AU9416998A - Foaming agent for leave-on foaming cosmetic compositions - Google Patents
Foaming agent for leave-on foaming cosmetic compositions Download PDFInfo
- Publication number
- AU9416998A AU9416998A AU94169/98A AU9416998A AU9416998A AU 9416998 A AU9416998 A AU 9416998A AU 94169/98 A AU94169/98 A AU 94169/98A AU 9416998 A AU9416998 A AU 9416998A AU 9416998 A AU9416998 A AU 9416998A
- Authority
- AU
- Australia
- Prior art keywords
- composition according
- hair mousse
- mousse composition
- group
- hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims description 70
- 239000004088 foaming agent Substances 0.000 title claims description 25
- 238000005187 foaming Methods 0.000 title claims description 19
- 239000002537 cosmetic Substances 0.000 title claims description 13
- 241000195940 Bryophyta Species 0.000 claims description 46
- 235000011929 mousse Nutrition 0.000 claims description 46
- 239000003380 propellant Substances 0.000 claims description 22
- 239000006260 foam Substances 0.000 claims description 20
- 239000012141 concentrate Substances 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000003755 preservative agent Substances 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 16
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 230000002335 preservative effect Effects 0.000 claims description 10
- 229960003237 betaine Drugs 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 229960005323 phenoxyethanol Drugs 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 1
- 241000947840 Alteromonadales Species 0.000 claims 1
- 150000003973 alkyl amines Chemical class 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- 229920001577 copolymer Polymers 0.000 description 19
- -1 nbutane Chemical compound 0.000 description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 229940048053 acrylate Drugs 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
- 125000002091 cationic group Chemical group 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- 150000001412 amines Chemical class 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 5
- 239000003915 liquefied petroleum gas Substances 0.000 description 5
- 229960004063 propylene glycol Drugs 0.000 description 5
- 235000013772 propylene glycol Nutrition 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 4
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 4
- 229960002216 methylparaben Drugs 0.000 description 4
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 3
- 229940008099 dimethicone Drugs 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 3
- 229940048866 lauramine oxide Drugs 0.000 description 3
- 229940094506 lauryl betaine Drugs 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 3
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 3
- 229960003415 propylparaben Drugs 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- IXOCGRPBILEGOX-UHFFFAOYSA-N 3-[3-(dodecanoylamino)propyl-dimethylazaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)CS([O-])(=O)=O IXOCGRPBILEGOX-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 2
- RZKSECIXORKHQS-UHFFFAOYSA-N Heptan-3-ol Chemical compound CCCCC(O)CC RZKSECIXORKHQS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229940067596 butylparaben Drugs 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229940008406 diethyl sulfate Drugs 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229920001519 homopolymer Chemical class 0.000 description 2
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 2
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- 150000002466 imines Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 235000013847 iso-butane Nutrition 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
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- ZITBHNVGLSVXEF-UHFFFAOYSA-N 2-[2-(16-methylheptadecoxy)ethoxy]ethanol Chemical compound CC(C)CCCCCCCCCCCCCCCOCCOCCO ZITBHNVGLSVXEF-UHFFFAOYSA-N 0.000 description 1
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- 238000013019 agitation Methods 0.000 description 1
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- 125000000278 alkyl amino alkyl group Chemical group 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000006226 butoxyethyl group Chemical group 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 235000008957 cocaer Nutrition 0.000 description 1
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
- 229940031728 cocamidopropylamine oxide Drugs 0.000 description 1
- 229940096362 cocoamphoacetate Drugs 0.000 description 1
- 229940047648 cocoamphodiacetate Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920013750 conditioning polymer Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- WTYGAUXICFETTC-UHFFFAOYSA-N cyclobarbital Chemical compound C=1CCCCC=1C1(CC)C(=O)NC(=O)NC1=O WTYGAUXICFETTC-UHFFFAOYSA-N 0.000 description 1
- 229960004138 cyclobarbital Drugs 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 150000008050 dialkyl sulfates Chemical class 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- HVTICUPFWKNHNG-UHFFFAOYSA-N iodoethane Chemical compound CCI HVTICUPFWKNHNG-UHFFFAOYSA-N 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 229940113094 isopropylparaben Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- UYPSRNLGLSAOPV-UHFFFAOYSA-N n,n-dimethyl-3-octadecanoyloxypropan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC[N+](C)(C)[O-] UYPSRNLGLSAOPV-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical class [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002851 polycationic polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- LOBXNKKFDKXXQW-UHFFFAOYSA-M sodium;3-[dodecanoyl(methyl)amino]propanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CCC([O-])=O LOBXNKKFDKXXQW-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
Ra~ialion 3.2(2)
AUSTRALIA
Patents Act 1990
ORIGINAL
COMPLETE
SPECIFICATION
STANDARD
PATENT
Application Number: Lodged: Invention Title: FOAMING AGENT FOR LEAVE-ON FOAMING
COSMETIC
COMMOsNLI The following statement is a full description of this invention, Including the best method of performing it known to us -1- FOAMING AGENT FOR LEAVE-ON FOAMING COSMETIC
COMPOSITIONS
TECHNICAL FIELD The present invention relates to a foaming agent comprising an amphoteric surfactant and an amine oxide which provides voluminous and stable foaming, and smooth nd mild touch to leave-on foaming cosmetic compositions. In particular, the present invention relates o hair S 10 mousse products comprising this foaming agent.
