Holmbo et al., 2016 - Google Patents
A catalytic intermolecular formal ene reaction between ketone-derived silyl enol ethers and alkynesHolmbo et al., 2016
View PDF- Document ID
- 15085410590454873564
- Author
- Holmbo S
- Godfrey N
- Hirner J
- Pronin S
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
A catalytic formal ene reaction between ketone-derived silyl enol ethers and terminal alkynes is described. This transformation is uniquely capable of bimolecular assembly of 2- siloxy-1, 4-dienes and can be used to access β, γ-unsaturated ketones containing …
- 150000002576 ketones 0 title abstract description 115
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
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