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Advanced filters: Author: América Y. Torres-Boy Clear advanced filters

  • The role of cationic intermediates in the benzylidene-directed synthesis of 1,2-cis glycosidic linkages is unclear. Now cryogenic infrared spectroscopy provides insight into the SN1 mechanism of benzylidene-directed glycosylation reactions. The analysis reveals that cationic intermediates form anhydro cations through a two-step process, which correlates with the observed stereochemical outcome.

    • Chun-Wei Chang
    • Kim Greis
    • Kevin Pagel
    ResearchOpen Access
    Nature Synthesis
    Volume: 3, P: 1377-1384