BACKGROUND
Cosmetic compositions such as shaving creams, hair mousses, spray foams, foaming lotions and foaming creams are aimed to be dispensed or sprayed as foams and applied on the 15 human skin or hair. These products are described in the present invention as "leave-on foaming Scosmetic products". One common characteristic desired for these leave-on foaming cosmetic products is a foam having favorable characteristics to the consumer such as voluminous and stable foaming, with smooth and mild touch to the skin and hair.
20Leave-on foaming cosmetic compositions for hair are usually referred to as -mousses", S 20 which term will be used in the present invention. Hair mousses were bom in Europe in the early 1980s. Hair mousses are fundamentally an aerosol foam, however, non-aerosol foams are also known. The general appeal of hair mousses canbe largely attributed to the ease of application and controlled amount of product which are possible from mousse formulation air mouse compositions are generally dispensed by a compressible dispenser or a valve and applied to the user's hand or specifically designed comb and spread through the hair. Alternatively. hair mousers hand m sitions can be directly applied to the hair by dispensing through nozzles. Hair ,,_,mousse Camp, mousses are formulated for the purpose of styling, setting, and arrangin or for other purposes such as shampooing. conditioning, treating, dyeing, and combinations thereof.
In recent years, some consumers have expressed a desire to have "alcohol-free" hair mousse products because of concerns relating to drying of the hair, or concerns of volatile solvents being emitted to the environment. In this context, alcohol refers to volatile primary alcohols having about 1 to 6 carbons, particularly ethanol. Alcohol is used in mousses for a nurber of reasons. First, the presence of volatile alcohol cn aid styling by decreasing drying time. However, it is assumed that tis drying has raised the conces of se consumers that alcohol is also drying hair. Second, alcohol aids foam breakage as the mousse is spread r~
^C
r rr n throughout the hair. It is known that foam breakage is a result of the ability of alcohol to act as a defoaming agent. Third. alcohol itself improves product preservation. Fourth, alcohol enhances the compatibiiily of the concentrate with the propellant, and acts as a solubility bridge between the resin and the water base. Fifth, alcohol is a good so!,.ent for dissolving oil base ingredients such as conditioning fatty alcohols. Consequently, elimination of alcohol from the formulation may affect product performance. Thus, there is a desire to provide a foaming agent which can be used in hair mousse compositions with or without alcohol.
The species and level of preservatives are also known to affect product performance.
Preservatives such as OMDM Hydantoin (dimethylol dimethyl hydanloin) andKalbdin'CG (mixture 10 of methylchloro-isothiazolinone and methyl isothiazolinone) are known as effective preservatives at low levels, however, are not approved for use in leave-on cosmetic products in a number of countries. Phenoxyethanol and EDTA are widely accepted for use, however, aiv not satisfactorily effective at low levels. Parabens such as methyl paraben, propyl paraben, butyl paraben. and LiquaPar oil (mixture of isobutyl paraben, isopropyl paraben, and butyl paraben) are also widely accepted for use. However, because parabens are lipophilic, they cannot dissolve in water, and thus have some formulation constraints. Methyl paraben and propyl oaraben ara difficull to formulate at high levels, for they are solid at room temperature. Thus, there is also a desire to provide a foaming agent which can be used in hair mousse compositions in combination with a wide range of preservatives.
The type of propellants are also known to affect produc performance. It is known that fluorohydrocarbons such as difluoroethane 152a (supplied by DuPont) can be used for a wide range of formulations. Propane and dimethyl ether can also be used for a wide range of formulations. However, propane is relatively combustible. Dimethyl ether when used at high levels can be corrosive. LPG (liquefied petroleum gas) is a mixture of mainly iso-butane, nbutane, and propane, and is available in different pressure grades. LPG is a relatively safe propellant, however, have some formulation constraints. Thus, there is also a desire to provide a foaming agent which can be used in hair mousse compositions in combination with a wide range of propellants.
Evaluation of product performance for hair mousse compositions vary depending on the purpose and concept of the product. In evaluating the performance of a hair mousse, one generally considers properties seen in three major stages: the properties of the foam upon dispensing from the package, the properties of the foam upon applying to the hair, and properties of end rc-3i to the hair. Properties considered upon dispensing include volume of foam and foam expansioiifspeed. It is known that when foam expansion is slow or delayed. 'pooling" of the product occurs. Propetiies considered upon applying to the hair include stability and breakability -3of the foam, non-soapiness, smoothness, softness, creaminess, and stickiness. Properties considered on the end results to the hair include style control, dry or wet feel of hair, washability, shine, moisturizing, conditioning, anti-static, and brushing.
