CN106118905A - A kind of high-effective disinfecting liquid detergent - Google Patents
A kind of high-effective disinfecting liquid detergent Download PDFInfo
- Publication number
- CN106118905A CN106118905A CN201610470580.XA CN201610470580A CN106118905A CN 106118905 A CN106118905 A CN 106118905A CN 201610470580 A CN201610470580 A CN 201610470580A CN 106118905 A CN106118905 A CN 106118905A
- Authority
- CN
- China
- Prior art keywords
- parts
- liquid detergent
- disinfecting liquid
- effective disinfecting
- ethylidene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000007788 liquid Substances 0.000 title claims abstract description 25
- 239000003599 detergent Substances 0.000 title claims abstract description 23
- 230000000249 desinfective effect Effects 0.000 title claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- HCFPRFJJTHMING-UHFFFAOYSA-N ethane-1,2-diamine;hydron;chloride Chemical compound [Cl-].NCC[NH3+] HCFPRFJJTHMING-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims abstract description 3
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000679 carrageenan Substances 0.000 claims description 4
- 235000010418 carrageenan Nutrition 0.000 claims description 4
- 229920001525 carrageenan Polymers 0.000 claims description 4
- 229940113118 carrageenan Drugs 0.000 claims description 4
- 239000001509 sodium citrate Substances 0.000 claims description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 4
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 238000005282 brightening Methods 0.000 claims description 3
- 229960001631 carbomer Drugs 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- KHJWSKNOMFJTDN-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical group [Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KHJWSKNOMFJTDN-UHFFFAOYSA-N 0.000 claims description 2
- ZDFDJKNMVBIUTI-UHFFFAOYSA-N 1-(2-bromopropan-2-yl)-2-dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1C(C)(C)Br ZDFDJKNMVBIUTI-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- AQLLBJAXUCIJSR-UHFFFAOYSA-N OC(=O)C[Na] Chemical compound OC(=O)C[Na] AQLLBJAXUCIJSR-UHFFFAOYSA-N 0.000 claims 1
- AGEZXYOZHKGVCM-UHFFFAOYSA-N benzyl bromide Chemical compound BrCC1=CC=CC=C1 AGEZXYOZHKGVCM-UHFFFAOYSA-N 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 17
- 241000894006 Bacteria Species 0.000 abstract description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract description 8
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 241000192125 Firmicutes Species 0.000 abstract description 2
- 230000000845 anti-microbial effect Effects 0.000 abstract description 2
- 239000003093 cationic surfactant Substances 0.000 abstract description 2
- 239000002736 nonionic surfactant Substances 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 241000233866 Fungi Species 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 8
- 241000222122 Candida albicans Species 0.000 description 7
- 229940095731 candida albicans Drugs 0.000 description 7
- -1 glutaraldehyde) Chemical class 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 241000191967 Staphylococcus aureus Species 0.000 description 6
- 241000588724 Escherichia coli Species 0.000 description 5
- 239000000645 desinfectant Substances 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 2
- 238000004500 asepsis Methods 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XPADKDZILXPJBG-UHFFFAOYSA-N [NH4+].[Br-].C[PH+](CC1=CC=CC=C1)C.[Br-] Chemical compound [NH4+].[Br-].C[PH+](CC1=CC=CC=C1)C.[Br-] XPADKDZILXPJBG-UHFFFAOYSA-N 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 229940023064 escherichia coli Drugs 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000013641 positive control Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 239000012137 tryptone Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of high-effective disinfecting liquid detergent, including the component of following weight portion: dodecyl dimethyl benzyl ammonium bromide 10～15 parts, double-track suspended self-propelled conveyor 5～10 parts, ethylidene oleamide ethylenediamine-hydrochloride 5～10 parts, fatty alcohol-polyoxyethylene ether 8～15 parts, thickening agent 0.1～0.5 part, chelating agen 0.1～0.5 part, deionized water 80～95 parts.The present invention uses three kinds of cationic surfactants and nonionic surfactant to compound, and by unique proportioning, reaches the effect of Synergistic antimicrobial, can not only effectively kill gram positive bacteria and gram negative bacteria, moreover it is possible to kill fungus, and bactericidal effect is good.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, be specifically related to a kind of high-effective disinfecting liquid detergent.
