation forming device for cellulose spinning also includes a second type of porous grid 5 . The second type of porous grid 5 is arranged on the inner side of the annular boss 4 , and the circle where the second type of porous grid 5 is located is centered on the annular boss 4 and the solidification disk 10 . The second type of porous grid 5 is placed vertically, and the second type of porous grid 5 has a pore diameter of 1000-1500 μm. The porous grid 5 provided on the inner side of the annular boss 4 is a detachable porous grid. In this case, referring to FIG. 2 , after passing through the annular boss 4 , the supplementary water flows from the holes 19 a of the porous grid 5 respectively. , 19b, 19c and 19d enter the guide cone ring 6 in four directions, which can eliminate or reduce the turbulence of the coagulation bath water flow, achieve a stable coagulation bath liquid level, and reduce the filament bundle caused by the fluctuation of the tow during the spinning process. The quality of the fibers obtained after spinning by the coagulation molding device for cellulose spinning provided in the embodiments of the invention.
其中,导流锥环6的中心外侧呈外锥面,导流锥环6的中心内侧呈锥孔,加速水管15的顶端呈内锥面。外锥面与内锥面之间具有V型间隙7,V型间隙7的取值范围为0~1.5mm。加速水水速可调,水速范围150~1000m/min,凝固浴加速水以垂直于凝固浴加速水管道的方向进入。导流锥环6的外锥面与加速水管15的内锥面之间具有V型间隙7,水流从V型间隙7的上方总管进入,随着进入V型间隙7水流流速瞬间变大,进而在V型间隙7下端形成一个真空区,当后续水流靠近真空区时,便会产生一定的吸附作用,进而实现水流加速。该水流加速的方法是由该V型间隙7直接带来的,其原理简单,便于实现。The outer side of the center of the guide cone ring 6 is an outer cone surface, the inner side of the center of the guide cone ring 6 is a tapered hole, and the top end of the accelerating water pipe 15 is an inner cone surface. There is a V-shaped gap 7 between the outer tapered surface and the inner tapered surface, and the value of the V-shaped gap 7 ranges from 0 to 1.5 mm. The speed of the accelerating water is adjustable, and the water speed ranges from 150 to 1000 m/min. The accelerating water of the coagulation bath enters in the direction perpendicular to the accelerating water pipeline of the coagulation bath. There is a V-shaped gap 7 between the outer conical surface of the guide cone ring 6 and the inner conical surface of the accelerating water pipe 15. The water flow enters from the upper main pipe of the V-shaped gap 7, and the water flow velocity increases instantly as it enters the V-shaped gap 7, and then A vacuum area is formed at the lower end of the V-shaped gap 7. When the subsequent water flow approaches the vacuum area, a certain adsorption effect will be produced, thereby realizing the acceleration of the water flow. The method of accelerating the water flow is directly brought about by the V-shaped gap 7, and its principle is simple and easy to implement.
其中,用于纤维素纺丝的凝固成型装置还包括导流弯头9和牵伸出口管17。导流弯头9与出水管16连通并对中,牵伸出口管17与导流弯头9连通并对中,使得牵伸出口管17的方向与水平方向的夹角ɑ的取值范围满足-15°<ɑ<15°。在这种情况下,能够使得本发明实施例提供的用于纤维素纺丝的凝固成型装置在应用过程中,最终的水流方向与纤维素纺丝丝束的牵伸方向一致,从而使应用本发明实施例提供的用于纤维素纺丝的凝固成型装置在进行纤维素纺丝的过程中,纺丝更加稳定,并且,减少纺丝过程中的纤丝断裂。优选地,牵伸出口管17的方向与水平方向的夹角ɑ的取值范围满足-8°<ɑ<10°。Wherein, the coagulation and forming device for cellulose spinning also includes a guide elbow 9 and a drawing outlet pipe 17 . The diversion elbow 9 is communicated with the water outlet pipe 16 and is centered, and the drawn outlet pipe 17 is communicated with the diversion elbow 9 and is centered, so that the value range of the angle ɑ between the direction of the drafted outlet pipe 17 and the horizontal direction satisfies -15°<ɑ<15°. In this case, the final water flow direction of the coagulation forming device for cellulose spinning provided by the embodiment of the present invention can be made consistent with the drawing direction of the cellulose spinning tow during the application process, so that the application of this During the process of cellulose spinning, the coagulation forming device for cellulose spinning provided by the embodiment of the invention has more stable spinning and reduces filament breakage during the spinning process. Preferably, the value range of the included angle ɑ between the direction in which the outlet tube 17 is drawn out and the horizontal direction satisfies -8°<ɑ<10°.