OBJECT OF THE INVENTION It is an object of the present invention to provide a foaming agent which foams by being dispensed or sprayed, and provides voluminous and stable foaming, smooth and mild touch, and stylingiconditioning effect to leave-on foaming cosmetic compositions.
It is also an object of the present invention to provide a hair mousse compositio, 10 comprising said foaming agent which can be formulated in combination with a wide range of solvents, preservatives, and propellants.
It is further an object of the present invention to provide a hair mousse composition comprising said foaming agent which provides quick, voluminous foam expansion and reduced pooling upon dispensing.
It is further an object of the present invention to provide a hair mousse composition; comprising said foaming agent which provides a foam having appropriate foam breakdown under. shear and is easy to spread on hair, has a smooth, soft and creamy texture, and has a mild touch.
It is further an object of the present invention to provide a hair mousse composition comprising said foaming agent which provides good style control, conditioning effect, and good feel tr the hair.
SUMMARY OF THE INVENTION The present invention relates to a foaming agent comprising an amnhoteric surfactant and an amine oxide which foams by being dispensed or sprayed, and provides improved foaming 25 characteristics to leave-on foaming cosmetic compositions.
In one preferred embodiment of the present invention; the foaming agent is comprised in a hair mousse composition further comprising a solvent and a propellant. In a particularly preferred embodiment of the present invention, the foaming agent comprises amphoteric surfactant and an amine oxide at a weight ratio of 50:50 to 20:80 and further comprises a polymer, a solvent, a preservative, and a propellant.
DETAIL DESCRIPTION OF THE INVENTION All percentages and ratios are based on weight unl-ss otherwise specified. The total of components except for propellant is defined as a concentrate. For non-aerosol products containing no propellant, the concentrate is equal to the entire composition.
FOAMAING AGENT The foaming agent of the present invention comprises an amphotenic surfactant and an amine oxide. When comprised in hair mnousses such as hair mousses. the foaming agent is preferably comprised at a level of 0.1-205S. more preferably 0.1-10%A, most preferably 0.1-5% to the concentrate.
When comprised in hair mousses, the foaming agent of the present invention preferably comprises an amphoteric surfaclant and an amine oxide at a ratio of 50:20 to 5.95. more preferably 50:50 to 20:80.
Amohoteric Surfactant 110 Amphoteflo surfactants useful in the present invention are those having the following general formulae (1ll) and (IV and mixtures thereof
R
2
R
3 wherein RI is an alk~yl, alkenyl. ar)l, or hydroxyalkyl radical Of from about 8 to about 22 carbon atoms, optionally interrupted with up to aboul 10 ethylene oxide moieties andlor 1 glyceryl moiety.
R
2 and R 3 are individually selected from alkyl and monohydroxyalkyl groups containing from about 1 to about 3 carbon atoms. R 4 is atkylene. or hydroxyalkylene of from about I to about 4 carbon atoms. Z 1 is a radical selected from carhoxylate. sulfonate. sulfate, phosphate, or phosphonale. xis 0 or 1. ni is from about I to about 6, and m is 0 or 1. Preferably. R1 is an alkyl.
alkenyl, or hydroxyalkyl radical of from 11 to 17 carton atoms, R 2 and R 3 are individually selected from alkyl goups containing of from I to 3 carbon atoms. R 4 is alkylenie or hydroxyalkylefle of from 1. to 2 carbon atomns. Z' is a radical selected from carboxylate. sulfonate.
4 xis~ori, nlsl 1to3. and m NOrl RSCO:4(CH.2)y N(+)-CH2Z 2 5R8
R
6 wherein R 5 is CB-C22 alkyl, akenyl, aryi. r hydroxYalkyi preferably' CB-C22. R 6 is hydrogen or CHC2 1 R7 is CH 2 CH20H or CH 2 CH2OCH2H2C_00,11 R3 is hydrogen,
CH
2 CH2OH. or
CH
2 C 0 2 M~ 1CH COO N. 1 Z 2 is C0 2 M 1 or CH 2 CO-2M'. y is 2 or 3, preferably 2. M' is hydrogen or a cation, such as alkali metal, alkaline earth metal. amfh~.aknlamfim 10 sulfate, sulfonate, phosphate, or ahosphoflate.
R9-NH(CH2)a'CDOC~ 2 -(lI) A:,R9N[(CH2)ctCCOOM 2 12
-V
wherein a. is a number from 1 to 4, R 9 is c8-c22 alkyl, alkenyl, aryl, hydroxyalkyl or alkylatmidoalkyls. and N1 2 is hydrogen, alkali metal, alkaline earth metal. ammoniumn or 15 alkanolammoflium.