Background technology
Since outburst SARS in 2003, people have higher requirement for the clean hygiene of the medicated clothing of self-contact,
Do not require nothing more than medicated clothing softness without dirt, and require that clothing surface is without pathogenic bacterium.Corresponding, sterilizing class cleaning product is fast
Speed development.Disinfecting cleaning product mainly includes anti-bacterial hand lotion, high-effective disinfecting liquid detergent and disinfectant solution etc., these sterile products
Major antibacterial composition is chloride class (sodium hypochlorite, chlorine dioxide and dichloroisocyanuric acid sodium etc.), (hydrogen peroxide is water-soluble for peroxide
Liquid, SODIUM PERCARBONATE, Dexol etc.), phenols (such as parachlorometaxylenol), aldehydes (such as glutaraldehyde), ethers (such as triclosan),
Quaternary ammonium salt etc..Chloride class, peroxide disinfectant cost are relatively low, and sterilization is thorough, but big to skin irritation, and life-time service can cause
Medicated clothing turns to be yellow, becomes fragile.This two classes disinfectant has Strong oxdiative zinc, is corrosive the metal ornament of medicated clothing, is difficult to live with surface
The property compatibility such as agent, auxiliary agent, is typically used alone, should not be used in liquid detergent.Phenols, ethers disinfectant, stimulate less, but kill
Bacterium weak effect, disinfectant consumption is big, and cost is high, and water solublity is bad, and needing to add solvent could dissolve, it is difficult to ensure that on medicated clothing
Noresidue.Aldehydes bactericidal effect is good, broad-spectrum, and sterilization consumption is little, but it has penetrating odor, relatively costly, the most individually makes
With, it is used in handwashing liquid.Conventional quaternary ammonium salts class surfactant is the most degradable, and water solublity is bad, with other surfactants
Compatibility is poor, is used for sterilizing, and due to long-term a large amount of uses, antibacterial produces drug resistance to it, and antibacterial effect is the best.And sterilize
Class cleaning product is effective mainly for escherichia coli, staphylococcus aureus sterilization, but to Candida albicans without obvious effect.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high-effective disinfecting liquid detergent, and this liquid detergent is by kinds of surface activity
Agent compounds, broad-spectrum, and bactericidal effect is good, can not only effectively kill escherichia coli and staphylococcus aureus, moreover it is possible to
Effectively kill Candida albicans.
The technical scheme that the present invention provides is to provide a kind of high-effective disinfecting liquid detergent, including the component of following weight portion: ten
Dialkyl dimethyl Benzylphosphonium Bromide ammonium 10～15 parts, double-track suspended self-propelled conveyor 5～10 parts, ethylidene oleamide ethylenediamine
Hydrochlorate 5～10 parts, fatty alcohol-polyoxyethylene ether 8～15 parts, thickening agent 0.1～0.5 part, chelating agen 0.1～0.5 part, go from
Sub-water 80～95 parts.
Described chelating agen is 1-hydroxy ethylidene-1,1-diphosphonic acid or sodium citrate.
Described thickening agent is carbomer, sodium carboxymethyl cellulose, xanthan gum or carrageenan.
Further, above-mentioned high-effective disinfecting liquid detergent is possibly together with 0.2～0.5 weight portion brightening agent.
Described brightening agent is sodium ethylene diamine tetracetate.
The preparation method of the high-effective disinfecting liquid detergent of the present invention:
1) remove ionized water total amount 30～40% join in stirred tank, are heated to 70～80 DEG C, successively while stirring
Add dodecyl dimethyl benzyl ammonium bromide 10～15 parts, double-track suspended self-propelled conveyor 5～10 parts, ethylidene oleamide
Ethylenediamine-hydrochloride 5～10 parts and fatty alcohol-polyoxyethylene ether 8～15 parts, stir 0.5～1h and be allowed to mix homogeneously after dissolving,
To surfactant stock solution；
2) remove ionized water total amount 30～40% and join in stirred tank, be heated to 50～60 DEG C, add increasing while stirring
Thick dose, continue stirring until solution homogeneous transparent, obtain thickening agent stock solution；
3) surfactant stock solution and thickening agent stock solution are mixed, supply the deionized water of surplus, add chelating agen and increasing
White agent, after all dissolving, then regulates pH to 6.0～8.0, is antibacterial ethylene also.
