References
Song R, Zhao G, Restrepo-Flórez J M, et al. Ethylene production via photocatalytic dehydrogenation of ethane using LaMn1−xCuxO3. Nature Energy, 2024, 9(6): 750–760
Welch G C, Cabrera L, Chase P A, et al. Tuning Lewis acidity using the reactivity of “frustrated Lewis pairs”: Facile formation of phosphine-boranes and cationic phosphonium-boranes. Dalton Transactions, 2007(31): 3407–3414
Ghuman K K, Wood T E, Hoch L B, et al. Illuminating CO2 reduction on frustrated Lewis pair surfaces: Investigating the role of surface hydroxides and oxygen vacancies on nanocrystalline In2O3−x(OH)y. Physical Chemistry Chemical Physics, 2015, 17(22): 14623–14635
Yan X, Gao B, Zheng X, et al. Cooperatively tailored surface frustrated Lewis pairs and N-doping on CeO2 for photocatalytic CO2 reduction to high-value hydrocarbon products. Applied Catalysis B: Environmental, 2024, 343: 123484
Pu Y, Luo Y, Wei X, et al. Synergistic effects of Cu2O-decorated CeO2 on photocatalytic CO2 reduction: Surface Lewis acid/base and oxygen defect. Applied Catalysis B: Environmental, 2019, 254: 580–586
Tian X R, Jiang X L, Hou S L, et al. Selectively regulating Lewis acid-base sites in metal–organic frameworks for achieving turn-on/off of the catalytic activity in different CO2 reactions. Angewandte Chemie International Edition, 2022, 61(18): e202200123
Huang Z Q, Su X, Yu X Y, et al. Theoretical perspective on the design of surface frustrated Lewis pairs for small-molecule activation. Journal of Physical Chemistry Letters, 2024, 15(20): 5436–5444
Li M, Wang H, Yang Z, et al. Synergistic enhancement of alkaline hydrogen evolution reaction by role of Ni–Fe LDH introducing frustrated Lewis pairs via vacancy-engineered. Chinese Chemical Letters, 2024110199
Yu X Y, Huang Z Q, Ban T, et al. Finding natural, dense, and stable frustrated Lewis pairs on wurtzite crystal surfaces for small-molecule activation. Angewandte Chemie International Edition, 2024, 63(23): e202405405
Chen W, Han J, Wei Y, et al. Frustrated lewis pair in zeolite cages for alkane activations. Angewandte Chemie International Edition, 2022, 61(15): e202116269
Huang Z Q, Zhang T, Chang C R, et al. Dynamic frustrated Lwis pairs on ceria for direct nonoxidative coupling of methane. ACS Catalysis, 2019, 9(6): 5523–5536
Ma J, Zhang Q, Chen Z, et al. Design of frustrated Lewis pair in defective TiO2 for photocatalytic non-oxidative methane coupling. Chem Catalysis, 2022, 2(7): 1775–1792
Ryan M F, Fiedler A, Schroeder D, et al. Radical-like behavior of manganese oxide cation in its gas-phase reactions with dihydrogen and alkanes. Journal of the American Chemical Society, 1995, 117(7): 2033–2040
Ozin G. Accelerated optochemical engineering solutions to CO2 photocatalysis for a sustainable future. Matter, 2022, 5(9): 2594–2614
Sun W, Cao X E. Photothermal CO2 catalysis: Fom catalyst discovery to reactor design. Chem Catalysis, 2022, 2(2): 215–217
Wang S, Tountas A A, Pan W, et al. CO2 footprint of thermal versus photothermal CO2 catalysis. Small, 2021, 17(48): 2007025
Acknowledgements
This work was supported by the National Key R&D Program of China (Grant No. 2021YFF0502000) the National Natural Science Foundation of China (Grant No. 52372233), and the China Postdoctoral Science Foundation (No. 2024M762820).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing Interests The authors declare that they have no competing interests.
Rights and permissions
About this article
Cite this article
Sun, W., Wang, S. Surface frustrated Lewis pairs in perovskite enhance photocatalytic non-oxidative conversion of ethane. Front. Energy 19, 413–416 (2025). https://doi.org/10.1007/s11708-025-0982-8
Received:
Accepted:
Published:
Version of record:
Issue date:
DOI: https://doi.org/10.1007/s11708-025-0982-8