Examples of ampttoterc surfactants useful for hair mousse compositions having general formula are amide betaines. amnide sulfa betai.nes, alkyl betairtes, alkenyl betaines, sultaines (sulfo beta ines). and imidazoliniurn betaines. Examples of amphoteric Surfactant.t particularly useful for hair Mousse compositions are high alkyl betaifles, such as coco dimethyl ca .'oxymelhyl fletaine, cocamidopropyl betaine under the trade name of TEGO BETAINE. coca belaine. lauryl betaine under the trade name REWVOTERIC AMA IDIL-35, lauryl amidopropyl betaine. oleyl A b etaine, lauryl dimethyl carboxymetyl betaine. lauryl dimethyl alpha-carboxyethyl helaille. cetyl dimethyl carboxymnethYl betaine, lauryl bis-(2-hydroxyethyli caitoxymethyl betaine. stearyl bhs-(2hydroxyptoPYl) carboxymethyl beaine, oleyl dimethyl gam a -ca.ypoy btieluyibs A 25 (2-hydroxypropAl alpha-carboxyethyl betaine. cocamidopropyl hydroxy sultaine (sulfobetaifle).
A A~ A lauryl sultaine fjauryl sulfobetaifle), and cocamfidpompryl hydroxy sultaille under the trade name REVVOTERIC AM CAS_ Examples of amphoteflo surfactants useful for hair mouste compositions having general formula (11) are, marketed under the trade name NiRANOL and are understood to comprise a complex mixture of species, and caii exist in protonated and non-p-otonated species depending upon pH with respect to spp-cies that can have a hydrogen at R6. The imidazoliflium amphoteric surfactant hereof can be derived via an imidazalinium intermediate.
Preferred amphoteric surfactafits .of formula (1t) are monocarboxylates and dicarboxylates. Exam7ples of these materials include cocoa mphoccxpropmio nate, cocoamphocarboxypropionic acid. cocoamphocarboxyglycinate (alternately referred to as cocoamphodiacetate). and cocoamphoacetate.
Specific commercial products providing the imidazolinium derivative component of the present cornpositions include those said under the trade names MIRANOL C2M CONC. N.P MIRANOL C2M CONC. MIRANOL C2M SF, MIRANOL CM SPECIAL (Miranol, Inc.); ALKATERIC 2CIP (Alkaril Chemicals): cocoamphocarboxy propionate under the trade name NIKKOL AM-101, AMPHOTERGE W-2 (Lonza. Inc.): MONATERIC CDX-38. MONATERIC CSH- 32 (Mona Industries): REWOTERIC AM-2C (Rewo Chemical Group); and SCHEROITERIC MS-2 K (Scfier Chemicals).
Examples of amphoteric surfactants useful for hair mousse compositions having general formulae (1ll) and (IV) include n-alkytarninopropionates and n-alkyliminodipropionates. Such materials are sold under the trade name DER[PHAT by Henkel and MIRATAINE by Miranol, Inc.
Specific examples include N-lauryl-beta-amino propionic acid or salts thereof, and N-lauryl-betaimino-dipropionic acid or salts thereof.
AmineO0--de Amine oxides useful in the present invention are those having the following general formula (V)tertiary phosphine oxides, dialkyl sulfoxides, and mixtures thereof:
R
1 0 Rll wherein RIO is metnyi, ethyl, or hydroxyethyl, and R 11 is O8-C22 alkyl, alkenyl. or aryl, or
CH
3
(CH
2 )pCONH(CH 2 )q wherein p is 8-22 and q is Preferably, R 1 0 is methyl. R 1 1 is 25 alkyl. alkenlyl. p is 11-17,2and q is 1-3.
Examples of amine oxides particularly useful for hair mousse compositions are lauramine oxide under the trade name AMMONYX LO, and steara midopropyla mine oxide under the trade name VAROX 1770.- -7-
SOLVENT
Solvents used in the present invention are selected depending on variables such as the remainder components, viscosity, and desired foaming characteristic of the composition.
When comorised In hair mousses, the solvent is preferably comprised at a level of 99%, more preferably 80-99S%,. ost preferably-S5-98% of the concentrate.
Non-limiting examples: of isolvents useful in the present invention are: water, lower alcohols having 1 to 6 carbons such as ethanol and isopropanol, and polyhydric alcohols such as propylene glycol, hexylene glycol, glycerin, and propane diol, and mixtures thereof.
PROPELLANT
Propellants when used in the present invention are selected depending on variables such as the remainder components, the package, and how the product is designed to be used (standing or invert).
When comprised in hair mousses, the propellant is preferably comprised at a level of 0more preferably 0-30% of the entire composition. When no propellant is used, the hair mousse composition is usually provided in a package equipped with an air or gas mixing device.
Non-limiting examples of propellants useful in the present invention are: fluarohydrocarbons such as difluoroethane 152a (supplied by DuPont), dimethyl ether, and hydrocarbons such as propane, iso-butane, n-butane, and mixtures of hydrocarbons such as LPG (liquefied petroleum gas).
S' 20 OPTIONAL COMPONENTS Optional components can be included in the leave-on foaming cosmetic compositions of Sthe present invention, depending on the needs of the product Non-limiting examples of such Soptional components include additional surfactants, ultraviolet and infrared screening and absorbing agents, hair conditioning agents, skin conditioning agents, perfume, color, pH adjusters, polymers, dyes, vitamins, proteins, plant extracts, and nutrients.
