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Showing 1–5 of 5 results
Advanced filters: Author: Ming-Yao Huang Clear advanced filters

  • Iron-catalyzed C–C reductive coupling avoids sensitive reagents but struggles to build quaternary centers. Using phosphine-ligated Fe and carbonyl directing groups, this work enables tertiary–primary/secondary C(sp³) coupling under mild conditions.

    • Qiao Zhang
    • Xiang-Yu Liu
    • Shou-Fei Zhu
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-8

  • The Taiwan Precision Medicine Initiative recruited and genotyped more than half a million Taiwanese participants, almost all of Han Chinese ancestry, and performed comprehensive genomic analyses and developed polygenic risk score prediction models for numerous health conditions.

    • Hung-Hsin Chen
    • Chien-Hsiun Chen
    • Cathy S. J. Fann
    ResearchOpen Access
    Nature
    P: 1-10

  • Allenes are versatile substrates in synthetic chemistry. Now an iron catalyst enables unusual regioselectivity by mediating an electrophilicity reversal of allenes for stereoselective alkenylzincation reactions affording 1,4-diene zinc products.

    • Jun-Jia Chen
    • Mu-Han Guan
    • Shou-Fei Zhu
    Research
    Nature Catalysis
    Volume: 8, P: 178-186

  • While the counterion of a metal catalyst can influence the activity and selectivity of reactions, this phenomenon is rarely observed in carbonzincation reactions. Herein, the authors report increased catalytic efficiency in the iron-catalyzed alkylzincation of alkynes when the weakly coordinating bulky counterion tetrakis(3,5-bis(trifluoromethyl)phenyl)borate is added.

    • Lu-Jie Li
    • Qiao Zhang
    • Shou-Fei Zhu
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-12