其中,用于纤维素纺丝的凝固成型装置还包括若干导流环8。导流环8设置于出水管16和/或导流弯头9和/或牵伸出口管17的内部,并且,导流环8的外径与容置其的内腔的直径相等。通过设置该若干导流环8,能够尽可能减小高速水流与出水管16和/或导流弯头9和/或牵伸出口管17接触产生的较大的瞬间冲击力,因此,能够延长出水管16和/或导流弯头9和/或牵伸出口管17的服役寿命。Among them, the coagulation and forming device for cellulose spinning also includes several guide rings 8 . The guide ring 8 is arranged inside the water outlet pipe 16 and/or the guide elbow 9 and/or the drawing outlet pipe 17, and the outer diameter of the guide ring 8 is equal to the diameter of the inner cavity in which it is accommodated. By arranging the several guide rings 8, the large instantaneous impact force generated by the contact of the high-speed water flow with the water outlet pipe 16 and/or the guide elbow 9 and/or the drawn outlet pipe 17 can be reduced as much as possible. Service life of the water outlet pipe 16 and/or the guide elbow 9 and/or the drawn outlet pipe 17 .
本实施例中,若干导流环8包括第一导流环8a、第二导流环8b和第三导流环8c。第一导流环8a设置于出水管16的入口处,第二导流环8b设置于导流弯头9的转弯处,第三导流环8c设置于牵伸出口管17的出口处。其中,若不设置该若干导流环8,第一导流环8a设置于出水管16的入口处,第二导流环8b设置于导流弯头9的转弯处,第三导流环8c设置于牵伸出口管17的出口处这几个位置刚好是高速水流形成的冲击力的直接作用点,因此,在第一导流环8a设置于出水管16的入口处,第二导流环8b设置于导流弯头9的转弯处,第三导流环8c设置于牵伸出口管17的出口处这几个位置设置该若干导流环8能够更加直接地减小高速水流在这三处位置产生的较大的瞬间冲击力,因此,能够延长出水管16、导流弯头9、牵伸出口管17的服役寿命。In this embodiment, the plurality of guide rings 8 include a first guide ring 8a, a second guide ring 8b and a third guide ring 8c. The first guide ring 8 a is arranged at the inlet of the water outlet pipe 16 , the second guide ring 8 b is arranged at the turn of the guide elbow 9 , and the third guide ring 8 c is arranged at the outlet of the drawn outlet pipe 17 . Wherein, if the several guide rings 8 are not provided, the first guide ring 8a is arranged at the entrance of the water outlet pipe 16, the second guide ring 8b is arranged at the turning of the guide elbow 9, and the third guide ring 8c The positions arranged at the outlet of the drawn outlet pipe 17 are just the direct acting points of the impact force formed by the high-speed water flow. 8b is arranged at the turn of the deflector elbow 9, and the third deflector ring 8c is arranged at the outlet of the draft outlet pipe 17. The arrangement of the plurality of deflector rings 8 can more directly reduce the high-speed water flow in these three positions. Therefore, the service life of the water outlet pipe 16, the guide elbow 9 and the drawn outlet pipe 17 can be prolonged.
其中,第一种多孔格栅、第二种多孔格栅5、导流锥环6和若干导流环8均由陶瓷制成。其能够利用陶瓷表面光滑的特性,可最大程度的减少凝固成型设备出口对丝束的磨损,同时,导流弯头最终将凝固成型设备出口水流水平导出,降低高速水流对丝束的冲击力,有效避免高速纺丝过程中部分纤维由于受力不均匀导致的断裂问题消除凝固浴水流的湍流,实现凝固浴液面平稳,减少纺丝过程中丝束波动造成的并丝,保证纤维质量。Among them, the first type of porous grid, the second type of porous grid 5, the guide cone ring 6 and several guide rings 8 are all made of ceramics. It can take advantage of the smooth surface of ceramics, which can minimize the wear of the tow at the outlet of the coagulation and forming equipment. At the same time, the guide elbow will eventually lead out the water flow at the outlet of the coagulation and forming equipment horizontally, reducing the impact force of the high-speed water flow on the tow. Effectively avoid the breakage of some fibers due to uneven force in the high-speed spinning process, eliminate the turbulence of the coagulation bath water flow, achieve a stable coagulation bath liquid surface, reduce the filament bundle caused by the fluctuation of the tow during the spinning process, and ensure the fiber quality.