Hair mousse compositions can comprise a polymer and a preservative, and can further comprise other optional components.
s Polymer Hair mousse compositions may further comprise a polymer. Such polymer comprise f 30 cationic, nonionic, anionic and amphoteric polymers. Polymer is typically included at a level of 0preferab'y 0-10% of the concentrate.
Polymeis suitable for use herein include any polymer soluble or colloidally dispersible in the aqueous phase (if water is the only solvent in the aqueous phase, the polymer should be soluble or dispersible in water if an optional cosolvent such as ethanol is present the polymer should be soluble or dispersible in the combined solvent system). Solubility/dispersibility is determined at ambient conditions of temperature and pressure (25*C at IlAt). Polymers for use in the comT.positions of the present invention include cationic, anionic, nonionic. and arnphoteric resins- Non-limiting examples of cationic polymers useful in the present invention include quatemnized cellulose ethers such as Polyquatemium 10 (hyd roxyethylcell ulose hydroxypropyl trimethylammoniumn chloride ether) under the trade name Ucare Polymer LR and Polyquaternium 4 hydroxyethylcellulase dimethlyldiallyl ammonium chloride copolymer) under the trade name Celquat. quatemnized vinyl pyrrolidone/alkyleminoacrylate or methacrylo:3 copolymers such as Polyquatemium 11 (polyvinylpyrrolidons N.N'-dimethylam inoae thylmeth acrylic acid copolymer diethyl sulfate salt) under the trade name Gafquat, methylvinylimidazoliurn vinylpyirolidone 4 quaternary ammonium copolymers commercially available under the trade name Luviqunt, vinylmethyl ether ethyl maleate copolymer (PVMIMA copolymer), PVPINA copolyrner under the -rde name Luviskol, polyvinyl alcohol, copolymers of polyvinylalcohol and crotonic; acid, copolymers of polyvinylalcohocl and maleic anhydride, hydfoxypropyl celluilose, hydroxypropyl guar gum, sodium polystyrene sulfonate, polyvinylpyrrolidone ethylm etha cry late methacrylic acid terpolymer. octylacrylarnide acrylate butylaminoethyl methacrylate copolymers, N-methacryloyl ethyl-M, 1'-dirnethyl ammonium gamma-N-methyl carboxy hetaine butyl methacrylate copolymer u nder the trade name Yukaforrner AM-75, and mixtures thereof.
Other examples of cationic polymers are cationic guar gums, for example.
hydroxypropyltrimethylammenium guar oum., qUatemizEd cellulose ethers such as copolymers of hydroxyethylcellulose with diaillyldimethyl ammonium chloride or with trimethyl ammonium substituted ePoxides, homopolymers of lower alkylamino alkyl acrylate or methacrylate monomers dimethyl amino ethylmethacrylate) and copolymers thereof with compatible monomers such as N-vinylpyrrolidone or with methacrylate derivatives such as methyl. ethyl abietyl and oleyl 2' methacrylates and mixtures thereof and!or with alkyl acrylates such as methyl and butyl acrylates and mixtures thereof. copolymers of dimethyldiallyl ammonium chlorfide and acrylamide, homopolymers of dimetryldiallyl ammonium chloride. vinyl iridazoliuim/vinyl pyrrolidone copolymers, and mixtures thereof.
Polycatfonic hair conditioning polymers can be derived from polymerizable cationic starting monomers, or from polynrzable nrtionic monomers which are modified subsequent to polymnerization to be of cationic character.
Examples of the cationic monomers include: monomers derived from acrylic acid Ofrmethacrylic acid, which is referred to hereinafter collectively as (meth)acrylic; acid, and a quatemized epihalohydrin product of a trialkyl amine having 1 to 5 carton atoms in the alkyl group such as (methy)adyloxypropyllfmethylammonium choride 2nd CmE-th)acryoxypropyltfleth'yla~mon ,ium bromide: (i i amine derivatives of (meth)acry'ic acid or amine derivatix es of (melh)acrylamide derived from (meth)acrylic acid or (Meth)acryjamide and a dialkylalkaflclarnife have C 1 -C4 alkyl giroups such as dimethylaminofethyl (meth)acrylate, diezhylaminoethyl (meth)aCcylate.
dimeihylamilopopyl (meth)acrylate, or dimethylaminofpropyl (meth)acrylamide; an,' ciii) dearivativeS of the pmd.!ucts of the q rou p Ci above by neutralizatio, with a n inorganic or organic acid, such as hydrochloric acid, or lactic acid, modification with a halogienated alkyl, sucli as methyl chloride, ethyl chloride, methyl bmamide, or ethyl iodide,() modification with a halogenated fatty acid ester such as ethyl moachloroscetate. or methyl rnonochloropropilate, and modification -with a dialkyl sulfate such as dimnelhyl su01ate, or diethyl sulfate.
Furthermolfre, the cationic; unsaturated moners include amine derivatives of allyl compounds such as diallyldimethylafflnoniurn chloride and the like as well as vinylim'idazolium quaternary ammonium monomers.