The present invention uses three kinds of cationic surfactants and nonionic surfactant to compound, and by uniqueness
Proportioning, reaches the effect of Synergistic antimicrobial, can not only effectively kill gram positive bacteria and gram negative bacteria, moreover it is possible to kill true
Bacterium, bactericidal effect is good.
Detailed description of the invention
The present invention is further elaborated for specific examples below, but not as a limitation of the invention.
Embodiment 1
Dodecyl dimethyl benzyl ammonium bromide 10kg, double-track suspended self-propelled conveyor 5kg, ethylidene oleamide second two
Amine hydrochlorate 5kg, fatty alcohol-polyoxyethylene ether 8kg, carbomer 0.1kg, 1-hydroxy ethylidene-1,1-diphosphonic acid 0.1kg, deionized water 80kg.
Embodiment 2
Dodecyl dimethyl benzyl ammonium bromide 15kg, double-track suspended self-propelled conveyor 10kg, ethylidene oleamide second
Diamine hydrochloride 10kg, fatty alcohol-polyoxyethylene ether 15kg, sodium carboxymethyl cellulose 0.5kg, sodium citrate 0.5kg, deionization
Water 95kg.
Embodiment 3
Dodecyl dimethyl benzyl ammonium bromide 12kg, double-track suspended self-propelled conveyor 8kg, ethylidene oleamide second two
Amine hydrochlorate 8kg, fatty alcohol-polyoxyethylene ether 12kg, xanthan gum 0.3kg, 1-hydroxy ethylidene-1,1-diphosphonic acid 0.3kg, ethylenediaminetetraacetic acid
Sodium 0.4kg, deionized water 90kg.
Embodiment 4
Dodecyl dimethyl benzyl ammonium bromide 10kg, double-track suspended self-propelled conveyor 10kg, ethylidene oleamide second
Diamine hydrochloride 5kg, fatty alcohol-polyoxyethylene ether 15kg, carrageenan 0.1kg, sodium citrate 0.5kg, sodium ethylene diamine tetracetate
0.2kg, deionized water 95kg.
Comparative example 1
Dodecyl dimethyl benzyl ammonium bromide 25kg, fatty alcohol-polyoxyethylene ether 15kg, carrageenan 0.1kg, citric acid
Sodium 0.5kg, sodium ethylene diamine tetracetate 0.2kg, deionized water 95kg.
Experimental example
For proving the bactericidal effect of the anti-bacterial hand lotion of the present invention, carry out following bactericidal assay.
1, experiment material
1.1 test organismss: staphylococcus aureus ATCC 6538, escherichia coli 8099, Candida albicans ATCC 10231
1.2 nertralizers contain 3g/L lecithin, 30g/L tween, 5g/L sodium thiosulfate, the diluent of 10g/L glycine.
The preparation of 1.3 bacteria suspensions: staphylococcus aureus, escherichia coli and Candida albicans and Candida albicans are closely sought
After supporting agar plate differentiation culture, take its single colonies typical respectively and be inoculated in ordinary nutrient agar medium slant, at 37 DEG C
Lower cultivation 24h.Wash lower lawn, abundant shaken well dilution with the tryptone normal saline (TPS) of 1000mg/L and be made into reality
Test bacteria suspension standby.
2, nertralizer suspension Quantitative measurement experiment
Select staphylococcus aureus and Candida albicans as representative, design 6 groups of experiments, by bacteria suspension and embodiment 1
Liquid detergent or nertralizer mixing, act on to the stipulated time, sample inoculated and cultured, carry out count plate.