本发明提供的用于纤维素纺丝的凝固成型装置的有效性验证实施例分别如下:Examples of validity verification of the coagulation molding device for cellulose spinning provided by the present invention are as follows:
实施例1~4Examples 1 to 4
通过对补充水流量Q1、加速水流量Q2、出水口直径、圆锥V型间隙等参数进行调节,获得不同条件下的水速,其结果如表1。By adjusting the parameters such as the supplemental water flow Q1, the accelerated water flow Q2, the diameter of the water outlet, and the conical V-shaped gap, the water velocity under different conditions was obtained, and the results are shown in Table 1.
表1Table 1
实施例5Example 5
聚合度为600的纤维素浆粕经过溶胀、溶解制备成纺丝液。纺丝液浓度为9%,纺丝温度为95℃,纺丝用喷丝板孔径为0.15mm,气隙高度20mm,纺丝速度300m/min,纤度1.67dtex;The cellulose pulp with a degree of polymerization of 600 is swollen and dissolved to prepare a spinning solution. The concentration of the spinning solution is 9%, the spinning temperature is 95°C, the diameter of the spinneret for spinning is 0.15mm, the air gap height is 20mm, the spinning speed is 300m/min, and the fineness is 1.67dtex;
高速纺丝装置中凝固浴盘使用凸台格栅,N1格栅水平放置,孔径为1800μm,N2格栅水平放置,孔径为1500μm,N3格栅竖直放置,孔径为750μm,;调节补充水流量Q1使浴盘中液面平稳;圆锥狭缝1.5mm,凝固成型设备出水口管径16mm,凝固成型设备导流弯头方向与水平方向夹角ɑ=5°,纺丝稳定,纺丝过程中无纤维断裂。The coagulation bath tray in the high-speed spinning device uses a boss grille, the N1 grille is placed horizontally with a pore size of 1800 μm, the N2 grille is placed horizontally with a pore size of 1500 μm, and the N3 grille is placed vertically with a pore size of 750 μm; adjust the flow of supplementary water Q1 makes the liquid level in the bath tray stable; the conical slit is 1.5mm, the diameter of the water outlet of the coagulation molding equipment is 16mm, the angle between the direction of the diversion elbow of the coagulation molding equipment and the horizontal direction is ɑ=5°, the spinning is stable, and the spinning process is stable. No fiber breakage.
实施例5中所制备纤维性能指标如表2所示。The performance indexes of the fibers prepared in Example 5 are shown in Table 2.
实施例6~8Examples 6 to 8
其他条件与实施例5相同,区别仅在于圆锥狭缝和出水口管径。圆锥狭缝依次为1.1mm、0.8mm、0.5mm,出水口管径依次为15mm、12mm、8mm。Other conditions are the same as in Example 5, the difference is only the conical slit and the diameter of the water outlet. The conical slits are 1.1mm, 0.8mm, and 0.5mm in sequence, and the diameter of the water outlet is 15mm, 12mm, and 8mm in sequence.
实施例6~8中所制备纤维性能指标如表2所示。The performance indexes of the fibers prepared in Examples 6-8 are shown in Table 2.
表2Table 2
实施例9~12Examples 9 to 12
其他条件与实施例5相同,区别仅在于实施例2中凝固成型设备导流弯头方向与水平方向夹角,依次为:无导流弯头,ɑ=-3°,ɑ=0°,ɑ=10°Other conditions are the same as in Example 5, the difference is only that the angle between the direction of the guide elbow of the solidification molding equipment and the horizontal direction in Example 2 is as follows: no guide elbow, ɑ=-3°, ɑ=0°, ɑ =10°
实施例9~12中所制备纤维性能指标如表3所示。The performance indexes of the fibers prepared in Examples 9-12 are shown in Table 3.
表3table 3
实施例13~14Examples 13 to 14
其他条件与实施例5相同,区别仅在于是否存在凸台格栅。Other conditions are the same as in Example 5, the difference is only whether there is a boss grid.
实施例13~14中所制备纤维性能指标如表4所示。The performance indexes of the fibers prepared in Examples 13-14 are shown in Table 4.
表4Table 4
尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。Although preferred embodiments of the present invention have been described, additional changes and modifications to these embodiments may occur to those skilled in the art once the basic inventive concepts are known. Therefore, the appended claims are intended to be construed to include the preferred embodiment and all changes and modifications that fall within the scope of the present invention.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention. Thus, provided that these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include these modifications and variations.
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