These cationic unsaturated monomners can be polymerized in cationic form, Or as an 2ltematiVe they can be polymerized in the form of their precursors, which are then modified to be cationic, for example, by a quaternizing agent (ea. ethyl mnonuchloracetate, dimethyl sulfate, etc.) Non-limiting examnples of noionic; monomers are acrylic or methacrylic acid esters of Cl- C24 alcohols, such as methanol, ethanol, 1-propanol, 2-propanol, 1-butariol. 2-methyl-1-propanrol, 1-pentanol, 2-pentanol, 3-pentaflol. 2-methyl-1-butanol, l-mathyl-1-butaflol, 3-methyl-1 -butanal, A-methyl-1-pentarlol, 2-fnethyl-l-pentanal, 3-methyl-i-pentall It-butanol, cyclohexal. 2-ethyl- 1-butanol, 3-heptanol, benzyl alcohol, 2-octanol. e-rnethytl-heptanol, 2-ethyP-I-hexanal, dimethyl-1-hexaflol, 3,5,5Slrimethyl-1-hexarrol, 1-decanol. 1-dodecanol, l-hexadecanlfl,
I-
octadecanol, and the like, the alcohols having from about 1-24 carbon atoms.- styrene; chlorostyrene- vinyl esters 5uch as vinyl acetate; vinyl chloride-, vinylidene chloride; acrylonitrile; aipha-methy styreneC; t-butylstyrene; butadiene-, cydoahexadiele: ethylene, propylene; inyl toluene; alkoxyalkyl (meth)acrylate. such as methoxy ethyl (meth)acrylate and butoxyethyl (methlacylate; and mixures thereof. Other nanionic monomers include acrylate and methacrylate derivatives such as altyl acrylate and methacrylate. cyclohexyl acrylate and methacrylate. olayl acrylate arid methacrytate, benzyl aciytate and methacrylate, trahydrofurfuryl acrylta and methaCrylate, ethylene qlycol diacrylate and -methacrylate, 1,3butyleneialycal d-acrylate and me-thactlate, dia-cetaflacrylamfide, isobomyl (rrnelh)acryiate, and the like.
Non-limiting examples of pola: monomers include acvaide N,Ndimne'hy!n-crylarnide, mnethacytamide. bt, .md. ehrynire.a"2vmrice. aczylate alcohols (en.C 2 -C5 acrylate alconols such 25 hydro--y~thy: acr-ylate, hydroxyproxyl acrylate).
hydroxyethyl hbethacrylate, hydroxypropyi Methacylate. vinyi pyrrol~done, vinyl! ethers,. such as Smethyl vinyl ether, acyl iaones and vinyl pyridine. ally[ alcohols. vinyl alcohols and vinyl caprolactarri.
Ncni-imiting examples of polycationic polymers include cationic polysaccharides, homopotymers of dirnethyldiallyl ammoniurn chloride, copolymers of dirnethyldiallyt amnmonium chloride and acrylamIde. cationic amino-functionral homogolymers and copolymers derived from 210 acrylic acid andior methacrylic acid, e-soecially from alkylaminoaiky acrylate and methacrylate monomers such as dimethytarninoelhyl acrytate and methacrylate, polyalkyene imines and jethoxy potyalkytene imines, vinylirnidazoliumb. inyloyrrolidone quaternary amn-mnium copolymers, and mixtures thereof.
Preservative 15 H-afr mousse compositions can further comprise a preservative. Such~ preservative is preferably included at a level of 0-51/, nmore preferably 0-311 of tl-e concentrate.
Non-limiting examples of preservatives useful in the present invention are OMOMA: 25 at tefain g agie t o f the presntiin iton C on-lmitinrexae of yclr-sach azilionl uact ety incusoiu lauroyf imidtolylra. orpjeotate, odium ancdy issnats e sodu cccoiethyi efseulfonpaten, isoste~ ara 1 and butropon TC-42 (a'-CcyN-ahiarte Olaroi ai dimeth nae. diinlststn i yial nlddatalvlols.ta 0Har mousse compostots cay further comprise, advdiet fotional compcneants. Such dto~ suctri cm p enns ince;taicer and ioity oders suc ra itants wich. o onot csainfatts ancd, sodium clorid, ed sfrodim sulate, sl odimon acgyletnt (s a ctiu oal com ne nts lchld, Mi alchol and piscit oldi~ltasrigaet uta c salicylate, pH adjusting agents such a-s -:itric acd, succinic acid, sodium hydroxide anid, -11triethanolamine, coloring agents, hair oxidizing agents such as hydrogen peroxide, perborate salts and persulfate salts, hair reducing agents such as thioglycolates, perfumes, perfume solubilizing agents such as polyethylene glycol fatty acid esters, sequestering agents,- polymer plasticizing agents such as glycerin and propylene glycol, and volatile and non-volatile silicone fluids. Such optional ingredients are typically included at a level of 0.01-20%; preferably from 0.1-10% of the concentrate.
*U
e ti g f -12-
EXAMPLES
The following examples illustrate the compositions of the present invention, but are not intended to be limiling thereofl. All percentages and ratios are based on weight unless otherwise specified.
TABLE 1 C C* .54 0.
COMPONENT
Concentrate Propellant L.P.G.