3, suspension quantitative bacteric idal experiment
Embodiment 1～4 and the liquid detergent Sterile Hard Water of comparative examples 1 be configured to respective concentration.Experiment is used with bacterium
Organic substance chaff interference equimultiple dilutes, and concentration is 1 × 108～5 × 108cfu/ml.Liquid detergent and experiment are placed in 20 DEG C ± 1 DEG C with bacterium
Constant temperature water bath.Draw 1.0ml bacterial suspension and inject in 4.0ml liquid detergent, mixing timing rapidly.Act on to each scheduled time,
Draw 0.5ml mixed liquor respectively to be added in 4.5ml nertralizer, mixing.After neutralizing 10min, suitably diluting, pour plate method counts
Remaining viable bacteria, in duplicate.Do positive control simultaneously, replace the liquid detergent of experimental example with PBS.Calculating kill logarithm value (KL)=
The logarithm value of matched group mean viable concentration-experimental group viable bacteria concentration logarithm value.
4, result
4.1 nertralizer identification experiment results
As seen from the above table, giving birth to the 6th group of asepsis growth, the 1st group of asepsis growth or only a small amount of bacterium, the 2nd group is compared the 1st group
Antibacterial is many, fewer than the 3rd, 4,5 groups of antibacterials, therefore judges, nertralizer can neutralize safely the disinfection composition in liquid detergent.
4.2 bacteria suspension quantitative bacteric idal experiment results
As seen from the above table, the liquid detergent bactericidal action time of embodiment 1-4 is short, and only effect 1min kills logarithm value and is greater than
5, can not only effectively kill escherichia coli and staphylococcus aureus, moreover it is possible to effectively kill Candida albicans, and bacteriocidal concentration is remote
Far below comparative examples 1.
Claims (5)
1. a high-effective disinfecting liquid detergent, it is characterised in that: include the component of following weight portion: dodecyl dimethyl benzyl bromide a-bromotoluene
Change ammonium 10～15 parts, double-track suspended self-propelled conveyor 5～10 parts, ethylidene oleamide ethylenediamine-hydrochloride 5～10 parts, fat
Polyoxyethylenated alcohol 8～15 parts, thickening agent 0.1～0.5 part, chelating agen 0.1～0.5 part, deionized water 80～95 parts.
High-effective disinfecting liquid detergent the most according to claim 1, it is characterised in that: described chelating agen is 1-hydroxy ethylidene-1,1-diphosphonic acid
Or sodium citrate.
High-effective disinfecting liquid detergent the most according to claim 1, it is characterised in that: described thickening agent is carbomer, carboxymethyl
Sodium cellulosate, xanthan gum or carrageenan.
High-effective disinfecting liquid detergent the most according to claim 1, it is characterised in that: brighten possibly together with 0.2～0.5 weight portion
Agent.
High-effective disinfecting liquid detergent the most according to claim 5, it is characterised in that: described brightening agent is ethylenediaminetetraacetic acid
Sodium.
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| CN201610470580.XA CN106118905A (en) | 2016-06-23 | 2016-06-23 | A kind of high-effective disinfecting liquid detergent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110106038A (en) * | 2019-06-04 | 2019-08-09 | 江苏爱特福84股份有限公司 | A kind of disinfecting washing liquid |
| CN115737611A (en) * | 2022-12-01 | 2023-03-07 | 成都科宏达科技有限公司 | Low-temperature stable animal medicated bath lotion |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906356A (en) * | 2010-08-12 | 2010-12-08 | 江苏爱特福84股份有限公司 | Laundry liquid and preparation method thereof |
| CN102643722A (en) * | 2011-11-18 | 2012-08-22 | 北京京东方光电科技有限公司 | Washing agent and preparation method thereof |
-
2016
- 2016-06-23 CN CN201610470580.XA patent/CN106118905A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906356A (en) * | 2010-08-12 | 2010-12-08 | 江苏爱特福84股份有限公司 | Laundry liquid and preparation method thereof |
| CN102643722A (en) * | 2011-11-18 | 2012-08-22 | 北京京东方光电科技有限公司 | Washing agent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110106038A (en) * | 2019-06-04 | 2019-08-09 | 江苏爱特福84股份有限公司 | A kind of disinfecting washing liquid |
| CN115737611A (en) * | 2022-12-01 | 2023-03-07 | 成都科宏达科技有限公司 | Low-temperature stable animal medicated bath lotion |
| CN115737611B (en) * | 2022-12-01 | 2024-05-14 | 成都科宏达科技有限公司 | Animal medicated bath lotion with low temperature stability |
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Application publication date: 20161116 |