Total of Composition COMPONENTS IN CONCENTRATE Cocamidopropyl Betaine' Cocamidopropyl Hydroxysultaine 2 Lauryl Betaine'3 Cocoamphocarboxypropionate" Lauramine Oxide 5 Cocamidopropylamine Oxide'6 Sodium lauroyl methylarninopropionate~g Isosteareth 10.10 Lauramide DEVI 1 Polyquatemium 4 Palyquatemiumn 7 Polyquatemium 11 Ethyl ether of PVMJMA copolymer Ethanol Methyl Paraben Propyl Paraben Phenoxyethanot* Disadiumn EDTA Dimethicone Copolyol Perfume Propylene Glycol DI Water Total of Concentrate AMOUNT EXAMPLE NO.
1 2 3 4 94.0 90.0 75.0 95.0 6.0 10.0 25.0 100 10JO 100 100 0.10 0.10 0.05 0.05 0.20 0.40 2.50 0.30 0.20 0.10 0.20 0.30 0.10 0.05 0.15 3.00 1.00 1.00 2.00 6.00 15.00 0.25 0.20 0.10 0.30 0.25 0.10 0.20 0.10 0.05 0.50 g.s. g-s.
100 100 0.15 0.20 0.15 0.25 0.10 0.10 0.10 0.05 0.10 0.10 100 100 -13- TABLE 2
COMPONENT
Concentrate Propellant L.P.G.
AMOUNT EXAMPLE NO.
6 7 93.0 93.0 72.5 7.0 7.0 27.5 Total of Composition 100 100 100 C CS a C
C
COMPONENTS IN CONCENTRATE Cocamidopropyl Betaine 1 Lauryl Betaine*3 Cocoamphocarboxypropiortate* 4 Lauramine Oxide's Cocarnidapropylamine Oxide*5 Sodium Cocoamphohydroxypropysulfonate& 7 Sodium Cocoyl Isethionate& 9 Isosteareth 1 0" Lauramide DEA' 1 1 Polyquatemiumn 7 Polyquatemium 10 Polyquatemiumn 11 PVPNA Copolymer Ethyl ether of PVMIMA copolymer Ethanol 0.20 0.20 0.15 1.00 1.00 1.00 2.00 5.00 3.00 0.20 0-15 Methyl Paraben Propyl Paraben Phenoxyethanol Disodiumn EDTA Dimethicone Copolyol Perfume Propylene Glycol DI Water 0.07 0.075 0.50 100 100 Total of Concentrate _I Y- C *1 Active of TEGO BETAINE S (30% solution).
*2 Active of REWOTERIC AM CAS (50% solution).
"3 Active of REWOTERIC AM DML-35 (35% solution).
'4 Active of NIKKOL AM-101 (40% solution).
Active of AMMONYX LO (30% solution).
"6 Active of VAROX 1770 (35% solution).
"7 Active of MIRANOL CS CONC. (45% solution).
"8 Active of ALANON ALE (30% solution).
'9 Active of DIAPON Cl-R (90% solution).
'O10 Active of AROSURF 66 E10 (100% solution).
11 Active of STANDAMID LDS-RV (30% solution).
The components shown in Tables 1 and 2 can be prepared by any conventional method well known in the art. A suitable method is as follows: Propyleneglycol, dimethicone copolyol, preservatives, polymers, and foaming agent are added into distilled water under agitation at room temperature until homogenized. The obtained mixture is heated up to 70-75 0 C. Other optional components are added to the heated mixture, and agitated until homogenized. The obtained mixture is allowed to cool to 30-40 0 C, and perfume S* and and other heat sensitive components such as sodium cocyl isethionate are added. The obtained concentrate is packed into cans with propellant.
"Ccmprises/comprising" when used in this specification is taken to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers, steps, components or groups thereof.
a 6 r
Claims (14)
1. A foaming agent for leave-on foaming cosmetic composition which foams by being dispensed or sprayed, comprising: an amphoteric surfactant selected from the group consisting of general formula R 1 fCONH(CH2)nxN(+)- CH2CR 4 )mZ 1 -0I R 3 wherein R 1 is an alkyl, alkenyl, aryl, or hydroxyalkyl radical of from about 8 to about 22 carbon atoms, optionally interrupted with up to about 10 ethylene oxide moieties andlor 1 glyceryl moiety. R 2 and R 3 are individually selected from alkyl and mono Nydroxyalkyl a. groups containing from about 1 to about 3 carbon atoms, R 4 is alkylene, or hydroxyalkylene of from about i to about 4 carbon atoms, Z 1 is a radical selected from carboxylate, sulfonate, sulfate, phosphate, or phosphonate, x is 0 or 1, n is from about 1 to about 6, and m Is 0 orn; 'general formula (11): 1 15 R 5 CON(CH2)y NC-I)-CH2Z 2 wherein R5 is C8-C22 alkyl, alkenyl, aryl, or hydroxyalkyl, R 6 is hydrogen or 20 CH
2 CO 2 R 7 is CH2CH2OH or CH2CH2OCH2CH2COOM 1 RB is hydrogen. CH2CH2OI-, or CH2CI-2OCH2CH2COOM', Z 2 is C02M 1 or CH2CO2M', y is 2 or 3, M1 is hydrogen or a cation, such as alkali metal, alkaline earth metal, ammonium: alkanol ammonium, sulfate, sulfonate, phosphate, orphosphonate; general formula (1ll): R 9 -NH(CH2) 0 .CCOOM 2 -Il -16- wherein cL is a number from 1 to 4, R 9 is Ca-C22 alkyl. alkenyl. ar~jI, hydroxyalkyl or alkytamidoalkyls, and M 2 is hydrogen, alkali metal, alkaline earth metal, ammonium or ,alkanolammaniurm general formula (lV: Rg-N((CH 2 0 .COOM 2 ]2 -(IV) wherein cL is a number from I to 4. R 9 is C8-C22 alkyl, alkenyl. aryl, hydroxyalkyl or alkylamidoalkylls,.and M 2 is hydrogen, alkali metal, alkaline earth metal, ammonium or alkanolammot i~ul;. and mixtures hereof: and ~a ane oxide :selected from the group consistnofgerlomuaV) R 1 1 W nPrein RIO is methyl, ethyl, or hydroxyelhyl, and RI I s C8-C22 alkyl, alkenyl. or aryl. or CH 3 (CH 2 )pCONHCCH2)q wherein p is 8-22 and q is 1-6: and mixtures thereof, o2. The foaming agent useful for leave-on foaming cosmetic compositions according to Claim 1 wherein said amphoteric surfaclant is selected from the group consisting of general formula and mixtures thereof.
3. A hair mousse composition according- to Claim 2 which foams by being dispensed or sprayed, comprising by weight: i) 40-100% concentrate comprising: a) 0-1-20% foaming agent: and b) 60-990/ solvent:, and ii 0-O% 'ropellant. -17-
4. The hair mousse composition according to Claim 3 comprising by weight: i) 40-100% concentrate comprising: a) 0.1-10% foaming agent; b) 80-99% solvent; c) 0-15% polymer: and d) 0-5% preservative; and ii) 0-60% propellant.
The hair mousse composition according to Claim 4 comprising by weight: i) 70-100% concentrate comprising: a) 0.1-5% foaming agent comprising betaine and alkyl amine oxide; b) 85-98% solvent; and c) 0-10% polymer; d) 0-3% preservative; and ii) 0-30% propellant.
6. The hair mousse composition according to Claim 3 wherein said solvent is substantially selected from the group consisting of water and polyhydric alcohol.
7. The hair mousse composition according to Claim 4 wherein said solvent is substantially selected from the group consisting of water and polyhydric alcohol.
8. The hair mousse composition according to Claim 5 wherein said solvent is substantially selected from the group consisting of water and polyhydric alcohol.
9. The hair mousse composition according to Claim 3 wherein said propellant is substantially a hydrocarbon.
The hair mousse composition according to Claim 4 wherein said propellant is substantially a hydrocarbon.
11. The hair mousse composition according to Claim 5 wherein said propellant is substantially a hydrocarbon. fG* ~9d 4'* 4 a ft 40 -C. o of,. a
12. The hair mousse composition. according to Claimn 3 wherein said, preservative is substantially select-d from the group consisting of parabens. Ohenoxyethar.i and EDTA and its salts.
13. The hair mousse composition according to Claim 4 wherein said preservative is substantially selected from the group consisting of parabens, phenoxyethahol, and EDTA and its salts.
14. The hair mousse composition according to Claim 51 wherein said preservative is substantially selected from the group coasisting of parabens, phenoxyethanol, and EDTA and its salts. DATED this 26th day of:Novemnber 1998. THE PROCTER GAMBLE CCMPANY WATERMARK PATENT TRADET4ARK A'TORNEYS 290 BUPWCX)D ROAD HM-nHORN. VIC- 3122.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU94169/98A AU9416998A (en) | 1993-11-18 | 1998-11-26 | Foaming agent for leave-on foaming cosmetic compositions |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15423193A | 1993-11-18 | 1993-11-18 | |
| US154231 | 1993-11-18 | ||
| AU79730/94A AU7973094A (en) | 1993-11-18 | 1994-10-11 | Foaming agent for leave-on foaming cosmetic compositions |
| AU94169/98A AU9416998A (en) | 1993-11-18 | 1998-11-26 | Foaming agent for leave-on foaming cosmetic compositions |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU79730/94A Division AU7973094A (en) | 1993-11-18 | 1994-10-11 | Foaming agent for leave-on foaming cosmetic compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU9416998A true AU9416998A (en) | 1999-01-28 |
Family
ID=27156356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU94169/98A Abandoned AU9416998A (en) | 1993-11-18 | 1998-11-26 | Foaming agent for leave-on foaming cosmetic compositions |
Country Status (1)
| Country | Link |
|---|---|
| AU (1) | AU9416998A (en) |
-
1998
- 1998-11-26 AU AU94169/98A patent/AU9416998A/en not_active Abandoned
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